WO2008065002A2 - Process and apparatus for waste treatment - Google Patents

Process and apparatus for waste treatment Download PDF

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Publication number
WO2008065002A2
WO2008065002A2 PCT/EP2007/062353 EP2007062353W WO2008065002A2 WO 2008065002 A2 WO2008065002 A2 WO 2008065002A2 EP 2007062353 W EP2007062353 W EP 2007062353W WO 2008065002 A2 WO2008065002 A2 WO 2008065002A2
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WO
WIPO (PCT)
Prior art keywords
waste
pressure
loading
pressure tank
outlet
Prior art date
Application number
PCT/EP2007/062353
Other languages
French (fr)
Other versions
WO2008065002A3 (en
Inventor
Rafael Ribas Lopez
Oscar Ribas Martinez
Original Assignee
Ambiensys, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Ambiensys, S.L. filed Critical Ambiensys, S.L.
Priority to ES07847168.7T priority Critical patent/ES2557929T3/en
Priority to CN200780043715.3A priority patent/CN101541352B/en
Priority to EP07847168.7A priority patent/EP2086595B1/en
Publication of WO2008065002A2 publication Critical patent/WO2008065002A2/en
Publication of WO2008065002A3 publication Critical patent/WO2008065002A3/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L11/00Methods specially adapted for refuse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation

Definitions

  • the present invention relates to a process and an apparatus for waste treatment, particularly suitable for urban solid waste treatment and similar industrial waste, wherein the treated waste is introduced in a pressure tank inside which it is subjected to pressure and temperature conditions during a determined period of time, sufficient for its sterilization and transformation in useful by-products.
  • waste sanitation In these types of processes, also called waste sanitation, the waste is exposed during a predetermined period of time to a steam bath, at a high temperature, at the same time as being mechanically agitated with the aim, among others, of extracting the liquids the waste contains.
  • the apparatuses especially designed to carry out this sanitation process generally comprise a rotary drum of large dimensions, conventionally of cylindrical shape, capable of rotating around its longitudinal axis.
  • These receptacles are provided with an opening, provided with a gate which allows the receptacle to be hermetically closed, wherein the waste to be treated is introduced and the waste is extracted therefrom once treated.
  • the process followed for the sanitation of the waste first consists of introducing a large quantity of waste in the receptacle, hermetically closing the receptacle and then increasing the pressure and temperature therein whilst the waste is agitated as the receptacle rotates around its longitudinal axis.
  • the pressure and temperature inside the receptacle reach the desired values, the pressure and temperature conditions inside the receptacle are maintained constant for a predetermined time, which varies in accordance with the composition of the waste, producing the actual waste sanitation. Then the pressure is decreased inside the receptacle in controlled manner and the waste is extracted therefrom.
  • One of the greatest drawbacks of the sanitation processes disclosed in said documents is related to the high energy consumption necessary, in each operating cycle, to raise the pressure and temperature inside the receptacle after the introduction of the waste therein, generally introduced at atmospheric pressure and at ambient temperature, until the necessary values for its sanitation, and the consequent energy loss produced later when, once the waste is treated for a predetermined time at the working conditions, the receptacle is depressurized to safely open its gate and extract the waste from inside it.
  • the opening of the receptacle also entails a considerable lowering of the temperature inside the receptacle.
  • a following operative cycle after introducing a new quantity of waste inside the receptacle sufficient new energy should be provided to raise the pressure and the temperature inside the receptacle to the suitable values for waste sanitation.
  • a first objective of the invention is to disclose a process and an apparatus which improve the output of the known processes and apparatuses, reducing the energy consumption and the time necessary per unit of volume of treated waste.
  • the use as pressure tanks of the rotary pressure receptacles involves the use of suitable materials to resist the mechanical stresses or demands to which these receptacles are subjected due to being rotary, and also to resist the high pressure and temperatures inside the receptacles.
  • the inner walls of the receptacles which are in direct contact with the waste, should resist the mechanical aggressions to which the solid waste is subjected, on being agitated, they continually impact and rub against the inner walls of the receptacles.
  • the receptacles described in said documents have other drawbacks related to the complexity of the communications between the inside and outside of the receptacle, especially regarding the passages for the intake of steam and for the outlet of liquids, if we do not want to alter the pressure and temperature conditions inside the receptacle and hinder the rotary movement to which it is subjected.
  • the process for waste treatment object of the invention is particularly suitable for the treatment of urban solid waste and similar industrial waste, and is characterized in that it comprises the continuous operation of treating the waste in a closed enclosure, turning it and/or mixing it and subjecting it, in an uninterrupted manner, during its retention in the closed enclosure to a pressure over 2 bar and a temperature between 100 Q C and 200 Q C, and the discontinuous operations of subjecting to pressure, one by one, successive waste loading units and introducing them, also one by one, inside the closed treatment enclosure; extracting from the closed treatment enclosure and decompressing, also one by one, several already treated waste discharge units, - A -
  • the closed enclosure is not depressurized every time waste is extracted from inside it nor is it necessary to increase the pressure therein, from atmospheric pressure until reaching a pressure over 2 bar, each time new waste to be treated is introduced.
  • the waste from multiple loading units successively introduced therein accumulate in the closed enclosure.
  • the closed treatment enclosure is a pressure tank, inside which the waste is made to pass through a rotary drum, coaxial with the pressure tank, of perforated walls through which the liquids may flow towards the exterior of the rotary drum.
  • the perforations are of aproximately 1 mm to aproximately 7 mm of diameter.
  • a communication is established between said loading or compression and discharge or decompression chambers designed to equal the pressures in both chambers at least during the compression and decompression operations.
  • the waste of said loading unit before the introduction operation of a waste loading unit in the loading or compression chamber, is sufficiently compacted to deform or break elements that exceed predetermined dimensions or to detect the inclusion of unbreakable elements that exceed said predetermined dimensions, avoiding the unnecessary dripping of liquids contained in the waste, to authorize the introduction of the loading unit in the loading or compression chamber, and subsequently in the closed enclosure, or temporarily reject it.
