WO2008032506A1

WO2008032506A1 - Mineral water and process for producing the mineral water

Info

Publication number: WO2008032506A1
Application number: PCT/JP2007/065315
Authority: WO
Inventors: Osamu Hirota; Morio Sekiguchi; Yoshinari Kato; Kenji Watanabe
Original assignee: Osamu Hirota; Morio Sekiguchi; Yoshinari Kato; Kenji Watanabe
Priority date: 2006-09-15
Filing date: 2007-07-30
Publication date: 2008-03-20
Also published as: JP5152452B2; JP2008068237A

Abstract

Mineral water which contains mineral ingredients released from a soft porous ancient marine humic substance and including a calcium ingredient, the calcium ingredient accounting for at least 90% of the mineral ingredients. The mineral water contains SiO2, Al, Fe, Ca, Mg, K, Ti, P, Na, and Mn which are mineral ingredients released from a soft porous ancient marine humic substance and in which the calcium ingredient accounts for 90 wt.% or more of the total amount of the mineral ingredients. Also provided is a process for mineral water production which comprises passing raw water through superposed layers of a soft porous ancient marine humic substance ceramic obtained by adhering a powder of a soft porous ancient marine humic substance in a layer arrangement to a particulate ore of a soft porous ancient marine humic substance and burning them and through superposed layers comprising a burned powder of a soft porous ancient marine humic substance to dissolve mineral ingredients, i.e., SiO2, Al, Fe, Ca, Mg, K, Ti, P, Na, Mn, Co, Ba, Zn, Sn, V, Ni, and Cu, in the raw water. Thus, mineral water containing the calcium ingredient in an amount of 90 wt.% or larger based on the total amount of the mineral ingredients is produced.

Description

Description Mineral water and method for producing the mineral water Technical Field

The present invention relates to a mineral water obtained by eluting a mineral component from a soft porous ancient marine humus and a method for producing the mineral water. Background art

As is well known, the soft porous ancient marine humus, aluminum oxide (A1 ₂ 0 ₃₎ 13. 0 wt%, silicon dioxide (Si0 ₂₎ 55.0 wt%, calcium oxide (CaO) 3.6 wt%, acid iron (Fe ₂ 0 ₃ ) 4.1% by weight, magnesium oxide (MgO) 1.6% by weight, manganese oxide (M ηθ) 0.04% by weight, sodium oxide (Na ₂ 0) 0.05% by weight, phosphorus oxide (P ₂ 0 ₅ ) 0.07% by weight %, Titanium oxide (TiO) 0.16 wt%, Cobalt oxide (Co0) 0.06 wt%, Sulfur (S) 1.1 wt%, Potassium (K) 0.473 wt%, Besides, barium, copper, nickel, It contains tin, strontium, vanadium, zinc, etc. and is used as a mineral eluent.

In addition, a calcined bioceramic obtained by mixing and calcining the soft porous ancient marine humus and Si ₆₀ ₁₈ is used as a mineral water production or soil improver, and the calcined bioceramic is placed in distilled circulating water. Silica anhydride (Si0 ₂ ) 6.6 mg / l, aluminum (Al) 0.76 mg / l, iron (Fe) 0.05 mg, calcium (Ca) 18 mg / l, magnesium (Mg) 0.64 mg / l, potassium (K) 0.68mg, titanium (Ti) 0. lmg / l, phosphorus (P) 0.1 3mg / l, sodium (Na) 1.7mg / l, manganese (Mn) 0.01mg / l, cobalt (Co) 0.01 mg / l, Barium (Ba) 0.01 mg / l, Zinc (Zn) 0.01 mg / l, Tin (Sn) 0. lmg / l, Panaji A water treatment method has been proposed to elute the minerals of hum (V) 0. lmg / l, nickel (Ni) 0. Olmg / 1 and copper (Cu) 0. Olmg / 1. 9 2 8 0). Mineral water obtained by the above water treatment method is silicic anhydride (Si0 ₂ ) 6.6 mg / l, aluminum (A1) 0.76 mg, iron (Fe) 0.05 mg / l, calcium (Ca) 18 mg / l , Magnesium (Mg) 0.64 mg / l, Potassium (K) 0.668 _mg / l, Titanium (Ti) 0.1 mg / l, Phosphorus (P) 0.13 mg / l, Sodium (Na) 1. 7mg / l, Manganese (Mn) 0. Olmg / 1, Cobalt (Co) 0. Olmg / 1, Barium (Ba) 0. Olmg / 1, Zinc (Zn) 0. Olmg / 1, Tin (Sn) 0. Contains lmg / l, Panadium (V) 0. lmg / l, Nickel (Ni) 0. Olmg / 1 and Copper (Cu) 0. Olmg / 1. each mineral components in the case of the Si0 ₂ of about 22.8 wt% relative to該全body weight 28. 92mg / l, A1 is about 2.6 wt%, Fe is from about 0.2 wt%, Ca of about 62 2% by weight, Mg about 2.2%, K about 2.4%, Ti about 0.3%, P about 0.4%, about 5.9%, Mn Is about 0.03 wt% Co is about 0.03 wt%, Ba is about 0.03 wt%, Zn is about 0.03 wt%, Sn is about 0.3 wt%, V is about 0.3 wt%, M is about 0 03 wt% and Cu was about 0.03 wt%.

