WO2007087099A3 - Method of removing scale and acidic composition used thereof - Google Patents

Method of removing scale and acidic composition used thereof Download PDF

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Publication number
WO2007087099A3
WO2007087099A3 PCT/US2006/062023 US2006062023W WO2007087099A3 WO 2007087099 A3 WO2007087099 A3 WO 2007087099A3 US 2006062023 W US2006062023 W US 2006062023W WO 2007087099 A3 WO2007087099 A3 WO 2007087099A3
Authority
WO
WIPO (PCT)
Prior art keywords
composition used
acidic composition
removing scale
addition
urea
Prior art date
Application number
PCT/US2006/062023
Other languages
French (fr)
Other versions
WO2007087099A2 (en
Inventor
James C Emerson
Lyle H Steimel
Original Assignee
Johnson Diversey Inc
James C Emerson
Lyle H Steimel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Diversey Inc, James C Emerson, Lyle H Steimel filed Critical Johnson Diversey Inc
Priority to CA002637314A priority Critical patent/CA2637314A1/en
Priority to MX2008009193A priority patent/MX2008009193A/en
Publication of WO2007087099A2 publication Critical patent/WO2007087099A2/en
Publication of WO2007087099A3 publication Critical patent/WO2007087099A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F14/00Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
    • C23F14/02Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/086Condensed phosphates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • C02F5/125Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/141Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/145Amides; N-substituted amides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/149Heterocyclic compounds containing nitrogen as hetero atom
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10Other heavy metals
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023Water in cooling circuits
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/08Corrosion inhibition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The corrosion inhibiting activity of quaternary ammonium compounds is enhanced by the addition of a carbamide, specifically urea, in particular, the aryfquinoiinium halide corrosion inhibitor's activity with respect to a galvanized surface is significantly enhanced by the addition of the urea.
PCT/US2006/062023 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof WO2007087099A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA002637314A CA2637314A1 (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof
MX2008009193A MX2008009193A (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/333,155 US20070164258A1 (en) 2006-01-17 2006-01-17 Enhanced galvanized corrosion inhibitor
US11/333,155 2006-01-17

Publications (2)

Publication Number Publication Date
WO2007087099A2 WO2007087099A2 (en) 2007-08-02
WO2007087099A3 true WO2007087099A3 (en) 2008-02-21

Family

ID=37831842

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/062023 WO2007087099A2 (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof

Country Status (4)

Country Link
US (1) US20070164258A1 (en)
CA (1) CA2637314A1 (en)
MX (1) MX2008009193A (en)
WO (1) WO2007087099A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2939146B1 (en) 2008-11-28 2012-11-16 Arkema France USE OF ALKANE SULFONIC ACID FOR RUST REMOVAL
WO2010151641A2 (en) 2009-06-25 2010-12-29 Henkel Ag & Co. Kgaa Metal loss inhibitor formulations and processes
ES2711924T3 (en) * 2010-01-25 2019-05-08 Westinghouse Electric Co Llc Process and composition to remove scale deposits formed on a metal surface within a steam generating system
CA3075329C (en) 2010-01-26 2022-11-01 Dominion Engineering, Inc. Method and composition for removing deposits
CN101892489B (en) * 2010-07-23 2012-11-07 广州唯普电力科技有限公司 Cleaning agent for flue dust scale on surface of gas heat exchanger of gas desulfurization system and preparation method thereof
FR3004460B1 (en) * 2013-04-16 2015-04-17 Cba World S A Rl PRODUCT FOR THE REMOVAL OF RESIDUES FROM INSOLUBLE CALCIUM SALTS.
US20150034315A1 (en) * 2013-07-31 2015-02-05 Schlumberger Technology Corporation Viscosified acid fluid and method for use thereof
CA2866658A1 (en) * 2014-10-02 2016-04-02 Fluid Energy Group Ltd. Synthetic acid compositions alternatives to conventional acids in the oil and gas industry
CN104761065A (en) * 2015-04-24 2015-07-08 张萍 Descaling agent
CA2892877A1 (en) * 2015-05-28 2016-11-28 Fluid Energy Group Ltd. Using non-regulated synthetic acid compositions as alternatives to conventional acids in the oil and gas industry
CA2892895A1 (en) 2015-05-28 2016-11-28 Fluid Energy Group Ltd. Novel organic acid compositions for use in the oil and gas industry
US10683576B2 (en) * 2017-03-27 2020-06-16 Baker Hughes, A Ge Company, Llc Corrosion inhibitors for passivation of galvanized coatings and carbon steel
FR3079528A1 (en) * 2018-03-29 2019-10-04 Suez Groupe PROCESS FOR PREVENTING THE FORMATION OF WHITE RUST ON A ZINC-COATED STEEL SURFACE
CN109183048A (en) * 2018-11-13 2019-01-11 中化化工科学技术研究总院有限公司 A kind of hydrochloric acid high temperature corrosion-retarding fog inhibitor and its application method

