WO2007121074A2 - Annealing of hot rolled steel coils with clam shell furnace - Google Patents

Annealing of hot rolled steel coils with clam shell furnace Download PDF

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Publication number
WO2007121074A2
WO2007121074A2 PCT/US2007/065739 US2007065739W WO2007121074A2 WO 2007121074 A2 WO2007121074 A2 WO 2007121074A2 US 2007065739 W US2007065739 W US 2007065739W WO 2007121074 A2 WO2007121074 A2 WO 2007121074A2
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WO
WIPO (PCT)
Prior art keywords
furnace
annealing
hot rolled
gas
coils
Prior art date
Application number
PCT/US2007/065739
Other languages
French (fr)
Other versions
WO2007121074A3 (en
Inventor
David L. Chase
Original Assignee
Nucor Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/549,286 external-priority patent/US7204894B1/en
Application filed by Nucor Corporation filed Critical Nucor Corporation
Publication of WO2007121074A2 publication Critical patent/WO2007121074A2/en
Publication of WO2007121074A3 publication Critical patent/WO2007121074A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/06Surface hardening
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length

Definitions

  • the hot rolled coils of steel may be placed on circumferential surfaces within a retaining element.
  • the furnace may be capable of providing annealing of the hot rolled steel coil in a cycle time of less than 75 hours at temperature range between about 1200 0 F and about 1650 0 F.
  • the system of the furnace may be capable of establishing a reducing atmosphere that comprises at least one inert gas, and at least one polyolefin gas and at least one inert gas may be nitrogen and at least one polyolefin gas may be propylene.
  • the reducing atmosphere may comprise nitrogen gas in an amount greater than about 90%, hydrogen gas in a range between about 5% to about 7%, and propylene gas in an amount less than about 1%.
  • FIG. 1 is a plan view of the annealing furnace of the present invention
  • FIG. 2 is a front elevation view of the annealing furnace of the present invention
  • FIG. 3 is a cross-section view across of the annealing furnace of the present invention across lines 2-2 of FIG. 2.
  • This invention relates to all hot rolled steel coils wherein the steel includes any commercially available steel, such as, for example, high carbon steel, medium carbon steel, low carbon steel, and high temperature austenite grain coarsening steel such as those described in U.S. Patent No. 7,048,033, which is hereby incorporated by reference.
  • Two grades of steel that can be annealed in the annealing furnace of the present disclosure include high carbon steel, having approximately 0.50 or more weight percent carbon in the total steel, and low carbon steel, having approximately less than 0.02 weight percent carbon in the total steel.
  • the hot roll annealing of the high carbon steel in the furnace provides a softening of the material to permit more efficient downstream processing, for example cold reduction, of the steel coils.
  • the hot roll annealing of low carbon steel coils is also an embodiment of the present disclosure.
  • This type of steel includes a low carbon motor lam grade material that is used in motor lamination of electrical steels for motors of automotive vehicles.
  • the hot roll annealing of the low carbon steel produces the growth of larger grains within the steel which ultimately yields improved magnetic properties. These improvements include lower core loss, which is a reduction in the loss of magnetic field as the magnetic fields are alternated, and higher permeability of the steel that allows more of the magnetic field to permeate it.
  • Another benefit of the hot roll annealing of the low carbon steel is that it softens the steel to promote a more efficient cold rolling process.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)

Abstract

Disclosed is a high temperature annealing furnace (10) for hot rolled steel coils. The furnace (10) of the present invention pivotably rotates about a pivot member (13) between an opened and a closed position. Prior to the annealing step, the hot rolled coils are supported on a retaining element secured to a base portion (1 1) located within the housing (12) of the furnace (10). The hot rolled steel coils may be positioned on the base portion (11) such that the axial opening of each coil is generally horizontal with the base portion (11).