  • an apparatus for waste treatment particularly of urban solid waste and similar industrial waste, equipped with a fixed pressure tank being arranged at one longitudinal end an inlet of the waste to treat and at the other longitudinal end, an outlet of the treated waste, being disposed inside the pressure tank means to transport the waste introduced from the inlet to the outlet of the pressure tank and turn and/or agitate said waste.
  • the apparatus object of the invention is characterized in that it comprises a loading or compression chamber, designed to house a loading unit of waste to treat, equipped with separate inlet and outlet channels of the waste to which the outlet channel gives access, through the inlet of the pressure tank, to the inside of said pressure tank, both inlet and outlet channels being equipped with respective sluice gates; a discharge or decompression chamber, designed to house a discharge unit of treated waste, equipped with inlet and outlet channels of the already treated waste, of which the inlet channel is juxtaposed to the pressure tank outlet, both inlet and outlet channels being provided with respective sluice gates; and means to increase and decrease the pressure inside the loading or compression and discharge or decompression chambers from atmospheric pressure until reaching the value of the pressure inside the pressure tank and vice-versa, respectively.
  • the means to transport, turn and/or agitate the waste inside the pressure tank comprise a rotary drum, coaxial respect to the pressure tank, of perforated walls and equipped with elements which are projected from the inner surface of the side wall of said rotary drum, designed to turn and to move in longitudinal direction, respectively, the waste introduced therein with the rotation of the rotary drum around its longitudinal axis.
  • the diameter of the perforations are of aproximately 1 mm to aprox. 7 mm., in order to prevent the waste from flowing towards the exterior of the tubular body but enabling the liquids released by the waste to flow through said perforations.
  • the walls of the rotary drum are only perforated along an end longitudinal portion of said rotary drum, corresponding to the reception end of the waste.
  • the outlet channel of the loading or compression chamber is disposed inside the pressure tank so that when the waste contained in said loading or compression chamber is extracted, it is deposited, by gravity, in the means to transport, turn and/or agitate the waste.
  • the loading or compression chamber of the waste is essentially cylindrical, is disposed horizontally and is equipped with means of pushing the waste contained in direction of the outlet channel.
  • the means of pushing comprises a hydraulic cylinder which can move longitudinally through the inside of the loading or compression chamber.
  • the outlet of the pressure tank is disposed in the lower side thereof and the inlet channel of the discharge or decompression chamber is disposed juxtaposed under said outlet, so that the waste extracted from the pressure tank is introduced, by gravity, in said discharge or decompression chamber.
  • the apparatus is equipped with means of communication between the loading and compression and discharge or decompression chambers, whereby the internal pressures of both chambers can be equalled.
  • the pressure tank is disposed inclined with respect to the horizontal and so that the end equipped with the outlet is raised with respect to the end equipped with the inlet.
  • FIG. 1 is a longitudinal section view of the apparatus for waste treatment
  • Figs. 2, 3 and 4 are schematic views of the apparatus of Fig. 1 in successive stages of the waste treatment process object of the invention.
  • the apparatus 20 represented in Figs. 1 to 4 is designed for waste treatment, and more particularly treatment of urban solid waste 22a, 22b and
  • FIG. 1 it is observed that said apparatus 20 is equipped with a fixed pressure tank 1 at whose longitudinal ends 4a and 4b are disposed separate inlets 30 of the waste to treat and outlets 29 of the treated waste 22c and inside which the waste 22b is subjected during a predetermined period of time to determined pressure and temperature conditions in accordance with its composition.
  • Means to transport 21 , turn and/or agitate the waste introduced from the inlet 30 to the outlet 29 are disposed inside the pressure tank 1.
  • the apparatus 20 also comprises a loading or compression chamber 13, a discharge or decompression chamber 16 and means 23 and 24 to increase the pressure inside said chambers from atmospheric pressure until reaching the pressure value inside the pressure tank 1 and vice-versa.
  • the apparatus 20 operates in continuous process, which means that the waste to treat 22a is introduced inside the pressure tank 1 by the inlet 30 discontinuously, in successive loading units, without interrupting the treatment of the waste 22b which is carried out inside the pressure tank 1 , and the treated waste 22c is extracted from inside the pressure tank 1 in successive discharge units through the outlet 29, also without interrupting the treatment of the waste 22b which continues inside the pressure tank 1.
  • the operations of introducing and extracting the waste 22a and 22c from inside the pressure tank 1 are simultaneous with the waste 22b treatment operation which is carried out in continuous and uninterrupted form whilst there is waste inside the pressure tank 1 .
  • the pressure tank 1 preferably has the capacity for housing the content of multiple loading units successively introduced in said pressure tank 1 , which are accumulated therein and are turned and/or mixed in uninterrupted manner, subjected to a pressure over 2 bar and a temperature between 100 Q C and 200 Q C throughout its retention inside the pressure tank 1 .
  • the pressure tank 1 is equipped with a series of intake conduits 9 of gas, and preferably steam, whereby this is injected inside the pressure tank 1 to maintain the suitable pressure and temperature conditions for the correct waste sanitation 22b.
  • the apparatus 20 comprises a loading or compression chamber 13 to compensate this pressure difference and thus be able to introduce the waste inside the pressure tank 1 without significantly altering the pressure conditions inside the pressure tank 1 .
  • the loading or compression chamber 13 essentially cylindrical and horizontally disposed, is designed to house a loading unit 22a of waste to treat, equipped with separate waste inlet 14a and outlet 12a channels.
  • the outlet channel 12a gives access, through the inlet 30 of the pressure tank 1 , inside said tank, both inlet 14a and outlet channels 12a being provided with respective sluice gates 14 and 12.
  • a loading unit of waste to treat 22a inside the pressure tank 1 the following is done. With the sluice gate 12 of the loading or compression chamber 13 closed, a waste loading unit 22a is introduced through its inlet channel 14a (situation represented in Fig. 1 ). Next, the sluice gate 14 is closed and the pressure P1 is increased in the loading or compression chamber 13 by means 23, which inject steam therein, until reaching the pressure P2 value inside the pressure tank 1 . Once the pressures P1 and P2 (situation represented in Fig.
