WO2008111568A1 - 変性金属錯体及びその用途 - Google Patents

変性金属錯体及びその用途 Download PDF

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Publication number
WO2008111568A1
WO2008111568A1 PCT/JP2008/054329 JP2008054329W WO2008111568A1 WO 2008111568 A1 WO2008111568 A1 WO 2008111568A1 JP 2008054329 W JP2008054329 W JP 2008054329W WO 2008111568 A1 WO2008111568 A1 WO 2008111568A1
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WIPO (PCT)
Prior art keywords
mass
ring
complex
nitrogenous aromatic
modified metal
Prior art date
Application number
PCT/JP2008/054329
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English (en)
French (fr)
Inventor
Tadafumi Matsunaga
Nobuyoshi Koshino
Hideyuki Higashimura
Hiroshi Hamamatsu
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Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Priority to CA002680244A priority Critical patent/CA2680244A1/en
Priority to US12/530,174 priority patent/US8519131B2/en
Priority to EP08721745.1A priority patent/EP2133336B1/en
Publication of WO2008111568A1 publication Critical patent/WO2008111568A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30—Oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

　分子内に含窒素芳香族複素環を１つと、さらにフェノール環、チオフェノール環、アニリン環、および含窒素芳香族複素環からなる群から選ばれた構造を４つ以上有する有機化合物を配位子とする金属錯体を、加熱処理、放射線照射処理又は放電処理の何れかの処理により、処理前後の質量減少率を１質量％以上９０質量％以下となるまで処理し、処理後の炭素含有率を５質量％以上とした変性金属錯体、及び分子内に、含窒素芳香族複素環及びフェノール環を１つずつ有し、さらにフェノール環、チオフェノール環、および含窒素芳香族複素環からなる群から選ばれた構造を１つまたは２つ有する有機化合物を配位子とする単核錯体を、加熱処理、放射線照射処理又は放電処理の何れかの変性処理により、処理前後の質量減少率を１質量％以上９０質量％以下となるまで処理し、処理後の炭素含有率を５質量％以上とした変性金属錯体。
PCT/JP2008/054329 2007-03-09 2008-03-10 変性金属錯体及びその用途 WO2008111568A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA002680244A CA2680244A1 (en) 2007-03-09 2008-03-10 Modified metal complex and use thereof
US12/530,174 US8519131B2 (en) 2007-03-09 2008-03-10 Modified metal complex and use thereof
EP08721745.1A EP2133336B1 (en) 2007-03-09 2008-03-10 Modified metal complexes and use thereof

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007061009 2007-03-09
JP2007-061009 2007-03-09
JP2007084345 2007-03-28
JP2007-084345 2007-03-28
JP2007-205956 2007-08-07
JP2007205956 2007-08-07

Publications (1)

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WO2008111568A1 true WO2008111568A1 (ja) 2008-09-18

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PCT/JP2008/054329 WO2008111568A1 (ja) 2007-03-09 2008-03-10 変性金属錯体及びその用途

Country Status (5)

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US (1) US8519131B2 (ja)
EP (1) EP2133336B1 (ja)
KR (1) KR20090130018A (ja)
CA (1) CA2680244A1 (ja)
WO (1) WO2008111568A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009084283A1 (ja) * 2007-12-28 2009-07-09 Sumitomo Chemical Company, Limited 環状化合物、その金属錯体及び変性金属錯体
WO2010095765A1 (ja) * 2009-02-23 2010-08-26 住友化学株式会社 環状化合物
WO2012036185A1 (ja) * 2010-09-17 2012-03-22 住友化学株式会社 金属錯体、その変性物及びそれに有用な化合物

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5396031B2 (ja) * 2007-03-09 2014-01-22 住友化学株式会社 金属錯体
WO2011099493A1 (ja) * 2010-02-10 2011-08-18 昭和電工株式会社 燃料電池用電極触媒の製造方法、遷移金属炭窒酸化物の製造方法、燃料電池用電極触媒およびその用途
US10044045B2 (en) * 2011-08-09 2018-08-07 Showa Denko K.K. Process for producing a fuel cell electrode catalyst, fuel cell electrode catalyst and use thereof
US10837949B1 (en) * 2012-03-22 2020-11-17 Piers Richard Warburton Peracetic acid sensor with filter to remove hydrogen peroxide
US9409125B2 (en) 2013-03-29 2016-08-09 The University Of Kentucky Research Foundation Method of increasing mass transfer rate of acid gas scrubbing solvents
US9468883B2 (en) 2013-03-29 2016-10-18 The University Of Kentucky Research Foundation Solvent and method for removal of an acid gas from a fluid stream
US9266102B2 (en) 2013-03-29 2016-02-23 The University Of Kentucky Research Foundation Catalysts and methods of increasing mass transfer rate of acid gas scrubbing solvents

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006035186A (ja) * 2004-07-30 2006-02-09 Toyota Central Res & Dev Lab Inc 電極触媒体及びその製造方法
JP2007061009A (ja) 2005-08-31 2007-03-15 Riken Vitamin Co Ltd 乳成分含有飲料
JP2007084345A (ja) 2006-12-27 2007-04-05 Duplo Seiko Corp 画像形成装置
JP2007205956A (ja) 2006-02-03 2007-08-16 Raito Kogyo Co Ltd 内部検査装置
WO2007091616A1 (ja) * 2006-02-08 2007-08-16 Sumitomo Chemical Company, Limited 金属錯体及びその用途

