WO2008079031A2 - Dairy product and process - Google Patents
Dairy product and process Download PDFInfo
- Publication number
- WO2008079031A2 WO2008079031A2 PCT/NZ2007/000390 NZ2007000390W WO2008079031A2 WO 2008079031 A2 WO2008079031 A2 WO 2008079031A2 NZ 2007000390 W NZ2007000390 W NZ 2007000390W WO 2008079031 A2 WO2008079031 A2 WO 2008079031A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mpc
- calcium
- ions
- mpi
- phosphate
- Prior art date
Links
- 235000013365 dairy product Nutrition 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims description 47
- 230000008569 process Effects 0.000 title claims description 14
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 36
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 36
- 235000021239 milk protein Nutrition 0.000 claims abstract description 35
- 235000013351 cheese Nutrition 0.000 claims abstract description 30
- 235000014059 processed cheese Nutrition 0.000 claims abstract description 27
- 238000005341 cation exchange Methods 0.000 claims abstract description 22
- 238000005349 anion exchange Methods 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 235000013618 yogurt Nutrition 0.000 claims abstract description 17
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 11
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 11
- 238000011026 diafiltration Methods 0.000 claims abstract description 8
- 238000000909 electrodialysis Methods 0.000 claims abstract description 6
- 239000011575 calcium Substances 0.000 claims description 60
- 229910052791 calcium Inorganic materials 0.000 claims description 54
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 54
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 51
- 229910019142 PO4 Inorganic materials 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 33
- 239000010452 phosphate Substances 0.000 claims description 31
- 150000002500 ions Chemical class 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 23
- 239000000725 suspension Substances 0.000 claims description 23
- 239000004615 ingredient Substances 0.000 claims description 20
- 235000018102 proteins Nutrition 0.000 claims description 20
- 102000004169 proteins and genes Human genes 0.000 claims description 20
- 108090000623 proteins and genes Proteins 0.000 claims description 20
- 238000010411 cooking Methods 0.000 claims description 19
- 239000005018 casein Substances 0.000 claims description 18
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 18
- 235000021240 caseins Nutrition 0.000 claims description 18
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- 150000001768 cations Chemical class 0.000 claims description 15
- 239000003925 fat Substances 0.000 claims description 15
- 235000020183 skimmed milk Nutrition 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 14
- 108010046377 Whey Proteins Proteins 0.000 claims description 13
- 150000001450 anions Chemical class 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910001424 calcium ion Inorganic materials 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 235000013336 milk Nutrition 0.000 claims description 12
- 239000008267 milk Substances 0.000 claims description 12
- 210000004080 milk Anatomy 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 10
- 102000007544 Whey Proteins Human genes 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000007900 aqueous suspension Substances 0.000 claims description 8
- 238000005342 ion exchange Methods 0.000 claims description 8
- 239000005862 Whey Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000000796 flavoring agent Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 235000020121 low-fat milk Nutrition 0.000 claims description 3
- 230000020477 pH reduction Effects 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 230000001112 coagulating effect Effects 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 235000021185 dessert Nutrition 0.000 claims 1
- 239000012141 concentrate Substances 0.000 abstract description 18
- 235000011850 desserts Nutrition 0.000 abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
- 235000019197 fats Nutrition 0.000 description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 239000000499 gel Substances 0.000 description 9
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 8
- 239000008101 lactose Substances 0.000 description 8
- 235000021119 whey protein Nutrition 0.000 description 8
- 101100238326 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) SPO21 gene Proteins 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 235000004213 low-fat Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 229940108461 rennet Drugs 0.000 description 4
- 108010058314 rennet Proteins 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003729 cation exchange resin Substances 0.000 description 3
- 235000020809 full-fat yoghurt Nutrition 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- WPWUFUBLGADILS-WDSKDSINSA-N Ala-Pro Chemical compound C[C@H](N)C(=O)N1CCC[C@H]1C(O)=O WPWUFUBLGADILS-WDSKDSINSA-N 0.000 description 2
- 108010087924 alanylproline Proteins 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 102100021935 C-C motif chemokine 26 Human genes 0.000 description 1
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 101000897493 Homo sapiens C-C motif chemokine 26 Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 235000021243 milk fat Nutrition 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000008476 powdered milk Nutrition 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/14—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment
- A23C9/146—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by ion-exchange
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
- A23C19/068—Particular types of cheese
- A23C19/08—Process cheese preparations; Making thereof, e.g. melting, emulsifying, sterilizing
- A23C19/082—Adding substances to the curd before or during melting; Melting salts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/12—Fermented milk preparations; Treatment using microorganisms or enzymes
- A23C9/13—Fermented milk preparations; Treatment using microorganisms or enzymes using additives
- A23C9/1307—Milk products or derivatives; Fruit or vegetable juices; Sugars, sugar alcohols, sweeteners; Oligosaccharides; Organic acids or salts thereof or acidifying agents; Flavours, dyes or pigments; Inert or aerosol gases; Carbonation methods
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/14—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment
- A23C9/142—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by dialysis, reverse osmosis or ultrafiltration
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/14—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment
- A23C9/144—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by electrical means, e.g. electrodialysis
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J1/00—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites
- A23J1/20—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites from milk, e.g. casein; from whey
- A23J1/202—Casein or caseinates
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J1/00—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites
- A23J1/20—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites from milk, e.g. casein; from whey
- A23J1/205—Obtaining protein compositions for foodstuffs; Bulk opening of eggs and separation of yolks from whites from milk, e.g. casein; from whey from whey, e.g. lactalbumine
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- This invention relates to milk protein products, processes for their preparation and use, for example in manufacture of processed cheese, yoghurts, spreads, cheese and dairy desserts.
- Milk protein concentrates (MPCs) and milk protein isolates are milk fractions that are enriched in protein relative to lactose. These products differ from milk concentrates in that they are high in protein and low in lactose and usually low in fat. They differ from skim milk concentrates in that they are high in protein and low in lactose.
- MPCs and MPIs are used in cheese manufacture as cheese milk extenders. By addition of these to increase the protein concentration of milk used in the manufacture of cheese, cheese making can be made more consistent and more efficient. Dried MPC is particularly useful for boosting the protein content of the cheese milk and increases the yield of curds and thus cheese for the volume of cheese milk provided.
- MPCs and MPIs can be used in processed cheese but are limited by solubility and reactivity.