Description

ANNEALING OF HOT ROLLED STEEL COILS WITH CLAM SHELL FURNACE
[0001] This international patent application claims priority to and the benefit of U.S. Patent Application serial number 11/549,286 filed on October 13, 2006, which is a continuation of U.S. Patent Application No. 11/279,192 filed April 10, 2006, both of which are hereby incorporated by reference.
BACKGROUND
[0002] The present invention relates to the field of high temperature annealing of steel coils.
[0003] In the manufacture of flat-rolled steel sheet and strip products, it may often be important to intermittently anneal the material for further cold-rolling operations. It may also be necessary to anneal the material at the finish gauge to render it suitable for fabrication (e.g., stamping and cold forming). Annealing is important because cold reduction elongates the grains of the steel microstructure, distorts the crystal lattice, and induces internal stresses. The steel that results from the cold reduction process is typically very hard and has reduced ductility. The annealing process recrystallizes the cold- worked steel, and if the steel is held at the proper annealing temperature for a sufficient time, the microstructure of the annealed steel will return to substantially undistorted lattices and the steel will be more ductile. Cold- rolled steel and heat-resisting steel sheets can be produced by hot rolling, hot annealing and pickling, cold rolling-finish annealing and pickling (cold-rolled annealing and pickling), and subsequent skin-pass rolling. The finish annealing and pickling procedure generally comprises a continuous annealing, pickling or continuous bright annealing. [0004] Annealing techniques may be divided into two general categories: (a) batch operations, such as conventional box annealing; and (b) continuous operations. In the steelmaking, the softening of flat rolled sheet and strip products is typically accomplished through the use of continuous annealing.
[0005] The continuous annealing process involves unwinding the coil from a payoff reel, continuously feeding the coil through an annealing furnace, and then rewinding the coil on a take-up reel. The annealing furnace is typically electric or gas fired. The steel strip, while traveling through the furnace, is typically heated to a temperature in the range of about 1800 0F to about 2200 0F in the case of austenitic alloys, and to a temperature in the range of about 1400 0F to about 1800 0F for ferritic alloys. The annealing temperatures vary depending upon the particular alloy being annealed and desired microstructure, as well as the end-use of the steel alloy.
[0006] A continuous annealing line is useful for mass production, but may not always appropriate for smaller production runs. Instead of finish annealing (cold-roll annealing) and pickling requiring huge facilities, the use of box annealing (also called "bell annealing" or "batch annealing") may be of economically advantageous in shorter production runs. [0007] Batch coil annealing furnaces (sometimes called "box annealing furnaces" or "bell shaped" furnaces) have been long used and are well known in the industry. In such furnaces steel coils are stacked vertically, edge to edge, on a base, and a removable inner cover is placed over the stacked coils. An outer cover then is placed over the inner cover, and the covers are removably sealed to the base. The outer cover typically contains gas fired burners that heat the inner cover, and in turn radiation heats the stacked coils. Batch coil annealing processes in the steel mill industry typically take about 20 hours to several days to complete. [0008] Prior art annealing furnaces are off-line annealing furnaces. Because of the size and time requirements of annealing, the furnaces are usually not in-line in a steelmaking line. Annealing treatment of metal product in such off-line processes normally involves long cycle times, resulting in low productivity levels, high heat treatment costs and less energy savings.
SUMMARY OF THE DISCLOSURE
[0009] The present invention relates to an annealing furnace for thermal treating of hot rolled steel coils. The furnace of the present invention anneals hot rolled steel coils and includes a housing that pivotably opens and closes about a pivot member. The present invention overcomes the disadvantages of the prior art and can obtain cycle times of less than 75 hours at a temperature range from about 1200 0F to about 1650 0F. In one embodiment of the present invention, a method of converting hot rolled steel coil to a condition suitable for subsequent cold rolling includes annealing at least one hot rolled coil of steel in a furnace, wherein a portion of the furnace pivotably rotates about a pivot member between an opened and closed position, wherein the pivot member has a pivot axis generally lateral with its base portion, pickling the annealed steel coil, cold reducing the pickled steel coil and subjecting the cold reduced steel coil to a second annealing treatment. [0010] A method is disclosed of annealing hot rolled steel coil comprising the steps of:
(a) assembling a furnace housing comprising a plurality of side walls, a base portion and a roof portion, where the housing pivotably rotates about a pivot member between an opened and closed position, wherein the pivot member has a lateral axis,
(b) positioning hot rolled coils of steel in the furnace with the axis of positioned coils generally horizontal to the base portion,
(c) pivoting housing about the axis of the pivot member to close the furnace,
(d) establishing a reducing atmosphere within the furnace,
(e) annealing the hot rolled coils of steel in the furnace with the axis of positioned coils generally horizontal to the base portion, and
