WO2007090816A1 - Laminated labels for containers - Google Patents

Laminated labels for containers Download PDF

Info

Publication number
WO2007090816A1
WO2007090816A1 PCT/EP2007/051080 EP2007051080W WO2007090816A1 WO 2007090816 A1 WO2007090816 A1 WO 2007090816A1 EP 2007051080 W EP2007051080 W EP 2007051080W WO 2007090816 A1 WO2007090816 A1 WO 2007090816A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
paper
label
plastic material
joined
Prior art date
Application number
PCT/EP2007/051080
Other languages
French (fr)
Inventor
Pedro Espelt Villegas
Pere Angelats Padres
Original Assignee
Manipulados Del Ter, S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Manipulados Del Ter, S.A. filed Critical Manipulados Del Ter, S.A.
Publication of WO2007090816A1 publication Critical patent/WO2007090816A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F23/00—Advertising on or in specific articles, e.g. ashtrays, letter-boxes
    • G09F23/06—Advertising on or in specific articles, e.g. ashtrays, letter-boxes the advertising matter being combined with articles for restaurants, shops or offices
    • G09F23/08—Advertising on or in specific articles, e.g. ashtrays, letter-boxes the advertising matter being combined with articles for restaurants, shops or offices with tableware
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/12—Coating on the layer surface on paper layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/408—Matt, dull surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
    • B32B2439/60—Bottles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00—Labels, badges

