WO2008043247A1 - Alcohol-gasoline dual-fuel supply device for vehicle - Google Patents

Alcohol-gasoline dual-fuel supply device for vehicle Download PDF

Info

Publication number
WO2008043247A1
WO2008043247A1 PCT/CN2007/002694 CN2007002694W WO2008043247A1 WO 2008043247 A1 WO2008043247 A1 WO 2008043247A1 CN 2007002694 W CN2007002694 W CN 2007002694W WO 2008043247 A1 WO2008043247 A1 WO 2008043247A1
Authority
WO
WIPO (PCT)
Prior art keywords
ethanol
gasoline
cylinder
pipe
layer
Prior art date
Application number
PCT/CN2007/002694
Other languages
French (fr)
Chinese (zh)
Inventor
Kaijuan Sun
Huishu Zhang
Original Assignee
Kaijuan Sun
Huishu Zhang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaijuan Sun, Huishu Zhang filed Critical Kaijuan Sun
Publication of WO2008043247A1 publication Critical patent/WO2008043247A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D19/00Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/06Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
    • F02D19/0663Details on the fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02D19/0668Treating or cleaning means; Fuel filters
    • F02D19/0671Means to generate or modify a fuel, e.g. reformers, electrolytic cells or membranes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D19/00Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/06Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
    • F02D19/0639Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed characterised by the type of fuels
    • F02D19/0649Liquid fuels having different boiling temperatures, volatilities, densities, viscosities, cetane or octane numbers
    • F02D19/0652Biofuels, e.g. plant oils
    • F02D19/0655Biofuels, e.g. plant oils at least one fuel being an alcohol, e.g. ethanol
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/02Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M31/00Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture
    • F02M31/02Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating
    • F02M31/16Other apparatus for heating fuel
    • F02M31/18Other apparatus for heating fuel to vaporise fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D19/00Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/06Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
    • F02D19/0626Measuring or estimating parameters related to the fuel supply system
    • F02D19/0628Determining the fuel pressure, temperature or flow, the fuel tank fill level or a valve position
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

