WO2008053871A1 - Air purifier - Google Patents

Air purifier Download PDF

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Publication number
WO2008053871A1
WO2008053871A1 PCT/JP2007/071082 JP2007071082W WO2008053871A1 WO 2008053871 A1 WO2008053871 A1 WO 2008053871A1 JP 2007071082 W JP2007071082 W JP 2007071082W WO 2008053871 A1 WO2008053871 A1 WO 2008053871A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
air
nozzle
air purification
purification device
Prior art date
Application number
PCT/JP2007/071082
Other languages
French (fr)
Japanese (ja)
Inventor
Masahiko Asano
Hitoshi Yagi
Koji Yamanaka
Haruyo Suzuki
Masashi Fujita
Original Assignee
Misawa Homes Co., Ltd.
Organo Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Misawa Homes Co., Ltd., Organo Corporation filed Critical Misawa Homes Co., Ltd.
Priority to JP2008542129A priority Critical patent/JPWO2008053871A1/en
Priority to CN2007800396581A priority patent/CN101535729B/en
Publication of WO2008053871A1 publication Critical patent/WO2008053871A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/10Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
    • F24F8/117Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering
    • F24F8/133Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering by direct contact with liquid, e.g. with sprayed liquid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/14Packed scrubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44Ion-selective electrodialysis
    • B01D61/46Apparatus therefor
    • B01D61/48Apparatus therefor having one or more compartments filled with ion-exchange material, e.g. electrodeionisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/30Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ionisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents

Definitions

  • the present invention relates to an air purification device, and more particularly to a technique for purifying air sent to a house or the like.
  • a ventilator is installed in a house, and outside air is taken into the house by the ventilator to ventilate the house.
  • the outside air contains NOx, SOx, NH4, and other gases and dust, and these are also taken into the house by the ventilator.
  • a ventilator equipped with a filter is installed in the house, dust is collected by the finotor, and purified air is taken into the house (for example, Japanese Patent Application Publication No. 2003- 21375).
  • the water-type air purification device As a device for purifying air using water without using a filter. Therefore, the water-type air purification device accumulates a constant amount of water in the bottom of the water tank, blows air into the water, and brings the air into contact with water.
  • the filter cannot sufficiently remove gases such as NOx, SOx, NH4, etc. in the outside air that cause bad odors, and gas such as NOx, SOx, NH4, etc. is taken into the house.
  • the main object of the present invention is that almost no cleaning or replacement of the filter is required, and gases such as NOx, SOx, NH4, and other gases that cause odors can be removed and taken into the house. Furthermore, it is to provide an air purification device that can purify air even with a low-power blower.
  • a cleaning tower having an internal space that communicates with an intake port and also communicates with an exhaust port, and air is taken into the internal space of the cleaning tower from the intake port.
  • a blower for sending air to the outside of the washing tower; and a nozzle arranged in the internal space of the washing tower for spraying water in the internal space of the washing tower, wherein the water sprayed from the nozzle is
  • An air purification device is provided that contacts the air blown by the blower in the cleaning tower.
  • FIG. 1 is a schematic view showing the air purification device in a first embodiment of the present invention in a broken state.
  • FIG. 2 is a schematic diagram showing the air purification device in a second embodiment of the present invention in a broken state.
  • FIG. 3 is a schematic view showing an air purification device in a third embodiment of the present invention in a broken state.
  • FIG. 4 A graph showing the measurement results of the concentration of NOx contained in the air at the intake and exhaust ports.
  • FIG. 5 is a schematic view showing a state in which an air purification device according to a fourth embodiment of the present invention is broken.
  • FIG. 6 is a perspective view showing a bag provided in the gas-liquid contact structure of the air purification device in the fourth embodiment.
  • FIG. 7 is a schematic view showing a state in which an air purification device according to a fifth embodiment of the present invention is broken.
  • FIG. 8 is a perspective view showing a bag provided in a gas-liquid contact structure of an air purification device in a fifth embodiment.
  • FIG. 9 is a schematic view showing an air purification device in a broken state according to a sixth embodiment of the present invention.
  • FIG. 10 is a schematic view showing an air purification device in a broken state according to a seventh embodiment of the present invention.
  • FIG. 11 shows a modification of the plate provided in the gas-liquid contact structure of the air purification device according to the seventh embodiment. It is the shown schematic.
  • FIG. 12 is a schematic view showing a modification of the plate provided in the gas-liquid contact structure of the air purifying device in the seventh embodiment.
  • FIG. 13 is a schematic view showing an air purification device in a broken state according to an eighth embodiment of the present invention.
  • FIG. 14 A graph showing the measurement results of the concentration of NOx contained in the air at the intake and exhaust ports.
  • FIG. 1 is a longitudinal sectional view of the air purification device 1.
  • the air purification apparatus 1 is installed in a house, and the air purification apparatus 1 takes in air outside the house into the house.
  • a space is formed inside the casing 30.
  • An intake port 31 is formed in the lower part of the side surface of the casing 30, and an exhaust port 37 is formed in the upper part of the side surface of the casing 30! /.
  • the louver 5 is provided at the intake port 31 and the louver 6 is provided at the exhaust port 37! /.
  • the air inlet 31 is exposed outside the house and communicates with the outside through the force or duct.
  • the outlet 37 communicates with the force exposed in the house or through the duct.
  • an intake duct 33, an exhaust duct 35, and a cleaning tower 40 are provided inside the casing 30, an intake duct 33, an exhaust duct 35, and a cleaning tower 40 are provided.
  • the cleaning tower 40 is long in the vertical direction, and an internal space is formed inside the cleaning tower 40.
  • the upper and lower middle part of the internal space of the cleaning tower 40 is the spray chamber 41
  • the lower part of the internal space of the cleaning tower 40 is the drain pan 42
  • the upper part of the internal space of the cleaning tower 40 is the exhaust chamber 43.
  • the spray chamber 41 and the drain pan 42 communicate with each other
  • the exhaust chamber 43 and the spray chamber 41 communicate with each other.
  • Water is stored in the drain pan 42.
  • the drain pan 42 is provided with a sterilizer 15, and water stored in the drain pan 42 is sterilized by the sterilizer 15.
  • the sterilizing device 15 has an ultraviolet irradiation, electrolytic sterilization, high-temperature sterilization, water flow to the sterilizing agent packed layer, or sterilizing effect on at least a part of the surface of the structure of the air purification device 1 of the present embodiment. It is constituted by any one of surface treatments to be applied or a combination thereof.
  • a light source that emits light having a sterilizing ability such as a mercury lamp
  • a mercury lamp is installed in either the drain pan 42 or the water circulation channel, and water is circulated through the sterilizing lamp section. It is done by the distribution formula.
  • a high-pressure or low-pressure mercury lamp is preferably used, and as the irradiated ultraviolet light, ultraviolet light with a wavelength of about 254 nm and / or about 182 nm irradiated from the lamp preferably achieves a sterilizing effect.
  • the amount of UV irradiation for achieving sterilization is a force greatly influenced by the distance between the light source and the water to be irradiated and the irradiation time.
  • 0.01 W-s / cm 2 or more, preferably 0.025- 0. 05W 's / cm 2 is desirable.
  • the electrolytic sterilization is to apply a DC voltage to at least a pair of electrodes of the anode and the cathode, and is installed in either the force immersed in the drain pan 42 or the water circulation path, and the electrolytic sterilization unit It is carried out by a circulation type that circulates water.
  • electrolysis sterilization when chlorine ions are contained in water, effective chlorine produced at the anode is the main sterilizing active ingredient. If the chloride ion concentration of water is low, chemicals containing chloride ions such as salt, hydrochloric acid, calcium chloride, or natural products containing chloride ions such as seawater and bittern may be added to the water. good.
  • the effective chlorine concentration that suitably achieves the bactericidal effect is affected by the pH of water, and generally has a high bactericidal effect in acidity.
  • water with acidic pH and high concentration of effective chlorine causes odor and especially corrosion on metal materials. Therefore, in this air purifier 1, effective chlorine concentration is 0.;! ⁇ LOOmg C1 / 1
  • the electrolytic sterilization is performed by ozone, hydrogen peroxide, This can be achieved by sterilization by active oxygen such as OH radicals, or by anodic oxidation by contacting cells with the anode. In this case, sterilization can be more suitably achieved by increasing the contact efficiency between water and the anode by increasing the surface area of at least a portion of the anode as a porous body and flowing water through the porous body. it can.
  • a conductive carbon material, iron, stainless steel, and other metals are preferably used as the cathode used for electrolytic sterilization.
  • the anode platinum, gold and other precious metals, titanium substrate with platinum, iridium It is preferable to form a metal oxide or a sintered oxide film of these by mixing a single component or a mixture of a plurality of components such as mu, ruthenium, rhodium, and tantalum.
  • the electrode material is preferably the above anode material.
  • the anode contains lead dioxide.
  • the shape of the electrode is appropriately selected from a plate, a porous body, a punching metal, an expanded metal, and the like in consideration of a liquid contact method such as a water flow type and an immersion type.
  • the electrolysis current density passed between the electrodes is preferably a force of 0.;! To 2 OA / dm 2 selected in accordance with the target electrode reaction due to the difference in the sterilization mechanism.
  • the high temperature sterilization means that the temperature of water or air is raised to a high temperature of 60 ° C or higher, preferably 80 ° C or higher, or the fluid is applied to a temperature rising body such as a metal mesh heated to the same temperature or higher. This is a means for killing bacteria in the fluid by bringing them into contact with each other.
  • the temperature of a part of the circulating water flow path is raised, or a temperature raising body is installed in the air circulation path to perform sterilization.
  • the eliminator 11 described later may be heated with an electric heater or the like, and may also be used as a heating element for sterilization.
  • the bactericidal agent used in the sterilization by the surface treatment that imparts the bactericidal effect to the surface of at least a part of the structure of the air purifier 1 or the water passing through the bactericidal agent packed layer is, for example, silver or copper
  • a metal having a bactericidal effect on an adsorbent such as activated carbon or zeolite, or by further kneading a powder of activated carbon or zeolite adsorbed with the metal into nylon or the like
  • the antibacterial agent and antibacterial agent are immobilized by covalent bonds, such as benzyl group and methylene group.
  • the water stored in the drain pan 42 may be sterilized with residual chlorine.
  • water can be sterilized by setting the effective chlorine content of the water stored in the drain pan 42 to 0.1 mg / L or more and 10 mg / L or less, preferably 1 mg / L or more and 3 mg / L or less! / ,.
  • One end of the intake duct 33 communicates with the intake port 31, and the other end of the intake duct 33 is connected to the upper and lower middle portions of the cleaning tower 40 and communicates with the spray chamber 41.
  • a prefilter 7 is provided inside the intake duct 33, and the intake port 31 is closed by the prefilter 7. The place where the prefilter 7 is installed may be anywhere as long as it is between the connection portion of the spray chamber 41 and the intake duct 33 and the intake port 31.
  • the blower 8 is connected to the upper end of the cleaning tower 40, and the blower 8 is connected to one end of the exhaust duct 35, and the other end of the exhaust duct 35 communicates with the exhaust port 37.
  • the blower 8 sucks the air in the cleaning tower 40 and sends it out to the exhaust duct 35. External air is taken into the air inlet 31 by the air blower 8 and is discharged from the air outlet 37 into the house through the air intake duct 33, the cleaning tower 40, the air blower 8, and the air exhaust duct 35.
  • a filter 9 is provided inside the exhaust duct 35, and the filter 9 can collect finer dust than the exhaust port 37 is closed.
  • the filter 9 is a HEPA filter or a ULP A filter.
  • the place where the filter 9 is installed may be anywhere between the blower 8 and the exhaust port 37.
  • a plurality of spray nozzles 10 serving as sprayers are provided inside the cleaning tower 40 and above the spray chamber 41. These spray nozzles 10 spray water in the form of a mist, and water is sprayed downward from these spray nozzles 10.
  • the spray nozzle 10 sprays water having an average particle diameter of 10 m or more and 1000 m or less. More preferably, Spray Nozure 10 sprays water with an average particle size of 300 m or more and 1000 m or less. Good.
  • the number of spray nozzles 10 may be one instead of a plurality.
  • the falling end velocity of the water droplet is larger than the flow velocity of the air in the spray chamber 41.
  • the dissolution efficiency of the soluble gas such as NOx, S Ox, NH4, etc. depends on the particle size of the contact, and the particle size of the water droplet is Smaller force Increases dissolution efficiency of soluble gas. Therefore, the average particle diameter of water sprayed from the spray nozzle 10 is 10 m or more and 1000 m or less. Preferably, the average particle size of water sprayed from the spray nozzle 10 is 300 Hm or more and 1000 ⁇ m or less.
  • An eliminator 11 is provided inside the cleaning tower 40 and above the spray nozzle 10, and the spray chamber 41 and the exhaust chamber 43 are partitioned by the eliminator 11. When air passes through the eliminator 11 1, moisture in the passing air adheres to and is captured by the eliminator 11 1, and the water attached to the eliminator 11 1 drops as a water droplet on the drain pan 42.
  • a pressure feed pump 12 is connected to the drain pan 42.
  • the pressure pump 12 is connected to the spray nozzle 10 by a pipe 13.
  • the pressure pump 12 sucks up the water stored in the drain pan 42 and pumps it to the spray nozzle 10.
  • the water sent to the spray nozzle 10 by the pressure feed pump 12 is sprayed from the spray nozzle 10 by the pressure by the pressure feed pump 12.
  • a supply pipe 16 is connected to the cleaning tower 40, and water from the supply source 17 is supplied into the cleaning tower 40 through the supply pipe 16.
  • the water supplied from the supply source 17 is tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these. Therefore, the water sprayed from the spray nozzle 10 is also tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these.
  • the water supplied from the supply source 17 is pure water
  • the water is pure water purified by a reverse osmosis device or an ion exchange device.
  • the water supplied from the supply source 17 is acidic water
  • an anodizing water of an electric softening device or an electric regenerative deionization device is the water supplied from the supply source 17 is alkaline water
  • Electrosoftening device cathode It is water (soft water), cathodic water of an electric regenerative deionization device, or cathodic water of the electrolysis device obtained by supplying soft water to the electrolysis device.
  • a drain pipe 14 is connected to a portion above the bottom of the drain pan 42. When the water level stored in the drain pan 42 becomes the connection point of the drain pipe 14, the water in the drain pan 42 is discharged through the drain pipe 14.
  • water from the supply source 17 is stored in the drain pan 42 through the supply pipe 16. Then, the pump 12 is operated, the water in the drain pan 42 is pumped to the spray nozzle 10, and water is sprayed from the spray nozzle 10. Thus, water is circulated while the pressure pump 12 is operating. During the circulation of water, the sterilizer 15 operates, and the circulated water is sterilized by the sterilizer 15. Even during the circulation of water, the water from the supply source 17 is supplied to the drain pan 42 intermittently, continuously or in a predetermined cycle.
  • the blower 8 is activated, and the air outside the house is sucked into the intake 31 and exhausts through the intake 37 through the intake duct 33, the cleaning tower 40, the blower 8, and the exhaust duct 35 in this order. It is done.
  • the air exhausted from the exhaust port 37 is sent into the house.
  • insects, large dust, debris, and the like are captured by the prefilter 7.
  • the air that has passed through the cleaning tower 40 passes through the filter 9, it is captured by the dust force S filter 9 that could not be removed by the pre-filter 7 or the cleaning tower 40. Then, the air passing through the filter 9 is discharged from the exhaust port 37 and sent into the house.
  • the air sucked into the intake port 31 passes through the cleaning tower 40 before passing through the filter 9, and dust or the like in the air is mostly caused by fog in the cleaning tower 40. Removed. In addition to dust, water-soluble gases and solids are removed by the mist in the cleaning tower 40. The power to do S. In addition, when the air passes through the filter 9, the air hardly contains dust and the like, so that the filter 9 can be prevented from being clogged for a long period of time. Therefore, even if the filter 9 is not cleaned over a long period of time, the replacement cycle of the filter 9 can be lengthened.
  • the air sent into the house can be purified and deodorized, and the air supply to the house can be made more sanitary.
  • water is captured by the eliminator 11, spray water does not remain in the air sent into the house, and more purified air is sent into the house.
  • the air purification device 1 since the water stored at the bottom of the drain pan 42 is sterilized by the sterilizer 15, contamination of the circulating water can be suppressed. Therefore, even if the air purification device 1 has been operating for a long time, the air sent into the house can be kept purified.
  • the air inlet 31 is exposed to the inside of the house. You may communicate with the house through force or data. In this way, the air in the house is sucked into and sucked into the air inlet 31, and the air from which dust and the like are removed is supplied into the house through the air outlet 37. Thereby, the air in a house can be purified.
  • an intake port is provided in the casing 30, the other intake port and the spray chamber 41 are connected by a duct, and the other intake port is exposed in the house or through the duct. You may let it go into the house. By doing so, outside air is taken in from the air intake 31, air in the house is taken in from another air intake, and the taken-in air is purified in the cleaning tower 40, and the purified air is It is sent into the house through exhaust port 37.
  • the pre-filter 7 and the filter 9 provided with the pre-filter 7 and the filter 9 respectively in the front and rear stages of the cleaning tower 40 may be either the pre-filter 7 or the filter 9. Further, both the pre-filter 7 and the filter 9 may not be provided.
  • the spray nozzle 10 sprays water downward.
  • the spray nozzle 10 may spray water upward.
  • the force of the air taken in to rise in the spray chamber 41 may flow so as to descend.
  • the direction force of the water sprayed from the spray nozzle 10 is opposite to the direction of the air flow in the spray chamber 41, but the relationship between these directions is not particularly limited.
  • the direction of water sprayed from the spray nozzle 10 may be the same as the direction of air flow in the spray chamber 41, or the direction of water sprayed from the spray nozzle 10 in the spray chamber 41. It may be perpendicular to the direction of air flow.
  • water is pumped to the spray nozzle 10 by the pumping pump 12, but compressed air may be fed to the spray nozzle 10 by a compressor in addition to water.
  • the water in the drain pan 42 is sucked up by the pressure pump 12 and is pumped to the spray nozzle 10.
  • the water of the supply source 17 may be sucked up by the pressure pump 12A and pumped to the spray nozzle 10. Therefore, in this air purification device 1A, water does not circulate, and the water sprayed from the spray nozzle 10 and stored in the drain pan 42 is discharged through the drain pipe 14. Further, in this air purification device 1A, since water does not circulate, no sterilizer is provided in the cleaning tower 40.
  • this air purification device 1A is provided in the same manner as the air purification device 1 of the first embodiment, and the air purification device 1A and the air purification device 1 correspond to each other.
  • the same reference numerals are given. Even with this air purification device 1A, it is possible to purify and deodorize the air sent into the house, and to extend the replacement cycle of the filter 9.
  • the spray chamber 41 is divided into three chambers 41B, 41C, and 41D by yarn hooks 91 ⁇ and 92 ⁇ . It is divided into three chambers 42 ⁇ , 42C, and 42D by force walls 95B and 96 ⁇ .
  • the thread basket 91B continues on the partition wall 95 ⁇
  • the net 92 ⁇ continues on the partition wall 96 ⁇ .
  • Net 95 ⁇ separates room 41B and 41C
  • net 96 ⁇ separates room 41C and 41D
  • bulkhead 95 ⁇ separates room 42 ⁇ and room 42C
  • ⁇ wall 96 divides room 42C and room 42 ⁇ Yes.
  • Duct 33 leads to chamber 41B on the opposite side of chamber 41C.
  • the chamber 41B and the chamber 41C are closed by a partition wall 98 ⁇
  • the chamber 41D is opened
  • the chamber 41D and the exhaust chamber 43 are connected via the eliminator 11.
  • the chamber 41B and the chamber 42 ⁇ are vertically connected, the chamber 41C and the chamber 42C are vertically connected, and the chamber 41D and the chamber 42D are vertically connected.
  • a supply pipe 16B is connected to the chamber 41B, and water from the supply source 17B is supplied to the chamber 41B through the supply pipe 16B and stored in the chamber 42 ⁇ .
  • the chamber 41C is supplied with water from the supply source 17C through the supply pipe 16C, and the chamber 41D is supplied with water from the supply source 17D through the supply pipe 16D.
  • the water supplied from the supply source 17B is acidic water
  • the water supplied from the supply source 17C is alkaline water
  • the water supplied from the supply source 17D is pure water.
  • the combination of source 17B, 17C, 17D and the type of water is not particularly limited.For example, water at source 17 ⁇ is alkaline water, water at source 17C is acidic water, and water at source 17D is pure. It may be water.
  • a spray nozzle 10B is provided above the chamber 41B, a spray nozzle 10C is provided above the chamber 41C, and a spray nozzle 10D is provided above the chamber 41D.
  • the pressure pump 12B sucks up water stored in the chamber 42 ⁇ and pumps it to the spray nozzle 10B.
  • the pump 12C sucks up the water stored in the chamber 42C and pumps it to the spray nozzle 1 OC.
  • the pump 12D sucks up the water stored in the chamber 42D and pumps it to the spray nozzle 10D.
  • this air purification device 1B is provided in the same manner as the air purification device 1 of the first embodiment, and the air purification device 1B and the air purification device 1 correspond to each other. The same sign is attached to the minutes.
  • water from the supply source 17B is stored in the chamber 42 ⁇ through the supply pipe 16B. Water from sources 17C and 17D is also stored in chambers 42C and 42D, respectively. And the pumping pump 12B is activated, Water in chamber 42B is pumped to spray nozzle 1OB and water is sprayed from spray nozzle 10B. Similarly, water in the chambers 42C and 42D is sprayed from the spray nozzles IOC and 10D, respectively.
  • the blower 8 While the water is circulated by the pressure pumps 12B, 12C, 12D, the blower 8 is activated, and the air outside the house is sucked into the intake port 31, and the intake duct 33, chamber 41B, chamber 41C, chamber 41D, fan 8, and The gas is discharged from the exhaust port 37 through the exhaust duct 35 in order. The air discharged from the exhaust port 37 is sent into the house.
  • a NOx confirmation test was conducted using the air purification device 1 shown in FIG.
  • the air purifier 1 was installed in the laboratory, and the laboratory room air was introduced into the spray chamber 41 from the air inlet 31 by the blower 8.
  • the size of the spray chamber 41 is 300mm x 300mm x 300mm, and its capacity is 27L.
  • the flow rate for introducing indoor air was about 100 m 3 / hr.
  • the gas introduced into the air inlet 31 at regular intervals is collected in a gas collection bottle containing pure water, and the gas is purified in the gas collection bottle. After dissolving in water, the concentration of nitrite ion (NO-) in pure water was analyzed.
  • FIG. 5 is a longitudinal sectional view of the air purification device 1E.
  • This air purification device 1E is installed in a house, and air outside the house is taken into the house by this air purification device 1E.
  • a space is formed inside the cleaning tower 30E.
  • An intake port 31E is formed in the lower part of the side surface of the cleaning tower 30E, and an exhaust port 37E is formed in the upper part of the side surface of the cleaning tower 30E.
  • the air inlet 31E communicates with the force exposed outside the house or the outside through the duct.
  • Exhaust port 37E is exposed in the house or leads to the house through a dart.
  • a blower 8E is provided in an upper portion inside the cleaning tower 30E. This blower 8E blows air from the lower intake port 31E of the cleaning tower 30E toward the upper exhaust port 37E, and this blower 8E passes from the intake port 31E to the exhaust port 37E via the inside of the cleaning tower 30E. For Force and airflow are generated.