Definitions

  • the present invention refers to a laminated label for containers, especially devised to be used in bottles for beverages.
  • labels of different kinds In the field of the containers for beverages, especially wine and the like, it is known to use labels of different kinds.
  • One of these labels consists in a paper sheet which is attached to the bottle by an adhesive.
  • These labels present the drawback that when the bottle is in a humid environment, e.g. if it is submerged in ice or water, the paper absorbs water and wrinkles and loses its opacity and consistency, which causes an unsuitable appearance and the label to be broken or removed.
  • Another kind of labels comprises a waterproof plastic sheet attached to the external face of the paper, which make the water difficult to pass the paper and damage it rapidly.
  • the appearance provided by these labels is not satisfactory, because the external plastic layer makes the paper to lose its matt appearance, providing a shiny appearance and an impression of a lower quality than the paper.
  • labels comprising a sheet of paper without any kind of covering at its external face, with the objective to preserve its original appearance, and comprising a waterproof plastic material adhered to the rear face of the paper. Said rear plastic sheet increases the resistance of the paper when the label gets wet, and it improves the adherence of the label to the container.
  • the external face of the paper layer remains exposed directly to the humidity, and therefore the paper absorbs water, loses its opacity and wrinkles.
  • the object of the present invention is to solve the drawbacks present in the labels of the prior art, providing a laminated label for containers comprising a layer of paper and a layer of plastic material, characterized in that said layer of paper comprises a covering based in a copolymer of ethylexyl acrylate methylmetacrylate at its external face, and in that said layer of paper is intimately joined by its internal face to said layer of plastic material.
  • the label of the invention prevents the water to pass to the sheet of paper through its external face, and it also preserves the original appearance of the paper.
  • the covering based in a copolymer of ethylexyl acrylate - methylmetacrylate is a transparent varnish which prevents the water to pass to the layer of paper and it also permits to preserve the matt appearance of the paper .
  • the layer of paper remains protected from water at both faces, so that the label of the present invention can be subjected to humid environments without damages, preserving also the original matt appearance of the paper.
  • said layer of plastic material comprises at least a copolymer of propylene-polyethylene .
  • This layer of plastic prevents the water to pass to the layer of paper through its internal face, and it also provides a greater consistency.
  • the layer of plastic is joined to the layer of paper preferably by co- extrusion, to obtain a more consistent joining between both layers and a constant thickness of the label.
  • the label also comprises an adhesive material after said layer of plastic material.
  • the label also comprises a support sheet detachably joined to the adhesive material.
  • the support sheet comprises a layer of silicone joined to an additional layer of paper, said layer of silicone being detachably joined to the adhesive material.
  • This support sheet permits to handle the label before being attached in its final position.
  • the container is a bottle of glass.
  • Fig. 1 is a cross-section view of an embodiment of the label of the invention, comprising a support sheet;
  • Fig. 2 is a view of the label according to the present invention attached to a bottle;
  • Fig. 3 is a cross-section view of the label of
  • Fig. 1 it can be seen a cross-section view of a label 1 according to the present invention, which comprises a support sheet 2.
  • the label 1 presents a laminar structure, and it comprises a first layer of paper 3, whose external face constitutes the visible part of the label 1.
  • the layer of paper 3 comprises, at its external face, a covering 3 based in a copolymer of ethylhexyl acrylate - methylacrylate .
  • Said covering 5 constitutes a varnish which is transparent and prevents the water to pass to the layer of paper 3 through its external face, so that the layer of paper 3 maintains its opacity and consistency even if it is submerged in humid environments.
  • the varnish 5 of the invention permits, instead of the usual laminates and products, to preserve the original appearance of the external face of the paper 3, which is a matt appearance.
  • the covering 5 of the label could be obtained by the preparation of an aqueous dispersion of a copolymer of ethylexyl acrylate and of methylmetacrylate with a water- based colloidal dispersion of silicon. Once this composition is prepared, it would be applied then to the external face of the layer of paper 3, e.g. by cylinders with a non-smooth surface which deposit the covering 5 on the layer of paper 3.
  • the label 1 also comprises another layer of plastic material 4 which is intimately joined to the internal face of the layer of paper 3.
  • the layer of plastic 4 is waterproof, and it prevents the water to pass to the layer of paper 3 through its internal face.
  • the layer of paper 3 and the layer of plastic material 4 are joined by co-extrusion.
  • This joining process prevents the necessity to use adhesives to join both layers and the obtained joining is more resistant, because the two layers remain joined directly by the adherence produced between the materials constituting them.
  • the co-extrusion is a well-known process and relatively cheap consisting in the simultaneous extrusion of several layers of different materials.
  • said method comprises the joint extrusion of the paper of layer 3 and the plastic material of layer 4.
  • the plastic material of layer 4 is applied from a lip or extrusion head in fluid state to a sheet of paper like a curtain or cascade, so that a layer of plastic material is formed on the layer of paper.
  • the paper and the plastic material pass through a plurality of rollers that cool the layer of plastic 4 and shape the laminate, providing the necessary thickness and joining the two layers 3, 4 consistently to each other.
  • the obtained product consists in a laminate composed by two layers 3, 4 which are intimately joined to each other, and presenting a constant thickness along all its extension. Furthermore, the joining between the layer of paper 3 and the layer of plastic 4 is stronger than the one obtained by other methods, such as lamination, in which the two layers are joined by adhesives.
  • the joining between the layer of paper 3 and the layer of plastic material 4 will be preferably by co-extrusion, these layers could also be joined by lamination, in which the layer of plastic would be joined to the layer of paper using an adhesive .
  • the layer of plastic material 4 will be constituted preferably by a copolymer of propylene- polyethylene .
  • This material is especially suitable for co- extrusion processes, even though another kinds of plastic could also be used, such as polyesters, PVC or polyolefins .
  • the label 1 also comprises a layer of adhesive material 6 in the internal face of the layer of plastic 4, by which the label 1 is attached to the desired surface.
  • the adhesive 6 can be of any kind of those used in the field of the art, which preferably maintains its features in humid environments.
  • One of the used adhesives could consist in an auto-adhesive of the water-based acrylic kind.
  • the label 1 includes a support sheet 2, comprising a layer of silicone 7 joined to an additional layer of paper 8.
  • This support sheet 2 protects the layer of adhesive material 6 and permits to transport and handle the label 1 easily before attaching it in this final placement.
  • the support sheet 2 is joined to the rest of the label 1 by its layer is silicone 7.
  • the layer of silicone 7 is adhered to the adhesive material 6, and it permits to separate easily the support sheet 2 from the adhesive 6 and from the rest of the label 1.
  • the label 1 is attached by the adhesive 6 on the surface of its final placement, in this case a bottle 9 (Fig. 2 and 3) .
  • the layer of paper 3 of the label 1 of the invention remains waterproofed by its external and internal faces.
  • the layer of varnish 5 permits to preserve the original appearance of the paper 3, and it also prevents the water to pass through the external face of the layer of paper 3.
  • the layer of plastic 4 prevents the water to pass to the layer of paper 3 through is internal face, and also provides the label 1 a greater consistency.
  • the label 1 according to the present invention is especially suitable to be used in bottles of wine or other beverages, which are normally subjected to humid environments during its use.