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008072758A1 (ja) 2006-12-11 2008-06-19 Sumitomo Chemical Company, Limited 金属錯体及びその用途
CA2680251A1 (en) 2007-03-09 2008-09-18 Sumitomo Chemical Company, Limited Membrane-electrode assembly and fuel battery using the same
WO2008111569A1 (ja) 2007-03-09 2008-09-18 National Institute Of Advanced Industrial Science And Technology 燃料電池用電極触媒
JP5396031B2 (ja) 2007-03-09 2014-01-22 住友化学株式会社 金属錯体
JP5422159B2 (ja) 2007-12-28 2014-02-19 住友化学株式会社 環状化合物、その金属錯体及び変性金属錯体

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006035186A (ja) * 2004-07-30 2006-02-09 Toyota Central Res & Dev Lab Inc 電極触媒体及びその製造方法
JP2007061009A (ja) 2005-08-31 2007-03-15 Riken Vitamin Co Ltd 乳成分含有飲料
JP2007205956A (ja) 2006-02-03 2007-08-16 Raito Kogyo Co Ltd 内部検査装置
WO2007091616A1 (ja) * 2006-02-08 2007-08-16 Sumitomo Chemical Company, Limited 金属錯体及びその用途
JP2007084345A (ja) 2006-12-27 2007-04-05 Duplo Seiko Corp 画像形成装置

Non-Patent Citations (24)

* Cited by examiner, † Cited by third party
Title
"Base of Carbonization Engineering", 1982, OHMSHA, LTD.
"New Applications of Conducting Polymers", CMC PUBLISHING CO., LTD.
A CHEMISTRY, EUROPEAN JOURNAL, vol. 5, 1999, pages 1460
ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 42, 2003, pages 6008
AUSTRALIAN JOURNAL OF CHEMISTRY, vol. 23, 1970, pages 2225
BULLETIN OF CHEMICAL SOCIETY OF JAPAN, vol. 68, 1995, pages 1105
CHEMICAL COMMUNICATION, 2005, pages 3385
IWANAMI: "Physical and Chemical Science Dictionary", 1988
KITAGAWA S. ET AL.: "Functional Porous Coordination Polymers", ANGEWANDTE CHEMIE, vol. 43, no. 18, 2004, pages 2334 - 2375, XP002456418 *
LAM F. ET AL.: "Synthesis of acyclic dinucleating phenanthroline-pyridine and phenanthroline-phosphine ligands", TETRAHEDRON LETTERS, vol. 36, no. 35, 1995, pages 6261 - 6262, XP004027364 *
LAM F. ET AL.: "Synthesis of dinucleating phenanthroline-based ligands", TETRAHEDRON, vol. 55, no. 28, 1999, pages 8377 - 8384, XP004170003 *
LWANAMI: "Physical and Chemical Science Dictionary", 1988
M. D. GODBOLE ET AL., EUROPIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, pages 305
NIKKAN KOGYO SHIMBUN: "Adhesion Society of Japan", 19 December 2003, article "Chemistry of Surface Analysis, Reformation"
OKADA T. ET AL.: "A Comparative Study of Organic Cobalt Complex Catalysts for Oxygen Reduction in Polymer Electrolyte Fuel Cells", JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, vol. 9, no. 4, 1999, pages 199 - 219, XP002384120 *
RYOGO KUBO ET AL.: "Encyclopedia of Physics and Chemistry 4th ed.", 10 January 1991, LWANAMI SHOTEN, pages: 966
See also references of EP2133336A4
SHADAN HOJIN NIPPON KAGAKU GAKKAI: "Kagaku Sosetsu No. 34 Sokubai Sekkei", 1982, JAPAN SCIENTIFIC SOCIETIES PRESS, pages: 176 - 189, XP008118104 *
SHINICHI YOSHIMURA: "Conductive Polymer", KYORITSU SHUPPAN CO., LTD
SUSUMU KITAGAWA; RYO KITAURA; SHIN-ICHIRO NORO, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 43, 2004, pages 2334
TATSUHIRO OKADA, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, vol. 9, 1999, pages 199
TETRAHEDRON, vol. 55, 1999, pages 8377
TETRAHEDRON., vol. 55, 1999, pages 8377
Z. LIU; F. C. ANSON, INORGANIC CHEMISTRY, vol. 40, 2001, pages 1329

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009084283A1 (ja) * 2007-12-28 2009-07-09 Sumitomo Chemical Company, Limited 環状化合物、その金属錯体及び変性金属錯体
US8546291B2 (en) 2007-12-28 2013-10-01 Sumitomo Chemical Company, Limited Cyclic compound, its metal complex and modified metal complex
US9236613B2 (en) 2007-12-28 2016-01-12 Sumitomo Chemical Company, Limited Cyclic compound, its metal complex and modified metal complex
WO2010095765A1 (ja) * 2009-02-23 2010-08-26 住友化学株式会社 環状化合物
JP2010215603A (ja) * 2009-02-23 2010-09-30 Sumitomo Chemical Co Ltd 環状化合物、その金属錯体及び変性金属錯体
CN102325772A (zh) * 2009-02-23 2012-01-18 住友化学株式会社 环状化合物
WO2012036185A1 (ja) * 2010-09-17 2012-03-22 住友化学株式会社 金属錯体、その変性物及びそれに有用な化合物
JP2012082190A (ja) * 2010-09-17 2012-04-26 Sumitomo Chemical Co Ltd 金属錯体、その変性物及びそれに有用な化合物
US9130233B2 (en) 2010-09-17 2015-09-08 Sumitomo Chemical Company, Limited Metal complex, modified compound thereof and useful compound thereof

Also Published As

Publication number Publication date
EP2133336A1 (en) 2009-12-16
EP2133336B1 (en) 2014-05-07
US20100105909A1 (en) 2010-04-29
US8519131B2 (en) 2013-08-27
KR20090130018A (ko) 2009-12-17
EP2133336A4 (en) 2010-10-13
CA2680244A1 (en) 2008-09-18

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