  • the sluice gate 12 of the loading or compression chamber 13 is again closed and said loading or compression chamber 13 is depressurized until reaching the suitable pressure for the opening of its inlet gate 14 and a new cycle of waste is started with the introduction of a new waste loading unit 22a in the inlet or compression chamber 13.
  • the loading unit 22a is temporary rejected and it is separated to be examined, manually or automatically extracting the unbreakable elements, and being later introduced in the inlet or compression chamber 13. In any case, it is not desirable that liquids contained in the container drip during the compacting operation.
  • the means to transport 21 , turn and/or agitate the waste 22b introduced from the inlet 30 to the outlet 29, comprises a rotary drum 25, coaxial with respect to the pressure tank 1 , having perforated walls 27 and equipped with elements 26 which are projected from the inner surface of the side wall of said rotary drum 25. These projected elements 26 are designed to turn and move in longitudinal direction, respectively, the waste 22b introduced in said rotary drum with rotation around its longitudinal axis.
  • the perforated wall 27 of the rotary drum 25 covers only an end longitudinal portion of said rotary drum 25, corresponding to the reception end of the waste to treat 22a.
  • the waste 22a contained in a loading unit introduced in the pressure tank 1 is instantaneously subjected to the temperature conditions inside the pressure tank 1 causing, among other effects, that the liquids contained in the waste are released at the start of their path through the rotary drum 25, in other words in the area close to the intake end of the pressure tank 1 .
  • the function of the perforations is to evacuate the water for the interior of rotary drum 25, preventing the waste form flowing towards the exterior of the rotary drum.
  • the diameter of the perforations are less than 7 mm, and preferabily are from 1 mm to 4 mm.
  • the gap between the perforations it is from aproximately 5 mm to aproximately 20 mm.
  • the pressure tank 1 is disposed inclined with respect to the horizontal although, unlike the known apparatus, it is the end with the outlet 29 which is raised with respect to the end equipped with the inlet 30.
  • the steam condensates and the liquids contained in the waste 22b which are precipitated in the pressure tank 1 are extracted therefrom through a connection 2 located in its lower part, in this case the intake end, using the interior overpressure and the inclination of the pressure tank 1.
  • the apparatus 20 for waste treatment comprises a liquid level meter in charge of transmitting an activation signal to a central control system which regulates the extraction of liquids through the connection 2 when the level of liquid accumulated inside the tank exceeds a certain value.
  • the apparatus 20 is equipped with a series of sprinklers 5 designed to inject pressurized steam in a controlled manner against the outer wall of the rotary drum 25, and in particular directed against the portion provided with orifices to give the water free passage through it.
  • the retention time of the waste 22b inside the pressure tank 1 is determined by the length of the rotary drum 25 and its rotation rate. These parameters are adjusted so that the retention time of the waste, generally between 15 and 20 minutes inside the pressure tank 1 and subjected to the constant pressure and temperature conditions inside, is necessary for its correct sanitation. Once the waste 22b has longitudinally travelled through the rotary drum
  • the apparatus 20 comprises a discharge or decompression chamber 16 designed to house a discharge unit of treated waste 22c, equipped with separate inlet 17a and outlet channels 18a of the already treated waste, in this case the inlet channel 17a being juxtaposed to the outlet 29 of the pressure tank, which are provided with respective sluice gates 17 and 18.
  • the apparatus 20 comprises means 24 to decrease the pressure inside the discharge or decompression chamber 16 to atmospheric pressure and thus allow the treated waste 22c to be expulsed outside without causing considerable depressurizations or temperature losses inside the pressure tank 1. Due to the fact that the outlet 29 of the pressure tank 1 is disposed on the lower side thereof and that the inlet channel 17a of the discharge or decompression chamber 16 is disposed juxtaposed under said outlet 29, the waste 22c extracted from the pressure tank 1 is introduced in said discharge or decompression chamber 16 by gravity.
  • Fig. 1 represents the sluice gate 17 of the discharge or decompression chamber 16 open, with the corresponding sluice gate 18 closed, so that the waste 22c discharged by the rotary drum 25 is deposited in said discharge or decompression chamber 16.
  • the sluice gate 17 of said discharge or decompression chamber 16 closes (situation represented in Fig. 2) and the discharge or decompression chamber 16 is depressurized until the pressure P3 therein approaches or is equal to the pressure outside the apparatus.
  • the sluice gate 18 opens expulsing the waste 22c outside (situation represented in Fig. 3) which falls by gravity, the sluice gate 18 again closing (situation represented in Fig. 4) to start a new discharge cycle of the treated waste 22c which starts increasing the pressure P3 inside the discharge or decompression chamber 16 until the value of the pressure P2 inside the pressure tank 1 is reached.
  • the apparatus 20 for waste treatment may be equipped with means of communication 28 between the loading or compression 13 and discharge or decompression chambers 16, whereby the internal pressures of both chambers can be equalled.
  • the loading unit of waste to treat 22a is found in the loading or compression chamber 13 at a pressure P1 lower than the pressure P2 inside the pressure tank, which makes it necessary to increase the pressure P1 until reaching the value of the pressure P2 to introduce the waste in the pressure tank 1 without significantly altering the pressure conditions inside said pressure tank 1.
  • the already treated waste 22c has just come out of the inside of the pressure tank 1 , which means the value of the pressure P3, equal to the pressure P2 inside the pressure tank 1 , is higher than the outside or atmospheric pressure necessary to be able to expulse said waste 22c to the outside in a controlled and safe manner.
  • the pressures P1 in the loading or compression chamber 13 and P3 in the discharge or decompression chamber 16 are equalled, i.e. the excess pressure from the depressurization of the waste 22c contributes to the increase in pressure of the waste loading unit 22a.
  • the pressure P1 in the loading or compression chamber 13, previously in communication with the inside of the pressure tank 1 is equal to the pressure P2 inside said pressure tank 1 , which is higher than the outside or atmospheric pressure at which the loading units of the waste to treat 22a is found.
  • the discharge or decompression chamber 16 has just expulsed the waste 22c for which reason it is found at a pressure P3 close to the outside or atmospheric pressure.
  • a pressure P3 close to the outside or atmospheric pressure To be able to again receive the waste 22c from the inside of the pressure tank 1 without altering the pressure conditions inside said pressure tank 1 , it will be necessary that the pressure P3 inside the discharge or decompression chamber 16 increases until reaching the value of the pressure P2 inside the pressure tank.