  • the intake port 31E is formed on the side surface of the cleaning tower 30E above the lower end of the cleaning tower 30E. 99E of water is stored in a portion 32E below the intake port 31E (hereinafter referred to as the storage chamber 32E) in the space inside the cleaning tower 30E.
  • the storage chamber 32E may be provided with a sterilization device, and the water 99E stored in the storage chamber 32E may be sterilized by the sterilization device.
  • the sterilization device means ultraviolet irradiation, electrolytic sterilization, high-temperature sterilization, water passing through the sterilizing agent-packed layer, or sterilization effect on at least a part of the surface of the structure of the air purification device 1E of the present embodiment. It is comprised by the surface treatment which provides singly, or these combination.
  • a light source that emits light having a sterilizing ability such as a mercury lamp
  • a mercury lamp is immersed in the storage chamber 32E or placed in one of the water circulation channels, and water is allowed to flow through the sterilizing lamp section. It is done by the circulation type.
  • a high-pressure or low-pressure mercury lamp or the like is preferably used, and as the irradiated ultraviolet light, ultraviolet light having a wavelength of about 254 nm and / or about 182 nm irradiated from the lamp preferably has a sterilizing effect. Can be achieved.
  • the amount of UV irradiation that can suitably achieve sterilization is a force that is greatly influenced by the distance between the light source and the water to be irradiated and the irradiation time. Generally, it is 0. OlW's / cm 2 or more, preferably 025—0.05 W 's / cm 2 is desirable.
  • the electrolytic sterilization is to apply a DC voltage to at least the pair of electrodes of the anode and the cathode, and is immersed in the storage chamber 32E or installed in one of the water circulation paths, It is carried out by a distribution formula that distributes water.
  • a distribution formula that distributes water.
  • chlorine ions when chlorine ions are contained in water, effective chlorine produced at the anode is the main sterilizing active ingredient. If the chloride ion concentration in water is low, add chemicals containing chloride ions such as salt, hydrochloric acid, and calcium chloride to water, or natural products containing chloride ions such as seawater and bittern. Also good.
  • the effective chlorine concentration that suitably achieves the bactericidal effect is affected by the pH of water, and in general, the bactericidal effect is high in acidity.
  • the effective chlorine concentration of this air purifier 1E is 0.;! ⁇ LOOmg Cl / 1, preferably 0.2 to 10 mg Cl / 1, force, pH 2 to; 12, more preferably pH 3 to 10 desirable.
  • the electrolytic sterilization is performed by ozone, hydrogen peroxide, This can be achieved by sterilization by active oxygen such as OH radicals, or by anodic oxidation by contacting cells with the anode. In this case, sterilization can be more suitably achieved by increasing the contact efficiency between water and the anode by increasing the surface area of at least a portion of the anode as a porous body and flowing water through the porous body. it can.
  • a conductive carbon material, iron, stainless steel, and other metals are preferably used as the cathode used for electrolytic sterilization.
  • anode noble metals such as platinum and gold, platinum substrate, platinum, iridium, ruthenium, rhodium, tantalum, etc. alone or mixed with multiple components to form a plating or a sintered oxide film of these. Is preferred.
  • the electrode material is preferably the above anode material. In order to efficiently produce effective chlorine at the anode, it is desirable that iridium and ruthenium are included as anode material components.
  • the anode contains lead dioxide.
  • the shape of the electrode is appropriately selected from a plate, a porous body, a punching metal, an expanded metal, and the like in consideration of a liquid contact method such as a water flow type and an immersion type.
  • the electrolysis current density passed between the electrodes is preferably a force of 0.;! To 2 OA / dm 2 selected in accordance with the target electrode reaction due to the difference in the sterilization mechanism.
  • the high temperature sterilization means that the temperature of water or air is raised to a high temperature of 60 ° C or higher, preferably 80 ° C or higher, or the fluid is applied to a temperature rising body such as a metal mesh heated to the same temperature or higher. This is a means for killing bacteria in the fluid by bringing them into contact with each other.
  • the temperature of a part of the circulating water flow path is raised, or a temperature raising body is installed in the air circulation path to perform sterilization.
  • An eliminator 11E described later may be heated with an electric heater or the like, and may also be used as a sterilization heating element.
  • the bactericidal agent used in the sterilization by the surface treatment that imparts the bactericidal effect to the surface of at least a part of the structure of the air purification device 1E through water through the bactericide packed layer is, for example, silver or copper Metals having sterilizing effect such as activated carbon are adsorbed on adsorbents such as zeolite Or activated carbon adsorbed with the metal or zeolite powder and kneaded into a fiber and processed into a fibrous form. Iodine is fixed to a solid surface having an anion exchange group by ionic bonds.
  • Quaternary ammonium group-containing anion exchanger, polymyxin bonded to agarose, alkoxysilyl group-introduced antibacterial agent ⁇ antibacterial agent and hydroxyl group on the carrier surface are bound by dealcoholization reaction
  • the surface of the object is fixed or sterilized and antibacterial agent is applied or coated on the surface (Kano Hiroki, Chemistry and Biology, 26 (1 2), 834—841 (1988)).
  • These disinfectants are used alone or in combination, and are installed in the water circulation path to form a disinfectant filling part, and the force of circulating water or air through the disinfectant part, or the structure of this air purification device 1E At least a part of the surface can be surface-treated with the above-mentioned disinfectant, and the surface can be sterilized by bringing water or air into contact therewith.
  • the water stored in the storage chamber 32E may be sterilized with residual chlorine.
  • the effective chlorine of water stored in the storage chamber 32E can be sterilized by setting it to 0.1 mg / L or more and 10 mg / L or less, preferably 1 mg / L or more and 3 mg / L or less! / ,.
  • a plurality of nozzles 10E are provided inside the cleaning tower 30E and above the storage chamber 32E. These nozzles 10E spray water downward.
  • the nozzle 10E may spray water in the form of a mist. In this case, it is more preferable that the nozzle 10E sprays water having a particle size of 10 m or more and 1000 m or less!
  • the nozzle 10E may spray water by continuously dropping water droplets.
  • nozzles 10E may be one.
  • An eliminator 11E is provided inside the cleaning tower 30E and above the nozzle 10E, and the space in the cleaning tower 30E is partitioned vertically by the eliminator 11E. When air passes through the eliminator 11E, moisture in the passing air adheres to and is captured by the eliminator 11E, and water attached to the eliminator 11E drops downward as water droplets.
  • the gas-liquid contact structure 20E captures the water dispersed from the nozzle 10E and brings the air passing through the gas-liquid contact structure 20E upward into contact with the captured water so that the water-soluble gas (for example, NOx gas, SOx gas, NH4 gas) are absorbed by water.
  • the gas-liquid contact structure 20E has a layer filled with a plurality of fillers 21E. Examples of the filling material 21E include Raschig rings, Lessing rings, ball rings, peddle saddles, interlock saddles, terralet, and the like.
  • the gas-liquid contact structure 20E is configured as shown in FIG.
  • a soot 22E as shown in FIG. 2 is disposed below the nozzle 10E and above the intake port 31E, and the soot 22E is filled with a filling material 21E.
  • ⁇ 22E has a wire mesh in a box shape.
  • a pump 12E is connected to the storage chamber 32E.
  • Pump 12E is connected to Nozure 10E by pipe 13E.
  • the pump 12E sucks up the water 99E stored in the storage chamber 32E and sends it to the nozzle 10E.
  • the water sent to the nozzle 10E by the pump 12E is also sprayed by the pressure of the pump 12E.
  • a supply pipe 16E is connected to the cleaning tower 30E, and water from the supply source 17E is supplied into the cleaning tower 30E through the supply pipe 16E.
  • the supply pipe 16E is provided with a valve 18E. When the valve 18E is opened, water as a supply source is supplied into the cleaning tower 30E.
  • the water supplied from the source 17E is tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these. Therefore, the water sprayed from the nozzle 10E is also tap water, pure water, acidic water, alkaline water, or a mixture of two or more of these.
  • the water supplied from the supply source 17E is pure water
  • the water is pure water purified by a reverse osmosis device or an ion exchange device.
  • the water supplied from the supply source 17E is acidic water
  • it is an anodic water of an electrosoftening device or an electric regenerative deionization device.
  • the dissolution efficiency of alkaline gases such as NH4 gas in the air depends on the pH of the water in contact. The lower the pH of the water in contact, the higher the efficiency of dissolving alkaline gases such as NH4 gas in the air.
  • the water supplied from the supply source 17E is set to pH 2 to 9, more preferably pH 3 to 6.
  • the water supplied from the supply source 17E is alkaline water
  • the water is the cathodic water of the electrolysis device obtained by supplying concentrated water or brine purified by a reverse osmosis device to the electrolysis device. It is the cathode water (soft water) of the electrosoftening device, the cathode water of the electric regenerative deionization device, or the cathode water of the electrolysis device obtained by supplying soft water to the electrolysis device .
  • the dissolution efficiency of acidic gases such as NOx gas and SOx gas in the air depends on the pH of the water in contact.
  • the water supplied from the supply source 17E is pH 5 to 12; more preferably pH 8 to 10;
  • salts such as magnesium hydroxide are liable to be formed when pHIO is exceeded.
  • a drain pipe 14E is connected to a portion above the bottom of the storage chamber 32E.
  • the level of the water 99E stored in the storage chamber 32E becomes the connection point of the drain pipe 14E, the water 99E in the storage chamber 32E is discharged through the drain pipe 14E.
  • water from the supply source 17E is stored in the storage chamber 32E through the supply pipe 16E.
  • the pump 12E is activated, the water 99E in the storage chamber 32E is sent to the Noznore 10E, and water is sprayed from the Noznole 10E.
  • the water sprayed from the nozzle 10E is captured and absorbed by the gas-liquid contact structure 20E. Specifically, the water is absorbed into the gap of the filling 21E.
  • Water circulates while pump 12E is operating.
  • the sterilizer operates during the water circulation, and the circulating water is sterilized by the sterilizer. Note that the water from the supply source 17E is supplied to the storage chamber 32E intermittently, continuously or in a predetermined cycle even during the circulation of water.
  • the blower 8E operates, the air outside the house is sucked into the intake port 31E, and the sucked air rises through the cleaning tower 30E and is discharged through the exhaust port 37E. The air discharged from the exhaust port 37E is sent into the house.
  • part of the dust and the like removed by the water in the gas-liquid contact structure 20E floats on the surface of the water stored in the storage chamber 32E, and the floating dust and the like are discharged through the drain pipe 14E together with the water. Is done. Therefore, it is possible to suppress the accumulation of dust and the like in the circulating water.
  • the air inlet 31E is exposed to the inside of the house. It may lead into the house through force or ducts. In this way, the air in the house is sucked into the air inlet 31E, and the air from which dust, water-soluble gas, etc. are removed is supplied into the house through the air outlet 37E. Thereby, the air in a house can be purified.
  • an air intake port may be provided in the cleaning tower 30E, and the other air intake port may be exposed in the house or connected to the house through a duct. In this way, outside air is taken in from the air inlet 31E, air in the house is taken in from another air inlet, and the taken-in air is purified in the cleaning tower 30E, and the purified air is It is sent to the house through the exhaust 37E.
  • the force of the air taken in so as to rise in the cleaning tower 30E may flow so as to descend.
  • sprayed from the nozzle 10E sprayed from the nozzle 10E.
  • the direction of the generated water is the opposite of the direction of the air flow in the washing tower 30E, but the relationship between the directions is not particularly limited.
  • the direction of the water sprayed from the nozzle 10E The direction of the air flow in the tower 30E may be the same, or the direction of the water dispersed from the nozzle 10E may be perpendicular to the direction of the air flow in the washing tower 30.
  • compressed air may be sent to the nozzle 10E by a compressor in addition to the force water that has sent water to the nozzle 10E by the pump 12E.
  • a partition plate may be disposed in the gas-liquid contact structure 20E, and the air may contact the acid water, alkaline water, and pure water in this order in the gas-liquid contact structure 20E. Further, in the gas-liquid contact structure 20E, air may contact in the order of alkaline water, acidic water, and pure water, or may contact in the order of alkaline water and pure water.
  • a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
  • the air purifying device 1E of the fourth embodiment has a gas-liquid contact structure 20E with two rods 22E, and the rod 22E is filled with a plurality of fillers 21E.
  • the gas-liquid contact structure 20F includes a plurality of ridges 22F shown in FIG. 8, and these ridges 22F are filled with the filling 21F. ing.
  • these flanges 22F are provided in a plate shape and a box shape. With the thickness direction of 22F perpendicular to the direction of the air flow in the cleaning tower 30E, these 22F are arranged at intervals below the nozzle 10E!
  • a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
  • this air purification device 1F is provided in the same manner as the air purification device 1E of the fourth embodiment, and there are portions corresponding to each other between the air purification device 1F and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1F !, it is possible to purify and deodorize the air sent into the house.
  • the gas-liquid contact structure 20G has a plurality of perforated plates 24G. Specifically, these multi-hole plates 24G are stacked at a distance below the nozzle 10E, and the thickness of the multi-hole plate 24G is parallel to the direction of the air flow in the cleaning tower 30E.
  • the perforated plate 24G is formed with a plurality of through holes penetrating from one surface to the other surface.
  • the water sprayed from Nozure 10E is trapped in the through holes of these porous plates 24G, and when the air passes upward through the through holes, the air and water come into contact with each other. Water-soluble gas (for example, NOx gas, SOx gas, NH4 gas) is absorbed by water.
  • a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
  • this air purification device 1G is provided in the same manner as the air purification device 1E of the fourth embodiment, and there are portions corresponding to each other between the air purification device 1G and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1G! /, You can clean and deodorize the air sent into the house.
  • the gas-liquid contact structure 20H has a plurality of plates 25H. These plates 25H are arranged in a shelf shape, and further, these plates 25H are provided in the left-right force and the wrong positions. These plates 25H are provided with an inclination, and the ends of these plates 25H are directed obliquely downward. These plates 25H may be parallel to each other.
  • the plate 25H may be a corrugated plate, and as shown in FIG. 12, a groove 26H may be formed on the surface of the plate 25H. If the plate 25H is a corrugated plate, it will be easy to trap the water sprayed on the plate 25H! If the groove 26H is formed in the plate 25H! /, Water will flow easily.
  • a pre-fre- quency is provided between the intake port 31E and the internal space of the cleaning tower 30E.
  • a filter may be provided, and a filter may be provided between the exhaust port 37E and the blower 8.
  • this air purification device 1H is provided in the same manner as the air purification device 1E of the fourth embodiment, and there is a portion corresponding to each other between the air purification device 1H and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1H! /, It is possible to purify and deodorize the air sent into the house.
  • the space inside the cleaning tower 30E is divided into three chambers by the nets 93M and 94M, and these three chambers are air-conditioned.
  • Liquid contact structures 20J, 20K, and 20L are provided.
  • the gas-liquid contact structures 20J to 20L are provided in the same manner as any of the gas-liquid contact structures 20E, 20F, 20G, and 20H in the fourth to seventh embodiments.
  • a nozzle 10J is provided above the gas-liquid contact structure 20J
  • a nozzle 10K is provided above the gas-liquid contact structure 20K
  • a nozzle 10L is provided above the gas-liquid contact structure 20L.
  • the upper side of the nozzle 10J and the upper side of the nozzle 10K are closed by a partition wall 98M, and the chamber provided with the gas-liquid contact structures 20J and 20K is partitioned from the eliminator 11E by the partition wall 98M.
  • the chamber provided with the gas-liquid contact structure 20L leads to the eliminator 11E.
  • a supply pipe 16J is connected to the storage chamber 32J, and water from the supply source 17J is supplied to the storage chamber 32J through the supply pipe 16J.
  • a supply pipe 16K is connected to the storage chamber 32K, and water from the supply source 17K is supplied to the storage chamber 32K through the supply pipe 16K.
  • a supply pipe 16L is connected to the storage chamber 32L, and water from the supply source 17L is supplied to the storage chamber 32L through the supply pipe 16L.
  • the water supplied from the supply source 17J is acidic water
  • the water supplied from the supply source 17K is alkaline water
  • the water supplied from the supply source 17L is pure water.
  • the combination of 17L and 17L and water types is not particularly limited.
  • the water at source 17J is alkaline water
  • the water at source 17K is acidic water
  • the water at source 17L is pure. Even water Yes.
  • the pump 12J sucks / raises water 99J stored in the storage chamber 32J, and feeds it to the nozzle 10J.
  • the pump 12K sucks up 99K of water stored in the storage chamber 32K and sends it to the nozzle 10K.
  • the pump 12L sucks up 99L of water stored in the storage chamber 32L and sends it to the 10L Nozure 10L.
  • a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
  • this air purification device 1J is provided in the same manner as the air purification device 1E of the fourth embodiment, and the air purification device 1J and the air purification device 1E correspond to each other. The same sign is attached to the minutes.
  • water from the supply source 17J is stored in the storage chamber 32J through the supply pipe 16J. Water from the supply sources 17K and 17L is also stored in the storage chambers 32K and 32L, respectively. Then, the pump 12J operates, the water 99J in the storage chamber 32J is fed to the nozzle 10J, the water is sprayed downward from the nozzle 10J, and the sprayed water 99J is captured by the gas-liquid contact structure 20J. Similarly, the water 99K and 99L in the storage chambers 32K and 32L are sprayed downward from the nozzles 10K and 10L, respectively, and are captured by the gas-liquid contact structures 20K and 20L.
  • a NOx confirmation test was conducted using the air purifier 1E shown in FIG.
  • the air purifier 1E was installed in the laboratory, and the air in the laboratory was introduced from the air inlet 31E into the gas-liquid contact structure 20E by the blower 8E.
  • the size of the gas-liquid contact structure 20E is 200mm x 200mm x 200mm, and its capacity is 8L.
  • As the filling material 21E a Raschig ring having an inner diameter of 5 mm and a length of 5 mm was used.
  • the flow rate of the indoor air introduced was about 150m 3 / hr.
  • pure water generated by the reverse osmosis device was sprinkled from the nozzle 10E at a water volume of 1.5 L / min.
  • the gas discharged at the exhaust port 37E at regular intervals is collected in a gas collection bottle containing pure water, dissolved in pure water in the gas collection bottle, and nitrous acid in pure water.
  • the ion (NO-) concentration was analyzed with an ion chromatography analyzer.
  • the volume of the gas collection bottle was lOOmL, the amount of pure water for gas collection was 5 OmL, and a gas with a flow rate of 5 NL / min was collected for 60 minutes.
  • the gas introduced into the air inlet 31E at regular intervals was collected in a gas collection bottle containing pure water, and the gas was purified in the gas collection bottle. It was dissolved in water and analyzed for nitrite ion (NO-) concentration in pure water.
  • air in the house or outside of the house is also taken into the internal space of the washing tower (40 or 40E) by the blower (8 or 8E), and the washing tower (40 or 4E).
  • the air taken into 0E) is sent into the exhaust outlet (37 or 37E) force, etc.
  • water is sprayed into the washing tower (40 or 30E) by the nozzle (10 or 10E)
  • the water comes into contact with the dust in the air being blown, and the dust is removed from the air.
  • water-soluble gases in the air being blown such as NOx gas, SOx gas, NH4 gas, and gases that cause malodors, are dissolved in the sprayed water, and the water-soluble gas is removed from the air.
  • the purified air is sent into the house.
  • the filter cleans the air by contact with water, so there is no need to clean or replace the filter.
  • the air taken into the intake tower (31 or 31E) and the washing tower (40 or 30E) passes through an atmosphere in which the dispersed water is dispersed rather than being blown into the water, so there is little pressure loss. Therefore, it is not necessary to increase the output of the blower (8 or 8E).
  • the nozzle (10) sprays water in the form of a mist.
  • the water sprayed from the nozzle is in the form of a mist, dust, water-soluble gas, etc. in the blown air easily come into contact with the water particles.
  • the nozzle (10) sprays water having a particle diameter of 10 m or more and 1000 m or less.
  • the sprayed water has a particle size of 10 m or more and 1000 ⁇ m or less, dust, water-soluble gas, etc. in the blown air can easily come into contact with the water particles.
  • the air purification device (1E, 1F, 1H or 1J) is provided at a spray destination of the nozzle (10E) in an internal space of the cleaning tower (30E), and the nozzle (10E) And a gas-liquid contact structure (20E, 20F, 20G, or 20H) that captures the water sprayed from the air and makes the captured water contact the air blown by the blower (8E).
  • the gas-liquid contact structure (20E or 20F) force S is filled with a plurality of fillers (21E or 21F) at the spray destination of the nozzle (10E).
  • the gas-liquid contact structure (20G) is formed by stacking a perforated plate (24G) at a spray destination of the nozzle.
  • the porous plate (24G) is stacked at the spray destination of the nozzle (10E), the water sprayed from the nozzle (10E) is trapped in the hole of the porous plate (24G) and the air flowing by the blower (8E) is Passes through holes in the perforated plate (24G). For this reason, air and water come into contact with each other, and dust and water-soluble gas in the air are removed.
  • the gas-liquid contact structure (20H) includes a plurality of plates (25H) arranged in a shelf shape, and the plurality of plates (25H) in a shelf shape at a spray destination of the nozzle (10E). Since it is arranged, the water sprayed from the nozzle (10E) is caught on the surface of the plate 25H), and the air flowing by the blower (8E) passes between the plates (25H). For this reason, air and water come into contact with each other, and dust and water-soluble gas in the air are removed.
  • the air purification device (1) further includes a filter (7) provided between the air inlet (31) and the washing tower (40).
  • the intake port (31 Dust and the like in the air taken in by the filter are captured by the filter (7). Therefore, the air purification efficiency is improved.
  • the air from which dust has been removed is sent to the cleaning tower (40), when the water sprayed in the cleaning tower (40) is stored or drained, the amount of dust contained in the water is small. Therefore, the post-treatment of the water can be easily performed.
  • the air purification device (1) further includes a filter (9) provided between the blower (8) and the exhaust port (37).
  • the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H or 1J) feeds water to the nozzle (10 or 10E), and the nozzle (10 or 10E).
  • Preferred ⁇ is that the pump (12, 12B, 12C, 12D, 12E, 12J, 12K or 12L) sprays water stored in the lower part of the internal space of the washing tower after being sprayed from the nozzle.
  • the solution is fed to the Nozure (10 or 10E).
  • the air purification device (1) is disposed in the internal space of the cleaning tower (40), and is sprayed from the nozzle (10) and stored in the bottom of the internal space of the cleaning tower (40). It is further provided with a sterilizer (15) for sterilizing the generated water.
  • the sterilizer (15) is an electrolytic sterilizer.
  • the sterilizer (15) is an ultraviolet irradiation device.
  • the water stored in the lower part of the internal space of the washing tower (40 or 30E) is sterilized with residual chlorine.
  • the water is sterilized by setting the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower (40 or 30E) to 0.1 mg / L or more and 10 mg / L or less.
  • the water is sterilized by setting the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower (40 or 30E) to 1 mg / L or more and 3 mg / L or less.
  • the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H, or 1J) is more than the nozzle (10 or 10E) in the internal space of the washing tower (40 or 30E). It further includes an eliminator (11 or 11E) that is disposed on the exhaust port (37 or 37E) side and captures water sprayed from the nozzle (10 or 10E).