The present inventor also produced mineral water by eluting mineral components using soft porous ancient marine humus, and gave the mineral water to experimental animals such as mice. There were significant differences in growth between animals. It is not clear what effect the mineral water has on animal growth, but it is compared with the mineral water component obtained by the water treatment method described in Japanese Patent Laid-Open No. 6-9280. As a result, the mineral water contained an extremely large amount of Ca component.

Therefore, the present invention provides mineral water in which the Ca component in the mineral component eluted from the soft porous ancient marine humus is contained in an amount of 90% or more based on the total amount of the mineral. It is. Disclosure of the invention

Mineral water according to claim 1, wherein the present invention, containing the soft porous ancient marine humus minerals eluted from _{Si0 2, Al, Fe, Ca} , Mg, K, Ti, P, the Na and Mn In addition, the Ca component accounts for 90% or more of the total amount of the mineral component.

Also, mineral water according to claim 2 of the present invention, the soft porous ancient marine humus minerals eluted from _{Si0 2, Al, Fe, Ca} , Mg, K, Ti, P, Na, Mn , Co, Ba, Zn, Sn, V, Ni, and Cu, and the Ca component accounts for 90% or more of the total amount of the mineral component.

Further, the method for producing mineral water according to claim 3 of the present invention is characterized in that raw water is attached to granular raw stone of soft porous ancient marine humus and soft porous ancient marine humus powder is adhered in layers. Mineral components Si0 ₂ , Al, Fe, Ca, Mg, K, Ti, P through the lamination of fired soft porous ancient marine humic ceramics and the soft porous ancient marine humic material Na, Mn, Co, Ba, Zn, Sn, V, Ni and Cu are eluted to produce mineral water containing 90% or more of the Ca component relative to the total amount of the mineral component.

Further, the method for producing mineral water according to claim 4 of the present invention is the method for producing mineral water according to claim 3, wherein the soft porous ancient marine humic ceramics has a diameter of 4 It uses sintered ceramics with a diameter of 5 to 30 mm, in which a soft porous ancient marine humic powder is attached in layers to a ~ 10mm granular rough.

According to the present invention, the Ca component is contained in the mineral component eluted from the soft porous ancient marine humus. Mineral water with more than 90% share can be provided. BEST MODE FOR CARRYING OUT THE INVENTION

Mineral water according to the present embodiment, ₂ of a soft porous ancient marine humus Si0, Al, Fe, Ca, M g, K, Ti, P, Na, Mn, Co, Ba, Zn N Sn, V, The mineral components of Ni and Cu are eluted so that the Ca component accounts for 90% by weight or more of the total amount of the mineral component.

