WO2008113472A2 - Improvements in or relating to comestibles - Google Patents

Improvements in or relating to comestibles Download PDF

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Publication number
WO2008113472A2
WO2008113472A2 PCT/EP2008/001705 EP2008001705W WO2008113472A2 WO 2008113472 A2 WO2008113472 A2 WO 2008113472A2 EP 2008001705 W EP2008001705 W EP 2008001705W WO 2008113472 A2 WO2008113472 A2 WO 2008113472A2
Authority
WO
WIPO (PCT)
Prior art keywords
fruit
vegetable
vegetable according
coating
stem
Prior art date
Application number
PCT/EP2008/001705
Other languages
French (fr)
Other versions
WO2008113472A3 (en
Inventor
Jonathan Michael Forbis
Ijsbrand Martinus Kodde
Elias Frank Partyka
Original Assignee
Syngenta Participations Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag
Publication of WO2008113472A2 publication Critical patent/WO2008113472A2/en
Publication of WO2008113472A3 publication Critical patent/WO2008113472A3/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/16Coating with a protective layer; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/42Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/03Products from fruits or vegetables; Preparation or treatment thereof consisting of whole pieces or fragments without mashing the original pieces
    • A23L19/05Stuffed or cored products; Multilayered or coated products; Binding or compressing of original pieces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P20/00Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
    • A23P20/10Coating with edible coatings, e.g. with oils or fats

