WO2008046174A1 - Solution de nettoyage contenant un lignosulfonate - Google Patents
Solution de nettoyage contenant un lignosulfonate Download PDFInfo
- Publication number
- WO2008046174A1 WO2008046174A1 PCT/CA2006/001705 CA2006001705W WO2008046174A1 WO 2008046174 A1 WO2008046174 A1 WO 2008046174A1 CA 2006001705 W CA2006001705 W CA 2006001705W WO 2008046174 A1 WO2008046174 A1 WO 2008046174A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cleaning
- lignosulfonate
- cleaning solution
- kitchen
- floor
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 62
- 229920001732 Lignosulfonate Polymers 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000004615 ingredient Substances 0.000 claims abstract description 6
- 229920005550 ammonium lignosulfonate Polymers 0.000 claims description 9
- 238000005201 scrubbing Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 abstract description 15
- 239000012459 cleaning agent Substances 0.000 abstract description 4
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- 239000011538 cleaning material Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 238000010411 cooking Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 235000019501 Lemon oil Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000010501 lemon oil Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 235000021167 banquet Nutrition 0.000 description 2
- 235000019506 cigar Nutrition 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 239000011440 grout Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 241000269333 Caudata Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 235000021162 brunch Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 235000014438 salad dressings Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the present invention relates to a cleaning solution, and more particularly, relates to a novel cleaning solution containing lignin sulfonate as the primary cleaning agent.
- compositions containing various solvents and detergents function effectively, they can, in the case of solvents, be dangerous to employ and the problem of disposal of the solvent is always present.
- Detergents have also been widely used; however, they are frequently not as effective as the harsher solvents. Furthermore, biodegradability of detergents is an ever present issue.
- a method of cleaning a surface comprising the step of applying an aqueous cleaning solution to the surface wherein the active cleaning ingredient of the aqueous cleaning solution consists essentially of a lignosulfonate.
- Lignosulfonates have been utilized in cleaning solutions in the prior art.
- a method for the cleaning of a substrate to remove hydrocarbon therefrom comprising the step of applying to the substrate a composition comprising a lignosulfonate and a microbially effective amount of micro organisms.
- a cleaning composition comprising a liquid multi phase composition with at least two continuous phases and which contains a relatively small proportion of a lignosulfonate.
- the lignosulfonate is effective, even without the microbial bacteria, to clean different types of surfaces.
- Lignosulfonates are salts of lignin sulfonic acid which is the reaction product of lignin and sulfurous acid which is obtained in the sulfite pulping of wood to obtain cellulose.
- lignosulfonates are known including alkaline metal and alkaline earth metal lignosulfonates and the ammonium lignosulfonates, all of which are suitable for the purposes of the present invention.
- the method of the present invention can be applied to many different types of surfaces.
- the surface may be either vertical or horizontal or at some other angle.
- the surface may comprise practically any material as the lignosulfonate is generally not considered to be deleterious to any of the known surfaces.
- the lignosulfonate can be applied to all types of flooring material (with appropriate caution taken for materials adversely affected by water).
- the concentration of the lignosulfonate in the aqueous solution may vary depending upon the particular use of the cleaning solution. Generally, a ratio of between 3 ml and 60 ml of lignosulfonate per liter of water is satisfactory with a preferred ratio being between
- the cleaning solution may, if desired, contain other ingredients with the understanding that the main cleaning ingredient is the lignosulfonate.
- the cleaning solution may include certain enzymes, surfactants, polymers, etc.
- the cleaning solution may be used over a wide PH range — i.e. between 2 and 13.
- the cleaning solution will be applied by appropriate means depending on the surface being treated. Thus, it may be poured, sprayed, or wiped on. Appropriate cleaning implements may be used in conjunction with the above.
- the cleaning solution may be applied and left for a period of time. Scrubbing implements may be utilized with the remaining solution/debris being appropriately removed.
- Step 1 General cleaning - Blended 30 ml of dry ammonium lignosulfonate (ALS) in 4.5 litres of hot water in a mop bucket. The mixture was allowed to let stand for about 5 to
- Step 2 Mopping and degreasing kitchen floors - Blended 45 ml of ALS with 4.5 litres of hot water and was allowed to let stand for at least 90 minutes.
- Product was sprayed on (60 ml to 4.5 litres ratio) the surfaces multiple times and left for about 10 minutes. Cleaning conducted in the same manner as in step 9 above, using the same dilution and cleaning implements.
- Housekeeping cleaning is done on a 24-hour basis with guestrooms done during the day, as well as all of the public areas and a first cleaning of the restaurant in the afternoon.
- the evening houseperson spot cleans public areas and washrooms, including brass cleaning.
- the overnight cleaner does the second cleaning of the restaurant, the pool and hot tub area, loading dock, all public washrooms, and the lobbies.
- the hotel has 25 smoking rooms in its 155-room inventory located on the 2 nd floor of the Tower section. Keeping these rooms clean and smelling clean has always been more challenging.
