WO2008062242A2 - Équipements de traitement de matériaux organiques et de déchets principalement issus de pneus, de caoutchouc ou de matières plastiques - Google Patents

Équipements de traitement de matériaux organiques et de déchets principalement issus de pneus, de caoutchouc ou de matières plastiques Download PDF

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Publication number
WO2008062242A2
WO2008062242A2 PCT/HU2007/000110 HU2007000110W WO2008062242A2 WO 2008062242 A2 WO2008062242 A2 WO 2008062242A2 HU 2007000110 W HU2007000110 W HU 2007000110W WO 2008062242 A2 WO2008062242 A2 WO 2008062242A2
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WIPO (PCT)
Prior art keywords
reactor
stub
demand
coal
typical
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Application number
PCT/HU2007/000110
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English (en)
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WO2008062242A3 (fr
Inventor
András URBÁN
Zsolt TÓTH
Original Assignee
Urban Andras
Toth Zsolt
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Application filed by Urban Andras, Toth Zsolt filed Critical Urban Andras
Publication of WO2008062242A2 publication Critical patent/WO2008062242A2/fr
Publication of WO2008062242A3 publication Critical patent/WO2008062242A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/20—Stationary reactors having moving elements inside in the form of helices, e.g. screw reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05—Stirrers
    • B01F27/11—Stirrers characterised by the configuration of the stirrers
    • B01F27/112—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades
    • B01F27/1122—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades anchor-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05—Stirrers
    • B01F27/11—Stirrers characterised by the configuration of the stirrers
    • B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
    • B01F27/192—Stirrers with two or more mixing elements mounted in sequence on the same axis with dissimilar elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/23—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis
    • B01F27/232—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes
    • B01F27/2323—Mixers with rotary stirring devices in fixed receptacles; Kneaders characterised by the orientation or disposition of the rotor axis with two or more rotation axes with perpendicular axes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
    • B01F27/72—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with helices or sections of helices
    • B01F27/726—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with helices or sections of helices with two helices with opposite pitch on the same shaft; with two helices on the same axis, driven in opposite directions or at different speeds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/92—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with helices or screws
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/006—Processes utilising sub-atmospheric pressure; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/008—Feed or outlet control devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/32—Other processes in ovens with mechanical conveying means
    • C10B47/40—Other processes in ovens with mechanical conveying means with endless conveying devices
    • C10B47/42—Other processes in ovens with mechanical conveying means with endless conveying devices in vertical direction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/32—Other processes in ovens with mechanical conveying means
    • C10B47/44—Other processes in ovens with mechanical conveying means with conveyor-screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/02—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
    • F28D7/024—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00085—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/0009—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics

Definitions

  • Equipments for processing organic materials and waste materials principally tyre and rubber or plastic material
  • the object of the contrivance is equipments for processing organic materials and waste materials, principally tyre and rubber or plastic material.
  • the object of the contrivance is specifically is a reactor for the thermic cracking of organic materials and refuse, principally tyre and rubber or plastic waste material, and producing active coal, and a cooling system for the refrigeration of false coal or soot.
  • the further treatment of the flue gas might be necessary depending on the composition of the waste material which is burnt.
  • the thermic tranformation of the waste material might be more economical which offers an opportunity for extracting decomposition product that may be utilized as raw material too.
  • false coal is often produced too, which can be transformed into active coal and it is also a valuable raw material as false coal too.
  • the reaction products arising in the thermic cracking reaction are not used only for producing heat but they can be realized also as raw material.
  • the arising products are usually of higher temperature than the usual temperature of the environment, so because of the temperature difference they have utility heat energy, without burning too, which may also be used for reducing the energy demand of the process.
  • the aim is achieved so, that the steps of the process based on the thermic cracking and the step of the process important regarding the heat transfer is done in a separated reactor regarding the process, on the other side the reactors are shaped according to the different steps of the process.
  • the cracking process might be done by more favourable conditions not only in the respect of energy utilization but the materials that arise during the chemical process may be regulated more easily in the way that results cheaper products.
  • the object of the contrivance is a reactor appropriate for the thermic cracking of organic materials and refuse, principally tyre and rubber or plastic material.
  • the object of the contrivance is furthermore a reactor producing active coal.
  • the object of the contrivance is furthermore the produce of a cooling system for the refrigeration of false coal or soot.
  • the object of the contrivance is furthermore a chemical technological device for processing organic materials and material, principally tyres and rubber or plastic material.
  • the reactor body according to the contrivance is equipped with a power unit, a mixer, a pulley appropriate for mixing or a transferring, a fuel oil or a fuel gas intake premixing chamber, heating unit, and a carbon-dioxide doser, a reactor gas stub, a basic material- dosing stub, and a flue gas stub, an air stub and a soot- gathering stub.
  • a special mixing device is developed so that a centrally located, vertical pulley serves as a recirculating mixer, on which a pair of mixing element is located in a single axis.
  • the reactor body is equipped with a horizontal pulley that runs in the lower third of it.
  • the horizontal pulley is developed into a single unit containing a section of reverse angle with equal rotation direction .
  • an infraradiant burner that is in touch with the prechamber, is located.
  • the infraradiant burner is connected with the tube reactor for a follow-up pirolization in a concrete case.
  • the reactor that serves the development of active coal is similarly developed as the reactor that serves the thermic cracking, with the difference that it possesses nitrogen-dosing stub, the pirolizis gas stub, the soot-dosing stub, water vapour-blow stub and active coal-gathering stub.
  • the cooling equipment for cooling the false coal or soot is developed similarly as the reactors mentioned previously, with the difference that it is equipped with a false coal-dosing stub, a warm air stub, an air blowing stub and a coal- gathering stub.
  • an advantegously liquid cooling equipment is located in the cooling equipment.
  • the heat energy of the liquid-cooling equipment driven through the heat exchanger offers an opportunity for further energy utilization.
  • the air used for heating the reactor can be preheated or this heat might be used for preheating the basic material and the heat conservation.
  • the chemical equipment for processing organic materials and waste materials principally tyre and rubber or plastic material possesses a reactor for thermic cracking which makes the object of the contrivance, a reactor for producing active coal, and a cooling system for the refrigeration of false coal or active coal.
  • the 4. draft is the schematic illustration of a complex technologic machine.
  • the 1. illustration shows a possible development of a reactor appropriate for the thermic cracking operating at almost athmospheric or lower pressure.
  • the reactor body equipped with 9 reactor gas stub, 10 basic material-dosing stub, 11 fuel gas stub, 12 soot-gathering stub and closing accessories has 2 mixing elements driven with 13 power unit, 3 vertical pulley developed as a recirculating mixer, 4 horizontal pulley, 8 carbon-dioxide dosers, 26 air stub, and a heating unit.
  • the mixers are frequency-controlled driven by 13 power unit.