Definitions

  • the present invention relates to an automotive fuel supply apparatus, and more particularly to an ethanol-gasoline dual fuel automobile fuel supply apparatus. Second, the background technology
  • Patent No. 01136415. 7 discloses a patented "Method for Realizing Alcohol and Gasoline Fuel Vehicles", which is still atomized and then supplied to the engine as a fuel. Third, the invention content
  • the object of the present invention is to provide a simple structure, a gasification cracking cylinder is arranged outside the engine, and the heat energy of the exhaust gas of the engine is fully utilized, and the liquid ethanol in the gasification cracking cylinder is heated and vaporized, and the cracking reaction is generated under the action of the catalyst.
  • the fuel gas formed by cracking is supplied to the ethanol-gasoline fuel vehicle fuel supply device of the engine.
  • the technical solution adopted by the object of the present invention is that the intake manifold of the engine is equipped with a vaporizer with an air cleaner and an exhaust manifold, and a gasoline tank with a fuel gauge is connected to one end of the gasoline tube, and the other end of the gasoline tube is connected.
  • the output end of the gasoline valve is connected to the input end of the gasoline filter, and the output end of the gasoline filter is connected to the input end of the gasoline pump with the oil cup, which is characterized in that the bottom wall of the ethanol tank with the ethanol meter is connected to the input end of the ethanol valve.
  • the output end of the ethanol valve is connected to the oil pipe between the gasoline gas and the gasoline filter; the output end of the gasoline pump is connected to the ethanol feed pipe of the gasification cracking cylinder; the gasification cracking gas output of the gasification cracking cylinder is connected One end of the ethanol pipe of the interlayer interlayer, the other end of the ethanol pipe with the interlayer is connected to the input end of the vaporizer; the bolt passes through the hole of the flange of the upper end of the gasification cracking cylinder and the hole of the exhaust manifold output flange engages with the nut , the bolt passes through the hole of the flange of the lower end of the gasification cracking cylinder and the hole of the muffler input connection flange engages with the nut.
  • an inner cylinder, a middle cylinder and an outer cylinder are welded from the inner and outer sides of the upper and lower flanges of the gasification cracking cylinder, and an insulation layer is filled between the outer cylinder and the middle cylinder, and a middle layer is formed between the inner cylinder and the inner cylinder.
  • the annular exhaust passage has a hole in the upper and lower flanges of the annular exhaust passage, and the ethanol feed pipe is welded through the outer tube, the middle cylinder, and the lower tube wall of the inner cylinder, and the gasification cracking gas output pipe passes through the outer cylinder
  • the upper tube wall of the middle tube and the inner tube are welded and connected, and the lower part of the inner tube of the lower flange is provided with an inner bushing with a hole and a preheating resistance box with a resistance wire in the outer portion from the outer to the inner side, and the upper end of the preheating resistance box is placed.
  • the first layer of the catalyst device layer from the bottom to the top is platinum wire on the metal mesh plate.
  • copper oxide is placed on the second layer of the catalyst device layer from the bottom to the top.
  • ferroferric oxide powder is placed on the third layer of the catalyst device layer from the bottom to the top.
  • titanium dioxide powder is placed on the fourth layer of the catalyst device layer from the bottom to the top.
  • gasoline and diesel currently used in internal combustion engines are liquid fuels
  • their combustion in the engine must be carried out under gas phase conditions. That is to say, after the liquid fuel enters the engine cylinders, the first is to absorb heat (ie, latent heat of vaporization).
  • the gasification phase change is carried out, and the second step is the combustion in the gas phase state.
  • the invention firstly vaporizes the ethanol liquid fuel before entering the engine cylinder, and releases the latent heat of vaporization outside the cylinder to reduce the heat load loss in the engine, and the gas phase fuel can be evenly mixed with the gas fuel of other varieties.
  • the air entering the air inlet is mixed with the air.
  • the invention utilizes the exhaust heat energy of the engine, which accounts for about 35% of the total energy consumption of the engine, the exhaust gas temperature is generally 700 ° C -800 ° C, and the diesel engine is generally 600 ° C - 700 ° C.
  • gasification of a liquid fuel such as ethanol is performed.
  • the catalyst will be provided: there may be copper oxide, triiron tetroxide, titanium dioxide, platinum, cerium oxide, etc. , the gaseous ethanol produces the following cracking reaction:
  • the invention has the advantages of simple and compact structure, convenient manufacture and assembly, and the invention is installed on the basis of the existing engine, and the cost is low.
  • the use of ethanol is a renewable energy source, and the exhaust gas discharged is favorable for environmental protection. You can mix gasoline-ethanol gas in any ratio, or you can burn pure ethanol or burn pure gasoline.
  • the resistance wire in the preheating resistance box is electrically heated to make the gasification cracking cylinder have a certain temperature, which is convenient for gasification and cracking reaction. After the temperature is constant, the power is turned off, and the temperature of the exhaust gas is exhausted by the engine to be constant.
  • Figure 1 is a schematic view of the structure of the present invention
  • FIG. 2 is a schematic cross-sectional view showing the gasification cracking cylinder of the present invention.
  • the manifold 4 of the engine 18 is equipped with a vaporizer 3 with an air cleaner 1 and an exhaust manifold 5, and a gasoline tank 11 with a fuel gauge 1 is connected to the 10-end of the gasoline tube.
  • the other end of the gasoline pipe 10 is connected to the gasoline wide 12 input end, the output of the gasoline valve 12 is connected to the input end of the gasoline filter 8 , and the output end of the gasoline filter 8 is connected to the input end of the gasoline pump 6 with the oil cup 7 , which carries the ethanol
  • the bottom wall of the ethanol tank 14 of Table 15 is connected to the input end of the ethanol valve 13 , the output end of the ethanol valve 13 is connected to the oil pipe between the gasoline valve 12 and the gasoline filter 8; the output end of the gasoline pump 6 is connected to the ethanol feed pipe of the gasification cracking cylinder 17 '25; the gasification cracking gas output pipe 30 of the gasification cracking cylinder 17 communicates with one end of the intercalated ethanol gas pipe 19, and the other end of the inter
  • Gasifier cracking cylinder 17, between the lower flange 31 from the inside out has a welded inner tube 21, the tube 28, the outer cylinder 20, and the outer cylinder 20 has the cylinder 28 is filled between the insulating layer 29,
  • An annular exhaust passage 26 is formed between the middle cylinder 28 and the inner cylinder 21, and the upper and lower flanges 31 of the annular exhaust passage 26'
  • the ethanol feed pipe 25 is welded through the outer cylinder 20, the middle cylinder 28, and the lower pipe wall of the inner cylinder, and the gasification cracking gas output pipe 30 passes through the outer cylinder 20, the middle cylinder 28, and the upper tube of the inner cylinder.
  • Wall welded joint, lower flange 3 1 upper end inner cylinder 2 1 lower part from the outside to the inside is placed with a perforated inner bushing 24 and a resistor
  • the preheating resistor box 23 of the wire, the upper end of the preheating resistor box 23 is provided with a separating plate 22, and the upper end of the inner bushing 24 is sequentially placed with four layers of the metal mesh plate 32, four layers of the catalyst device layer 33 and four layers of the bushing 27, at the top
  • the hole of the bushing 27 of the layer faces the gasification cracking output pipe 30, and the hole of the bushing 27 of the lowermost layer faces the ethanol feed pipe 25.
  • the first layer of the catalyst device layer 33 is platinum wire on the metal mesh plate 32.
  • Copper oxide is placed on the second layer of the catalyst device layer 33 from the bottom to the top.
  • Four iron triiron powder was placed on the third layer of the catalyst device layer 33 from the bottom to the top.
  • Titanium dioxide powder was placed on the fourth layer of the catalyst device layer 33 from the bottom to the top.
  • the insulating layer 29 may be made of aluminum silicate fiber or expanded by 3 beads.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)

Abstract

A vehicle fuel supply device is disclosed, the bottom wall of an alcohol tank (14) with an alcohol meter (15) is communicated with the input end of an alcohol valve (13), the output end of the alcohol valve (13) is communicated with the oil pipe between a gasoline valve (12) and a gasoline filter (8), the output end of a gasoline pump (6) is communicated with the alcohol input pipe (25) of a gasifying dissociator (17), the output pipe (30) of the gasifying dissociator (17) is communicated with one end of an alcohol pipe (19) with a sandwich, the other end of the alcohol pipe (19) with a sandwich is communicated with the input end of a carburetor (3); bolts are engage with nuts through the holes of the flange (31) disposed on the upper end of the gasifying dissociator (17) and the holes of the flange disposed on the output end of an exhaust manifold (5); bolts are engage with nuts through the holes of the flange (31) disposed on the lower end of the gasifying dissociator (17) and the holes of the flange disposed on the output end of a muffler (9).