- a cigar smoker occupied one of the smoking rooms, and the room was saturated with smoke.
- the room was cleaned with the product, as were the drapes and carpet with a light spray of the product. After inspection, the floor supervisor was consciously surprised to find the aroma of cigar smoke was gone. Nornially, the room would need to be put out of order and aired out for at least a day, along with liberal use of an air freshener.
- An area that has always been a challenge is the tile floor of the pool area.
- the product and the rotary machine then tackled another problem area.
- the tile floor in one of the men's public washrooms is a textured tile, and regular mopping with a chemical cleaner would leave dirt residues in both the grout and nooks and crannies of the tiles.
- the representatives used a spray bottle of lignosulfonate to lightly wet down about four 12 x 12 tiles.
- the product lay on the floor for 5 minutes. Within seconds of the brushes scrubbing the tile, the dirt literally flaked off of both the tile and the grout.
- the field test was to be restricted to the housekeeping area only. However, some kitchen staff heard of the cleaning effectiveness of lignosulfonate and asked to try it. A demonstration of lignosulfonate was arranged, and the product was used to effectively clean grills in the ovens. Subsequently, the kitchen received their own 22.5 litre container of lignosulfonate that was used to clean the floor, the hoods, and the stainless steel tables and equipment. The dishwashing staff even found another use when some lignosulfonate was sprayed into a large pot that had burned food on the bottom. After spraying the pot with lignosulfonate and letting it sit for ten minutes, the burned food residue lifted right off.
- the dishwashing staff member stated that he just had saved himself a good 30 minutes of scrubbing. Even the line cooks started using lignosulfonate by cleaning a salamander in less than 10 minutes, which normally would take twice that time. The thing that really impressed the kitchen staff was the fact that they did not need to wear masks, respirators, heavy aprons, or acid resistant gloves.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
La présente invention concerne un procédé de nettoyage de surface, comprenant l'application d'une solution de nettoyage aqueuse sur la surface, l'ingrédient de nettoyage actif de la solution aqueuse étant composé essentiellement d'un lignosulfonate. On a découvert que le lignosulfonate pouvait jouer le rôle d'agent de nettoyage pour divers matériaux de nettoyage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CA2006/001705 WO2008046174A1 (fr) | 2006-10-17 | 2006-10-17 | Solution de nettoyage contenant un lignosulfonate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CA2006/001705 WO2008046174A1 (fr) | 2006-10-17 | 2006-10-17 | Solution de nettoyage contenant un lignosulfonate |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008046174A1 true WO2008046174A1 (fr) | 2008-04-24 |
Family
ID=39313529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA2006/001705 WO2008046174A1 (fr) | 2006-10-17 | 2006-10-17 | Solution de nettoyage contenant un lignosulfonate |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2008046174A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8075637B2 (en) | 2008-09-19 | 2011-12-13 | The Procter & Gamble Company | Modified lignin biopolymer useful in cleaning compositions |
US8383571B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Dual character polymer useful in fabric care products |
US8383572B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Detergent composition containing suds boosting and suds stabilizing modified biopolymer |
US8383573B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Dual character biopolymer useful in cleaning products |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4636224A (en) * | 1984-12-10 | 1987-01-13 | Westvaco Corporation | Ammonium lignosulfonates |
US6288015B1 (en) * | 1998-12-23 | 2001-09-11 | Henkel Kommanditgesellschaft Auf Aktien | Multiphase cleaning composition containing lignin sulfonate |
US6475290B2 (en) * | 2000-10-17 | 2002-11-05 | Earth Alive Resources Inc. | Cleaning solution to remove hydrocarbons from a substrate |
CA2547100A1 (fr) * | 2005-05-27 | 2006-11-27 | David H. Jones | Solution nettoyante |
-
2006
- 2006-10-17 WO PCT/CA2006/001705 patent/WO2008046174A1/fr active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4636224A (en) * | 1984-12-10 | 1987-01-13 | Westvaco Corporation | Ammonium lignosulfonates |
US6288015B1 (en) * | 1998-12-23 | 2001-09-11 | Henkel Kommanditgesellschaft Auf Aktien | Multiphase cleaning composition containing lignin sulfonate |
US6475290B2 (en) * | 2000-10-17 | 2002-11-05 | Earth Alive Resources Inc. | Cleaning solution to remove hydrocarbons from a substrate |
CA2547100A1 (fr) * | 2005-05-27 | 2006-11-27 | David H. Jones | Solution nettoyante |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8075637B2 (en) | 2008-09-19 | 2011-12-13 | The Procter & Gamble Company | Modified lignin biopolymer useful in cleaning compositions |
US8383571B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Dual character polymer useful in fabric care products |
US8383572B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Detergent composition containing suds boosting and suds stabilizing modified biopolymer |
US8383573B2 (en) | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Dual character biopolymer useful in cleaning products |
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