Abstract

The laminated label (1) for containers (9) comprises a layer of paper (3) and a layer of plastic material (4), and it is characterized in that said layer of paper (3) comprises a covering (5) based in a copolymer of ethylexyl acrylate - methylmetacrylate at its external face, and in that said layer of paper (3) is intimately joined by its internal face to said layer of plastic material (4) . The label of the invention prevents the water to pass to the sheet of paper through its external face, and it also preserves the original appearance of the paper.

Description

The present invention refers to a laminated label for containers, especially devised to be used in bottles for beverages.
BACKGROUND OF THE INVENTION
In the field of the containers for beverages, especially wine and the like, it is known to use labels of different kinds. One of these labels consists in a paper sheet which is attached to the bottle by an adhesive. These labels present the drawback that when the bottle is in a humid environment, e.g. if it is submerged in ice or water, the paper absorbs water and wrinkles and loses its opacity and consistency, which causes an unsuitable appearance and the label to be broken or removed.
Another kind of labels comprises a waterproof plastic sheet attached to the external face of the paper, which make the water difficult to pass the paper and damage it rapidly. However, the appearance provided by these labels is not satisfactory, because the external plastic layer makes the paper to lose its matt appearance, providing a shiny appearance and an impression of a lower quality than the paper. Finally, it is also known to use labels comprising a sheet of paper without any kind of covering at its external face, with the objective to preserve its original appearance, and comprising a waterproof plastic material adhered to the rear face of the paper. Said rear plastic sheet increases the resistance of the paper when the label gets wet, and it improves the adherence of the label to the container. However, the external face of the paper layer remains exposed directly to the humidity, and therefore the paper absorbs water, loses its opacity and wrinkles. DESCRIPTION OF THE INVENTION
The object of the present invention is to solve the drawbacks present in the labels of the prior art, providing a laminated label for containers comprising a layer of paper and a layer of plastic material, characterized in that said layer of paper comprises a covering based in a copolymer of ethylexyl acrylate methylmetacrylate at its external face, and in that said layer of paper is intimately joined by its internal face to said layer of plastic material.
Thanks to this feature, the label of the invention prevents the water to pass to the sheet of paper through its external face, and it also preserves the original appearance of the paper.
The covering based in a copolymer of ethylexyl acrylate - methylmetacrylate is a transparent varnish which prevents the water to pass to the layer of paper and it also permits to preserve the matt appearance of the paper .
Therefore, thanks to the combination of the layer of varnish disclosed and the layer of plastic placed at the internal face of the layer of paper, the layer of paper remains protected from water at both faces, so that the label of the present invention can be subjected to humid environments without damages, preserving also the original matt appearance of the paper.
Preferably, said layer of plastic material comprises at least a copolymer of propylene-polyethylene .
This layer of plastic prevents the water to pass to the layer of paper through its internal face, and it also provides a greater consistency. The layer of plastic is joined to the layer of paper preferably by co- extrusion, to obtain a more consistent joining between both layers and a constant thickness of the label.
Advantageously, the label also comprises an adhesive material after said layer of plastic material.
Also advantageously, the label also comprises a support sheet detachably joined to the adhesive material.
According to an embodiment of the present invention, the support sheet comprises a layer of silicone joined to an additional layer of paper, said layer of silicone being detachably joined to the adhesive material. This support sheet permits to handle the label before being attached in its final position.
Preferably, the container is a bottle of glass.
BRIEF DESCRIPTION OF THE DRAWINGS
Some drawings are attached to facilitate the description of what has been disclosed above, in which diagrammatically and only as a non-limitative example, a practical case of embodiment of the invention is shown, in which:
Fig. 1 is a cross-section view of an embodiment of the label of the invention, comprising a support sheet; Fig. 2 is a view of the label according to the present invention attached to a bottle; Fig. 3 is a cross-section view of the label of
Fig. 2.
DESCRIPTION OF A PREFERRED EMBODIMENT
In Fig. 1 it can be seen a cross-section view of a label 1 according to the present invention, which comprises a support sheet 2.
