WO2008136264A1 - Supported catalyst for hydrogenation/dehydrogenation reaction, method for production of the catalyst, and hydrogen storage/supply method using the catalyst - Google Patents

Supported catalyst for hydrogenation/dehydrogenation reaction, method for production of the catalyst, and hydrogen storage/supply method using the catalyst Download PDF

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Publication number
WO2008136264A1
WO2008136264A1 PCT/JP2008/057413 JP2008057413W WO2008136264A1 WO 2008136264 A1 WO2008136264 A1 WO 2008136264A1 JP 2008057413 W JP2008057413 W JP 2008057413W WO 2008136264 A1 WO2008136264 A1 WO 2008136264A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
hydrogenation
production
dehydrogenation reaction
hydrogen storage
Prior art date
Application number
PCT/JP2008/057413
Other languages
French (fr)
Japanese (ja)
Inventor
Masaru Ichikawa
Masashi Sakuramoto
Makoto Kurosawa
Satoru Kikuchi
Yukimitsu Mita
Yuji Isaka
Original Assignee
Hrein Energy, Inc.
Alumi Surface Technologies Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hrein Energy, Inc., Alumi Surface Technologies Co., Ltd. filed Critical Hrein Energy, Inc.
Priority to CN200880022491A priority Critical patent/CN101801841A/en
Publication of WO2008136264A1 publication Critical patent/WO2008136264A1/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0341—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B01J37/0226—Oxidation of the substrate, e.g. anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/06—Toluene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1252—Cyclic or aromatic hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

The object is to increase the reaction rate of hydrogenation or dehydrogenation to thereby enable to use a catalyst for a long period. Disclosed is a method for the storage/supply of hydrogen. The method comprises carrying out the hydrogenation reaction into an aromatic compound or the dehydrogenation reaction of a hydrogenated derivative of the aromatic compound by using a supported catalyst which comprises platinum and molybdenum carbide or tungsten carbide covering a part or the whole area of the surface of a carrier.
PCT/JP2008/057413 2007-04-27 2008-04-16 Supported catalyst for hydrogenation/dehydrogenation reaction, method for production of the catalyst, and hydrogen storage/supply method using the catalyst WO2008136264A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200880022491A CN101801841A (en) 2007-04-27 2008-04-16 Supported catalyst for hydrogenation/dehydrogenation reaction, method for production of the catalyst, and hydrogen storage/supply method using the catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-118578 2007-04-27
JP2007118578A JP5122178B2 (en) 2007-04-27 2007-04-27 Supported catalyst for hydrogenation / dehydrogenation reaction, production method thereof, and hydrogen storage / supply method using the catalyst

Publications (1)

Publication Number Publication Date
WO2008136264A1 true WO2008136264A1 (en) 2008-11-13

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PCT/JP2008/057413 WO2008136264A1 (en) 2007-04-27 2008-04-16 Supported catalyst for hydrogenation/dehydrogenation reaction, method for production of the catalyst, and hydrogen storage/supply method using the catalyst

Country Status (3)

Country Link
JP (1) JP5122178B2 (en)
CN (1) CN101801841A (en)
WO (1) WO2008136264A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9466843B2 (en) 2010-07-30 2016-10-11 Samsung Electronics Co., Ltd. Electrode catalyst and method of preparing electrode catalyst for fuel cell, and membrane electrode assembly and fuel cell including same
CN115485063A (en) * 2020-04-23 2022-12-16 千代田化工建设株式会社 Eggshell type platinum-loaded alumina catalyst, preparation method and application method thereof

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5489508B2 (en) * 2009-03-31 2014-05-14 日立エーアイシー株式会社 Hydrogen catalyst material
JP5489509B2 (en) * 2009-03-31 2014-05-14 日立エーアイシー株式会社 Hydrogen catalyst material
JP5620077B2 (en) * 2009-06-11 2014-11-05 日立エーアイシー株式会社 Hydrogen catalyst material
EP2305376A1 (en) * 2009-09-23 2011-04-06 Lonza Ltd. Process and catalyst for the catalytic hydrogenation of aromatic and heteroaromatic nitro compounds
KR20120115559A (en) * 2010-02-05 2012-10-18 바스프 에스이 Process for producing a catalyst and catalyst
JP5369126B2 (en) * 2010-04-28 2013-12-18 日本精線株式会社 Wire catalyst molded products for hydrogenation / dehydrogenation reactions
US20130045865A1 (en) * 2011-01-31 2013-02-21 The Regents Of The University Of Michigan High activity early transition metal carbide and nitride based catalysts
JP6269297B2 (en) * 2014-04-25 2018-01-31 トヨタ自動車株式会社 Piston top surface coating method
CN104307546A (en) * 2014-11-03 2015-01-28 太仓派欧技术咨询服务有限公司 Transition metal catalyst with Pt-group metal dotted active points
CN104307547B (en) * 2014-11-03 2017-02-15 太仓派欧技术咨询服务有限公司 Pt-ZrO2/WC (Wolfram Carbide) catalyst in methane-carbon dioxide catalytic reforming reaction
KR102098066B1 (en) * 2018-04-24 2020-04-07 울산과학기술원 Manufacturing method for high activity catalyst and high activity catalyst for the same
CN111054410B (en) * 2018-10-16 2023-04-07 中国石油化工股份有限公司 Liquid phase dehydrogenation catalyst, preparation and use
CN110124707B (en) * 2019-06-06 2022-05-31 中山大学 Spiral ultralow platinum loading Mo2C catalyst and preparation method and application thereof

Citations (2)

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JP2003117398A (en) * 2001-10-12 2003-04-22 Toyota Motor Corp Wc carrying catalyst and production method thereof
JP2003334571A (en) * 2002-03-11 2003-11-25 Nippon Shokubai Co Ltd Method for treating drain

Patent Citations (2)

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JP2003117398A (en) * 2001-10-12 2003-04-22 Toyota Motor Corp Wc carrying catalyst and production method thereof
JP2003334571A (en) * 2002-03-11 2003-11-25 Nippon Shokubai Co Ltd Method for treating drain

Non-Patent Citations (2)

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Title
LEE S.J. ET AL.: "Preparation and benzene hydrogenation activity of supported molybdenum carbide catalysts", J. CATAL., vol. 128, no. 1, 5 March 1991 (1991-03-05), pages 126 - 136 *
ZELLNER M.B. ET AL.: "Synthesis, characterization and surface reactivity of tungsten carbide (WC) PVD films", SURF. SCI., vol. 569, no. 1-3, 1 August 2004 (2004-08-01), pages 89 - 98, XP004572107, DOI: doi:10.1016/j.susc.2004.07.029 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9466843B2 (en) 2010-07-30 2016-10-11 Samsung Electronics Co., Ltd. Electrode catalyst and method of preparing electrode catalyst for fuel cell, and membrane electrode assembly and fuel cell including same
CN115485063A (en) * 2020-04-23 2022-12-16 千代田化工建设株式会社 Eggshell type platinum-loaded alumina catalyst, preparation method and application method thereof

Also Published As

Publication number Publication date
JP5122178B2 (en) 2013-01-16
JP2008273778A (en) 2008-11-13
CN101801841A (en) 2010-08-11

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