WO2008127083A1 - Stable powder of mamey pulp and food products made therefrom - Google Patents

Stable powder of mamey pulp and food products made therefrom Download PDF

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Publication number
WO2008127083A1
WO2008127083A1 PCT/MX2007/000151 MX2007000151W WO2008127083A1 WO 2008127083 A1 WO2008127083 A1 WO 2008127083A1 MX 2007000151 W MX2007000151 W MX 2007000151W WO 2008127083 A1 WO2008127083 A1 WO 2008127083A1
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Prior art keywords
mamey
pulp
fruit
composition
powder
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PCT/MX2007/000151
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Spanish (es)
French (fr)
Inventor
Dimas JIMÉNEZ MENDOZA
Original Assignee
Jimenez Mendoza Dimas
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Publication of WO2008127083A1 publication Critical patent/WO2008127083A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/02Dehydrating; Subsequent reconstitution
    • A23B7/022Dehydrating; Subsequent reconstitution with addition of chemicals before or during drying, e.g. semi-moist products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/01Instant products; Powders; Flakes; Granules
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
    • A23L2/385Concentrates of non-alcoholic beverages
    • A23L2/39Dry compositions
    • A23L2/395Dry compositions in a particular shape or form
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L9/00Puddings; Cream substitutes; Preparation or treatment thereof
    • A23L9/10Puddings; Dry powder puddings

Definitions

  • the present invention relates to the preservation of tropical fruits with a very short shelf life, specifically to the preservation of the mamey pulp through its controlled dehydration until its transformation into powders that can be stored at room temperature for prolonged periods without suffering alterations in its organoleptic properties.
  • the fruits have very desirable organoleptic characteristics for direct consumption as fresh food, the vast majority can only be produced and consumed in specific seasons of the year, so that their availability becomes limited and their consumption is preferably local , as is the case with Multiple tropical fruits As a consequence of these effects, multiple tropical fruits are not consumed in a generalized manner, which also causes significant waste at harvest times.
  • the mamey is a tropical tree from Central America which is
  • the Pantin and Maga ⁇ a varieties represent 95 to 98% of the total cultivated area in Florida, while the Tazumal and Pace varieties are also of commercial interest but on a much smaller scale.
  • the fruit of the mamey is ovoid distinguishing a rough shell of gray-reddish color, with dimensions generally 30 cm long by 15 cm wide, and weighing up to 2.5 Kg.
  • the fruit normally contains a single large seed, although there are varieties that can present up to 3 seeds, as well as an orange to red pulp when ripe with a sweet taste and very soft consistency that allow it to have an excellent quality for dessert.
  • the harvest of the fruit is preferably done in the months of April and May, although some other varieties such as Tazumal and Pace can bear fruit at other times of the year.
  • the fruit is collected for commercial distribution, when the appearance of a pink salmon color is detected in the shell, indicating the beginning of the fruit ripening stage.
  • Mamey pulp contains components of high nutritional value, as can be seen in Table 1, distinguishing its high content of moisture, fiber, carbohydrates, carotenes and ascorbic acid. It also contains a low acid content per Io that has a pH of 4.5 to 6, while the fiber it consists of cellulose and lignin;
  • the carbohydrates present in the pulp are basically glucose, fructose and sucrose.
  • the fruit contains violaxanthin as the main carotenoid pigment in Ia
  • polyphenols such as myrithitrine (see figure 1), as well as benzaldehyde, hexanal and
  • Mamey pulp is usually consumed mixed with other ingredients to obtain smoothies, ice cream, or to obtain jellies, pastes and preserves, although its food variants are very vast.
  • the post-harvest life of the fresh mamey fruit is very short (up to 7 days), depending on the maturity of the fruit and the storage conditions; the fresh fruit also has high exchange rates
  • the shelf life of the fresh fruit does not exceed 14 days of storage even under controlled conditions, which significantly limits its distribution.
  • the coating accelerates the Fruit softening, reducing its shelf life by at least 3 days compared to fresh uncoated fruit.
  • preservation techniques of fresh tropical fruits that allow extending their post-harvest life period, such as refrigerated storage (10-15 0 C), and coating the fruit with various
  • Another of the objectives of the present invention is to provide analytical determination methods to determine the identity of mamey pulp powders.
  • FIG. 1 Typical polyphenolic compounds with antioxidant activity found in the pulp of Pouteria sapota are shown, such as gallic acid (1), (+) - gallocatechin (2), (+) - catechin (3), (-) - epicatechin (4), dihydromyricetin (5), mycithitrine (6) and (+) - 3-O-catechin gallate (7).
  • FIG. 1 The colorimetric spectra obtained from samples of mamey powder of the invention, specifically Calocarpum mammosum Pierre, are shown. Standard mamey powder (A), mamey powders from the State of Veracruz (B, C, D) and standard mamey powder mixed with 30% glucose (E) are observed.
  • FIG. 3 The colorimetric spectra obtained from samples of mamey powder of the invention are shown. Standard powder of Calocarpum mammosum Pierre (A), standard powder of Mammea americana L (B) and Hass avocado pulp powders (C and D).
  • the present invention provides mamey pulp powders with great stability at room temperature, which allows them to keep the original organoleptic and nutritional properties of the mamey fruit unaltered.
  • the great stability that it exhibits allows storage times of at least 1 year at room temperature without any contamination or alterations in its color, taste, aroma and nutritional properties.
  • the mamey powder described here does not show enzymatic or non-enzymatic darkening, such that the original and typical organoleptic properties of the mamey fruit from which it is obtained are preserved.
  • the mamey pulp powder of the invention represents an excellent alternative for the efficient conservation of the mamey pulp and completely eliminates the problems associated with the loss of organoleptic properties during storage, transport and post-harvest life of the fresh fruit.
  • Mamey powder is completely rehydrated at the time of use, just add any liquid of interest to form a uniform paste that looks very similar to the pulp of the fresh fruit.
  • the hydrated powder can be used in the same way that the pulp of the fresh fruit is used, allowing it to be combined with a large number of food products to obtain derived products flavored with mamey pulp.
  • the powder of the invention has a particle size of 125 to 250 ⁇ m, which allows it to provide a good sensation and texture to taste if it is consumed directly, while allowing a good dissolution in liquids and good dispersion in solids.
  • the Powder of the invention exhibits values of 0.2 to 0.7, preferably 0.4 to 0.6, which allows that there is no contamination by microorganisms because of these values of aqueous activity, the establishment and growth of microorganisms is completely inhibited.
  • the stable mamey powder of the present invention is a composition comprising dehydrated mamey pulp in a percentage of 98 to 99.99% by weight with respect to the total weight of the composition, and a grinding additive selected from the group that It comprises citric acid, ascorbic acid or mixtures thereof in a percentage of 0.01 to 2% by weight with respect to the total weight of the composition.
  • the above characteristics allow mamey powder to be stable at room temperature for prolonged periods of storage, while maintaining the typical organoleptic and nutritional properties observed in the pulp of the fresh fruit.
  • the powder of the invention contains a greater concentration of its nutritional elements per unit of weight in comparison with the same quantities of the pulp of the fresh fruit, so that smaller volumes of the powder can be used to obtain food products, remaining its nutritional value
  • the stable powder can itself constitute a directly consumable and commercial product, since the powder can be easily collected, stored, transported, sold and used through its packaging in sealed containers, which can be transparent.
  • the powder can be packed without using a vacuum to remove the resident air in the container, since it does not suffer any contamination, so the costs associated with this process decrease significantly.
  • the powder described here is easily soluble in water and other compatible liquids, such as milk, concentrated juices, etc., so it can be used to obtain various kinds of beverages, such as soft drinks, smoothies, syrups or the like, depending on The edible substance that is used.
  • This process can be carried out directly by the consumer or in the beverage production industry, simply by dissolving a small amount of the powder of the invention concentrated directly in a glass with water or milk and optionally adding sugar or similar sweeteners in the desired proportions.
  • mamey powder can be perfectly combined with yogurts, ice cream, cakes, jams, jellies, various confectionery products, food supplements, baby food, porridge or spirits, resulting in obtaining excellent flavored food products to mamey.
  • the powder of the invention can be used to provide mamey pulp flavor in multiple food mixtures, for which a sufficient amount thereof must be added to impart the desired qualities of mamey flavor, appearance and aroma to the edibles in which will add.
  • the mamey powder of the invention is generally in amounts of 10 to 20% by weight with respect to the total weight of the food mixture.
  • the organoleptic characteristics of the powder of the invention are sufficiently concentrated to develop the desirable intensity of taste and smell of mamey in the food material that is added, so that low amounts thereof can be occupied, although the amount used depends on the preference of the consumer or of the food composition in question.
  • the stable powder of the invention reduces the cost of packaging, storage, and transportation by reducing the weight and volume of the product desired, in this case fresh fruit of mamey.
  • the powder of the invention represents a good alternative as an instant, convenient and high nutritional quality food product.
  • the mamey pulp powder of the invention does not suffer color alterations, so that the pleasant appearance observed in the original fruit is conserved as well as the characteristic natural color of the mamey pulp.
  • any convenient container for the packaging of the powder can be used, it is preferred to store the powder of the invention at room temperature in closed transparent containers, in the absence of moisture and direct sunlight, so that the powder remains unchanged in its properties at least for 1 year, thereby eliminating cold preservation procedures, the use of toxic antioxidants and the use of refrigeration chambers for fruit transport.
  • the characteristics of the powder of the invention allow that when combined with liquid or solid foods, homogeneous food mixtures are obtained more simply and without the use of complex industrial processes that involve a greater expenditure of energy, and consequently a higher cost.
  • the powder of the invention also allows the safe transport of a greater number of grams of processed mamey pulp at the same time, without this presenting risks due to darkening or microbial contamination; Likewise, its long shelf life and the preservation of its nutritional properties allow its transport and distribution to any place where the product is required.
  • a process is carried out that allows the efficient dehydration of the mamey pulp in conjunction with the fruit peel.
  • efficient dehydration is understood as the process that allows the elimination of the water contained in the breast pulp by means of dehydration until the minimum moisture necessary is left to prevent the growth of microorganisms. This eliminates the use of complicated procedures or devices that can generate significant losses in the yield of obtaining the dehydrated pulp or the investment of a longer time in obtaining the fruit powder.
  • drying fruits by dehydration does not necessarily guarantee that dried fruits have prolonged periods of conservation at room temperature, since various factors associated with the dried fruit are involved in its shelf stability.
  • the pH and the aqueous activity of the product, as well as the physical characteristics of the fruit to be dehydrated are decisive for obtaining stable nuts; for example, the generation of microorganisms that can break down preserved foods is related to minimum values of water activity of 0.93 or 0.94, so that most of the technologies aimed at obtaining dried fruits try to obtain products with values of water activity lower than 0.9.
  • Water activity is one of the most critical factors in determining the quality and safety of food products consumed daily, since it affects the shelf life, safety, texture, taste and smell of food. While the manipulation of temperature and pH can negatively influence the growth of microorganisms on food products, aqueous activity is the most important factor that controls said growth, since it determines the lowest limit of water available for microbial growth. . In addition to influencing microbial growth, the aqueous activity has a significant role in the enzymatic and vitamin activity of food, as well as an important impact on its color, flavor and aroma.
  • the mixture of nutritional components of the pulp of the fruit also causes deleterious effects in obtaining fluid powders.
  • the quantity and type of constituents of the pulp have important effects in the efficient obtaining of powders from the pulps, for example in Ia fluid dynamics; in this case the concentration and mixture of sugars, pectin and lipids significantly affect the pulps.
  • the process of the invention manages to obtain stable mamey pulp powders on shelf for long periods and that exhibit the typical organoleptic properties of the fresh fruit (see example 1), whereby the typical conservation problems associated with the Fresh mamey fruit.
  • the process of obtaining the powder of the invention comprises the following steps: a) Selection and washing of the whole mamey.
  • the selected fruits are washed and sanitized with chlorinated water at 20 ppm to eliminate undesirable residues adhered to the shell and avoid contamination of the pulp when the shell is subsequently removed. Then the whole fruits are drained and blown to completely eliminate the excess water; The water resulting from this process is received by a draining tray and sent to the drain.
  • the seed in a conveyor belt used for this purpose is the seed in a conveyor belt used for this purpose.
  • the fruit cut in half is dehydrated by any conventional method that allows the dehydration of the pulp, however a method of dehydration selected from the group comprising thermosecado, microwave or hot air is preferred .
  • a method of dehydration selected from the group comprising thermosecado, microwave or hot air is preferred .
  • the choice of the method depends largely on the design of the processing plant for obtaining the powder of the invention, but for the purposes of the invention any of the aforementioned It gives favorable results.
  • thermosecado the dehydration is carried out in a temperature range of 60 to 120 0 C in a time of 0.5 to 4 hours.
  • microwave dehydration it is carried out in a temperature range of 60 to 110 0 C in a time of 3 to 50 minutes, while for hot air dehydration, this is carried out at a temperature of 60 to 120 ° C for 0.5 4 hours
  • the first stage of dehydration is carried out during the times indicated for each methodology, preferably until the pulp of the fruit peel can be easily separated.
  • the dehydrated and equilibrated pulp at room temperature is mixed until homogenization with a compound selected from the group comprising citric acid, ascorbic acid or mixtures thereof, in a proportion of 0.01 to 2% by weight with respect to the total weight of the dehydrated pulp , subjecting the mixture to grinding by means of a conventional mill under conditions that allow obtaining a particle size of 125 to 250 ⁇ m; then the grinding obtained is sifted by a granulometric classifier with a mesh size that allows the passage of the mentioned particle size, such as 60 to 115 mesh. At this stage of the process, the particles that have been retained by the classifier are they send the grinding process again with the purpose of obtaining the appropriate particle size.
  • samples of the product obtained can be taken to perform bromatological analyzes and verify the quality of the product as it is obtained, which allows to guarantee the food quality of the product obtained.
  • the mamey powder of the invention is transported and emptied into the hoppers of a packaging system, to be subsequently placed in containers by means of a conventional packaging machine.
  • Virtually any type of clean and dry container can be used for the conservation of the mamey powder of the invention, however those that are easily accessible, that do not present difficulties in handling and transportation, and that have a recognized commercial value are preferred. Examples of these are Peet bottles, glass or glass bottles, cardboard boxes with inner lining or aluminized bags.
  • the process of the present invention allows, after the first stage of dehydration, a simple, complete and efficient separation of the dehydrated pulp from the shell, without the need to use devices specifically designed for it.
  • the yields of obtaining the powder of the invention it is possible to obtain at least 200 to 250 g of powder for each 1,000 g of fresh pulp of the fruit, which represents high proportions of yield, given the large percentage of humidity (at least 70% w / w) that contains the fresh mamey pulp (see table 1).
  • the process of the invention removes a large amount of moisture from the fresh mamey pulp, for the purposes of the invention the water content should not be completely removed from the raw material, since it can be quickly carbonized.
  • the milling of the dehydrated pulp of mamey can be carried out in any convenient grinding device, disintegrator, or fractionator mill to a particle size convenient for consumption.
  • the process of the invention allows eliminating the problem that occurs during the dehydration of the mamey pulp, since for this fruit, the appearance of the amorphous crystallization effect of the pulp carbohydrates is frequent (see example 2), which prevents the dehydrated pulp can be ground later to obtain dust.
  • the pulp obtained cannot be easily separated from the shell, since when it becomes viscous and taffy, it adheres strongly to its internal walls.
  • Subjecting the mamey pulp in this state to another dehydration process to try to eliminate the viscosity is not effective, since when the pulp cools, it becomes viscous again while areas of carbonized pulp begin to appear, which It provides an unpleasant taste to the product.
  • Lewis describes the obtaining of fruit or vegetable products free of additives with an aqueous activity of 0.5 to 0.95 and exhibiting high microbiological stability.
  • the fruits are partially dehydrated to a moisture content of 26 to 60% and subsequently are packaged under an oxygen-free environment, which allows them to retain their nutritional characteristics, color and appearance for prolonged periods (6 to 24 months).
  • fruits such as potatoes, carrots, cherries, apples, pears and grapes are peeled and cut into different forms to be subsequently dehydrated.
  • the dehydrated product described by Lewis is not in powder form and involves packaging processes in which the presence of oxygen has to be eliminated (for example, adding nitrogen or oxygen absorbers in laminated packages) as well as its conservation at low temperatures, since otherwise the product could not be preserved.
  • Varga describes the obtaining of soft-shell fruit powders such as apple, pear, grape, lemon, plum and banana by dehydration by means of microwaves at a temperature of 65 ° C for 10 to 15 minutes to subsequently grind the dehydrated product in conventional mills
  • the product obtained has an amount of 5 to 17% w / w of water, is soluble in water, can include the peel of the fruit with the purpose of providing dietary fiber to the powder and can be stored for years at a temperature of 10 to 15 ° C without losing its nutritional properties.
  • Varga cannot be used in fruits that have hard peels (for example mamey or avocado), since the conditions of dehydration and grinding are not sufficient to obtain powders of this type of fruit; Likewise, it is not possible to obtain powders stable at room temperature and that do not need refrigeration for their conservation.
  • Suzuki describes the generation of long shelf life food products at room temperature by drying the food product and subsequent addition of edible oil to the dry product, adjusting the aqueous activity of the mixture from 0.55 to 0.75 to prevent the generation of microorganisms and Ia formation of crystals that cause problems in the packaging and in the texture of the product.
  • the amount of water necessary to adjust the desired aqueous activity in the product is added.
  • the products described do not have particle sizes smaller than 300 ⁇ m and integrate water into the food product for preservation; Likewise, the addition of edible oil is necessary to provide stability to the product.
  • DuII describes the obtaining of legumes (beans, for example) with a reduced aqueous activity of 0.5 by adding moisturizing solutions based on glycerol, propylene glycol, sucrose, fructose, galactose or mixtures thereof, to the food product previously hydrated with Water;
  • the food product obtained is stable on shelf and retains its nutritional properties.
