WO2009011639A3 - Diesel range fuels from carboxylic acids with plant origin - Google Patents

Diesel range fuels from carboxylic acids with plant origin Download PDF

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Publication number
WO2009011639A3
WO2009011639A3 PCT/SE2008/000457 SE2008000457W WO2009011639A3 WO 2009011639 A3 WO2009011639 A3 WO 2009011639A3 SE 2008000457 W SE2008000457 W SE 2008000457W WO 2009011639 A3 WO2009011639 A3 WO 2009011639A3
Authority
WO
WIPO (PCT)
Prior art keywords
renewable diesel
carboxylic acids
plant origin
treatment
carboxylic acid
Prior art date
Application number
PCT/SE2008/000457
Other languages
French (fr)
Other versions
WO2009011639A2 (en
Inventor
Lars Stigsson
Original Assignee
Sunpine Ab
Lars Stigsson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunpine Ab, Lars Stigsson filed Critical Sunpine Ab
Publication of WO2009011639A2 publication Critical patent/WO2009011639A2/en
Publication of WO2009011639A3 publication Critical patent/WO2009011639A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C10G2300/203—Naphthenic acids, TAN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

The present invention provides a process for manufacturing renewable diesel fuels from carboxylic acid rich organic material originating in plants, by treatment of said carboxylic acid rich material in at least three process stages; a) a distillation step under vacuum b)a decarboxylation step in the presence of an heterogeneous decarboxylation catalyst forming a renewable diesel fuel with a high cetane number c)a separation step wherein carbon dioxide is separated from the renewable diesel formed in step b).The renewable diesel fuel produced by the treatments of the present invention may be further treated by esterif ication for removal a traces of carboxylic acids, by adsorption or by treatment with hydrogen for deep removal of sulphur.
PCT/SE2008/000457 2007-07-19 2008-07-18 Diesel range fuels from carboxylic acids with plant origin WO2009011639A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US92995807P 2007-07-19 2007-07-19
US60/929,958 2007-07-19
US99600907P 2007-10-24 2007-10-24
US60/996,009 2007-10-24

Publications (2)

Publication Number Publication Date
WO2009011639A2 WO2009011639A2 (en) 2009-01-22
WO2009011639A3 true WO2009011639A3 (en) 2009-04-02

Family

ID=40114326

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE2008/000457 WO2009011639A2 (en) 2007-07-19 2008-07-18 Diesel range fuels from carboxylic acids with plant origin

Country Status (1)