  • the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H or 1J) is above the bottom of the internal space of the washing tower (40 or 30E)! /,
  • the drainage pipe (14 or 14E) is further connected to the washing tower (40 or 30E) and drains the stored water up to the water level at the connection point.
  • the sprayed water does not accumulate at the water level beyond the connection point of the drain pipe (14 or 14E).
  • dust that has come into contact with water floats on the surface of the water stored in the washing tower (40 or 30E), so that dust removed from the air is discharged from the drain pipe (14 or 14E) together with water.
  • the nozzle sprays tap water, pure water, acidic water, alkaline water, or a mixture of two or more thereof.
  • the nozzle sprays pure water purified by a reverse osmosis device or an ion exchange device.
  • the nozzle is anodic water of the electrolysis apparatus obtained by supplying concentrated water or brine purified by a reverse osmosis apparatus to the electrolysis apparatus, or an electrosoftening apparatus or an electric regeneration type. Spray the anode water of the deionizer.
  • the nozzle comprises cathodic water of the electrolysis apparatus obtained by supplying concentrated water or brine purified by a reverse osmosis apparatus to the electrolysis apparatus, cathodic water of an electrosoftening apparatus, The cathodic water of the electrolysis apparatus obtained by supplying cathodic water or soft water of an electroregenerative deionization apparatus to the electrolysis apparatus is sprayed.
  • 2007-51539 is incorporated herein by reference as far as the national laws of the designated country designated in this international application or the selected country selected.
  • water-soluble gas in the blown air for example, NOx gas, SOx gas, NH4 gas, gas causing malodor, etc. is scattered.
  • Water soluble gas and dust can be removed from the air by dissolving in the cloth water and further coming into contact with the water sprayed with dust in the air. Can be sent.
  • the air can be purified by the contact of water and air without cleaning and replacement of the filter and even when the frequency is low.
  • the pressure loss can be reduced and the output of the blower can be lowered.
  • the present invention can be particularly suitably used for a technology for purifying air sent to a house or the like.

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Abstract

An air purifier comprises a cleaning tower having an internal space communicating with a suction port and a discharge port, a blower for taking air from the suction port into the internal space of the cleaning tower and send it from the discharge port to the outside of the cleaning tower, and nozzles disposed in the internal space of the cleaning tower and spraying water in the internal space of the cleaning tower. The water sprayed from the nozzles is brought into contact with the air supplied by the blower in the cleaning tower.

Description

明 細 書  Specification
空気浄化装置  Air purification device
技術分野  Technical field
[0001] 本発明は、空気浄化装置に関し、特に、住宅等に送り込む空気を浄化する技術に 関する。  [0001] The present invention relates to an air purification device, and more particularly to a technique for purifying air sent to a house or the like.
背景技術  Background art
[0002] 従来、住宅には換気装置が設置され、その換気装置によってその住宅内に外気を 取り込んでその住宅内を換気する。し力、し、外気には、 NOx、 SOx、 NH4等のガスや 塵埃が含まれており、そのようなものも換気装置によって住宅内に取り込まれてしまう 。塵埃を除去するために、フィルタを備えた換気装置が住宅に設置され、そのフィノレ タによって塵埃が集塵されて、浄化した空気が住宅内に取り込まれる(例えば、 日本 国公開特許公報第 2003— 21375号参照)。  Conventionally, a ventilator is installed in a house, and outside air is taken into the house by the ventilator to ventilate the house. The outside air contains NOx, SOx, NH4, and other gases and dust, and these are also taken into the house by the ventilator. In order to remove dust, a ventilator equipped with a filter is installed in the house, dust is collected by the finotor, and purified air is taken into the house (for example, Japanese Patent Application Publication No. 2003- 21375).
[0003] また、フィルタを用いずに、水を用いて空気を浄化する装置として、ため水式の空 気浄化装置がある。ため水式の空気浄化装置は、水槽内底部に一定の水をためて、 空気をその水中に吹き込んで空気を水に接触させるものである。  [0003] Further, there is a water-type air purification device as a device for purifying air using water without using a filter. Therefore, the water-type air purification device accumulates a constant amount of water in the bottom of the water tank, blows air into the water, and brings the air into contact with water.
[0004] しかし、フィルタ付換気装置によって外気を取り込み続けると、塵埃によってフィルタ が目詰まりする。そのため、フィルタの清掃又は交換を必要とし、そのメンテナンスに 手間とコストが掛かってしまう。また、フィルタでは、外気中の NOx、 SOx、 NH4等のガ スゃ悪臭の元となるガスを十分に除去することはできず、 NOx、 SOx、 NH4等のガスを 住宅内に取り込んでしまう。  However, if the outside air is continuously taken in by the ventilation device with a filter, the filter is clogged with dust. Therefore, it is necessary to clean or replace the filter, and the maintenance thereof takes time and cost. In addition, the filter cannot sufficiently remove gases such as NOx, SOx, NH4, etc. in the outside air that cause bad odors, and gas such as NOx, SOx, NH4, etc. is taken into the house.
また、ため水式の空気浄化装置では、水中に気体を吹き込む過程において抵抗が 高ぐ水中に空気を吹き込むために高出力の送風機が必要となる。  In addition, in order to blow air into the water, which has high resistance in the process of blowing gas into the water, a high-power blower is required for the water-type air purification device.
[0005] そこで、本発明の主な目的は、フィルタの清掃'交換を殆ど必要とせず、 NOx、 SOx 、 NH4等のガスや悪臭の元となるガスを除去して住宅内に取り込むことができ、更に 低出力の送風機でも空気を浄化することができる空気浄化装置を提供することである [0005] Therefore, the main object of the present invention is that almost no cleaning or replacement of the filter is required, and gases such as NOx, SOx, NH4, and other gases that cause odors can be removed and taken into the house. Furthermore, it is to provide an air purification device that can purify air even with a low-power blower.
Yes
発明の開示 [0006] 本発明の一態様によれば、吸気口に通じるとともに排気口に通じる内部空間を有し た洗浄塔と、空気を前記吸気口から前記洗浄塔の内部空間に取り込んで前記排気 口から前記洗浄塔の外に送り出すよう送風する送風機と、前記洗浄塔の内部空間に 配置され、前記洗浄塔の内部空間内で水を散布するノズルと、を備え、前記ノズルか ら散布された水が前記洗浄塔内で前記送風機により送風された空気と接触する、空 気浄化装置が提供される。 Disclosure of the invention [0006] According to one aspect of the present invention, a cleaning tower having an internal space that communicates with an intake port and also communicates with an exhaust port, and air is taken into the internal space of the cleaning tower from the intake port. A blower for sending air to the outside of the washing tower; and a nozzle arranged in the internal space of the washing tower for spraying water in the internal space of the washing tower, wherein the water sprayed from the nozzle is An air purification device is provided that contacts the air blown by the blower in the cleaning tower.
図面の簡単な説明  Brief Description of Drawings
[0007] [図 1]本発明の第 1実施形態における空気浄化装置を破断した状態で示した概略図 である。  FIG. 1 is a schematic view showing the air purification device in a first embodiment of the present invention in a broken state.
[図 2]本発明の第 2実施形態における空気浄化装置を破断した状態で示した概略図 である。  FIG. 2 is a schematic diagram showing the air purification device in a second embodiment of the present invention in a broken state.
[図 3]本発明の第 3実施形態における空気浄化装置を破断した状態で示した概略図 である。  FIG. 3 is a schematic view showing an air purification device in a third embodiment of the present invention in a broken state.
[図 4]吸気口及び排気口の空気中に含まれる NOxの濃度の測定結果を示したグラフ である。  [Fig. 4] A graph showing the measurement results of the concentration of NOx contained in the air at the intake and exhaust ports.
[図 5]本発明の第 4実施形態における空気浄化装置を破断した状態で示した概略図 である。  [Fig. 5] Fig. 5 is a schematic view showing a state in which an air purification device according to a fourth embodiment of the present invention is broken.
[図 6]第 4実施形態における空気浄化装置の気液接触構造に備わる籠を示した斜視 図である。  FIG. 6 is a perspective view showing a bag provided in the gas-liquid contact structure of the air purification device in the fourth embodiment.
[図 7]本発明の第 5実施形態における空気浄化装置を破断した状態で示した概略図 である。  [Fig. 7] Fig. 7 is a schematic view showing a state in which an air purification device according to a fifth embodiment of the present invention is broken.
[図 8]第 5実施形態における空気浄化装置の気液接触構造に備わる籠を示した斜視 図である。  FIG. 8 is a perspective view showing a bag provided in a gas-liquid contact structure of an air purification device in a fifth embodiment.
[図 9]本発明の第 6実施形態における空気浄化装置を破断した状態で示した概略図 である。  FIG. 9 is a schematic view showing an air purification device in a broken state according to a sixth embodiment of the present invention.
[図 10]本発明の第 7実施形態における空気浄化装置を破断した状態で示した概略 図である。  FIG. 10 is a schematic view showing an air purification device in a broken state according to a seventh embodiment of the present invention.
[図 11]第 7実施形態における空気浄化装置の気液接触構造に備わる板の変形例を 示した概略図である。 FIG. 11 shows a modification of the plate provided in the gas-liquid contact structure of the air purification device according to the seventh embodiment. It is the shown schematic.
[図 12]第 7実施形態における空気浄化装置の気液接触構造に備わる板の変形例を 示した概略図である。  FIG. 12 is a schematic view showing a modification of the plate provided in the gas-liquid contact structure of the air purifying device in the seventh embodiment.
[図 13]本発明の第 8実施形態における空気浄化装置を破断した状態で示した概略 図である。  FIG. 13 is a schematic view showing an air purification device in a broken state according to an eighth embodiment of the present invention.
[図 14]吸気口及び排気口の空気中に含まれる NOxの濃度の測定結果を示したダラ フである。  [Fig. 14] A graph showing the measurement results of the concentration of NOx contained in the air at the intake and exhaust ports.
発明を実施するための好ましい形態  Preferred form for carrying out the invention
[0008] 以下に、本発明を実施するための好ましい形態について図面を用いて説明する。  [0008] Preferred embodiments for carrying out the present invention will be described below with reference to the drawings.
[0009] <第 1の実施の形態〉  <First Embodiment>
図 1は、空気浄化装置 1の縦断面図である。この空気浄化装置 1は住宅に設置され ており、この空気浄化装置 1によって住宅の外の空気が住宅内に取り込まれる。  FIG. 1 is a longitudinal sectional view of the air purification device 1. The air purification apparatus 1 is installed in a house, and the air purification apparatus 1 takes in air outside the house into the house.
[0010] 図 1に示すように、ケーシング 30によってその内側に空間が形成されている。ケー シング 30の側面の下部には、吸気口 31が形成されており、ケーシング 30の側面の 上部には、排気口 37が形成されて!/、る。吸気口 31には、ルーバー 5が設けられ、排 気口 37にも、ルーバー 6が設けられて!/、る。吸気口 31は、住宅の外に露出して!/、る 力、、又はダクトを通じて住宅の外に通じている。排気口 37は、住宅の中に露出してい る力、、又は、ダクトを通じて住宅の中に通じている。  As shown in FIG. 1, a space is formed inside the casing 30. An intake port 31 is formed in the lower part of the side surface of the casing 30, and an exhaust port 37 is formed in the upper part of the side surface of the casing 30! /. The louver 5 is provided at the intake port 31 and the louver 6 is provided at the exhaust port 37! /. The air inlet 31 is exposed outside the house and communicates with the outside through the force or duct. The outlet 37 communicates with the force exposed in the house or through the duct.
[0011] ケーシング 30の内側には、吸気ダクト 33、排気ダクト 35及び洗浄塔 40が設けられ ている。洗浄塔 40は上下方向に長尺に設けられており、その洗浄塔 40の内側に内 部空間が形成されている。洗浄塔 40の内部空間の上下中間部が噴霧室 41とされて おり、洗浄塔 40の内部空間の下部がドレインパン 42とされ、洗浄塔 40の内部空間の 上部が排気室 43とされている。噴霧室 41とドレインパン 42は通じ、排気室 43と噴霧 室 41が通じている。  [0011] Inside the casing 30, an intake duct 33, an exhaust duct 35, and a cleaning tower 40 are provided. The cleaning tower 40 is long in the vertical direction, and an internal space is formed inside the cleaning tower 40. The upper and lower middle part of the internal space of the cleaning tower 40 is the spray chamber 41, the lower part of the internal space of the cleaning tower 40 is the drain pan 42, and the upper part of the internal space of the cleaning tower 40 is the exhaust chamber 43. . The spray chamber 41 and the drain pan 42 communicate with each other, and the exhaust chamber 43 and the spray chamber 41 communicate with each other.
[0012] ドレインパン 42には、水が貯留される。また、ドレインパン 42には、殺菌装置 15が 設けられており、ドレインパン 42に貯留された水が殺菌装置 15により殺菌される。  [0012] Water is stored in the drain pan 42. In addition, the drain pan 42 is provided with a sterilizer 15, and water stored in the drain pan 42 is sterilized by the sterilizer 15.
[0013] 殺菌装置 15は、紫外線照射、電解殺菌、高温殺菌、殺菌剤充填層への通水、又 は本実施形態の空気浄化装置 1の構造体の少なくとも一部の表面への殺菌効果を 付与する表面処理の何れか単独又はこれらの組み合わせによって構成される。 [0013] The sterilizing device 15 has an ultraviolet irradiation, electrolytic sterilization, high-temperature sterilization, water flow to the sterilizing agent packed layer, or sterilizing effect on at least a part of the surface of the structure of the air purification device 1 of the present embodiment. It is constituted by any one of surface treatments to be applied or a combination thereof.
[0014] 紫外線照射は、水銀ランプなどの殺菌能力を有する光線を発する光源をドレインパ ン 42に浸漬する力、、又は水の循環流路のいずれかに設置し、該殺菌ランプ部に水 を流通させる流通式によって行われる。該殺菌能力を有する光源としては、高圧又は 低圧水銀ランプなどが好適に用いられ、照射紫外線としては、該ランプより照射され る波長 254nm付近、及び/又は 182nm付近の紫外線が好適に殺菌効果を達成す ること力 Sできる。殺菌を好適に達成する紫外線照射量は、光源と被照射水との距離、 及び照射時間によって大きく影響される力 一般に光源において、 0. 01W- s/cm2 以上、好ましくは、 0. 025—0. 05W' s/cm2が望ましい。 [0014] In the ultraviolet irradiation, a light source that emits light having a sterilizing ability, such as a mercury lamp, is installed in either the drain pan 42 or the water circulation channel, and water is circulated through the sterilizing lamp section. It is done by the distribution formula. As the light source having the sterilizing ability, a high-pressure or low-pressure mercury lamp is preferably used, and as the irradiated ultraviolet light, ultraviolet light with a wavelength of about 254 nm and / or about 182 nm irradiated from the lamp preferably achieves a sterilizing effect. Sliding power S The amount of UV irradiation for achieving sterilization is a force greatly influenced by the distance between the light source and the water to be irradiated and the irradiation time. Generally, at the light source, 0.01 W-s / cm 2 or more, preferably 0.025- 0. 05W 's / cm 2 is desirable.
[0015] 電解殺菌とは、少なくとも陽極、陰極一対の電極に直流電圧を印加するものであり 、ドレインパン 42に浸漬する力、、又は水の循環経路の何れかに設置し、該電解殺菌 部に水を流通させる流通式によって行われる。電解による殺菌は、水に塩化物イオン が含まれる場合は、陽極で生成される有効塩素が主たる殺菌有効成分である。水の 塩化物イオン濃度が低い場合は、水に食塩、塩酸、塩化カルシウムなどの塩化物ィ オンを含有する薬品、または海水、にがりなどの塩化物イオンを含有する天然物など を添加しても良い。殺菌効果を好適に達成する有効塩素濃度は、水の pHの影響を 受け、一般に酸性において殺菌効果は高い。し力もながら、 pH酸性で高濃度の有 効塩素を含有する水は、臭気、並びに特に金属材料に対する腐食などを引き起こす ため、この空気浄化装置 1においては、有効塩素濃度 0. ;!〜 lOOmg C1/1好ましく は 0. 2~10mg C1/1であり、力、つ pH2〜; 12、より好ましくは、 pH3〜; 10とすることカ 望ましい。水に塩化物イオンが含まれないか、又は、塩化物イオン濃度が lmg/1以 下などの低濃度の場合には、電解殺菌は、陽極において水分解によって生成するォ ゾン、過酸化水素、 OHラジカルなどの活性酸素による殺菌、または陽極への菌体の 接触による陽極酸化による殺菌によって達成される。この場合、少なくとも陽極の一 部を多孔質体として表面積を大きくし、該多孔質体部に水を流通させることによって、 水と陽極の接触効率を高めると、より好適に殺菌を達成することができる。電解殺菌 で用いられる陰極としては、導電性炭素材料、鉄、ステンレス、その他金属類が好適 に用いられる。陽極としては、白金、金などの貴金属類、チタン基板に白金、イリジゥ ム、ルテニウム、ロジウム、タンタルなどを単独または複数成分混合して、メツキまたは これらの焼結体酸化物被膜を形成させたものが好適である。水に硬度成分が多く存 在し、かつ流通式の電解殺菌を行う場合などでは、定期的に陽極と陰極の極性を反 転させることにより、陰極への硬度スケールの付着を防止することが出来る。この場合 、電極材料としては、上記陽極材料が好ましい。また、陽極における有効塩素生成を 効率よく行うには、陽極材料成分として、イリジウム、ルテニウムが含まれることが望ま しぐオゾン生成を促進するには、陽極に二酸化鉛が含まれることが望ましい。電極 の形状は、板、多孔質体、パンチングメタル、エキスパンドメタルなどより、通水型、浸 漬型などの接液方式を勘案して適宜選択される。電極間に流される電解電流密度は 、上記の殺菌機構の違いから、 目的とする電極反応に応じて選択される力 0. ;!〜 2 OA/dm2が好適である。 [0015] The electrolytic sterilization is to apply a DC voltage to at least a pair of electrodes of the anode and the cathode, and is installed in either the force immersed in the drain pan 42 or the water circulation path, and the electrolytic sterilization unit It is carried out by a circulation type that circulates water. In electrolysis sterilization, when chlorine ions are contained in water, effective chlorine produced at the anode is the main sterilizing active ingredient. If the chloride ion concentration of water is low, chemicals containing chloride ions such as salt, hydrochloric acid, calcium chloride, or natural products containing chloride ions such as seawater and bittern may be added to the water. good. The effective chlorine concentration that suitably achieves the bactericidal effect is affected by the pH of water, and generally has a high bactericidal effect in acidity. However, water with acidic pH and high concentration of effective chlorine causes odor and especially corrosion on metal materials. Therefore, in this air purifier 1, effective chlorine concentration is 0.;! ~ LOOmg C1 / 1 Preferably 0.2 to 10 mg C1 / 1, and force, pH 2 to 12, more preferably pH 3 to 10 is desirable. If the water does not contain chloride ions, or if the chloride ion concentration is low, such as lmg / 1 or less, the electrolytic sterilization is performed by ozone, hydrogen peroxide, This can be achieved by sterilization by active oxygen such as OH radicals, or by anodic oxidation by contacting cells with the anode. In this case, sterilization can be more suitably achieved by increasing the contact efficiency between water and the anode by increasing the surface area of at least a portion of the anode as a porous body and flowing water through the porous body. it can. As the cathode used for electrolytic sterilization, a conductive carbon material, iron, stainless steel, and other metals are preferably used. As the anode, platinum, gold and other precious metals, titanium substrate with platinum, iridium It is preferable to form a metal oxide or a sintered oxide film of these by mixing a single component or a mixture of a plurality of components such as mu, ruthenium, rhodium, and tantalum. When there are many hardness components in water and flow-type electrolytic sterilization is performed, it is possible to prevent the hardness scale from adhering to the cathode by periodically reversing the polarity of the anode and the cathode. . In this case, the electrode material is preferably the above anode material. In order to efficiently produce effective chlorine at the anode, it is desirable that iridium and ruthenium are included as anode material components. To promote the ozone generation that is desirable, it is desirable that the anode contains lead dioxide. The shape of the electrode is appropriately selected from a plate, a porous body, a punching metal, an expanded metal, and the like in consideration of a liquid contact method such as a water flow type and an immersion type. The electrolysis current density passed between the electrodes is preferably a force of 0.;! To 2 OA / dm 2 selected in accordance with the target electrode reaction due to the difference in the sterilization mechanism.
[0016] 高温殺菌とは、 60°C以上、好ましくは 80°C以上の高温に水又は空気を昇温するか 、または同温度以上に昇温された金属メッシュなどの昇温体に該流体を接触せしめ ることにより該流体中の菌を死滅させる手段である。この空気浄化装置 1においては 、循環水流路の一部を昇温するか、または空気流通経路に昇温体を設置して殺菌を 行う。後述のエリミネータ 11を電気ヒータなどで昇温し、殺菌用昇温体として兼用して も良い。 [0016] The high temperature sterilization means that the temperature of water or air is raised to a high temperature of 60 ° C or higher, preferably 80 ° C or higher, or the fluid is applied to a temperature rising body such as a metal mesh heated to the same temperature or higher. This is a means for killing bacteria in the fluid by bringing them into contact with each other. In the air purification device 1, the temperature of a part of the circulating water flow path is raised, or a temperature raising body is installed in the air circulation path to perform sterilization. The eliminator 11 described later may be heated with an electric heater or the like, and may also be used as a heating element for sterilization.
[0017] 殺菌剤充填層への通水、又は空気浄化装置 1の構造体の少なくとも一部の表面へ の殺菌効果を付与する表面処理による殺菌で用いられる殺菌剤とは、例えば、銀や 銅などの殺菌効果を有する金属を活性炭ゃゼオライトなどの吸着剤に物理吸着させ たもの、あるいは該金属を吸着させた活性炭ゃゼオライトなどの粉末を更にナイロン などに練り込んで繊維状に加工したもの、沃素を陰イオン交換基を有する固体表面 にイオン結合によって固定化したもの、第 4級アンモニゥム基を有する陰イオン交換 体、ポリミキシンをァガロースに結合させたもの、アルコキシシリル基を導入した殺菌 剤-抗菌剤と担体表面の水酸基などとを脱アルコール反応で結合させて共有結合に よって殺菌剤 ·抗菌剤を固定化したもの、ベンジル基、メチレン基、エステルなどを介 してポリマー鎖に殺菌剤 ·抗菌剤を共有結合によって固定化したもの、更にこれらを 対象物表面に塗布又はコーティングして対象物表面を固定化殺菌 ·抗菌剤化したも のなどを挙げることができる(高麗寛紀、化学と生物、 26 (12)、 834— 841 (1988) ) 。これらの殺菌剤を単独、又は複数組み合わせて、水循環経路に設置して殺菌剤充 填部を形成し、該殺菌剤部に水又は空気を流通させる力、、又はこの空気浄化装置 1 の構造体の少なくとも一部の表面を上記殺菌剤で表面処理し、該表面に水または空 気を接触させて殺菌を行うことができる。 [0017] The bactericidal agent used in the sterilization by the surface treatment that imparts the bactericidal effect to the surface of at least a part of the structure of the air purifier 1 or the water passing through the bactericidal agent packed layer is, for example, silver or copper Such as those obtained by physically adsorbing a metal having a bactericidal effect on an adsorbent such as activated carbon or zeolite, or by further kneading a powder of activated carbon or zeolite adsorbed with the metal into nylon or the like, Iodine immobilized on a solid surface having an anion exchange group by an ionic bond, an anion exchanger having a quaternary ammonium group, a polymyxin bonded to agarose, a fungicide containing an alkoxysilyl group-antibacterial The antibacterial agent and antibacterial agent are immobilized by covalent bonds, such as benzyl group and methylene group. Which was via ester and was covalently immobilized disinfectant and antibacterial agent to the polymer chain, also further immobilized sterilization and antibacterial Zaika coating or coating to the surface of the object to the object surface thereof (Kano Hiroki, Chemistry and Biology, 26 (12), 834—841 (1988)). These disinfectants are used alone or in combination, and are installed in the water circulation path to form a disinfectant filling part, and the force for flowing water or air through the disinfectant part, or the structure of the air purification device 1 It is possible to perform sterilization by subjecting at least a part of the surface to a surface treatment with the above bactericide and bringing the surface into contact with water or air.