(f) pivoting housing about the axis of the pivot member to open the furnace.
[0011] The hot rolled coils of steel may be placed on circumferential surfaces within a retaining element.
[0012] The reducing atmosphere may comprise at least one inert gas and at least one polyolefin gas, and at least one inert gas may be nitrogen and at least one polyolefin gas may be propylene. The reducing atmosphere may comprise nitrogen gas in an amount greater than about 90%, hydrogen gas in a range between about 5% to about 7%, and propylene gas in an amount less than about 1%. The annealing of the hot rolled steel coil may provide a cycle time of less than 75 hours at temperature range from about 1200 0F to about 1650 0F. [0013] Also disclosed is a furnace for annealing hot rolled steel coil comprising:
(a) a furnace housing comprising a plurality of side walls, a base portion, a roof portion and a pivot member with an axis generally parallel with the base portion, where the housing pivotably rotates about a pivot member between an opened and a closed position;
(b) a retaining element within the furnace housing where the retaining element holds each coil such that the axis of each coil is generally horizontal to the base portion while the housing pivotably rotates about the pivot member,
(c) a sealing device capable of sealing the furnace housing when in the closed position,
(d) a system capable of establishing a reducing atmosphere within the furnace when sealed, and
(e) a plurality of heating elements located within the furnace housing capable of heating hot rolled steel coil during the annealing process. [0014] The retaining element may be configured such that each of the hot rolled steel coils is capable of resting on circumferential surfaces of the coils within the retaining element.
[0015] The furnace may be capable of providing annealing of the hot rolled steel coil in a cycle time of less than 75 hours at temperature range between about 1200 0F and about 1650 0F. The system of the furnace may be capable of establishing a reducing atmosphere that comprises at least one inert gas, and at least one polyolefin gas and at least one inert gas may be nitrogen and at least one polyolefin gas may be propylene. The reducing atmosphere may comprise nitrogen gas in an amount greater than about 90%, hydrogen gas in a range between about 5% to about 7%, and propylene gas in an amount less than about 1%. [0016] The above summary of the present invention is not intended to describe each embodiment or every implementation of the present invention. Advantages, together with a more complete understanding of the invention, will become apparent and appreciated by referring to the following detailed description and claims taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0017] FIG. 1 is a plan view of the annealing furnace of the present invention; [0018] FIG. 2 is a front elevation view of the annealing furnace of the present invention; and
[0019] FIG. 3 is a cross-section view across of the annealing furnace of the present invention across lines 2-2 of FIG. 2.
DETAILED DESCRIPTION OF THE DRAWINGS
[0020] For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiments illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, such alterations and further modifications in the illustrated device, and such further applications of the principles of the invention as illustrated therein being contemplated as would normally occur to one skilled in the art to which the invention relates.
[0021] The present invention is directed towards the hot roll annealing of steel coils. The annealing of hot roll steel coils is a novel processing route when compared with the standard cold roll annealing route, wherein the hot roll steel coils are typically pickled, annealed, sometimes pickled again, cold reduced and then annealed one last time. In comparison, the new processing route of the present disclosure, which may be a batch process, has hot rolled steel coils avoid the initial pickling step of the cold rolled annealing process and proceed directly to the annealing stage, wherein the annealed steel coils are then pickled, cold reduced and then annealed one last time if desired. This hot roll annealing process provides substantial energy savings, since the steel coils are annealed while they are still hot, and more consistent mechanical properties, as measured in the ksi yield strength, when compared to the standard cold roll annealing process.
[0022] The high temperature annealing furnace of the present disclosure is illustrated in FIGS. 1-3. Reference numeral 10 indicates a furnace for annealing hot rolled steel coils. Furnace 10 includes a base portion 11 and a furnace housing 12. The base portion 11 is the base on which the furnace 10 is positioned on the floor of the steel plant. Housing 12 includes a roof portion 14 and a plurality of side walls 15, 16, 17 and 18. Located within housing 12 are a plurality of heating elements 19 that are used to heat the hot rolled steel coils during the annealing process. Housing 12 pivotably rotates about a pivot member 13 between an opened and closed position, as seen in FIG. 3. Pivot member 13 has a lateral axis and is generally parallel with base portion 11.
[0023] Located within housing 12 and secured to base portion 11 is a retaining element (not shown) that configured to support at least one hot rolled steel coil, wherein each steel coil has an axial opening therethrough which is substantially horizontal to base portion 11 of the furnace. The retaining element is capable of holding a plurality of hot rolled steel coils separate from one another. Prior to the annealing process and when housing 12 is in the opened position, the retaining element is configured such that when each of the hot rolled steel coils is placed on the retaining element. Each steel coil may be capable of resting on the circumferential surface of the coil within the retaining element.