  • the heating unit is advantageously consists of a burner with 5 premixing chamber, which is connected with 6 infraradiant burner.
  • the 6 infraradiant burner made of silicon-carbon is advantageously appropriate as heating unit, which enables an energy saving heat transmission, while it terminates the burning reaction and the heat- cracking reaction from each other.
  • horizontal pulley is developed in the lower third of it, which have two sections of reverse angle with equal rotation direction.
  • the two sections of reverse angle with equal rotation direction is shaped into a single unit. This is advantegous because of the mixing and the conveying.
  • One pair of the mixing elements of the cracking reactor is equipped advantageously close to the inner wall of the 1 reactor body, while the two mixing elements of the other pair is equipped close to the 3 vertical pulley, which is enables an advantageous flow inside the reactor body.
  • the 6 infraradiant burner is bounded to the 7 pirolizing tube reactor used for follow-up pirolizing. This development of the heating unit enables advantageously the execution of parallell thermic cracking processes, mainly pirolises.
  • the gaseous components of the thermic cracking leave the reaction space through the 9 reactor gas stub.
  • the 9 reactor gas stub is bounded to usual technologic devices for the cleaning, the separation and further process of the decomposition products.
  • the 7 pirolizing tube reactor is bounded close to the heating element.
  • the components of the decomposition products leaving the cracking reactor that need further cracking can be cracked further with little loss of heat.
  • the accessories of the cracking reactor that assort with the basic material directly, are made of austinated steel of high nickel content.
  • the 2. draft reviews a false coal-activating reactor for the further process of false coal produced in the cracking reactor.
  • the advantagous development of the reactor serving the activation of false coal or soot is illustrated.
  • the 2. draft reviews a false coal-activating reactor serving the further process of false coal produced in the cracking reactor, which is a false coal-activating reactor developed with a 1 reactor body operating at atmospheric or at a more advantageously lower pressure than the atmospheric pressure.
  • the reactor illustrated on the 2. draft is developed very similarly to the cracking reactor illustrated on the 1. draft.
  • the false coal-activating reactor has a heating reactor similarly developed as the cracking reactor illustarted on the 1.
  • the false coal-activating reactor has 2 mixing element equally developed to the cracking reactor, its 3 vertical pulley furthermore 4 horizontal pulley developed to centrally located, recirculating mixer.
  • the reactor that serves the activation of the false coal has 14 nitrogen-dosing stub, 15 pirolisis gas stub, 16 soot-dosing stub, 17 water vapour -blowing stub, 26 air stub and 23 active coal-gathering stub.
  • the 6 infraradiant burner with the 5 premixing chamber can be applied economically. Beside the fuel gas and fuel oil other substances that are inappropriate for further processing and may arise from pirolisis either and crack gas or crack oil can also be burnt. The burning product not demanding further making harmless might be driven through 11 flue gas stub and technologic establishments serving preheating or heat conservation and can be bounded straight to the chimney.
  • the 7 pirolizing tube reactor is made of not austenited steel alloy with an advantageously high nickel-content.
  • the reactor developed to perform a thermal operation is also appropriate for cooling the coal arisen in the cracking reactor and the false coal-activating reactor.
  • the mechanic development of the rector is similarto the development of the cracking recator, illustrated on the 1. draft and the false coal-activating rector, illustrated on the 2. draft with the difference that instead of the heating unit accessories serving the cooling are built in the reactor.
  • the cooling equipment operates at atmospheric pressure or at higher pressure than the atmospheric. In the cooling equipment 2 mixing element inside 1 reactor body and 3 vertical pulley, and 4 horizontal pulley, that is developed into a centrally located, recirculating mixer, are built in.
  • the cooling equipment possesses 22 false coal-dosing stub, 19 air-blowing stub, 18 warm air stub, 20 soot-gathering stub and a 21 spiral-executed liquid heat exchangers.
  • the 21 liquid refrigerator is configured so that the equipment is able to preheat the air advantageously at the same time.
  • the elements of the cooling equipment serving the mixing that are configured equal to the mixing elements of the cracking and the false coal-activating reactor, are operated by 13 frequency-controlled power unit.
  • liquid heat-exchanger may be configured fitting the complex technologic equipment if it is developed as a liquid heat spiral inside 1 reactor body that it contains a space appropriate for preheating the air.
  • the operation time of the cooling may be advantageously reduced as well and conveying out the final product can be simplified.