[0018] なお、ドレインパン 42に貯留された水を残留塩素で殺菌してもよい。また、ドレイン パン 42に貯留された水の有効塩素を 0. lmg/L以上 10mg/L以下、好ましくは 1 mg/L以上 3mg/L以下とすることで、水を殺菌してもよ!/、。  [0018] The water stored in the drain pan 42 may be sterilized with residual chlorine. In addition, water can be sterilized by setting the effective chlorine content of the water stored in the drain pan 42 to 0.1 mg / L or more and 10 mg / L or less, preferably 1 mg / L or more and 3 mg / L or less! / ,.
[0019] 吸気ダクト 33の一端が吸気口 31に通じ、吸気ダクト 33の他端が洗浄塔 40の上下 中間部に連結されて噴霧室 41に通じている。吸気ダクト 33の内側には、プレフィルタ 7が設けられ、プレフィルタ 7によって吸気口 31が閉塞されている。なお、プレフィルタ 7が設置される箇所は、噴霧室 41と吸気ダクト 33の連結部から吸気口 31までの間で あればどこでも良い。  One end of the intake duct 33 communicates with the intake port 31, and the other end of the intake duct 33 is connected to the upper and lower middle portions of the cleaning tower 40 and communicates with the spray chamber 41. A prefilter 7 is provided inside the intake duct 33, and the intake port 31 is closed by the prefilter 7. The place where the prefilter 7 is installed may be anywhere as long as it is between the connection portion of the spray chamber 41 and the intake duct 33 and the intake port 31.
[0020] 洗浄塔 40の上端には送風機 8が連結され、更にその送風機 8は排気ダクト 35の一 端に連結され、排気ダクト 35の他端が排気口 37に通じている。送風機 8は洗浄塔 40 内の空気を吸引して、排気ダクト 35へ送り出すものである。送風機 8によって外部の 空気が吸気口 31に取り込まれて、吸気ダクト 33、洗浄塔 40、送風機 8、排気ダクト 3 5を通って排気口 37から住宅内へ排出される。  The blower 8 is connected to the upper end of the cleaning tower 40, and the blower 8 is connected to one end of the exhaust duct 35, and the other end of the exhaust duct 35 communicates with the exhaust port 37. The blower 8 sucks the air in the cleaning tower 40 and sends it out to the exhaust duct 35. External air is taken into the air inlet 31 by the air blower 8 and is discharged from the air outlet 37 into the house through the air intake duct 33, the cleaning tower 40, the air blower 8, and the air exhaust duct 35.
[0021] 排気ダクト 35の内側には、フィルタ 9が設けられ、フィルタ 9によって排気口 37が閉 よりも細かい塵埃を集塵することができる。具体的には、フィルタ 9は、 HEPAフィルタ 又は ULP Aフィルタである。なお、フィルタ 9が設置される箇所は、送風機 8から排気 口 37までの間であればどこでも良い。  [0021] A filter 9 is provided inside the exhaust duct 35, and the filter 9 can collect finer dust than the exhaust port 37 is closed. Specifically, the filter 9 is a HEPA filter or a ULP A filter. The place where the filter 9 is installed may be anywhere between the blower 8 and the exhaust port 37.
[0022] 洗浄塔 40の内側であって噴霧室 41の上側には、噴霧器としての複数のスプレーノ ズル 10が設けられている。これらスプレーノズル 10は水を霧状にして散布するもので あり、これらスプレーノズル 10から下側に向力、つて水が噴霧される。具体的には、スプ レーノズル 10は、平均粒子径 10 m以上 1000 m以下の水を噴霧する。更に好ま しくは、スプレーノズノレ 10は、平均粒子径 300 m以上 1000 m以下の水を噴霧 するとよい。なお、スプレーノズル 10の数は複数ではなぐ 1個であっても良い。 A plurality of spray nozzles 10 serving as sprayers are provided inside the cleaning tower 40 and above the spray chamber 41. These spray nozzles 10 spray water in the form of a mist, and water is sprayed downward from these spray nozzles 10. Specifically, the spray nozzle 10 sprays water having an average particle diameter of 10 m or more and 1000 m or less. More preferably, Spray Nozure 10 sprays water with an average particle size of 300 m or more and 1000 m or less. Good. The number of spray nozzles 10 may be one instead of a plurality.
ここで、水滴の落下終末速度が、噴霧室 41内での空気の流速よりも大きぐ NOx、 S Ox、 NH4等の可溶性ガスの溶解効率は接触する粒子径に依存し、水滴の粒子径が 小さいほう力 可溶性ガスの溶解効率が高くなる。そのため、スプレーノズル 10から 噴霧される水の平均粒子径が 10 m以上 1000 m以下である。好ましくは、スプレ 一ノズル 10から噴霧される水の平均粒子径を 300 H m以上 1000 μ m以下とすると 良い。  Here, the falling end velocity of the water droplet is larger than the flow velocity of the air in the spray chamber 41. The dissolution efficiency of the soluble gas such as NOx, S Ox, NH4, etc. depends on the particle size of the contact, and the particle size of the water droplet is Smaller force Increases dissolution efficiency of soluble gas. Therefore, the average particle diameter of water sprayed from the spray nozzle 10 is 10 m or more and 1000 m or less. Preferably, the average particle size of water sprayed from the spray nozzle 10 is 300 Hm or more and 1000 μm or less.
[0023] 洗浄塔 40の内側であってスプレーノズル 10の上方には、エリミネータ 1 1が設けら れ、エリミネータ 1 1によって噴霧室 41と排気室 43が仕切られている。エリミネータ 1 1 を空気が通過すると、通過する空気中の水分がエリミネータ 1 1に付着して捕捉され、 エリミネータ 1 1に付着した水が水滴としてドレインパン 42に滴下する。  An eliminator 11 is provided inside the cleaning tower 40 and above the spray nozzle 10, and the spray chamber 41 and the exhaust chamber 43 are partitioned by the eliminator 11. When air passes through the eliminator 11 1, moisture in the passing air adheres to and is captured by the eliminator 11 1, and the water attached to the eliminator 11 1 drops as a water droplet on the drain pan 42.
[0024] ドレインパン 42には圧送ポンプ 12が連結されている。圧送ポンプ 12は配管 13によ つてスプレーノズル 10に接続している。圧送ポンプ 12はドレインパン 42に貯留され た水を吸い上げ、スプレーノズル 10へと圧送するものである。圧送ポンプ 12によって スプレーノズル 10へ送られた水が圧送ポンプ 12による圧力によってスプレーノズル 1 0から噴霧される。  A pressure feed pump 12 is connected to the drain pan 42. The pressure pump 12 is connected to the spray nozzle 10 by a pipe 13. The pressure pump 12 sucks up the water stored in the drain pan 42 and pumps it to the spray nozzle 10. The water sent to the spray nozzle 10 by the pressure feed pump 12 is sprayed from the spray nozzle 10 by the pressure by the pressure feed pump 12.
[0025] 洗浄塔 40には供給管 16が接続されており、供給源 1 7の水が供給管 16を通って洗 浄塔 40内に供給される。供給源 1 7から供給される水は、水道水、純水、酸性水若し くはアルカリ水又はこれらのうち二種以上を混合させたものである。そのため、スプレ 一ノズル 10から噴霧される水も、水道水、純水、酸性水若しくはアルカリ水又はこれ らのうち二種以上を混合させたものである。  A supply pipe 16 is connected to the cleaning tower 40, and water from the supply source 17 is supplied into the cleaning tower 40 through the supply pipe 16. The water supplied from the supply source 17 is tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these. Therefore, the water sprayed from the spray nozzle 10 is also tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these.
[0026] 供給源 1 7から供給される水が純水である場合、その水は逆浸透装置又はイオン交 換装置によって精製された純水である。供給源 1 7から供給される水が酸性水である 場合、その水は、逆浸透装置によって精製された濃縮水若しくは巿水を電解装置に 供することで得られる当該電解装置の陽極水であるか、又は、電気軟化装置若しくは 電気再生式脱イオン装置の陽極水である。供給源 1 7から供給される水がアルカリ水 である場合、その水は、逆浸透装置によって精製された濃縮水若しくは巿水を電解 装置に供することで得られる当該電解装置の陰極水であるか、電気軟化装置の陰極 水(軟水)であるか、電気再生式脱イオン装置の陰極水であるか、又は、軟水を電解 装置に供することで得られる当該電解装置の陰極水である。 [0026] When the water supplied from the supply source 17 is pure water, the water is pure water purified by a reverse osmosis device or an ion exchange device. If the water supplied from the supply source 17 is acidic water, is the anodic water of the electrolyzer obtained by supplying concentrated water or brine purified by a reverse osmosis device to the electrolyzer? Or an anodizing water of an electric softening device or an electric regenerative deionization device. If the water supplied from the supply source 17 is alkaline water, is the water the cathode water of the electrolyzer obtained by supplying concentrated water or brine purified by a reverse osmosis device to the electrolyzer? , Electrosoftening device cathode It is water (soft water), cathodic water of an electric regenerative deionization device, or cathodic water of the electrolysis device obtained by supplying soft water to the electrolysis device.
[0027] ドレインパン 42の底よりも上の部分には、排水管 14が接続されている。ドレインパン 42に貯留された水の水位が排水管 14の接続箇所になると、ドレインパン 42内の水 が排水管 14を通って排出される。  A drain pipe 14 is connected to a portion above the bottom of the drain pan 42. When the water level stored in the drain pan 42 becomes the connection point of the drain pipe 14, the water in the drain pan 42 is discharged through the drain pipe 14.
[0028] 次に、この空気浄化装置 1の動作について説明する。  Next, the operation of the air purification device 1 will be described.
まず、供給源 17の水が供給管 16を通ってドレインパン 42に貯留される。そして、圧 送ポンプ 12が作動し、ドレインパン 42の水がスプレーノズル 10へ圧送され、スプレー ノズル 10から水が噴霧される。このように圧送ポンプ 12が作動している間、水が循環 する。水の循環中では殺菌装置 15が作動し、循環水が殺菌装置 15によって殺菌さ れる。なお、水の循環中でも供給源 17の水が断続的に、連続的に又は所定サイクル でドレインパン 42に供給される。  First, water from the supply source 17 is stored in the drain pan 42 through the supply pipe 16. Then, the pump 12 is operated, the water in the drain pan 42 is pumped to the spray nozzle 10, and water is sprayed from the spray nozzle 10. Thus, water is circulated while the pressure pump 12 is operating. During the circulation of water, the sterilizer 15 operates, and the circulated water is sterilized by the sterilizer 15. Even during the circulation of water, the water from the supply source 17 is supplied to the drain pan 42 intermittently, continuously or in a predetermined cycle.
[0029] 水の循環中、送風機 8が作動し、住宅の外の空気が吸気口 31に吸い込まれ、吸気 ダクト 33、洗浄塔 40、送風機 8及び排気ダクト 35を順に通って排気口 37から排出さ れる。排気口 37から排出された空気は住宅の中に送られる。ここで、吸気口 31に吸 い込まれた空気がプレフィルタ 7を通過する時に、虫、大きな塵埃、屑等がプレフィル タ 7に捕捉される。  [0029] During the circulation of water, the blower 8 is activated, and the air outside the house is sucked into the intake 31 and exhausts through the intake 37 through the intake duct 33, the cleaning tower 40, the blower 8, and the exhaust duct 35 in this order. It is done. The air exhausted from the exhaust port 37 is sent into the house. Here, when the air sucked into the intake port 31 passes through the prefilter 7, insects, large dust, debris, and the like are captured by the prefilter 7.
[0030] 噴霧室 41に取り込まれた空気が上昇している時に、スプレーノズル 10から噴霧さ れた水滴が空気中の塵埃等に接触する。スプレーノズル 10から水が噴霧される向き は、噴霧室 41内において空気が上昇する向きと逆である。塵埃等を含んだ水はドレ インパン 42に滴下したり、エリミネータ 11に捕捉されてドレインパン 42に滴下したりす る。そのため、洗浄塔 40を通過する空気から塵埃等が除去される。  [0030] When the air taken into the spray chamber 41 is rising, water droplets sprayed from the spray nozzle 10 come into contact with dust or the like in the air. The direction in which water is sprayed from the spray nozzle 10 is opposite to the direction in which air rises in the spray chamber 41. The water containing dust or the like is dripped onto the drain pan 42 or is captured by the eliminator 11 and dropped onto the drain pan 42. Therefore, dust and the like are removed from the air passing through the cleaning tower 40.
[0031] 洗浄塔 40を通過した空気がフィルタ 9を通過する時に、プレフィルタ 7や洗浄塔 40 で除去しきれなかった塵埃力 Sフィルタ 9に捕捉される。そして、フィルタ 9を通過した空 気が排気口 37から排出されて住宅の中に送られる。  When the air that has passed through the cleaning tower 40 passes through the filter 9, it is captured by the dust force S filter 9 that could not be removed by the pre-filter 7 or the cleaning tower 40. Then, the air passing through the filter 9 is discharged from the exhaust port 37 and sent into the house.
[0032] 以上のように本実施形態によれば、吸気口 31に吸い込まれた空気はフィルタ 9の 通過前に洗浄塔 40を通過し、空気中の塵埃等が洗浄塔 40内の霧によって殆ど除去 される。また、塵埃のみならず水溶性のガスや固体も洗浄塔 40内の霧によって除去 すること力 Sできる。そのうえ、空気がフィルタ 9を通過する際には、その空気には塵埃 等が殆ど含まれていないから、フィルタ 9の目詰まりを長期間にわたって防止すること ができる。従って、フィルタ 9を長期間にわたって清掃せずとも、フィルタ 9の交換サイ クノレを長くすることカでさる。 As described above, according to the present embodiment, the air sucked into the intake port 31 passes through the cleaning tower 40 before passing through the filter 9, and dust or the like in the air is mostly caused by fog in the cleaning tower 40. Removed. In addition to dust, water-soluble gases and solids are removed by the mist in the cleaning tower 40. The power to do S. In addition, when the air passes through the filter 9, the air hardly contains dust and the like, so that the filter 9 can be prevented from being clogged for a long period of time. Therefore, even if the filter 9 is not cleaned over a long period of time, the replacement cycle of the filter 9 can be lengthened.
[0033] 以上のようにこの空気浄化装置 1を用いれば、住宅の中に送り込む空気の浄化'脱 臭をすることができ、住宅内への給気もより衛生的にすることができる。特に、エリミネ ータ 11によって水が捕捉されることによって、住宅内に送り込まれる空気中に噴霧水 が残留せず、より浄化された空気が住宅内に送り込まれる。  [0033] By using the air purification device 1 as described above, the air sent into the house can be purified and deodorized, and the air supply to the house can be made more sanitary. In particular, when water is captured by the eliminator 11, spray water does not remain in the air sent into the house, and more purified air is sent into the house.
[0034] その上、ドレインパン 42の底に貯留された水が殺菌装置 15によって殺菌されるの で、循環している水の汚染を抑えることができる。そのため、空気浄化装置 1が長期 に動作していても、住宅内に送り込まれる空気が浄化された状態を保つことができる  In addition, since the water stored at the bottom of the drain pan 42 is sterilized by the sterilizer 15, contamination of the circulating water can be suppressed. Therefore, even if the air purification device 1 has been operating for a long time, the air sent into the house can be kept purified.
[0035] 更に、噴霧された水によって取り除かれた塵埃等の一部は、ドレインパン 42に貯留 した水の水面に浮上し、浮上した塵埃等は水とともに排水管 14を通じて排出される。 そのため、循環している水に塵埃等が貯まっていくことを抑えることができる。 Furthermore, a part of the dust removed by the sprayed water floats on the surface of the water stored in the drain pan 42, and the dust that has floated is discharged through the drain pipe 14 together with the water. Therefore, it can suppress that dust etc. accumulate in the circulating water.
[0036] なお、上記実施形態では、吸気口 31が住宅の外に露出している力、、又はダクトを 通じて住宅の外に通じていた力 吸気口 31が住宅の中に露出している力、、又は、ダ タトを通じて住宅の中に通じていても良い。このようにすれば、住宅の中の空気が吸 気口 31に吸レ、込まれ、塵埃等を除去した空気が排気口 37から住宅の中に供給され る。これにより、住宅の中の空気を浄化することができる。  [0036] In the above embodiment, the force that the air inlet 31 is exposed to the outside of the house, or the force that has led to the outside of the house through the duct. The air inlet 31 is exposed to the inside of the house. You may communicate with the house through force or data. In this way, the air in the house is sucked into and sucked into the air inlet 31, and the air from which dust and the like are removed is supplied into the house through the air outlet 37. Thereby, the air in a house can be purified.
[0037] また、吸気口 31とは別に吸気口をケーシング 30に設け、その別の吸気口と噴霧室 41をダクトで接続し、その別の吸気口を住宅の中に露出させるか又はダクトを通じて 住宅の中に通じさせても良い。このようにすることで、吸気口 31から外気が取り込まれ 、別の吸気口からは住宅内の空気が取り込まれ、取り込まれた空気が洗浄塔 40内に おいて浄化し、その浄化した空気が排気口 37から住宅に送り込まれる。  [0037] In addition to the intake port 31, an intake port is provided in the casing 30, the other intake port and the spray chamber 41 are connected by a duct, and the other intake port is exposed in the house or through the duct. You may let it go into the house. By doing so, outside air is taken in from the air intake 31, air in the house is taken in from another air intake, and the taken-in air is purified in the cleaning tower 40, and the purified air is It is sent into the house through exhaust port 37.
[0038] また、洗浄塔 40の前段と後段にそれぞれプレフィルタ 7、フィルタ 9が設けられてい る力 プレフィルタ 7とフィルタ 9のどちらか一方であっても良い。更に、プレフィルタ 7 、フィルタ 9の両方が設けられていなくても良い。 [0039] また、上記実施形態ではスプレーノズル 10が下向きに水を噴霧していた力 スプレ 一ノズル 10が上向きに水を噴霧しても良い。また、上記実施形態では取り込まれた 空気が噴霧室 41で上昇するよう流れている力 逆に下降するように流れても良い。上 記実施形態では、スプレーノズル 10から噴霧される水の向き力 噴霧室 41内での空 気の流れの向きの逆になつていたが、それら向きの関係は特に限定するものではな く、例えば、スプレーノズル 10から噴霧される水の向きが噴霧室 41内での空気の流 れの向きと同じであっても良いし、スプレーノズル 10から噴霧される水の向きが噴霧 室 41内での空気の流れの向きに対して垂直であっても良い。 [0038] Further, the pre-filter 7 and the filter 9 provided with the pre-filter 7 and the filter 9 respectively in the front and rear stages of the cleaning tower 40 may be either the pre-filter 7 or the filter 9. Further, both the pre-filter 7 and the filter 9 may not be provided. [0039] In the above embodiment, the spray nozzle 10 sprays water downward. The spray nozzle 10 may spray water upward. Further, in the above embodiment, the force of the air taken in to rise in the spray chamber 41 may flow so as to descend. In the above embodiment, the direction force of the water sprayed from the spray nozzle 10 is opposite to the direction of the air flow in the spray chamber 41, but the relationship between these directions is not particularly limited. For example, the direction of water sprayed from the spray nozzle 10 may be the same as the direction of air flow in the spray chamber 41, or the direction of water sprayed from the spray nozzle 10 in the spray chamber 41. It may be perpendicular to the direction of air flow.
[0040] また、上記実施形態では圧送ポンプ 12によって水をスプレーノズル 10に圧送して いたが、水に加えて圧縮空気をコンプレッサーによってスプレーノズル 10に送っても 良い。  [0040] In the above embodiment, water is pumped to the spray nozzle 10 by the pumping pump 12, but compressed air may be fed to the spray nozzle 10 by a compressor in addition to water.
[0041] <第 2の実施の形態〉  [0041] <Second Embodiment>
第 1実施形態の空気浄化装置 1においては、圧送ポンプ 12によってドレインパン 4 2の水を吸い上げてスプレーノズル 10に圧送していた。それに対して、第 2実施形態 においては、図 2に示された空気浄化装置 1Aのように、圧送ポンプ 12Aによって供 給源 17の水を吸い上げてスプレーノズル 10に圧送しても良い。そのため、この空気 浄化装置 1Aでは、水が循環せず、スプレーノズル 10から噴霧されてドレインパン 42 に貯留された水は排水管 14を通って排出される。また、この空気浄化装置 1Aにお いては、水が循環しないので、前記洗浄塔 40内には、殺菌装置が設けられていない In the air purification device 1 of the first embodiment, the water in the drain pan 42 is sucked up by the pressure pump 12 and is pumped to the spray nozzle 10. On the other hand, in the second embodiment, as in the air purification device 1A shown in FIG. 2, the water of the supply source 17 may be sucked up by the pressure pump 12A and pumped to the spray nozzle 10. Therefore, in this air purification device 1A, water does not circulate, and the water sprayed from the spray nozzle 10 and stored in the drain pan 42 is discharged through the drain pipe 14. Further, in this air purification device 1A, since water does not circulate, no sterilizer is provided in the cleaning tower 40.
Yes
[0042] 以上のことを除いて、この空気浄化装置 1Aは第 1実施形態の空気浄化装置 1と同 様に設けられており、空気浄化装置 1Aと空気浄化装置 1の間で互いに対応する部 分が同様に設けられている場合には同一の符号を付す。この空気浄化装置 1Aにお いても、住宅の中に送り込む空気の浄化 ·脱臭をすることができ、フィルタ 9の交換サ イタルを長期化することができる。  [0042] Except for the above, this air purification device 1A is provided in the same manner as the air purification device 1 of the first embodiment, and the air purification device 1A and the air purification device 1 correspond to each other. When the minutes are provided in the same manner, the same reference numerals are given. Even with this air purification device 1A, it is possible to purify and deodorize the air sent into the house, and to extend the replacement cycle of the filter 9.