As it can be seen, the label 1 presents a laminar structure, and it comprises a first layer of paper 3, whose external face constitutes the visible part of the label 1. The layer of paper 3 comprises, at its external face, a covering 3 based in a copolymer of ethylhexyl acrylate - methylacrylate .
Said covering 5 constitutes a varnish which is transparent and prevents the water to pass to the layer of paper 3 through its external face, so that the layer of paper 3 maintains its opacity and consistency even if it is submerged in humid environments.
Furthermore, the varnish 5 of the invention permits, instead of the usual laminates and products, to preserve the original appearance of the external face of the paper 3, which is a matt appearance.
The covering 5 of the label could be obtained by the preparation of an aqueous dispersion of a copolymer of ethylexyl acrylate and of methylmetacrylate with a water- based colloidal dispersion of silicon. Once this composition is prepared, it would be applied then to the external face of the layer of paper 3, e.g. by cylinders with a non-smooth surface which deposit the covering 5 on the layer of paper 3.
The label 1 also comprises another layer of plastic material 4 which is intimately joined to the internal face of the layer of paper 3. The layer of plastic 4 is waterproof, and it prevents the water to pass to the layer of paper 3 through its internal face.
Preferably, the layer of paper 3 and the layer of plastic material 4 are joined by co-extrusion. This joining process prevents the necessity to use adhesives to join both layers and the obtained joining is more resistant, because the two layers remain joined directly by the adherence produced between the materials constituting them.
The co-extrusion is a well-known process and relatively cheap consisting in the simultaneous extrusion of several layers of different materials. In the case of the present invention, said method comprises the joint extrusion of the paper of layer 3 and the plastic material of layer 4.
During the method, the plastic material of layer 4 is applied from a lip or extrusion head in fluid state to a sheet of paper like a curtain or cascade, so that a layer of plastic material is formed on the layer of paper.
Then, the paper and the plastic material pass through a plurality of rollers that cool the layer of plastic 4 and shape the laminate, providing the necessary thickness and joining the two layers 3, 4 consistently to each other.
After the co-extrusion method, the obtained product consists in a laminate composed by two layers 3, 4 which are intimately joined to each other, and presenting a constant thickness along all its extension. Furthermore, the joining between the layer of paper 3 and the layer of plastic 4 is stronger than the one obtained by other methods, such as lamination, in which the two layers are joined by adhesives.
Even though, as disclosed, the joining between the layer of paper 3 and the layer of plastic material 4 will be preferably by co-extrusion, these layers could also be joined by lamination, in which the layer of plastic would be joined to the layer of paper using an adhesive .
The layer of plastic material 4 will be constituted preferably by a copolymer of propylene- polyethylene . This material is especially suitable for co- extrusion processes, even though another kinds of plastic could also be used, such as polyesters, PVC or polyolefins .
The label 1 also comprises a layer of adhesive material 6 in the internal face of the layer of plastic 4, by which the label 1 is attached to the desired surface. The adhesive 6 can be of any kind of those used in the field of the art, which preferably maintains its features in humid environments.
One of the used adhesives could consist in an auto-adhesive of the water-based acrylic kind.
As stated above, in the present embodiment the label 1 includes a support sheet 2, comprising a layer of silicone 7 joined to an additional layer of paper 8. This support sheet 2 protects the layer of adhesive material 6 and permits to transport and handle the label 1 easily before attaching it in this final placement.
The support sheet 2 is joined to the rest of the label 1 by its layer is silicone 7. The layer of silicone 7 is adhered to the adhesive material 6, and it permits to separate easily the support sheet 2 from the adhesive 6 and from the rest of the label 1.
Once the support sheet 2 is separated from the rest of the label 1 (the layer of paper 3, the covering 5, the layer of plastic 4 and the adhesive 6) , the label 1 is attached by the adhesive 6 on the surface of its final placement, in this case a bottle 9 (Fig. 2 and 3) .
As it can be seen, the layer of paper 3 of the label 1 of the invention remains waterproofed by its external and internal faces. The layer of varnish 5 permits to preserve the original appearance of the paper 3, and it also prevents the water to pass through the external face of the layer of paper 3. The layer of plastic 4 prevents the water to pass to the layer of paper 3 through is internal face, and also provides the label 1 a greater consistency.
The label 1 according to the present invention is especially suitable to be used in bottles of wine or other beverages, which are normally subjected to humid environments during its use.