[0024] Heating elements 19 are located within the interior of housing 12 of furnace 10. In one embodiment, heating elements 19 are curved pipes positioned in a predetermined arrangement along the sides of side walls 15, 16, 17 and 18, as seen in FIG. 3, which are directly exposed to the hot rolled steel coils during the annealing process. In order to reach the desired annealing temperature for the hot rolled steel coils, compressed air, which may be heated by natural gas burners, is circulated through heating elements 19. [0025] It will be understood that the annealing furnace of the present disclosure will be provided with a full compliment of controls, sensors, piping and the like. These elements are well known in the art and do not constitute a part of the present invention. The furnace cycle, including heating and cooling rates, atmosphere control, and the like, can be manually or computer controlled, or both. Various types of computer and manual controls are well known in the art and again do not constitute a part of the present disclosure.
[0026] This invention relates to all hot rolled steel coils wherein the steel includes any commercially available steel, such as, for example, high carbon steel, medium carbon steel, low carbon steel, and high temperature austenite grain coarsening steel such as those described in U.S. Patent No. 7,048,033, which is hereby incorporated by reference. [0027] Two grades of steel that can be annealed in the annealing furnace of the present disclosure include high carbon steel, having approximately 0.50 or more weight percent carbon in the total steel, and low carbon steel, having approximately less than 0.02 weight percent carbon in the total steel. The hot roll annealing of the high carbon steel in the furnace provides a softening of the material to permit more efficient downstream processing, for example cold reduction, of the steel coils. At an annealing temperature from about 1200 0F to about 1650 0F, the cycle time of the annealing process is less than 75 hours. At an annealing temperature in the range from about 1200 0F to about 1650 0F, the annealing process may have a cycle time in the range from about 40 hours to about 60 hours. [0028] One type of high temperature annealing process is called "spherodize annealing". In this type of annealing process for high carbon steel, the controlled heating and cooling process produces spheroidal globular particles resulting in steel coils that have good machining characteristics. In this type of high temperature annealing, the use of a normal air atmosphere during the annealing promotes decarburization of the steel coil. The combination of high heat and a normal air atmosphere initially depletes a layer of carbon on the surface of the steel coil and decarburization results. Decarburization produces a steel product having both structural and mechanical inconsistencies throughout its surface.
[0029] In order to inhibit the effects of decarburization that takes place in a normal atmosphere during the high temperature annealing process, the annealing furnace includes a system capable of establishing a reducing atmosphere within the furnace when it is sealed. Included in furnace 10 is a sealing device (not shown) that is capable of sealing housing 12 when it is in the closed position. The sealing device promotes an efficient and effective annealing process by maintaining a desired annealing temperature and reducing atmosphere during the annealing process.
[0030] The reducing atmosphere includes at least one inert gas and at least one polyolefin gas. The at least one inert gas may include helium, neon, argon, xenon, and nitrogen. The reducing atmosphere can also include at least one other gas that facilitates the annealing process. The reducing atmosphere may include nitrogen as an inert gas, propylene as a polyolefin gas and hydrogen gas. In one embodiment, the reducing atmosphere used in the high temperature annealing process of high carbon steel includes nitrogen gas in an amount greater than about 90%, hydrogen gas in a range between about 5% to about 7% and propylene gas in an amount less than about 1%.
[0031] The hot roll annealing of low carbon steel coils is also an embodiment of the present disclosure. This type of steel includes a low carbon motor lam grade material that is used in motor lamination of electrical steels for motors of automotive vehicles. The hot roll annealing of the low carbon steel produces the growth of larger grains within the steel which ultimately yields improved magnetic properties. These improvements include lower core loss, which is a reduction in the loss of magnetic field as the magnetic fields are alternated, and higher permeability of the steel that allows more of the magnetic field to permeate it. Another benefit of the hot roll annealing of the low carbon steel is that it softens the steel to promote a more efficient cold rolling process.
[0032] Based on the foregoing disclosure, it should be apparent that the furnace used for annealing hot rolled steel coils of the present invention will achieve the objectives set forth above. It is therefore understood that any evident variations will fall within the scope of the claimed invention. Thus, alternate specific component elements can be selected without departing from the spirit of the invention disclosed and described therein.