The soft porous ancient marine humus is, for example, seafood, plankton, algae 'seaweeds, etc., which lived in the sea tens of millions of years ago in Tanakakura, Higashishirakawa-gun, Fukushima It can be collected at a fault that is said to be petrified sea mud. The soft porous ancient marine humus contains aluminum oxide (A1 ₂ 0 ₃ ) 13.0 wt%, silicon dioxide (Si0 ₂₎ 55.0 wt%, calcium oxide (CaO) 3. 6 wt%, iron oxide (Fe ₂ 0 ₃₎ 4. 1 wt ^_0/0, magnesium oxide (MgO) 1. 6 wt%, manganese oxide (MnO ) 0.04 wt ^_0/0, oxide Natoriumu (Na ₂ 0) 0. 05% by weight, phosphorylated (P ₂ 0 ₅₎ 0. 07% by weight of titanium oxide (T iO) 0. 16 wt%, cobalt oxide (CoO) 0.06 wt%, Sulfur (S) 1.1 wt%, Powered Rium (K) 0.473 wt%, and Barium (Ba) 0.007 wt%, Copper (Cu) 0 001 wt%, nickel (Ni) 0. 002 weight ⁰ /. , Tin (Sn) 0.006% by weight, strontium (Sr) 0.007% by weight, vanadium (V) 0.003% by weight, zinc (Zn) 0.006% by weight, and the like.

In the mineral component extracted from the soft porous ancient marine humus so that the eluted Ca component accounts for 90% by weight or more of the total amount of the eluted mineral component, Si0 ₂ is 4 to 6 mg / l as a main component, A1 is less than about 0.05mg, Fe is less than about 0.05mg / l, Ca is 160 to 190mg, Mg is 2 to 4mg, K is 2 to 3mg, Ti is less than about 0.05mg / l P is less than about 0.05 mg / l, Na is 0.5 ~l mg / l, Mn is less than about 0. Olmg / 1, Co less than about 0. 01m _g / l, Ba is less than about 0. Olmg / 1, Zn is less than about 0. Olmg / 1, Sn is about 0. Less than Olmg / 1, V is about 0.003 mg / l, Ni is less than about 0. Olmg / 1 and Cu is less than about 0.001 mg / l. For the total weight of 168.764-204.264 mg / l, the Ca component was about 93.02-94.81% by weight. In addition, in the mineral component extracted from the soft porous ancient marine humus so that the eluted Ca component accounts for 90% by weight or more of the total amount of the eluted mineral component, Si 0 ₂ as a main component is 4-6 mg / l, A1 less than about 0.05 mg / l, Fe less than about 0.05 mg, Ca 160-190 mg / l, Mg 2-4 mg / l, K 2-3 mg / l, Ti about 0 It has been confirmed that less than 05 mg / l, P is less than about 0.05 mg / l, Na is 0.5 to 1 mg / 1 and Mn is less than about 0. Olmg / 1. The Ca component was about 93.04 to 94.84% by weight with respect to the total amount of the components 168.71 to 204.21 _mg / l.

The mineral water is a laminate of soft porous ancient marine humic ceramics made by laminating raw water with soft porous ancient marine humic granular raw stones and laminating soft porous ancient marine humic powder in layers. If the mineral component of soft porous ancient marine humus is eluted in the raw water through the laminate composed of the calcined powder of soft porous ancient marine humus, the eluted mineral component (Si0 ₂ , Al, Fe, Ca, Mg, K, Ti ゝ P, Na, Mn, Co, Ba, Zn, Sn, V, Ni, and Cu) Mineral water containing over 90% by weight of dissolved Ca component is generated with respect to the total amount. Can.

As the raw water, distilled water, tap water or well water may be used.