Country Link
WO (1) WO2009011639A2 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7982078B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
US7982076B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks
US7999143B2 (en) 2007-09-20 2011-08-16 Uop Llc Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption
US7999142B2 (en) 2007-09-20 2011-08-16 Uop Llc Production of diesel fuel from biorenewable feedstocks
US8003834B2 (en) 2007-09-20 2011-08-23 Uop Llc Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks
US7982075B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption
US7915460B2 (en) 2007-09-20 2011-03-29 Uop Llc Production of diesel fuel from biorenewable feedstocks with heat integration
US7982077B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
US8742183B2 (en) 2007-12-21 2014-06-03 Uop Llc Production of aviation fuel from biorenewable feedstocks
US8198492B2 (en) 2008-03-17 2012-06-12 Uop Llc Production of transportation fuel from renewable feedstocks
US8039682B2 (en) 2008-03-17 2011-10-18 Uop Llc Production of aviation fuel from renewable feedstocks
US8193400B2 (en) 2008-03-17 2012-06-05 Uop Llc Production of diesel fuel from renewable feedstocks
US8058492B2 (en) 2008-03-17 2011-11-15 Uop Llc Controlling production of transportation fuels from renewable feedstocks
US8193399B2 (en) 2008-03-17 2012-06-05 Uop Llc Production of diesel fuel and aviation fuel from renewable feedstocks
US8324438B2 (en) 2008-04-06 2012-12-04 Uop Llc Production of blended gasoline and blended aviation fuel from renewable feedstocks
US8329967B2 (en) 2008-04-06 2012-12-11 Uop Llc Production of blended fuel from renewable feedstocks
US8329968B2 (en) 2008-04-06 2012-12-11 Uop Llc Production of blended gasoline aviation and diesel fuels from renewable feedstocks
CA2720599C (en) 2008-04-06 2015-02-24 Michael J. Mccall Fuel and fuel blending components from biomass derived pyrolysis oil
US8304592B2 (en) 2008-06-24 2012-11-06 Uop Llc Production of paraffinic fuel from renewable feedstocks
US8766025B2 (en) 2008-06-24 2014-07-01 Uop Llc Production of paraffinic fuel from renewable feedstocks
US7982079B2 (en) 2008-09-11 2011-07-19 Uop Llc Integrated process for production of diesel fuel from renewable feedstocks and ethanol denaturizing
US8921627B2 (en) 2008-12-12 2014-12-30 Uop Llc Production of diesel fuel from biorenewable feedstocks using non-flashing quench liquid
US8471079B2 (en) 2008-12-16 2013-06-25 Uop Llc Production of fuel from co-processing multiple renewable feedstocks
US8314274B2 (en) 2008-12-17 2012-11-20 Uop Llc Controlling cold flow properties of transportation fuels from renewable feedstocks
US8283506B2 (en) 2008-12-17 2012-10-09 Uop Llc Production of fuel from renewable feedstocks using a finishing reactor
FI124194B (en) * 2009-05-04 2014-04-30 Upm Kymmene Corp Method and apparatus for separating components from fuel feedstock
US8686203B2 (en) * 2009-06-12 2014-04-01 Exxonmobil Research And Engineering Company Process for preparing diesel fuels using vegetable oils or fatty acid derivatives
US8471081B2 (en) 2009-12-28 2013-06-25 Uop Llc Production of diesel fuel from crude tall oil
FI126337B (en) * 2010-03-26 2016-10-14 Forchem Oy Procedure for utilizing tall oil pitch
US8366907B2 (en) 2010-08-02 2013-02-05 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons
FI20106252A0 (en) 2010-11-26 2010-11-26 Upm Kymmene Corp Method and system for making fuel components
US8900443B2 (en) 2011-04-07 2014-12-02 Uop Llc Method for multi-staged hydroprocessing using quench liquid
US9120982B2 (en) 2011-04-18 2015-09-01 Upm-Kymmene Corporation Process and apparatus for producing hydrocarbons
AU2012350313B2 (en) 2011-12-08 2016-10-27 Sunpine Ab Process for obtaining a diesel like fuel
EP2602306B1 (en) 2011-12-08 2014-11-12 Invico Tech AB Process for obtaining a diesel like fuel
JP6205098B2 (en) * 2012-12-21 2017-09-27 サンパイン アーベーＳｕｎｐｉｎｅ Ａｂ Bio-refining of crude tall oil
WO2019188492A1 (en) * 2018-03-26 2019-10-03 不二製油グループ本社株式会社 Transesterified fat or oil

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5705722A (en) * 1994-06-30 1998-01-06 Natural Resources Canada Conversion of biomass feedstock to diesel fuel additive
EP1681337A1 (en) * 2005-01-14 2006-07-19 Neste Oil OYJ Method for the manufacture of hydrocarbons
EP1728844A1 (en) * 2005-05-19 2006-12-06 Uop Llc Production of diesel fuel from biorenewable feedstocks
EP1741768A1 (en) * 2005-07-04 2007-01-10 Neste Oil OYJ Process for the manufacture of diesel range hydrocarbons
EP1795576A1 (en) * 2005-12-12 2007-06-13 Neste Oil OYJ Process for the manufacture of hydrocarbons

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5705722A (en) * 1994-06-30 1998-01-06 Natural Resources Canada Conversion of biomass feedstock to diesel fuel additive
EP1681337A1 (en) * 2005-01-14 2006-07-19 Neste Oil OYJ Method for the manufacture of hydrocarbons
EP1728844A1 (en) * 2005-05-19 2006-12-06 Uop Llc Production of diesel fuel from biorenewable feedstocks
EP1741768A1 (en) * 2005-07-04 2007-01-10 Neste Oil OYJ Process for the manufacture of diesel range hydrocarbons
EP1795576A1 (en) * 2005-12-12 2007-06-13 Neste Oil OYJ Process for the manufacture of hydrocarbons

Non-Patent Citations (1)

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Title
HUBER ET AL: "Processing biomass in conventional oil refineries: Production of high quality diesel by hydrotreating vegetable oils in heavy vacuum oil mixtures", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 329, 7 July 2007 (2007-07-07), pages 120 - 129, XP022200019, ISSN: 0926-860X *

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