WO2008077835A3 - Trägerkatalysator für die metathese - Google Patents

Trägerkatalysator für die metathese Download PDF

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Publication number
WO2008077835A3
WO2008077835A3 PCT/EP2007/064040 EP2007064040W WO2008077835A3 WO 2008077835 A3 WO2008077835 A3 WO 2008077835A3 EP 2007064040 W EP2007064040 W EP 2007064040W WO 2008077835 A3 WO2008077835 A3 WO 2008077835A3
Authority
WO
WIPO (PCT)
Prior art keywords
carrier
weight
metathesis
carrier catalyst
catalyst
Prior art date
Application number
PCT/EP2007/064040
Other languages
English (en)
French (fr)
Other versions
WO2008077835A2 (de
Inventor
Marcus Sigl
Daniel Schneider
Original Assignee
Basf Se
Marcus Sigl
Daniel Schneider
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Marcus Sigl, Daniel Schneider filed Critical Basf Se
Publication of WO2008077835A2 publication Critical patent/WO2008077835A2/de
Publication of WO2008077835A3 publication Critical patent/WO2008077835A3/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Ein Trägerkatalysator für Metathesereaktionen, enthaltend eine Aktivkomponente (A), enthaltend Re2O7 und B2O3, sowie eine Trägerkomponente (B), enthaltend SiO2 und Al2O3, wobei der SiO2-Anteil in der Trägerkomponente 50 bis 90 Gew.-% beträgt und der Al2O3-Anteil in der Trägerkomponente 10 bis 50 Gew.-% beträgt, sowie der Re2O7- Anteil im Trägerkatalysator 1 bis 10 Gew.-% beträgt und der B2O3-Anteil im Trägerkatalysator 0,5 bis 10 Gew.-% beträgt, eignet sich insbesondere für die Metathesereaktion von funktionalisierten Olefinen, wie Ölsäuremethylester.
PCT/EP2007/064040 2006-12-21 2007-12-17 Trägerkatalysator für die metathese WO2008077835A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06126758 2006-12-21
EP06126758.9 2006-12-21

Publications (2)

Publication Number Publication Date
WO2008077835A2 WO2008077835A2 (de) 2008-07-03
WO2008077835A3 true WO2008077835A3 (de) 2008-08-14

Family

ID=39432203

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/064040 WO2008077835A2 (de) 2006-12-21 2007-12-17 Trägerkatalysator für die metathese

Country Status (1)

Country Link
WO (1) WO2008077835A2 (de)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5143885A (en) * 1990-03-02 1992-09-01 Huls Aktiengesellschaft Catalysts for the metathesis of olefins and functionalized olefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5143885A (en) * 1990-03-02 1992-09-01 Huls Aktiengesellschaft Catalysts for the metathesis of olefins and functionalized olefins
US5183791A (en) * 1990-03-02 1993-02-02 Huels Aktiengesellschaft Catalysts for the metathesis of olefins and functionalized olefins

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
MOL J C: "Olefin metathesis over supported rhenium catalysts", CATALYSIS TODAY, AMSTERDAM, NL, vol. 51, 1 January 1999 (1999-01-01), pages 289 - 299, XP002222177 *
REGINA BUFFON, IVAN J. MAROCHIO, CRISTIANE B. RODELLA, JOHANNES C. MOL: "Germanium and silicon compounds as promoters for Re2O7/SiO2-Al2O3 metathesis catalysts", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 190, no. 1-2, 12 June 2002 (2002-06-12), pages 171 - 176, XP002482934 *
RODELLA C B ET AL: "Characterization and catalytic performance of rhenium oxide-based catalysts supported on borated silica-alumina", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 263, no. 2, 10 June 2004 (2004-06-10), pages 203 - 211, XP004506889, ISSN: 0926-860X *
RODELLA C B ET AL: "Metathesis of methyl oleate over rhenium oxide-based catalysts supported on borated silica-alumina: catalyst recycling", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 274, no. 1-2, 28 October 2004 (2004-10-28), pages 213 - 217, XP004558617, ISSN: 0926-860X *

Also Published As

Publication number Publication date
WO2008077835A2 (de) 2008-07-03

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