- WO01/41578 discloses dried milk protein concentrates that are calcium-depleted. These have improved properties. They show greater solubility in water at ambient temperatures and a reduction in the fonnation of "nuggets" in the cheese relative to that in cheese where standard MPC was used in cheese manufacture. Nuggets are thin protein gels of a different colour in cheese.
- the calcium-depleted MPCs and MPIs can be used in processed cheese manufacture and have improved solubility characteristics. However, it would be desirable to use an ingredient that provides further improved texture. It is an object of the invention to provide an ingredient for use in preparing a milk protein gel having a high protein content and/or to provide a method for preparing the milk protein gels and/or to provide the public with a useful choice.
- the inventors disclose a method of altering the texture of milk protein gels, including processed cheese and processed cheese-like products, spreads, yoghurt and desserts by the use of an ingredient prepared as a dairy concentrate and the manipulation of the calcium and phosphate content.
- the manufacture of protein products such as milk protein concentrates (MPCs), and the like, is made using long production runs, thereby giving the possibility of well controlled conditions to manipulate the mineral content.
- MPCs milk protein concentrates
- the applicants have found that lowering of calcium and phosphate in the protein ingredient confers a modified texture to the processed cheese product.
- the ingredient may be either liquid or dried.
- the steps to lower calcium and phosphate are preferably performed before concentration of the protein stream immediately prior to drying (preferably spray drying). .
- the invention provides a method for producing a dairy product comprising:
- the solution/suspension is subjected to (in any order) (i) cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, and one or more processes selected from:
- process (i) and one or more processes of (ii)-(iv) are carried out on at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and phosphate ions.
- the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
- the invention provides a method for producing a dairy product comprising:
- the- solution/suspension is subjected to (in any order) (i) cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, and one or more processes selected from:
- process (i) and one or more processes of (ii)-(iv) are carried out on at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and phosphate ions.
- the invention provides a method for preparing a dried MPC or MPI, product comprising:
- the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
- the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
- milk protein concentrate refers to a milk protein product in which more than 42%, preferably more than 50%, more preferably more than 55%, most preferably more than 70% of the solids-not-fat (SNF) is milk protein (by weight) and the weight ratio of casein to whey proteins is between about 95:5 and about 40:60, preferably between 90:10 and 60:40, more preferably between 90:10 and 70:30, most preferably that of milk.
- SNF solids-not-fat
- Such concentrates are known in the art.
- MPCs are frequently described with the % dry matter as milk protein being appended to "MPC".
- MPC70 is an MPC with 70% of the dry matter as milk protein.
- MPCs are prepared by processes involving ultrafiltration either to prepare a stream enriched in casein or a stream enriched in whey protein or both. Streams may be blended to attain desired ratios of casein to whey protein.
- the milk protein concentrate may be prepared by blending a stream of skim milk with a stream of whey protein concentrate prepared by ultrafiltration, treating either the skim milk stream or the combined stream by cation exchange and at least one of anion exchange, ultrafiltration/diafiltraiton and electrodialysis and optionally concentrating or drying.
- milk protein concentrates are low in fat (up to 5% w/w total solids). Such concentrates can have more than 42%, preferably more than 50%, more preferably more than 55%, most preferably more than 70% of the dry matter is milk protein (by weight). However for some applications MPCs with up to 70% fat are desirable. Fat can be added to an ultrafiltered dairy stream in the desired proportions.
- milk protein concentrate also includes a corresponding blend of casein/ate and whey proteins.
- the term also includes milk protein concentrates that have been heated-treated to denature whey proteins (for example by the methods of PCT published application WO 2004/057971 and US 2006/0159804 both hereby incorporated by reference). - O -
- milk protein isolate refers to a milk protein composition comprising a substantially unaltered proportion of casein to whey proteins wherein the dry matter consists of more than 85% milk protein. Such isolates are known in the art.
- skim milk includes not only fresh skim milk but also reconstituted skim milk and skim milks of altered mineral composition an/or casein to whey ratios.
- phosphate ion is used broadly and includes ionic phosphate and colloidal inorganic phosphate unless the context requires otherwise.
- low fat milk solution means that the milk comprises less that 5% total solids as fat (by weight), preferably less than 0.5%.
- the resulting calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100%, preferably 20-100% removal of both ions is dried, preferably by spray drying.
- the liquid calcium and phosphate depleted MPC or MPI is mixed with another milk or milk protein concentrate solution while maintaining at 10-100%, preferably 10- 100%, preferably 20-100% depletion of both calcium ions and phosphate ions. For dried products this is generally carried out shortly before the drying step.
- the preferred cation exchangers are based on resins bearing strongly acidic groups, preferably sulphonate groups.
- a preferred strong acid cation exchange resin for use in this and other embodiments of the invention is IMAC HP 1 11 E manufactured by Rohm & Haas.
- This resin has a styrene divinylbenzene copolymer matrix.
- the functional groups are sulphonic acid groups that- can be obtained in the Na + form or alternatively converted to .the K + form.
- the use of the Na + or K + form or a mixture of both is preferred.
- Another preferred cation exchange resin is Amberlite SRlL, Rohm & Haas.
- One cation preferred for the use with sodium and/or potassium is magnesium.
- the anion exchanger may be in the Cl or OH form.
- the anion exchanger bears weak basic groups e.g. primary, secondary or tertiary amines.
- a preferred ion exchanger is Al 03 S, Purolite.
- the ion exchange steps are preferably carried out at 4-12°C, but may be carried out at temperatures as high as 50°C.
- the skim milk or MPC or MPI applied to the cation exchanger and anion exchanger preferably has a pH in the range 5.6-7.0, more preferably 5.6-6.2. Once the MPC or MPI has passed through the column, its pH changes. If it increases above 7.0, it will generally be adjusted to about 6.4-7.0 to make it more palatable.
- One embodiment of the invention provides a method for preparing a dried MPC or MPI comprising a method of the invention in which the pH of the ion-exchanged material is adjusted to a pre-selected point in the range 5.0-8.0, preferably 6.2-7.2, more preferably 6.4-7.0, most preferably 6.6-6.8 prior to the spray drying step.
- This ingredient is particularly advantageous for providing firmness in dairy gels as the pH can be selected so that on cooking the properties of the material can be optimised for its use as an ingredient.
- the MPC or MPI at the desired pH is subjected to a cooking step.
- the pH is preferably adjusted to a pH in the range 4.5-7.5, preferably 4.5-6.2, more preferably 4.8-5.9 before drying.
- the adjusted pH can be chosen to suit particular requirements of products in which the ingredient is to be used.