  • the characteristics of the product described by DuII are subject to the addition of non-plant substances.
  • Cross describes the production of stable food products at room temperature with an aqueous activity of 0.2 to 0.3 and an average particle size of 15 to 31 ⁇ m, which can be obtained by subjecting desired food mixtures to consecutive reductions in their particle size by use of a system of refining chocolate based on rollers and the addition of liquid fat, as well as the optional addition of emulsifiers such as lecithins.
  • a system of refining chocolate based on rollers and the addition of liquid fat, as well as the optional addition of emulsifiers such as lecithins.
  • Each of the food components is reduced in particle size before being subjected to treatment by the chocolate refining system.
  • fruits can be included for obtaining the food mixtures, these are previously added as a powder together with liquid edible oils and soy lecithin.
  • Liu describes the obtaining of apple peel powder useful for inhibiting the proliferation of cancer cells.
  • the apple peel is subjected to a previous biochemical preservation treatment with citric acid baths, bleaching with boiling water, dehydrated and grinding until a 40 to 60 mesh powder is obtained.
  • the obtained powder exhibits an aqueous activity of 0.12 to 0.36 and a large amount of flavonoids and anthocyanins.
  • tropical fruit pulps such as mamey cannot be treated with this method since the preservation and bleaching treatment are negative for the preservation of the organoleptic properties of the fruit pulp.
  • Flores describes the obtaining of jams and stable powdered jellies.
  • Strawberries for example are dehydrated until they have a humidity of less than 1% w / w and then crushed to a particle size of 1 mm so as not to disintegrate the seeds. Subsequently the disintegrated fruit is mixed with high amounts of sugar (89% w / w), pectin powder and citric acid to subsequently pack the mixture under vacuum. The product is subsequently mixed with sugar and boiling water to obtain jam or jelly. Unlike the mixtures described by Duran, the mamey powder of the present invention does not include high amounts of sugar or the addition of pectin so that it can be stable on the shelf.
  • Radatti describes the obtaining of food products in the form of flour from fruit waste pulp, which can be used as food supplements.
  • Fruit pulp used to obtain natural juices is washed and dried with calcium hydroxide to be subsequently dehydrated, ground and added with hydrocolloids.
  • the products obtained contain substances that affect the integrity of the cellulosic components that the pulp may contain and the aqueous activity they contain is not specified, which does not guarantee their stability at room temperature.
  • Jiménez describes the obtaining of stable avocado pulp flour by means of the dehydration of the avocado pulp and subsequent addition of various dehydrated vegetable elements to avoid the enzymatic darkening of the pulp.
  • avocados with peel, halved and devoid of seed are dehydrated at high temperatures to obtain dehydrated pulp that is then ground to a particle size of 20 to 35 ⁇ m and mixed with garlic, onion, citric acid and other elements to obtain The stable avocado flour.
  • the mamey powder of the invention can be combined without problems with countless food products to provide mamey flavor.
  • the mamey powder is rehydrated, either by means of the direct addition to the nutrient liquid powder or its addition to foods with important contents of moisture, a paste with an appearance, taste and smell very similar to those exhibited by the fresh pulp of the fruit that can be perfectly integrated into the food mixture forming homogeneous mixtures is generated.
  • the powder of the invention can also be used as a standard and specific reagent to inspect the quality of dehydrated mamey products, as well as to determine their identity and concentration of carbohydrates
  • the mamey powder of the invention By containing the mamey powder of the invention the typical natural components contained in the pulp of the fresh fruit and without the presence of additives that affect its typical organoleptic properties, it becomes a very useful reagent to inspect the typical properties of the mamey fruit, as well as dehydrated obtained from its pulp.
  • the mamey powder of the invention describes a characteristic colorimetric pattern of each species used, both for Calocarpum mammosum Pierre and for Mammea americana L, (see figure 3) that allows laboratory analytical determinations and the inspection of possible dehydrates of mamey in which it is intended to verify the content of mamey pulp and the existence of possible adulterations of the product, such as by adding additives, or various agents that are intended to increase the weight of the mixture and reduce the amount of mamey pulp .
  • bromatological analyzes are performed to verify its components and its organoleptic properties.
  • a process is carried out that includes the following steps: 1. Determination of the colorimetric pattern of the samples.
  • the colorimetric pattern of the powder of the invention used as a standard is determined, using colorimetric techniques by scanning the percentage reflectance readings of the sample based on the wavelength in a range of 400 to 700 nm, using as control the cell that has been used to inspect the sample of the standard. Subsequently, using a sample of the dehydrated product of mamey to be inspected, the same colorimetric scanning is performed at the same conditions as for the standard sample, to obtain the wavelength pattern corresponding to the inspected sample.
  • the colorimetric standards of the standard and the inspected sample are compared with each other to determine if both patterns coincide in their behavior. If the comparison is positive, a bromatological analysis is performed to verify the components and organoleptic properties of the dehydrated mamey inspected, which when compared with the bromatological characteristics of the standard sample, should not present significant variations.
  • the carbohydrate concentration of the inspected sample should not exceed 52% w / w, because it is the maximum concentration contained in the standard.
  • the value of proteins should be in the range of 6.8 to 8.2% w / w, while that of fats in the range of 0.9 to 1.1% w / w, since they are the ranges of value contained in the standard. If it contains a concentration greater than 52% w / w carbohydrates and a concentration lower than the indicated range for proteins and fats, it is concluded that the sample corresponds effectively dehydrated from mamey but that has been adulterated or added with carbohydrates.
  • the method of identifying dehydrates of mamey pulp also allows determining the amount of total carbohydrates contained in the sample using the same methodology described. This from the observation of the applicant that the addition of sugars to the mamey powder of the invention does not alter the behavior of the colorimetric pattern of the powder, but does cause alteration in the dust reflectance values, generally increasing its magnitude. In this case, after determining that the colorimetric standards of the standard and the inspected sample coincide in their behavior, the variation of the reflectance readings between the samples is determined and is related to the concentration of total carbohydrates of the standard, thus determining the concentration of carbohydrates of the inspected sample. As can be seen in example 5, it is feasible to determine the concentration of carbohydrates contained in dehydrated or mamey powders using the described methodology and using as standard the mamey powder of the invention.
  • Example 1 Obtaining stable powder from mamey pulp.
  • the pulp obtained was then subjected to dehydration by termosecado at a temperature of 60 to 120 0 C for 0.5 to 4 hours.
  • the aqueous activity value of a sample of the pulp obtained was determined, obtaining a value of 0.2 to 0.7.
  • the dehydrated pulp with said aqueous activity was mixed with citric acid in a proportion of 0.01 to 2% by weight with respect to the total weight of the dehydrated pulp obtained, to subsequently subject the mixture to continuous grinding by means of a blade mill or turbomoline until a particle size of 125 to 250 ⁇ m is obtained.
  • the obtained powder was sifted by a granulometric classifier according to the desired particle size, grinding again and at the same conditions, the powder that has been retained in the classifier. Obtained the particle size in the mentioned range, the powders were mixed until homogenization. Finally, the powder obtained was placed in polyethylene bags that were subsequently introduced into Pet containers of 100 to 200 g capacity, taking a sample of the powder for subsequent bromatological analysis. Various characteristics of the mamey powder obtained were analyzed by certain analytical methods, obtaining the results shown in Table 2.
  • P ⁇ r ⁇ atls 100 gés ⁇ mieras indicaeo fe s "is equipped by Aquatefi from 3 ⁇ cir rsms Dscagc- 1 to 2S 11 C.
  • the amount of nutritional elements found in the powder of the invention was greater than that found in the fresh pulp of the fruit, which is due to the fact that the nutritional elements of the mamey pulp are concentrated in the powder due to the dehydration process.
  • the enzymatic activities explored in the powder no polyphenol oxidase activity was found, while the proteolytic and lipase activity were also very low;
  • the water activity value was at most 0.6, so that the organoleptic properties of the powder do not suffer alteration during storage due to enzymatic activity or microbial contamination.
  • the powder of the invention was subjected to storage during the course of
  • the powder had a typical smell, color and taste of mamey pulp, and no caking or contamination of any kind was observed.
  • Example 4 Preparation of foods that include the powder of the invention.
  • the mamey powder obtained from example 1 was used to prepare the following food compositions:
  • Example 5 Analytical determination of samples of dehydrated mamey powder.
  • the mamey powder described in example 1 was used as a standard reagent to determine the concentration and identity of various mixtures containing mamey powder.
  • the powder of the invention used as a standard, served as an analytical reference reagent to determine the identity of mamey powder samples, as well as the variation in carbohydrate concentration of mamey powders.
  • Rodr ⁇ guez-Amaya D. B., 1999. Latin American food sources of carotenoids. Latin American Nutrition Archives 49 (3), 74S-84S.

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Abstract

The invention describes stable powders of mamey pulp with prolonged shelf lives at room temperature, which preserve unchanged the typical organoleptic properties of fresh mamey fruit. Mamey powder eliminates the preservation problems associated with the fresh fruit, such as very short after-harvest life, significant loss of water, enzymatic darkening, high probability of deterioration of components thereof and difficult transport. Also described are effective dehydration methods for obtaining stable mamey powder, methods which avoid the amorphous crystallization effect on mamey pulp sugars which occurs at high temperatures and prevents the pulp being processed into powder.

Description

Polvo estable de pulpa de mamey y productos alimenticios a partir de éste. Stable mamey pulp powder and food products from it.
Campo de Ia invención.Field of the invention.
La presente invención se relaciona con Ia preservación de frutos tropicales con una vida de anaquel muy corta, específicamente a Ia preservación de Ia pulpa de mamey mediante su deshidratación controlada hasta su transformación en polvos que pueden almacenarse a temperatura ambiente por periodos prolongados sin que sufran alteraciones en sus propiedades organolépticas.The present invention relates to the preservation of tropical fruits with a very short shelf life, specifically to the preservation of the mamey pulp through its controlled dehydration until its transformation into powders that can be stored at room temperature for prolonged periods without suffering alterations in its organoleptic properties.
Antecedentes de Ia invención.Background of the invention.
El acceso y preservación de los alimentos es una preocupación constante de Ia industria alimenticia a nivel mundial. En gran medida, Ia disponibilidad de los nutrientes encontrados en los alimentos y que son necesarios para el desarrollo humano, depende básicamente de que estos puedan llegar sin alteraciones a las manos del consumidor; una de las formas de lograr esto es mediante el consumo de alimentos frescos. Sin embargo, el disponer de alimentos frescos implica que estos sean trasladados desde el sitio de su producción a los lugares donde serán adquiridos y consumidos; en múltiples ocasiones, el traslado de éste tipo de alimentos, sobre todo a grandes distancias, es una gran limitante para su distribución debido a los periodos tan cortos de preservación que poseen. Un ejemplo de ello son las frutas, las cuales se prefieren comer frescas debido a Ia gran facilidad que representa su consumo, ya que solo es necesario lavarlas para poder consumirlas. A pesar de que las frutas reúnen características organolépticas muy deseables para su consumo directo como alimento fresco, en su gran mayoría solo pueden ser producidas y consumidas en temporadas específicas del año, por Io que su disponibilidad llega a ser limitada y su consumo preferentemente es local, como es el caso de múltiples frutas tropicales. Como consecuencia de estos efectos, múltiples frutas tropicales no se consumen de manera generalizada, Io que causa también desperdicios importantes en las épocas de cosecha.The access and preservation of food is a constant concern of the food industry worldwide. To a large extent, the availability of nutrients found in food and that are necessary for human development, basically depends on their being able to reach the consumer's hands without alterations; One of the ways to achieve this is by eating fresh foods. However, having fresh food means that they are transferred from the place of production to the places where they will be acquired and consumed; on multiple occasions, the transfer of this type of food, especially over long distances, is a great limitation for its distribution due to the short preservation periods they have. An example of this are fruits, which are preferred to eat fresh due to the great ease of consumption, since it is only necessary to wash them in order to consume them. Although the fruits have very desirable organoleptic characteristics for direct consumption as fresh food, the vast majority can only be produced and consumed in specific seasons of the year, so that their availability becomes limited and their consumption is preferably local , as is the case with Multiple tropical fruits As a consequence of these effects, multiple tropical fruits are not consumed in a generalized manner, which also causes significant waste at harvest times.
A pesar de Io anterior, existe en el mercado una gran demanda por frutas tropicales, ya que son consideradas productos alimenticios de presentación y sabor novedosos, con altos contenidos nutricionales y que proporcionan beneficios claros para Ia salud, ya que son una fuente importante de sustancias antioxidantes o con que exhiben diversas actividades farmacológicas. Así mismo, en Ia actualidad existe una mayor tendencia a evitar el consumo de alimentos altamente procesados, sintéticos o que tengan productos químicos, ya que se prefiere consumir alimentos naturales o con procesamientos industriales mínimos. En este sentido, productos obtenidos a partir de frutas tropicales que exhiban las mismas propiedades organolépticas y que puedan ser más estables en anaquel son muy apreciados y deseables en el mercado.In spite of the above, there is a great demand in the market for tropical fruits, since they are considered novel presentation and flavor food products, with high nutritional contents and that provide clear health benefits, since they are an important source of substances antioxidants or with which they exhibit various pharmacological activities. Likewise, at present there is a greater tendency to avoid the consumption of highly processed, synthetic or chemical-containing foods, since it is preferred to consume natural foods or with minimal industrial processes. In this sense, products obtained from tropical fruits that exhibit the same organoleptic properties and that may be more stable on shelf are highly appreciated and desirable in the market.
Uno de las frutas tropicales más apreciadas en mercados locales es el mamey, del cual su pulpa puede comerse directamente al natural debido al sabor delicado y delicioso que posee. En América latina, Ia pulpa del fruto es muy apreciada y es considerada "delicatessen", gracias a su sabor y a su baja disponibilidad en el mercado, principalmente en las zonas urbanas.One of the most appreciated tropical fruits in local markets is the mamey, from which its pulp can be eaten directly from the natural one due to the delicate and delicious flavor it possesses. In Latin America, the pulp of the fruit is highly appreciated and is considered "delicatessen", thanks to its flavor and its low availability in the market, mainly in urban areas.
El mamey es un árbol tropical proveniente de América Central el cual seThe mamey is a tropical tree from Central America which is
1,2 localiza y se cultiva típicamente en el sur de México y Centroamérica . Se distinguen varias especies de Ia planta importantes a nivel comercial, tales como Pouteria sapota (Jacq.) H. E. Moore & Stearn (anteriormente clasificada como Lúcuma mammosa Gaertn) a Ia que también se Ie conoce como1.2 locates and is typically grown in southern Mexico and Central America. Several important plant species are distinguished commercially, such as Pouteria sapota (Jacq.) H. E. Moore & Stearn (previously classified as Lúcuma mammosa Gaertn) which is also known as
33
Calocarpum mammosum (L) Pierre y que pertenece a Ia familia Sapotaceae , así como Mammea americana L. que pertenece a Ia familia Guttiferae. A pesar de que existe una gran variación en el tamaño y forma de! fruto, así como en Ia calidad, sabor y color de su pulpa, se distinguen algunas variedades que producen frutos de mayor calidad. Por ejemplo, las variedades Pantin y Magaña representan del 95 al 98% del total de Ia superficie cultivada en Florida, mientras que las variedades Tazumal y Pace resultan también de interés comercial pero en mucho menor escala. En el caso de México, tanto Pouteria sapota como Mammea americana L poseen gran importancia comercial, alcanzando producciones anuales del orden de 12,700 toneladas, distinguiéndose el estado de Yucatán el cual aporta el 49.4% de Ia producción nacional; otros estados como Puebla, Guerrero, Edo. de México, Veracruz, San Luis Potosí, Tabasco, Oaxaca, Colima y Chiapas también son importantesCalocarpum mammosum (L) Pierre and which belongs to the Sapotaceae family, as well as Mammea americana L. which belongs to the Guttiferae family. Although there is a great variation in the size and shape of! fruit, as well as in the quality, flavor and color of its pulp, some varieties that produce higher quality fruits are distinguished. For example, the Pantin and Magaña varieties represent 95 to 98% of the total cultivated area in Florida, while the Tazumal and Pace varieties are also of commercial interest but on a much smaller scale. In the case of Mexico, both Pouteria sapota and Mammea americana L have great commercial importance, reaching annual productions of the order of 12,700 tons, distinguishing the state of Yucatán which contributes 49.4% of the national production; other states like Puebla, Guerrero, Edo. Mexico, Veracruz, San Luis Potosí, Tabasco, Oaxaca, Colima and Chiapas are also important
4 productores de mamey .4 producers of mamey.
El fruto del mamey es ovoide distinguiéndose una cascara áspera de color gris-rojizo, con dimensiones generalmente de 30 cm de largo por 15 cm de ancho, y con un peso de hasta 2.5 Kg. El fruto contiene normalmente una sola semilla grande, aunque existen variedades que pueden presentar hasta 3 semillas, así como una pulpa de color naranja a roja cuando está madura con sabor dulce y consistencia muy suave que Ie permiten tener una calidad excelente para postre.The fruit of the mamey is ovoid distinguishing a rough shell of gray-reddish color, with dimensions generally 30 cm long by 15 cm wide, and weighing up to 2.5 Kg. The fruit normally contains a single large seed, although there are varieties that can present up to 3 seeds, as well as an orange to red pulp when ripe with a sweet taste and very soft consistency that allow it to have an excellent quality for dessert.
La cosecha del fruto se realiza preferentemente en los meses de abril y mayo, aunque algunas otras variedades como Tazumal y Pace pueden dar frutos en otras épocas del año. El fruto se colecta para su distribución comercial, cuando en Ia cascara se detecta Ia aparición de un color rosado tipo salmón, indicando el inicio de Ia etapa de maduración del fruto.The harvest of the fruit is preferably done in the months of April and May, although some other varieties such as Tazumal and Pace can bear fruit at other times of the year. The fruit is collected for commercial distribution, when the appearance of a pink salmon color is detected in the shell, indicating the beginning of the fruit ripening stage.
