WO2008009816A3 - Aromatic sulfinates and sulfonyl halides, and the preparation thereof - Google Patents

Aromatic sulfinates and sulfonyl halides, and the preparation thereof Download PDF

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Publication number
WO2008009816A3
WO2008009816A3 PCT/FR2007/001227 FR2007001227W WO2008009816A3 WO 2008009816 A3 WO2008009816 A3 WO 2008009816A3 FR 2007001227 W FR2007001227 W FR 2007001227W WO 2008009816 A3 WO2008009816 A3 WO 2008009816A3
Authority
WO
WIPO (PCT)
Prior art keywords
preparation
sulfinates
sulfonyl halides
aromatic
halides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2007/001227
Other languages
French (fr)
Other versions
WO2008009816A2 (en
Inventor
Jean-Yves Sanchez
Bernard Langlois
Maurice Medebielle
Fabien Toulgoat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institut Polytechnique de Grenoble
Eras Labo SAS
Universite Claude Bernard Lyon 1
Original Assignee
Institut Polytechnique de Grenoble
Eras Labo SAS
Universite Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institut Polytechnique de Grenoble, Eras Labo SAS, Universite Claude Bernard Lyon 1 filed Critical Institut Polytechnique de Grenoble
Priority to EP07823294A priority Critical patent/EP2064219A2/en
Publication of WO2008009816A2 publication Critical patent/WO2008009816A2/en
Publication of WO2008009816A3 publication Critical patent/WO2008009816A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/70—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78—Halides of sulfonic acids
    • C07C309/79—Halides of sulfonic acids having halosulfonyl groups bound to acyclic carbon atoms
    • C07C309/81—Halides of sulfonic acids having halosulfonyl groups bound to acyclic carbon atoms of an unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/64—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/64—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton
    • C07C323/66—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton containing sulfur atoms of sulfo, esterified sulfo or halosulfonyl groups, bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to aromatic sulfinates and sulfonyl halides, and to the preparation thereof. The halides and the sulfinates are respectively of formulae Ar-Z- (CF2) n-CFRf-SO2Y (I) and [Ar-Z- (CF2) n-CFRf-SO2] m M wherein Z is a sulfide, sulfinyl or sulfonyl group; n is 0 or 1; Rf is F or a perfluoroalkyl group; Ar is an aromatic grouping; Y is Cl, Br or F; M is H, an alkaline metal, an alkaline-earth metal cation, a trivalent or tetravalent metal cation, or an organic cation. The sulfinates can be used for the preparation of sulfonyl halides which can be used for producing sulfonates and sulfonylimidides as salts for an electrolyte.
PCT/FR2007/001227 2006-07-17 2007-07-17 Aromatic sulfinates and sulfonyl halides, and the preparation thereof Ceased WO2008009816A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07823294A EP2064219A2 (en) 2006-07-17 2007-07-17 Aromatic sulfinates and sulfonyl halides, and the preparation thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0606466 2006-07-17
FR0606466A FR2903693B1 (en) 2006-07-17 2006-07-17 SULFINATES AND AROMATIC SULPHONYL HALIDES, AND THEIR PREPARATION.

Publications (2)

Publication Number Publication Date
WO2008009816A2 WO2008009816A2 (en) 2008-01-24
WO2008009816A3 true WO2008009816A3 (en) 2008-04-03

Family

ID=37965045

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/001227 Ceased WO2008009816A2 (en) 2006-07-17 2007-07-17 Aromatic sulfinates and sulfonyl halides, and the preparation thereof

Country Status (3)

Country Link
EP (1) EP2064219A2 (en)
FR (1) FR2903693B1 (en)
WO (1) WO2008009816A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUE031652T2 (en) 2011-02-07 2017-07-28 Scipharm Sarl Novel composition for the treatment of cystic fibrosis
CN115947751B (en) * 2023-03-15 2023-06-16 北京奇点势能科技有限公司 Sufex click chemistry thioether silane coupling agent, preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5086178A (en) * 1990-09-20 1992-02-04 Air Products And Chemicals, Inc. Fluorinated diazabicycloalkane derivatives
EP1447397A1 (en) * 2003-02-17 2004-08-18 Ecole Polytechnique Fédérale de Lausanne Polyfunctional sulfonamides and sulfonates and process for preparing them
WO2004072021A1 (en) * 2003-02-14 2004-08-26 Daikin Industries, Ltd. Fluorosulfonic acid compound, process for producing the same, and use thereof
WO2005113491A1 (en) * 2004-05-07 2005-12-01 E.I. Dupont De Nemours And Company Stable trifluorostyrene containing compounds, and their use in polymer electrolyte membranes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5086178A (en) * 1990-09-20 1992-02-04 Air Products And Chemicals, Inc. Fluorinated diazabicycloalkane derivatives
WO2004072021A1 (en) * 2003-02-14 2004-08-26 Daikin Industries, Ltd. Fluorosulfonic acid compound, process for producing the same, and use thereof
EP1447397A1 (en) * 2003-02-17 2004-08-18 Ecole Polytechnique Fédérale de Lausanne Polyfunctional sulfonamides and sulfonates and process for preparing them
WO2005113491A1 (en) * 2004-05-07 2005-12-01 E.I. Dupont De Nemours And Company Stable trifluorostyrene containing compounds, and their use in polymer electrolyte membranes

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
CHEM QINGYUN ET AL.: "Some reactions of fluorosulfonyldifluoroacetic acid with N-heterocyclic compounds", CHINESE JOURNAL OF CHEMISTRY, vol. 10, no. 4, 1992, pages 350 - 354 *
DATABASE CAPLUS CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; XP002432476, Database accession no. 1993:495414 *
DATABASE CAPLUS CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; XP002432477, Database accession no. 1972:447864 *
G.K. SURYA ET AL.: "Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides and sulfones.", JOURNAL OF ORGANIC CHEMISTRY, vol. 68, 2003, pages 4457 - 4463, XP002432157 *
L. BOUCHEZ ET AL.: "One-pot, tree component synthesis of open-chain, polyfunctional sulfones", SYNTHESIS, no. 2, 2002, pages 225 - 231, XP002432156 *
L. BOUCHEZ ET AL.: "Sulfur dioxide mediated one-pot, three and four-component syntheses of polyfunctional sulfonamides and sulfonic esters: a study of the stereoselectivity of the ene reaction of sulfur dioxide.", JOURNAL OF ORGANIC CHEMISTRY, no. 69, 2004, pages 6413 - 6418, XP002432158 *
N.P. AKTAEV ET AL.: "Fluoro-containing beta-sulfones", IZVESTIYA AKADEMII NAUK SSSR, vol. 2, 1972, pages 366 - 371 *
R. PANDYA ET AL.: "Facile one -pot synthesis of aromatic and heteroaromatic sulfonamides", JOURNAL OF ORGANIC CHEMISTRY, vol. 68, 2003, pages 8274 - 8276, XP002432155 *
R.E. BANKS: "Selectfluor TM reagent F-TEDA-BF4 in action: tamed fluorine at your service", JOURNAL OF FLUORINE CHEMISTRY, vol. 87, 1998, pages 1 - 17, XP002462694 *

Also Published As

Publication number Publication date
WO2008009816A2 (en) 2008-01-24
FR2903693A1 (en) 2008-01-18
EP2064219A2 (en) 2009-06-03
FR2903693B1 (en) 2012-03-30

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