[0043] <第 3の実施の形態〉  [0043] <Third embodiment>
第 3実施形態においては、図 3に示された空気浄化装置 1Bのように、噴霧室 41が 糸罔 91Β· 92Βによって三つの室 41B, 41C, 41Dに区画されており、ドレインノ ン 42 力 ^鬲壁 95B, 96Βによって三つの室 42Β, 42C, 42Dに区画されている。ここで、糸罔 91Bは隔壁 95Βの上に連なっており、網 92Βは隔壁 96Βの上に連なっている。網 95 Βは室 41Bと室 41Cとを仕切り、網 96Βは室 41Cと室 41Dとを仕切り、隔壁 95Βは室 42Βと室 42Cとを仕切り、 鬲壁 96は室 42Cと室 42Βとを仕切っている。ダクト 33は室 41Cの反対側において室 41Bに通じている。室 41B及び室 41Cの上は隔壁 98Βに よって塞がれ、室 41Dの上が開放されて、室 41Dと排気室 43がエリミネータ 11を介 して通じている。 In the third embodiment, as in the air purification device 1B shown in FIG. 3, the spray chamber 41 is divided into three chambers 41B, 41C, and 41D by yarn hooks 91Β and 92Β. It is divided into three chambers 42Β, 42C, and 42D by force walls 95B and 96Β. Here, the thread basket 91B continues on the partition wall 95Β, and the net 92Β continues on the partition wall 96Β. Net 95 Β separates room 41B and 41C, net 96 仕切 separates room 41C and 41D, bulkhead 95 仕切 separates room 42 Β and room 42C, 鬲 wall 96 divides room 42C and room 42Β Yes. Duct 33 leads to chamber 41B on the opposite side of chamber 41C. The chamber 41B and the chamber 41C are closed by a partition wall 98 隔壁, the chamber 41D is opened, and the chamber 41D and the exhaust chamber 43 are connected via the eliminator 11.
[0044] また、室 41Bと室 42Βが上下に連なり、室 41Cと室 42Cが上下に連なり、室 41Dと 室 42Dが上下に連なる。室 41Bには供給管 16Bが接続されており、供給源 17Bの水 が供給管 16Bを通って室 41Bに供給され、室 42Βに貯留される。室 41Cには、供給 源 17Cの水が供給管 16Cを通じて供給され、室 41Dには、供給源 17Dの水が供給 管 16Dを通じて供給される。供給源 17Bから供給される水は酸性水であり、供給源 1 7Cから供給される水はアルカリ水であり、供給源 17Dから供給される水は純水である 。供給源 17B, 17C, 17Dと水の種類の組み合わせは特に限定するものではなぐ 例えば供給源 17Βの水がアルカリ水であり、供給源 17Cの水が酸性水であり、供給 源 17Dの水が純水であっても良い。  [0044] Further, the chamber 41B and the chamber 42Β are vertically connected, the chamber 41C and the chamber 42C are vertically connected, and the chamber 41D and the chamber 42D are vertically connected. A supply pipe 16B is connected to the chamber 41B, and water from the supply source 17B is supplied to the chamber 41B through the supply pipe 16B and stored in the chamber 42Β. The chamber 41C is supplied with water from the supply source 17C through the supply pipe 16C, and the chamber 41D is supplied with water from the supply source 17D through the supply pipe 16D. The water supplied from the supply source 17B is acidic water, the water supplied from the supply source 17C is alkaline water, and the water supplied from the supply source 17D is pure water. The combination of source 17B, 17C, 17D and the type of water is not particularly limited.For example, water at source 17Β is alkaline water, water at source 17C is acidic water, and water at source 17D is pure. It may be water.
[0045] 室 41Bの上側にはスプレーノズル 10Bが設けられ、室 41Cの上側にはスプレーノ ズル 10Cが設けられ、室 41Dの上側にはスプレーノズル 10Dが設けられている。圧 送ポンプ 12Bは室 42Βに貯留された水を吸い上げ、スプレーノズル 10Bへ圧送する ものである。圧送ポンプ 12Cは室 42Cに貯留された水を吸い上げ、スプレーノズル 1 OCへ圧送するものである。圧送ポンプ 12Dは室 42Dに貯留された水を吸い上げ、ス プレーノズノレ 10Dへ圧送するものである。  [0045] A spray nozzle 10B is provided above the chamber 41B, a spray nozzle 10C is provided above the chamber 41C, and a spray nozzle 10D is provided above the chamber 41D. The pressure pump 12B sucks up water stored in the chamber 42Β and pumps it to the spray nozzle 10B. The pump 12C sucks up the water stored in the chamber 42C and pumps it to the spray nozzle 1 OC. The pump 12D sucks up the water stored in the chamber 42D and pumps it to the spray nozzle 10D.
[0046] 以上のことを除いて、この空気浄化装置 1Bは第 1実施形態の空気浄化装置 1と同 様に設けられており、空気浄化装置 1Bと空気浄化装置 1の間で互いに対応する部 分に同一の符号を付す。  [0046] Except for the above, this air purification device 1B is provided in the same manner as the air purification device 1 of the first embodiment, and the air purification device 1B and the air purification device 1 correspond to each other. The same sign is attached to the minutes.
[0047] この空気浄化装置 1Bの動作につ!/、て説明する。  [0047] The operation of the air purifier 1B will be described.
まず、供給源 17Bの水が供給管 16Bを通って室 42Βに貯留される。供給源 17C, 1 7Dの水も室 42C, 42Dにそれぞれ貯留される。そして、圧送ポンプ 12Bが作動し、 室 42Bの水がスプレーノズル 1 OBへ圧送され、スプレーノズル 10Bから水が噴霧され る。同様に、室 42C, 42Dの水もスプレーノズル IOC, 10Dからそれぞれ噴霧される 。圧送ポンプ 12B, 12C, 12Dによる水の循環中、送風機 8が作動し、住宅の外の空 気が吸気口 31に吸い込まれ、吸気ダクト 33、室 41B、室 41C、室 41D、送風機 8及 び排気ダクト 35を順に通って排気口 37から排出される。排気口 37から排出された空 気は住宅の中に送られる。 First, water from the supply source 17B is stored in the chamber 42Β through the supply pipe 16B. Water from sources 17C and 17D is also stored in chambers 42C and 42D, respectively. And the pumping pump 12B is activated, Water in chamber 42B is pumped to spray nozzle 1OB and water is sprayed from spray nozzle 10B. Similarly, water in the chambers 42C and 42D is sprayed from the spray nozzles IOC and 10D, respectively. While the water is circulated by the pressure pumps 12B, 12C, 12D, the blower 8 is activated, and the air outside the house is sucked into the intake port 31, and the intake duct 33, chamber 41B, chamber 41C, chamber 41D, fan 8, and The gas is discharged from the exhaust port 37 through the exhaust duct 35 in order. The air discharged from the exhaust port 37 is sent into the house.
[0048] <実施例 1〉  <Example 1>
図 1に示された空気浄化装置 1を用いて NOxの確認試験を行った。  A NOx confirmation test was conducted using the air purification device 1 shown in FIG.
実験室内に空気浄化装置 1を設置し、吸気口 31から実験室室内空気を噴霧室 41 に送風機 8により導入した。噴霧室 41の大きさは 300mm X 300mm X 300mmであ り、その容量は 27Lである。室内空気導入の流量を約 100m3/hrとした。 The air purifier 1 was installed in the laboratory, and the laboratory room air was introduced into the spray chamber 41 from the air inlet 31 by the blower 8. The size of the spray chamber 41 is 300mm x 300mm x 300mm, and its capacity is 27L. The flow rate for introducing indoor air was about 100 m 3 / hr.
[0049] 送風機 8を運転し、室内空気を導入した状態で、逆浸透装置によって生成された純 水をスプレーノズル 10から水量 1L/分で噴霧した。そして、一定時間ごとに排気口 37から排出される気体を純水の入ったガス捕集瓶に捕集し、その気体をガス捕集瓶 内の純水に溶解し、純水中の亜硝酸イオン (NO―)濃度をイオンクロマトグラフィー分 析装置で分析した。なお、ガス捕集瓶の容量は lOOmLであり、ガス捕集用純水量は 50mLであり、 5NL/分の流量の気体を 60分間捕集した。  [0049] Pure air generated by the reverse osmosis device was sprayed from the spray nozzle 10 at a water amount of 1 L / min while the blower 8 was operated and the room air was introduced. The gas discharged from the exhaust port 37 is collected in a gas collection bottle containing pure water at regular intervals, and the gas is dissolved in pure water in the gas collection bottle. The ion (NO-) concentration was analyzed with an ion chromatography analyzer. The volume of the gas collection bottle was lOOmL, the amount of pure water for gas collection was 50 mL, and a gas with a flow rate of 5 NL / min was collected for 60 minutes.
[0050] 比較例として、前記の確認試験において、一定時間ごとに吸気口 31に導入される 気体を純水の入ったガス捕集瓶に捕集し、その気体をガス捕集瓶内の純水に溶解し 、純水中の亜硝酸イオン (NO―)濃度を分析した。  [0050] As a comparative example, in the confirmation test described above, the gas introduced into the air inlet 31 at regular intervals is collected in a gas collection bottle containing pure water, and the gas is purified in the gas collection bottle. After dissolving in water, the concentration of nitrite ion (NO-) in pure water was analyzed.
[0051] その結果を表 1及び図 4に示す。  [0051] The results are shown in Table 1 and FIG.
[表 1] 試験開始からの時間 装置出口 装置入口 [table 1] Time from the start of test Equipment exit Equipment entrance
(=噴霧時間) 亜硝酸イオン濃度 (mg/m3) 亜硝酸イオン濃度 (mg/m3)(= Spray time) nitrite ion concentration (m g / m 3) nitrite ion concentration (mg / m 3)
0時間 0.0070 0.00720 hours 0.0070 0.0072
2時間 0.0015 0.00802 hours 0.0015 0.0080
4時間 0.0026 0.00954 hours 0.0026 0.0095
6時間 0.0026 0.01006 hours 0.0026 0.0100
8時間 0.0016 0.0102 8 hours 0.0016 0.0102
[0052] 表 1及び図 4から明らかなように、スプレーノズル 10力も純水を噴霧している噴霧室 の前後である吸気口と排気口の亜硝酸イオン濃度を比較すると、スプレーノズル 10 力も純水を噴霧した後である排気口のほうが亜硝酸イオン濃度が低い。そのため、ス プレーノズル 10から純水を噴霧すると、吸気口から導入される室内空気中の亜硝酸 イオン濃度を低く抑えることができる。 [0052] As can be seen from Table 1 and Fig. 4, when the spray nozzle 10 force is compared with the concentration of nitrite ions at the intake and exhaust before and after the spray chamber spraying pure water, the spray nozzle 10 force is also pure. Nitrite ion concentration is lower in the exhaust port after spraying water. Therefore, when pure water is sprayed from the spray nozzle 10, the nitrite ion concentration in the indoor air introduced from the intake port can be kept low.
[0053] <第 4の実施の形態〉  <Fourth embodiment>
図 5は、空気浄化装置 1Eの縦断面図である。この空気浄化装置 1Eは住宅に設置 されており、この空気浄化装置 1Eによって住宅の外の空気が住宅内に取り込まれる  FIG. 5 is a longitudinal sectional view of the air purification device 1E. This air purification device 1E is installed in a house, and air outside the house is taken into the house by this air purification device 1E.
[0054] 図 5に示すように、洗浄塔 30Eの内側に空間が形成されている。洗浄塔 30Eの側 面の下部には、吸気口 31Eが形成されており、洗浄塔 30Eの側面の上部には、排気 口 37Eが形成されている。吸気口 31Eは、住宅の外に露出している力、、又はダクトを 通じて住宅の外に通じている。排気口 37Eは、住宅の中に露出しているか、又は、ダ タトを通じて住宅の中に通じている。 [0054] As shown in FIG. 5, a space is formed inside the cleaning tower 30E. An intake port 31E is formed in the lower part of the side surface of the cleaning tower 30E, and an exhaust port 37E is formed in the upper part of the side surface of the cleaning tower 30E. The air inlet 31E communicates with the force exposed outside the house or the outside through the duct. Exhaust port 37E is exposed in the house or leads to the house through a dart.
[0055] 洗浄塔 30Eの内側の上部には、送風機 8Eが設けられている。この送風機 8Eは洗 浄塔 30Eの下側の吸気口 31Eから上側の排気口 37Eに向けて送風するものであり、 この送風機 8Eによって吸気口 31Eから洗浄塔 30E内部を経由して排気口 37Eに向 力、つた気流が生じる。 [0055] A blower 8E is provided in an upper portion inside the cleaning tower 30E. This blower 8E blows air from the lower intake port 31E of the cleaning tower 30E toward the upper exhaust port 37E, and this blower 8E passes from the intake port 31E to the exhaust port 37E via the inside of the cleaning tower 30E. For Force and airflow are generated.
[0056] 吸気口 31Eは洗浄塔 30Eの下端よりも上において洗浄塔 30Eの側面に形成され ている。洗浄塔 30Eの内側の空間のうち吸気口 31Eよりも下側の部分 32E (以下、貯 留室 32Eという。)には、水 99Eが貯留されるようになつている。貯留室 32Eに殺菌装 置が設けられ、貯留室 32Eに貯留された水 99Eが殺菌装置によって殺菌処理されて も良い。  [0056] The intake port 31E is formed on the side surface of the cleaning tower 30E above the lower end of the cleaning tower 30E. 99E of water is stored in a portion 32E below the intake port 31E (hereinafter referred to as the storage chamber 32E) in the space inside the cleaning tower 30E. The storage chamber 32E may be provided with a sterilization device, and the water 99E stored in the storage chamber 32E may be sterilized by the sterilization device.
[0057] 前記殺菌装置とは、紫外線照射、電解殺菌、高温殺菌、殺菌剤充填層への通水、 又は本実施形態の空気浄化装置 1Eの構造体の少なくとも一部の表面への殺菌効 果を付与する表面処理の何れか単独又はこれらの組み合わせによって構成される。  [0057] The sterilization device means ultraviolet irradiation, electrolytic sterilization, high-temperature sterilization, water passing through the sterilizing agent-packed layer, or sterilization effect on at least a part of the surface of the structure of the air purification device 1E of the present embodiment. It is comprised by the surface treatment which provides singly, or these combination.
[0058] 紫外線照射は、水銀ランプなどの殺菌能力を有する光線を発する光源を貯留室 32 Eに浸漬するか、又は水の循環流路のいずれかに設置し、該殺菌ランプ部に水を流 通させる流通式によって行われる。該殺菌能力を有する光源としては、高圧又は低 圧水銀ランプなどが好適に用いられ、照射紫外線としては、該ランプより照射される 波長 254nm付近、及び/又は 182nm付近の紫外線が好適に殺菌効果を達成する ことができる。殺菌を好適に達成する紫外線照射量は、光源と被照射水との距離、及 び照射時間によって大きく影響される力 一般に光源において、 0. OlW' s/cm2以 上、好ましくは、 0. 025—0. 05W' s/cm2が望ましい。 [0058] In the ultraviolet irradiation, a light source that emits light having a sterilizing ability, such as a mercury lamp, is immersed in the storage chamber 32E or placed in one of the water circulation channels, and water is allowed to flow through the sterilizing lamp section. It is done by the circulation type. As the light source having the sterilizing ability, a high-pressure or low-pressure mercury lamp or the like is preferably used, and as the irradiated ultraviolet light, ultraviolet light having a wavelength of about 254 nm and / or about 182 nm irradiated from the lamp preferably has a sterilizing effect. Can be achieved. The amount of UV irradiation that can suitably achieve sterilization is a force that is greatly influenced by the distance between the light source and the water to be irradiated and the irradiation time. Generally, it is 0. OlW's / cm 2 or more, preferably 025—0.05 W 's / cm 2 is desirable.
[0059] 電解殺菌とは、少なくとも陽極、陰極一対の電極に直流電圧を印加するものであり 、貯留室 32Eに浸漬するか、又は水の循環経路の何れかに設置し、該電解殺菌部 に水を流通させる流通式によって行われる。電解による殺菌は、水に塩化物イオンが 含まれる場合は、陽極で生成される有効塩素が主たる殺菌有効成分である。水の塩 化物イオン濃度が低い場合は、水に食塩、塩酸、塩化カルシウムなどの塩化物ィォ ンを含有する薬品、または海水、にがりなどの塩化物イオンを含有する天然物などを 添加しても良い。殺菌効果を好適に達成する有効塩素濃度は、水の pHの影響を受 け、一般に酸性において殺菌効果は高い。し力もながら、 pH酸性で高濃度の有効 塩素を含有する水は、臭気、並びに特に金属材料に対する腐食などを引き起こすた め、この空気浄化装置 1Eにおいては、有効塩素濃度 0. ;!〜 lOOmg Cl/1好ましく は 0. 2~10mg Cl/1であり、力、つ pH2〜; 12、より好ましくは、 pH3〜; 10とすることカ 望ましい。水に塩化物イオンが含まれないか、又は、塩化物イオン濃度が lmg/1以 下などの低濃度の場合には、電解殺菌は、陽極において水分解によって生成するォ ゾン、過酸化水素、 OHラジカルなどの活性酸素による殺菌、または陽極への菌体の 接触による陽極酸化による殺菌によって達成される。この場合、少なくとも陽極の一 部を多孔質体として表面積を大きくし、該多孔質体部に水を流通させることによって、 水と陽極の接触効率を高めると、より好適に殺菌を達成することができる。電解殺菌 で用いられる陰極としては、導電性炭素材料、鉄、ステンレス、その他金属類が好適 に用いられる。陽極としては、白金、金などの貴金属類、チタン基板に白金、イリジゥ ム、ルテニウム、ロジウム、タンタルなどを単独または複数成分混合して、メツキまたは これらの焼結体酸化物被膜を形成させたものが好適である。水に硬度成分が多く存 在し、かつ流通式の電解殺菌を行う場合などでは、定期的に陽極と陰極の極性を反 転させることにより、陰極への硬度スケールの付着を防止することが出来る。この場合 、電極材料としては、上記陽極材料が好ましい。また、陽極における有効塩素生成を 効率よく行うには、陽極材料成分として、イリジウム、ルテニウムが含まれることが望ま しぐオゾン生成を促進するには、陽極に二酸化鉛が含まれることが望ましい。電極 の形状は、板、多孔質体、パンチングメタル、エキスパンドメタルなどより、通水型、浸 漬型などの接液方式を勘案して適宜選択される。電極間に流される電解電流密度は 、上記の殺菌機構の違いから、 目的とする電極反応に応じて選択される力 0. ;!〜 2 OA/dm2が好適である。 [0059] The electrolytic sterilization is to apply a DC voltage to at least the pair of electrodes of the anode and the cathode, and is immersed in the storage chamber 32E or installed in one of the water circulation paths, It is carried out by a distribution formula that distributes water. In the case of sterilization by electrolysis, when chlorine ions are contained in water, effective chlorine produced at the anode is the main sterilizing active ingredient. If the chloride ion concentration in water is low, add chemicals containing chloride ions such as salt, hydrochloric acid, and calcium chloride to water, or natural products containing chloride ions such as seawater and bittern. Also good. The effective chlorine concentration that suitably achieves the bactericidal effect is affected by the pH of water, and in general, the bactericidal effect is high in acidity. However, since water containing acidic chlorine with a high concentration of acidic pH causes odors and corrosion on metal materials in particular, the effective chlorine concentration of this air purifier 1E is 0.;! ~ LOOmg Cl / 1, preferably 0.2 to 10 mg Cl / 1, force, pH 2 to; 12, more preferably pH 3 to 10 desirable. If the water does not contain chloride ions, or if the chloride ion concentration is low, such as lmg / 1 or less, the electrolytic sterilization is performed by ozone, hydrogen peroxide, This can be achieved by sterilization by active oxygen such as OH radicals, or by anodic oxidation by contacting cells with the anode. In this case, sterilization can be more suitably achieved by increasing the contact efficiency between water and the anode by increasing the surface area of at least a portion of the anode as a porous body and flowing water through the porous body. it can. As the cathode used for electrolytic sterilization, a conductive carbon material, iron, stainless steel, and other metals are preferably used. As anode, noble metals such as platinum and gold, platinum substrate, platinum, iridium, ruthenium, rhodium, tantalum, etc. alone or mixed with multiple components to form a plating or a sintered oxide film of these. Is preferred. When there are many hardness components in water and flow-type electrolytic sterilization is performed, it is possible to prevent the hardness scale from adhering to the cathode by periodically reversing the polarity of the anode and the cathode. . In this case, the electrode material is preferably the above anode material. In order to efficiently produce effective chlorine at the anode, it is desirable that iridium and ruthenium are included as anode material components. To promote the ozone generation that is desirable, it is desirable that the anode contains lead dioxide. The shape of the electrode is appropriately selected from a plate, a porous body, a punching metal, an expanded metal, and the like in consideration of a liquid contact method such as a water flow type and an immersion type. The electrolysis current density passed between the electrodes is preferably a force of 0.;! To 2 OA / dm 2 selected in accordance with the target electrode reaction due to the difference in the sterilization mechanism.
[0060] 高温殺菌とは、 60°C以上、好ましくは 80°C以上の高温に水又は空気を昇温するか 、または同温度以上に昇温された金属メッシュなどの昇温体に該流体を接触せしめ ることにより該流体中の菌を死滅させる手段である。この空気浄化装置 1Eにおいて は、循環水流路の一部を昇温するか、または空気流通経路に昇温体を設置して殺 菌を行う。後述のエリミネータ 11Eを電気ヒータなどで昇温し、殺菌用昇温体として兼 用しても良い。 [0060] The high temperature sterilization means that the temperature of water or air is raised to a high temperature of 60 ° C or higher, preferably 80 ° C or higher, or the fluid is applied to a temperature rising body such as a metal mesh heated to the same temperature or higher. This is a means for killing bacteria in the fluid by bringing them into contact with each other. In this air purification device 1E, the temperature of a part of the circulating water flow path is raised, or a temperature raising body is installed in the air circulation path to perform sterilization. An eliminator 11E described later may be heated with an electric heater or the like, and may also be used as a sterilization heating element.
[0061] 殺菌剤充填層への通水、又は空気浄化装置 1Eの構造体の少なくとも一部の表面 への殺菌効果を付与する表面処理による殺菌で用いられる殺菌剤とは、例えば、銀 や銅などの殺菌効果を有する金属を活性炭ゃゼオライトなどの吸着剤に物理吸着さ せたもの、あるいは該金属を吸着させた活性炭ゃゼオライトなどの粉末を更にナイ口 ンなどに練り込んで繊維状に加工したもの、沃素を陰イオン交換基を有する固体表 面にイオン結合によって固定化したもの、第 4級アンモニゥム基を有する陰イオン交 換体、ポリミキシンをァガロースに結合させたもの、アルコキシシリル基を導入した殺 菌剤 ·抗菌剤と担体表面の水酸基などとを脱アルコール反応で結合させて共有結合 によって殺菌剤 ·抗菌剤を固定化したもの、ベンジル基、メチレン基、エステルなどを 介してポリマー鎖に殺菌剤 ·抗菌剤を共有結合によって固定化したもの、更にこれら を対象物表面に塗布又はコーティングして対象物表面を固定化殺菌 ·抗菌剤化した ものなどを挙げることができる(高麗寛紀、化学と生物、 26 (12)、 834— 841 (1988) )。これらの殺菌剤を単独、又は複数組み合わせて、水循環経路に設置して殺菌剤 充填部を形成し、該殺菌剤部に水又は空気を流通させる力、、又はこの空気浄化装置 1Eの構造体の少なくとも一部の表面を上記殺菌剤で表面処理し、該表面に水また は空気を接触させて殺菌を行うことができる。 [0061] The bactericidal agent used in the sterilization by the surface treatment that imparts the bactericidal effect to the surface of at least a part of the structure of the air purification device 1E through water through the bactericide packed layer is, for example, silver or copper Metals having sterilizing effect such as activated carbon are adsorbed on adsorbents such as zeolite Or activated carbon adsorbed with the metal or zeolite powder and kneaded into a fiber and processed into a fibrous form. Iodine is fixed to a solid surface having an anion exchange group by ionic bonds. , Quaternary ammonium group-containing anion exchanger, polymyxin bonded to agarose, alkoxysilyl group-introduced antibacterial agent ・ antibacterial agent and hydroxyl group on the carrier surface are bound by dealcoholization reaction Antibacterial agent immobilized by covalent bond, antibacterial agent immobilized on polymer chain via benzyl group, methylene group, ester, etc. The surface of the object is fixed or sterilized and antibacterial agent is applied or coated on the surface (Kano Hiroki, Chemistry and Biology, 26 (1 2), 834—841 (1988)). These disinfectants are used alone or in combination, and are installed in the water circulation path to form a disinfectant filling part, and the force of circulating water or air through the disinfectant part, or the structure of this air purification device 1E At least a part of the surface can be surface-treated with the above-mentioned disinfectant, and the surface can be sterilized by bringing water or air into contact therewith.