  • the excess pressure from the depressurization of the loading or compression chamber 13 will contribute to the pressurization of the discharge or decompression chamber 16 necessary to admit the waste 22c therein.
  • the pressure and temperature conditions inside the pressure tank 1 are essentially maintained constant, it only being necessary to compensate the small pressure and temperature losses therein as a consequence of the operations of introduction and extraction of the waste inside it, but in no case being necessary to raise the pressure and the temperature from the ambient conditions outside the apparatus each time new waste is introduced in the pressure tank 1.

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Abstract

Process for waste treatment, particularly suitable for urban solid waste which comprises the continuous operation of treating the waste in a closed enclosure, turning it and/or mixing it and subjecting it in an uninterrupted manner during its retention in the closed enclosure to a pressure over 2 bar and a temperature between 100 ºC and 200 ºC, and the discontinuous operations of subjecting to pressure, one by one, successive waste loading units and introducing them, also one by one, inside the closed treatment enclosure; extracting from the closed treatment enclosure and decompressing, also one by one, several already treated waste discharge units, compensating the small pressure and temperature losses inside the closed enclosure, whose values are maintained essentially constant.

Description

D E S C R I P T I O N
"Process and apparatus for waste treatment" Technical field of the invention The present invention relates to a process and an apparatus for waste treatment, particularly suitable for urban solid waste treatment and similar industrial waste, wherein the treated waste is introduced in a pressure tank inside which it is subjected to pressure and temperature conditions during a determined period of time, sufficient for its sterilization and transformation in useful by-products.
Background of the invention
Among the different known processes for the treatment of urban solid waste or household waste, as well as similar industrial waste, that where the waste is sterilized and partially desiccated is of particular interest, transforming the organic fraction of the waste in a homogenized by-product for its subsequent separation and use via recycling circuits and/or energy recovery.
In these types of processes, also called waste sanitation, the waste is exposed during a predetermined period of time to a steam bath, at a high temperature, at the same time as being mechanically agitated with the aim, among others, of extracting the liquids the waste contains.
The apparatuses especially designed to carry out this sanitation process generally comprise a rotary drum of large dimensions, conventionally of cylindrical shape, capable of rotating around its longitudinal axis. These receptacles are provided with an opening, provided with a gate which allows the receptacle to be hermetically closed, wherein the waste to be treated is introduced and the waste is extracted therefrom once treated.
The process followed for the sanitation of the waste first consists of introducing a large quantity of waste in the receptacle, hermetically closing the receptacle and then increasing the pressure and temperature therein whilst the waste is agitated as the receptacle rotates around its longitudinal axis. When the pressure and temperature inside the receptacle reach the desired values, the pressure and temperature conditions inside the receptacle are maintained constant for a predetermined time, which varies in accordance with the composition of the waste, producing the actual waste sanitation. Then the pressure is decreased inside the receptacle in controlled manner and the waste is extracted therefrom.
As a representative part of the state of the art, documents US 5427650, WO 03025101 and US 5427650 are cited, which disclose sanitation processes that follow the aforementioned steps as well as apparatuses especially suitable for performing said processes.
One of the greatest drawbacks of the sanitation processes disclosed in said documents is related to the high energy consumption necessary, in each operating cycle, to raise the pressure and temperature inside the receptacle after the introduction of the waste therein, generally introduced at atmospheric pressure and at ambient temperature, until the necessary values for its sanitation, and the consequent energy loss produced later when, once the waste is treated for a predetermined time at the working conditions, the receptacle is depressurized to safely open its gate and extract the waste from inside it. Naturally, the opening of the receptacle also entails a considerable lowering of the temperature inside the receptacle. In a following operative cycle, after introducing a new quantity of waste inside the receptacle sufficient new energy should be provided to raise the pressure and the temperature inside the receptacle to the suitable values for waste sanitation.
The fact that the pressure and temperature inside the receptacle have to be increased to the suitable values for the waste treatment in each operative cycle, in addition to the energy cost it entails for the production of the necessary water vapour, appreciably extends the duration of each operative cycle.
At this point we should state that the great quantity of waste generated in the large population centres obliges increasing the dimensions of the receptacles designed to treat the waste, since the treatment facilities should have sufficient capacity to treat a high volume of waste at the same time. Nevertheless, the greater dimension of the receptacle the greater the energy consumption necessary and the time required to reach the suitable pressure and temperature conditions inside the receptacle, for the waste sanitation, each time an operative cycle starts.
A first objective of the invention is to disclose a process and an apparatus which improve the output of the known processes and apparatuses, reducing the energy consumption and the time necessary per unit of volume of treated waste. On the other hand, and in relation to the known apparatuses, the use as pressure tanks of the rotary pressure receptacles involves the use of suitable materials to resist the mechanical stresses or demands to which these receptacles are subjected due to being rotary, and also to resist the high pressure and temperatures inside the receptacles. Furthermore, the inner walls of the receptacles, which are in direct contact with the waste, should resist the mechanical aggressions to which the solid waste is subjected, on being agitated, they continually impact and rub against the inner walls of the receptacles.
In addition to the aforementioned drawbacks, regarding the mechanical stresses and inner wear to which these rotary receptacles are subjected, the receptacles described in said documents have other drawbacks related to the complexity of the communications between the inside and outside of the receptacle, especially regarding the passages for the intake of steam and for the outlet of liquids, if we do not want to alter the pressure and temperature conditions inside the receptacle and hinder the rotary movement to which it is subjected.
It is therefore another object of the invention to disclose an apparatus for waste treatment which is simpler and/or reduces the manufacturing costs in comparison with known apparatuses.
It is also an objective of the apparatus according to the invention to improve the extraction of the liquids released by the waste inside the receptacles, consequently improving the drying level and the quality of the waste obtained, in the sense that its water content is reduced in comparison with the waste obtained from carrying out the sanitation process in a conventional apparatus.