  • the 4. draft is the outline of a complex technologic flowchart, which reviews the schemic execution of a complex technologic equipment, that can be developed by a possible connection of the cracking reactor according to the 1. draft and the false coal-activating reactor according to the 2. draft and the cooling equipment according to the 3. draft.
  • the equipments of the supplementary operation ranges are illustrated only schematically, the substential characteristic of the draft is that no technologic equipment for operating any catalyzer or material flow are illustrated. Since an important advantage of the complex technology is that there are no processing steps of the catalyzer, and no material flow for operating and regenerating the separating catalyzer because of the appropriate selection of the structure material.
  • the schematic flowchart (4. draft) of the complex technology reviews only the connection of the cracking reactor, the false coal-activating and the suggested cooling equipment, representing the usually applied technologic equipments and connecting points.
  • the cracking reactor is bounded to the 27 basic material-dosing machine through 10 basic material stub.
  • the 20 soot-gathering stub of the cooling equipment is joins the 22 false coal-dosing stub of the cooling equipment.
  • the 20 soot-gathering stub of the cooling equipment is bounded to the 28 final product processing row.
  • the 27 basic material -dosing receiver and the cracking reactor join the 29 chimney through the 11 flue gas stub.
  • the 18 warm air stub of the cooling equipment is connected to the 26 air stub of the cracking reactor.
  • the solid final product is coal.
  • the false coal may be transformed to activated coal as well.
  • the connecting method in the right side of the 4. draft comes into operation.
  • the 16 soot-dosing stub of the false coal-activating reactor diverges from the 28 processing row and its 11 flue gas stub is bounded to the 29 chimney.
  • the 23 active soot-gathering stub is connected to the 22 false coal -dosing stub of the cooling equipment.
  • the 18 warm air stub of the cooling equipment is connected to the 26 air stub of the false coal-activating reactor, while its 20 soot-gathering stub is in touch with the 28 final product row.
  • the oxigen content is reduced in the cracking reactor by dosing carbon-dioxide through 8 carbon-dioxide-doser before filling.
  • the cracking reactor can be filled with dimensioned preheated basic material through 27 basic material equipment.
  • the heating unit reviewed on the 1. and 2. draft serves the heating or if required the preheating of the cracking reactor.
  • the heat of the side by side operating reactor can also be applied. This heat may also derive from the cooling equipment according to the 3. draft.
  • the cracking oil and cracking gas sorts of components in the 5 premixing chamber. The oil or the gas is portioned in the 5 premixing chamber through the 25 fuel oil or 24 fuel gas intake.
  • the temperature is raised and the charge of the reactor is cracked by operating the heating elements, advantageously applying three heating units.
  • the heat energy leaving through the 11 flue gas stub can be utilized advantageously for preheating the basic material and conservating it at 15O 0 C .
  • This is an advantageous temperature because the possibilty of self-ignition may be eliminated and the demand for the thermic cracking can be reduced as well by fractional incorporation.
  • the cracking is done at 200 - 1200 °C, advantageously at 350 - 600 °C by operating the 3 vertical pulley and the 4 horizontal pulley and the 2 mixing elements continuously.
  • the cracking is executed at almost atmospheric pressure or reduced atmospheric pressure. Different polimers can be cracked advantageously in the range of 0,2 — 2 bar pressure.
  • the adherence of the basic material inside the reactor must be specially observed during the cracking.
  • the adherence of the basic material is specially harmful if the mixture of inhomogeneous substantial composition, for instance wired chopped tyre surrounded by rubber is cracked.
  • the basic material that adherences on the structural elements of the reactor for a long time is disadvantageous in the respect of the composition of the reactor gas arisen in the thermic cracking.
  • the 26 air stub of the cracking reactor is kept in a closed position during normal operation and the composition of gas in the reactor is observed continuously. By emergency shotdown the 26 air stub might also be applied for vaccine overflow
  • the fraction of the long coal range (mainly of liquid base) of the compound leaving through the 9 reactor gas stub can be processed directly or they can be pirolized advantageously into substances of shorter coal range in a 7 pirolizing tube reactor connected to the 6 infraradiant burner.
  • the cracking oils and other fractioned products produced in the thermic cracking reaction which relatively arise in a small quantity, may be processed fractionally in the 7 pirolizing tube reactor, which is connected to the 6 infraradiant burner.
  • thermic cracking of further portion of basic material can be executed.
  • the false coal gets into the cooling equipment, where it is cooled to 250 -350 0 C, advantageously to under 300 0 C.
  • the false coal dependent of the kind of the basic material, is driven through the separator of the 28 final product-processing row and the metallic remains, which are realizable separately, can be extracted out of it.