The soft porous ancient marine humic ceramics are prepared by placing granular soft porous ancient marine humic raw stones with a diameter of about 4 to 10 mm in a bowl-shaped iron dish container with a diameter of about 2000 mm, and rotating the bowl-shaped iron dish container at 30 rpm. Applying water in a mist to the extent that the granular rough is moist, and after stopping the spraying, uniformly distribute the powder of soft porous ancient marine humus with a diameter of 0.1 to 1 mm. Sprinkling, using the water droplets attached to the rough as a binder, the spraying and sprinkling process to attach the powder to the rough is repeated to grow it into a ball with a diameter of 5-30 mm, and then the ball is placed in an oxygen atmosphere. It can be obtained by baking at a temperature of 800-900 ° C for 20-40 minutes. That is, the ceramic is obtained by forming a soft porous ancient marine humus powder in a granular soft porous ancient marine humic raw stone in a layered form and firing it. The soft porous ancient marine humic powder is pulverized by drying 10 to 50 kg of the collected soft porous ancient marine humic substance with a tray-type far-infrared dryer (food dryer). Using a vibrating sieve machine, remove the sand and roots with a 4-mesh sieve, then remove further sand, etc. with a 32-mesh sieve, and apply to a 100-mesh sieve to obtain a powder. This can be obtained by evaporating and removing suspended impurities, drying the clay after evaporating with a tray-type far-infrared dryer, and pulverizing it again. In addition, two rollers with different speeds in the container (for example, 60c / s and 80c / s) are contact-reversed, and the soft porous ancient marine humus sampled between the rollers is introduced, It can also be obtained by a method of sucking out dust that has been crushed and powdered and collecting it with a filter.

Furthermore, the soft porous ancient marine humus calcined powder is obtained by calcining the soft porous ancient marine humic powder in an oxygen atmosphere at a temperature of 500 to 600 ° C.

Example:! ~ Five .

Two rollers are contact-reversed at 60c / s and 80c / s, soft porous ancient marine humus sampled between the rollers is inserted, and dust that is crushed by the roller's reversal and dances in powder is sucked out by a filter It was recovered to obtain a powder of 0.1 to 1 diameter of soft porous ancient marine humus. Next, a granular soft porous ancient marine humic raw stone with a diameter of about 4-10 mm Put it in a 2000mm bowl-shaped iron dish container, rotate the bowl-shaped iron dish container at 30rpm, and use the water droplets adhering to the rough as a binder to attach the powder of 0.1 to 1 diameter in a bowl shape. The ball was baked in an oxygen atmosphere at a temperature of 800 to 900 ° C. for 20 to 40 minutes to obtain a soft porous ancient marine humic ceramic having a diameter of 5 to 30 mm. Further, the powder having a diameter of 1 to 1 mm was fired in an oxygen atmosphere at a temperature of 500 to 600 ° C. to obtain a fired powder.

Subsequently, tap water is passed through the laminate of the soft porous ancient marine humic ceramics and the laminate composed of the calcined powder by a patch treatment of 5 to 10 liters, and the soft porous ancient ocean is passed into the water. minerals Si0 ₂ of humus, Al, Fe, Ca, M g, K, Ti, to produce P, Na, Mn, Co, Ba, Zn, Sn, V, each mineral water to elute the Ni and Cu (Example 1: 5 mm diameter ceramics, Example 2: 8 thigh ceramics, Example 3: 10 mm diameter ceramics, Example 4: 20 mm diameter ceramics, Example 5: 30 mm diameter ceramics). The eluted mineral components in Examples 1 to 5 are shown in Table 1. Mineral component analysis was performed by a colorimetric method for SiO, Al, Ti, P and Sn, and by atomic absorption spectrophotometry for others.

Comparative Example 1

Mineral composition of soft porous ancient marine humus in tap water by immersing tap water in a layer of granular soft porous ancient marine humus rough with a diameter of about 4-10 mm in a ratio of 5-10 liters Z. _{Si0 2, Al, Fe, Ca} , produced Mg, K, Ti, P, Na, Mn, Co, Ba, Zn, Sn, V, mineral dissolution tap water Ni and Cu was eluted.

Comparative Example 2

Minerals Si0 ₂ of the tap water the 0.. 1 to l mm fired powder consisting laminated immersed at a rate of 5-10 l / min soft porous to the tap water ancient marine humus, Al, Fe, Ca, Mineral-eluting tap water from which Mg,:, Ti, P, Na, Mn, Co, Ba, Zn, Sn, V, Ni and Cu were eluted was generated.

Comparative Example 3

Mineral elution amount described in the publication, which is confirmed by immersing the fired bioceramic described in JP-A-6_9280 in Japan for 2 hours in distilled circulating water.

