WO2008108346A1 - Water-based polyurethane resin composition and coating composition comprising the same - Google Patents

Water-based polyurethane resin composition and coating composition comprising the same Download PDF

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Publication number
WO2008108346A1
WO2008108346A1 PCT/JP2008/053795 JP2008053795W WO2008108346A1 WO 2008108346 A1 WO2008108346 A1 WO 2008108346A1 JP 2008053795 W JP2008053795 W JP 2008053795W WO 2008108346 A1 WO2008108346 A1 WO 2008108346A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyurethane resin
composition
water
ingredient
crosslinking agent
Prior art date
Application number
PCT/JP2008/053795
Other languages
French (fr)
Japanese (ja)
Inventor
Takaki Jono
Naotaka Izumi
Iku Oki
Mitsuru Chiba
Original Assignee
Nippon Polyurethane Industry Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Polyurethane Industry Co., Ltd. filed Critical Nippon Polyurethane Industry Co., Ltd.
Priority to CN200880006932XA priority Critical patent/CN101627068B/en
Priority to JP2009502580A priority patent/JPWO2008108346A1/en
Priority to KR1020097017262A priority patent/KR101159151B1/en
Publication of WO2008108346A1 publication Critical patent/WO2008108346A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/36Hydroxylated esters of higher fatty acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6659Compounds of group C08G18/42 with compounds of group C08G18/34
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
    • C08G18/7818Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A two-pack type composition which comprises a water-based polyurethane resin coating composition, an internal crosslinking agent, and an external crosslinking agent and which gives a coating film having a higher hardness. The composition gives a coating film improved in gloss even when the external crosslinking agent has been diluted with a high-boiling solvent in order to heighten the mixability of the external crosslinking agent with a main-ingredient emulsion. The two-pack type water-based polyurethane resin composition is characterized by comprising: an ingredient (A) which is a water-compatible polyurethane resin obtained by reacting a diisocyanate compound (a) with a fatty acid having an active-hydrogen group (b) and with a polyol compound (c) to obtain a urethane prepolymer, incorporating a polyfunctional polyisocyanate compound and a succinate type sulfonic acid salt into the prepolymer, neutralizing the mixture, and then subject it to a chain extension reaction; and an ingredient (B) which includes a polyfunctional polyisocyanate compound dispersible in the ingredient (A).
PCT/JP2008/053795 2007-03-02 2008-03-03 Water-based polyurethane resin composition and coating composition comprising the same WO2008108346A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN200880006932XA CN101627068B (en) 2007-03-02 2008-03-03 Water-based polyurethane resin composition and coating composition comprising the same
JP2009502580A JPWO2008108346A1 (en) 2007-03-02 2008-03-03 Water-based polyurethane resin composition and coating composition using the same
KR1020097017262A KR101159151B1 (en) 2007-03-02 2008-03-03 Water-based polyurethane resin composition and coating composition comprising the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-053526 2007-03-02
JP2007053526 2007-03-02

Publications (1)

Publication Number Publication Date
WO2008108346A1 true WO2008108346A1 (en) 2008-09-12

Family

ID=39738224

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/053795 WO2008108346A1 (en) 2007-03-02 2008-03-03 Water-based polyurethane resin composition and coating composition comprising the same

Country Status (4)

Country Link
JP (1) JPWO2008108346A1 (en)
KR (1) KR101159151B1 (en)
CN (1) CN101627068B (en)
WO (1) WO2008108346A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013155335A (en) * 2012-01-31 2013-08-15 Dai Ichi Kogyo Seiyaku Co Ltd Method for producing aqueous polyurethane resin composition
JP6076478B2 (en) * 2013-06-27 2017-02-08 旭化成株式会社 Polyisocyanate composition and production method thereof, block polyisocyanate composition and production method thereof, resin composition, curable resin composition, and cured product
CN110776817A (en) * 2019-10-29 2020-02-11 河北晨阳工贸集团有限公司 Water-based color-changing heat-insulating glass paint and preparation method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6669742B2 (en) * 2015-06-09 2020-03-18 旭化成株式会社 Aqueous resin composition for touch panel, transfer film and cured film laminate, method for producing resin pattern, and touch panel display device
KR101714740B1 (en) * 2016-05-17 2017-03-09 주식회사 노루알앤씨 Aqueous peelable paint composition including polyurethane water-dispersion
KR102109975B1 (en) 2018-11-16 2020-05-28 (주)진주에스이씨 Water-base Urethane resin emulsion composion for Pollution prevention
KR102172886B1 (en) * 2019-06-07 2020-11-02 애경특수도료 주식회사 Paint against scattering glass
KR102420431B1 (en) 2022-03-17 2022-07-14 한서포리머주식회사 Water-soluble top-coating composition of two-component type

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08259884A (en) * 1995-03-22 1996-10-08 Mitsubishi Chem Corp Aqueous polyurethane resin coating material
JP2003183347A (en) * 2001-10-26 2003-07-03 Solutia Austria Gmbh High molecular weight polyurethane dispersion
JP2003292565A (en) * 2002-01-29 2003-10-15 Achilles Corp Aqueous polyurethane resin emulsion for two-pack water-based urethane resin adhesive and the adhesive containing the emulsion
JP2005194375A (en) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd Preparation method of polyurethane emulsion for aqueous one-component coating agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08259884A (en) * 1995-03-22 1996-10-08 Mitsubishi Chem Corp Aqueous polyurethane resin coating material
JP2003183347A (en) * 2001-10-26 2003-07-03 Solutia Austria Gmbh High molecular weight polyurethane dispersion
JP2003292565A (en) * 2002-01-29 2003-10-15 Achilles Corp Aqueous polyurethane resin emulsion for two-pack water-based urethane resin adhesive and the adhesive containing the emulsion
JP2005194375A (en) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd Preparation method of polyurethane emulsion for aqueous one-component coating agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013155335A (en) * 2012-01-31 2013-08-15 Dai Ichi Kogyo Seiyaku Co Ltd Method for producing aqueous polyurethane resin composition
JP6076478B2 (en) * 2013-06-27 2017-02-08 旭化成株式会社 Polyisocyanate composition and production method thereof, block polyisocyanate composition and production method thereof, resin composition, curable resin composition, and cured product
CN110776817A (en) * 2019-10-29 2020-02-11 河北晨阳工贸集团有限公司 Water-based color-changing heat-insulating glass paint and preparation method thereof

Also Published As

Publication number Publication date
JPWO2008108346A1 (en) 2010-06-17
CN101627068B (en) 2012-05-23
CN101627068A (en) 2010-01-13
KR20090101385A (en) 2009-09-25
KR101159151B1 (en) 2012-06-22

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