- Preferred cooking temperatures are in the range 50 0 C and up to the boiling point of the mixture, typically 70 0 C-IOO 0 C.
- the preferred cooking time varies according to temperature used and the nature of the starting material. Generally times in the range 1 second to 30 minutes are used.
- Preferred cooking times may be chosen on the basis that they are sufficient for modification of the casein whey interaction.
- Casein whey interactions provided by the cooking step provide increased strength of the texture of products produced from the casein whey mixture relative to uncooked controls or controls cooked at a pH of approximately 5.7.
- any suitable agent may be used to make the pH adjustments.
- the pH adjustment either before or after the cooking step is carried out by direct addition of an alkali or acidulant.
- Preferred agents may be selected as allowed by Codex Alimentarius Standard 221-2001 (Codex group standard for unripened cheese including fresh cheese). This may be found at http://www.codexalimentarius.net/standard list.asp or its updates.
- the liquid calcium and phosphate depleted MPC or MPI obtained may be dried by standard techniques including thermal falling film evaporation and spray drying. Drying may be preceded : by dewatering.
- the dried MPC and MPI products have the property of good stability on storage. This can be demonstrated by observation of the retention of good cold solubility on storage.
- the invention provides a 10-100%, preferably 20-100% calcium- and phosphate-depleted MPI or MPC powder preferably having at least 70% by weight of protein. Throughout the range of calcium and phosphate depletion the powders are useful for preparing nutritional drinks and have the advantage of superior solubility relative to MPC or MPI powders that have no such calcium and phosphate depletion.
- the MPC or MPI powder has 30-100%, preferably 50-100% depletion of calcium wherein the calcium is substituted by sodium and/or potassium.
- the MPC or MPI has 30-100% preferably 50-100% depletion of phosphate. These preferred percentage depletions are also preferred in the concentrates and methods of the invention.
- the invention provides a method for preparing a dairy gel comprising mixing ingredients including milk proteins and water and optionally fats and emulsifiers with heating to 70- 100 0 C and/or acidification to pH 4.5-6.0 to produce a gel, wherein at least a portion of the milk proteins are added as a calcium- and phosphate-depleted MPC or MPI.
- a particularly preferred method is where the calcium- or phosphate-depleted MPC or MPI is 10-100%, preferably 20-100% depleted in both ions, particularly by cation exchange and at least one of anion exchange, ultrafiltration/diafiltration and electr ⁇ dialysis as described above.
- Dairy gels that may be produced by these methods include cheese, processed cheese, cheese spreads, yoghurts, and imitation cheese.
- the invention provides a method for the manufacture of processed cheese, yoghurts, spreads, cheese and dairy desserts using calcium- and phosphate-depleted MPC or MPI prepared by the method of these aspects of the invention.
- the advantages of higher protein concentration in cheese manufacture are obtained but with increase in firmness without texture defects associated with protein insolubility.
- the use of the calcium- and phosphate- depleted MPC or MPI prepared by the method allows reduction or avoiding of the use of . emulsifying salts. ⁇
- a method for preparing a processed cheese comprising cooking cheese or another gelled casein rich source together with other optional processed cheese ingredients and a calcium- and phosphate-depleted MPC, preferably prepared by a method of the invention.
- a method for preparing a cheese spread comprising cooking a mixture comprising an oil, a gelled casein source and water with optional flavourings and a calcium- and phosphate-depleted MPC with 10-100% depletion of both ions.
- a method of cheese manufacture comprising including in the cheese milk an MPC or MPI, preferably dried or in concentrated liquid form, treating the resulting mixture with one or more coagulating enzymes to produce a curd and processing the curd, wherein the MPC or MPI is a calcium and phosphate-depleted MPC or MPI with 10-100% depletion of both ions.
- the term "comprising” as used in this specification means “consisting at least in part of, that is to say when interpreting statements in this specification which include that term, the features, prefaced by that term in each statement, all need to be present but other features can also be present.
- Figure 1 shows stirred yoghurt viscosities (in mPa.s at 50/s) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)).
- Figure 2 shows set yoghurt consistency (texture area g.s) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)).
- Figure 3 shows set yoghurt fracture force (peak g) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)).
- MPC milk protein concentrate, 70% milk protein, Fonterra 200 g was mixed with 1800 mL of water at 50°C, chilled to 4 0 C and adjusted to pH 5.95 with 10% HCl.
- the pH adjusted solution was passed twice through a one litre bed of cation exchange resin (Amberlite SRlL Na form, Rohm & Haas) to fully substitute sodium for calcium as the counterion associated with the protein in solution.
- the breakthrough (calcium depleted, sodium form of the proteinate) was recovered and cooled to below 10°C.
- 2 L of the calcium-depleted solution was passed through 2 L of anion exchange resin (A103S, Purolite, chloride form). A temperature of less than 1O 0 C was maintained throughout the cation and ion exchange steps.
- the resulting double ion exchanged product was collected and freeze-dried.
- the product comprised protein 72.36%, moisture 1.36%, calcium 359 mg/kg, phosphate 185 mmol/kg, total phosphorus 10100 mg/kg.
- the model processed cheeses were prepared using an RVA mixture cooker (Newport Scientific,
- rennet • casein (ALAREN 799, 90 mesh, Fonterra, New Zealand) was hydrated in salt solution (trisodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and sodium chloride (Pacific salt, Wales, New Zealand) and water) in the aluminium cup.
- salt solution trisodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and sodium chloride (Pacific salt, Wales, New Zealand) and water
- ALACEN 392 and MPC and lactose if used
- the mixture was cooked using the following programme:
- the model processed cheeses were prepared using RVA mixture cooker (Newport Scientific, Warriewood, NSW 3 Australia). The recipe is as detailed in Table 1.
- the required amount of rennet casein (ALAREN 799, 90 mesh, Fonterra, New Zealand) was hydrated in salt solution (trisodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), part of the citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and sodium chloride (Pacific salt, Cnristchurch, New Zealand) and water).
- the predetermined amount of citric acid used at this stage is shown in Table 2.
- the mixture was hydrated for 5 min. ALACEN 392 and MPC (and lactose if used) were added and the mixture was stirred. Oil was then added and stirred in to the mixture.
- the mixture was cooked using the programme detailed in the sample preparation for cook pH 5.7. After 10 min cook time, the remaining acid (Table 2) was added. Cooking resumed for another 2 min. The total cooking time was 12 min.
- the molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C. The final pH of the processed cheese was 6.7.
