WO2007120173A3 - N-halamine/quaternary ammonium polysiloxane copolymers - Google Patents

N-halamine/quaternary ammonium polysiloxane copolymers Download PDF

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Publication number
WO2007120173A3
WO2007120173A3 PCT/US2006/030909 US2006030909W WO2007120173A3 WO 2007120173 A3 WO2007120173 A3 WO 2007120173A3 US 2006030909 W US2006030909 W US 2006030909W WO 2007120173 A3 WO2007120173 A3 WO 2007120173A3
Authority
WO
WIPO (PCT)
Prior art keywords
biocidal
halamine
materials
quaternary ammonium
precursor
Prior art date
Application number
PCT/US2006/030909
Other languages
French (fr)
Other versions
WO2007120173A2 (en
Inventor
Shelby D Worley
Yongjun Chen
Jie Liang
Paul Kevin Barnes
Original Assignee
Univ Auburn
Shelby D Worley
Yongjun Chen
Jie Liang
Paul Kevin Barnes
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Auburn, Shelby D Worley, Yongjun Chen, Jie Liang, Paul Kevin Barnes filed Critical Univ Auburn
Priority to EP06851123A priority Critical patent/EP1919981A4/en
Priority to CA002618732A priority patent/CA2618732A1/en
Publication of WO2007120173A2 publication Critical patent/WO2007120173A2/en
Publication of WO2007120173A3 publication Critical patent/WO2007120173A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/452—Block-or graft-polymers containing polysiloxane sequences containing nitrogen-containing sequences
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/10—Block or graft copolymers containing polysiloxane sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Silicon Polymers (AREA)

Abstract

Precursor N-halamine/quaternary ammonium random copolymers which are soluble in water for the purpose of functionalizing surfaces or materials so as to render them biocidal upon exposure to oxidative halogen solutions. The biocidal function can be imparted to the precursor N-halamine moiety either before or after siloxane bonding or adhesion to the surface or material. The biocidal surfaces and materials can then be used to inactivate pathogenic microorganisms such as bacteria, fungi, and yeasts, as well as virus particles, that can cause infectious diseases and those microorganisms that cause noxious odors and unpleasant coloring such as mildew. Examples of surfaces and materials which can be rendered biocidal include, but are not limited to, cellulose, chitin, chitosan, synthetic fibers, glass, ceramics, plastics, rubber, cement grout, latex caulk, porcelain, acrylic films, vinyl, polyurethanes, silicon tubing, marble, metals, metal oxides, and silica.
PCT/US2006/030909 2005-08-11 2006-08-08 N-halamine/quaternary ammonium polysiloxane copolymers WO2007120173A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06851123A EP1919981A4 (en) 2005-08-11 2006-08-08 N-halamine/quaternary ammonium polysiloxane copolymers
CA002618732A CA2618732A1 (en) 2005-08-11 2006-08-08 N-halamine/quaternary ammonium polysiloxane copolymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US70743805P 2005-08-11 2005-08-11
US60/707,438 2005-08-11

Publications (2)

Publication Number Publication Date
WO2007120173A2 WO2007120173A2 (en) 2007-10-25
WO2007120173A3 true WO2007120173A3 (en) 2008-08-28

Family

ID=38609942

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/030909 WO2007120173A2 (en) 2005-08-11 2006-08-08 N-halamine/quaternary ammonium polysiloxane copolymers

Country Status (4)

Country Link
EP (1) EP1919981A4 (en)
CA (1) CA2618732A1 (en)
TW (1) TW200734406A (en)
WO (1) WO2007120173A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012096694A1 (en) * 2011-01-13 2012-07-19 Auburn University Novel n-halamine acrylamide monomers and copolymers thereof for biocidal coatings
US20150118179A1 (en) * 2012-05-17 2015-04-30 University Of Manitoba Biocidal compounds and methods for using same
US20140154297A1 (en) * 2012-10-30 2014-06-05 Baxter Healthcare S.A. Antimicrobial substrates and methods for processing the same
CN103193903A (en) * 2013-04-19 2013-07-10 上海师范大学 Sterilization polymer containing quaternary ammonium salt and halamine or halamine precursor functional group as well as preparation method and application of sterilization polymer
AT515029B1 (en) 2013-10-21 2015-12-15 Polymer Competence Ct Leoben Contact biocides based on poly (oxazine) s, poly (oxazpein) s and poly (oxazozin) s
JP6096704B2 (en) * 2014-03-31 2017-03-15 富士フイルム株式会社 Thermal or photocurable composition, and insulating film and thin film transistor using the same
WO2017079825A1 (en) 2015-11-13 2017-05-18 Exigence Technologies Inc. Monomers, polymers and coating formulations that comprise at least one n-halamine precursor, a cationic center and a coating incorporation group
CN109316622B (en) * 2017-07-31 2022-03-25 苏州佰济生物科技有限公司 Chlorinated chitosan antibacterial material and preparation method and application thereof
CN109912801A (en) * 2019-03-18 2019-06-21 山东交通学院 One kind siloxanes of functional poly containing quaternary ammonium salt and its synthetic method
CN116075564A (en) 2020-09-22 2023-05-05 Swimc有限公司 Coating composition containing chitosan
CN113336783B (en) * 2021-06-22 2022-07-15 山东科技大学 Multifunctional silane bactericide with surface migration characteristic and preparation and application thereof
CN116606402B (en) * 2023-05-25 2023-11-17 西北师范大学 Preparation method of self-assembled antibacterial nano microsphere containing zwitterionic polyhaloamine
CN116535859B (en) * 2023-07-06 2023-08-25 汕头市永昌钦发针织实业有限公司 Flexible skin-friendly silica gel, preparation method thereof and application thereof in silica gel underwear

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6383996B1 (en) * 1999-09-29 2002-05-07 L'oreal Antidandruff composition for treating the hair and the scalp, based on an antidandruff agent and an acrylic terpolymer

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6969769B2 (en) * 2002-06-14 2005-11-29 Vanson Halosource, Inc. N-halamine siloxanes for use in biocidal coatings and materials
US7335373B2 (en) * 2003-11-17 2008-02-26 Auburn University Biocidal siloxane coating material containing N-halogenated amine and amide functional groups

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6383996B1 (en) * 1999-09-29 2002-05-07 L'oreal Antidandruff composition for treating the hair and the scalp, based on an antidandruff agent and an acrylic terpolymer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1919981A4 *

Also Published As

Publication number Publication date
EP1919981A4 (en) 2012-04-04
CA2618732A1 (en) 2007-10-25
TW200734406A (en) 2007-09-16
WO2007120173A2 (en) 2007-10-25
EP1919981A2 (en) 2008-05-14

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