WO2009017387A2 - Composites and methods of the articles manufacturing by using based on plastic matrix organic fibers filled composites, by plastic injection molding method - Google Patents

Composites and methods of the articles manufacturing by using based on plastic matrix organic fibers filled composites, by plastic injection molding method Download PDF

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Publication number
WO2009017387A2
WO2009017387A2 PCT/LV2008/000005 LV2008000005W WO2009017387A2 WO 2009017387 A2 WO2009017387 A2 WO 2009017387A2 LV 2008000005 W LV2008000005 W LV 2008000005W WO 2009017387 A2 WO2009017387 A2 WO 2009017387A2
Authority
WO
WIPO (PCT)
Prior art keywords
fibers
articles
gas
polyprophylene
additives
Prior art date
Application number
PCT/LV2008/000005
Other languages
English (en)
French (fr)
Other versions
WO2009017387A3 (en
Inventor
Raimonds Cirulis
Original Assignee
Rungis, Aigars
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rungis, Aigars filed Critical Rungis, Aigars
Publication of WO2009017387A2 publication Critical patent/WO2009017387A2/en
Publication of WO2009017387A3 publication Critical patent/WO2009017387A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/22Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials

Definitions

  • the invention is related to the plastic matrix based composites with high level of f ⁇ llament as well based on them articles manufacturing with plastic injection molding technologies in combination with gas or gas—liquid injection support method, including plastic co-injection method used.
  • This method is especially suitable for such an articles manufacturing as pallets, one-piece chairs, boxes, body parts of the automotive, large size cable bobbins, other products manufacturing where low weight, high mechanical properties, aesthetic design and high requirements to the ecological aspects of the articles are demanded- their recyclability, biodestruction, reduced energy consumption in their manufacturing process.
  • the invention is related as well to innovative receptions of the composites, which are usable without above mentioned gas or gas-liquid assisted injection molding method used, and are usable for the articles manufacturing by using standard plastic injection molding technology.
  • (OOlO)Patent CN 1837277 is protecting inorganic nanoparticles and plastic- woodfibers composites with recepie: 24-98 % plastic, 0-70 % organic fibers, 1-30 % inorganic nanoparticles.
  • (OOll)Patent CN 1850900 is protecting a composite: 100/25 -100/170 parts of the weight polyprophylene-woodfibers mixture, 1-40 parts of the weight nanometric density intensificator, 0-10 parts chlorinated polyethylene, 1.0-3.0 antioxydant, 0.5-3.0 parts polyethylene vax, 0.5-3.0 parts stearine acid , and 2.0-10% nanometric density dispersion agent/.
  • Patent US 7151125 is protecting polymer-cellulosic fibers composite, which consist from polymer-cellulose fibers composition, where from 30 to 70% is usded polymer, from 70 to30%-cellulose fibers and 1 to 7% lubricant.
  • the fibers are piling and blocking, as well absorbing the gas or gas-water presure,
  • plastic injection molding technology and high ( 40-65%) fillament level compond materials , including such a type which are biologically diestructing and contain natural fibers-flax,cotton, hemp,woodfibers e.t.c, and thermoplastic compounds (monomeres, ologomeres or polymer compositions) as couplers for different articles manufacturing, in combination with plastic co-injection include ;
  • Plastic and gas or liquid co-injection method is realized in a way as until the composite mass is still viscosous in locations of the article channels , but the part of the composite mass near the mold inner surface has been already crystalized, the plastic co- injection is performed, by immediate following gas injection after it. If to use Gas -liquid assisted injection, immediate after snail amount of the gas injected, the liquid is to be injected. As the result of gennerated pressure by gas or gas/liquid the plastic together with still non-cry stalized composite is pushed longitudinally forward the channel. In a such of way, the co-injected plastic is forming the backing layer.
  • the method in adition increase the tenacity of the articles as the plastic layer in hollow chanels is performing as sandvich, and is preventing the porous character of inner surface of the hollow channels (which weaken the physical-mechanic properties of the article).
  • (0033)offered composites are providing possibility the articles to form even at +80/+85 degrees Celsium hot molds , as the crystallization of the materials begins at temperature +125/+130 0 C , resulting to shortened manufacturing cycle time and consumption of energy ( to compare , it is to be noted that polyprohylene and polyethylene traditionally is formed in + 30 0 C hot molds, and the cooling time is much longer nor organic fibers filled composites);
  • FIG.5 where schematically is shown the constuction of the tare box , there are used following notations: (8)- basic corpey of the article, (9i)-hollow reinforcement ribs,(13)- plastic and/or gas and/or liquid possible co-injection alocation;
  • mentioned fibers can particularly or in full to replace flax, sizal, hemp and other such a kind of fibers usage in mentioned composites, in lieu of it using woodfibers, straws and other low cost fibers.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/LV2008/000005 2007-07-30 2008-07-30 Composites and methods of the articles manufacturing by using based on plastic matrix organic fibers filled composites, by plastic injection molding method WO2009017387A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
LVP-07-87A LV13891B (lv) 2007-07-30 2007-07-30 Kompozīcijas un paņēmieni izstrādājumu ražošanai, pielietojot īpašus ar organisko šķiedru pildītus, uz plastmasu matrici bāzētus kompozītus, ar plastmasas spiedienliešanas metodi
LVP-07-87 2007-07-30

Publications (2)

Publication Number Publication Date
WO2009017387A2 true WO2009017387A2 (en) 2009-02-05
WO2009017387A3 WO2009017387A3 (en) 2009-05-14

Family

ID=40091255

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/LV2008/000005 WO2009017387A2 (en) 2007-07-30 2008-07-30 Composites and methods of the articles manufacturing by using based on plastic matrix organic fibers filled composites, by plastic injection molding method

Country Status (2)

Country Link
LV (1) LV13891B (lv)
WO (1) WO2009017387A2 (lv)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880464A (zh) * 2010-07-12 2010-11-10 安徽农业大学 一种竹基/热塑性塑料纳米复合材料
EP3170862A1 (en) 2015-11-23 2017-05-24 Elix Polymers, S.L. Thermoplastic abs composition reinforced with natural fibres

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040001940A1 (en) * 2002-06-28 2004-01-01 Neogi Amar N. Composite siding
US7151125B2 (en) * 2002-04-18 2006-12-19 Lonza Inc. Non-wood fiber plastic composites
WO2007036037A1 (en) * 2005-09-30 2007-04-05 Magna International Inc. Water-assist injection molded structural members

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7151125B2 (en) * 2002-04-18 2006-12-19 Lonza Inc. Non-wood fiber plastic composites
US20040001940A1 (en) * 2002-06-28 2004-01-01 Neogi Amar N. Composite siding
WO2007036037A1 (en) * 2005-09-30 2007-04-05 Magna International Inc. Water-assist injection molded structural members

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880464A (zh) * 2010-07-12 2010-11-10 安徽农业大学 一种竹基/热塑性塑料纳米复合材料
EP3170862A1 (en) 2015-11-23 2017-05-24 Elix Polymers, S.L. Thermoplastic abs composition reinforced with natural fibres
WO2017089222A1 (en) 2015-11-23 2017-06-01 Elix Polymers, S.L. Thermoplastic abs composition reinforced with natural fibres
US10759936B2 (en) 2015-11-23 2020-09-01 Elix Polymers, S.L. Thermoplastic ABS composition reinforced with natural fibres

Also Published As

Publication number Publication date
LV13891B (lv) 2009-06-20
LV13891A (lv) 2009-03-20
WO2009017387A3 (en) 2009-05-14

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