- weight of water includes allowance of 1 g for evaporation
- TSC Trisodium citrate dihydrate
- TSC and sodium chloride were added to the water in a plastic pottle.
- the salts were allowed to dissolve before adding the MPC.
- the MPC was mixed into the solution and stood for 40 minutes. The remaining ingredients were added and mixed vigorously by hand. The blended material was then transferred to a canister for cooking in the RVA.
- Cooking profile Temperature - the initial temperature was 25 0 C. This was raised to 85 0 C over 4 minutes and then held at 85 0 C for 6 minutes. Total cook time was thus 10 minutes.
- Speed - the initial speed was 0 rpm. This was raised stepwise to 800 rpm over 3 minutes and then held at 800 rpm for 7 minutes.
- the cooked processed cheese was poured onto polypropylene film. A second layer of film was placed on top of the molten material. A heavy rolling pin was used to flatten the processed cheese into a 2 mm thick slice, which was then cooled rapidly by placing it on a pre-cooled aluminium tray in a 4 0 C chiller. Observations:
- MPC70 (ALAPRO 4700) formed a pale yellow paste during hydration and gave a slice that appeared well emulsified, homogeneous but slightly soft.
- Both low and full fat yoghurt formulations were prepared with a total protein concentration of 4.6%.
- the test ingredient provided 1.2% protein.
- Total solids were standardised with lactose. The pH was adjusted to within pH 6.6-6.8 (if necessary)
- FF Full fat
- test ingredients were calcium and phosphate depleted MPC85 (2-IX MPC) or MPC85 (MPC4850) or Ca-deplete MPC 4862. SMP was used in the SMP control. '
- Yoghurts were prepared by the conventional method from the yoghurt milk formulations using addition of a standard starter culture.
- the material subjected to calcium depletion can show variations in protein concentration and pH
- the methods of calcium phosphate depletion can be varied
- the percentage calcium and phosphate depletion and drying procedures can also be varied.
Abstract
The invention relates to a calcium- and phosphate-depleted milk protein concentrate or isolate. This may be prepared by use of cation exchange together with one or more of anion exchange, ultrafiltration/diafiltration and electrodialysis. The products are useful in the manufacture of processed cheese, yoghurts, spreads, cheese, dairy desserts and other milk protein products.
Description
DAIRY PRODUCT AND PROCESS
Technical Field
This invention relates to milk protein products, processes for their preparation and use, for example in manufacture of processed cheese, yoghurts, spreads, cheese and dairy desserts.
Background Art
Milk protein concentrates (MPCs) and milk protein isolates are milk fractions that are enriched in protein relative to lactose. These products differ from milk concentrates in that they are high in protein and low in lactose and usually low in fat. They differ from skim milk concentrates in that they are high in protein and low in lactose.
One use for MPCs and MPIs is in cheese manufacture as cheese milk extenders. By addition of these to increase the protein concentration of milk used in the manufacture of cheese, cheese making can be made more consistent and more efficient. Dried MPC is particularly useful for boosting the protein content of the cheese milk and increases the yield of curds and thus cheese for the volume of cheese milk provided.
MPCs and MPIs can be used in processed cheese but are limited by solubility and reactivity.
WO01/41578 discloses dried milk protein concentrates that are calcium-depleted. These have improved properties. They show greater solubility in water at ambient temperatures and a reduction in the fonnation of "nuggets" in the cheese relative to that in cheese where standard MPC was used in cheese manufacture. Nuggets are thin protein gels of a different colour in cheese.
The calcium-depleted MPCs and MPIs can be used in processed cheese manufacture and have improved solubility characteristics. However, it would be desirable to use an ingredient that provides further improved texture.
It is an object of the invention to provide an ingredient for use in preparing a milk protein gel having a high protein content and/or to provide a method for preparing the milk protein gels and/or to provide the public with a useful choice.
Disclosure of the Invention
The inventors disclose a method of altering the texture of milk protein gels, including processed cheese and processed cheese-like products, spreads, yoghurt and desserts by the use of an ingredient prepared as a dairy concentrate and the manipulation of the calcium and phosphate content.
The manufacture of protein products such as milk protein concentrates (MPCs), and the like, is made using long production runs, thereby giving the possibility of well controlled conditions to manipulate the mineral content. The applicants have found that lowering of calcium and phosphate in the protein ingredient confers a modified texture to the processed cheese product. The ingredient may be either liquid or dried. When the ingredient is a dried ingredient, the steps to lower calcium and phosphate are preferably performed before concentration of the protein stream immediately prior to drying (preferably spray drying). .
In one aspect the invention provides a method for producing a dairy product comprising:
(a) providing a skim milk or an MPI or MPC, in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10- 100%, preferably 20- 100% removal of both ions wherein either:
(1) the solution/suspension is subjected to (in any order) (i) cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, and one or more processes selected from:
(ii) anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions, (iii) ultrafiltration and/or diafiltration, and
(iv) electrodialysis, or
(2) process (i) and one or more processes of (ii)-(iv) are carried out on at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and
phosphate ions.
In one embodiment the invention provides a method for producing a dairy product comprising:
(a) providing an MPI or MPC, in aqueous solution/suspension (b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having
10-100%, preferably 20-100% removal of both ions by carrying out both cation exchange and anion exchange (in either order) wherein either:
(1) the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
(2) the two ion exchange steps are carried out on separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20- 100% depletion of both calcium and phosphate ions
(c) drying to prepare a dried product.
In another aspect the invention provides a method for producing a dairy product comprising:
(a) providing a skim milk or an MPI or MPC, preferably having at least 70% dry matter as milk protein in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100%, preferably 20-100% removal of both ions by carrying out (in any order) wherein either:
(1) the- solution/suspension is subjected to (in any order) (i) cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, and one or more processes selected from:
(ii) anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions, (iii) ultrafiltration and/or diafiltration, and
(iv) electrodialysis, or
(2) process (i) and one or more processes of (ii)-(iv) are carried out on at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and
phosphate ions.
In a preferred embodiment, the invention provides a method for preparing a dried MPC or MPI, product comprising:
(a) providing an MPI or MPC, preferably having at least 70% dry matter as milk protein, in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100%, preferably 20-100% removal of both ions by carrying out cation exchange and anion exchange (in either order) wherein either:
(1) the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
(2) the two ion exchange steps are carried out on separate samples that are combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and phosphate ions
(c) drying to prepare a dried product.
