WO2008120660A1 - Novel phosphine, method for producing the same and use of the same - Google Patents

Novel phosphine, method for producing the same and use of the same Download PDF

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Publication number
WO2008120660A1
WO2008120660A1 PCT/JP2008/055855 JP2008055855W WO2008120660A1 WO 2008120660 A1 WO2008120660 A1 WO 2008120660A1 JP 2008055855 W JP2008055855 W JP 2008055855W WO 2008120660 A1 WO2008120660 A1 WO 2008120660A1
Authority
WO
WIPO (PCT)
Prior art keywords
groups
substituted
group
same
hydrocarbon
Prior art date
Application number
PCT/JP2008/055855
Other languages
French (fr)
Japanese (ja)
Inventor
Michio Yamamoto
Hidenori Hanaoka
Fumisato Goto
Original Assignee
Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Publication of WO2008120660A1 publication Critical patent/WO2008120660A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/58—Pyridine rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Abstract

Disclosed is a phosphine represented by the following formula (1). (In the formula, R1, R2, R3, R4 and R5 independently represent a hydrogen atom, a halogen atom, or a substituent selected from the group consisting of alkyl groups, aralkyl groups and aryl groups, each of which may substituted with a fluorine atom, silyl groups substituted with a hydrocarbon group, amino groups substituted with two hydrocarbon groups, alkoxy groups, aralkyloxy groups and aryloxy groups; and R6, R7, R8 and R9 independently represent a hydrogen atom, a halogen atom, or a substituent selected from the group consisting of alkyl groups, aralkyl groups, aryl groups, silyl groups substituted with a hydrocarbon group, amino groups substituted with two hydrocarbon groups, alkoxy groups, aralkyloxy groups and aryloxy groups. In this connection, at least one of R2, R3 and R4 represents a fluorine atom or an alkyl group substituted with a fluorine atom; and adjacent two groups among R1, R2, R3, R4, R5, R6, R7, R8 and R9 may combine together to form a ring.) This phosphine is useful as a catalyst component for producing a methacrylate ester from an acetylene compound, carbon monoxide and an alcohol.
PCT/JP2008/055855 2007-03-29 2008-03-27 Novel phosphine, method for producing the same and use of the same WO2008120660A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-087296 2007-03-29
JP2007087296 2007-03-29

Publications (1)

Publication Number Publication Date
WO2008120660A1 true WO2008120660A1 (en) 2008-10-09

Family

ID=39808242

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055855 WO2008120660A1 (en) 2007-03-29 2008-03-27 Novel phosphine, method for producing the same and use of the same

Country Status (2)

Country Link
JP (1) JP2008266307A (en)
WO (1) WO2008120660A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011111806A1 (en) * 2010-03-09 2011-09-15 Sumitomo Chemical Company, Limited METHOD FOR PRODUCING α, β-UNSATURATED CARBOXYLATE, AND CATALYST FOR PRODUCING THEREOF
WO2012111737A1 (en) * 2011-02-17 2012-08-23 国立大学法人岡山大学 Novel compound, novel ligand, novel transition metal complexes, and catalysts consisting of novel transition metal complexes

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009104781A1 (en) 2008-02-18 2009-08-27 住友化学株式会社 Composition and organic photoelectric converter using the same
EP2487179A4 (en) * 2009-10-08 2013-02-27 Sumitomo Chemical Co Metal complex, pyridylphosphine compound, and method for producing alkyl methacrylate

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03167196A (en) * 1989-10-20 1991-07-19 Shell Internatl Res Maatschappij Bv Phosphorus compound
JPH0592984A (en) * 1991-02-15 1993-04-16 Shell Internatl Res Maatschappij Bv Preparation of diarylphosphinopyridine
JPH05255362A (en) * 1991-12-14 1993-10-05 Hoechst Ag Preparation of tertiary phosphine
JPH0820592A (en) * 1994-07-04 1996-01-23 Hokko Chem Ind Co Ltd Production of 2-diphenylphosphinopyridine
JPH09188632A (en) * 1986-12-05 1997-07-22 Shell Internatl Res Maatschappij Bv Carbonylation of acetylenic unsaturated compound
JPH11147855A (en) * 1997-11-17 1999-06-02 Daicel Chem Ind Ltd Carbonylation
JP2008088153A (en) * 2006-04-10 2008-04-17 Okayama Univ Method for producing amide compound and catalyst used for the same method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09188632A (en) * 1986-12-05 1997-07-22 Shell Internatl Res Maatschappij Bv Carbonylation of acetylenic unsaturated compound
JPH03167196A (en) * 1989-10-20 1991-07-19 Shell Internatl Res Maatschappij Bv Phosphorus compound
JPH0592984A (en) * 1991-02-15 1993-04-16 Shell Internatl Res Maatschappij Bv Preparation of diarylphosphinopyridine
JPH05255362A (en) * 1991-12-14 1993-10-05 Hoechst Ag Preparation of tertiary phosphine
JPH0820592A (en) * 1994-07-04 1996-01-23 Hokko Chem Ind Co Ltd Production of 2-diphenylphosphinopyridine
JPH11147855A (en) * 1997-11-17 1999-06-02 Daicel Chem Ind Ltd Carbonylation
JP2008088153A (en) * 2006-04-10 2008-04-17 Okayama Univ Method for producing amide compound and catalyst used for the same method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SPENCER L.P. ET AL.: "Pyridine- and Imidazole-Phosphinimine Bidentate Ligand Complexes: Considerations for Ethylene Oligomerization Catalysts", ORGANOMETALLICS, vol. 22, no. 19, 2003, pages 3841 - 3854, XP001174915, DOI: doi:10.1021/om030311t *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011111806A1 (en) * 2010-03-09 2011-09-15 Sumitomo Chemical Company, Limited METHOD FOR PRODUCING α, β-UNSATURATED CARBOXYLATE, AND CATALYST FOR PRODUCING THEREOF
WO2012111737A1 (en) * 2011-02-17 2012-08-23 国立大学法人岡山大学 Novel compound, novel ligand, novel transition metal complexes, and catalysts consisting of novel transition metal complexes
US8779133B2 (en) 2011-02-17 2014-07-15 National University Corporation Okayama University Compound, novel ligand, novel transition metal complex, and catalyst including novel transition metal complex

Also Published As

Publication number Publication date
JP2008266307A (en) 2008-11-06

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