Definitions

  • the present invention relates to comestibles, in particular fruit and vegetables of the kind having a relatively short shelf life.
  • the invention relates to a non-GM based simple process of increasing the shelf life of such fruit and/or vegetables.
  • a common problem with many particularly nutritious fruits and vegetables post harvest concerns shrinkage, rotting and wilting.
  • shrunken and/or wilted broccoli or cauliflower is an unwelcome sight familiar to many, particularly on a Sunday lunch-time.
  • the present invention provides, at least to some extent, solutions to the problem of short shelf life in vegetables and fruits.
  • the invention provides nutritionally enhanced fruits and/or vegetables the shelf life of which has been extended by the present inventive method, and in particular a snack or desert frozen for direct consumption, absent an intervening thawing step, which is both low calorie and nutritious.
  • Such snacks or deserts are envisaged as a healthy alternative to those presently consumed, particularly in the Western world, which contribute to obesity and morbid obesity in its various increasingly severe designations.
  • the use of small portion (snack sized) grapes could be a substitute for less healthy processed snacks in the prevention and treatment of obesity.
  • Such portions must be appropriately packaged and may consist of grapes detached from the stem.
  • a challenge however - is to prolong the integrity and freshness of the grape, which currently experiences rapid degradation once detached from the stem.
  • Another challenge is the cost effective removal of the grape from the stem without damaging the integrity of the fruit.
  • a method of preventing or reducing desiccation and associated shrinkage of fruits and vegetables, susceptible to desiccation, attached to a stem which is detached from the plant structures supporting the said fruits or vegetables comprising cauterising or otherwise sealing the cut end of the stem substantially immediately after detachment takes place. This prevents tissue from being exposed post detachment and acting as a point of entry for plant pathogens.
  • the cauterisation itself may be selected from the group consisting of physical and chemical cauterisation, and the sealing may comprise treating the cut end of the stem with hot liquefied wax which hardens on cooling, or treating the cut end of the stem with a viscous (preferably edible) oil.
  • sealing the cut end of the fruit or fruit structure at the time of harvest to prevent the exit of water or entry of pathogens involves using a sealant (preferably a lipophilic material, possibly in the form of an oil or wax as indicated above) or heat to cauterize the tissues at the cutting point wherein the delivery of the sealant or heat to the cut surface is via the cutting tool itself- for example by coating the shearing instrument with the lipophilic material or through use of heat or caustic material (i.e. phosphoric acid) which will cauterize the tissue at the point of cutting.
  • a sealant preferably a lipophilic material, possibly in the form of an oil or wax as indicated above
  • heat to cauterize the tissues at the cutting point
  • any conventional method to seal the cut end of the fruit or vegetable may also be used, such as dipping the said end into a reservoir of sealant or spraying the sealant on to the end.
  • the sealing means may be via other than heat or coating with a lipophilic material and may thus comprise treating the cut end of the stem with an acid or alkali.
  • Phosphoric acid at a suitable concentration may be used for this purpose, although other, preferably edible, acids, such as ascorbic, acetic and tartaric may also be used likewise at a suitable concentration.
  • a particularly preferred acid is phosphoric acid.
  • the inventive method is likely to add costs to the provision of fruit or vegetables produced by it in comparison with inferior prior art harvesting processes.
  • the fruit or vegetable subjected to this method preferably be of premium grade, or otherwise enhanced.
  • a pesticide which, unrelated to the principal mode of action of the pesticide, has coincidentally increased the concentration in the fruit or vegetable of compounds selected from the group consisting of polyphenols, vitamins, etc. This can be achieved by applying to the plant during its growing phase various pesticides, such as a fungicide such as Azoxystrobin, or other strobilurin or other effective fungicide or an insecticide such as thiamethoxam etc.
  • the cut end of the fruit or vegetable is sealed with a wax or oil
  • that contains an antimicrobial agent which is heat stable in the case of the wax sealant.
  • a particularly preferred fruit is a seedless "table" grape and the plant structure supporting it prior to detachment is a vine.
  • the present invention also includes an oxygen impermeable, nitrogen filled container which contains an isolated fruit or vegetable, the container preferably being in the form of a flexible bag.
  • the bag may be adapted, particularly in terms of size and strength, for use in vending machines.
  • the bag may be coated with a light impenetrable coating, but nevertheless contain a window of transparent material - to enable the consumer to assess the contents whilst substantially protecting it from light induced degeneration.
  • the fruit and/or vegetable contents of the container preferably have been subjected to the present inventive method as disclosed above so that the container comprises a premium grade, shelf-life-extended, food.
  • the present invention also includes a fruit or vegetable frozen for direct consumption without an intervening thawing step, coated with a vitamin or other nutrient enhancing coating, and or other edible coating which inhibits or prevents the growth of micro- organisms.
  • the fruit or vegetable may be further coated with a coating which enhances the organoleptic experiences of the consumer.
  • the second coating is one which is "healthy” in that, for example, it is low calorie and substantially salt free - other coatings falling outside this definition are not excluded.
  • preferred coatings are organic acids such as citric, tartaric and ascorbic.
  • the coating may also be comprised by chocolate or even cheese, in which case stilton, Wensleydale and camembert are particularly preferred examples.
  • the coating may comprise omega three and/or omega 6 unsaturated fatty acids, such as eicosapentaenoic and docohexaenoic acids which might be useful in delivering to the consumer a useful quantity of an agent known to assist in the prevention and treatment of human cardiovascular disorders.
  • a particularly preferred embodiment of the fruit or vegetable frozen for direct consumption and coated as indicated above is a seedless "table" grape which in addition may have been subjected to the present inventive method.
  • the present invention includes a process that removes the grape from the stem cost effectively and with minimal damage to the fruit comprising treating the fruit and or vegetable: (i) pre-harvest with agents which increase "shattering"; and/or (ii) post harvest through physical, environmental means.
  • This process facilitates the removal of the fruit for further packaging as indicated above or for use in fresh cut preparations in combinations with other fruits.
  • "Shattering" inducing agents include gibberellins.
  • “shattering” refers to the detachment of fruit or vegetables from the stem.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Botany (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Cultivation Receptacles Or Flower-Pots, Or Pots For Seedlings (AREA)

Abstract

A fruit or vegetable frozen for direct consumption without an intervening thawing step, coated with a vitamin or other nutrient enhancing coating, and or other edible coating which inhibits or prevents the growth of micro-organisms.