In a further preferred embodiment the invention provides a method of preparing a dried MPC or MPI comprising:
(a) providing a low fat milk solution, for example skim milk, as a solution/suspension.
(b) preparing a calcium and phosphate-depleted solution/suspension having 10-100%, preferably 20-100% removal of both ions by carrying out both cation exchange and anion exchange (in either order) wherein either:
(1) the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
(2) the two ion exchange steps are carried out on separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20- 100% depletion of both calcium and phosphate ions
(c) concentrating the solution obtained by ultrafiltration, optionally with diafiltration, to form an MPI or MPC having preferably at least 70% dry weight as protein; and (optionally)
(d) drying to prepare a dried product.
Definitions
The term "milk protein concentrate" (MPC) refers to a milk protein product in which more than 42%, preferably more than 50%, more preferably more than 55%, most preferably more than 70% of the solids-not-fat (SNF) is milk protein (by weight) and the weight ratio of casein to whey proteins is between about 95:5 and about 40:60, preferably between 90:10 and 60:40, more preferably between 90:10 and 70:30, most preferably that of milk. Such concentrates are known in the art.
MPCs are frequently described with the % dry matter as milk protein being appended to "MPC". For example MPC70 is an MPC with 70% of the dry matter as milk protein.
Generally MPCs are prepared by processes involving ultrafiltration either to prepare a stream enriched in casein or a stream enriched in whey protein or both. Streams may be blended to attain desired ratios of casein to whey protein. In another embodiment, the milk protein concentrate may be prepared by blending a stream of skim milk with a stream of whey protein concentrate prepared by ultrafiltration, treating either the skim milk stream or the combined stream by cation exchange and at least one of anion exchange, ultrafiltration/diafiltraiton and electrodialysis and optionally concentrating or drying.
Generally milk protein concentrates are low in fat (up to 5% w/w total solids). Such concentrates can have more than 42%, preferably more than 50%, more preferably more than 55%, most preferably more than 70% of the dry matter is milk protein (by weight). However for some applications MPCs with up to 70% fat are desirable. Fat can be added to an ultrafiltered dairy stream in the desired proportions.
The term "milk protein concentrate" also includes a corresponding blend of casein/ate and whey proteins. The term also includes milk protein concentrates that have been heated-treated to denature whey proteins (for example by the methods of PCT published application WO 2004/057971 and US 2006/0159804 both hereby incorporated by reference).
- O -
The term "milk protein isolate" (MPI) refers to a milk protein composition comprising a substantially unaltered proportion of casein to whey proteins wherein the dry matter consists of more than 85% milk protein. Such isolates are known in the art.
The term "skim milk" includes not only fresh skim milk but also reconstituted skim milk and skim milks of altered mineral composition an/or casein to whey ratios.
The term "calcium ion" is used broadly and includes ionic calcium and colloidal calcium unless the context requires otherwise. ■ ■
The term "phosphate ion" is used broadly and includes ionic phosphate and colloidal inorganic phosphate unless the context requires otherwise.
The term "low fat milk solution" means that the milk comprises less that 5% total solids as fat (by weight), preferably less than 0.5%.
Preferred Embodiments and Advantages
In embodiments preferred for some applications the resulting calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100%, preferably 20-100% removal of both ions is dried, preferably by spray drying.
' In some embodiments, the liquid calcium and phosphate depleted MPC or MPI is mixed with another milk or milk protein concentrate solution while maintaining at 10-100%, preferably 10- 100%, preferably 20-100% depletion of both calcium ions and phosphate ions. For dried products this is generally carried out shortly before the drying step.
The preferred cation exchangers are based on resins bearing strongly acidic groups, preferably sulphonate groups.
A preferred strong acid cation exchange resin for use in this and other embodiments of the invention is IMAC HP 1 11 E manufactured by Rohm & Haas. This resin has a styrene divinylbenzene copolymer matrix. The functional groups are sulphonic acid groups that- can be
obtained in the Na+ form or alternatively converted to .the K+ form. The use of the Na+ or K+ form or a mixture of both is preferred. Another preferred cation exchange resin is Amberlite SRlL, Rohm & Haas.
By manipulating the pH and the choice of ions exchanged,, it is possible to vary the flavour of the product. For some circumstances it will be useful also to provide micronutrient cations in addition to sodium or potassium.
One cation preferred for the use with sodium and/or potassium is magnesium.
The anion exchanger may be in the Cl or OH form. Preferably, the anion exchanger bears weak basic groups e.g. primary, secondary or tertiary amines. A preferred ion exchanger is Al 03 S, Purolite.
In another preferred alternative cation-exchange and anion-exchange steps are carried out at the same time using a mixed bed of the two ion-exchange resins.
The ion exchange steps are preferably carried out at 4-12°C, but may be carried out at temperatures as high as 50°C.
The skim milk or MPC or MPI applied to the cation exchanger and anion exchanger preferably has a pH in the range 5.6-7.0, more preferably 5.6-6.2. Once the MPC or MPI has passed through the column, its pH changes. If it increases above 7.0, it will generally be adjusted to about 6.4-7.0 to make it more palatable.
One embodiment of the invention provides a method for preparing a dried MPC or MPI comprising a method of the invention in which the pH of the ion-exchanged material is adjusted to a pre-selected point in the range 5.0-8.0, preferably 6.2-7.2, more preferably 6.4-7.0, most preferably 6.6-6.8 prior to the spray drying step. This ingredient is particularly advantageous for providing firmness in dairy gels as the pH can be selected so that on cooking the properties of the material can be optimised for its use as an ingredient.
In a variation of the above embodiment, the MPC or MPI at the desired pH is subjected to a cooking step. Following cooking, the pH is preferably adjusted to a pH in the range 4.5-7.5,
preferably 4.5-6.2, more preferably 4.8-5.9 before drying. The adjusted pH can be chosen to suit particular requirements of products in which the ingredient is to be used.
Preferred cooking temperatures are in the range 500C and up to the boiling point of the mixture, typically 700C-IOO0C. The preferred cooking time varies according to temperature used and the nature of the starting material. Generally times in the range 1 second to 30 minutes are used.
Preferred cooking times may be chosen on the basis that they are sufficient for modification of the casein whey interaction. Casein whey interactions provided by the cooking step provide increased strength of the texture of products produced from the casein whey mixture relative to uncooked controls or controls cooked at a pH of approximately 5.7.