[0062] なお、貯留室 32Eに貯留された水を残留塩素で殺菌してもよい。また、貯留室 32E に貯留された水の有効塩素を 0. lmg/L以上 10mg/L以下、好ましくは lmg/L 以上 3mg/L以下とすることで、その水を殺菌してもよ!/、。  [0062] The water stored in the storage chamber 32E may be sterilized with residual chlorine. In addition, the effective chlorine of water stored in the storage chamber 32E can be sterilized by setting it to 0.1 mg / L or more and 10 mg / L or less, preferably 1 mg / L or more and 3 mg / L or less! / ,.
[0063] 洗浄塔 30Eの内側であって貯留室 32Eの上方には、複数のノズル 10Eが設けられ ている。これらノズル 10Eは下に向けて水を散布するものである。ノズル 10Eは水を 霧状に散布するものとしてもよい。この場合、ノズル 10Eが粒子径 10 m以上 1000 m以下の水を噴霧することがより好まし!/、。  [0063] A plurality of nozzles 10E are provided inside the cleaning tower 30E and above the storage chamber 32E. These nozzles 10E spray water downward. The nozzle 10E may spray water in the form of a mist. In this case, it is more preferable that the nozzle 10E sprays water having a particle size of 10 m or more and 1000 m or less!
また、ノズル 10Eは、水滴を連続的に滴下することで水を散布するものとしてもよい Further, the nozzle 10E may spray water by continuously dropping water droplets.
Yes
なお、ノズル 10Eの数は複数でなぐ 1個であっても良い。  Note that the number of nozzles 10E may be one.
[0064] 洗浄塔 30Eの内側であってノズル 10Eの上方には、エリミネータ 11Eが設けられ、 洗浄塔 30E内の空間がエリミネータ 11Eによって上下に仕切られている。エリミネ一 タ 11Eを空気が通過すると、通過する空気中の水分がエリミネータ 11Eに付着して捕 捉され、エリミネータ 11Eに付着した水が水滴として下方に滴下する。  [0064] An eliminator 11E is provided inside the cleaning tower 30E and above the nozzle 10E, and the space in the cleaning tower 30E is partitioned vertically by the eliminator 11E. When air passes through the eliminator 11E, moisture in the passing air adheres to and is captured by the eliminator 11E, and water attached to the eliminator 11E drops downward as water droplets.
[0065] ノズノレ 10Eの散布先には、つまりノズノレ 10Eの下方であって吸気口 31Eの上方に は、気液接触構造 20Eが設けられている。気液接触構造 20Eは、ノズル 10Eから散 布された水を捕捉するとともに、上方に向かって当該気液接触構造 20Eを通過する 空気とその捕捉した水を接触させ、空気中の水溶性ガス(例えば、 NOxガス、 SOxガ ス、 NH4ガス)を水に吸収させるものである。気液接触構造 20Eは、複数の充填物 21 Eを充填した層を有する。なお、充填物 21Eとしては、ラシヒリング、レッシングリング、 ボールリング、ぺドルサドル、インタロックサドル、テラレット等がある。 [0065] At the spray destination of Nozunore 10E, that is, below Nozunore 10E and above intake port 31E. The gas-liquid contact structure 20E is provided. The gas-liquid contact structure 20E captures the water dispersed from the nozzle 10E and brings the air passing through the gas-liquid contact structure 20E upward into contact with the captured water so that the water-soluble gas ( For example, NOx gas, SOx gas, NH4 gas) are absorbed by water. The gas-liquid contact structure 20E has a layer filled with a plurality of fillers 21E. Examples of the filling material 21E include Raschig rings, Lessing rings, ball rings, peddle saddles, interlock saddles, terralet, and the like.
[0066] 具体的には、気液接触構造 20Eは図 6に示すように構成されている。図 2に示すよ うな籠 22Eがノズル 10Eの下方であって吸気口 31Eの上方に配設され、この籠 22E の中に充填物 21Eが充填されている。籠 22Eは金網を箱状に設けたものである。  [0066] Specifically, the gas-liquid contact structure 20E is configured as shown in FIG. A soot 22E as shown in FIG. 2 is disposed below the nozzle 10E and above the intake port 31E, and the soot 22E is filled with a filling material 21E.籠 22E has a wire mesh in a box shape.
[0067] 貯留室 32Eにはポンプ 12Eが連結されている。ポンプ 12Eは配管 13Eによってノズ ノレ 10Eに接続している。ポンプ 12Eは貯留室 32Eに貯留された水 99Eを吸い上げ、 ノズル 10Eへと送液するものである。ポンプ 12Eによってノズル 10Eへ送られた水が ポンプ 12Eによる圧力によってノズル 10E力も散布される。  [0067] A pump 12E is connected to the storage chamber 32E. Pump 12E is connected to Nozure 10E by pipe 13E. The pump 12E sucks up the water 99E stored in the storage chamber 32E and sends it to the nozzle 10E. The water sent to the nozzle 10E by the pump 12E is also sprayed by the pressure of the pump 12E.
[0068] 洗浄塔 30Eには供給管 16Eが接続されており、供給源 17Eの水が供給管 16Eを 通って洗浄塔 30E内に供給される。供給管 16Eにはバルブ 18Eが設けられ、バルブ 18Eが開弁することによって供給源の水が洗浄塔 30E内に供給される。供給源 17E 力、ら供給される水は、水道水、純水、酸性水若しくはアルカリ水又はこれらのうち二種 以上を混合させたものである。そのため、ノズル 10Eから散布される水も、水道水、純 水、酸性水若しくはアルカリ水又はこれらのうち二種以上を混合させたものである。  [0068] A supply pipe 16E is connected to the cleaning tower 30E, and water from the supply source 17E is supplied into the cleaning tower 30E through the supply pipe 16E. The supply pipe 16E is provided with a valve 18E. When the valve 18E is opened, water as a supply source is supplied into the cleaning tower 30E. The water supplied from the source 17E is tap water, pure water, acidic water or alkaline water, or a mixture of two or more of these. Therefore, the water sprayed from the nozzle 10E is also tap water, pure water, acidic water, alkaline water, or a mixture of two or more of these.
[0069] 供給源 17Eから供給される水が純水である場合、その水は逆浸透装置又はイオン 交換装置によって精製された純水である。供給源 17Eから供給される水が酸性水で ある場合、その水は、逆浸透装置によって精製された濃縮水若しくは巿水を電解装 置に供することで得られる当該電解装置の陽極水であるか、又は、電気軟化装置若 しくは電気再生式脱イオン装置の陽極水である。空気中の NH4ガスなどのアルカリ性 ガスの溶解効率は、接触する水の pHに依存する。接触する水の pHが低いほうが、 空気中の NH4ガスなどのアルカリ性ガス溶解効率が高くなる。そのため、空気中にァ ルカリ性ガスが含まれる場合、供給源 17Eから供給される水を pH2〜9とし、より好ま しくは pH3〜6とする。 供給源 17Eから供給される水がアルカリ水である場合、その水は、逆浸透装置によ つて精製された濃縮水若しくは巿水を電解装置に供することで得られる当該電解装 置の陰極水であるか、電気軟化装置の陰極水(軟水)であるか、電気再生式脱イオン 装置の陰極水であるか、又は、軟水を電解装置に供することで得られる当該電解装 置の陰極水である。空気中の NOxガス、 SOxガスなどの酸性ガスの溶解効率は、接 触する水の pHに依存する。接触する水の pHが高いほう力 S、空気中の NOxガス、 SOx ガスなどの酸性ガスの溶解効率が高くなる。そのため、空気中に酸性ガスが含まれる 場合、供給源 17Eから供給される水は pH5〜; 12とし、より好ましくは pH8〜; 10とする 。特に、水道水を電解装置、電気軟化装置又は電気再生式脱イオン装置に供して 得られた陰極水の場合には、 pHIOを越えると、水酸化マグネシウムなどの塩が生じ やすいので、 pHIO以下であることが好ましい。 [0069] When the water supplied from the supply source 17E is pure water, the water is pure water purified by a reverse osmosis device or an ion exchange device. If the water supplied from the supply source 17E is acidic water, is the water anodic water of the electrolyzer obtained by supplying concentrated water or brine purified by a reverse osmosis device to the electrolyzer? Or, it is an anodic water of an electrosoftening device or an electric regenerative deionization device. The dissolution efficiency of alkaline gases such as NH4 gas in the air depends on the pH of the water in contact. The lower the pH of the water in contact, the higher the efficiency of dissolving alkaline gases such as NH4 gas in the air. Therefore, when alkaline gas is contained in the air, the water supplied from the supply source 17E is set to pH 2 to 9, more preferably pH 3 to 6. When the water supplied from the supply source 17E is alkaline water, the water is the cathodic water of the electrolysis device obtained by supplying concentrated water or brine purified by a reverse osmosis device to the electrolysis device. It is the cathode water (soft water) of the electrosoftening device, the cathode water of the electric regenerative deionization device, or the cathode water of the electrolysis device obtained by supplying soft water to the electrolysis device . The dissolution efficiency of acidic gases such as NOx gas and SOx gas in the air depends on the pH of the water in contact. The higher the pH of the water in contact with S, the higher the efficiency of dissolving acidic gases such as NOx gas and SOx gas in the air. Therefore, when acidic gas is contained in the air, the water supplied from the supply source 17E is pH 5 to 12; more preferably pH 8 to 10; In particular, in the case of cathodic water obtained by subjecting tap water to an electrolyzer, an electrosoftening device, or an electric regenerative deionization device, salts such as magnesium hydroxide are liable to be formed when pHIO is exceeded. Preferably there is.
[0070] 貯留室 32Eの底よりも上の部分には、排水管 14Eが接続されている。貯留室 32E に貯留された水 99Eの水位が排水管 14Eの接続箇所になると、貯留室 32E内の水 9 9Eが排水管 14Eを通って排出される。  [0070] A drain pipe 14E is connected to a portion above the bottom of the storage chamber 32E. When the level of the water 99E stored in the storage chamber 32E becomes the connection point of the drain pipe 14E, the water 99E in the storage chamber 32E is discharged through the drain pipe 14E.
[0071] 次に、この空気浄化装置 1Eの動作について説明する。  Next, the operation of this air purification device 1E will be described.
まず、供給源 17Eの水が供給管 16Eを通って貯留室 32Eに貯留される。そして、ポ ンプ 12Eが作動し、貯留室 32Eの水 99Eがノズノレ 10Eへ送液され、ノズノレ 10Eから 水が散布される。ノズル 10Eから散布された水は気液接触構造 20Eに捕捉されて吸 収され、具体的には、水が充填物 21Eの隙間に吸収される。ポンプ 12Eの作動して いる間、水が循環する。水の循環中では殺菌装置が作動し、循環水が殺菌装置によ つて殺菌される。なお、水の循環中でも供給源 17Eの水が断続的に、連続的に又は 所定サイクルで貯留室 32Eに供給される。  First, water from the supply source 17E is stored in the storage chamber 32E through the supply pipe 16E. Then, the pump 12E is activated, the water 99E in the storage chamber 32E is sent to the Noznore 10E, and water is sprayed from the Noznole 10E. The water sprayed from the nozzle 10E is captured and absorbed by the gas-liquid contact structure 20E. Specifically, the water is absorbed into the gap of the filling 21E. Water circulates while pump 12E is operating. The sterilizer operates during the water circulation, and the circulating water is sterilized by the sterilizer. Note that the water from the supply source 17E is supplied to the storage chamber 32E intermittently, continuously or in a predetermined cycle even during the circulation of water.
[0072] 水の循環中、送風機 8Eが作動し、住宅の外の空気が吸気口 31Eに吸い込まれ、 吸い込まれた空気が洗浄塔 30E中を上昇して、排気口 37E力 排出される。排気口 37Eから排出された空気は住宅の中に送られる。  [0072] During the circulation of water, the blower 8E operates, the air outside the house is sucked into the intake port 31E, and the sucked air rises through the cleaning tower 30E and is discharged through the exhaust port 37E. The air discharged from the exhaust port 37E is sent into the house.
[0073] 洗浄塔 30Eに取り込まれた空気が上昇している時に、空気が気液接触構造 20Eを 通過する。空気が気液接触構造 20Eを通過している時に、気液接触構造 20Eに吸 収された水と空気が接触する。また、気流中の塵埃が水に接触する。そのため、気液 接触構造 20Eを通過する空気から塵埃等が除去される。更に、気液接触構造 20Eを 通過する空気中の水溶性ガスが水に溶けて除去される。そして、気液接触構造 20E を通過した空気が排気口 37E力 排出されて住宅の中に送られる。 [0073] When the air taken into the cleaning tower 30E is rising, the air passes through the gas-liquid contact structure 20E. When air passes through the gas-liquid contact structure 20E, the water and air absorbed by the gas-liquid contact structure 20E come into contact with each other. Also, dust in the airflow comes into contact with water. Therefore, gas-liquid Dust etc. are removed from the air passing through the contact structure 20E. Further, the water-soluble gas in the air passing through the gas-liquid contact structure 20E is dissolved in water and removed. Then, the air passing through the gas-liquid contact structure 20E is exhausted by the exhaust port 37E and sent into the house.
[0074] 以上のように本実施形態によれば、吸気口 31Eに吸い込まれた空気が気液接触構 造 20Eを通過している時に、空気中の塵埃や水溶性ガスが水に吸収される。そのた め、住宅の中に送り込む空気の浄化'脱臭をすることができ、住宅内への給気もより 衛生的にすること力 Sできる。特に、エリミネータ 11Eによって水が捕捉されることによつ て、住宅内に送り込まれる空気中に水が残留せず、より浄化された空気が住宅内に 送り込まれる。 [0074] As described above, according to the present embodiment, when the air sucked into the intake port 31E passes through the gas-liquid contact structure 20E, dust and water-soluble gas in the air are absorbed by the water. . For this reason, the air sent into the house can be purified and deodorized, and the air supply to the house can be made more hygienic. In particular, when water is captured by the eliminator 11E, water does not remain in the air sent into the house, and more purified air is sent into the house.
[0075] その上、貯留室 32Eの底に貯留された水が殺菌装置によって殺菌されるので、循 環している水の汚染を抑えることができる。そのため、空気浄化装置 1Eが長期に動 作していても、住宅内に送り込まれる空気が浄化された状態を保つことができる。  [0075] In addition, since the water stored at the bottom of the storage chamber 32E is sterilized by the sterilizer, contamination of the circulating water can be suppressed. Therefore, even if the air purification device 1E has been operating for a long period of time, the air sent into the house can be kept in a purified state.
[0076] 更に、気液接触構造 20E中の水によって取り除かれた塵埃等の一部は、貯留室 3 2Eに貯留した水の水面に浮上し、浮上した塵埃等は水とともに排水管 14Eを通じて 排出される。そのため、循環している水に塵埃等が貯まっていくことを抑えることがで きる。  [0076] Furthermore, part of the dust and the like removed by the water in the gas-liquid contact structure 20E floats on the surface of the water stored in the storage chamber 32E, and the floating dust and the like are discharged through the drain pipe 14E together with the water. Is done. Therefore, it is possible to suppress the accumulation of dust and the like in the circulating water.
[0077] なお、上記実施形態では、吸気口 31Eが住宅の外に露出している力、、又はダクトを 通じて住宅の外に通じていた力 吸気口 31Eが住宅の中に露出している力、、又は、 ダクトを通じて住宅の中に通じていても良い。このようにすれば、住宅の中の空気が 吸気口 31Eに吸い込まれ、塵埃 ·水溶性ガス等を除去した空気が排気口 37Eから住 宅の中に供給される。これにより、住宅の中の空気を浄化することができる。  [0077] In the above embodiment, the force that the air inlet 31E is exposed to the outside of the house, or the force that has passed the outside of the house through the duct. The air inlet 31E is exposed to the inside of the house. It may lead into the house through force or ducts. In this way, the air in the house is sucked into the air inlet 31E, and the air from which dust, water-soluble gas, etc. are removed is supplied into the house through the air outlet 37E. Thereby, the air in a house can be purified.
[0078] また、吸気口 31Eとは別に吸気口を洗浄塔 30Eに設け、その別の吸気口を住宅の 中に露出させるか又はダクトを通じて住宅の中に通じさせても良い。このようにするこ とで、吸気口 31Eから外気が取り込まれ、別の吸気口からは住宅内の空気が取り込 まれ、取り込まれた空気が洗浄塔 30E内において浄化し、その浄化した空気が排気 口 37Eから住宅に送り込まれる。  [0078] In addition to the air intake port 31E, an air intake port may be provided in the cleaning tower 30E, and the other air intake port may be exposed in the house or connected to the house through a duct. In this way, outside air is taken in from the air inlet 31E, air in the house is taken in from another air inlet, and the taken-in air is purified in the cleaning tower 30E, and the purified air is It is sent to the house through the exhaust 37E.
[0079] また、上記実施形態では取り込まれた空気が洗浄塔 30Eで上昇するよう流れてい る力 逆に下降するように流れても良い。上記実施形態では、ノズル 10Eから散布さ れる水の向きが、洗浄塔 30E内での空気の流れの向きの逆になつていたが、それら 向きの関係は特に限定するものではなぐ例えば、ノズル 10Eから散布される水の向 きが洗浄塔 30E内での空気の流れの向きと同じであっても良いし、ノズル 10Eから散 布される水の向きが洗浄塔 30内での空気の流れの向きに対して垂直であっても良い [0079] Further, in the above embodiment, the force of the air taken in so as to rise in the cleaning tower 30E may flow so as to descend. In the above embodiment, sprayed from the nozzle 10E. The direction of the generated water is the opposite of the direction of the air flow in the washing tower 30E, but the relationship between the directions is not particularly limited.For example, the direction of the water sprayed from the nozzle 10E The direction of the air flow in the tower 30E may be the same, or the direction of the water dispersed from the nozzle 10E may be perpendicular to the direction of the air flow in the washing tower 30.
[0080] また、上記実施形態ではポンプ 12Eによって水をノズル 10Eに送液していた力 水 に加えて圧縮空気をコンプレッサーによってノズル 10Eに送っても良い。 [0080] Further, in the above embodiment, compressed air may be sent to the nozzle 10E by a compressor in addition to the force water that has sent water to the nozzle 10E by the pump 12E.
[0081] また、気液接触構造 20E内に仕切板を配置し、気液接触構造 20E内において空 気が酸性水、アルカリ水、純水の順で接触しても良い。また、気液接触構造 20E内に おいて空気がアルカリ水、酸性水、純水の順に接触しても良いし、アルカリ水、純水 の順に接触しても良い。  [0081] Further, a partition plate may be disposed in the gas-liquid contact structure 20E, and the air may contact the acid water, alkaline water, and pure water in this order in the gas-liquid contact structure 20E. Further, in the gas-liquid contact structure 20E, air may contact in the order of alkaline water, acidic water, and pure water, or may contact in the order of alkaline water and pure water.
[0082] また、第 1実施形態のように、吸気口 31Eと洗浄塔 30Eの内部空間との間にプレフ ィルタを設け、排気口 37Eと送風機 8との間にフィルタを設けてもよい。  [0082] In addition, as in the first embodiment, a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
[0083] <第 5の実施の形態〉  [0083] <Fifth embodiment>
第 4実施形態の空気浄化装置 1Eにおいては、気液接触構造 20E力 つの籠 22E を有し、籠 22Eに複数の充填物 21Eが充填されている。それに対して図 7に示された 第 5実施形態の空気浄化装置 1Fにおいては、気液接触構造 20Fが図 8に示された 籠 22Fを複数個備え、これら籠 22Fに充填物 21Fが充填されている。ここで、これら 籠 22Fは板状且つ箱状に設けられている。籠 22Fの厚み方向が洗浄塔 30E内の気 流の向きに対して垂直となった状態で、これら籠 22Fがノズル 10Eの下方において 間隔をおレ、て配列されて!/、る。  The air purifying device 1E of the fourth embodiment has a gas-liquid contact structure 20E with two rods 22E, and the rod 22E is filled with a plurality of fillers 21E. On the other hand, in the air purifying apparatus 1F of the fifth embodiment shown in FIG. 7, the gas-liquid contact structure 20F includes a plurality of ridges 22F shown in FIG. 8, and these ridges 22F are filled with the filling 21F. ing. Here, these flanges 22F are provided in a plate shape and a box shape. With the thickness direction of 22F perpendicular to the direction of the air flow in the cleaning tower 30E, these 22F are arranged at intervals below the nozzle 10E!
なお、第 1実施形態のように、吸気口 31Eと洗浄塔 30Eの内部空間との間にプレフ ィルタを設け、排気口 37Eと送風機 8との間にフィルタを設けてもよい。  Note that, as in the first embodiment, a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
[0084] 以上のことを除いて、この空気浄化装置 1Fは第 4実施形態の空気浄化装置 1Eと 同様に設けられており、空気浄化装置 1Fと空気浄化装置 1Eの間で互いに対応する 部分が同様に設けられている場合には同一の符号を付す。この空気浄化装置 1Fに お!/、ても、住宅の中に送り込む空気の浄化 ·脱臭をすること力 Sできる。  [0084] Except for the above, this air purification device 1F is provided in the same manner as the air purification device 1E of the fourth embodiment, and there are portions corresponding to each other between the air purification device 1F and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1F !, it is possible to purify and deodorize the air sent into the house.
[0085] <第 6の実施の形態〉 図 9に示すように、第 6実施形態の空気浄化装置 1Gにおいては、気液接触構造 20 Gが複数の多孔板 24Gを有する。具体的には、ノズル 10Eの下方においてこれら多 孔板 24Gは間隔を空けて重ねられており、多孔板 24Gの厚みが洗浄塔 30E内の気 流の向きに対して平行となっている。多孔板 24Gには、一方の面から他方の面に貫 通した複数の貫通孔が形成されている。この気液接触構造 20Gにおいては、ノズノレ 10Eから散布された水はこれら多孔板 24Gの貫通孔に捕捉され、空気が上方に向 かって各貫通孔を通過する時に空気と水が接触し、空気中の水溶性ガス(例えば、 N Oxガス、 SOxガス、 NH4ガス)が水に吸収される。 [0085] <Sixth Embodiment> As shown in FIG. 9, in the air purification device 1G of the sixth embodiment, the gas-liquid contact structure 20G has a plurality of perforated plates 24G. Specifically, these multi-hole plates 24G are stacked at a distance below the nozzle 10E, and the thickness of the multi-hole plate 24G is parallel to the direction of the air flow in the cleaning tower 30E. The perforated plate 24G is formed with a plurality of through holes penetrating from one surface to the other surface. In this gas-liquid contact structure 20G, the water sprayed from Nozure 10E is trapped in the through holes of these porous plates 24G, and when the air passes upward through the through holes, the air and water come into contact with each other. Water-soluble gas (for example, NOx gas, SOx gas, NH4 gas) is absorbed by water.