Description

IMPROVEMENTS IN OR RELATING TO COMESTIBLES
The present invention relates to comestibles, in particular fruit and vegetables of the kind having a relatively short shelf life. Inter alia, the invention relates to a non-GM based simple process of increasing the shelf life of such fruit and/or vegetables.
A common problem with many particularly nutritious fruits and vegetables post harvest concerns shrinkage, rotting and wilting. For example, shrunken and/or wilted broccoli or cauliflower is an unwelcome sight familiar to many, particularly on a Sunday lunch-time.
Huge quantities of fruit and vegetables are discarded domestically each week because they have become soft, rotten or have shrunk and/or have wilted - most probably because of a loss of cell wall turgor pressure, resulting from the loss of a substantial quantity of fluid via the cut end(s) of the fruit or vegetable, a phenomenon which is either unrecognised or underestimated by the fruit and vegetable consuming public.
This deterioration in quality is a preliminary step in the "rotting process", which gives rise to many secondary or additional effects some of which are caused by plant pathogens. Rot can also occur when pathogens enter open wounds on fruits and vegetables. One common source of open wounds is when the fruit becomes detached from the stem, leaving exposed soft tissue as a point of entry and quickly available substrate for pathogenic life. Infection spreads rapidly throughout the fruit and quickly moves into adjacent fruits as well accelerating the degradation process.
The present invention provides, at least to some extent, solutions to the problem of short shelf life in vegetables and fruits. In addition the invention provides nutritionally enhanced fruits and/or vegetables the shelf life of which has been extended by the present inventive method, and in particular a snack or desert frozen for direct consumption, absent an intervening thawing step, which is both low calorie and nutritious. Such snacks or deserts are envisaged as a healthy alternative to those presently consumed, particularly in the Western world, which contribute to obesity and morbid obesity in its various increasingly severe designations. The use of small portion (snack sized) grapes could be a substitute for less healthy processed snacks in the prevention and treatment of obesity. Such portions must be appropriately packaged and may consist of grapes detached from the stem. A challenge however - is to prolong the integrity and freshness of the grape, which currently experiences rapid degradation once detached from the stem. Another challenge is the cost effective removal of the grape from the stem without damaging the integrity of the fruit.
According to the present invention there is provided a method of preventing or reducing desiccation and associated shrinkage of fruits and vegetables, susceptible to desiccation, attached to a stem which is detached from the plant structures supporting the said fruits or vegetables, comprising cauterising or otherwise sealing the cut end of the stem substantially immediately after detachment takes place. This prevents tissue from being exposed post detachment and acting as a point of entry for plant pathogens.
The cauterisation itself may be selected from the group consisting of physical and chemical cauterisation, and the sealing may comprise treating the cut end of the stem with hot liquefied wax which hardens on cooling, or treating the cut end of the stem with a viscous (preferably edible) oil. In a particularly preferred embodiment of the present inventive method, sealing the cut end of the fruit or fruit structure at the time of harvest to prevent the exit of water or entry of pathogens involves using a sealant (preferably a lipophilic material, possibly in the form of an oil or wax as indicated above) or heat to cauterize the tissues at the cutting point wherein the delivery of the sealant or heat to the cut surface is via the cutting tool itself- for example by coating the shearing instrument with the lipophilic material or through use of heat or caustic material (i.e. phosphoric acid) which will cauterize the tissue at the point of cutting.
Having said that, any conventional method to seal the cut end of the fruit or vegetable may also be used, such as dipping the said end into a reservoir of sealant or spraying the sealant on to the end.
As hinted at above, the sealing means may be via other than heat or coating with a lipophilic material and may thus comprise treating the cut end of the stem with an acid or alkali. Phosphoric acid at a suitable concentration may be used for this purpose, although other, preferably edible, acids, such as ascorbic, acetic and tartaric may also be used likewise at a suitable concentration.
A particularly preferred acid, however, is phosphoric acid.
The skilled man reading this present disclosure will recognise that the inventive method is likely to add costs to the provision of fruit or vegetables produced by it in comparison with inferior prior art harvesting processes. In this respect it is intended that the fruit or vegetable subjected to this method preferably be of premium grade, or otherwise enhanced. In this regard, it is preferred that during the growth phase of the fruit or vegetable it has been treated with a pesticide which, unrelated to the principal mode of action of the pesticide, has coincidentally increased the concentration in the fruit or vegetable of compounds selected from the group consisting of polyphenols, vitamins, etc. This can be achieved by applying to the plant during its growing phase various pesticides, such as a fungicide such as Azoxystrobin, or other strobilurin or other effective fungicide or an insecticide such as thiamethoxam etc.
In the case that the cut end of the fruit or vegetable is sealed with a wax or oil, it is preferred that that contains an antimicrobial agent, which is heat stable in the case of the wax sealant.
Whilst the present inventive method can be applied to virtually any fruit or vegetable, a particularly preferred fruit is a seedless "table" grape and the plant structure supporting it prior to detachment is a vine.
The present invention also includes an oxygen impermeable, nitrogen filled container which contains an isolated fruit or vegetable, the container preferably being in the form of a flexible bag. The bag may be adapted, particularly in terms of size and strength, for use in vending machines. The bag may be coated with a light impenetrable coating, but nevertheless contain a window of transparent material - to enable the consumer to assess the contents whilst substantially protecting it from light induced degeneration. The fruit and/or vegetable contents of the container preferably have been subjected to the present inventive method as disclosed above so that the container comprises a premium grade, shelf-life-extended, food. The present invention also includes a fruit or vegetable frozen for direct consumption without an intervening thawing step, coated with a vitamin or other nutrient enhancing coating, and or other edible coating which inhibits or prevents the growth of micro- organisms. The fruit or vegetable may be further coated with a coating which enhances the organoleptic experiences of the consumer. Whilst it is intended primarily that the second coating is one which is "healthy" in that, for example, it is low calorie and substantially salt free - other coatings falling outside this definition are not excluded. So preferred coatings are organic acids such as citric, tartaric and ascorbic. However the coating may also be comprised by chocolate or even cheese, in which case stilton, Wensleydale and camembert are particularly preferred examples.
Returning to "healthy" coatings - although not necessarily ones which fulfil the strict criteria as regards organoleptic quality enhancing ones, the coating may comprise omega three and/or omega 6 unsaturated fatty acids, such as eicosapentaenoic and docohexaenoic acids which might be useful in delivering to the consumer a useful quantity of an agent known to assist in the prevention and treatment of human cardiovascular disorders.
Once again, a particularly preferred embodiment of the fruit or vegetable frozen for direct consumption and coated as indicated above is a seedless "table" grape which in addition may have been subjected to the present inventive method.
In addition the present invention includes a process that removes the grape from the stem cost effectively and with minimal damage to the fruit comprising treating the fruit and or vegetable: (i) pre-harvest with agents which increase "shattering"; and/or (ii) post harvest through physical, environmental means. This process facilitates the removal of the fruit for further packaging as indicated above or for use in fresh cut preparations in combinations with other fruits. "Shattering" inducing agents include gibberellins.
For the avoidance of doubt — "shattering" refers to the detachment of fruit or vegetables from the stem. A non-mechanical method of intentionally causing a fruit to be separated from the supporting stem structure in order to facilitate packaging into a desired serving size without the introduction of fruit trauma as a course of the method.