La pulpa de mamey contiene componentes de alto valor nutricional, tal como puede observarse en Ia tabla 1 , distinguiéndose su alto contenido en humedad, fibra, carbohidratos, carotenos y ácido ascórbico. Contiene a su vez un bajo contenido de ácidos por Io que presenta un pH de 4.5 a 6, mientras que Ia fibra está constituida por celulosa y lignina; los carbohidratos presentes en Ia pulpa son básicamente glucosa, fructuosa y sacarosa.Mamey pulp contains components of high nutritional value, as can be seen in Table 1, distinguishing its high content of moisture, fiber, carbohydrates, carotenes and ascorbic acid. It also contains a low acid content per Io that has a pH of 4.5 to 6, while the fiber it consists of cellulose and lignin; The carbohydrates present in the pulp are basically glucose, fructose and sucrose.
El fruto contiene violaxantina como pigmento principal carotenoide en IaThe fruit contains violaxanthin as the main carotenoid pigment in Ia
5 cascara y Ia pulpa , mientras que en las semillas se han identificado compuestos bencenoides tales como lucumina, lucuminamida y ácido5 husk and pulp, while in the seeds benzenoid compounds such as lucumin, lucuminamide and acid have been identified
6 lucumínico . Por otra parte, se han identificado en el fruto compuestos con actividad antioxidante importante tales como ácido gálico, (+)-galocatequina, (+)-catequina, (-)-epicatequina, dihidromiricetina, (+)-3-O-galato de catequina y6 lucumin. On the other hand, compounds with significant antioxidant activity such as gallic acid, (+) - gallocatechin, (+) - catechin, (-) - epicatechin, dihydromyricetin, (+) - 3-O-gallate have been identified in the fruit catechin and
7 polifenoles como miricitrina (ver figura 1), así como benzaldehído, hexanal y7 polyphenols such as myrithitrine (see figure 1), as well as benzaldehyde, hexanal and
8 ácido hexadecanoico como los principales constituyentes volátiles del fruto .8 hexadecanoic acid as the main volatile constituents of the fruit.
Compuestos tales como hidroxicinamatos, glicósidos de flavona y numerosos fenoles no identificados se han encontrado en el fruto, así como cantidades significativas de fibra dietética total (6.1 g/100 g) y pectina (0.77 g/100 g) que llegan a ser superiores a los encontrados en Ia mayoría de las frutas (por ejemplo cerezas y frambuesas) y comparables con los encontrados en uva, naranja, manzana y plátano; debido a ello el consumo de mamey representaCompounds such as hydroxycinnamates, flavone glycosides and numerous unidentified phenols have been found in the fruit, as well as significant amounts of total dietary fiber (6.1 g / 100 g) and pectin (0.77 g / 100 g) that become greater than those found in most fruits (for example cherries and raspberries) and comparable with those found in grapes, orange, apples and bananas; because of this the consumption of mamey represents
9 ventajas nutricionales y saludables . La pulpa del mamey se consume generalmente mezclada con otros ingredientes para obtener batidos, helados, o bien para obtener jaleas, pastas y conservas, aunque sus variantes alimenticias son muy vastas.9 nutritional and healthy benefits. Mamey pulp is usually consumed mixed with other ingredients to obtain smoothies, ice cream, or to obtain jellies, pastes and preserves, although its food variants are very vast.
Al igual que para otras frutas tropicales (aguacate y mango, por ejemplo), Ia vida postcosecha del fruto fresco del mamey es muy corta (hasta 7 días), dependiendo de Ia madurez del fruto y de las condiciones de su almacenamiento; así mismo el fruto fresco presenta altas tasas de intercambioAs with other tropical fruits (avocado and mango, for example), the post-harvest life of the fresh mamey fruit is very short (up to 7 days), depending on the maturity of the fruit and the storage conditions; the fresh fruit also has high exchange rates
15 de gases con el ambiente , está expuesto a putrefacciones causadas por15 of gases with the environment, is exposed to rot caused by
16 microorganismos oportunistas y a Ia pérdida de agua y abrasión de su cascara, por Io que su conservación como fruto fresco resulta muy difícil e infructuosa. Así mismo el fruto almacenado alcanza su mayor concentración de16 opportunistic microorganisms and the loss of water and abrasion of their husk, so that their conservation as a fresh fruit is very difficult and fruitless Likewise, the stored fruit reaches its highest concentration of
1717
CO y etileno a los 8 días aun en condiciones controladas de almacenaje mientras que Ia cantidad de pectina soluble en agua de Ia pulpa aumentaCO and ethylene at 8 days even under controlled storage conditions while the amount of water soluble pectin in the pulp increases
18 conforme Ia firmeza del fruto disminuye , Io que no permite extender Ia vida útil del fruto.18 as the firmness of the fruit decreases, which does not allow extending the useful life of the fruit.
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A pesar de que se han reportado diversos intentos para extender Ia vida postcosecha del fruto fresco del mamey mediante tratamiento con aguaAlthough several attempts have been reported to extend the post-harvest life of the fresh mamey fruit through water treatment
19 caliente (60°C por 60 minutos), así como recubriendo el fruto con 1-metil- ciclopropeno, Ia vida útil del fruto fresco no rebasa los 14 días de almacenamiento aun en condiciones controladas, Io que limita importantemente su distribución. Por otro lado, a pesar de que recubriendo el fruto con cera carnauba se mantiene un buen aspecto visual del fruto así como una menor pérdida de agua durante su almacenaje a 200C, el recubrimiento acelera el ablandamiento del fruto, reduciendo su vida útil en al menos 3 días en comparación con el fruto fresco sin recubrir.19 hot (60 ° C for 60 minutes), as well as covering the fruit with 1-methylcyclopropene, the shelf life of the fresh fruit does not exceed 14 days of storage even under controlled conditions, which significantly limits its distribution. On the other hand, although coating the fruit with carnauba wax maintains a good visual appearance of the fruit as well as a lower loss of water during storage at 20 0 C, the coating accelerates the Fruit softening, reducing its shelf life by at least 3 days compared to fresh uncoated fruit.
Por otro lado, técnicas de preservación de frutas tropicales frescas que permiten extender su periodo de vida postcosecha, tales como el almacenamiento refrigerado (10-150C), y el recubrimiento del fruto con diversasOn the other hand, preservation techniques of fresh tropical fruits that allow extending their post-harvest life period, such as refrigerated storage (10-15 0 C), and coating the fruit with various
20,21 ceras , no resultan convenientes aplicar al fruto fresco del mamey debido a una serie de inconvenientes que no permiten mejorar las cualidades del fruto fresco.20,21 waxes, it is not convenient to apply to the fresh fruit of the mamey due to a series of inconveniences that do not allow to improve the qualities of the fresh fruit.
La conservación del fruto fresco de mamey a temperaturas menores a 100C afecta significativamente su contenido de azúcares, principalmente deThe conservation of fresh mamey fruit at temperatures below 10 0 C significantly affects its sugar content, mainly from
22 fructosa , mientras que la refrigeración de Ia pulpa a 150C durante periodos prolongados de tiempo (6 meses) causa pérdidas en el contenido de azúcares22 fructose, while refrigeration of the pulp at 15 0 C for prolonged periods of time (6 months) causes losses in the sugar content
23 y deterioro en sus propiedades organolépticas . La maduración del fruto fresco del mamey a temperatura ambiente y bajo refrigeración, causa deterioro en su concentración de pectina debido a demetoxilación, mientras que Ia refrigeración23 and deterioration in its organoleptic properties. The ripening of the fresh fruit of the mamey at room temperature and under refrigeration, causes deterioration in its concentration of pectin due to demethoxylation, while refrigeration
24 causa daños similares en frutas tropicales . A pesar de que la refrigeración de24 causes similar damage to tropical fruits. Although the cooling of
25 frutos no maduros de mamey puede retardar su proceso de maduración , esta causa un deterioro muy importante en sus cualidades organolépticas.25 immature fruits of mamey can delay its ripening process, this causes a very important deterioration in its organoleptic qualities.
En cuanto a las actividades enzimáticas propias del fruto que están relacionadas con Ia degradación de Ia pulpa debido a oscurecimiento enzimático, al igual que para otras frutas tropicales este efecto llega a ser muy importante a considerar, ya que está directamente relacionado con Ia degradación postcosecha del fruto. En el caso del mamey, se ha demostrado que Ia actividad de Ia polifenoloxidasa y peroxidasa que se encuentra en el fruto, varía en proporción directa conforme se incrementa Ia temperatura de almacenaje, observándose mayor actividad a 20°C y la consecuente aparición de oscurecimiento enzimático. Sin embargo, a pesar de que Ia actividad de peroxidasa en el mamey permanece constante a 2.5°C, (85.3 unidades / g min)As for the enzymatic activities of the fruit that are related to the degradation of the pulp due to enzymatic darkening, as for other tropical fruits this effect becomes very important to consider, since it is directly related to the postharvest degradation of the fruit. In the case of mamey, it has been shown that the activity of the polyphenoloxidase and peroxidase found in the fruit varies in direct proportion as the storage temperature increases, observing greater activity at 20 ° C and the consequent appearance of enzymatic darkening . However, although the activity of peroxidase in the mamey remains constant at 2.5 ° C, (85.3 units / g min)
26 se observa pérdida significativa de Ia firmeza de Ia pulpa .26 significant loss of the firmness of the pulp is observed.
Debido a que múltiples factores propios del fruto fresco de mamey impiden o dificultan su traslado como alimento fresco, es necesario desarrollar alternativas tecnológicas que permitan conservar Ia pulpa del fruto en condiciones tales que se conserven sus propiedades organolépticas y alimenticias típicas, y que a Ia vez pueda tener una vida más amplia de anaquel; esto permitiría hacer más disponible el fruto de mamey para Ia obtención de múltiples productos alimenticios, aun en lugares donde el mamey no se cultiva.Because multiple factors typical of the fresh mamey fruit prevent or hinder its transfer as fresh food, it is necessary to develop technological alternatives that allow the pulp of the fruit to be preserved in conditions such that its typical organoleptic and nutritional properties are preserved, and that at the same time can have a wider shelf life; This would make the mamey fruit more available for obtaining multiple food products, even in places where the mamey is not grown.
Objetivos de Ia invención.Objectives of the invention.
Es uno de los objetivos de Ia presente invención proporcionar un producto alimenticio de pulpa de mamey en polvo, estable en anaquel a temperatura ambiente y con las características organolépticas y nutritivas típicas del fruto.It is one of the objectives of the present invention to provide a food product of mamey pulp powder, stable on shelf at room temperature and with the typical organoleptic and nutritional characteristics of the fruit.
Es otro de los objetivos de Ia invención proporcionar un producto alimenticio de pulpa de mamey en polvo estable en anaquel, que pueda rehidratarse con facilidad hasta el momento de usarse.It is another of the objectives of the invention to provide a food product of mamey pulp in stable shelf powder, which can be easily rehydrated until it is used.
Es otro de los objetivos de Ia invención proporcionar un producto alimenticio de pulpa de mamey en polvo estable en anaquel, que no presente oscurecimiento enzimático o no enzimático, así como una actividad acuosa de 0.2 a 0.7.It is another of the objectives of the invention to provide a food product of mamey pulp in stable powder on shelf, which does not present enzymatic or non-enzymatic darkening, as well as an aqueous activity of 0.2 to 0.7.
Es otro de los objetivos de Ia invención proporcionar un estándar analítico para determinar Ia identidad de polvos de pulpas de mamey. Otro de los objetivos de Ia presente invención es proporcionar métodos de obtención eficientes para Ia obtención de un producto alimenticio de pulpa de mamey en polvo, estable en anaquel a temperatura ambiente y con las características organolépticas y nutritivas típicas del fruto.It is another objective of the invention to provide an analytical standard for determining the identity of mamey pulp powders. Another objective of the present invention is to provide efficient methods for obtaining a food product of mamey pulp powder, stable on shelf at room temperature and with the typical organoleptic and nutritional characteristics of the fruit.
Otro de los objetivos de Ia presente invención es proporcionar métodos de determinación analítica para determinar Ia identidad de polvos de pulpas de mamey.Another of the objectives of the present invention is to provide analytical determination methods to determine the identity of mamey pulp powders.
Es otro de los objetivos de Ia invención proporcionar productos alimenticios que contengan pulpa de mamey en polvo, estable en anaquel a temperatura ambiente y con las características organolépticas y nutritivas típicas del fruto.It is another objective of the invention to provide food products containing mamey pulp powder, stable on shelf at room temperature and with the typical organoleptic and nutritional characteristics of the fruit.
Breve descripción de las figuras.Brief description of the figures.
Figura 1. Se muestran compuestos polifenólicos típicos con actividad antioxidante encontrados en Ia pulpa de Pouteria sapota, tales como ácido gálico (1), (+)-galocatequina (2), (+)-catequina (3), (-)- epicatequina (4), dihidromiricetina (5), miricitrina (6) y (+)-3-O-galato de catequina (7).Figure 1. Typical polyphenolic compounds with antioxidant activity found in the pulp of Pouteria sapota are shown, such as gallic acid (1), (+) - gallocatechin (2), (+) - catechin (3), (-) - epicatechin (4), dihydromyricetin (5), mycithitrine (6) and (+) - 3-O-catechin gallate (7).
Figura 2. Se muestran los espectros colorimétricos obtenidos a partir de muestras de polvo de mamey de Ia invención, específicamente de Calocarpum mammosum Pierre. Se observa polvo de mamey estándar (A), polvos de mamey del Estado de Veracruz (B, C, D) y polvo de mamey estándar mezclado con 30% de glucosa (E).Figure 2. The colorimetric spectra obtained from samples of mamey powder of the invention, specifically Calocarpum mammosum Pierre, are shown. Standard mamey powder (A), mamey powders from the State of Veracruz (B, C, D) and standard mamey powder mixed with 30% glucose (E) are observed.
Figura 3. Se muestran los espectros colorimétricos obtenidos a partir de muestras de polvo de mamey de Ia invención. Se observa polvo estándar de Calocarpum mammosum Pierre (A), polvo estándar de Mammea americana L (B) y polvos de pulpa de aguacate Hass (C y D).Figure 3. The colorimetric spectra obtained from samples of mamey powder of the invention are shown. Standard powder of Calocarpum mammosum Pierre (A), standard powder of Mammea americana L (B) and Hass avocado pulp powders (C and D).
Descripción detallada de Ia invención.Detailed description of the invention.
La presente invención proporciona polvos de pulpa de mamey con una gran estabilidad a temperatura ambiente, Io que les permite conservar inalteradas las propiedades organolépticas y nutritivas originales del fruto de mamey. La gran estabilidad que exhibe Ie permite tiempos de almacenaje de al menos 1 año a temperatura ambiente sin que presente contaminación ó alteraciones en su color, sabor, aroma y propiedades nutritivas. Así mismo, el polvo de mamey descrito aquí no presenta oscurecimiento enzimático o no enzimático, de tal manera que las propiedades organolépticas originales y típicas del fruto de mamey del cual se obtiene se conservan.The present invention provides mamey pulp powders with great stability at room temperature, which allows them to keep the original organoleptic and nutritional properties of the mamey fruit unaltered. The great stability that it exhibits allows storage times of at least 1 year at room temperature without any contamination or alterations in its color, taste, aroma and nutritional properties. Likewise, the mamey powder described here does not show enzymatic or non-enzymatic darkening, such that the original and typical organoleptic properties of the mamey fruit from which it is obtained are preserved.
El polvo de pulpa de mamey de Ia invención representa una excelente alternativa para Ia conservación eficiente de Ia pulpa de mamey y elimina por completo los problemas asociados a Ia pérdida de propiedades organolépticas durante el almacenaje, transporte y vida postcosecha del fruto fresco.The mamey pulp powder of the invention represents an excellent alternative for the efficient conservation of the mamey pulp and completely eliminates the problems associated with the loss of organoleptic properties during storage, transport and post-harvest life of the fresh fruit.
El polvo de mamey es completamente rehidratable en el momento de usarse, bastando agregar cualquier líquido de interés para formar una pasta uniforme con aspecto muy semejante al de Ia pulpa del fruto fresco. El polvo hidratado puede ocuparse de Ia misma manera que se ocupa Ia pulpa del fruto fresco, permitiendo combinarse con una gran cantidad de productos alimenticios para obtener productos derivados con sabor a pulpa de mamey.Mamey powder is completely rehydrated at the time of use, just add any liquid of interest to form a uniform paste that looks very similar to the pulp of the fresh fruit. The hydrated powder can be used in the same way that the pulp of the fresh fruit is used, allowing it to be combined with a large number of food products to obtain derived products flavored with mamey pulp.
El polvo de Ia invención tiene un tamaño de partícula de 125 a 250 μm, Io que Ie permite proporcionar una buena sensación y textura al gusto si es que se consume directamente, mientras que Ie permite una buena disolución en líquidos y buena dispersión en sólidos. En cuanto a su actividad acuosa, el polvo de Ia invención exhibe valores de 0.2 a 0.7, preferentemente de 0.4 a 0.6, Io que permite que no exista contaminación por microorganismos debido a que a estos valores de actividad acuosa, el establecimiento y crecimiento de microorganismos se inhibe completamente. Con respecto a Ia presencia de actividades enzimáticas relacionadas con el desarrollo de oscurecimiento enzimático en alimentos, estas resultan no estar presentes en el polvo de Ia invención, incluso cuando el polvo se somete a determinación de Ia actividad de polifenoloxidasa durante tiempos largos (60 min) y a las máximas concentraciones ensayadas en Ia determinación.The powder of the invention has a particle size of 125 to 250 μm, which allows it to provide a good sensation and texture to taste if it is consumed directly, while allowing a good dissolution in liquids and good dispersion in solids. As for its water activity, the Powder of the invention exhibits values of 0.2 to 0.7, preferably 0.4 to 0.6, which allows that there is no contamination by microorganisms because of these values of aqueous activity, the establishment and growth of microorganisms is completely inhibited. With respect to the presence of enzymatic activities related to the development of enzymatic darkening in foods, these are not present in the powder of the invention, even when the powder is subjected to determination of the activity of polyphenoloxidase for long periods (60 min) and to the maximum concentrations tested in the determination.