  • the cooling of the false coal takes place in the cooling equipment. If the products that are rich in hydrocarbons, leaving through the 9 reactor gas stub, are processed by further operations, can be realized as chemical basic materials or source of energy.
  • the soot-like false coal can be realized as substantive final products.
  • the connecting method which is illustrated on the 4. draft serves the production of active coal.
  • the false coal that is soot-like regarding its composition, arisen in the cracking reactor, is filled from the soot receiver of the 28 final product-processing row through the 16 soot-dosing stub in the false coal activating reactor. Before take in and under this period the oxygen- discharge in the false coal activating reactor is superintended. Under the period of the portioning and in the period of the heat conservation of the activation, the activation id done with nitrogen, after the period of heat conservation the activation is done with different steam/nitrogen compounds, advantageously with 75/25 proportioned compound. From the take in to the gathering of the final product, the material filled in the reactor is stirred by the 2 mixing elements and the 3 vertical pulley and the 4 horizontal pulley.
  • the false coal-activating reactor is heated to 600 - 1000 °C, advantageously to 800 - 850 0 C by burning the fuel mixture mixed in the 5 mixing chamber and burnt in the 6 infraradiant burner. Meanwhile the pressure of the reactor is kept at a rate that is smaller than the atmospheric pressure, advantageously at 0,1 — 0,5 bar. In order to produce active coal of a deliberately good quality the specially advantageous balance pressure should be maintained, which is important in the sight of the quality of the material being produced in the activating step.
  • the nitrogen and the water portioning the 15 pirolisis gas stub is closed, and the active coal is conveyed out by the 4 horizontal pulley through the 23 active coal-gathering stub into the cooling equipment.
  • the cooling is done at 250 -350 °C, advantageously under 300 °C, beside excluding oxygen.
  • the active coal is processed on the 28 final product-processing row.
  • the heating unit of the cracking and false coal activating reactor and the liquid and air- cooling ranges can be connected to further technologic equipments, and hereby the energy demand of the complex technology can be reduced.
  • the reactors and the technologic equipments according to the contrivance polimers chopped to 1-10 cm and organic substances and waste materials advantageously to 2-8 cm chopped rubber, 2-6 cm chopped tyre, 2-8 cm chopped different plastics, for instance different polyethylenes, polyprophyles, polystyrenes, polyamids and other plastcis, or the mixtures of them that are unclassed regarding the material quality.
  • the energy demand of the accomplishment might be reduced by utilizing the waste heat.
  • the complex technology may be appropriate for the thermic cracking of different basic materials by proportional guidance.
  • the premixing chamber-infraradiant burner development is not only favourable energetically , but its further advantage is that the investment demand and its maintanance of the thermic cracking is more favourable as well.
  • the flue gas range it is not necessary to establish and operate a technologic investment, that is usual for the treatment and making harmless of the further flue gas components, arising beside the carbon-dioxides.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un équipement de craquage thermique, un dispositif de refroidissement et un équipement de production de charbon actif ainsi qu'une ligne technologique (graphique 4) qui matérialise le recyclage par rayonnement infrarouge du caoutchouc, des déchets de caoutchouc (comprenant le caoutchouc des câbles), des matières plastiques et des déchets de matières plastiques ainsi que d'autres matériaux ou déchets organiques. Après broyage du matériau de base (graphique 1) jusqu'à atteindre la dimension appropriée, ledit matériau est ajouté dans le réacteur de craquage (graphique 1). La chaleur nécessaire à la dégradation thermique est produite par un système de chauffage par infrarouge (6) dans lequel est incorporée une unité de partie de pyrolyse (7). Pendant la réaction, des paramètres déterminés au préalable peuvent amener le procédé à former des hydrocarbures liquides ou gazeux. Après raffinage dans les tours de distillation, les hydrocarbures liquides/gazeux produits après condensation et après décontamination de la bouillie sont acheminés dans des contenants. La suie produite est refroidie soit dans un dispositif de refroidissement (graphique 3) puis classée et réalisée directement, soit dans un réacteur à charbon actif où elle est transformée en charbon actif (graphique 2).
PCT/HU2007/000110 2006-11-22 2007-11-21 Équipements de traitement de matériaux organiques et de déchets principalement issus de pneus, de caoutchouc ou de matières plastiques WO2008062242A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HUP0600863 2006-11-22
HU0600863A HUP0600863A2 (en) 2006-11-22 2006-11-22 Method and apparatus for thermic cracking of scrap rubber and other organic materials