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1039187A (en) * 1963-06-26 1966-08-17 Dow Chemical Co A method for removing scale from metallic surfaces
US3345296A (en) * 1964-02-28 1967-10-03 Fmc Corp Corrosion inhibition
US3356526A (en) * 1964-05-13 1967-12-05 Armour & Co Method of preparing water-dispersible softener compositions and products produced thereby
US3634270A (en) * 1969-06-20 1972-01-11 Dow Chemical Co Inhibitor
US3985671A (en) * 1974-09-26 1976-10-12 Universal Oil Products Company Scale control agents
EP0408297A1 (en) * 1989-07-11 1991-01-16 Warwick International Group Limited Scale inhibition
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
US6866797B1 (en) * 2000-08-03 2005-03-15 Bj Services Company Corrosion inhibitors and methods of use

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335085A (en) * 1964-04-08 1967-08-08 Calgon Corp Inhibiting corrosion by acids
NL155315B (en) * 1964-06-09 1977-12-15 Ver Kunstmestfabriekn Mekog Al PROCEDURE FOR CLEANING IRONS OR STEEL, INTERNAL SURFACES OF INDUSTRIAL EQUIPMENT
US3332871A (en) * 1966-06-27 1967-07-25 Myron L Robinson Water treatment
US3779935A (en) * 1971-07-12 1973-12-18 Exxon Research Engineering Co Inhibition of corrosion
US4025359A (en) * 1974-04-01 1977-05-24 Connelly Jr George F Inhibited acid composition for cleaning water systems
US4138276A (en) * 1976-03-01 1979-02-06 J. M. Eltzroth & Associates, Inc. Coating compositions
WO1990001478A1 (en) * 1988-07-29 1990-02-22 Sri International Synergistic corrosion inhibitors based on substituted pyridinium compounds
US5697443A (en) * 1996-02-09 1997-12-16 Halliburton Energy Services, Inc. Method and composition for acidizing subterranean formations utilizing corrosion inhibitor intensifiers

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1039187A (en) * 1963-06-26 1966-08-17 Dow Chemical Co A method for removing scale from metallic surfaces
US3345296A (en) * 1964-02-28 1967-10-03 Fmc Corp Corrosion inhibition
US3356526A (en) * 1964-05-13 1967-12-05 Armour & Co Method of preparing water-dispersible softener compositions and products produced thereby
US3634270A (en) * 1969-06-20 1972-01-11 Dow Chemical Co Inhibitor
US3985671A (en) * 1974-09-26 1976-10-12 Universal Oil Products Company Scale control agents
EP0408297A1 (en) * 1989-07-11 1991-01-16 Warwick International Group Limited Scale inhibition
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
US6866797B1 (en) * 2000-08-03 2005-03-15 Bj Services Company Corrosion inhibitors and methods of use

Also Published As

Publication number Publication date
CA2637314A1 (en) 2007-08-02
MX2008009193A (en) 2008-09-10
US20070164258A1 (en) 2007-07-19
WO2007087099A2 (en) 2007-08-02

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