De manera general, el polvo estable de mamey de Ia presente invención es una composición que comprende pulpa deshidratada de mamey en un porcentaje del 98 al 99.99% en peso con respecto del peso total de Ia composición, y un aditivo de molienda seleccionado del grupo que comprende ácido cítrico, ácido ascórbico o mezclas de los mismos en un porcentaje del 0.01 al 2% en peso con respecto del peso total de Ia composición.In general, the stable mamey powder of the present invention is a composition comprising dehydrated mamey pulp in a percentage of 98 to 99.99% by weight with respect to the total weight of the composition, and a grinding additive selected from the group that It comprises citric acid, ascorbic acid or mixtures thereof in a percentage of 0.01 to 2% by weight with respect to the total weight of the composition.
En su conjunto, las características anteriores Ie permiten al polvo de mamey ser estable a temperatura ambiente durante periodos prolongados de almacenaje, conservando inalteradas las propiedades organolépticas y alimenticias típicas que se observan en Ia pulpa del fruto fresco. Así mismo, el polvo de Ia invención contiene una mayor concentración de sus elementos nutritivos por unidad de peso en comparación con las mismas cantidades de Ia pulpa del fruto fresco, por Io que pueden ocuparse volúmenes menores del polvo para Ia obtención de productos alimenticios, permaneciendo su valor nutricional.As a whole, the above characteristics allow mamey powder to be stable at room temperature for prolonged periods of storage, while maintaining the typical organoleptic and nutritional properties observed in the pulp of the fresh fruit. Likewise, the powder of the invention contains a greater concentration of its nutritional elements per unit of weight in comparison with the same quantities of the pulp of the fresh fruit, so that smaller volumes of the powder can be used to obtain food products, remaining its nutritional value
El polvo estable puede constituir en si mismo un producto directamente consumible y comercial, ya que el polvo puede ser fácilmente colectado, almacenado, transportado, vendido y utilizado a través de su empaque en envases sellados, los cuales pueden ser transparentes. El polvo puede ser empacado sin necesidad de utilizar vacío para eliminar el aire residente en el envase, ya que no sufre contaminación alguna, por Io que los costos asociados a este proceso disminuyen notablemente.The stable powder can itself constitute a directly consumable and commercial product, since the powder can be easily collected, stored, transported, sold and used through its packaging in sealed containers, which can be transparent. The powder can be packed without using a vacuum to remove the resident air in the container, since it does not suffer any contamination, so the costs associated with this process decrease significantly.
El polvo descrito aquí es fácilmente soluble en agua y en otros líquidos compatibles, tales como leche, jugos concentrados, etc., por Io que puede utilizarse para obtener diversas clases de bebidas, tales como bebidas refrescantes, licuados, jarabes o similares, dependiendo de Ia sustancia comestible que sea utilizada. Este proceso puede realizarse directamente por el consumidor o en Ia industria de obtención de bebidas, simplemente disolviendo una cantidad pequeña del polvo de Ia invención concentrado directamente en un vaso con agua o leche y agregando opcionalmente azúcar o dulcificantes similares en las proporciones deseadas. Al igual que para bebidas, el polvo de mamey puede combinarse perfectamente con yogures, helados, pasteles, mermeladas, jaleas, productos diversos de confitería, complementos alimenticios, alimentos para bebes, papillas o licores, resultando en Ia obtención de excelentes productos alimenticios con sabor a mamey.The powder described here is easily soluble in water and other compatible liquids, such as milk, concentrated juices, etc., so it can be used to obtain various kinds of beverages, such as soft drinks, smoothies, syrups or the like, depending on The edible substance that is used. This process can be carried out directly by the consumer or in the beverage production industry, simply by dissolving a small amount of the powder of the invention concentrated directly in a glass with water or milk and optionally adding sugar or similar sweeteners in the desired proportions. As for drinks, mamey powder can be perfectly combined with yogurts, ice cream, cakes, jams, jellies, various confectionery products, food supplements, baby food, porridge or spirits, resulting in obtaining excellent flavored food products to mamey.
El polvo de Ia invención se puede utilizar para proporcionar sabor a pulpa de mamey en múltiples mezclas alimenticias, para Io cual debe agregarse una cantidad suficiente del mismo para impartir las cualidades deseadas de sabor, aspecto y aroma a mamey a los comestibles en los cuales se adicionará. En dichas mezclas alimenticias, el polvo de mamey de Ia invención se encuentra generalmente en cantidades de 10 a 20% en peso con respecto del peso total de Ia mezcla alimenticia. Las características organolépticas del polvo de Ia invención son Io suficientemente concentradas para desarrollar Ia intensidad deseable de sabor y olor a mamey en el material alimenticio que se agregue, por Io que pueden ocuparse bajas cantidades del mismo, aunque Ia cantidad empleada depende de Ia preferencia del consumidor o bien de Ia composición alimenticia que se trate.The powder of the invention can be used to provide mamey pulp flavor in multiple food mixtures, for which a sufficient amount thereof must be added to impart the desired qualities of mamey flavor, appearance and aroma to the edibles in which will add. In said food mixtures, the mamey powder of the invention is generally in amounts of 10 to 20% by weight with respect to the total weight of the food mixture. The organoleptic characteristics of the powder of the invention are sufficiently concentrated to develop the desirable intensity of taste and smell of mamey in the food material that is added, so that low amounts thereof can be occupied, although the amount used depends on the preference of the consumer or of the food composition in question.
El polvo estable de Ia invención reduce el costo del empaquetado, almacenamiento, y transporte al reducirse el peso y el volumen del producto deseado, en este caso fruto fresco de mamey. Así mismo el polvo de Ia invención representa una buena alternativa como un producto alimenticio instantáneo, conveniente y de gran calidad nutricional.The stable powder of the invention reduces the cost of packaging, storage, and transportation by reducing the weight and volume of the product desired, in this case fresh fruit of mamey. Likewise, the powder of the invention represents a good alternative as an instant, convenient and high nutritional quality food product.
Durante el almacenamiento, el polvo de pulpa de mamey de Ia invención no sufre alteraciones de color, con Io que se conserva el aspecto agradable observado en el fruto original así como el color natural característico de Ia pulpa de mamey. Aunque cualquier recipiente conveniente para el envasado del polvo se puede utilizar, se prefiere almacenar el polvo de Ia invención a temperatura ambiente en envases cerrados trasparentes, en ausencia de humedad y luz solar directa, con Io que el polvo permanece inalterado en sus propiedades al menos durante 1 año, eliminando con ello los procedimientos de conservación en frío, el uso de antioxidantes tóxicos y el uso de cámaras de refrigeración para el transporte del fruto.During storage, the mamey pulp powder of the invention does not suffer color alterations, so that the pleasant appearance observed in the original fruit is conserved as well as the characteristic natural color of the mamey pulp. Although any convenient container for the packaging of the powder can be used, it is preferred to store the powder of the invention at room temperature in closed transparent containers, in the absence of moisture and direct sunlight, so that the powder remains unchanged in its properties at least for 1 year, thereby eliminating cold preservation procedures, the use of toxic antioxidants and the use of refrigeration chambers for fruit transport.
Las características del polvo de Ia invención permiten que al combinarse con alimentos líquidos o sólidos, se obtengan mezclas alimenticias homogéneas de manera más sencilla y sin el uso de procedimientos industriales complejos que implican un gasto mayor de energía, y en consecuencia un mayor costo.The characteristics of the powder of the invention allow that when combined with liquid or solid foods, homogeneous food mixtures are obtained more simply and without the use of complex industrial processes that involve a greater expenditure of energy, and consequently a higher cost.
Debido a las características de conservación del polvo de mamey de Ia invención, se mantiene una calidad uniforme en el producto final y en los productos derivados de éste, así como en sus características organolépticas y en el color característico de Ia pulpa del mamey.Due to the conservation characteristics of the mamey powder of the invention, a uniform quality is maintained in the final product and in the products derived therefrom, as well as in its organoleptic characteristics and in the characteristic color of the mamey pulp.
El polvo de Ia invención también permite el transporte seguro de mayor número de gramos de pulpa de mamey procesada al mismo tiempo, sin que ésta presente riesgos por oscurecimiento ó contaminación microbiana; así mismo su larga vida de anaquel y de conservación de sus propiedades alimenticias, permite con suma facilidad su transporte y distribución a cualquier lugar donde sea requerido el producto. Para la obtención del polvo estable de pulpa de mamey de Ia invención, se realiza un proceso que permite Ia deshidratación eficiente de Ia pulpa de mamey en conjunto con Ia cascara del fruto. Para efectos de Ia invención se entiende como deshidratación eficiente al proceso que permite Ia eliminación del agua contenida en Ia pulpa de mamey mediante deshidratación hasta dejar el mínimo necesario de humedad para impedir crecimiento de microorganismos. Con ello se elimina Ia utilización de procedimientos o dispositivos complicados que pueden generar pérdidas importantes en el rendimiento de obtención de Ia pulpa deshidratada o Ia inversión de un mayor tiempo en Ia obtención del polvo del fruto.The powder of the invention also allows the safe transport of a greater number of grams of processed mamey pulp at the same time, without this presenting risks due to darkening or microbial contamination; Likewise, its long shelf life and the preservation of its nutritional properties allow its transport and distribution to any place where the product is required. To obtain the stable mamey pulp powder of the invention, a process is carried out that allows the efficient dehydration of the mamey pulp in conjunction with the fruit peel. For the purposes of the invention, efficient dehydration is understood as the process that allows the elimination of the water contained in the breast pulp by means of dehydration until the minimum moisture necessary is left to prevent the growth of microorganisms. This eliminates the use of complicated procedures or devices that can generate significant losses in the yield of obtaining the dehydrated pulp or the investment of a longer time in obtaining the fruit powder.
A pesar de que comúnmente Ia conservación de frutas en condiciones óptimas de consumo, se ha logrado mediante el uso de técnicas comunes de conservación que incluyen congelación, deshidratación mediante secado al sol o por aire caliente y liofilización, dichos métodos necesitan tiempos de procesamiento muy largos para obtener productos que puedan ser estables en anaquel (al menos de 20 a 24 hrs.). En este sentido, el secado de frutas es una opción muy utilizada para Ia obtención de productos que exhiben mayores tiempos de conservación, sin embargo las condiciones de un secado efectivo dependen básicamente de las características del fruto. Por ejemplo, frutas secas como manzana, pera, ó cereza, solo pueden ser estables a temperatura ambiente con contenidos máximos de humedad del 23%, mientras que en periodos largos de deshidratación, los carbohidratos típicos del fruto resultan afectados, se pierde el aroma característico de Ia fruta y se presentan reacciones de oscurecimiento, las cuales solo pueden controlarse con Ia adición de aditivos que proporcionan sabores indeseables al producto final. Por ejemplo, frutas secas comercialmente disponibles tienden a ser resistentes y correosas en textura, oscuras y poco atractivas en su color, así como con un típico sabor caramelizado, careciendo del aroma de Ia fruta fresca.Although commonly the preservation of fruits in optimal conditions of consumption, has been achieved through the use of common preservation techniques that include freezing, dehydration by drying in the sun or by hot air and lyophilization, these methods need very long processing times to obtain products that can be stable on shelf (at least 20 to 24 hrs.). In this sense, the drying of fruits is a widely used option for obtaining products that exhibit longer shelf life, however the conditions of effective drying basically depend on the characteristics of the fruit. For example, dried fruits such as apple, pear, or cherry, can only be stable at room temperature with maximum moisture content of 23%, while in long periods of dehydration, the typical carbohydrates of the fruit are affected, the characteristic aroma is lost of the fruit and darkening reactions occur, which can only be controlled with the addition of additives that provide undesirable flavors to the final product. For example, commercially available dried fruits tend to be resistant and leathery in texture, dark and unattractive in color, as well as with a typical caramelized flavor, lacking the aroma of fresh fruit.
Por otro lado, el secado de frutas mediante deshidratación, no garantiza necesariamente que las frutas secas tengan periodos prolongados de conservación a temperatura ambiente, ya que diversos factores asociados al fruto seco están involucrados en su estabilidad en anaquel. En este sentido, el pH y Ia actividad acuosa del producto, así como las características físicas del fruto a deshidratar resultan determinantes para Ia obtención de frutos secos estables; por ejemplo Ia generación de microorganismos que pueden descomponer alimentos conservados está relacionada con valores mínimos de actividad acuosa de 0.93 o 0.94, por Io que Ia mayoría de las tecnologías dirigidas a Ia obtención de frutas secas tratan de obtener productos con valores de actividad acuosa menores a 0.9.On the other hand, drying fruits by dehydration does not necessarily guarantee that dried fruits have prolonged periods of conservation at room temperature, since various factors associated with the dried fruit are involved in its shelf stability. In this sense, the pH and the aqueous activity of the product, as well as the physical characteristics of the fruit to be dehydrated, are decisive for obtaining stable nuts; for example, the generation of microorganisms that can break down preserved foods is related to minimum values of water activity of 0.93 or 0.94, so that most of the technologies aimed at obtaining dried fruits try to obtain products with values of water activity lower than 0.9.
La actividad acuosa es uno de los factores más críticos para determinar Ia calidad y seguridad de los productos alimenticios que se consumen diariamente, ya que afecta Ia vida útil, seguridad, textura, sabor y olor de los alimentos. Mientras que Ia manipulación de Ia temperatura y el pH pueden influenciar negativamente en el crecimiento de microorganismos sobre los productos alimenticios, Ia actividad acuosa es el factor más importante que controla dicho crecimiento, ya que determina el límite más bajo de agua disponible para el crecimiento microbiano. Además de influenciar el crecimiento microbiano, Ia actividad acuosa tiene un papel significativo en Ia actividad enzimática y vitamínica de los alimentos, así como un impacto importante en su color, sabor y aroma.Water activity is one of the most critical factors in determining the quality and safety of food products consumed daily, since it affects the shelf life, safety, texture, taste and smell of food. While the manipulation of temperature and pH can negatively influence the growth of microorganisms on food products, aqueous activity is the most important factor that controls said growth, since it determines the lowest limit of water available for microbial growth. . In addition to influencing microbial growth, the aqueous activity has a significant role in the enzymatic and vitamin activity of food, as well as an important impact on its color, flavor and aroma.
A pesar de que Ia deshidratación de alimentos es uno de los métodos más efectivos para obtener productos con valores de actividad acuosa por debajo de 0.7, el tratamiento térmico del alimento provoca frecuentemente desnaturalización de sus proteínas y descomposición de sus pigmentos naturales, por Io que el apreciado y típico sabor y color de Ia fruta tratada resultan dañados. Así mismo, Ia cantidad de agua y de aceites en diversosAlthough food dehydration is one of the most effective methods to obtain products with water activity values below 0.7, heat treatment of the food frequently causes denaturation of its proteins and decomposition of its natural pigments, so that Appreciated and typical taste and color of the treated fruit are damaged. Likewise, the amount of water and oils in various
27 28 alimentos procesados , así como Ia hidrólisis de sucrosa afectan el valor de actividad acuosa del alimento. Por Io tanto, obtener alimentos con valores bajos de actividad acuosa y que a Ia vez conserven sus propiedades alimenticias es una tarea muy difícil.27 28 processed foods, as well as the hydrolysis of sucrose affect the water activity value of the food. Therefore, obtain food with low values of water activity and that at the same time retain their nutritional properties is a very difficult task.
Por otro lado, Ia deshidratación de alimentos con contenidos considerables de carbohidratos provoca efectos indeseables en Ia configuración y organización de dichas moléculas, ya que el tratamiento con calor del alimento genera frecuentemente Ia formación de cristales amorfos que se unen entre sí formando bloques, causando Ia formación de pastas que no pueden manipularse y en consecuencia no pueden ser transportadas o envasadas.On the other hand, the dehydration of foods with considerable carbohydrate contents causes undesirable effects in the configuration and organization of said molecules, since the heat treatment of the food frequently generates the formation of amorphous crystals that join together forming blocks, causing the formation of pastes that cannot be handled and consequently cannot be transported or packaged.
Este efecto impide que el alimento deshidratado pueda molerse para obtener polvos fluidos, que son más convenientes para el consumo, envasado, conservación, transporte y comercialización del producto deshidratado. En este sentido y como podrá observarse en el ejemplo 2, en el caso del procesamiento de pulpa de mamey utilizando parte del proceso de deshidratación reportado por Jiménez para pulpa de aguacate, se obtienen productos deshidratados de pulpa de mamey que no pueden molerse para obtener polvos estables de pulpa de mamey.This effect prevents dehydrated food from being milled to obtain fluid powders, which are more convenient for the consumption, packaging, preservation, transport and commercialization of the dehydrated product. In this sense and as can be seen in example 2, in the case of mamey pulp processing using part of the dehydration process reported by Jiménez for avocado pulp, dehydrated products of mamey pulp are obtained that cannot be milled to obtain powders stable of mamey pulp.
