WO2008149370A3 - Oxidation of aldehydes and alkenes - Google Patents

Oxidation of aldehydes and alkenes Download PDF

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Publication number
WO2008149370A3
WO2008149370A3 PCT/IL2008/000777 IL2008000777W WO2008149370A3 WO 2008149370 A3 WO2008149370 A3 WO 2008149370A3 IL 2008000777 W IL2008000777 W IL 2008000777W WO 2008149370 A3 WO2008149370 A3 WO 2008149370A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkenes
aldehydes
oxidation
oxygen
diols
Prior art date
Application number
PCT/IL2008/000777
Other languages
French (fr)
Other versions
WO2008149370A2 (en
Inventor
Arkadi Vigalok
Nelly Shapiro
Original Assignee
Univ Ramot
Arkadi Vigalok
Nelly Shapiro
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Ramot, Arkadi Vigalok, Nelly Shapiro filed Critical Univ Ramot
Publication of WO2008149370A2 publication Critical patent/WO2008149370A2/en
Publication of WO2008149370A3 publication Critical patent/WO2008149370A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

A general method is disclosed for the conversion of aldehydes and alkenes to the corresponding carboxylic acids and 1,2-diols. The method is carried out in a catalyst-free aqueous medium under an atmosphere of oxygen or oxygen containing gas.
PCT/IL2008/000777 2007-06-06 2008-06-05 Oxidation of aldehydes and alkenes WO2008149370A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US92494007P 2007-06-06 2007-06-06
US60/924,940 2007-06-06

Publications (2)

Publication Number Publication Date
WO2008149370A2 WO2008149370A2 (en) 2008-12-11
WO2008149370A3 true WO2008149370A3 (en) 2009-03-05

Family

ID=39938157

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IL2008/000777 WO2008149370A2 (en) 2007-06-06 2008-06-05 Oxidation of aldehydes and alkenes

Country Status (1)

Country Link
WO (1) WO2008149370A2 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265716A (en) * 1963-07-09 1966-08-09 Eastman Kodak Co Epoxidation of olefins during the simultaneous air oxidation of secondary aldehydes
US3415877A (en) * 1965-10-19 1968-12-10 Millmaster Onyx Corp Process for preparing 2-ethyl-3-methyl pentanoic acid
US3579575A (en) * 1967-05-26 1971-05-18 Melle Bezons Process for oxidizing lower aliphatic aldehydes
US4046782A (en) * 1975-05-08 1977-09-06 John Kollar Process for the industrial production of ethylene oxide and aromatic acid
US5466838A (en) * 1991-10-30 1995-11-14 Sumitomo Chemical Company, Limited Process for producing epoxide
US5686638A (en) * 1994-09-06 1997-11-11 Dsm Chemie Linz Gmbh Process for the preparation of mono- or dicarboxylic acids from aldehydes, from their full acetals or hemiacetals or from mixtures thereof
US20060052633A1 (en) * 2003-06-05 2006-03-09 Sang-Gi Lee Method for preparing organic acid

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265716A (en) * 1963-07-09 1966-08-09 Eastman Kodak Co Epoxidation of olefins during the simultaneous air oxidation of secondary aldehydes
US3415877A (en) * 1965-10-19 1968-12-10 Millmaster Onyx Corp Process for preparing 2-ethyl-3-methyl pentanoic acid
US3579575A (en) * 1967-05-26 1971-05-18 Melle Bezons Process for oxidizing lower aliphatic aldehydes
US4046782A (en) * 1975-05-08 1977-09-06 John Kollar Process for the industrial production of ethylene oxide and aromatic acid
US5466838A (en) * 1991-10-30 1995-11-14 Sumitomo Chemical Company, Limited Process for producing epoxide
US5686638A (en) * 1994-09-06 1997-11-11 Dsm Chemie Linz Gmbh Process for the preparation of mono- or dicarboxylic acids from aldehydes, from their full acetals or hemiacetals or from mixtures thereof
US20060052633A1 (en) * 2003-06-05 2006-03-09 Sang-Gi Lee Method for preparing organic acid

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
LIM ET AL: "Environmentally benign oxidation reaction of aldehydes to their corresponding carboxylic acids using Pd/C with NaBH4 and KOH", TETRAHEDRON LETTERS, ELSEVIER, AMSTERDAM, vol. 48, no. 22, 3 May 2007 (2007-05-03), pages 3835 - 3839, XP022058991, ISSN: 0040-4039 *
STEPHENSON, JOURNAL OF CHEMICAL AND ENGINEERING DATA, vol. 38, 1993, pages 630 - 633, XP002505983 *

Also Published As

Publication number Publication date
WO2008149370A2 (en) 2008-12-11

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