Description

乙醇-汽油双燃料汽车燃料供给装置 一、 技术领域  Ethanol-gasoline dual fuel vehicle fuel supply device
本发明涉及汽车燃料供给装置, 尤其是一种乙醇-汽油双燃料汽车燃料供 给装置。 二、 背景技术  The present invention relates to an automotive fuel supply apparatus, and more particularly to an ethanol-gasoline dual fuel automobile fuel supply apparatus. Second, the background technology
随着地球温室效应的不断加剧, 恶劣气候的灾害频发, 所以大力发展乙 醇的生产和应用, 以替代石油类化石能源, 已经成为当前的全球共识, 各国 都在争先恐后的大力研发、 推广、 应用生物燃料乙醇, 于汽车领域, 但目前 在大量应用上还存在着阻碍快速推广的技术瓶颈, 主要有两点: 一是低比例 掺用, 在现有的发动机上使用乙醇, 由于汽油与乙醇的互溶性很差, 很容易 分层, 故我国目前只推广应用掺 10%乙醇的 "乙醇汽油" 即 E10 , 国外也有用 掺 15%、 20%最高也就是 25% (巴西); 二是需要专门设计制造的发动机, 例如 美国掺乙醇 85%, 巴西、 瑞典和日本用 100%乙醇的发动机都是另行专门设计 制造。 同时在实际使用中必须加入几种添加剂来解决乙醇与汽油混合后雾化 性能不一致、 燃烧速度不一致、 做功时会产生自相矛盾、 功率抵消和燃烧不 完全等问题, 而所添加的添加剂价格高, 使乙醇汽油价格优势不够明显, 而 制造添加剂的生产过程中也要产'生污染。  With the increasing global warming effect of the earth and the frequent occurrence of severe weather disasters, it has become the current global consensus to vigorously develop the production and application of ethanol to replace petroleum fossil energy. Countries are scrambling to vigorously develop, promote and apply. Biofuel ethanol, in the automotive field, but there are still technical bottlenecks that hinder rapid promotion in a large number of applications. There are two main points: First, low ratio blending, using ethanol on existing engines, due to gasoline and ethanol. The mutual solubility is very poor, and it is easy to stratify. Therefore, China currently only promotes the use of "ethanol gasoline" with 10% ethanol, that is, E10, and 15% for foreign countries, and 25% for 20% (Brazil); Engines designed and manufactured, such as the United States with 85% ethanol, Brazil, Sweden and Japan with 100% ethanol engines are specially designed and manufactured. At the same time, in the actual use, several additives must be added to solve the problem that the atomization performance is inconsistent, the burning speed is inconsistent, the self-contradictory, the power offset and the incomplete combustion are generated when the ethanol and the gasoline are mixed, and the added additive is expensive. The price advantage of ethanol gasoline is not obvious enough, and the production of additives is also produced in the production process.
在专利号为 01136415. 7 , 公开了 "一种实现酒精与汽油默燃料汽车的方 法" 专利技术, 仍然用酒精经雾化后, 供给发动机作为燃料。 三、 发明内容  Patent No. 01136415. 7 discloses a patented "Method for Realizing Alcohol and Gasoline Fuel Vehicles", which is still atomized and then supplied to the engine as a fuel. Third, the invention content
本发明的目的是提供一种结构简单, 在发动机外设置气化裂化筒, 充分 利用发动机排出废气热能, 使气化裂化筒内的液态乙醇受热气相的同时, 并 在催化剂作用下, 产生裂化反应, 裂化形成的燃料气体, 再供给发动机的乙 醇-汽油汉燃料汽车燃料供给装置。  The object of the present invention is to provide a simple structure, a gasification cracking cylinder is arranged outside the engine, and the heat energy of the exhaust gas of the engine is fully utilized, and the liquid ethanol in the gasification cracking cylinder is heated and vaporized, and the cracking reaction is generated under the action of the catalyst. The fuel gas formed by cracking is supplied to the ethanol-gasoline fuel vehicle fuel supply device of the engine.
本发明的目的所采取的技术方案是, 发动机的进气歧管装配有带空气滤 清器的汽化器和排气歧管, 带有汽油表的汽油箱连通汽油管一端, 汽油管的 另一端连通汽油阀输入端, 汽油阀输出端连接汽油滤清器输入端, 汽油滤清 器输出端连接带油杯的汽油泵输入端, 其特征是带有乙醇表的乙醇箱箱底壁 连通乙醇阀输入端, 乙醇阀输出端连通汽油阔与汽油滤清器之间油管; 汽油 泵输出端连通气化裂化筒的乙醇进料管; 气化裂化筒的气化裂化气输出管连 通带夹层的乙醇气管一端, 带夹层的乙醇气管另一端连通汽化器的输人端; 螺栓穿过气化裂化筒上端的法兰盘的孔和排气歧管输出法兰盘的孔与螺母啮 合, 螺栓穿过气化裂化筒下端的法兰盘的孔和消声器输入连接法兰盘的孔与 螺母啮合。 