La mezcla de componentes nutricionales de Ia pulpa de Ia fruta también causa efectos deletéreos en Ia obtención de polvos fluidos. Por ejemplo, en diversos estudios realizados sobre Ia producción de polvos de frutas tropicales como el mango, se ha demostrado que Ia cantidad y tipo de constituyentes de Ia pulpa tienen efectos importantes en Ia obtención eficiente de polvos a partir de las pulpas, por ejemplo en Ia dinámica de fluidos; en este caso Ia concentración y mezcla de azúcares, pectina y lípidos afectan de manera significativa IaThe mixture of nutritional components of the pulp of the fruit also causes deleterious effects in obtaining fluid powders. For example, in various studies on the production of tropical fruit powders such as mango, it has been shown that the quantity and type of constituents of the pulp have important effects in the efficient obtaining of powders from the pulps, for example in Ia fluid dynamics; in this case the concentration and mixture of sugars, pectin and lipids significantly affect the
29 obtención efectiva de polvos fluidos a partir de pulpas de frutas tropicales .29 Effectively obtain fluid powders from tropical fruit pulps.
Múltiples productos deshidratados de frutas tropicales son propensos a reacciones de oscurecimiento enzimáticό y no enzimático que pueden dar lugar a Ia formación de sabores y olores muy desagradables en dichos productos. La mayoría de las reacciones enzimáticas que causan oscurecimiento, dadasMultiple dehydrated tropical fruit products are prone to enzymatic and non-enzymatic darkening reactions that can lead to the formation of very unpleasant tastes and odors in such products. The most enzymatic reactions that cause darkening, given
30,31 principalmente por polifenol oxidasa (PPO) , disminuyen en actividades acuosas por debajo de 0.8, sin embargo algunas de estas reacciones ocurren incluso en valores muy bajos de actividad acuosa. El oscurecimiento no enzimático dado por reacciones conocidas como tipo Maillard donde se producen polímeros marrones llamados melanoidinas, se presenta en valores de actividad acuosa de 0.6 a 0.7, intervalo donde el oscurecimiento dado por dichas reacciones es más probable. A pesar de que diversos métodos se han30,31 mainly by polyphenol oxidase (PPO), decrease in aqueous activities below 0.8, however some of these reactions occur even in very low values of aqueous activity. The non-enzymatic darkening given by reactions known as the Maillard type where brown polymers called melanoidins are produced, occurs in values of aqueous activity of 0.6 to 0.7, interval where the darkening given by said reactions is most likely. Although various methods have been
32 utilizado para el control de Ia actividad de PPO en frutas y vegetales , siendo32 used to control the activity of PPO in fruits and vegetables, being
33 el tratamiento con calor uno de los más populares para ¡nactivar Ia PPO , este tratamiento no llega a eliminar del todo Ia actividad de PPO y no previene Ia generación posterior de reacciones de Maillard. Por ejemplo, a pesar de que Jiménez reporta que el tratamiento térmico de mamey con microondas reduce Ia actividad de PPO, dicho tratamiento no llega a eliminar del todo Ia actividad33 the heat treatment one of the most popular to activate the PPO, this treatment does not completely eliminate the PPO activity and does not prevent the subsequent generation of Maillard reactions. For example, although Jiménez reports that the thermal treatment of mamey with microwaves reduces the activity of PPO, said treatment does not completely eliminate the activity
34 enzimática .34 enzymatic.
Como podrá observarse, múltiples factores están involucrados en Ia obtención eficiente de polvos de frutas que sean estables a temperatura ambiente y que conserven al mismo tiempo sus propiedades nutritivas y organolépticas naturales, tal como se pueden percibir del fruto fresco a partir del cual se obtienen. Esto implica el diseño de procesos específicos de deshidratación con condiciones particulares que permitan la obtención de polvos estables de frutas de corta vida de anaquel. En este sentido, el proceso de Ia invención logra obtener polvos de pulpa de mamey estables en anaquel por tiempos prolongados y que exhiben las propiedades organolépticas típicas del fruto fresco (ver ejemplo 1), con Io cual se resuelven los problemas típicos de conservación asociados al fruto fresco de mamey.As it can be observed, multiple factors are involved in the efficient obtaining of fruit powders that are stable at room temperature and that at the same time retain their natural nutritional and organoleptic properties, as can be perceived from the fresh fruit from which they are obtained. This implies the design of specific dehydration processes with particular conditions that allow obtaining stable powders of short shelf life fruits. In this sense, the process of the invention manages to obtain stable mamey pulp powders on shelf for long periods and that exhibit the typical organoleptic properties of the fresh fruit (see example 1), whereby the typical conservation problems associated with the Fresh mamey fruit.
De manera general, el proceso de obtención del polvo de Ia invención comprende las siguientes etapas: a) Selección y lavado del mamey entero.In general, the process of obtaining the powder of the invention comprises the following steps: a) Selection and washing of the whole mamey.
Durante ésta etapa frutos frescos enteros de mamey son clasificados mediante un transportador de clasificado convencional, eligiéndose solo aquellos que se encuentren en buenas condiciones, es decir, aquellos frutos que no estén golpeados o con Ia cascara fracturada y con una consistencia firme, tanto en Ia cascara como en el fruto.During this stage, fresh whole mamey fruits are classified by means of a conventional classified conveyor, choosing only those that are in good condition, that is, those fruits that are not beaten or with the fractured shell and with a firm consistency, both in the peel as in the fruit.
Posteriormente los frutos seleccionados son lavados y sanitizados con agua clorada en 20 ppm para eliminar residuos indeseables adheridos a Ia cascara y evitar contaminación de Ia pulpa cuando Ia cascara sea retirada posteriormente. Seguidamente los frutos enteros se escurren y sopletean para eliminar por completo el agua excedente; el agua resultante de éste proceso es recibida por una charola escurridora y enviada al drenaje.Subsequently, the selected fruits are washed and sanitized with chlorinated water at 20 ppm to eliminate undesirable residues adhered to the shell and avoid contamination of the pulp when the shell is subsequently removed. Then the whole fruits are drained and blown to completely eliminate the excess water; The water resulting from this process is received by a draining tray and sent to the drain.
b) Cortado y eliminación de Ia semilla del mamey.b) Cutting and elimination of the mamey seed.
Los frutos enteros tratados en Ia etapa anterior, son cortados en 2 a 12 partes, preferentemente en 2 a 6 partes para posteriormente ser eliminadaThe whole fruits treated in the previous stage, are cut in 2 to 12 parts, preferably in 2 to 6 parts to later be eliminated
Ia semilla en una banda transportadora utilizada para tal fin.The seed in a conveyor belt used for this purpose.
c) Primera etapa de deshidratación.c) First stage of dehydration.
Eliminada Ia semilla y expuesta Ia pulpa del mamey, el fruto cortado por Ia mitad es deshidratado mediante cualquier método convencional que permita Ia deshidratación de Ia pulpa, sin embargo se prefiere un método de deshidratación seleccionado del grupo que comprende de termosecado, microondas ó aire caliente. La elección del método depende en gran medida del diseño de Ia planta de procesado para Ia obtención del polvo de Ia invención, pero para efectos de Ia invención cualquiera de los mencionados da resultados favorables. Para el caso del uso de termosecado, Ia deshidratación se realiza en un intervalo de temperatura de 60 a 1200C en un tiempo de 0.5 a 4 horas. Para Ia deshidratación por microondas se realiza en un intervalo de temperatura de 60 a 1100C en un tiempo de 3 a 50 minutos, mientras que para Ia deshidratación por aire caliente, esta se realiza a una temperatura de 60 a 120°C durante 0.5 a 4 horas. La primera etapa de deshidratación se realiza durante los tiempos indicados para cada metodología, preferentemente hasta que pueda separarse con facilidad Ia pulpa de Ia cascara del fruto.Removed the seed and exposed the pulp of the mamey, the fruit cut in half is dehydrated by any conventional method that allows the dehydration of the pulp, however a method of dehydration selected from the group comprising thermosecado, microwave or hot air is preferred . The choice of the method depends largely on the design of the processing plant for obtaining the powder of the invention, but for the purposes of the invention any of the aforementioned It gives favorable results. In the case of the use of thermosecado, the dehydration is carried out in a temperature range of 60 to 120 0 C in a time of 0.5 to 4 hours. For microwave dehydration it is carried out in a temperature range of 60 to 110 0 C in a time of 3 to 50 minutes, while for hot air dehydration, this is carried out at a temperature of 60 to 120 ° C for 0.5 4 hours The first stage of dehydration is carried out during the times indicated for each methodology, preferably until the pulp of the fruit peel can be easily separated.
eparación de Ia cascara y segunda etapa de deshidratación.eparation of the shell and second stage of dehydration.
Terminada Ia primera etapa de deshidratación del fruto, este es enfriado por aire y Ia pulpa obtenida parcialmente deshidratada es separada completamente por medio de una cucharilla de acero inoxidable previamente sanitizada. Posteriormente la cascara es desechada y Ia pulpa parcialmente deshidratada es sometida a una segunda etapa de deshidratación bajo las mismas condiciones que se mencionan en Ia primera etapa de deshidratación.After the first stage of dehydration of the fruit, this is cooled by air and the pulp obtained partially dehydrated is completely separated by means of a spoon of stainless steel previously sanitized. Subsequently the shell is discarded and the partially dehydrated pulp is subjected to a second stage of dehydration under the same conditions mentioned in the first stage of dehydration.
Terminada esta etapa de deshidratación, se toma una muestra de Ia pulpa deshidratada para determinar su valor de actividad acuosa, el cual deberá estar comprendido en el intervalo de 0.2 a 0.7. Si el valor de actividad acuosa del producto deshidratado no se encuentra dentro del intervalo especificado anteriormente, el producto se torna altamente viscoso, chicloso y difícil de manejar en el momento de la molienda, por Io que no puede molerse. En este caso es necesario repetir el proceso de deshidratación de Ia pulpa hasta obtener una pulpa con valores de actividad acuosa dentro del intervalo mencionado. e) Molienda de Ia pulpa deshidratada.Once this dehydration stage is finished, a sample of the dehydrated pulp is taken to determine its value of aqueous activity, which should be in the range of 0.2 to 0.7. If the water activity value of the dehydrated product is not within the range specified above, the product becomes highly viscous, tacky and difficult to handle at the time of grinding, so it cannot be ground. In this case, it is necessary to repeat the pulp dehydration process until obtaining a pulp with water activity values within the mentioned range. e) Dehydrated pulp milling.
La pulpa deshidratada y equilibrada a temperatura ambiente es mezclada hasta homogeneización con un compuesto seleccionado del grupo que comprende ácido cítrico, ácido ascórbico o mezclas de los mismos, en una proporción del 0.01 al 2% en peso con respecto del peso total de Ia pulpa deshidratada, sometiendo Ia mezcla a molienda mediante un molino convencional bajo condiciones tales que permitan Ia obtención de un tamaño de partícula de 125 a 250 μm; seguidamente Ia molienda obtenida es cernida mediante un clasificador granulométrico con un tamaño de malla que permita el paso del tamaño de partícula mencionado, como por ejemplo de malla 60 a 115. En esta etapa del proceso, las partículas que hayan quedado retenidas por el clasificador se envían de nueva cuenta al proceso de molienda con Ia finalidad de obtener el tamaño de partícula adecuado.The dehydrated and equilibrated pulp at room temperature is mixed until homogenization with a compound selected from the group comprising citric acid, ascorbic acid or mixtures thereof, in a proportion of 0.01 to 2% by weight with respect to the total weight of the dehydrated pulp , subjecting the mixture to grinding by means of a conventional mill under conditions that allow obtaining a particle size of 125 to 250 μm; then the grinding obtained is sifted by a granulometric classifier with a mesh size that allows the passage of the mentioned particle size, such as 60 to 115 mesh. At this stage of the process, the particles that have been retained by the classifier are they send the grinding process again with the purpose of obtaining the appropriate particle size.
Posterior a cada una de las etapas de deshidratación del proceso de Ia invención, se pueden tomar muestras del producto obtenido para realizar análisis bromatológicos y verificar Ia calidad del producto conforme se obtiene, Io que permite garantizar Ia calidad alimenticia del producto obtenido.After each of the stages of dehydration of the process of the invention, samples of the product obtained can be taken to perform bromatological analyzes and verify the quality of the product as it is obtained, which allows to guarantee the food quality of the product obtained.
Finalizado el proceso de obtención, el polvo de mamey de Ia invención es transportado y vaciado hacia tolvas de paso de un sistema de envasado, para posteriormente ser colocado en envases mediante una envasadora convencional.Once the process of obtaining is finished, the mamey powder of the invention is transported and emptied into the hoppers of a packaging system, to be subsequently placed in containers by means of a conventional packaging machine.
Prácticamente puede utilizarse cualquier tipo de envase limpio y seco para Ia conservación del polvo de mamey de Ia invención, sin embargo se prefieren aquellos que sean de fácil acceso, que no presenten dificultades en su manejo y transportación, y que tengan un valor comercial reconocido. Ejemplos de ellos son los frascos en Peet, frascos de cristal o vidrio, cajas de cartón con forro interior o bien bolsas aluminizadas. El proceso de la presente invención, permite después de Ia primera etapa de deshidratación, una separación sencilla, completa y eficiente de Ia pulpa deshidratada de Ia cascara, sin necesidad de utilizar dispositivos diseñados específicamente para ello.Virtually any type of clean and dry container can be used for the conservation of the mamey powder of the invention, however those that are easily accessible, that do not present difficulties in handling and transportation, and that have a recognized commercial value are preferred. Examples of these are Peet bottles, glass or glass bottles, cardboard boxes with inner lining or aluminized bags. The process of the present invention allows, after the first stage of dehydration, a simple, complete and efficient separation of the dehydrated pulp from the shell, without the need to use devices specifically designed for it.
Con respecto a los rendimientos de obtención del polvo de Ia invención, se logra obtener al menos de 200 a 250 g de polvo por cada 1 ,000 g de pulpa fresca del fruto, Io que representa proporciones altas de rendimiento, dado el gran porcentaje de humedad (al menos 70% p/p) que contiene Ia pulpa fresca de mamey (ver tabla 1).With respect to the yields of obtaining the powder of the invention, it is possible to obtain at least 200 to 250 g of powder for each 1,000 g of fresh pulp of the fruit, which represents high proportions of yield, given the large percentage of humidity (at least 70% w / w) that contains the fresh mamey pulp (see table 1).
A pesar de que el proceso de Ia invención elimina una gran cantidad de humedad de Ia pulpa fresca de mamey, para efectos de Ia invención el contenido de agua no debe quitarse totalmente de Ia materia prima, ya que ésta puede carbonizarse rápidamente.Although the process of the invention removes a large amount of moisture from the fresh mamey pulp, for the purposes of the invention the water content should not be completely removed from the raw material, since it can be quickly carbonized.
La molienda de Ia pulpa deshidratada de mamey se puede realizar en cualquier aparato conveniente de molido, desintegrador, ó molino fraccionador hasta un tamaño de partícula conveniente para consumo.The milling of the dehydrated pulp of mamey can be carried out in any convenient grinding device, disintegrator, or fractionator mill to a particle size convenient for consumption.
Con el proceso de Ia invención se obtienen polvos estables de pulpa mamey que se rehidratan fácilmente, con una alta concentración de los nutrientes típicos del fruto fresco, con un aspecto visual agradable y sin color o sabor alterados. Así mismo el polvo de mamey no presenta caramelización, o reacciones de oscurecimiento enzimático o de tipo Maillard.With the process of the invention, stable powders of mamey pulp are obtained that are easily rehydrated, with a high concentration of the nutrients typical of the fresh fruit, with a pleasant visual appearance and without altered color or flavor. Likewise, mamey powder does not show caramelization, or enzymatic or Maillard dimming reactions.
El proceso de Ia invención permite eliminar el problema que se presenta durante Ia deshidratación de Ia pulpa de mamey, ya que para este fruto, es frecuente Ia aparición del efecto de cristalización amorfa de los carbohidratos de Ia pulpa (ver ejemplo 2), Io que impide que Ia pulpa deshidratada pueda molerse posteriormente para Ia obtención de polvo. Así mismo, al aparecer el efecto de cristalización amorfa, Ia pulpa obtenida no puede separarse fácilmente de Ia cascara, puesto que al tornarse viscosa y chiclosa, se adhiere fuertemente a las paredes internas de ésta. El someter Ia pulpa de mamey en este estado a otro proceso de deshidratación para tratar de eliminar Ia viscosidad, no resulta efectivo, puesto que al enfriarse Ia pulpa, este se vuelve a tornar viscosa mientras que comienzan a aparecer zonas de pulpa carbonizada, Io que proporciona un sabor desagradable al producto.The process of the invention allows eliminating the problem that occurs during the dehydration of the mamey pulp, since for this fruit, the appearance of the amorphous crystallization effect of the pulp carbohydrates is frequent (see example 2), which prevents the dehydrated pulp can be ground later to obtain dust. Likewise, when the Amorphous crystallization effect, the pulp obtained cannot be easily separated from the shell, since when it becomes viscous and taffy, it adheres strongly to its internal walls. Subjecting the mamey pulp in this state to another dehydration process to try to eliminate the viscosity is not effective, since when the pulp cools, it becomes viscous again while areas of carbonized pulp begin to appear, which It provides an unpleasant taste to the product.
A pesar de que en el estado del arte existen diversas metodologías dirigidas a Ia obtención de polvos de frutas, como podrá observarse las condiciones del proceso de Ia invención para obtener el polvo de pulpa de mamey, resultan ser muy particulares para lograr obtener polvos de mamey con una actividad acuosa de 0.4 a 0.6, valores de PPO nulos o cercanos a cero, alta concentración de sus componentes nutritivos originales, tamaños de partícula convenientes, alta disolución en líquidos y una larga vida de anaquel.Although in the state of the art there are various methodologies aimed at obtaining fruit powders, as you can see the conditions of the process of the invention to obtain mamey pulp powder, they are very particular to achieve obtain mamey powders with an aqueous activity of 0.4 to 0.6, zero or near zero PPO values, high concentration of its original nutritional components, convenient particle sizes, high dissolution in liquids and a long shelf life.