Table 1 shows the eluted mineral components in Comparative Examples 1 to 3.

As shown in Table 1, the Ca component in Example 1 is 167/1 76.85, that is, 94.43% by weight in the total amount of SiO to Mn mineral, or 167 / 176.904, that is, 94 in the total amount of SiO to Cu mineral. . 40 by weight ^_0/0 170/180. 63, i.e., 94.12% by weight in an Ca component SiO~Mn mineral total amount in example 2, in SiO~Cu mineral total amount 170/180. 684, i.e. 94 09 wt%, Ca component in Example 3 is 174 / 184.77 in total amount of SiO to Mn minerals, ie 94.17 wt%, SiO

174/184 The ~Cu mineral total amount. 824, i.e. 94.14 wt%, the Ca component SiO~Mn mineral total amount in Example 4 178/189. 25, i.e., 94.06 weight ⁰ SiO~Cu minerals The total weight is 178 89.304, ie 94.03 wt%, the Ca component in Example 5 is 181 / 192.89, ie 93.84 wt%, and the total amount of SiO to Cu mineral is SiO1 / Mn mineral total 181/1 92.944, ie 93.81% by weight, Ca component in Comparative Example 1 is 62.8 / 92.93, ie 67.58% by weight, and SiO to Cu mineral 62. 8/92. 984, ie 67. 54 wt%, Ca component in Comparative Example 2 is 155.1 1 / 18.2 in the total amount of SiO to Mn mineral, ie 83. 30 wt%, SiO to Cu mineral total 155. 1/186. 254 in terms of quantity, ie 83. 27% by weight, 3 components in Comparative Example 3 are 18 / 28.67 in total amount of 5 ^ -1 ^ mineral, ie 62. 78% by weight, 18 / 28.9 for total SiO to Cu minerals 11, ie 62.27% by weight. The A1 component, Fe component, Ti component and P component of 0.05> mg 8 are 0.05 mg / l, and the Mn component, Co component, Ba component, Zn component, Sn component and Ni component of 0.01> The mg / l was calculated as 0. Olmg-8, and the 0.001> mg / l of the Cu component was calculated as 0.OOlmg / 1.

Example: Diabetic model mice induced with STZ (streptozotoc in): When ˜5 mineral water was given daily, the blood glucose level dropped from the 6th week and maintained the normal level by the 12th week. There was no change in the model mice to which the eluted mineral water of Comparative Examples 1 to 3 was given. As a result, it was confirmed that the mineral waters of Examples 1 to 5 were useful. According to the present invention, it is possible to provide mineral drinking water in which the Ca component eluted from the soft porous ancient marine humus occupies 90% by weight or more of the total amount of the eluted mineral component.

Claims

The scope of the claims

1. Mineral component eluted from soft porous ancient marine humus Si0 ₂ , Al, Fe, Ca, Mg, K, Ti, P, Na and Mn, and the Ca component is the mineral component Mineral water accounts for over 90% of the total volume.

2. Soft porous ancient minerals eluted from marine humus _{Si0 2, Al, Fe, Ca} , Mg, K, Ti, P, Na, Mn, Co, Ba, Zn, Sn, V, Ni and Cu Mineral water that is contained and the Ca component accounts for 90% or more of the total amount of the mineral component.

3. Lamination of soft porous ancient marine humic ceramics by laminating raw water with soft porous ancient marine humic granular raw stones and laminating soft porous ancient marine humic powder in layers and soft porosity Mineral components Si0 ₂ , Al, Fe, Ca, Mg, K, Ti, P, Na, Mn, Co, Ba, Zn, Sn, V, Ni, and the like through the lamination of calcined powder of ancient marine humus A method for producing mineral water, comprising eluting Cu to produce mineral water containing 90% or more of the above-mentioned components with respect to the total amount of the mineral components.

4. A soft porous ancient marine humic ceramic is a calcined ceramic with a diameter of 5 to 30 in which a powder of soft porous ancient marine humic substance is deposited in layers on a granular raw stone with a diameter of 4 to 10 4. The method for producing mineral water according to item 3 of the above.