The technical solution adopted by the object of the present invention is that the intake manifold of the engine is equipped with a vaporizer with an air cleaner and an exhaust manifold, and a gasoline tank with a fuel gauge is connected to one end of the gasoline tube, and the other end of the gasoline tube is connected. At the input end of the gasoline valve, the output end of the gasoline valve is connected to the input end of the gasoline filter, and the output end of the gasoline filter is connected to the input end of the gasoline pump with the oil cup, which is characterized in that the bottom wall of the ethanol tank with the ethanol meter is connected to the input end of the ethanol valve. The output end of the ethanol valve is connected to the oil pipe between the gasoline gas and the gasoline filter; the output end of the gasoline pump is connected to the ethanol feed pipe of the gasification cracking cylinder; the gasification cracking gas output of the gasification cracking cylinder is connected One end of the ethanol pipe of the interlayer interlayer, the other end of the ethanol pipe with the interlayer is connected to the input end of the vaporizer; the bolt passes through the hole of the flange of the upper end of the gasification cracking cylinder and the hole of the exhaust manifold output flange engages with the nut , the bolt passes through the hole of the flange of the lower end of the gasification cracking cylinder and the hole of the muffler input connection flange engages with the nut.
本发明, 气化裂化筒的上、 下法兰盘之间从内向外焊接有内筒、 中筒、 外筒, 外筒与中筒之间填充有保温层, 中筒与内筒之间形成环形排气通道, 环形排气通道的上、 下法兰盘有孔, 乙醇进料管穿过外筒、 中筒、 内筒的下 部管壁焊接连接, 气化裂化气输出管穿过外筒、 中筒、 内筒的上部管壁焊接 连接, 下法兰盘上端面内筒下部由外向内依次放有带孔的内衬套和带电阻丝 的预热电阻盒, 预热电阻盒上端放置有隔离板, 内衬套上端依次放置金属网 板四层、 催化剂装置层四层和衬套四层, 在最上一层的衬套的孔对着气化裂 化输出管, 在最下一层的衬套的孔对着乙醇进料管。  According to the present invention, an inner cylinder, a middle cylinder and an outer cylinder are welded from the inner and outer sides of the upper and lower flanges of the gasification cracking cylinder, and an insulation layer is filled between the outer cylinder and the middle cylinder, and a middle layer is formed between the inner cylinder and the inner cylinder. The annular exhaust passage has a hole in the upper and lower flanges of the annular exhaust passage, and the ethanol feed pipe is welded through the outer tube, the middle cylinder, and the lower tube wall of the inner cylinder, and the gasification cracking gas output pipe passes through the outer cylinder The upper tube wall of the middle tube and the inner tube are welded and connected, and the lower part of the inner tube of the lower flange is provided with an inner bushing with a hole and a preheating resistance box with a resistance wire in the outer portion from the outer to the inner side, and the upper end of the preheating resistance box is placed. There is a separating plate, four layers of metal mesh plates, four layers of catalyst device layers and four layers of bushings are placed in the upper end of the inner bushing, and the holes of the bushing in the uppermost layer face the gasification cracking output pipe, in the lowermost layer. The bore of the liner faces the ethanol feed tube.
本发明, 从下往上第一层催化剂装置层是铂丝扎在金属网板上。  In the present invention, the first layer of the catalyst device layer from the bottom to the top is platinum wire on the metal mesh plate.
本发明, 从下往上第二层催化剂装置层上放置有氧化铜。  In the present invention, copper oxide is placed on the second layer of the catalyst device layer from the bottom to the top.
本发明, 从下往上第三层催化剂装置层上放置有四氧化三铁粉。 . 本发明, 从下往上第四层催化剂装置层上放置有二氧化钛粉。  In the present invention, ferroferric oxide powder is placed on the third layer of the catalyst device layer from the bottom to the top. In the present invention, titanium dioxide powder is placed on the fourth layer of the catalyst device layer from the bottom to the top.
内燃发动机目前使用的汽油、 柴油虽然是液体燃料, 但它们在发动机内 的燃烧, 却必须在气相条件下进行, 也就是说液态的燃料进入发动机气缸后, 首先是吸收热量(即汽化潜热), 进行气化相变, 第二步才是气相状态下的燃 烧。 本发明则将乙醇液体燃料, 在进入发动机汽缸前首先进行气化, 将汽化 潜热在汽缸以外幹放, 减轻发动机内的热负荷损失, 气相燃料又可以均匀地 与其他品种的气相燃料相混合, 与进气道进入的空气均勾地混合。 本发明是 利用发动机的排气热能, (占发动机总能耗的 35%左右, 排气温度汽油机一般 7 00 °C -800 °C , 柴油机一般 600 °C - 700 °C ), 加以充分利用, 在气化裂化筒中, 进行乙醇等液体燃料的气化。 