Explanation of the invention
The process for waste treatment object of the invention is particularly suitable for the treatment of urban solid waste and similar industrial waste, and is characterized in that it comprises the continuous operation of treating the waste in a closed enclosure, turning it and/or mixing it and subjecting it, in an uninterrupted manner, during its retention in the closed enclosure to a pressure over 2 bar and a temperature between 100 QC and 200 QC, and the discontinuous operations of subjecting to pressure, one by one, successive waste loading units and introducing them, also one by one, inside the closed treatment enclosure; extracting from the closed treatment enclosure and decompressing, also one by one, several already treated waste discharge units, - A -
performing the corresponding compression and decompression operations in respective loading or compression chambers and discharge or decompression chambers, wherein the pressure to which the waste is subjected is increased from ambient pressure to that of inside the closed enclosure and vice-versa, respectively, compensating the small pressure and temperature losses inside the closed enclosure, whose values are maintained essentially constant, after the waste introduction and extraction operations.
Advantageously, and unlike the known processes, the closed enclosure is not depressurized every time waste is extracted from inside it nor is it necessary to increase the pressure therein, from atmospheric pressure until reaching a pressure over 2 bar, each time new waste to be treated is introduced.
Preferably, the waste from multiple loading units successively introduced therein accumulate in the closed enclosure. According to another characteristic of the invention, the closed treatment enclosure is a pressure tank, inside which the waste is made to pass through a rotary drum, coaxial with the pressure tank, of perforated walls through which the liquids may flow towards the exterior of the rotary drum.
Preferabily, the perforations are of aproximately 1 mm to aproximately 7 mm of diameter.
In accordance with another characteristic of the process according to the invention, a communication is established between said loading or compression and discharge or decompression chambers designed to equal the pressures in both chambers at least during the compression and decompression operations.
In accordance with another characteristic of the invention, before the introduction operation of a waste loading unit in the loading or compression chamber, the waste of said loading unit is sufficiently compacted to deform or break elements that exceed predetermined dimensions or to detect the inclusion of unbreakable elements that exceed said predetermined dimensions, avoiding the unnecessary dripping of liquids contained in the waste, to authorize the introduction of the loading unit in the loading or compression chamber, and subsequently in the closed enclosure, or temporarily reject it.
According to another aspect of the invention, it discloses an apparatus for waste treatment, particularly of urban solid waste and similar industrial waste, equipped with a fixed pressure tank being arranged at one longitudinal end an inlet of the waste to treat and at the other longitudinal end, an outlet of the treated waste, being disposed inside the pressure tank means to transport the waste introduced from the inlet to the outlet of the pressure tank and turn and/or agitate said waste. In essence, the apparatus object of the invention is characterized in that it comprises a loading or compression chamber, designed to house a loading unit of waste to treat, equipped with separate inlet and outlet channels of the waste to which the outlet channel gives access, through the inlet of the pressure tank, to the inside of said pressure tank, both inlet and outlet channels being equipped with respective sluice gates; a discharge or decompression chamber, designed to house a discharge unit of treated waste, equipped with inlet and outlet channels of the already treated waste, of which the inlet channel is juxtaposed to the pressure tank outlet, both inlet and outlet channels being provided with respective sluice gates; and means to increase and decrease the pressure inside the loading or compression and discharge or decompression chambers from atmospheric pressure until reaching the value of the pressure inside the pressure tank and vice-versa, respectively.
According to another characteristic of the invention, the means to transport, turn and/or agitate the waste inside the pressure tank comprise a rotary drum, coaxial respect to the pressure tank, of perforated walls and equipped with elements which are projected from the inner surface of the side wall of said rotary drum, designed to turn and to move in longitudinal direction, respectively, the waste introduced therein with the rotation of the rotary drum around its longitudinal axis. Preferabily, the diameter of the perforations are of aproximately 1 mm to aprox. 7 mm., in order to prevent the waste from flowing towards the exterior of the tubular body but enabling the liquids released by the waste to flow through said perforations.
In accordance with another characteristic of the invention, the walls of the rotary drum are only perforated along an end longitudinal portion of said rotary drum, corresponding to the reception end of the waste.
In accordance with another characteristic of the invention, the outlet channel of the loading or compression chamber is disposed inside the pressure tank so that when the waste contained in said loading or compression chamber is extracted, it is deposited, by gravity, in the means to transport, turn and/or agitate the waste. According to another characteristic of the invention, the loading or compression chamber of the waste is essentially cylindrical, is disposed horizontally and is equipped with means of pushing the waste contained in direction of the outlet channel. In accordance with another characteristic of the invention, the means of pushing comprises a hydraulic cylinder which can move longitudinally through the inside of the loading or compression chamber.
In accordance with another characteristic of the invention, the outlet of the pressure tank is disposed in the lower side thereof and the inlet channel of the discharge or decompression chamber is disposed juxtaposed under said outlet, so that the waste extracted from the pressure tank is introduced, by gravity, in said discharge or decompression chamber.
According to another characteristic of the invention, the apparatus is equipped with means of communication between the loading and compression and discharge or decompression chambers, whereby the internal pressures of both chambers can be equalled.
According to a particularly interesting embodiment, the pressure tank is disposed inclined with respect to the horizontal and so that the end equipped with the outlet is raised with respect to the end equipped with the inlet.
Brief description of the drawings
The attached drawings illustrate, by way of non-limitative example, a preferred embodiment of the apparatus for waste treatment object of the invention. In said drawings: Fig. 1 is a longitudinal section view of the apparatus for waste treatment; and
Figs. 2, 3 and 4 are schematic views of the apparatus of Fig. 1 in successive stages of the waste treatment process object of the invention.
Detailed description of the drawings
The apparatus 20 represented in Figs. 1 to 4 is designed for waste treatment, and more particularly treatment of urban solid waste 22a, 22b and
22c and similar industrial waste such as cardboard, office waste and derivatives of industrial processes such as waste from slaughter houses, vegetable plantations, composting plants, etc. In Fig. 1 it is observed that said apparatus 20 is equipped with a fixed pressure tank 1 at whose longitudinal ends 4a and 4b are disposed separate inlets 30 of the waste to treat and outlets 29 of the treated waste 22c and inside which the waste 22b is subjected during a predetermined period of time to determined pressure and temperature conditions in accordance with its composition. Means to transport 21 , turn and/or agitate the waste introduced from the inlet 30 to the outlet 29 are disposed inside the pressure tank 1. The apparatus 20 also comprises a loading or compression chamber 13, a discharge or decompression chamber 16 and means 23 and 24 to increase the pressure inside said chambers from atmospheric pressure until reaching the pressure value inside the pressure tank 1 and vice-versa.