Any suitable agent may be used to make the pH adjustments. Preferably the pH adjustment either before or after the cooking step is carried out by direct addition of an alkali or acidulant. Preferred agents may be selected as allowed by Codex Alimentarius Standard 221-2001 (Codex group standard for unripened cheese including fresh cheese). This may be found at http://www.codexalimentarius.net/standard list.asp or its updates.
The liquid calcium and phosphate depleted MPC or MPI obtained may be dried by standard techniques including thermal falling film evaporation and spray drying. Drying may be preceded : by dewatering. The dried MPC and MPI products have the property of good stability on storage. This can be demonstrated by observation of the retention of good cold solubility on storage.
In another embodiment the invention provides a 10-100%, preferably 20-100% calcium- and phosphate-depleted MPI or MPC powder preferably having at least 70% by weight of protein. Throughout the range of calcium and phosphate depletion the powders are useful for preparing nutritional drinks and have the advantage of superior solubility relative to MPC or MPI powders that have no such calcium and phosphate depletion.
In a preferred form of this embodiment of the invention, the MPC or MPI powder has 30-100%, preferably 50-100% depletion of calcium wherein the calcium is substituted by sodium and/or potassium. In another preferred form of this embodiment the MPC or MPI has 30-100% preferably 50-100% depletion of phosphate. These preferred percentage depletions are also preferred in the concentrates and methods of the invention.
In another aspect, the invention provides a method for preparing a dairy gel comprising mixing ingredients including milk proteins and water and optionally fats and emulsifiers with heating to 70- 1000C and/or acidification to pH 4.5-6.0 to produce a gel, wherein at least a portion of the milk proteins are added as a calcium- and phosphate-depleted MPC or MPI. A particularly preferred method is where the calcium- or phosphate-depleted MPC or MPI is 10-100%, preferably 20-100% depleted in both ions, particularly by cation exchange and at least one of anion exchange, ultrafiltration/diafiltration and electrαdialysis as described above. Dairy gels that may be produced by these methods include cheese, processed cheese, cheese spreads, yoghurts, and imitation cheese.
In another aspect the invention provides a method for the manufacture of processed cheese, yoghurts, spreads, cheese and dairy desserts using calcium- and phosphate-depleted MPC or MPI prepared by the method of these aspects of the invention. The advantages of higher protein concentration in cheese manufacture are obtained but with increase in firmness without texture defects associated with protein insolubility. Generally, the use of the calcium- and phosphate- depleted MPC or MPI prepared by the method allows reduction or avoiding of the use of . emulsifying salts. ■
In a further aspect, there is provided a method for preparing a processed cheese comprising cooking cheese or another gelled casein rich source together with other optional processed cheese ingredients and a calcium- and phosphate-depleted MPC, preferably prepared by a method of the invention.
In a further aspect there is provided a method for preparing a cheese spread comprising cooking a mixture comprising an oil, a gelled casein source and water with optional flavourings and a calcium- and phosphate-depleted MPC with 10-100% depletion of both ions.
In a further aspect there is provided a method of cheese manufacture comprising including in the cheese milk an MPC or MPI, preferably dried or in concentrated liquid form, treating the resulting mixture with one or more coagulating enzymes to produce a curd and processing the curd, wherein the MPC or MPI is a calcium and phosphate-depleted MPC or MPI with 10-100% depletion of both ions.
The term "comprising" as used in this specification means "consisting at least in part of, that is to say when interpreting statements in this specification which include that term, the features, prefaced by that term in each statement, all need to be present but other features can also be present.
Brief Description of the Drawings
Figure 1 shows stirred yoghurt viscosities (in mPa.s at 50/s) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)).
Figure 2 shows set yoghurt consistency (texture area g.s) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)).
Figure 3 shows set yoghurt fracture force (peak g) at day 7 for yoghurts prepared using SMP, MPC85, calcium-depleted MPC85 and calcium and phosphate-depleted MPC85 (each both low fat and full fat (FF)). -
EXAMPLES
The following examples further illustrate practice of the invention.
Example 1
MPC (milk protein concentrate, 70% milk protein, Fonterra) 200 g was mixed with 1800 mL of water at 50°C, chilled to 40C and adjusted to pH 5.95 with 10% HCl.
The pH adjusted solution was passed twice through a one litre bed of cation exchange resin (Amberlite SRlL Na form, Rohm & Haas) to fully substitute sodium for calcium as the counterion associated with the protein in solution. The breakthrough (calcium depleted, sodium form of the proteinate) was recovered and cooled to below 10°C. 2 L of the calcium-depleted solution was passed through 2 L of anion exchange resin (A103S, Purolite, chloride form). A temperature of less than 1O0C was maintained throughout the cation and ion exchange steps.
The resulting double ion exchanged product was collected and freeze-dried. The product comprised protein 72.36%, moisture 1.36%, calcium 359 mg/kg, phosphate 185 mmol/kg, total phosphorus 10100 mg/kg.
Example 2
Model processed cheese spread preparation at cookpH of 5.7
The model processed cheeses were prepared using an RVA mixture cooker (Newport Scientific,
Warriewood, NSW, Australia). The recipe is as detailed in Table 1.
The required amount of rennet • casein (ALAREN 799, 90 mesh, Fonterra, New Zealand) was hydrated in salt solution (trisodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and sodium chloride (Pacific salt, Christchurch, New Zealand) and water) in the aluminium cup. The mixture was hydrated for 5 min. ALACEN 392 and MPC (and lactose if used) were added and the mixture was stirred. Oil was then added and the mixture was stirred to mix..
The mixture was cooked using the following programme:
Time(min) Temp (0C) Speed (rpm)
Start
0 25 100
1 25 300
2 25 900 .
3 25 1200
4 85 1500
10 85 1500
Stop, add acid if required
12 85 1500
End
After 10 min cook time, the programme was stopped to allow acid to be added, but in this case, no acid needed to be added. Cooking resumed for another 2 min. The total cooking time was 12 min. The molten processed cheese was poured into plastic screwed cap container, inverted then stored at 4°C. The final pH of the processed cheese was 5.7.
Model processed cheese spread preparation at a cookpHo/6.7
The model processed cheeses were prepared using RVA mixture cooker (Newport Scientific, Warriewood, NSW3 Australia). The recipe is as detailed in Table 1. The required amount of rennet casein (ALAREN 799, 90 mesh, Fonterra, New Zealand) was hydrated in salt solution (trisodium citrate (Jungbunzlauer GmbH, Perhofen, Austria), part of the citric acid (Jungbunzlauer GmbH, Perhofen, Austria) and sodium chloride (Pacific salt, Cnristchurch, New Zealand) and water). The predetermined amount of citric acid used at this stage is shown in Table 2. The mixture was hydrated for 5 min. ALACEN 392 and MPC (and lactose if used) were added and the mixture was stirred. Oil was then added and stirred in to the mixture.