乙醇气化后, 在气相乙醇燃气中, 在大于 360 °C - 5 0 (TC的筒内温度条件下, 将设置催化剂: 可有氧化铜、 四氧化三铁、 二 氧化钛、 铂、 二氧化钌等, 使气态的乙醇产生如下裂化反应: Although gasoline and diesel currently used in internal combustion engines are liquid fuels, their combustion in the engine must be carried out under gas phase conditions. That is to say, after the liquid fuel enters the engine cylinders, the first is to absorb heat (ie, latent heat of vaporization). The gasification phase change is carried out, and the second step is the combustion in the gas phase state. The invention firstly vaporizes the ethanol liquid fuel before entering the engine cylinder, and releases the latent heat of vaporization outside the cylinder to reduce the heat load loss in the engine, and the gas phase fuel can be evenly mixed with the gas fuel of other varieties. The air entering the air inlet is mixed with the air. The invention utilizes the exhaust heat energy of the engine, which accounts for about 35% of the total energy consumption of the engine, the exhaust gas temperature is generally 700 ° C -800 ° C, and the diesel engine is generally 600 ° C - 700 ° C. In the gasification cracking cylinder, gasification of a liquid fuel such as ethanol is performed. After the gasification of ethanol, in the gas phase ethanol gas, at a temperature higher than 360 ° C - 5 0 (TC internal temperature, the catalyst will be provided: there may be copper oxide, triiron tetroxide, titanium dioxide, platinum, cerium oxide, etc. , the gaseous ethanol produces the following cracking reaction:
催化  Catalysis
C2H60 + 1/202 3H2 +2C0 C 2 H 6 0 + 1/20 2 3H 2 +2C0
Δ 裂化产生燃料气体, 供给发动机。  Δ cracking produces fuel gas that is supplied to the engine.
本发明具有结构简单紧凑, 制作装配方便, 在现有发动机基础上装置本 发明, 其费用低, 采用乙醇是一种再生能源, 所排出的废气有利于环保, 也 可以对汽油-乙醇气的用量按任意比例搭配, 也可以烧纯乙醇' 或烧纯汽油。 在使用前对预热电阻盒内电阻丝通电加热, 使气化裂化筒筒内有一定温度, 便于气化、 裂化反应, 待温度恒定后, 关掉电源, 利用发动机排出废气温度 来恒温。 四、 附图说明 The invention has the advantages of simple and compact structure, convenient manufacture and assembly, and the invention is installed on the basis of the existing engine, and the cost is low. The use of ethanol is a renewable energy source, and the exhaust gas discharged is favorable for environmental protection. You can mix gasoline-ethanol gas in any ratio, or you can burn pure ethanol or burn pure gasoline. Before use, the resistance wire in the preheating resistance box is electrically heated to make the gasification cracking cylinder have a certain temperature, which is convenient for gasification and cracking reaction. After the temperature is constant, the power is turned off, and the temperature of the exhaust gas is exhausted by the engine to be constant. Fourth, the description of the drawings
下面结合附图进一步说明本发明。  The invention will now be further described with reference to the accompanying drawings.
图 1是本发明结构示意图;  Figure 1 is a schematic view of the structure of the present invention;
图 2是本发明气化裂化筒剖视结构示意图。  2 is a schematic cross-sectional view showing the gasification cracking cylinder of the present invention.
图中: 卜汽油表 2-空气滤清器 3-汽化器 4-进气歧管 5-排气歧管 6 -汽油泵 7 -油杯 8-汽油滤清器 9-消声器 1 0-汽油管 11-汽油箱 12-汽油阀 1 3-乙醇阀 14-乙醇箱 I 5-乙醇表 16-乙醇管 I 7-气化裂化 筒 18-发动机 19-带夹层的乙醇气管 20-外筒 21 -内筒 22 -隔离板 23-预热电阻盒 24-内衬套 25-乙醇进料管 26-环形排气通道 27-衬套 28 -中筒 29-保温层 30 -气化裂化气输出管 31-法兰盘 32-金属网板 33 -催化剂装置层 五、 具体实施方式 In the picture: 卜油表2-air filter 3-vaporizer 4-intake manifold 5 - exhaust manifold 6 - petrol pump 7 - oil cup 8 - fuel filter 9 - muffler 1 0 - petrol pipe 11 - Gasoline tank 12 - Gasoline valve 1 3-ethanol valve 14 - Ethanol tank I 5 - Ethanol table 16 - Ethanol tube I 7 - Gasification cracking cylinder 18 - Engine 19 - Laminated ethanol tube 20 - Outer tube 21 - Inner tube 22 - Isolation plate 23 - Preheating resistance box 24 - Inner bushing 25 - Ethanol feed pipe 26 - Annular exhaust passage 2 7 - Bushing 28 - Intermediate cylinder 29 - Insulation layer 30 - Gasification cracking gas outlet pipe 31- Flange 32 - metal mesh plate 33 - catalyst device layer 5, a specific embodiment