Claims

1. A fruit or vegetable frozen for direct consumption without an intervening thawing step, coated with a vitamin or other nutrient enhancing coating, and or other edible coating which inhibits or prevents the growth of micro-organisms.
2. A fruit or vegetable according to claim 1, which is further coated with a coating which enhances the organoleptic experiences of the consumer.
3. A fruit or vegetable according to claim 2, wherein the organoleptic experience enhancing coating comprises at least one of the following:
(a) white chocolate, dark chocolate having a cocoa content of at least 65% (w/w);
(b) an organic acid selected from the group consisting of citric, tartaric and ascorbic;
(c) a cheese selected from the group consisting of Stilton, Camembert, Wendsleydale, Brie, Cheddar and Tilsiter.
4. A fruit or vegetable according to claim 1, wherein the coating comprises omega three and/or omega 6 unsaturated fatty acids.
5. A fruit or vegetable according to any one of claims 1 to 4, which is a seedless "table" grape.
6. A fruit or vegetable according to any one of claims 1 to 5, which has been subjected to a method of preventing or reducing desiccation and associated shrinkage of fruits and vegetables attached to a stem which is detached from the plant structures supporting the said fruits or vegetables, comprising physically or chemically cauterising or otherwise sealing the cut end of the stem substantially immediately after detachment takes place, wherein the otherwise sealing comprises treating the cut end of the stem with heat or a hot liquefied wax which hardens on cooling, or with a viscous oil, wherein the heat or sealant is provided to the cut surface by the shearing instrument.
7. A fruit or vegetable according to any preceding claim, which has, during its growth phase, been treated with a pesticide which, unrelated to the principal mode of action of the pesticide, has coincidentally increased the concentration in the fruit or vegetable of compounds selected from the group consisting of polyphenols, vitamins and antioxidants.
8. A fruit or vegetable according to the preceding claim, wherein the pesticide is selected from the group consisting of a strobilurin fungicide and a neonicotinid insecticide.
9. A fruit or vegetable according to any preceding claim, when present in an oxygen impermeable, nitrogen filled, preferably biodegradable, container.
10. A fruit or vegetable according to claim 9, when present in the form of a flexible bag, that is adapted to be dispensed from a vending machine.
PCT/EP2008/001705 2007-03-16 2008-03-04 Improvements in or relating to comestibles WO2008113472A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0705128.7 2007-03-16
GBGB0705128.7A GB0705128D0 (en) 2007-03-16 2007-03-16 Improvements in or relating to comestibles

Publications (2)

Publication Number Publication Date
WO2008113472A2 true WO2008113472A2 (en) 2008-09-25
WO2008113472A3 WO2008113472A3 (en) 2008-12-11

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GB (1) GB0705128D0 (en)
WO (1) WO2008113472A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUB20152687A1 (en) * 2015-07-30 2017-01-30 Alberto Maso Confectionery food product with high antioxidant content.