The mixture was cooked using the programme detailed in the sample preparation for cook pH 5.7. After 10 min cook time, the remaining acid (Table 2) was added. Cooking resumed for another 2 min. The total cooking time was 12 min. The molten processed cheese was poured into plastic screwed cap containers, inverted then stored at 4°C. The final pH of the processed cheese was 6.7.
Composition of 'the model processed cheese spread
All the processed cheeses had been formulated to contain 51.29% moisture, 32.88% fat, 10.01% protein, 1.32% lactose and remainder 4.5 % minerals and others. The firmness of the samples is • shown in Table 3.
Table 1 Recipe for model processed cheese spreads made using rennet casein and different MPCs. Whey protein to total protein ratio at 20%.
Ingredients MPC 70 T 7 , ™* nΛ Ca deplete MPC 85
6 deplete MPC 70 v
Soya oil 9.804 9.804 9.804
Rennet casein 1.439 1.440 ■ 1.440
MPC 70 2.143 0 0
Ca and P 04
0 2.076 ' 0 deplete MPC
Ca deplete MPC 0 0 1.83
WPC (Alacen 392) 0.372 0.372 ; 0.372
Lactose 0 0 0.315
Water . • 16.14 16.207 16.138
Sodium chloride 0.315 0.315 0.315
Trisodium citrate 0.612 0.612 0.636
Citric acid 0.175 0.175 0.150
Total 31 ' 31 31
Notes: all weight in grams
: weight of water includes allowance of 1 g for evaporation
Table 2. Amount of citric acid (CA) used to achieved cook pH of 6.7
MPC 70 * dTeap ?lent.de 1 M2PLC Ca dep vlete MPC
CA during
0.335 0.0485 0.0211 cooking
CA at the end of
1.415 0.126 0.129 10 min
Note: all weight in grams
Table 3. Firmness — Variation with pH and cook pH
Ca and PO4
Cook pH MPC 70 Ca deplete MPC deplete MPC pH 5.7 183.9 186.1 183.3 pH 6.7 289.6 296.4 241.5
Note: all results in Pa
Example 3
Model for preparation of processed cheese slice
Ingredients:
Control Depleted MPC70
Water 10.13 10.13
Trisodium citrate dihydrate (TSC) 0.82 0.82
Sodium chloride 0.3 0.3
MPC70 (ALAPRO® 4700) ■ 4.15 -
Ca and PO4 deplete MPC70 - 4.15
High solids cheese 9.78 9.78
Butter 4.58 4.58
Citric acid 0.18 0.18
Note: all values are in grams (g).
Method:
TSC and sodium chloride were added to the water in a plastic pottle. The salts were allowed to dissolve before adding the MPC. The MPC was mixed into the solution and stood for 40 minutes. The remaining ingredients were added and mixed vigorously by hand. The blended material was then transferred to a canister for cooking in the RVA.
Cooking profile: Temperature - the initial temperature was 250C. This was raised to 850C over 4 minutes and then held at 850C for 6 minutes. Total cook time was thus 10 minutes.
Speed - the initial speed was 0 rpm. This was raised stepwise to 800 rpm over 3 minutes and then held at 800 rpm for 7 minutes.
Slice formation:
The cooked processed cheese was poured onto polypropylene film. A second layer of film was placed on top of the molten material. A heavy rolling pin was used to flatten the processed cheese into a 2 mm thick slice, which was then cooled rapidly by placing it on a pre-cooled aluminium tray in a 40C chiller.
Observations:
MPC70 (ALAPRO 4700) formed a pale yellow paste during hydration and gave a slice that appeared well emulsified, homogeneous but slightly soft.
The Ca and P 04 depleted MPC70 hydrated more rapidly, was more reactive and formed a translucent gel during hydration. The slice appeared well emulsified and the break of the slice indicated that the structure was firmer and more brittle than the MPC70 slice.
Example 4 Evaluation of calcium depleted and phosphate reduced MPC in Yoghurt
An MPC product prepared as described in Example 1 except that the starting material was MPC85 was trialled in low fat and full fat yoghurt systems. It was compared with skim milk powder (SMP), standard MPC85 and Ca-deplete MPC 4862 (all Fonterra Co-operative Group Limited).
Both low and full fat yoghurt formulations were prepared with a total protein concentration of 4.6%. The test ingredient provided 1.2% protein. Total solids were standardised with lactose. The pH was adjusted to within pH 6.6-6.8 (if necessary)
For the Full fat (FF) system 3.0% fat (from Anhydrous Milk Fat) was added. .
The test ingredients were calcium and phosphate depleted MPC85 (2-IX MPC) or MPC85 (MPC4850) or Ca-deplete MPC 4862. SMP was used in the SMP control. '
Yoghurts were prepared by the conventional method from the yoghurt milk formulations using addition of a standard starter culture.
Results
The results are shown in Figures 1-3. The calcium- and phosphate-depleted MPC provided increased stirred yoghurt viscosity, set yoghurt consistency and fracture force relative to the SMP controls and the MPC 85 additive comparisons. This result occurred with both low fat and full fat yoghurts. The results were similar to those obtained using the -calcium depleted MPC.
Any discussion of documents, acts, materials, devices or the like that has been included in the present specification is solely for the purpose of providing a context for the present invention. It is not to be taken as an admission that any or all of these matters forms part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed before the priority date.
The above examples are illustrations of the practice of the invention. It will be appreciated by those skilled in the art that the invention can be carried out with numerous modifications and variations. For example, the material subjected to calcium depletion can show variations in protein concentration and pH, the methods of calcium phosphate depletion can be varied, and the percentage calcium and phosphate depletion and drying procedures can also be varied.
Claims
1. A method for producing a dairy product comprising: ■
(a) providing a skim milk or an MPI or MPC, in aqueous solution/suspension, and (b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100% removal of both ions wherein either:
(1) the solution/suspension is subjected to (in any order) one or more processes selected from: i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions, iii ultrafiltration and/or diafiltration iv electrodialysis, or . (2) processes of i-v may be carried out on at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20- 100% depletion of both calcium and phosphate ions.
■
2. A method for producing a dairy product comprising: . • (a) providing an MPI or MPC, in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100% removal of both ions by carrying out both cation exchange and anion exchange (in either order) wherein either:
(1) the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
(2) the two ion exchange steps may be carried out on separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and phosphate ions (d) drying to prepare a dried product.