如图 1、 图 2所示, 发动机 18的进 歧管 4装配有带空气滤清器 1的汽 化器 3和排气歧管 5 , 带有汽油表 1的汽油箱 11连通汽油管 10—端, 汽油管 10的另一端连通汽油阔 12输入端, 汽油阀 12输出端连接汽油滤清器 8输入 端, 汽油滤清器 8输出端连接带油杯 7的汽油泵 6输入端, 其带有乙醇表 15 的乙醇箱 14箱底壁连通乙醇阀 13输入端, 乙醇阀 13输出端连通汽油阀 12 与汽油滤清器 8之间油管; 汽油泵 6输出端连通气化裂化筒 17的乙醇进料管 '25 ; 气化裂化筒 17的气化裂化气输出管 30连通带夹层的乙醇气管 19一端, 带夹层的乙醇气管 19另一端连通汽化器 3的输入端;螺栓穿过气化裂化筒 17 上端的法兰盘 31的孔和排气歧管 5输出法兰盘的孔与螺母啮合, 螺栓穿过气 化裂化筒 17下端的法兰盘 31的孔和消声器 9输入连接法兰盘的孔与螺母啮 合。 气化裂化筒 17的上、 下法兰盘 31之间从内向外焊接有内筒 21、 中筒 28、 外筒 20 , 外筒 20与中筒 28之间填充有保温层 29 , 中筒 28与内筒 21之间形 成环形排气通道 26, 环形排气通道 26 '的上、 下法兰盘 31 As shown in FIG. 1 and FIG. 2, the manifold 4 of the engine 18 is equipped with a vaporizer 3 with an air cleaner 1 and an exhaust manifold 5, and a gasoline tank 11 with a fuel gauge 1 is connected to the 10-end of the gasoline tube. The other end of the gasoline pipe 10 is connected to the gasoline wide 12 input end, the output of the gasoline valve 12 is connected to the input end of the gasoline filter 8 , and the output end of the gasoline filter 8 is connected to the input end of the gasoline pump 6 with the oil cup 7 , which carries the ethanol The bottom wall of the ethanol tank 14 of Table 15 is connected to the input end of the ethanol valve 13 , the output end of the ethanol valve 13 is connected to the oil pipe between the gasoline valve 12 and the gasoline filter 8; the output end of the gasoline pump 6 is connected to the ethanol feed pipe of the gasification cracking cylinder 17 '25; the gasification cracking gas output pipe 30 of the gasification cracking cylinder 17 communicates with one end of the intercalated ethanol gas pipe 19, and the other end of the interlayered ethanol gas pipe 19 communicates with the input end of the vaporizer 3; the bolt passes through the upper end of the gasification cracking cylinder 17 flange nut bore hole 5 and the output manifold flange 3 engages a bolt through the holes 17 and the lower end of the muffler vaporized cracked cylinder flange 31 of the input aperture 9 is connected to the flange The nut is engaged. Gasifier cracking cylinder 17, between the lower flange 31 from the inside out has a welded inner tube 21, the tube 28, the outer cylinder 20, and the outer cylinder 20 has the cylinder 28 is filled between the insulating layer 29, An annular exhaust passage 26 is formed between the middle cylinder 28 and the inner cylinder 21, and the upper and lower flanges 31 of the annular exhaust passage 26'
有孔, 乙醇进料管 25穿过外筒 20、 中筒 28、 内筒 的下部管壁焊接连接, 气化裂化气输出管 30穿过外筒 20、 中筒 28、 内筒 的上部管壁焊接连接, 下法兰盘 31上端面内筒 21下部由外向内依次放有带孔的内衬套 24和带电阻 丝的预热电阻盒 23, 预热电阻盒 23上端放置有隔离板 22, 内衬套 24上端依 次放置金属网板 32四层、 催化剂装置层 33四层和衬套 27四层, 在最上一层 的衬套 27的孔对着气化裂化输出管 30, 在最下一层的衬套 27的孔对着乙醇 进料管 25。 从下往上第一层催化剂装置层 33是铂丝扎在金属网板 32上。 从 下往上第二层催化剂装置层 33上放置有氧化铜。 从下往上第三层催化剂装置 层 33上放置有四 化三铁粉。 从下往上第四层催化剂装置层 33上放置有二 氧化钛粉。 With a hole, the ethanol feed pipe 25 is welded through the outer cylinder 20, the middle cylinder 28, and the lower pipe wall of the inner cylinder, and the gasification cracking gas output pipe 30 passes through the outer cylinder 20, the middle cylinder 28, and the upper tube of the inner cylinder. Wall welded joint, lower flange 3 1 upper end inner cylinder 2 1 lower part from the outside to the inside is placed with a perforated inner bushing 24 and a resistor The preheating resistor box 23 of the wire, the upper end of the preheating resistor box 23 is provided with a separating plate 22, and the upper end of the inner bushing 24 is sequentially placed with four layers of the metal mesh plate 32, four layers of the catalyst device layer 33 and four layers of the bushing 27, at the top The hole of the bushing 27 of the layer faces the gasification cracking output pipe 30, and the hole of the bushing 27 of the lowermost layer faces the ethanol feed pipe 25. From the bottom to the top, the first layer of the catalyst device layer 33 is platinum wire on the metal mesh plate 32. Copper oxide is placed on the second layer of the catalyst device layer 33 from the bottom to the top. Four iron triiron powder was placed on the third layer of the catalyst device layer 33 from the bottom to the top. Titanium dioxide powder was placed on the fourth layer of the catalyst device layer 33 from the bottom to the top.
保温层 29可采用硅酸铝纤维或膨张 3个珠岩。  The insulating layer 29 may be made of aluminum silicate fiber or expanded by 3 beads.