Claims

CLAIMSWhat is claimed is:
1. A method of annealing hot rolled steel coil comprising the steps of:
(a) assembling a furnace housing comprising a plurality of side walls, a base portion and a roof portion, where the housing pivotably rotates about a pivot member between an opened and closed position, wherein the pivot member has a lateral axis,
(b) positioning hot rolled coils of steel in the furnace with the axis of positioned coils generally horizontal to the base portion,
(c) pivoting housing about the axis of the pivot member to close the furnace,
(d) establishing a reducing atmosphere within the furnace,
(e) annealing the hot rolled coils of steel in the furnace with the axis of positioned coils generally horizontal to the base portion, and
(f) pivoting housing about the axis of the pivot member to open the furnace.
2. The method of claim 1 where positioned coils are placed on circumferential surfaces within a retaining element.
3. The method of claim 1 where the reducing atmosphere comprises at least one inert gas and at least one polyolefin gas.
4. The method of claim 3 where the at least one inert gas is nitrogen.
5. The method of claim 3 where the at least one polyolefin gas is propylene.
6. The method of claim 1 where the reducing atmosphere comprises nitrogen gas in an amount greater than about 90%, hydrogen gas in a range between about 5% to about 7%, and propylene gas in an amount less than about 1%.
7. The method of claim 1 where the annealing of the hot rolled steel coil provides a cycle time of less than 75 hours at a temperature range from about 1200 0F to about 1650 0F.
8. A furnace for annealing hot rolled steel coil comprising:
(a) a furnace housing comprising a plurality of side walls, a base portion, a roof portion and a pivot member with an axis generally parallel with the base portion, where the housing pivotably rotates about the pivot member between an opened and a closed position;
(b) a retaining element within the furnace housing where the retaining element holds each coil such that the axis of each coil is generally horizontal to the base portion while the housing pivotably rotates about the pivot member,
(c) a sealing device capable of sealing the furnace housing when in the closed position,
(d) a system capable of establishing a reducing atmosphere within the furnace when sealed, and
(e) a plurality of heating elements located within the furnace housing capable of heating hot rolled steel coil during the annealing process.
9. The furnace of claim 8 where the retaining element is configured such that each of the hot rolled steel coils is capable of resting on circumferential surfaces of the coils.
10. The furnace of claim 8 where the furnace is capable of providing annealing of the hot rolled steel coil in a cycle time of less than 75 hours at a temperature range between about 1200 0F and about 1650 0F.
11. The furnace of claim 8 where the system capable of establishing a reducing atmosphere comprises at least one inert gas and at least one polyolefin gas.
12. The furnace of claim 8 where the system capable of establishing a reducing atmosphere comprises at least one inert gas, including nitrogen, and at least one polyolefin gas.
13. The furnace of claim 8 where the system capable of establishing a reducing atmosphere comprises at least one inert gas and at least one polyolefin gas, including propylene.
14. The furnace of claim 11 where the system is capable of further providing hydrogen gas in the reducing atmosphere.
15. The furnace of claim 8 where the system capable of establishing a reducing atmosphere comprises nitrogen gas in an amount greater than 90%, hydrogen gas ranging from about 5% to about 7%, and propylene gas in an amount less than 1%.
16. The furnace of claim 10 where the annealing process has a cycle time in a range from about 40 hours to about 60 hours at a temperature in the range from about 1,200 0F to about 1600 0F.
17. The method of claim 1 where the annealing of the hot rolled steel coils is performed by a batch process.
PCT/US2007/065739 2006-04-10 2007-03-31 Annealing of hot rolled steel coils with clam shell furnace WO2007121074A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US27919206A 2006-04-10 2006-04-10
US11/279,192 2006-04-10
US11/549,286 US7204894B1 (en) 2004-03-18 2006-10-13 Annealing of hot rolled steel coils with clam shell furnace
US11/549,286 2006-10-13

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WO2007121074A2 true WO2007121074A2 (en) 2007-10-25
WO2007121074A3 WO2007121074A3 (en) 2008-01-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016012860A1 (en) * 2014-07-24 2016-01-28 Sabic Global Technologies.B.V. Annealed cold rolled steel and method for preparing same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6177044B1 (en) * 1997-01-30 2001-01-23 Loi Thermprocess Gmbh Bell-shaped furnace
US6346214B1 (en) * 1998-10-14 2002-02-12 Otto Junker Gmbh Top hat furnace

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6177044B1 (en) * 1997-01-30 2001-01-23 Loi Thermprocess Gmbh Bell-shaped furnace
US6346214B1 (en) * 1998-10-14 2002-02-12 Otto Junker Gmbh Top hat furnace

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016012860A1 (en) * 2014-07-24 2016-01-28 Sabic Global Technologies.B.V. Annealed cold rolled steel and method for preparing same

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