3. A method for producing a dairy product comprising: (a) providing a skim milk or an MPI or MPC, preferably having at least 70% dry matter as milk protein in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100% removal of both ions by carrying out (in any order) wherein either:
(1) the solution/suspension is subjected to (in any order) one or more processes selected from: i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions, ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions, iii ultrafiltration and/or diafiltration, iv electrodialysis, or
(2) processes of i-v may be carried out on. at least two separate samples that are then combined to give an MPC or MPI with 10-100%, preferably 20-
100% depletion of both calcium and phosphate ions.
4. A method for preparing a dried MPC or MPI, product comprising:
(a) providing an MPI or MPC, preferably having at least 70% dry matter as milk protein, in aqueous solution/suspension
(b) preparing a calcium and phosphate-depleted MPC or MPI solution/suspension having 10-100% removal of both ions by carrying out cation exchange and anion exchange (in either order) wherein: (1) the solution/suspension is subjected to both i cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and ii anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or (2) the two ion exchange steps are carried out on separate samples that are combined to give an MPC or MPI with 10-100%, preferably 20-100% depletion of both calcium and phosphate ions
(c) drying to prepare a dried product.
5. A method of preparing a dried MPC or MPI comprising:
(a) providing a low fat milk solution, for example skim milk, as a solution/suspension. (b) preparing a calcium and phosphate-depleted solution/suspension having 10-100%, removal of both ions by carrying out both cation exchange and anion exchange (in either order) wherein either:
(1) solution/suspension is subjected to both iii cation exchange on a cation exchanger in the hydrogen, sodium, or potassium form to remove calcium ions and iv anion exchange on a anion exchanger in the hydroxide or chloride form to remove phosphate ions; or
(2) two ion exchange steps are carried out on separate samples that are then combined to give an MPC or MPL with 10-100%,, preferably 20-100% depletion of both calcium and phosphate ions
(c) concentrating the solution obtained by ultrafiltration, optionally with diafiltration, to form an MPI or MPC having preferably at least 70% dry weight as protein; and (optionally)
(d) drying to prepare a dried product.
6. A method as claimed in any one of claims 1-5 wherein the casein to whey ratio is between 90:10 and 60:40 by weight.
7. A method as claimed in any. one of claims 1, 3 and 6 wherein the calcium and phosphate depletion is carried out using cation exchange and anion exchange.
8. A method as claimed in claim 7 wherein calcium removed is replaced by sodium or potassium or both and the phosphate removed is replaced by chloride.
9. A method as claimed in any one of claims 1-8 wherein the calcium- and phosphate- depleted MPC or MPI has 20-100% depletion of both ions.
10. A method for preparing a dairy gel comprising mixing ingredients including milk proteins and water and optionally fats and emulsifiers with heating to 70-100°C and/or acidification to pH 4.5-6.0 to produce a gel, wherein at least a portion of the milk proteins are added as a calcium- and phosphate-depleted MPC or MPI with 10-100% depletion of both ions.
11. A method for preparing a dairy gel comprising mixing ingredients including milk proteins and water and optionally fats and emulsifiers with heating to 70-1000C and/or acidification to pH 4.5-6.0to produce a gel, wherein at least a portion of the milk proteins are added as a calcium- and phosphate-depleted MPC or MPI with 20-100% depletion of both ions prepared by a method as claimed in any one of claims 1-9.
12. A method as claimed in claim 10 or claim 11 wherein the dairy gel is selected from the group consisting of a processed cheese, a yoghurt, a dairy spread, a cheese and a dairy dessert.
13. A method for preparing a processed cheese comprising cooking cheese or another gelled casein rich source together with other optional processed cheese ingredients and a calcium- and phosphate-depleted MPC with 10-100% depletion of both ions.
14. A method for preparing a cheese spread comprising cooking a mixture comprising an oil, a gelled casein source and water with optional flavourings and a calcium- and phosphate- depleted MPC with 10-100% depletion of both ions.
15. A method of cheese manufacture comprising including in the cheese milk an MPC or MPI, treating the resulting mixture with one or more coagulating enzymes to produce a curd and processing the curd, wherein the MPC or MPI is a calcium and phosphate-depeleted MPC or MPI with 10-100% depletion of both ions.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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NZ552352 | 2006-12-22 | ||
NZ55235206A NZ552352A (en) | 2006-12-22 | 2006-12-22 | Dairy product produced from milk protein isolate or milk protein concentrate with reduced calcium and phosphate ion concentrations |
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WO2008079031A2 true WO2008079031A2 (en) | 2008-07-03 |
WO2008079031A3 WO2008079031A3 (en) | 2008-08-28 |
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PCT/NZ2007/000390 WO2008079031A2 (en) | 2006-12-22 | 2007-12-24 | Dairy product and process |
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WO (1) | WO2008079031A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014068187A1 (en) | 2012-10-31 | 2014-05-08 | Valio Ltd | Processed cheese and method of preparation |
CN113873888A (en) * | 2019-05-27 | 2021-12-31 | 菲仕兰坎皮纳荷兰公司 | Nutritional composition |
US11470857B2 (en) | 2013-01-23 | 2022-10-18 | Arla Foods Amba | Method of producing beta-casein compositions and related products |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108912345B (en) * | 2018-06-27 | 2020-06-09 | 江南大学 | Microcapsule wall material based on concentrated lactoprotein and microcapsule |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159034A (en) * | 1984-05-22 | 1985-11-27 | Nestle Sa | A process for the production of a skimmed milk |
-
2006
- 2006-12-22 NZ NZ55235206A patent/NZ552352A/en unknown
-
2007
- 2007-12-24 WO PCT/NZ2007/000390 patent/WO2008079031A2/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159034A (en) * | 1984-05-22 | 1985-11-27 | Nestle Sa | A process for the production of a skimmed milk |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014068187A1 (en) | 2012-10-31 | 2014-05-08 | Valio Ltd | Processed cheese and method of preparation |
US11470857B2 (en) | 2013-01-23 | 2022-10-18 | Arla Foods Amba | Method of producing beta-casein compositions and related products |
CN113873888A (en) * | 2019-05-27 | 2021-12-31 | 菲仕兰坎皮纳荷兰公司 | Nutritional composition |
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NZ552352A (en) | 2009-07-31 |
WO2008079031A3 (en) | 2008-08-28 |
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