Claims

权 利 要 求 Rights request
1、 一种乙醇-汽油双燃料汽车燃料供给装置, 发动机(18 ) 的进气歧管 (4)装配有带空气滤清器(2 ) 的汽化器(3)和排气歧管 (5), 带有汽油表 ( 1) 的汽油箱 (11)连通汽油管 (10)—端, 汽油管 (10) 的另一端连通汽 油阀 (12)输入端, 汽油阀 (12)输出端连接汽油滤清器(8)输入端, 汽油 滤清器(8)输出端连接带油杯(7) 的汽油泵(6)输入端, 其特征是带有乙 醇表(15 ) 的乙醇箱 (14 ) 箱底壁连通乙醇阀 (I3)输入端, 乙醇阀 (I3) 输出端连通汽油阀 (12) 与汽油滤清器 (8)之间油管; 汽油泵(6 )输出端 连通气化裂化筒 (17) 的乙醇进料管 (25); 气化裂化筒 (17) 的气化裂化气 输出管 (30)连通带夹层的乙醇气管 (19) 一端, 带夹层的乙醇气管 (I9 ) 另一端连通汽化器(3) 的输入端; 螺栓穿过气化裂化筒 (17 )上端的法兰盘 ( 31 ) 的孔和排气歧管 (5)输出法兰盘的孔与螺母啮合, 螺栓穿过气化裂化 筒 (17) 下端的法兰盘(31) 的孔和消声器(9)输入连接法兰盘的孔与螺母 啮合。 1. An ethanol-gasoline dual fuel vehicle fuel supply device, an intake manifold (4) of an engine (18) equipped with a vaporizer ( 3 ) with an air filter (2) and an exhaust manifold (5), The fuel tank (11) with the fuel gauge (1) is connected to the gasoline pipe (10)-end, the other end of the gasoline pipe (10) is connected to the input end of the gasoline valve (12), and the output of the gasoline valve (12) is connected to the gasoline filter. At the input end of the (8), the output of the fuel filter (8) is connected to the input end of the gasoline pump (6) with the oil cup (7), which is characterized by an ethanol tank (14) with an ethanol meter (15). ethanol communication valve (I 3) input, ethanol valve (I 3) the output of the gasoline communication valve (12) and the fuel filter (8) between the tubing; fuel pump (6) communicating the output of the gasification cracking tube (17 The ethanol feed pipe ( 25 ); the gasification cracking gas output pipe (30) of the gasification cracking cylinder (17) communicates with the one end of the intercalated ethanol gas pipe (19), the interlayer of the ethanol gas pipe (I 9 ) is connected The input end of the carburetor (3); the hole through the flange (31) of the upper end of the gasification cracking cylinder (17) and the hole of the output flange of the exhaust manifold (5) Engaged with the nut, the bolt passes through the hole of the flange (31) at the lower end of the gasification cracking cylinder (17) and the hole of the muffler (9) input connection flange engages with the nut.
2、 根据权利要求 1 所述的一种乙醇 -汽油双燃料汽车燃料供给装置, 其 特征是气化裂化筒( 17 )的上、下法兰盘( 31 )之间从内向外焊接有内筒( 21 )、 中筒 8)、 外筒 0), 外筒 (20) 与中筒 U8)之间填充有保温层 U9), 中筒 8) 与内筒 ( )之间形成环形排气通道 ( 26 ), 环形排气通道(26) 的上、 下法兰盘(31)有孔, 乙醇进料管 (25) 穿过外筒 (20)、 中筒 8)、 内筒 (21 ) 的下部管壁悍接连接, 气化裂化气输出管 (30) 穿过外筒 (20)、 中筒(28)、 内筒(21 )的上部管壁焊接连接, 下法兰盘(31 )上端面内筒(21 ) 下部由外向内 ^(衣次放有带孔的内衬套(24)和带电阻丝的预热电阻盒(23), 预热电阻盒 U3)上端放置有隔离板(22), 内衬套(24)上端依次放置金属 网板( 32) 四层、 催化剂装置层 (33) 四层和衬套 四层, 在最上一层 的衬套 (27) 的孔对着气化裂化输出管 ( 30), 在最下一层的衬套 (27) 的孔 对着乙醇进料管 (25)。 2. An ethanol-gasoline dual fuel automobile fuel supply apparatus according to claim 1, wherein the upper and lower flanges (31) of the gasification cracking cylinder (17) are welded with inner cylinders from the inside to the outside. (21), the middle cylinder 8), the outer cylinder 0), the outer cylinder ( 20 ) and the middle cylinder U8) are filled with the insulation layer U9), and the middle cylinder 8) forms an annular exhaust passage with the inner cylinder ( ) (26), the annular exhaust passage (26) and lower flange (31) with holes, ethanol feed tube (25) through the outer cylinder (20), the cylinder 8), the inner tube (21 The lower pipe wall is connected, and the gasification cracking gas outlet pipe (30) is welded through the outer pipe (20), the middle cylinder (28), the upper pipe wall of the inner cylinder (21), and the lower flange (31) The upper end inner tube (21) is placed from the outside to the inside (the inner bushing (24) with the hole and the preheating resistor box (23) with the resistance wire, and the upper end of the preheating resistor box U3) is isolated. The plate (2 2 ), the upper end of the inner bushing (24) is placed with four layers of metal mesh plates ( 32 ), four layers of catalyst device layers ( 33 ) and four layers of bushings, and holes in the uppermost bushing (27). Against the gasification cracking output tube (30), Liner (27) of the lowermost layer facing hole ethanol feed tube (25).
3、 根据权利要求 1 所述的一种乙醇-汽油双燃料汽车燃料供给装置, 其 特征是从下往上第一层催化剂装置层(33)是铂丝扎在金属网板(32)上。  An ethanol-gasoline dual fuel automobile fuel supply apparatus according to claim 1, wherein the first layer of the catalyst device layer (33) is platinum wire entangled on the metal mesh plate (32).
4、 根据权利要求 1 所述的一种乙醇 -汽油双燃料汽车燃料供给装置, 其 特征是从下往上第二层催化剂装置层(33)上放置有氧化铜。  An ethanol-gasoline dual fuel automobile fuel supply apparatus according to claim 1, wherein copper oxide is placed on the second layer of the catalyst device layer (33) from the bottom to the top.
5、 根据权利要求 1 所述的一种乙醇-汽油双燃料汽车燃料供给装置, 其 特征是从下往上第三层催化剂装置层(33)上放置有四氧化三铁粉。 5. An ethanol-gasoline dual fuel automobile fuel supply apparatus according to claim 1, wherein a ferroferric oxide powder is placed on the third layer of the catalyst device layer ( 33 ) from the bottom to the top.
6、 根据权利要求 1 所述的一种乙醇 -汽油双燃料汽车燃料供给装置, 其 特征是从下往上第四层催化剂装置层(33)上放置有二氧化钛粉。 6. An ethanol-gasoline dual fuel automobile fuel supply apparatus according to claim 1, wherein titanium dioxide powder is placed on the fourth layer of the catalyst device layer ( 33 ) from the bottom to the top.
PCT/CN2007/002694 2006-09-29 2007-09-11 Alcohol-gasoline dual-fuel supply device for vehicle WO2008043247A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CNB2006100951801A CN100417802C (en) 2006-09-29 2006-09-29 Fuel-feeding device of alcohol-gasoline double fuel automobile
CN200610095180.1 2006-09-29