3535
Por ejemplo, Lewis describe Ia obtención de productos de fruta o vegetales libres de aditivos con una actividad acuosa de 0.5 a 0.95 y que exhiben una alta estabilidad microbiológica. Los frutos se deshidratan parcialmente a un contenido de humedad del 26 al 60% y posteriormente son envasados bajo un ambiente libre de oxígeno, Io que les permite conservar sus características nutricionales, de color y aspecto por tiempos prolongados (6 a 24 meses). En este caso, frutos como papas, zanahorias, cerezas, manzanas, peras y uvas, son pelados y cortados en diferentes formas para ser posteriormente deshidratados. A diferencia de Ia presente invención, el producto deshidratado descrito por Lewis no se encuentra en forma de polvo e involucra procesos de empacado en los que se tiene que eliminar Ia presencia de oxígeno (por ejemplo, adicionando nitrógeno o absorbentes de oxígeno en empaques laminados) así como su conservación a bajas temperaturas, ya que de Io contrario el producto no podría conservarse. 36For example, Lewis describes the obtaining of fruit or vegetable products free of additives with an aqueous activity of 0.5 to 0.95 and exhibiting high microbiological stability. The fruits are partially dehydrated to a moisture content of 26 to 60% and subsequently are packaged under an oxygen-free environment, which allows them to retain their nutritional characteristics, color and appearance for prolonged periods (6 to 24 months). In this case, fruits such as potatoes, carrots, cherries, apples, pears and grapes are peeled and cut into different forms to be subsequently dehydrated. Unlike the present invention, the dehydrated product described by Lewis is not in powder form and involves packaging processes in which the presence of oxygen has to be eliminated (for example, adding nitrogen or oxygen absorbers in laminated packages) as well as its conservation at low temperatures, since otherwise the product could not be preserved. 36
Varga describe la obtención de polvos de frutas con cascara suave tales como manzana, pera, uva, limón, ciruela y plátano mediante su deshidratación por medio de microondas a una temperatura de 65°C durante 10 a 15 minutos para posteriormente moler el producto deshidratado en molinos convencionales. El producto obtenido posee una cantidad del 5 al 17% p/p de agua, es soluble en agua, puede incluir Ia cascara del fruto con Ia finalidad de proporcionar fibra dietética al polvo y puede almacenarse durante años a una temperatura de 10 a 15°C sin perder sus propiedades alimenticias. Sin embargo, el proceso descrito por Varga no puede utilizarse en frutos que posean cascaras duras (por ejemplo mamey o aguacate), ya que las condiciones de deshidratación y molienda no son suficientes para obtener polvos de éste tipo de frutos; así mismo, no es posible obtener polvos estables a temperatura ambiente y que no necesiten de refrigeración para su conservación.Varga describes the obtaining of soft-shell fruit powders such as apple, pear, grape, lemon, plum and banana by dehydration by means of microwaves at a temperature of 65 ° C for 10 to 15 minutes to subsequently grind the dehydrated product in conventional mills The product obtained has an amount of 5 to 17% w / w of water, is soluble in water, can include the peel of the fruit with the purpose of providing dietary fiber to the powder and can be stored for years at a temperature of 10 to 15 ° C without losing its nutritional properties. However, the process described by Varga cannot be used in fruits that have hard peels (for example mamey or avocado), since the conditions of dehydration and grinding are not sufficient to obtain powders of this type of fruit; Likewise, it is not possible to obtain powders stable at room temperature and that do not need refrigeration for their conservation.
3737
Suzuki describe Ia generación de productos alimenticios de larga vida de anaquel a temperatura ambiente mediante el secado del producto alimenticio y posterior adición de aceite comestible al producto seco, ajustando Ia actividad acuosa de Ia mezcla de 0.55 a 0.75 para impedir Ia generación de microorganismos y Ia formación de cristales que provocan problemas en el empaque y en Ia textura del producto. En dichas mezclas se agrega Ia cantidad de agua necesaria para ajustar Ia actividad acuosa deseada en el producto. Sin embargo, los productos descritos no poseen tamaños de partícula menores a 300 μm e integran agua al producto alimenticio para su preservación; así mismo es necesaria Ia adición de aceite comestible para proporcionar estabilidad al producto.Suzuki describes the generation of long shelf life food products at room temperature by drying the food product and subsequent addition of edible oil to the dry product, adjusting the aqueous activity of the mixture from 0.55 to 0.75 to prevent the generation of microorganisms and Ia formation of crystals that cause problems in the packaging and in the texture of the product. In said mixtures the amount of water necessary to adjust the desired aqueous activity in the product is added. However, the products described do not have particle sizes smaller than 300 μm and integrate water into the food product for preservation; Likewise, the addition of edible oil is necessary to provide stability to the product.
3838
DuII describe Ia obtención de legumbres (frijoles, por ejemplo) con una actividad acuosa reducida de 0.5 mediante Ia adición de soluciones humectantes a base de glicerol, propilenglicol, sucrosa, fructosa, galactosa o mezclas de los mismos, al producto alimenticio previamente hidratado con agua; el producto alimenticio obtenido es estable en anaquel y conserva sus propiedades alimenticias. Como podrá observarse, las características del producto descrito por DuII están supeditadas a Ia adición de sustancias no propias del vegetal.DuII describes the obtaining of legumes (beans, for example) with a reduced aqueous activity of 0.5 by adding moisturizing solutions based on glycerol, propylene glycol, sucrose, fructose, galactose or mixtures thereof, to the food product previously hydrated with Water; The food product obtained is stable on shelf and retains its nutritional properties. As can be seen, the characteristics of the product described by DuII are subject to the addition of non-plant substances.
3939
Cross describe Ia elaboración de productos alimenticios estables a temperatura ambiente con una actividad acuosa de 0.2 a 0.3 y un tamaño de partícula promedio de 15 a 31 μm, los cuales pueden obtenerse sometiendo mezclas alimenticias deseadas a reducciones consecutivas de su tamaño de partícula mediante el uso de un sistema de refinamiento de chocolate a base de rodillos y Ia adición de grasa líquida, así como Ia adición opcional de emulsificantes como lecitinas. Cada uno de los componentes alimenticios es reducido en su tamaño de partícula antes de ser sometidos a tratamiento por el sistema de refinamiento de chocolate. A pesar de que pueden incluirse frutos para Ia obtención de las mezclas alimenticias, estos se agregan previamente como polvo en conjunto con aceites comestibles líquidos y lecitina de soya.Cross describes the production of stable food products at room temperature with an aqueous activity of 0.2 to 0.3 and an average particle size of 15 to 31 μm, which can be obtained by subjecting desired food mixtures to consecutive reductions in their particle size by use of a system of refining chocolate based on rollers and the addition of liquid fat, as well as the optional addition of emulsifiers such as lecithins. Each of the food components is reduced in particle size before being subjected to treatment by the chocolate refining system. Although fruits can be included for obtaining the food mixtures, these are previously added as a powder together with liquid edible oils and soy lecithin.
4040
Liu describe Ia obtención de polvo de cascara de manzana útil para inhibir Ia proliferación de células cancerosas. La cascara de manzana es sometida a un tratamiento de preservación bioquímica previa con baños de ácido cítrico, blanqueo con agua hirviendo, deshidratado y molienda hasta obtener un polvo de malla 40 a 60. El polvo obtenido exhibe una actividad acuosa de 0.12 a 0.36 y una gran cantidad de flavonoides y antocianinas. Sin embargo, pulpas de frutas tropicales tales como el mamey, no pueden ser tratadas con éste método ya que el tratamiento de preservación y blanqueo resultan negativos para Ia preservación de las propiedades organolépticas de Ia pulpa del fruto.Liu describes the obtaining of apple peel powder useful for inhibiting the proliferation of cancer cells. The apple peel is subjected to a previous biochemical preservation treatment with citric acid baths, bleaching with boiling water, dehydrated and grinding until a 40 to 60 mesh powder is obtained. The obtained powder exhibits an aqueous activity of 0.12 to 0.36 and a large amount of flavonoids and anthocyanins. However, tropical fruit pulps such as mamey cannot be treated with this method since the preservation and bleaching treatment are negative for the preservation of the organoleptic properties of the fruit pulp.
4141
Flores describe Ia obtención de mermeladas y jaleas estables en polvo.Flores describes the obtaining of jams and stable powdered jellies.
Fresas por ejemplo, son deshidratadas hasta quedar con una humedad menor al 1% p/p y posteriormente trituradas hasta un tamaño de partícula de 1 mm para no desintegrar las semillas. Posteriormente Ia fruta desintegrada es mezclada con altas cantidades de azúcar (89% p/p), pectina en polvo y ácido cítrico para posteriormente envasar Ia mezcla bajo vacío. El producto es mezclado posteriormente con azúcar y agua bajo ebullición para obtener Ia mermelada o jalea. A diferencia de las mezclas descritas por Duran, el polvo de mamey de Ia presente invención, no incluye altas cantidades de azúcar o Ia adición de pectina para que pueda ser estable en anaquel.Strawberries for example, are dehydrated until they have a humidity of less than 1% w / w and then crushed to a particle size of 1 mm so as not to disintegrate the seeds. Subsequently the disintegrated fruit is mixed with high amounts of sugar (89% w / w), pectin powder and citric acid to subsequently pack the mixture under vacuum. The product is subsequently mixed with sugar and boiling water to obtain jam or jelly. Unlike the mixtures described by Duran, the mamey powder of the present invention does not include high amounts of sugar or the addition of pectin so that it can be stable on the shelf.
4242
Radatti describe Ia obtención de productos alimenticios en forma de harina a partir de pulpa de desecho de frutas, los cuales pueden utilizarse como complementos alimenticios. Pulpa de frutas utilizadas para obtener jugos naturales, es lavada y desecada con hidróxido de calcio para posteriormente ser deshidratada, molida y adicionada con hidrocoloides. Sin embargo, los productos obtenidos contienen sustancias que afectan Ia integridad de los componentes celulósicos que pueda contener Ia pulpa y no se especifica Ia actividad acuosa que contienen, Io que no garantiza su estabilidad a temperatura ambiente.Radatti describes the obtaining of food products in the form of flour from fruit waste pulp, which can be used as food supplements. Fruit pulp used to obtain natural juices, is washed and dried with calcium hydroxide to be subsequently dehydrated, ground and added with hydrocolloids. However, the products obtained contain substances that affect the integrity of the cellulosic components that the pulp may contain and the aqueous activity they contain is not specified, which does not guarantee their stability at room temperature.
4343
Jiménez describe Ia obtención de harina estable de pulpa de aguacate mediante Ia deshidratación de Ia pulpa de aguacate y posterior adición de diversos elementos vegetales deshidratados para evitar el oscurecimiento enzimático de Ia pulpa. Aguacates con cascara, partidos a Ia mitad y desprovistos de semilla, son deshidratados a altas temperaturas para obtener pulpa deshidratada que posteriormente es molida a un tamaño de partícula de 20 a 35 μm y mezclada con ajo, cebolla, ácido cítrico y otros elementos para obtener Ia harina estable de aguacate. A pesar de que se describe Ia deshidratación de Ia pulpa del fruto sin eliminar su cascara, el método descrito por Jiménez no permite Ia obtención de polvo estable de mamey de Ia invención, ya que al tratar pulpa de mamey con dicho proceso, Ia deshidratación causa un gran incremento en Ia viscosidad de Ia pulpa, tornándola chiclosa y muy plástica, Io que impide que Ia pulpa deshidratada pueda ser molida al tamaño deseado para obtener el polvo de Ia invención. Por otro lado, al incrementar Ia temperatura de deshidratación conforme a Io descrito por Jiménez para eliminar una mayor cantidad de agua de Ia pulpa de mamey y evitar así incrementos en su viscosidad, se obtienen pulpas con porcentajes considerables de carbonización, Io que afecta negativamente las propiedades organolépticas del producto.Jiménez describes the obtaining of stable avocado pulp flour by means of the dehydration of the avocado pulp and subsequent addition of various dehydrated vegetable elements to avoid the enzymatic darkening of the pulp. Avocados with peel, halved and devoid of seed, are dehydrated at high temperatures to obtain dehydrated pulp that is then ground to a particle size of 20 to 35 μm and mixed with garlic, onion, citric acid and other elements to obtain The stable avocado flour. Although the dehydration of the pulp of the fruit is described without removing its peel, the method described by Jiménez does not allow obtaining stable mamey powder of the invention, since when treating mamey pulp with said process, the dehydration causes a large increase in the viscosity of the pulp, making it tacky and very plastic, which prevents the dehydrated pulp from being milled to the desired size to obtain the powder of the invention. By On the other hand, by increasing the dehydration temperature according to what Jimenez described to eliminate a greater amount of water from the mamey pulp and thus avoiding increases in its viscosity, pulps with considerable percentages of carbonization are obtained, which negatively affects the properties product organoleptic.
Así mismo métodos de deshidratación aplicados a pulpas de frutas o vegetales han sido utilizados, como por ejemplo el uso de alto vacío paraAlso dehydration methods applied to fruit or vegetable pulps have been used, such as the use of high vacuum for
44 deshidratar capas muy finas de pulpa de plátano , congelación previa y44 dehydrate very thin layers of banana pulp, pre-freeze and
45 posterior adición de aire caliente para deshidratar material orgánico celular ,45 subsequent addition of hot air to dehydrate cellular organic material,
46 spray-drying y adición de esteres de ácidos grasos para secar frutas , adición de alcohol o cetonas previa al secado y posterior molienda para obtener polvos46 spray-drying and addition of fatty acid esters to dry fruits, addition of alcohol or ketones prior to drying and subsequent grinding to obtain powders
47 de frutas o bien secado por aire o congelación y posterior molienda de cubos47 fruit or air-dried or freezing and subsequent grinding of cubes
48 de frutas o vegetales para obtener polvos .48 fruits or vegetables to obtain powders.
A pesar de que las metodologías anteriores pueden aplicarse a frutas tropicales, hasta antes de Ia presente invención no existía alguna metodología que permitiera obtener polvos de frutos delicados y con tan corta vida de anaquel o postcosecha como Io es el fruto fresco del mamey. Como podrá observarse, la mayoría de las metodologías reportadas incluyen aditivos al fruto en alguna etapa del procesamiento, o procesos de blanqueamiento u oxidación, Io que altera significativamente las cualidades alimenticias y organolépticas originales del fruto. Así mismo Ia aplicación de las tecnologías mencionadas, no permiten obtener los polvos estables de pulpa de mamey de Ia invención.Although the previous methodologies can be applied to tropical fruits, until before the present invention there was no methodology that allowed obtaining powders of delicate fruits and with such a short shelf life or post-harvest as Io is the fresh fruit of the mamey. As can be seen, most of the reported methodologies include fruit additives at some stage of the processing, or bleaching or oxidation processes, which significantly alters the original nutritional and organoleptic qualities of the fruit. Likewise, the application of the aforementioned technologies does not allow obtaining stable mamey pulp powders of the invention.
El polvo de mamey de Ia invención puede combinarse sin problemas con infinidad de productos alimenticios para proporcionar sabor a mamey. De hecho al rehidratarse el polvo de mamey, ya sea mediante Ia adición directa al polvo de líquidos nutritivos o su adición a alimentos con contenidos importantes de humedad, se genera una pasta con un aspecto, sabor y olor muy parecidos a los que exhibe Ia pulpa fresca del fruto que puede integrarse perfectamente a Ia mezcla alimenticia formando mezclas homogéneas.The mamey powder of the invention can be combined without problems with countless food products to provide mamey flavor. In fact, when the mamey powder is rehydrated, either by means of the direct addition to the nutrient liquid powder or its addition to foods with important contents of moisture, a paste with an appearance, taste and smell very similar to those exhibited by the fresh pulp of the fruit that can be perfectly integrated into the food mixture forming homogeneous mixtures is generated.
Dada Ia gran versatilidad de aplicaciones del polvo de mamey de Ia invención como producto alimenticio, el polvo de Ia invención también puede ser utilizado como un reactivo estándar y específico para inspeccionar Ia calidad de productos deshidratados de mamey, así como para determinar su identidad y concentración de carbohidratos. Al contener el polvo de mamey de Ia invención los componentes naturales típicos contenidos en Ia pulpa del fruto fresco y sin Ia presencia de aditivos que afecten sus propiedades organolépticas típicas, se convierte en un reactivo muy útil para inspeccionar las propiedades típicas del fruto del mamey, así como de deshidratados obtenidos a partir de su pulpa.Given the great versatility of applications of the mamey powder of the invention as a food product, the powder of the invention can also be used as a standard and specific reagent to inspect the quality of dehydrated mamey products, as well as to determine their identity and concentration of carbohydrates By containing the mamey powder of the invention the typical natural components contained in the pulp of the fresh fruit and without the presence of additives that affect its typical organoleptic properties, it becomes a very useful reagent to inspect the typical properties of the mamey fruit, as well as dehydrated obtained from its pulp.
En este sentido, el polvo de mamey de Ia invención describe un patrón colorimétrico característico de cada especie utilizada, tanto para Calocarpum mammosum Pierre como para Mammea americana L, (ver figura 3) que permite determinaciones analíticas de laboratorio y Ia inspección de posibles deshidratados de mamey en los cuales se pretenda verificar el contenido de pulpa de mamey y Ia existencia de posibles adulteraciones del producto, como por ejemplo mediante Ia adición de aditivos, o diversos agentes que pretendan incrementan el peso de Ia mezcla y reducir Ia cantidad de pulpa de mamey. Determinado el comportamiento del patrón colorimétrico del deshidratado a inspeccionar, se realizan análisis bromatológicos para verificar sus componentes y sus propiedades organolépticas.In this sense, the mamey powder of the invention describes a characteristic colorimetric pattern of each species used, both for Calocarpum mammosum Pierre and for Mammea americana L, (see figure 3) that allows laboratory analytical determinations and the inspection of possible dehydrates of mamey in which it is intended to verify the content of mamey pulp and the existence of possible adulterations of the product, such as by adding additives, or various agents that are intended to increase the weight of the mixture and reduce the amount of mamey pulp . Determined the behavior of the colorimetric pattern of the dehydrated to be inspected, bromatological analyzes are performed to verify its components and its organoleptic properties.