Claims

C L A I M S
1. Laminated label (1) for containers (9) comprising a layer of paper (3) and a layer of plastic material (4), characterized in that said layer of paper (3) comprises a covering (5) based in a copolymer of ethylexyl acrylate - methylmetacrylate at its external face, and in that said layer of paper (3) is intimately joined by its internal face to said layer of plastic material (4) .
2. Label (1) according to claim 1, characterized in that said layer of plastic material (4) comprises at least a copolymer of propylene-polyethylene .
3. Label (1) according to any one of the previous claims, characterized in that it also comprises an adhesive material (6) after said layer of plastic material (4) .
4. Label (1) according to claims 1 and 3, characterized in that it also comprises a support sheet (2) detachably joined to the adhesive material (6) .
5. Label (1) according to claim 4, characterized in that the support sheet (2) comprises a layer of silicone (7) joined to an additional layer of paper (8), said layer of silicone (7) being detachably joined to the adhesive material (6) .
6. Label (1) according to any one of the previous claims, characterized in that said container is a bottle of glass (9) .
PCT/EP2007/051080 2006-02-10 2007-02-05 Laminated labels for containers WO2007090816A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ESU-200600291 2006-02-10
ES200600291U ES1062169Y (en) 2006-02-10 2006-02-10 LAMINATED LABEL FOR PACKAGING.

Publications (1)

Publication Number Publication Date
WO2007090816A1 true WO2007090816A1 (en) 2007-08-16

Family

ID=36578989

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/051080 WO2007090816A1 (en) 2006-02-10 2007-02-05 Laminated labels for containers

Country Status (3)

Country Link
AR (1) AR059419A4 (en)
ES (1) ES1062169Y (en)
WO (1) WO2007090816A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9978291B2 (en) 2008-09-03 2018-05-22 Ccl Label Meerane Gmbh Label, especially for a reusable container

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173300A1 (en) * 1984-08-29 1986-03-05 National Starch and Chemical Corporation Aqueous surfactant-free base coating for metallized paper
WO1987005276A1 (en) * 1986-02-26 1987-09-11 Plastipak Packaging, Inc. Plastic container with fluid barrier label
US5096767A (en) * 1989-02-03 1992-03-17 Mitsubishi Paper Mills Limited Alkali-removable label support and label
DE19801148A1 (en) * 1998-01-14 1999-07-15 Schreiner Etiketten Adhesive paper label for labeling bottles etc.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173300A1 (en) * 1984-08-29 1986-03-05 National Starch and Chemical Corporation Aqueous surfactant-free base coating for metallized paper
WO1987005276A1 (en) * 1986-02-26 1987-09-11 Plastipak Packaging, Inc. Plastic container with fluid barrier label
US5096767A (en) * 1989-02-03 1992-03-17 Mitsubishi Paper Mills Limited Alkali-removable label support and label
DE19801148A1 (en) * 1998-01-14 1999-07-15 Schreiner Etiketten Adhesive paper label for labeling bottles etc.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9978291B2 (en) 2008-09-03 2018-05-22 Ccl Label Meerane Gmbh Label, especially for a reusable container

Also Published As

Publication number Publication date
AR059419A4 (en) 2008-04-09
ES1062169U (en) 2006-06-01
ES1062169Y (en) 2006-08-16

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