Publications (1)

Publication Number Publication Date
WO2008043247A1 true WO2008043247A1 (en) 2008-04-17

Family

ID=37953983

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2007/002694 WO2008043247A1 (en) 2006-09-29 2007-09-11 Alcohol-gasoline dual-fuel supply device for vehicle

Country Status (2)

Country Link
CN (1) CN100417802C (en)
WO (1) WO2008043247A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102322376A (en) * 2011-07-18 2012-01-18 张忠宇 The mixed method of Vehicular alcohol Fuel Petroleum and device
KR101745272B1 (en) * 2016-07-27 2017-06-08 현대자동차주식회사 System for filling lpg of lpg vehicle using auxiliary bombe
CN111674560A (en) * 2020-06-19 2020-09-18 四川省天域航通科技有限公司 Unmanned aerial vehicle oil circuit repacking structure

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4210103A (en) * 1977-04-04 1980-07-01 Southwest Research Institute Fuel system for and a method of operating a spark-ignited internal combustion engine
US4408572A (en) * 1981-07-27 1983-10-11 Conoco Inc. Ether cold starter in alcohol fuel treatment and distribution apparatus and method
CN2050083U (en) * 1989-03-30 1989-12-27 昆明工学院 Nature-changing device for vehicle alcohols
US5097803A (en) * 1989-08-22 1992-03-24 Her Majesty The Queen In Right Of New Zealand Fuel supply and control system for compression ignition engines
CN2570481Y (en) * 2002-09-18 2003-09-03 姜忠扬 Omnivorous engine

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4612905A (en) * 1980-01-26 1986-09-23 Motoren-Werke Mannheim Ag, Vorm. Benz Stat. Motorenba Fuel injection apparatus
CN2760266Y (en) * 2004-09-09 2006-02-22 中国石油西南油气田分公司川西北气矿 Carbinol-gasoline dual-fuel engine
CN1811148A (en) * 2005-01-27 2006-08-02 北京利空燃料与汽车研究院 Alcohol fuel cracking device for gas turbine
CN1702316A (en) * 2005-05-27 2005-11-30 余浩洋 Dual fuel feed method and system for automobile

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4210103A (en) * 1977-04-04 1980-07-01 Southwest Research Institute Fuel system for and a method of operating a spark-ignited internal combustion engine
US4408572A (en) * 1981-07-27 1983-10-11 Conoco Inc. Ether cold starter in alcohol fuel treatment and distribution apparatus and method
CN2050083U (en) * 1989-03-30 1989-12-27 昆明工学院 Nature-changing device for vehicle alcohols
US5097803A (en) * 1989-08-22 1992-03-24 Her Majesty The Queen In Right Of New Zealand Fuel supply and control system for compression ignition engines
CN2570481Y (en) * 2002-09-18 2003-09-03 姜忠扬 Omnivorous engine

Also Published As

Publication number Publication date
CN1936310A (en) 2007-03-28
CN100417802C (en) 2008-09-10

Similar Documents

Publication Publication Date Title
Ahmed et al. Environment-friendly novel fuel additives: Investigation of the effects of graphite nanoparticles on performance and regulated gaseous emissions of CI engine
CN100439697C (en) Discharging system of diesel engine with mechanism for reconditioning fuel
CN103352777A (en) Hydrogen engine system
CN101251044A (en) Apparatus for petrol engine combustion methanol cracking gas
PT1662113E (en) Apparatus for operation of engines
Bo et al. Study of fuel consumption when introducing DME or ethanol into diesel engine
CN203321706U (en) Hydrogen energy engine system
CN105569883A (en) Methanol decomposition reactor based on waste heat of engine
CN107435601A (en) Alcohol hydrogen fuel combination dynamical system
WO2008043247A1 (en) Alcohol-gasoline dual-fuel supply device for vehicle
Bromberg et al. Alcohol fueled heavy duty vehicles using clean, high efficiency engines
CN201679586U (en) Reacting device for thermally cracking methanol by utilizing residue heat of engine exhaust gas
CN102039814A (en) Hydrogen vehicle capable of producing hydrogen by alcohol cracking
CN111305947A (en) Methanol and hydrogen dual-fuel power system
CN2883692Y (en) Low pollusion methyl alcohol engine
CN201610790U (en) Hydrogen-fuel mixed-combustion engine
US4395998A (en) Multi-fuel gasifier system for spark ignition engines
CN1821558A (en) Method for fuel methanol of igniting type engine
WO2007128200A1 (en) Catalytic fuel oil economizer in oil lines of motor vehicle
CN101699048A (en) Engine device with mixed fuel of petrol and hydrogen
CN101285588B (en) Fuel economizing device
Najjar Alternative fuels for spark ignition engines
CN2494771Y (en) Alcohol and hydrogen mixted combustion engine
CN207122373U (en) Alcohol hydrogen fuel combination dynamical system
Li et al. Effects of Butanol Isomers on the Combustion Characteristics and Particle Number Emissions of a GDI Engine

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07816314

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112 (1) EPC - EPO FORM 1205A DATED 13.07.09

122 Ep: pct application non-entry in european phase

Ref document number: 07816314

Country of ref document: EP

Kind code of ref document: A1