En una de las modalidades de Ia invención, para inspeccionar Ia identidad de deshidratados de pulpa de mamey, se realiza un proceso que incluye las siguientes etapas: 1. Determinación del patrón colorimétrico de las muestras.In one of the embodiments of the invention, to inspect the identity of dehydrated mamey pulp, a process is carried out that includes the following steps: 1. Determination of the colorimetric pattern of the samples.
Durante esta etapa, se determina el patrón colorimétrico del polvo de Ia invención utilizado como estándar, mediante técnicas colorimétricas realizando un barrido de lecturas de porcentaje de reflectancia de Ia muestra en función de Ia longitud de onda en un rango de 400 a 700nm, utilizando como control Ia celda que se haya utilizado para inspeccionar Ia muestra del estándar. Posteriormente, utilizando una muestra del producto deshidratado de mamey a inspeccionar, se realiza el mismo barrido colorimétrico a las mismas condiciones que para Ia muestra estándar, para obtener el patrón de longitud de onda correspondiente a Ia muestra inspeccionada.During this stage, the colorimetric pattern of the powder of the invention used as a standard is determined, using colorimetric techniques by scanning the percentage reflectance readings of the sample based on the wavelength in a range of 400 to 700 nm, using as control the cell that has been used to inspect the sample of the standard. Subsequently, using a sample of the dehydrated product of mamey to be inspected, the same colorimetric scanning is performed at the same conditions as for the standard sample, to obtain the wavelength pattern corresponding to the inspected sample.
2. Determinación y comparación analítica.2. Determination and analytical comparison.
Obtenidos los patrones colorimétricos del estándar y Ia muestra inspeccionada, se comparan entre sí para determinar si ambos patrones coinciden en su comportamiento. Si Ia comparación resulta positiva, se realiza un análisis bromatológico para verificar los componentes y las propiedades organolépticas del deshidratado de mamey inspeccionado, las cuales al compararse con las características bromatológicas de Ia muestra estándar, no deben presentar variaciones significativas. En este punto Ia concentración de carbohidratos de Ia muestra inspeccionada no debe exceder del 52% p/p, debido a que es Ia concentración máxima contenida en el estándar. Así mismo el valor de proteínas deberá estar comprendido en el intervalo de 6.8 a 8.2% p/p, mientras que el de grasas en un intervalo de 0.9 a 1.1 % p/p, ya que son los rangos de valor contenidos en el estándar. En caso de contener una concentración mayor al 52% p/p de carbohidratos y una concentración menor al intervalo indicado para proteínas y grasas, se concluye que Ia muestra corresponde efectivamente a deshidratado de mamey pero que ha sido adulterada o adicionada con carbohidratos.Obtained the colorimetric standards of the standard and the inspected sample, they are compared with each other to determine if both patterns coincide in their behavior. If the comparison is positive, a bromatological analysis is performed to verify the components and organoleptic properties of the dehydrated mamey inspected, which when compared with the bromatological characteristics of the standard sample, should not present significant variations. At this point, the carbohydrate concentration of the inspected sample should not exceed 52% w / w, because it is the maximum concentration contained in the standard. Likewise, the value of proteins should be in the range of 6.8 to 8.2% w / w, while that of fats in the range of 0.9 to 1.1% w / w, since they are the ranges of value contained in the standard. If it contains a concentration greater than 52% w / w carbohydrates and a concentration lower than the indicated range for proteins and fats, it is concluded that the sample corresponds effectively dehydrated from mamey but that has been adulterated or added with carbohydrates.
En caso de que el patrón colorimétrico de Ia muestra presente un comportamiento diferente al de Ia muestra estándar, se concluye que Ia muestra no corresponde con deshidratado de mamey.In the event that the colorimetric pattern of the sample exhibits a different behavior from that of the standard sample, it is concluded that the sample does not correspond with dehydrated mamey.
El método anterior permite determinar Ia identidad de deshidratados de pulpa de mamey en muestras determinadas. Como podrá observarse en las figuras 2 y 3, el método analítico descrito utilizando el polvo de mamey de Ia invención como estándar, permite identificar polvos de mamey adulterados o adicionados con otras sustancias.The previous method allows to determine the identity of dehydrated mamey pulp in certain samples. As can be seen in Figures 2 and 3, the analytical method described using the mamey powder of the invention as a standard, allows the identification of adulterated or added mamey powders with other substances.
En una de las modalidades de Ia invención, el método de identificación de deshidratados de pulpa de mamey también permite determinar Ia cantidad de carbohidratos totales contenidos en Ia muestra utilizando Ia misma metodología descrita. Esto a partir de Ia observación del solicitante de que Ia adición de azúcares al polvo de mamey de Ia invención no altera el comportamiento del patrón colorimétrico del polvo, pero si causa alteración en los valores de reflectancia del polvo, generalmente incrementando su magnitud. En este caso, después de determinar que los patrones colorimétricos del estándar y Ia muestra inspeccionada coinciden en su comportamiento, se determina Ia variación de las lecturas de reflectancia entre las muestras y se relaciona con Ia concentración de carbohidratos totales del estándar, determinándose así Ia concentración de carbohidratos de Ia muestra inspeccionada. Como podrá observarse en el ejemplo 5, es factible determinar Ia concentración de carbohidratos contenidos en deshidratados o polvos de mamey utilizando Ia metodología descrita y utilizando como estándar el polvo de mamey de Ia invención.In one of the embodiments of the invention, the method of identifying dehydrates of mamey pulp also allows determining the amount of total carbohydrates contained in the sample using the same methodology described. This from the observation of the applicant that the addition of sugars to the mamey powder of the invention does not alter the behavior of the colorimetric pattern of the powder, but does cause alteration in the dust reflectance values, generally increasing its magnitude. In this case, after determining that the colorimetric standards of the standard and the inspected sample coincide in their behavior, the variation of the reflectance readings between the samples is determined and is related to the concentration of total carbohydrates of the standard, thus determining the concentration of carbohydrates of the inspected sample. As can be seen in example 5, it is feasible to determine the concentration of carbohydrates contained in dehydrated or mamey powders using the described methodology and using as standard the mamey powder of the invention.
Como una manera de ilustrar Ia presente invención se muestran los siguientes ejemplos sin el propósito de limitar su alcance. Ejemplo 1. Obtención de polvo estable de pulpa de mamey.As a way to illustrate the present invention, the following examples are shown without the purpose of limiting its scope. Example 1. Obtaining stable powder from mamey pulp.
100 Kg de frutos frescos de mamey del Estado de Veracruz no golpeados, con consistencia firme y en buenas condiciones, fueron lavados con agua clorada a 20 ppm y escurridos para eliminar el agua excedente. Los frutos lavados se cortaron por Ia mitad y se retiró Ia semilla del fruto, Ia cual fue eliminada. Posteriormente el fruto cortado y provisto de cascara, fue sometido a deshidratación durante 3 a 50 minutos mediante microondas a una temperatura de 60 a 1100C. Terminada Ia deshidratación, Ia pulpa obtenida y enfriada a temperatura ambiente, se separó de Ia cascara del fruto mediante una cucharilla previamente sanitizada, desechándose Ia cascara del fruto. La pulpa obtenida se sometió entonces a una deshidratación mediante termosecado a una temperatura de 60 a 1200C durante un tiempo de 0.5 a 4 horas. Al término de Ia deshidratación y mediante un dispositivo Aqualab, se determinó el valor de actividad acuosa de una muestra de Ia pulpa obtenida, obteniéndose un valor de 0.2 a 0.7. La pulpa deshidratada con dicha actividad acuosa, fue mezclada con ácido cítrico en una proporción del 0.01 al 2% en peso con respecto del peso total de Ia pulpa deshidratada obtenida, para posteriormente someter Ia mezcla a una molienda continua mediante un molino de aspas o turbomolino hasta obtener un tamaño de partícula de 125 a 250 μm. El polvo obtenido fue cernido mediante un clasificador granulométrico conforme al tamaño de partícula deseado, moliendo de nueva cuenta y a las mismas condiciones, el polvo que haya quedado retenido en el clasificador. Obtenido el tamaño de partícula en el intervalo mencionado, los polvos fueron mezclados hasta homogeneización. Finalmente el polvo obtenido fue colocado en bolsas de polietileno que posteriormente fueron introducidas en envases de Pet de 100 a 200 g de capacidad, tomándose una muestra del polvo para posterior análisis bromatológico. Diversas características del polvo de mamey obtenido fueron analizadas mediante métodos analíticos determinados, obteniéndose los resultados que se muestran en Ia tabla 2.100 Kg of fresh mamey fruits from the State of Veracruz not hit, with firm consistency and in good condition, were washed with chlorinated water at 20 ppm and drained to remove excess water. The washed fruits were cut in half and the seed of the fruit was removed, which was eliminated. Subsequently the fruit cut and provided with peel, was subjected to dehydration for 3 to 50 minutes by microwave at a temperature of 60 to 110 0 C. After the dehydration, the pulp obtained and cooled to room temperature, was separated from the fruit peel by means of a spoon previously sanitized, discarding the husk of the fruit. The pulp obtained was then subjected to dehydration by termosecado at a temperature of 60 to 120 0 C for 0.5 to 4 hours. At the end of the dehydration and by means of an Aqualab device, the aqueous activity value of a sample of the pulp obtained was determined, obtaining a value of 0.2 to 0.7. The dehydrated pulp with said aqueous activity, was mixed with citric acid in a proportion of 0.01 to 2% by weight with respect to the total weight of the dehydrated pulp obtained, to subsequently subject the mixture to continuous grinding by means of a blade mill or turbomoline until a particle size of 125 to 250 μm is obtained. The obtained powder was sifted by a granulometric classifier according to the desired particle size, grinding again and at the same conditions, the powder that has been retained in the classifier. Obtained the particle size in the mentioned range, the powders were mixed until homogenization. Finally, the powder obtained was placed in polyethylene bags that were subsequently introduced into Pet containers of 100 to 200 g capacity, taking a sample of the powder for subsequent bromatological analysis. Various characteristics of the mamey powder obtained were analyzed by certain analytical methods, obtaining the results shown in Table 2.
Tabla 2. Propiedades del polvo estable de mamey de la invenciónTable 2. Properties of the stable mamey powder of the invention
Figure imgf000032_0001
Figure imgf000032_0001
Pαrαatls 100 gésí mieras indicaeo fe s"te equipa Aquatefi de 3 εcir rsms Dscagc-1 a 2S11C.Pαrαatls 100 gésí mieras indicaeo fe s "is equipped by Aquatefi from 3 εcir rsms Dscagc- 1 to 2S 11 C.
— mg fss-ra liberadla h í» g- mg fss-ra release it h í »g
Como podrá observarse en Ia tabla 2, Ia cantidad de elementos nutritivos encontrados en el polvo de Ia invención fue mayor que Ia encontrada en Ia pulpa fresca del fruto, Io cual es debido a que los elementos nutritivos de Ia pulpa del mamey se concentran en el polvo debido al proceso de deshidratación. Con respecto a las actividades enzimáticas exploradas en el polvo, no se encontró actividad de polifenol oxidasa, mientras que Ia actividad proteolítica y de lipasa también resultaron muy bajas; así mismo el valor de actividad acuosa resultó de 0.6 como máximo, por Io que las propiedades organolépticas del polvo no sufren alteración durante el almacenamiento debido a actividad enzimática o contaminación microbiana.As can be seen in Table 2, the amount of nutritional elements found in the powder of the invention was greater than that found in the fresh pulp of the fruit, which is due to the fact that the nutritional elements of the mamey pulp are concentrated in the powder due to the dehydration process. With respect to the enzymatic activities explored in the powder, no polyphenol oxidase activity was found, while the proteolytic and lipase activity were also very low; Likewise, the water activity value was at most 0.6, so that the organoleptic properties of the powder do not suffer alteration during storage due to enzymatic activity or microbial contamination.
Ejemplo 2. Procesamiento parcial de pulpa de mamey.Example 2. Partial processing of mamey pulp.
100 Kg de frutos frescos de mamey del Estado de Veracruz fueron procesados tal como se describe en el ejemplo 1 , con excepción de las etapas de determinación de Ia actividad acuosa, adición de ácido cítrico y posterior molienda. El producto obtenido fue una pasta viscosa y pegajosa que no pudo molerse para obtener polvo de mamey.100 Kg of fresh mamey fruits from the State of Veracruz were processed as described in example 1, with the exception of the steps of determining the aqueous activity, adding citric acid and subsequent grinding. The product obtained was a viscous and sticky paste that could not be ground to obtain mamey powder.
Ejemplo 3. Estabilidad en anaquel del polvo.Example 3. Stability in powder shelf.
El polvo de Ia invención fue sometido a almacenamiento por el transcurso deThe powder of the invention was subjected to storage during the course of
1 año a temperatura ambiente lejos de Ia luz solar para posteriormente determinar sus propiedades organolépticas. El polvo presentó olor, color y sabor típicos a pulpa de mamey, y no se observó apelmazamiento ni contaminación de ningún tipo.1 year at room temperature away from sunlight to subsequently determine its organoleptic properties. The powder had a typical smell, color and taste of mamey pulp, and no caking or contamination of any kind was observed.
Ejemplo 4. Preparación de alimentos que incluyen el polvo de Ia invención.Example 4. Preparation of foods that include the powder of the invention.
El polvo de mamey obtenido del ejemplo 1 , fue utilizado para preparar las siguientes composiciones alimenticias:The mamey powder obtained from example 1 was used to prepare the following food compositions:
Dulce de mamey.Mamey's sweet.
Se mezcló media taza de agua con % de taza de azúcar y se sometió a ebullición durante el tiempo suficiente para lograr una mezcla espesa. La mezcla obtenida fue colocada en una licuadora casera, a Ia cual se adicionaron 10Og del polvo de mamey, 1 cucharada de jerez y 3A de taza de leche, para posteriormente licuar los ingredientes. La mezcla obtenida tuvo un aspecto y sabor agradables, y exhibió un sabor y color característicos de Ia pulpa fresca de mamey. Malteada de mamey.Half a cup of water with% cup of sugar was mixed and boiled for long enough to achieve a thick mixture. The mixture obtained was placed in a homemade blender, to which 10Og of the mamey powder, 1 tablespoon of sherry and 3 A cup of milk were added, to subsequently liquefy the ingredients. The obtained mixture had a pleasant appearance and flavor, and exhibited a characteristic flavor and color of the fresh mamey pulp. Mamey milkshake.
Se disolvieron 4 cucharadas de fécula de maíz en media taza de leche. En un recipiente por separado, 1 litro de leche se colocó a ebullición, adicionando Ia fécula de maíz previamente disuelta y mezclando hasta completa incorporación; Ia mezcla resultante se refrigeró durante toda Ia noche. La mezcla enfriada se colocó en una licuadora casera junto con 100 g del polvo de mamey y una cucharada de azúcar. La bebida resultante presentó el sabor y color típicos de Ia pulpa fresca de mamey y se observó una perfecta incorporación del polvo de mamey en Ia bebida.4 tablespoons of cornstarch were dissolved in half a cup of milk. In a separate container, 1 liter of milk was boiled, adding the previously dissolved corn starch and mixing until completely incorporated; The resulting mixture was refrigerated overnight. The cooled mixture was placed in a homemade blender along with 100 g of the mamey powder and a tablespoon of sugar. The resulting beverage presented the typical flavor and color of the fresh mamey pulp and a perfect incorporation of the mamey powder was observed in the drink.
Postre de mamey.Mamey's dessert.
20Og de polvo de mamey fueron mezclados con 1 lata de leche condensada y 2 yemas de huevo por medio de una licuadora casera hasta lograr una mezcla uniforme. La mezcla obtenida presentó el sabor y color típicos de Ia pulpa fresca de mamey.20Og of mamey powder were mixed with 1 can of condensed milk and 2 egg yolks by means of a homemade blender until a uniform mixture was achieved. The obtained mixture presented the typical flavor and color of the fresh mamey pulp.
Helado de mamey.Mamey's ice cream.
20Og de polvo de mamey fueron mezclados en una licuadora casera con 1 litro de leche y azúcar al gusto. La mezcla obtenida fue congelada por espacio de 5 horas, obteniéndose un helado con sabor y color típicos de Ia pulpa fresca de mamey.20Og of mamey powder were mixed in a homemade blender with 1 liter of milk and sugar to taste. The obtained mixture was frozen for 5 hours, obtaining an ice cream with flavor and color typical of the fresh mamey pulp.
Flan de mamey.Flan de mamey.
2 tazas de azúcar se sometieron a calentamiento hasta su caramelización. En una licuadora casera se mezclaron por espacio de 5 minutos, 1 lata de leche condensada, 1 lata de leche, 5 huevos y de 100 a 200 g de polvo de mamey. La mezcla obtenida se vertió en recipientes individuales conteniendo azúcar caramelizada, colocando los recipientes en una olla de presión por espacio de 40 min. Los envases se dejaron enfriar a temperatura ambiente, obteniéndose un flan con el sabor y color típicos de Ia pulpa fresca de mamey.2 cups of sugar were heated until caramelization. In a homemade blender, 1 can of milk were mixed for 5 minutes condensed, 1 can of milk, 5 eggs and 100 to 200 g of mamey powder. The obtained mixture was poured into individual containers containing caramelized sugar, placing the containers in a pressure cooker for 40 min. The containers were allowed to cool to room temperature, obtaining a flan with the typical flavor and color of the fresh mamey pulp.
Bebida de mamey con tequila.Mamey drink with tequila.