It is convenient to mention that the apparatus 20 operates in continuous process, which means that the waste to treat 22a is introduced inside the pressure tank 1 by the inlet 30 discontinuously, in successive loading units, without interrupting the treatment of the waste 22b which is carried out inside the pressure tank 1 , and the treated waste 22c is extracted from inside the pressure tank 1 in successive discharge units through the outlet 29, also without interrupting the treatment of the waste 22b which continues inside the pressure tank 1. In other words, the operations of introducing and extracting the waste 22a and 22c from inside the pressure tank 1 are simultaneous with the waste 22b treatment operation which is carried out in continuous and uninterrupted form whilst there is waste inside the pressure tank 1 .
With regard to the pressure tank 1 , this preferably has the capacity for housing the content of multiple loading units successively introduced in said pressure tank 1 , which are accumulated therein and are turned and/or mixed in uninterrupted manner, subjected to a pressure over 2 bar and a temperature between 100 QC and 200 QC throughout its retention inside the pressure tank 1 . For said purpose, the pressure tank 1 is equipped with a series of intake conduits 9 of gas, and preferably steam, whereby this is injected inside the pressure tank 1 to maintain the suitable pressure and temperature conditions for the correct waste sanitation 22b.
Due to the fact that inside the pressure tank 1 there is a pressure higher than the outside pressure or atmospheric pressure at which the waste to treat 22a is subjected, the apparatus 20 comprises a loading or compression chamber 13 to compensate this pressure difference and thus be able to introduce the waste inside the pressure tank 1 without significantly altering the pressure conditions inside the pressure tank 1 .
The loading or compression chamber 13, essentially cylindrical and horizontally disposed, is designed to house a loading unit 22a of waste to treat, equipped with separate waste inlet 14a and outlet 12a channels. The outlet channel 12a gives access, through the inlet 30 of the pressure tank 1 , inside said tank, both inlet 14a and outlet channels 12a being provided with respective sluice gates 14 and 12.
To introduce a loading unit of waste to treat 22a inside the pressure tank 1 the following is done. With the sluice gate 12 of the loading or compression chamber 13 closed, a waste loading unit 22a is introduced through its inlet channel 14a (situation represented in Fig. 1 ). Next, the sluice gate 14 is closed and the pressure P1 is increased in the loading or compression chamber 13 by means 23, which inject steam therein, until reaching the pressure P2 value inside the pressure tank 1 . Once the pressures P1 and P2 (situation represented in Fig. 3) are equalled the sluice gate 12 of the loading or compression chamber 13 opens and the waste loading unit 22a is pushed by means of pushing 15, formed by a hydraulic cylinder which can move longitudinally through the inside of the loading or compression chamber 13, to the inside of the pressure tank 1 . It is observed in Figs. 1 to 3 that the outlet channel 12a of the loading or compression chamber 13 is disposed inside the pressure tank 1 so that, when the waste 22a contained in said loading or compression chamber 13 is extracted, it is deposited, by gravity, in the means to transport 21 , turn and/or agitate the waste 22b. Once the waste 22b is inside the pressure tank 1 (situation represented in Fig. 4), the sluice gate 12 of the loading or compression chamber 13 is again closed and said loading or compression chamber 13 is depressurized until reaching the suitable pressure for the opening of its inlet gate 14 and a new cycle of waste is started with the introduction of a new waste loading unit 22a in the inlet or compression chamber 13.
We should mention that varied elements are usually found among the urban solid waste to treat which may have dimensions over those suitable to permit their intake either in the loading or compression chamber 13 or in the pressure tank 1 , which may alter the behaviour of the sluice gates 12 and 14, hindering its subsequent extraction from the pressure tank 1 (for example, in the case of elongated and metal bodies which are not decomposed inside the pressure tank 1 ) or even produce damages therein. In order to avoid these drawbacks, before the operation of introducing a waste loading unit 22a in the loading or compression chamber 13, the waste of said loading unit is sufficiently compacted to deform or break elements that exceed predetermined dimensions or to detect the inclusion of unbreakable elements that exceed said predetermined dimensions. In this last case, the loading unit 22a is temporary rejected and it is separated to be examined, manually or automatically extracting the unbreakable elements, and being later introduced in the inlet or compression chamber 13. In any case, it is not desirable that liquids contained in the container drip during the compacting operation.
In the example of Fig. 1 , the means to transport 21 , turn and/or agitate the waste 22b introduced from the inlet 30 to the outlet 29, comprises a rotary drum 25, coaxial with respect to the pressure tank 1 , having perforated walls 27 and equipped with elements 26 which are projected from the inner surface of the side wall of said rotary drum 25. These projected elements 26 are designed to turn and move in longitudinal direction, respectively, the waste 22b introduced in said rotary drum with rotation around its longitudinal axis.
As has been represented in Fig. 1 , the perforated wall 27 of the rotary drum 25 covers only an end longitudinal portion of said rotary drum 25, corresponding to the reception end of the waste to treat 22a. And unlike conventional apparatus for waste treatment, the waste 22a contained in a loading unit introduced in the pressure tank 1 is instantaneously subjected to the temperature conditions inside the pressure tank 1 causing, among other effects, that the liquids contained in the waste are released at the start of their path through the rotary drum 25, in other words in the area close to the intake end of the pressure tank 1 .
The function of the perforations is to evacuate the water for the interior of rotary drum 25, preventing the waste form flowing towards the exterior of the rotary drum. With the aim of retaining the waste inside the rotary drum, the diameter of the perforations are less than 7 mm, and preferabily are from 1 mm to 4 mm.
Regarding the gap between the perforations, it is from aproximately 5 mm to aproximately 20 mm.