なお、第 1実施形態のように、吸気口 31Eと洗浄塔 30Eの内部空間との間にプレフ ィルタを設け、排気口 37Eと送風機 8との間にフィルタを設けてもよい。  Note that, as in the first embodiment, a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
[0086] 以上のことを除いて、この空気浄化装置 1Gは第 4実施形態の空気浄化装置 1Eと 同様に設けられており、空気浄化装置 1Gと空気浄化装置 1Eの間で互いに対応する 部分が同様に設けられている場合には同一の符号を付す。この空気浄化装置 1Gに お!/、ても、住宅の中に送り込む空気の浄化 ·脱臭をすること力 Sできる。 [0086] Except for the above, this air purification device 1G is provided in the same manner as the air purification device 1E of the fourth embodiment, and there are portions corresponding to each other between the air purification device 1G and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1G! /, You can clean and deodorize the air sent into the house.
[0087] <第 7の実施の形態〉 <Seventh Embodiment>
図 10に示すように、第 7実施形態の空気浄化装置 1Hにおいては、気液接触構造 20Hが複数の板 25Hを有する。これら板 25Hが棚段状に配列され、更にこれら板 2 5Hが左右力、ら入れ違いに設けられている。これら板 25Hは傾斜して設けられ、これ ら板 25Hの先が斜め下に指向している。なお、これら板 25Hが互いに平行とされて いても良い。  As shown in FIG. 10, in the air purification device 1H of the seventh embodiment, the gas-liquid contact structure 20H has a plurality of plates 25H. These plates 25H are arranged in a shelf shape, and further, these plates 25H are provided in the left-right force and the wrong positions. These plates 25H are provided with an inclination, and the ends of these plates 25H are directed obliquely downward. These plates 25H may be parallel to each other.
[0088] この気液接触構造 20Hにおいては、ノズル 10E力も散布された水はこれら板 25H の上に載ることで捕捉され、空気が板 25Hの間を通過する時に空気と水が接触し、 空気中の水溶性ガス(例えば、 NOxガス、 SOxガス、 NH4ガス)が水に吸収される。  [0088] In this gas-liquid contact structure 20H, the water sprayed with the nozzle 10E force is captured by being placed on these plates 25H, and when the air passes between the plates 25H, the air and water come into contact with each other. Water-soluble gas (for example, NOx gas, SOx gas, NH4 gas) is absorbed into water.
[0089] 図 11に示すように、板 25Hが波形板であっても良いし、図 12に示すように、板 25H の表面に溝 26Hが形成されていても良い。板 25Hが波形板であると、ノズノレ 10E力、 ら散布された水が板 25Hの上に捕捉されやす!/、。板 25Hに溝 26Hが形成されて!/、 ると、水が流動しやすい。  As shown in FIG. 11, the plate 25H may be a corrugated plate, and as shown in FIG. 12, a groove 26H may be formed on the surface of the plate 25H. If the plate 25H is a corrugated plate, it will be easy to trap the water sprayed on the plate 25H! If the groove 26H is formed in the plate 25H! /, Water will flow easily.
なお、第 1実施形態のように、吸気口 31Eと洗浄塔 30Eの内部空間との間にプレフ ィルタを設け、排気口 37Eと送風機 8との間にフィルタを設けてもよい。 Note that, as in the first embodiment, a pre-fre- quency is provided between the intake port 31E and the internal space of the cleaning tower 30E. A filter may be provided, and a filter may be provided between the exhaust port 37E and the blower 8.
[0090] 以上のことを除いて、この空気浄化装置 1Hは第 4実施形態の空気浄化装置 1Eと 同様に設けられており、空気浄化装置 1Hと空気浄化装置 1Eの間で互いに対応する 部分が同様に設けられている場合には同一の符号を付す。この空気浄化装置 1Hに お!/、ても、住宅の中に送り込む空気の浄化 ·脱臭をすること力 Sできる。  [0090] Except for the above, this air purification device 1H is provided in the same manner as the air purification device 1E of the fourth embodiment, and there is a portion corresponding to each other between the air purification device 1H and the air purification device 1E. In the case where they are similarly provided, the same reference numerals are given. Even with this air purifier 1H! /, It is possible to purify and deodorize the air sent into the house.
[0091] <第 8の実施の形態〉  [0091] <Eighth embodiment>
第 8実施形態においては、図 13に示された空気浄化装置 1Jのように、洗浄塔 30E の内側の空間が網 93M, 94Mによって三つの室に区画されており、それら三つの室 には気液接触構造 20J, 20K, 20Lが設けられている。気液接触構造 20J〜20Lは、 上記第 4から第 7の実施形態における気液接触構造 20E, 20F, 20G, 20Hの何れ 力、と同じように設けられたものである。  In the eighth embodiment, as in the air purification device 1J shown in FIG. 13, the space inside the cleaning tower 30E is divided into three chambers by the nets 93M and 94M, and these three chambers are air-conditioned. Liquid contact structures 20J, 20K, and 20L are provided. The gas-liquid contact structures 20J to 20L are provided in the same manner as any of the gas-liquid contact structures 20E, 20F, 20G, and 20H in the fourth to seventh embodiments.
[0092] 気液接触構造 20Jの上側にはノズル 10Jが設けられ、気液接触構造 20Kの上側に はノズル 10Kが設けられ、気液接触構造 20Lの上側にはノズル 10Lが設けられてい る。ノズル 10Jの上側及びノズル 10Kの上側は隔壁 98Mによって塞がれ、気液接触 構造 20J, 20Kが設けられた室が隔壁 98Mによってエリミネータ 11Eから仕切られて いる。一方、ノズル 10Lの上側は塞がれていないので、気液接触構造 20Lが設けら れた室がエリミネータ 11Eに通じる。  A nozzle 10J is provided above the gas-liquid contact structure 20J, a nozzle 10K is provided above the gas-liquid contact structure 20K, and a nozzle 10L is provided above the gas-liquid contact structure 20L. The upper side of the nozzle 10J and the upper side of the nozzle 10K are closed by a partition wall 98M, and the chamber provided with the gas-liquid contact structures 20J and 20K is partitioned from the eliminator 11E by the partition wall 98M. On the other hand, since the upper side of the nozzle 10L is not blocked, the chamber provided with the gas-liquid contact structure 20L leads to the eliminator 11E.
[0093] 吸気口 31Eよりも下側の領域が隔壁 95M, 96Mによって三つの貯留室 32J, 32K , 32Lに区画されている。ここで、網 93Mは隔壁 95Mの上に連なっており、網 94M は隔壁 96Mの上に連なって!/、る。  [0093] The region below the intake port 31E is partitioned into three storage chambers 32J, 32K, and 32L by partition walls 95M and 96M. Here, the net 93M continues on the partition wall 95M, and the net 94M continues on the partition wall 96M! /.
[0094] 貯留室 32Jには供給管 16Jが接続されており、供給源 17Jの水が供給管 16Jを通つ て貯留室 32Jに供給される。貯留室 32Kには供給管 16Kが接続されており、供給源 17Kの水が供給管 16Kを通って貯留室 32Kに供給される。貯留室 32Lには供給管 16Lが接続されており、供給源 17Lの水が供給管 16Lを通って貯留室 32Lに供給さ れる。供給源 17Jから供給される水は酸性水であり、供給源 17Kから供給される水は アルカリ水であり、供給源 17Lから供給される水は純水である。供給源 17J〜; 17Lと 水の種類の組み合わせは特に限定するものではなぐ例えば供給源 17Jの水がアル カリ水であり、供給源 17Kの水が酸性水であり、供給源 17Lの水が純水であっても良 い。 [0094] A supply pipe 16J is connected to the storage chamber 32J, and water from the supply source 17J is supplied to the storage chamber 32J through the supply pipe 16J. A supply pipe 16K is connected to the storage chamber 32K, and water from the supply source 17K is supplied to the storage chamber 32K through the supply pipe 16K. A supply pipe 16L is connected to the storage chamber 32L, and water from the supply source 17L is supplied to the storage chamber 32L through the supply pipe 16L. The water supplied from the supply source 17J is acidic water, the water supplied from the supply source 17K is alkaline water, and the water supplied from the supply source 17L is pure water. The combination of 17L and 17L and water types is not particularly limited. For example, the water at source 17J is alkaline water, the water at source 17K is acidic water, and the water at source 17L is pure. Even water Yes.
[0095] ポンプ 12Jは貯留室 32Jに貯留された水 99Jを吸!/、上げ、ノズル 10Jへ送液するもの である。ポンプ 12Kは貯留室 32Kに貯留された水 99Kを吸い上げ、ノズル 10Kへ送 液するものである。ポンプ 12Lは貯留室 32Lに貯留された水 99Lを吸い上げ、ノズノレ 10Lへ送液するものである。  [0095] The pump 12J sucks / raises water 99J stored in the storage chamber 32J, and feeds it to the nozzle 10J. The pump 12K sucks up 99K of water stored in the storage chamber 32K and sends it to the nozzle 10K. The pump 12L sucks up 99L of water stored in the storage chamber 32L and sends it to the 10L Nozure 10L.
なお、第 1実施形態のように、吸気口 31Eと洗浄塔 30Eの内部空間との間にプレフ ィルタを設け、排気口 37Eと送風機 8との間にフィルタを設けてもよい。  Note that, as in the first embodiment, a prefilter may be provided between the intake port 31E and the internal space of the cleaning tower 30E, and a filter may be provided between the exhaust port 37E and the blower 8.
[0096] 以上のことを除いて、この空気浄化装置 1Jは第 4実施形態の空気浄化装置 1Eと同 様に設けられており、空気浄化装置 1Jと空気浄化装置 1Eの間で互いに対応する部 分に同一の符号を付す。  [0096] Except for the above, this air purification device 1J is provided in the same manner as the air purification device 1E of the fourth embodiment, and the air purification device 1J and the air purification device 1E correspond to each other. The same sign is attached to the minutes.
[0097] この空気浄化装置 1Jの動作につ!/、て説明する。  [0097] The operation of this air purifying device 1J will be described.
まず、供給源 17Jの水が供給管 16Jを通って貯留室 32Jに貯留される。供給源 17K , 17Lの水も貯留室 32K, 32Lにそれぞれ貯留される。そして、ポンプ 12Jが作動し、 貯留室 32Jの水 99Jがノズル 10Jへ送液され、ノズル 10Jから下へ水が散布され、散布 された水 99Jが気液接触構造 20Jに捕捉される。同様に、貯留室 32K, 32Lの水 99 K, 99Lもノズル 10K, 10Lからそれぞれ下へ散布されて、気液接触構造 20K, 20L に捕捉される。ポンプ 12J, 12K, 12Lによる水の循環中、送風機 8Eが作動し、住宅 の外の空気が吸気口 31に吸い込まれ、気液接触構造 20J, 20K, 20L、エリミネータ 11E、送風機 8Eを順に通って排気口 37E力も排出される。排気口 37E力も排出され た空気は住宅の中に送られる。そのため、送風される空気は、ノズル 10J、 10K、 10 Lの順にそれらから散布される水に接触する。そのため、この空気浄化装置 1Jにおい ても、住宅の中に送り込む空気の浄化'脱臭をすることができる。  First, water from the supply source 17J is stored in the storage chamber 32J through the supply pipe 16J. Water from the supply sources 17K and 17L is also stored in the storage chambers 32K and 32L, respectively. Then, the pump 12J operates, the water 99J in the storage chamber 32J is fed to the nozzle 10J, the water is sprayed downward from the nozzle 10J, and the sprayed water 99J is captured by the gas-liquid contact structure 20J. Similarly, the water 99K and 99L in the storage chambers 32K and 32L are sprayed downward from the nozzles 10K and 10L, respectively, and are captured by the gas-liquid contact structures 20K and 20L. While the water is circulated by the pumps 12J, 12K, 12L, the blower 8E is activated and the air outside the house is sucked into the air intake 31. Exhaust port 37E force is also discharged. Exhaust port Air exhausted by 37E is sent into the house. Therefore, the blown air contacts the water sprayed from the nozzles 10J, 10K, and 10L in this order. Therefore, even with this air purification device 1J, it is possible to purify and deodorize the air sent into the house.
[0098] <実施例 2〉  <Example 2>
図 5に示された空気浄化装置 1Eを用いて NOxの確認試験を行った。  A NOx confirmation test was conducted using the air purifier 1E shown in FIG.
実験室内に空気浄化装置 1Eを設置し、吸気口 31Eから実験室室内空気を気液接 触構造 20Eに送風機 8Eにより導入した。気液接触構造 20Eの大きさは 200mm X 2 00mm X 200mmであり、その容量は 8Lである。充填物 21Eは内径 5mm X長さ 5m mのラシヒリングを用いた。室内空気導入の流量を約 150m3/hrとした。 [0099] 送風機 8を運転し、室内空気を導入した状態で、逆浸透装置によって生成された純 水をノズル 10Eから水量 1. 5L/分で散水した。そして、一定時間ごとに排気口 37E 力 排出される気体を純水の入ったガス捕集瓶に捕集し、その気体をガス捕集瓶内 の純水に溶解し、純水中の亜硝酸イオン (NO―)濃度をイオンクロマトグラフィー分析 装置で分析した。なお、ガス捕集瓶の容量は lOOmLであり、ガス捕集用純水量は 5 OmLであり、 5NL/分の流量の気体を 60分間捕集した。 The air purifier 1E was installed in the laboratory, and the air in the laboratory was introduced from the air inlet 31E into the gas-liquid contact structure 20E by the blower 8E. The size of the gas-liquid contact structure 20E is 200mm x 200mm x 200mm, and its capacity is 8L. As the filling material 21E, a Raschig ring having an inner diameter of 5 mm and a length of 5 mm was used. The flow rate of the indoor air introduced was about 150m 3 / hr. [0099] With the blower 8 operated and indoor air introduced, pure water generated by the reverse osmosis device was sprinkled from the nozzle 10E at a water volume of 1.5 L / min. Then, the gas discharged at the exhaust port 37E at regular intervals is collected in a gas collection bottle containing pure water, dissolved in pure water in the gas collection bottle, and nitrous acid in pure water. The ion (NO-) concentration was analyzed with an ion chromatography analyzer. The volume of the gas collection bottle was lOOmL, the amount of pure water for gas collection was 5 OmL, and a gas with a flow rate of 5 NL / min was collected for 60 minutes.
[0100] 比較例として、前記の確認試験において、一定時間ごとに吸気口 31Eに導入され る気体を純水の入ったガス捕集瓶に捕集し、その気体をガス捕集瓶内の純水に溶解 し、純水中の亜硝酸イオン (NO―)濃度を分析した。  [0100] As a comparative example, in the above-described confirmation test, the gas introduced into the air inlet 31E at regular intervals was collected in a gas collection bottle containing pure water, and the gas was purified in the gas collection bottle. It was dissolved in water and analyzed for nitrite ion (NO-) concentration in pure water.
[0101] その結果を表 2及び図 14に示す。  [0101] The results are shown in Table 2 and FIG.
[表 2]  [Table 2]
Figure imgf000026_0001
Figure imgf000026_0001
[0102] 表 2及び図 14から明らかなように、ノズル 10Eから純水を散水している気液接触構 造 20Eの前後である吸気口と排気口の亜硝酸イオン濃度を比較すると、ノズル 10E 力も純水を散水した後である排気口のほうが亜硝酸イオン濃度が低い。そのため、ノ ズル 10Eから純水を散水すると、吸気口から導入される室内空気中の亜硝酸イオン 濃度を低く抑えることができる。 [0102] As is clear from Table 2 and FIG. 14, the nitrite ion concentration at the inlet and outlet before and after the gas-liquid contact structure 20E sprinkling pure water from the nozzle 10E Nitrite ion concentration is lower in the exhaust port after sprinkling pure water. For this reason, when pure water is sprayed from nozzle 10E, the concentration of nitrite ions in the indoor air introduced from the intake port can be kept low.
[0103] 以上本発明の好ましい実施の形態を説明した力 本発明の好ましい実施の形態に よれば、吸気口(31又は 31E)に通じるとともに排気口(37又は 37E)に通じる内部空 間を有した洗浄塔(40又は 30E)と、空気を前記吸気口(31又は 31E)から前記洗浄 塔(40又は 30E)の内部空間に取り込んで前記排気口(37又は 37E)から前記洗浄 塔 (40又は 30E)の外に送り出すよう送風する送風機(8又は 8E)と、前記洗浄塔 (40 又は 30E)の内部空間に配置され、前記洗浄塔(40又は 30E)の内部空間内で水を 散布するノズル(10又は 10E)と、を備え、前記ノズル(10又は 10E)力、ら散布された 水が前記洗浄塔(40又は 30E)内で前記送風機(8又は 8E)により送風された空気と 接触する、空気浄化装置(1、 1A、 1B、 1E、 1F、 1H又は 1J)が提供される。 [0103] The power described above for the preferred embodiment of the present invention According to the preferred embodiment of the present invention, there is an internal space that leads to the intake port (31 or 31E) and to the exhaust port (37 or 37E). The cleaning tower (40 or 30E), and the air is taken into the internal space of the cleaning tower (40 or 30E) from the intake port (31 or 31E) and the cleaning tower (40 or 30E) is discharged from the exhaust port (37 or 37E). 30E) and a blower (8 or 8E) for sending air to the outside, and the washing tower (40 Or a nozzle (10 or 10E) that is disposed in the internal space of the washing tower (40 or 30E) and sprays water in the internal space of the washing tower (40 or 30E). Provided is an air purifier (1, 1A, 1B, 1E, 1F, 1H or 1J) in which the water contacts the air blown by the blower (8 or 8E) in the washing tower (40 or 30E). The
[0104] 従って、住宅内又はその屋外等の空気が送風機(8又は 8E)によって吸気口(31 又は 31E)力も洗浄塔(40又は 40E)の内部空間に取り込まれて、洗浄塔(40又は 4 0E)に取り込まれた空気が排気口(37又は 37E)力 住宅等内に送り出される。ノズ ノレ(10又は 10E)によって洗浄塔(40又は 30E)内に水が散布されると、送風されて いる空気中の塵埃等と水が接触し、空気から塵埃等が除去される。また、送風されて いる空気中の水溶性ガス例えば、 NOxガス、 SOxガス、 NH4ガス、悪臭の元となるガス 等が散布された水に溶け、空気から水溶性ガスが除去される。そのため、浄化された 空気が住宅等内に送り込まれる。また、フィルタではなぐ水との接触により空気を浄 化するので、フィルタの清掃 ·交換を必要としない。吸気口(31又は 31E)力も洗浄塔 (40又は 30E)に取り込まれた空気は、水中に吹き込まれるのではなぐ散布された 水が分散した雰囲気を通過するので、圧力損失が少ない。そのため、送風機(8又は 8E)の出力を高くせずとも済む。  [0104] Accordingly, air in the house or outside of the house is also taken into the internal space of the washing tower (40 or 40E) by the blower (8 or 8E), and the washing tower (40 or 4E). The air taken into 0E) is sent into the exhaust outlet (37 or 37E) force, etc. When water is sprayed into the washing tower (40 or 30E) by the nozzle (10 or 10E), the water comes into contact with the dust in the air being blown, and the dust is removed from the air. In addition, water-soluble gases in the air being blown, such as NOx gas, SOx gas, NH4 gas, and gases that cause malodors, are dissolved in the sprayed water, and the water-soluble gas is removed from the air. Therefore, the purified air is sent into the house. In addition, the filter cleans the air by contact with water, so there is no need to clean or replace the filter. The air taken into the intake tower (31 or 31E) and the washing tower (40 or 30E) passes through an atmosphere in which the dispersed water is dispersed rather than being blown into the water, so there is little pressure loss. Therefore, it is not necessary to increase the output of the blower (8 or 8E).
[0105] 好ましくは、前記ノズル(10)が水を霧状に散布する。  [0105] Preferably, the nozzle (10) sprays water in the form of a mist.
ノズルから噴霧された水が霧状であるから、送風される空気中の塵埃、水溶性ガス 等が水の粒子に接触しやすくなる。  Since the water sprayed from the nozzle is in the form of a mist, dust, water-soluble gas, etc. in the blown air easily come into contact with the water particles.
[0106] 好ましくは、前記ノズル(10)が粒子径 10 m以上 1000 m以下の水を噴霧する [0106] Preferably, the nozzle (10) sprays water having a particle diameter of 10 m or more and 1000 m or less.
Yes
噴霧される水の粒子径が粒子径 10 m以上 1000 μ m以下であると、送風される 空気中の塵埃、水溶性ガス等が水の粒子により接触しやすくなる。  When the sprayed water has a particle size of 10 m or more and 1000 μm or less, dust, water-soluble gas, etc. in the blown air can easily come into contact with the water particles.
[0107] 好ましくは、前記空気浄化装置(1 E、 1F、 1H又は 1J)が、前記洗浄塔(30E)の内 部空間において前記ノズル(10E)の散布先に設けられ、前記ノズル(10E)から散布 された水を捕捉するとともに捕捉した水を前記送風機(8E)で送風される空気に接触 させる気液接触構造(20E、 20F、 20G又は 20H)を更に備える。  [0107] Preferably, the air purification device (1E, 1F, 1H or 1J) is provided at a spray destination of the nozzle (10E) in an internal space of the cleaning tower (30E), and the nozzle (10E) And a gas-liquid contact structure (20E, 20F, 20G, or 20H) that captures the water sprayed from the air and makes the captured water contact the air blown by the blower (8E).
[0108] 従って、ノズル(10E)力も水が散布されると、その水が気液接触構造(20E、 20F、 20G又は 20H)に捕捉される。そして、住宅内又はその屋外等の空気が送風機(8E )によって吸気口(31E)力 洗浄塔(30E)の内部空間に取り込まれて、洗浄塔(30 E)に取り込まれた空気が気液接触構造(20E、 20F、 20G又は 20H)を通過して排 気口(37E)から住宅内等に送り出される。洗浄塔(30E)内の空気が気液接触構造( 20E、 20F、 20G又は 20H)を通過している際に、水と空気が接触し、空気中の塵埃 が水に取り込まれたり、空気中の水溶性ガス例えば、 NOxガス、 SOxガス、 NH4ガス等 が水に溶けたりする。そのため、浄化された空気が住宅内等に送り込まれる。 [0108] Accordingly, when water is sprayed on the nozzle (10E) force, the water is in contact with the gas-liquid contact structure (20E, 20F, 20G or 20H). And the air inside the house or outside of the house is taken into the internal space of the suction tower (30E) by the blower (8E), and the air taken into the washing tower (30E) comes into gas-liquid contact It passes through the structure (20E, 20F, 20G or 20H) and is sent out from the exhaust port (37E) to the house. When air in the cleaning tower (30E) passes through the gas-liquid contact structure (20E, 20F, 20G, or 20H), water and air come into contact with each other, and dust in the air is taken into the water, Water-soluble gases such as NOx gas, SOx gas, NH4 gas, etc. dissolve in water. Therefore, the purified air is sent into the house.
[0109] 好ましくは、前記気液接触構造(20E又は 20F)力 S、前記ノズル(10E)の散布先に ぉレ、て複数の充填物(21E又は 21F)を充填してなる。  [0109] Preferably, the gas-liquid contact structure (20E or 20F) force S is filled with a plurality of fillers (21E or 21F) at the spray destination of the nozzle (10E).