Se mezclaron en una licuadora convencional 10 almendras, 2 cucharadas de miel de abeja, una lata de leche evaporada, 100 a 200 g de polvo de mamey y hielo. A Ia mezcla resultante se adicionó tequila al gusto, obteniéndose una bebida con sabor a mamey.10 almonds, 2 tablespoons of honey, a can of evaporated milk, 100 to 200 g of mamey powder and ice were mixed in a conventional blender. To the resulting mixture was added tequila to taste, obtaining a mamey flavored drink.
Ejemplo 5. Determinación analítica de muestras de polvo de mamey deshidratado.Example 5. Analytical determination of samples of dehydrated mamey powder.
El polvo de mamey descrito en el ejemplo 1 , fue utilizado como reactivo estándar para determinar Ia concentración e identidad de diversas mezclas que contenían polvo de mamey.The mamey powder described in example 1, was used as a standard reagent to determine the concentration and identity of various mixtures containing mamey powder.
Se seleccionaron diversas muestras de polvo de mamey obtenidas según el ejemplo 1 , y que presentaron valores de actividad acuosa de 0.4 a 0.6. 10 g de cada una de las muestras se colocaron en una celda rectangular para posteriormente ser analizada mediante un colorímetro. La luz reflejada por el polvo de mamey de las muestras fue analizada mediante tres filtros de diferentes colores, obteniéndose lecturas que fueron enviadas a un programa de cómputo y graficadas en función de Ia longitud de onda y el porcentaje de luz reflejada por Ia muestra. Las muestras que presentaron una variación pequeña en sus lecturas fueron seleccionadas y mezcladas entre sí para generar el estándar, tanto para polvo de Calocarpum mammosum Pierre como para Mammea americana L, del que posteriormente se obtuvo el espectro colorimétrico que se observa en la figura 3 (ver A y B). Como puede observarse, existe un incremento en Ia reflectancia directamente proporcional al incremento de Ia longitud de onda a partir de los 550 nm para el caso de Calocarpum mammosum Pierre, mientras que para Mammea americana L el incremento observado no es tan significativo. Para las dos especies de mamey, Ia mayor reflectancia de las muestras estándar se dio en el intervalo de 600 a 700 nm.Various samples of mamey powder obtained according to example 1 were selected, and which showed aqueous activity values of 0.4 to 0.6. 10 g of each of the samples were placed in a rectangular cell and subsequently analyzed using a colorimeter. The light reflected by the mamey powder of the samples was analyzed by means of three filters of different colors, obtaining readings that were sent to a computer program and plotted according to the wavelength and the percentage of light reflected by the sample. The samples that presented a small variation in their readings were selected and mixed together to generate the standard, both for Calocarpum mammosum Pierre powder and for Mammea americana L, which subsequently obtained the colorimetric spectrum shown in Figure 3 (see A and B). As can be seen, there is an increase in reflectance directly proportional to the increase in wavelength from 550 nm in the case of Calocarpum mammosum Pierre, while for Mammea americana L the observed increase is not as significant. For the two species of mamey, the greatest reflectance of the standard samples was in the range of 600 to 700 nm.
Diversas muestras conteniendo polvo de mamey obtenido conforme al ejemplo 1 , polvo de pulpa de aguacate obtenido según Jiménez, o mezclas de polvo de mamey adicionadas con carbohidratos, fueron preparadas de Ia misma forma que Ia muestra estándar y sometidas a análisis colorimétrico mediante barrido en un rango de longitud de onda de 400 a 700 nm. Las lecturas obtenidas de las muestras inspeccionadas, generaron los espectros colorimétricos que se observan en las figuras 2 y 3.Various samples containing mamey powder obtained according to example 1, avocado pulp powder obtained according to Jiménez, or mixtures of mamey powder added with carbohydrates, were prepared in the same way as the standard sample and subjected to colorimetric analysis by scanning in a wavelength range from 400 to 700 nm. The readings obtained from the inspected samples generated the colorimetric spectra observed in Figures 2 and 3.
El comportamiento del espectro colorimétrico obtenido de diversas muestras de polvo de mamey (Calocarpum mammosum Pierre) del Estado de Veracruz (fig 2, B, C y D) fue muy similar al comportamiento del espectro obtenido para Ia muestra estándar (fig 2, A), sin embargo se observaron variaciones en el porcentaje de reflectancia de dichas muestras que llegaron a ser importantes (fig. 2, C). Por otro lado, al adicionar glucosa a Ia muestra estándar, se observó un incremento importante en los valores de reflectancia con respecto del estándar, pero sin observarse alteraciones en el comportamiento del espectro resultante (fig. 2, E).The behavior of the colorimetric spectrum obtained from various samples of mamey powder (Calocarpum mammosum Pierre) from the State of Veracruz (fig 2, B, C and D) was very similar to the behavior of the spectrum obtained for the standard sample (fig 2, A) , however, variations were observed in the percentage of reflectance of said samples that became important (fig. 2, C). On the other hand, when adding glucose to the standard sample, a significant increase in reflectance values with respect to the standard was observed, but without altering the behavior of the resulting spectrum (fig. 2, E).
Con respecto del comportamiento del espectro colorimétrico obtenido a partir de polvo de mamey de Ia especie Mammea americana L proveniente del Estado de Yucatán utilizado como estándar, se observó un comportamiento semejante al observado para polvo de mamey de Ia especie Calocarpum mammosum Pierre hasta los 550 nm, presentando un comportamiento diferente a partir de ésta longitud de onda. Al igual que para el espectro de la muestra estándar de Calocarpum mammosum Pierre, Ia adición de glucosa a Ia muestra estándar de Mammea americana L solo causó variaciones en los valores de reflectancia sin alterar el comportamiento del espectro.With respect to the behavior of the colorimetric spectrum obtained from mamey powder of the Mammea americana L species from the State of Yucatan used as a standard, a behavior similar to that observed for mamey powder of the Calocarpum mammosum Pierre species was observed up to 550 nm , presenting a behavior different from this wavelength. As with the spectrum of the standard Calocarpum mammosum Pierre sample, the addition of glucose to the standard Mammea americana L sample only caused variations in the reflectance values without altering the spectrum behavior.
En cuanto al espectro colorímetro obtenido de polvo de pulpa de aguacate Hass (fig. 3, C y D), este mostró un comportamiento completamente diferente al espectro obtenido de Ia muestra estándar de polvo de mamey, el cual no resultó comparable con el espectro obtenido del estándar de mamey.Regarding the colorimeter spectrum obtained from Hass avocado pulp powder (fig. 3, C and D), this showed a completely different behavior to the spectrum obtained from the standard sample of mamey powder, which was not comparable with the spectrum obtained from mamey's standard.
Conforme a los valores de reflectancia obtenidos para las diversas muestras de polvo de mamey inspeccionadas que se muestran en Ia figura 2, se calculó Ia concentración de carbohidratos de éstas en relación a Ia concentración de carbohidratos contenida en el estándar. Así mismo, las concentraciones de proteínas y grasas de cada una de las muestras fueron determinadas por análisis bromatológico. Los resultados se muestran en Ia tabla 3.According to the reflectance values obtained for the various samples of mamey powder inspected shown in Figure 2, the concentration of carbohydrates thereof in relation to the concentration of carbohydrates contained in the standard was calculated. Likewise, the protein and fat concentrations of each of the samples were determined by bromatological analysis. The results are shown in table 3.
Tabla 3Table 3
Figure imgf000037_0001
Figure imgf000037_0001
+ Porcentaje en peso respecto del peso total de Ia muestra. * Determinado mediante análisis bromatológico. ** Calculado confome al valor de reflectancia obtenido. *** Estándar + 30% de glucosa Los resultados de Ia tabla 3 muestran una disminución de Ia concentración de proteína y grasas en Ia mezcla del polvo estándar y 30% de glucosa por debajo de Ia especificación dada por el estándar, así como un aumento en Ia concentración de azúcares, Io que significa que Ia muestra es polvo de mamey pero que ha sido adicionado con azúcar. Para el resto de las muestras ensayadas (B, C y D) los valores encontrados de azúcares, proteínas y grasas se encontraron dentro de los parámetros del estándar, Io que significa que son muestras de polvos de mamey sin adulteración o adición de componentes. En el caso de Ia muestra C, los valores encontrados fueron superiores al del estándar, pero el incremento fue proporcional en cada uno de los componentes determinados, Io cual aparentemente está relacionado con las características del fruto utilizado, el cual pesó 1.5 Kg por fruto y su semilla fue pequeña en comparación con los otros frutos procesados.+ Weight percentage with respect to the total weight of the sample. * Determined by bromatological analysis. * * Calculated according to the reflectance value obtained. *** Standard + 30% glucose The results of Table 3 show a decrease in the concentration of protein and fat in the mixture of the standard powder and 30% glucose below the specification given by the standard, as well as an increase in the concentration of sugars, which means that the sample is mamey powder but that has been added with sugar. For the rest of the samples tested (B, C and D) the values found for sugars, proteins and fats were found within the standard parameters, which means that they are samples of mamey powders without adulteration or addition of components. In the case of sample C, the values found were higher than the standard, but the increase was proportional in each of the determined components, which apparently is related to the characteristics of the fruit used, which weighed 1.5 Kg per fruit and Its seed was small compared to the other processed fruits.
Como puede observarse, el polvo de Ia invención utilizado como estándar, sirvió como reactivo analítico de referencia para determinar Ia identidad de muestras de polvo de mamey, así como Ia variación en Ia concentración de carbohidratos de polvos de mamey. As can be seen, the powder of the invention used as a standard, served as an analytical reference reagent to determine the identity of mamey powder samples, as well as the variation in carbohydrate concentration of mamey powders.
Referencias.References.
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Claims

Reivindicaciones. Claims
1. Una composición estable de pulpa de mamey que no presenta oscurecimiento enzimático ó no enzimático, caracterizada porque comprende: a) Pulpa deshidratada de mamey en un porcentaje del 98 al 99.99% en peso con respecto del peso total de Ia composición, y b) Un aditivo de molienda seleccionado del grupo que comprende ácido cítrico, ácido ascórbico o mezclas de los mismos en un porcentaje del 0.01 al 2% en peso con respecto del peso total de Ia composición.1. A stable composition of mamey pulp that has no enzymatic or non-enzymatic darkening, characterized in that it comprises: a) dehydrated mamey pulp in a percentage of 98 to 99.99% by weight with respect to the total weight of the composition, and b) A milling additive selected from the group comprising citric acid, ascorbic acid or mixtures thereof in a percentage of 0.01 to 2% by weight with respect to the total weight of the composition.
2. La composición de Ia reivindicación 1 , caracterizada porque tiene un tiempo de vida en anaquel a temperatura ambiente de 12 meses.2. The composition of claim 1, characterized in that it has a shelf life at room temperature of 12 months.
3. La composición de Ia reivindicación 1 a 2, caracterizada porque tiene una actividad acuosa de 0.2 a 0.7.3. The composition of claim 1 to 2, characterized in that it has an aqueous activity of 0.2 to 0.7.
4. La composición de Ia reivindicación 1 a 3, caracterizada porque tiene un tamaño de partícula de 125 a 250 μm.4. The composition of claim 1 to 3, characterized in that it has a particle size of 125 to 250 μm.
5. La composición de Ia reivindicación 1 a 4, caracterizada porque el aditivo de molienda es ácido cítrico.5. The composition of claim 1 to 4, characterized in that the milling additive is citric acid.
6. La composición de Ia reivindicación 1 a 5, caracterizada porque el mamey se selecciona del grupo que comprende Calocarpum mammosum Pierre,6. The composition of claim 1 to 5, characterized in that the mamey is selected from the group comprising Calocarpum mammosum Pierre,
Mammea americana L, o mezclas de los mismos.Mammea americana L, or mixtures thereof.
7. Un proceso para obtener Ia composición estable de pulpa de mamey de Ia reivindicación 1 a 6, caracterizado porque comprende las etapas de: a) Cortar longitudinalmente el fruto fresco de mamey por Ia mitad conservando Ia cascara y eliminar Ia semilla del fruto, b) Deshidratar las mitades con cascara del fruto fresco de mamey hasta que Ia pulpa pueda desprenderse de Ia cascara, c) Separar Ia pulpa deshidratada de Ia cascara y deshidratarla de nuevo hasta que presente un valor de actividad acuosa de 0.2 a 0.7. d) Enfriar a temperatura ambiente Ia pulpa obtenida en c), adicionar un aditivo de molienda seleccionado del grupo que comprende ácido cítrico, ácido ascórbico o mezclas de los mismos en un porcentaje del 0.01 al 2% en peso con respecto del peso total de Ia composición y mezclar, y e) Moler Ia mezcla obtenida en d) hasta obtener un tamaño de partícula de 125 a 250 μm.7. A process to obtain the stable mamey pulp composition of claim 1 to 6, characterized in that it comprises the steps of: a) Cut the fresh mamey fruit lengthwise in half keeping the husk and eliminating the seed of the fruit, b) Dehydrate the halves with the shell of the fresh mamey fruit until the pulp can be released from the shell, c) Separate the dried pulp from the shell and dehydrate it again until it has an aqueous activity value of 0.2 to 0.7. d) Cool the pulp obtained in c) at room temperature, add a milling additive selected from the group comprising citric acid, ascorbic acid or mixtures thereof in a percentage of 0.01 to 2% by weight with respect to the total weight of the composition and mixing, and e) Grind the mixture obtained in d) until obtaining a particle size of 125 to 250 μm.
8. El proceso de Ia reivindicación 7 caracterizado porque Ia deshidratación se realiza mediante un método seleccionado del grupo que consiste de termosecado, microondas y aire caliente .8. The process of claim 7 characterized in that the dehydration is carried out by means of a method selected from the group consisting of heat drying, microwave and hot air.
9. El proceso de la reivindicación 8 caracterizado porque Ia deshidratación se realiza mediante termosecado a una temperatura de 100 a 1200C en un tiempo de 3 a 12 minutos.9. The process of claim 8 characterized in that the dehydration is carried out by heat drying at a temperature of 100 to 120 0 C in a time of 3 to 12 minutes.
10. El proceso de Ia reivindicación 8 caracterizado porque Ia deshidratación se realiza mediante microondas a una temperatura de 60 a 1100C en un tiempo de 3 a 30 minutos.10. The process of claim 8 characterized in that the dehydration is carried out by microwave at a temperature of 60 to 110 0 C in a time of 3 to 30 minutes.
11. El proceso de Ia reivindicación 8 caracterizado porque Ia deshidratación se realiza mediante aire caliente a una temperatura de 100 a 1200C en un tiempo de 3 a 20 minutos.11. The process of claim 8 characterized in that the dehydration is carried out by hot air at a temperature of 100 to 120 0 C in a time of 3 to 20 minutes.
12. Una composición alimenticia caracterizada porque comprende Ia composición estable de pulpa de mamey de conformidad con Ia reivindicación 1 a 6. 12. A food composition characterized in that it comprises the stable composition of mamey pulp in accordance with claim 1 to 6.
13. La composición alimenticia de Ia reivindicación 12, caracterizada porque Ia composición estable de pulpa de mamey se encuentra en un porcentaje en peso del 10 al 20% con respecto del peso total de Ia composición alimenticia.13. The food composition of claim 12, characterized in that the stable composition of mamey pulp is in a weight percentage of 10 to 20% with respect to the total weight of the food composition.
14. La composición alimenticia de Ia reivindicación 12 a 13, caracterizada porque se selecciona del grupo que comprende productos de confitería, postres, pasteles, mousses, helados, yogures, jarabes y bebidas.14. The food composition of claim 12 to 13, characterized in that it is selected from the group comprising confectionery products, desserts, cakes, mousses, ice cream, yogurts, syrups and beverages.
15. Un método para determinar Ia identidad de deshidratados de pulpa de mamey, caracterizado porque comprende las etapas de: a) Obtener el espectro colorimétrico de una muestra de Ia composición estable de pulpa de mamey de Ia reivindicación 1 , así como de una muestra del deshidratado de pulpa de mamey a inspeccionar, b) Comparar el comportamiento del espectro colorimétrico obtenido de las muestras, c) Determinar Ia concentración de azúcares, proteínas y grasas de aquellas muestras inspeccionadas que presentaron el mismo comportamiento espectrométrico que Ia composición estable de pulpa de mamey de Ia reivindicación 1 , y d) Comparar Ia concentración de azúcares, proteínas y grasas de Ia muestra inspeccionada con Ia concentración de los mismos componentes de Ia composición estable de pulpa de mamey de Ia reivindicación 1.15. A method for determining the identity of dehydrated mamey pulp, characterized in that it comprises the steps of: a) Obtaining the colorimetric spectrum of a sample of the stable mamey pulp composition of claim 1, as well as of a sample of the dehydrated mamey pulp to be inspected, b) Compare the behavior of the colorimetric spectrum obtained from the samples, c) Determine the concentration of sugars, proteins and fats of those inspected samples that exhibited the same spectrometric behavior as the stable composition of mamey pulp of claim 1, and d) Compare the concentration of sugars, proteins and fats of the inspected sample with the concentration of the same components of the stable mamey pulp composition of claim 1.
16. El método de Ia reivindicación 15, caracterizado por que el espectro colorimétrico se obtiene en un intervalo de longitud de onda de 400 a 700 nm.16. The method of claim 15, characterized in that the colorimetric spectrum is obtained in a wavelength range of 400 to 700 nm.
17. El uso de Ia composición de pulpa de mamey de conformidad con Ia reivindicación 1 a 6, como estándar analítico para determinar Ia identidad de Ia pulpa de mamey contenida en composiciones alimenticias. 17. The use of the mamey pulp composition according to claim 1 to 6, as an analytical standard for determining the identity of the mamey pulp contained in food compositions.
18. El uso de Ia reivindicación 17 donde las composiciones alimenticias son deshidratados de pulpa de mamey. 18. The use of claim 17 wherein the food compositions are dehydrated from mamey pulp.
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