It is also observed in Fig. 1 that the pressure tank 1 is disposed inclined with respect to the horizontal although, unlike the known apparatus, it is the end with the outlet 29 which is raised with respect to the end equipped with the inlet 30. In this way, the steam condensates and the liquids contained in the waste 22b which are precipitated in the pressure tank 1 are extracted therefrom through a connection 2 located in its lower part, in this case the intake end, using the interior overpressure and the inclination of the pressure tank 1. For said purpose, the apparatus 20 for waste treatment comprises a liquid level meter in charge of transmitting an activation signal to a central control system which regulates the extraction of liquids through the connection 2 when the level of liquid accumulated inside the tank exceeds a certain value.
In order to avoid the stopping up of the orifices of the perforated wall 27, the apparatus 20 is equipped with a series of sprinklers 5 designed to inject pressurized steam in a controlled manner against the outer wall of the rotary drum 25, and in particular directed against the portion provided with orifices to give the water free passage through it.
The retention time of the waste 22b inside the pressure tank 1 is determined by the length of the rotary drum 25 and its rotation rate. These parameters are adjusted so that the retention time of the waste, generally between 15 and 20 minutes inside the pressure tank 1 and subjected to the constant pressure and temperature conditions inside, is necessary for its correct sanitation. Once the waste 22b has longitudinally travelled through the rotary drum
25, and, therefore, has remained therein the required time for its correct treatment, it should be extracted from the pressure tank 1. Thus, and in a similar way to the loading or compression chamber 13, the apparatus 20 comprises a discharge or decompression chamber 16 designed to house a discharge unit of treated waste 22c, equipped with separate inlet 17a and outlet channels 18a of the already treated waste, in this case the inlet channel 17a being juxtaposed to the outlet 29 of the pressure tank, which are provided with respective sluice gates 17 and 18.
In collaboration with the inlet 17a and outlet channels 18a, the apparatus 20 comprises means 24 to decrease the pressure inside the discharge or decompression chamber 16 to atmospheric pressure and thus allow the treated waste 22c to be expulsed outside without causing considerable depressurizations or temperature losses inside the pressure tank 1. Due to the fact that the outlet 29 of the pressure tank 1 is disposed on the lower side thereof and that the inlet channel 17a of the discharge or decompression chamber 16 is disposed juxtaposed under said outlet 29, the waste 22c extracted from the pressure tank 1 is introduced in said discharge or decompression chamber 16 by gravity. Fig. 1 represents the sluice gate 17 of the discharge or decompression chamber 16 open, with the corresponding sluice gate 18 closed, so that the waste 22c discharged by the rotary drum 25 is deposited in said discharge or decompression chamber 16.
To extract a treated waste loading unit 22c from inside the pressure tank 1 the following is carried out. Once the waste 22c has been deposited in the discharge or decompression chamber 16, the sluice gate 17 of said discharge or decompression chamber 16 closes (situation represented in Fig. 2) and the discharge or decompression chamber 16 is depressurized until the pressure P3 therein approaches or is equal to the pressure outside the apparatus. Next, the sluice gate 18 opens expulsing the waste 22c outside (situation represented in Fig. 3) which falls by gravity, the sluice gate 18 again closing (situation represented in Fig. 4) to start a new discharge cycle of the treated waste 22c which starts increasing the pressure P3 inside the discharge or decompression chamber 16 until the value of the pressure P2 inside the pressure tank 1 is reached.
As is shown in Figs. 2, 3 and 4, the apparatus 20 for waste treatment may be equipped with means of communication 28 between the loading or compression 13 and discharge or decompression chambers 16, whereby the internal pressures of both chambers can be equalled.
Thus, in Fig. 2 the loading unit of waste to treat 22a is found in the loading or compression chamber 13 at a pressure P1 lower than the pressure P2 inside the pressure tank, which makes it necessary to increase the pressure P1 until reaching the value of the pressure P2 to introduce the waste in the pressure tank 1 without significantly altering the pressure conditions inside said pressure tank 1. At the same time, the already treated waste 22c has just come out of the inside of the pressure tank 1 , which means the value of the pressure P3, equal to the pressure P2 inside the pressure tank 1 , is higher than the outside or atmospheric pressure necessary to be able to expulse said waste 22c to the outside in a controlled and safe manner. Through the means of communication 28, the pressures P1 in the loading or compression chamber 13 and P3 in the discharge or decompression chamber 16 are equalled, i.e. the excess pressure from the depressurization of the waste 22c contributes to the increase in pressure of the waste loading unit 22a. Similarly, in the situation represented in Fig. 4, the pressure P1 in the loading or compression chamber 13, previously in communication with the inside of the pressure tank 1 , is equal to the pressure P2 inside said pressure tank 1 , which is higher than the outside or atmospheric pressure at which the loading units of the waste to treat 22a is found. Thus, before admitting a new waste loading unit 22a in the loading or compression chamber 13 this should be depressurized. At the same time, the discharge or decompression chamber 16 has just expulsed the waste 22c for which reason it is found at a pressure P3 close to the outside or atmospheric pressure. To be able to again receive the waste 22c from the inside of the pressure tank 1 without altering the pressure conditions inside said pressure tank 1 , it will be necessary that the pressure P3 inside the discharge or decompression chamber 16 increases until reaching the value of the pressure P2 inside the pressure tank. Through the means of communication 28, the excess pressure from the depressurization of the loading or compression chamber 13 will contribute to the pressurization of the discharge or decompression chamber 16 necessary to admit the waste 22c therein.
Throughout the waste treatment process, the pressure and temperature conditions inside the pressure tank 1 are essentially maintained constant, it only being necessary to compensate the small pressure and temperature losses therein as a consequence of the operations of introduction and extraction of the waste inside it, but in no case being necessary to raise the pressure and the temperature from the ambient conditions outside the apparatus each time new waste is introduced in the pressure tank 1.