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4751091A (en) * 1986-08-15 1988-06-14 University Of Hawaii Preservation of reddish color of lychee pericarp
JPH02109936A (en) * 1988-10-18 1990-04-23 Susumu Nakatani Preparation of skinned frozen grape, skewered frozen grape, preparation thereof and frozen grape wrapped with other food
EP0512274A1 (en) * 1991-04-09 1992-11-11 FIRMA FRUBELLA GmbH Deep-frozen, ready-to-use, cookable fruit mixture
EP1228702A1 (en) * 2001-02-06 2002-08-07 dirafrost F.F.I. n.v. Frozen fruits
WO2002065837A1 (en) * 2001-02-05 2002-08-29 Norsk Hydro Asa Method for controlling the temperature in wax coated plant tissue
JP2003055118A (en) * 2001-08-09 2003-02-26 Bayer Cropscience Kk Pest-controlling method
US20040146617A1 (en) * 1998-10-27 2004-07-29 Schrader Lawrence E Compositions and methods for suppressing cracking and water loss from cherries
EP1522226A1 (en) * 2003-10-01 2005-04-13 dirafrost F.F.I. n.v. Frozen fruit discs
US20050255203A1 (en) * 2004-05-17 2005-11-17 Morando E D Method of making a fresh fruit confection with improved shelf-life
WO2006114574A1 (en) * 2005-04-25 2006-11-02 Syngenta Limited Method for enhancing the quality of green leaf vegetables
US20070059340A1 (en) * 2005-09-09 2007-03-15 Anthony Bello Omega-3 Fatty Acids Encapsulated In Zein Coatings and Food Products Incorporating the Same
WO2007028517A2 (en) * 2005-09-09 2007-03-15 Bayer Cropscience Ag Use of cni-od formulations for controlling white fly

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4751091A (en) * 1986-08-15 1988-06-14 University Of Hawaii Preservation of reddish color of lychee pericarp
JPH02109936A (en) * 1988-10-18 1990-04-23 Susumu Nakatani Preparation of skinned frozen grape, skewered frozen grape, preparation thereof and frozen grape wrapped with other food
EP0512274A1 (en) * 1991-04-09 1992-11-11 FIRMA FRUBELLA GmbH Deep-frozen, ready-to-use, cookable fruit mixture
US20040146617A1 (en) * 1998-10-27 2004-07-29 Schrader Lawrence E Compositions and methods for suppressing cracking and water loss from cherries
WO2002065837A1 (en) * 2001-02-05 2002-08-29 Norsk Hydro Asa Method for controlling the temperature in wax coated plant tissue
EP1228702A1 (en) * 2001-02-06 2002-08-07 dirafrost F.F.I. n.v. Frozen fruits
JP2003055118A (en) * 2001-08-09 2003-02-26 Bayer Cropscience Kk Pest-controlling method
EP1522226A1 (en) * 2003-10-01 2005-04-13 dirafrost F.F.I. n.v. Frozen fruit discs
US20050255203A1 (en) * 2004-05-17 2005-11-17 Morando E D Method of making a fresh fruit confection with improved shelf-life
WO2006114574A1 (en) * 2005-04-25 2006-11-02 Syngenta Limited Method for enhancing the quality of green leaf vegetables
US20070059340A1 (en) * 2005-09-09 2007-03-15 Anthony Bello Omega-3 Fatty Acids Encapsulated In Zein Coatings and Food Products Incorporating the Same
WO2007028517A2 (en) * 2005-09-09 2007-03-15 Bayer Cropscience Ag Use of cni-od formulations for controlling white fly

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUB20152687A1 (en) * 2015-07-30 2017-01-30 Alberto Maso Confectionery food product with high antioxidant content.

Also Published As

Publication number Publication date
WO2008113472A3 (en) 2008-12-11
GB0705128D0 (en) 2007-04-25

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