ノズル(10E)の散布先において複数の充填物(21E又は 21F)が充填されている ので、ノズル(10E)から散布された水が充填物(21E又は 21F)の隙間に捕捉され、 送風機(8E)によって流れる空気は充填物(21E又は 21F)の隙間を通過する。その ため、空気と水が接触し、空気中の塵埃や水溶性ガスが除去される。  Since multiple fillers (21E or 21F) are filled at the spray destination of the nozzle (10E), the water sprayed from the nozzle (10E) is trapped in the gap between the fillers (21E or 21F) and the blower (8E ) Passes through the gap in the packing (21E or 21F). For this reason, air and water come into contact with each other, and dust and water-soluble gas in the air are removed.
[0110] 好ましくは、前記気液接触構造(20G) 、前記ノズルの散布先において多孔板(2 4G)を重ねてなる。  [0110] Preferably, the gas-liquid contact structure (20G) is formed by stacking a perforated plate (24G) at a spray destination of the nozzle.
ノズル(10E)の散布先において多孔板(24G)が重ねられているので、ノズル(10E )から散布された水が多孔板(24G)の孔に捕捉され、送風機(8E)によって流れる空 気は多孔板(24G)の孔を通過する。そのため、空気と水が接触し、空気中の塵埃や 水溶性ガスが除去される。  Since the porous plate (24G) is stacked at the spray destination of the nozzle (10E), the water sprayed from the nozzle (10E) is trapped in the hole of the porous plate (24G) and the air flowing by the blower (8E) is Passes through holes in the perforated plate (24G). For this reason, air and water come into contact with each other, and dust and water-soluble gas in the air are removed.
[0111] 好ましくは、前記気液接触構造(20H)が、複数の板(25H)を棚段状に配列してな ノズル(10E)の散布先において複数の板(25H)が棚段状に配列されているので、 ノズル(10E)から散布された水が板 25H)の表面に載って捕捉され、送風機(8E)に よって流れる空気は板(25H)の間を通過する。そのため、空気と水が接触し、空気 中の塵埃や水溶性ガスが除去される。 [0111] Preferably, the gas-liquid contact structure (20H) includes a plurality of plates (25H) arranged in a shelf shape, and the plurality of plates (25H) in a shelf shape at a spray destination of the nozzle (10E). Since it is arranged, the water sprayed from the nozzle (10E) is caught on the surface of the plate 25H), and the air flowing by the blower (8E) passes between the plates (25H). For this reason, air and water come into contact with each other, and dust and water-soluble gas in the air are removed.
[0112] 好ましくは、前記空気浄化装置(1)が、前記吸気口(31)と前記洗浄塔 (40)との間 に設けられたフィルタ(7)を更に備える。 [0112] Preferably, the air purification device (1) further includes a filter (7) provided between the air inlet (31) and the washing tower (40).
吸気口(31)と洗浄塔(40)との間にフィルタ(7)が設けられているので、吸気口(31 )に取り込まれる空気中の塵埃等がそのフィルタ(7)によって捕捉される。そのため、 空気の浄化効率が向上する。また、塵埃等が取り除かれた空気が洗浄塔 (40)に送 られるので、洗浄塔 (40)内において散布された水が貯留又は排水される場合に、そ の水に含まれる塵埃等が少なくなり、その水の後処理も容易に行うことができる。 Since a filter (7) is provided between the intake port (31) and the cleaning tower (40), the intake port (31 Dust and the like in the air taken in by the filter are captured by the filter (7). Therefore, the air purification efficiency is improved. In addition, since the air from which dust has been removed is sent to the cleaning tower (40), when the water sprayed in the cleaning tower (40) is stored or drained, the amount of dust contained in the water is small. Therefore, the post-treatment of the water can be easily performed.
[0113] 好ましくは、前記空気浄化装置(1)が、前記送風機(8)と前記排気口(37)との間に 設けられたフィルタ(9)を更に備える。  [0113] Preferably, the air purification device (1) further includes a filter (9) provided between the blower (8) and the exhaust port (37).
送風機(8)と排気口(37)との間にフィルタ(9)が設けられているので、洗浄塔 (40) 内で除去することができなかった塵埃等もそのフィルタ(9)によって捕捉される。その ため、空気の浄化効率が向上する。また、洗浄塔 (40)において塵埃等が殆ど除去さ れるので、排気口(37)を閉塞したフィルタ(9)の清掃 ·交換を頻繁に行わずに済む。  Since a filter (9) is provided between the blower (8) and the exhaust port (37), dust that could not be removed in the cleaning tower (40) is also captured by the filter (9). The Therefore, the air purification efficiency is improved. Further, since dust and the like are almost removed in the cleaning tower (40), it is not necessary to frequently clean and replace the filter (9) with the exhaust port (37) blocked.
[0114] 好ましくは、前記空気浄化装置(1、 1A、 1B、 1E、 1F、 1G、 1H又は 1J)が、前記ノ ズル(10又は 10E)に水を送液し、前記ノズル(10又は 10E)力も水を散布させるポン プ(12、 12A、 12B、 12C、 12D、 12E、 12J、 12K又は 12L)を更に備える。  [0114] Preferably, the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H or 1J) feeds water to the nozzle (10 or 10E), and the nozzle (10 or 10E). ) It is further equipped with a pump (12, 12A, 12B, 12C, 12D, 12E, 12J, 12K or 12L) that sprays water.
水力ポンプ(12、 12B、 12C、 12D、 12E、 12J、 12K又 (ま 12L)によってノス、ノレ(10 又は 10E)に送液されると、ノズル(10又は 10E)力も水が散布される。  When the liquid is fed to the nose, nore (10 or 10E) by the hydraulic pump (12, 12B, 12C, 12D, 12E, 12J, 12K or (or 12L), the nozzle (10 or 10E) is also sprayed with water.
[0115] 好まし <は、前記ポンプ(12、 12B、 12C、 12D、 12E、 12J、 12K又は 12L)は、前 記ノズルから散布されて前記洗浄塔の内部空間の下部に貯留された水を前記ノズノレ (10又は 10E)に送液する。  [0115] Preferred <is that the pump (12, 12B, 12C, 12D, 12E, 12J, 12K or 12L) sprays water stored in the lower part of the internal space of the washing tower after being sprayed from the nozzle. The solution is fed to the Nozure (10 or 10E).
従って、水が循環するので、水の消費を抑えることができる。  Therefore, since water circulates, water consumption can be suppressed.
[0116] 好ましくは、前記空気浄化装置(1)が、前記洗浄塔 (40)の内部空間に配置され、 前記ノズル(10)から散布されて前記洗浄塔 (40)の内部空間の底に貯留された水を 殺菌する殺菌装置(15)を更に備える。  [0116] Preferably, the air purification device (1) is disposed in the internal space of the cleaning tower (40), and is sprayed from the nozzle (10) and stored in the bottom of the internal space of the cleaning tower (40). It is further provided with a sterilizer (15) for sterilizing the generated water.
従って、循環している水の汚染を抑えることができ、空気浄化装置(1)が長期に動 作していても、住宅内に送り込まれる空気が浄化された状態を保つことができる。  Therefore, contamination of the circulating water can be suppressed, and even when the air purification device (1) has been operating for a long time, the air sent into the house can be kept purified.
[0117] 好ましくは、前記殺菌装置(15)が電解殺菌装置である。  [0117] Preferably, the sterilizer (15) is an electrolytic sterilizer.
[0118] 好ましくは、前記殺菌装置(15)が紫外線照射装置である。  [0118] Preferably, the sterilizer (15) is an ultraviolet irradiation device.
[0119] 好ましくは、前記洗浄塔 (40又は 30E)の内部空間の下部に貯留された水を残留 塩素で殺菌する。 [0120] 好ましくは、前記洗浄塔(40又は 30E)の内部空間の下部に貯留された水の有効 塩素濃度を 0. lmg/L以上 10mg/L以下とすることでその水を殺菌する。 [0119] Preferably, the water stored in the lower part of the internal space of the washing tower (40 or 30E) is sterilized with residual chlorine. [0120] Preferably, the water is sterilized by setting the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower (40 or 30E) to 0.1 mg / L or more and 10 mg / L or less.
[0121] 好ましくは、前記洗浄塔(40又は 30E)の内部空間の下部に貯留された水の有効 塩素濃度を lmg/L以上 3mg/L以下とすることでその水を殺菌する。 [0121] Preferably, the water is sterilized by setting the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower (40 or 30E) to 1 mg / L or more and 3 mg / L or less.
[0122] 好ましくは、前記空気浄化装置(1、 1A、 1B、 1E、 1F、 1G、 1H又は 1J)が、前記 洗浄塔(40又は 30E)の内部空間において前記ノズル(10又は 10E)よりも前記排気 口(37又は 37E)側に配置され、前記ノズル(10又は 10E)から散布された水を捕捉 するエリミネータ(11又は 11E)を更に備える。 [0122] Preferably, the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H, or 1J) is more than the nozzle (10 or 10E) in the internal space of the washing tower (40 or 30E). It further includes an eliminator (11 or 11E) that is disposed on the exhaust port (37 or 37E) side and captures water sprayed from the nozzle (10 or 10E).
エリミネータ(11又は 11E)によって水が捕捉されることによって、住宅内等に送り込 まれる空気中に水が残留することを抑えることができる。そのため、住宅内等に送り込 まれる空気がより効率的に浄化される。  By catching water by the eliminator (11 or 11E), it is possible to prevent water from remaining in the air sent into the house. Therefore, the air sent into the house is purified more efficiently.
[0123] 好ましくは、前記空気浄化装置(1、 1A、 1B、 1E、 1F、 1G、 1H又は 1J)が、前記 洗浄塔(40又は 30E)の内部空間の底よりも上にお!/、て前記洗浄塔(40又は 30E) に接続され、その接続箇所の水位まで貯留した水を排水する排水管(14又は 14E) を更に備える。 [0123] Preferably, the air purification device (1, 1A, 1B, 1E, 1F, 1G, 1H or 1J) is above the bottom of the internal space of the washing tower (40 or 30E)! /, The drainage pipe (14 or 14E) is further connected to the washing tower (40 or 30E) and drains the stored water up to the water level at the connection point.
排水管(14又は 14E)が洗浄塔 (40又は 30E)に接続されているので、散布された 水が排水管(14又は 14E)の接続箇所を越えた水位に貯まることがない。特に、水と 接触した塵埃等は洗浄塔 (40又は 30E)に貯留された水の水面に浮上するので、空 気から取り除いた塵埃等が水とともに排水管(14又は 14E)から排出される。  Since the drain pipe (14 or 14E) is connected to the washing tower (40 or 30E), the sprayed water does not accumulate at the water level beyond the connection point of the drain pipe (14 or 14E). In particular, dust that has come into contact with water floats on the surface of the water stored in the washing tower (40 or 30E), so that dust removed from the air is discharged from the drain pipe (14 or 14E) together with water.
[0124] 好ましくは、前記ノズルが水道水、純水、酸性水若しくはアルカリ水又はこれらのう ち二種以上を混合させたものを散布する。  [0124] Preferably, the nozzle sprays tap water, pure water, acidic water, alkaline water, or a mixture of two or more thereof.
[0125] 好ましくは、前記ノズルが逆浸透装置又はイオン交換装置によって精製された純水 を散布する。  [0125] Preferably, the nozzle sprays pure water purified by a reverse osmosis device or an ion exchange device.
[0126] 好ましくは、前記ノズルが、逆浸透装置によって精製された濃縮水若しくは巿水を 電解装置に供することで得られる当該電解装置の陽極水、又は、電気軟化装置若し くは電気再生式脱イオン装置の陽極水を散布する。  [0126] Preferably, the nozzle is anodic water of the electrolysis apparatus obtained by supplying concentrated water or brine purified by a reverse osmosis apparatus to the electrolysis apparatus, or an electrosoftening apparatus or an electric regeneration type. Spray the anode water of the deionizer.
[0127] 好ましくは、前記ノズルが、逆浸透装置によって精製された濃縮水若しくは巿水を 電解装置に供することで得られる当該電解装置の陰極水、電気軟化装置の陰極水、 電気再生式脱イオン装置の陰極水、又は、軟水を電解装置に供することで得られる 当該電解装置の陰極水を散布する。 [0127] Preferably, the nozzle comprises cathodic water of the electrolysis apparatus obtained by supplying concentrated water or brine purified by a reverse osmosis apparatus to the electrolysis apparatus, cathodic water of an electrosoftening apparatus, The cathodic water of the electrolysis apparatus obtained by supplying cathodic water or soft water of an electroregenerative deionization apparatus to the electrolysis apparatus is sprayed.
[0128] なお、明細書、特許請求の範囲、図面および要約書を含む 2006年 11月 1日提出 の日本国特許出願 2006 - 298122号及び 2007年 3月 1日提出の日本国特許出願[0128] Japanese patent application filed on November 1, 2006 including specification, claims, drawings, and abstract 2006-298122 and Japanese patent application filed on March 1, 2007
2007— 51539号の開示内容全体は、本国際出願で指定した指定国、又は選択し た選択国の国内法令の許す限り、そのまま引用してここに組み込まれる。 The entire disclosure of 2007-51539 is incorporated herein by reference as far as the national laws of the designated country designated in this international application or the selected country selected.
[0129] 種々の典型的な実施の形態を示しかつ説明してきた力 本発明はそれらの実施の 形態に限定されない。従って、本発明の範囲は、次の請求の範囲によってのみ限定 されるものである。 [0129] Forces Showing and Explaining Various Exemplary Embodiments The present invention is not limited to those embodiments. Accordingly, the scope of the invention is limited only by the following claims.
産業上の利用可能性  Industrial applicability
[0130] 以上説明したように、本発明の好ましい実施の形態によれば、送風されている空気 中の水溶性ガス例えば、 NOxガス、 SOxガス、 NH4ガス、悪臭の元となるガス等が散 布された水に溶けることによって、更に空気中の塵埃等が散布された水に接触するこ とによって、空気中から水溶性ガス及び塵埃等を取り除くことができ、浄化された空気 を住宅等に送り込むことができる。また、フィルタの清掃 ·交換をせずとも、またその頻 度が少なくても、水と空気の接触により空気を浄化することができる。また、吸気口か ら洗浄塔に取り込まれた空気は水が分散した雰囲気を通過するので、圧力損失を少 なくすること力 Sでき、送風機の出力を低くすることができる。 [0130] As described above, according to a preferred embodiment of the present invention, water-soluble gas in the blown air, for example, NOx gas, SOx gas, NH4 gas, gas causing malodor, etc. is scattered. Water soluble gas and dust can be removed from the air by dissolving in the cloth water and further coming into contact with the water sprayed with dust in the air. Can be sent. In addition, the air can be purified by the contact of water and air without cleaning and replacement of the filter and even when the frequency is low. In addition, since air taken into the washing tower from the intake port passes through the atmosphere in which water is dispersed, the pressure loss can be reduced and the output of the blower can be lowered.
その結果、本発明は、住宅等に送り込む空気を浄化する技術に特に好適に利用で きる。  As a result, the present invention can be particularly suitably used for a technology for purifying air sent to a house or the like.

Claims

請求の範囲 The scope of the claims
[I] 吸気口に通じるとともに排気口に通じる内部空間を有した洗浄塔と、  [I] a washing tower having an internal space that leads to the intake and the exhaust,
空気を前記吸気口から前記洗浄塔の内部空間に取り込んで前記排気口から前記 洗浄塔の外に送り出すよう送風する送風機と、  A blower that takes air from the intake port into the internal space of the cleaning tower and sends it out of the cleaning tower from the exhaust port;
前記洗浄塔の内部空間に配置され、前記洗浄塔の内部空間内で水を散布するノ ズノレと、を備え、  A nozzle arranged in the internal space of the cleaning tower and spraying water in the internal space of the cleaning tower,
前記ノズルから散布された水が前記洗浄塔内で前記送風機により送風された空気 と接触する、空気浄化装置。  The air purifier which the water sprayed from the said nozzle contacts with the air ventilated by the said air blower in the said washing tower.
[2] 前記ノズルが水を霧状に散布する、請求項 1に記載の空気浄化装置。  [2] The air purifier according to claim 1, wherein the nozzle sprays water in a mist form.
[3] 前記ノズルが粒子径 10 m以上 1000 μ m以下の水を噴霧する、請求項 2に記載 の空気浄化装置。 [3] The air purification device according to claim 2, wherein the nozzle sprays water having a particle diameter of 10 m or more and 1000 μm or less.
[4] 前記洗浄塔の内部空間において前記ノズルの散布先に設けられ、前記ノズルから 散布された水を捕捉するとともに捕捉した水を前記送風機で送風される空気に接触 させる気液接触構造を更に備える請求項 1から 3の何れか一項に記載の空気浄化装 置。  [4] A gas-liquid contact structure that is provided at a spray destination of the nozzle in the internal space of the cleaning tower, captures the water sprayed from the nozzle, and makes the captured water contact the air blown by the blower The air purifier according to any one of claims 1 to 3, further comprising:
[5] 前記気液接触構造が、前記ノズルの散布先において複数の充填物を充填してなる [5] The gas-liquid contact structure is formed by filling a plurality of fillers at the spray destination of the nozzle.
、請求項 4に記載の空気浄化装置。 The air purifier according to claim 4.
[6] 前記気液接触構造が、前記ノズルの散布先にお!/、て多孔板を重ねてなる、請求項 [6] The gas-liquid contact structure is formed by stacking a perforated plate at a spray destination of the nozzle!
4に記載の空気浄化装置。  4. The air purification device according to 4.
[7] 前記気液接触構造が、複数の板を棚段状に配列してなる、請求項 4に記載の空気 浄化装置。 7. The air purification apparatus according to claim 4, wherein the gas-liquid contact structure is formed by arranging a plurality of plates in a shelf shape.
[8] 前記吸気口と前記洗浄塔との間に設けられたフィルタを更に備える請求項 1に記載 の空気浄化装置。  8. The air purification device according to claim 1, further comprising a filter provided between the intake port and the cleaning tower.
[9] 前記送風機と前記排気口との間に設けられたフィルタを更に備える請求項 1に記載 の空気浄化装置。  [9] The air purification device according to [1], further comprising a filter provided between the blower and the exhaust port.
[10] 前記ノズルに水を送液し、前記ノズルから水を散布させるポンプを更に備える請求 項 1に記載の空気浄化装置。  10. The air purification device according to claim 1, further comprising a pump for feeding water to the nozzle and spraying water from the nozzle.
[I I] 前記ポンプは、前記ノズルから散布されて前記洗浄塔の内部空間の下部に貯留さ れた水を前記ノズルに送液することを特徴とする請求項 10に記載の空気浄化装置。 [II] The pump is sprayed from the nozzle and stored in the lower part of the internal space of the washing tower. 11. The air purifier according to claim 10, wherein the collected water is fed to the nozzle.
[12] 前記洗浄塔の内部空間に配置され、前記ノズルから散布されて前記洗浄塔の内部 空間の底に貯留された水を殺菌する殺菌装置を更に備える請求項 11に記載の空気 浄化装置。 12. The air purification device according to claim 11, further comprising a sterilizer disposed in the internal space of the cleaning tower and sterilizing water sprayed from the nozzles and stored in the bottom of the internal space of the cleaning tower.
[13] 前記殺菌装置が電解殺菌装置である、請求項 12に記載の空気浄化装置。  13. The air purification device according to claim 12, wherein the sterilizer is an electrolytic sterilizer.
[14] 前記殺菌装置が紫外線照射装置である、請求項 12に記載の空気浄化装置。 14. The air purification device according to claim 12, wherein the sterilizer is an ultraviolet irradiation device.
[15] 前記洗浄塔の内部空間の下部に貯留された水を残留塩素で殺菌する、請求項 11 に記載の空気浄化装置。 15. The air purification device according to claim 11, wherein water stored in a lower portion of the internal space of the cleaning tower is sterilized with residual chlorine.
[16] 前記洗浄塔の内部空間の下部に貯留された水の有効塩素濃度を 0. lmg/L以 上 10mg/L以下とすることでその水を殺菌する、請求項 11に記載の空気浄化装置 [16] The air purification according to claim 11, wherein the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower is sterilized by setting the effective chlorine concentration to 0.1 mg / L or more and 10 mg / L or less. Equipment
[17] 前記洗浄塔の内部空間の下部に貯留された水の有効塩素濃度を lmg/L以上 3 mg/L以下とすることでその水を殺菌する、請求項 11に記載の空気浄化装置。 17. The air purification device according to claim 11, wherein the effective chlorine concentration of the water stored in the lower part of the internal space of the washing tower is sterilized by setting it to 1 mg / L or more and 3 mg / L or less.
[18] 前記洗浄塔の内部空間において前記ノズルよりも前記排気口側に配置され、前記 ノズルから散布された水を捕捉するエリミネータを更に備える請求項 1に記載の空気 浄化装置。  18. The air purification device according to claim 1, further comprising an eliminator that is disposed closer to the exhaust port than the nozzle in the internal space of the cleaning tower and captures water sprayed from the nozzle.
[19] 前記洗浄塔の内部空間の底よりも上において前記洗浄塔に接続され、その接続箇 所の水位まで貯留した水を排水する排水管を更に備える請求項 1に記載の空気浄 化装置。  [19] The air purification device according to claim 1, further comprising a drain pipe connected to the cleaning tower above the bottom of the internal space of the cleaning tower and draining the water stored up to the water level at the connection point. .
[20] 前記ノズルが水道水、純水、酸性水若しくはアルカリ水又はこれらのうち二種以上 を混合させたものを散布する、請求項 1に記載の空気浄化装置。  [20] The air purification device according to claim 1, wherein the nozzle sprays tap water, pure water, acidic water, alkaline water, or a mixture of two or more thereof.
[21] 前記ノズルが逆浸透装置又はイオン交換装置によって精製された純水を散布する 、請求項 1に記載の空気浄化装置。  21. The air purification device according to claim 1, wherein the nozzle sprays pure water purified by a reverse osmosis device or an ion exchange device.
[22] 前記ノズルが、逆浸透装置によって精製された濃縮水若しくは巿水を電解装置に 供することで得られる当該電解装置の陽極水、又は、電気軟化装置若しくは電気再 生式脱イオン装置の陽極水を散布する、請求項 1に記載の空気浄化装置。  [22] Anodic water of the electrolysis apparatus obtained by supplying the concentrated water or brine purified by a reverse osmosis apparatus to the electrolysis apparatus, or an anode of an electrosoftening apparatus or an electroregenerative deionization apparatus The air purifier according to claim 1, which sprays water.
[23] 前記ノズルが、逆浸透装置によって精製された濃縮水若しくは巿水を電解装置に 供することで得られる当該電解装置の陰極水、電気軟化装置の陰極水、電気再生式 脱イオン装置の陰極水、又は、軟水を電解装置に供することで得られる当該電解装 置の陰極水を散布する、請求項 1に記載の空気浄化装置。 [23] Cathode water of the electrolysis device, cathodic water of an electrosoftening device, electric regenerative type obtained by supplying the concentrated water or brine purified by a reverse osmosis device to the electrolysis device. 2. The air purification apparatus according to claim 1, wherein the cathode water of the electrolysis apparatus obtained by supplying the deionizer cathode water or soft water to the electrolysis apparatus is sprayed.
PCT/JP2007/071082 2006-11-01 2007-10-30 Air purifier WO2008053871A1 (en)

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