Claims

C L A I M S
1. Process for waste treatment, particularly suitable for urban solid waste (22a; 22b and 22c) and similar industrial waste, characterized in that it comprises the continuous operation of
- treating the waste (22b) in a closed enclosure, turning it and/or mixing it and subjecting it in an uninterrupted manner during its retention in the closed enclosure to a pressure over 2 bar and a temperature between 100QC and 200QC, and the discontinuous operations of - subjecting to pressure, one by one, successive waste loading units and introducing them, also one by one, inside the closed treatment enclosure; and
- extracting from the closed treatment enclosure and decompressing, also one by one, several already treated waste discharge units, performing the corresponding compression and decompression operations in respective loading or compression chambers (13) and discharge or decompression chambers (16), wherein the pressure to which the waste is subjected is increased from ambient pressure to that of inside the closed enclosure and vice-versa, respectively, compensating the small pressure and temperature losses inside the closed enclosure, whose values are maintained essentially constant, after the waste introductions and extraction operations.
2. Process according to claim 1 , characterized in that the waste of multiple loading units successively introduced in the closed enclosure is accumulated.
3. Process according to the preceding claims, characterized in that the closed treatment enclosure is a pressure tank (1 ), inside which the waste (22b) is made to pass through a rotary drum (25), coaxial with the pressure tank, of perforated walls (27) through which the liquids may flow towards the exterior of the rotary drum.
4. Process according to claim 3, characterized in that the perforations are of aproximately 1 mm to aproximately 7 mm of diameter.
5. Process according to the preceding claims, characterized in that a communication is established between said loading or compression chambers
(13) and discharge or decompression chambers (16) designed to equal the pressures in both chambers at least during the compression and decompression operations.
6. Process according to the preceding claims, characterized in that, before the introduction operation of a waste loading unit (22a) in the loading or compression chamber (13), the waste of said loading unit is sufficiently compacted to deform or break elements that exceed predetermined dimensions or to detect the inclusion of unbreakable elements that exceed said predetermined dimensions, avoiding the unnecessary dripping of liquids contained in the waste, to authorize the introduction of the loading unit in the loading or compression chamber, and subsequently in the closed receptacle, or temporarily reject it.
7. Apparatus (20) for waste treatment, particularly urban solid waste (22a; 22b and 22c) and similar industrial waste, equipped with a fixed pressure tank
(1 ) being arranged at one longitudinal end (4a) an inlet (30) of the waste to treat and an outlet (29) at the other longitudinal end (4b) of the treated waste, being disposed inside the pressure tank means to transport (21 ) the waste introduced from the inlet to the outlet of the pressure tank and turn and/or agitate said waste, characterized in that it comprises
- a loading or compression chamber (13) designed to house a loading unit of the waste to treat (22a), equipped with separate inlet (14a) and outlet channels (12a) of the waste of which the outlet channel gives access, through the inlet (30) of the pressure tank, to inside said pressure tank, both inlet and outlet channels being provided with respective sluice gates (12; 14);
- a discharge or decompression chamber (16) designed to house a discharge unit of treated waste (22c), equipped with separate inlet (17a) and outlet channels (18a) of the already treated waste, of which the inlet channel is juxtaposed to the outlet (29) of the pressure tank, both inlet and outlet channels being provided with respective sluice gates (17; 18); and
- means (23, 24) to increase and decrease the pressure inside the loading or compression (13) and discharge or decompression chambers (16) from atmospheric pressure until reaching the value of the pressure inside the pressure tank and vice-versa, respectively.
8. Apparatus (20) according to claim 7, characterized in that the means to transport (21 ), turn and/or agitate the waste (22b) inside the pressure tank (1 ) comprise a rotary drum (25), coaxial with respect to the pressure tank, of perforated walls (27) and equipped with elements (26) which are projected from the inner surface of the side wall of said rotary drum, designed to turn and to move in longitudinal direction, respectively, the waste introduced therein with the rotation of the rotary drum around its longitudinal axis.
9. Apparatus according to claim 8, characterized in that the diameter of the perforations are of aproximately 1 mm to aprox. 7 mm., in order to prevent the waste from flowing towards the exterior of the tubular body but enabling the liquids released by the waste to flow through said perforations.
10. Apparatus (20) according to the preceding claim, characterized in that the walls of the rotary drum (25) are only perforated along an end longitudinal portion of said rotary drum, corresponding to the reception end of the waste.
1 1. Apparatus according to claims 7 to 10, characterized in that the outlet channel (12a) of the loading or compression chamber (13) is disposed inside the pressure tank (1 ) so that, when the waste (22a) contained in said loading or compression chamber is extracted, it is deposited, by gravity, in the means to transport (21 ), turn and/or agitate the waste.
12. Apparatus (20) according to the preceding claim, characterized in that the loading or compression chamber (13) of the waste (22a) is essentially cylindrical and is disposed horizontally, and in that it is equipped with means of pushing (15) the waste contained in the direction of the outlet channel (12a).
13. Apparatus (20) according to the preceding claim, characterized in that the means of pushing (15) comprise a hydraulic cylinder which can move longitudinally through the inside of the loading or compression chamber (13).
14. Apparatus (20) according to the claims 7 to 13, characterized in that the outlet (29) of the pressure tank (1 ) is disposed on the lower side thereof and in that the inlet channel (17a) of the discharge or decompression chamber (16) is disposed juxtaposed under said outlet, so that the waste (22c) extracted from th e pressure tank is introduced, by gravity, in said discharge or decompression chamber.
15. Apparatus (20) according to the claims 7 to 14, characterized in that it is equipped with means of communication (28) between the loading or compression (13) and discharge or decompression chambers (16), whereby the internal pressures of both chambers can be equalled.
16. Apparatus (20) according to the claims 7 to 15, characterized in that the pressure tank (1 ) is disposed inclined with respect to the horizontal and so that the end equipped with the outlet (29) is raised with respect to the end equipped with the inlet (30).
PCT/EP2007/062353 2006-11-27 2007-11-14 Process and apparatus for waste treatment WO2008065002A2 (en)

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EP07847168.7A EP2086595B1 (en) 2006-11-27 2007-11-14 Process and apparatus for waste treatment

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CN101541352A (en) 2009-09-23
ES2324075A1 (en) 2009-07-29
CN101541352B (en) 2014-08-06
EP2086595B1 (en) 2015-08-19
ES2324075B1 (en) 2010-05-25
EP2086595A2 (en) 2009-08-12
ES2557929T3 (en) 2016-01-29
WO2008065002A3 (en) 2008-11-27

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