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WO2008062242A2 true WO2008062242A2 (fr) 2008-05-29
WO2008062242A3 WO2008062242A3 (fr) 2008-07-24

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011102726A1 (fr) * 2010-02-19 2011-08-25 Enerpy B.V. Procédés et procédures pour la production de produits utiles à partir de déchets
WO2011150588A1 (fr) * 2010-06-02 2011-12-08 华南再生资源（中山）有限公司 Matériel de production pour l'utilisation exhaustive de ressources énergétiques renouvelables constituées de déchets de matières plastiques, de pneus et d'huile pour moteur usée
WO2014090574A1 (fr) * 2012-12-13 2014-06-19 Qinetiq Limited Système de traitement thermique comportant un agencement de vis sans fin et son procédé d'utilisation
WO2022174463A1 (fr) * 2021-02-22 2022-08-25 苏州昇特智能科技有限公司 Dispositif de dosage destiné à être utilisé dans des ingrédients d'impression et de teinture

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000053385A1 (fr) * 1999-03-09 2000-09-14 Svedala Industries, Inc. Processus de pyrolyse permettant de recuperer des matieres souhaitables de pneus de vehicules
WO2001044405A1 (fr) * 1999-12-14 2001-06-21 Tirenergy Corporation Procede pour la pyrolyse de dechets de pneus et systemes de pyrolyse de pneus
WO2002026914A2 (fr) * 2000-09-29 2002-04-04 Federal Recycling Technologies, Inc. Appareil et procede de recuperation de produits commercialisables a partir de caoutchouc de rebut
EP1647589A2 (fr) * 2004-09-25 2006-04-19 Alpo Co., Ltd. Installation de pyrolyse pour traiter des déchets de polymères synthétiques
WO2007000257A1 (fr) * 2005-06-29 2007-01-04 I.T.E.R. S.R.L. Procede de rupture de chaines carbones de molecules organiques dans des materiaux solides et appareil associe

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000053385A1 (fr) * 1999-03-09 2000-09-14 Svedala Industries, Inc. Processus de pyrolyse permettant de recuperer des matieres souhaitables de pneus de vehicules
WO2001044405A1 (fr) * 1999-12-14 2001-06-21 Tirenergy Corporation Procede pour la pyrolyse de dechets de pneus et systemes de pyrolyse de pneus
WO2002026914A2 (fr) * 2000-09-29 2002-04-04 Federal Recycling Technologies, Inc. Appareil et procede de recuperation de produits commercialisables a partir de caoutchouc de rebut
EP1647589A2 (fr) * 2004-09-25 2006-04-19 Alpo Co., Ltd. Installation de pyrolyse pour traiter des déchets de polymères synthétiques
WO2007000257A1 (fr) * 2005-06-29 2007-01-04 I.T.E.R. S.R.L. Procede de rupture de chaines carbones de molecules organiques dans des materiaux solides et appareil associe

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011102726A1 (fr) * 2010-02-19 2011-08-25 Enerpy B.V. Procédés et procédures pour la production de produits utiles à partir de déchets
CN102892872A (zh) * 2010-02-19 2013-01-23 恩尔彼有限公司 由废料生产有用产物的方法以及步骤
US9068133B2 (en) 2010-02-19 2015-06-30 Enerpy B.V. Photonic radiolysis of waste materials
CN105602643A (zh) * 2010-02-19 2016-05-25 恩尔彼有限公司 由废料生产有用产物的方法以及步骤
RU2607632C2 (ru) * 2010-02-19 2017-01-10 Энерпи Б.В. Фотонный радиолиз отходов
JP2017060938A (ja) * 2010-02-19 2017-03-30 エネルピー ベー．フェー．Ｅｎｅｒｐｙ Ｂ．Ｖ． 廃材から有用な製品を製造するための方法および手順
WO2011150588A1 (fr) * 2010-06-02 2011-12-08 华南再生资源（中山）有限公司 Matériel de production pour l'utilisation exhaustive de ressources énergétiques renouvelables constituées de déchets de matières plastiques, de pneus et d'huile pour moteur usée
WO2014090574A1 (fr) * 2012-12-13 2014-06-19 Qinetiq Limited Système de traitement thermique comportant un agencement de vis sans fin et son procédé d'utilisation
WO2022174463A1 (fr) * 2021-02-22 2022-08-25 苏州昇特智能科技有限公司 Dispositif de dosage destiné à être utilisé dans des ingrédients d'impression et de teinture

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HUP0600863A2 (en) 2009-10-28
HU0600863D0 (en) 2007-01-29

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