WO2007079580A1

WO2007079580A1 - Portable fuel cell systems and methods therefor

Info

Publication number: WO2007079580A1
Application number: PCT/CA2007/000029
Authority: WO
Inventors: Gerard F. Mclean; Mark Petersen; Jeremy Schrooten; Paul Sobejko; Joerg Zimmermann
Original assignee: Angstrom Power Inc.
Priority date: 2006-01-09
Filing date: 2007-01-09
Publication date: 2007-07-19
Also published as: JP5479737B2; EP1979960B1; US8785076B2; KR101382512B1; US20120321918A1; CA2636473C; CA2636473A1; CN101395735A; JP5854526B2; EP1979960A1; EP1979960A4; US20070184330A1; JP2014075357A; KR20080105040A; US8216743B2; CN101395735B; JP2009522734A

Abstract

A fuel cell system including, among other things, one or more of a fuel cell, a fuel reservoir, a current collecting circuit, a plenum, or a system cover. The fuel reservoir is configured to store fuel, and may include a regulator for controlling an output fuel pressure and a refueling port. A surface of the fuel reservoir may be positioned adjacent a first fuel cell portion. The current collecting circuit is configured to receive and distribute fuel cell power and may be positioned adjacent a second fuel cell portion. The plenum may be formed when the fuel reservoir and the first fuel cell portion are coupled or by one or more flexible fuel cell walls. The system cover allows air into the system and when combined when a fuel pressure in the plenum, may urge contact between the fuel cell and the current collecting circuit.

Description

PORTABLE FUEL CELL SYSTEMS AND METHODS

THEREFOR

PRIORITY OF INVENTION

This non-provisional application claims the benefit of priority under 35 U.S.C. § 119(e) to U.S. Provisional Patent Application Serial No. 60/757,750, filed January 9, 2006, which is herein incorporated by reference in its entirety.

TECHNICAL FIELD

This patent document pertains generally to fuel cells, and more particularly, but not by way of limitation, to a portable or micro-fuel cell system and methods therefor.

BACKGROUND

A fuel cell is an electrochemical energy conversion device that utilizes the reaction of fuel and oxygen to produce electricity. Fuel cells operate continuously as long as fuel is present. When hydrogen is used as the fuel, the only by-product is water vapor. The conversion reaction of the fuel cell occurs electrochemically and the energy is released as a combination of electrical energy and heat. The electrical energy can do useful work directly, while the heat can be dispersed.

Portable electrical devices, such as cellular phones and laptop computers (among others), demand a significant amount of electricity to operate. The primary and optionally secondary batteries that currently provide power to these devices are reaching performance limitations. As such, it is likely that battery sources may not be able to provide the necessary power to future portable devices, which will likely require even greater electrical power needs. Fuel cells are a viable alternative power source to traditional batteries, but are currently limited by their relatively large size, low energy density levels and insufficient power output. These drawbacks of current fuel cells are the result of, among other things, the awkward integration of current fuel cell components and positioning requirements in electrical devices.

Attorney Docket No. 2269.005WO1 It is with this recognition of the foregoing state of the technology that the present subject matter providing a portable fuel cell system that is able to maintain a high energy density and provide sufficient power output within an all-inclusive system has been conceived and is now set forth in the text and drawings associated with this patent document

SUMMARY

Embodiments of the present subject relate to a fuel cell system In one example, the fuel cell system includes at least one fuel cell or fuel cell layer including an anode, a cathode, and an electrolyte interposed therebetween, a fuel or a fuel storage material, a fuel reservoir including at least one surface positioned adjacent a first portion of the at least one fuel cell or fuel cell layer in which the fuel reservoir is configured to store the fuel or the fuel storage material, a current collecting circuit contacting a second portion of the at least one fuel cell or fuel cell layer in which the current collecting circuit is configured to receive and distribute current generated by the fuel cell or fuel cell layer, and a fuel plenum interposed between the at least one reservoir surface and the first portion of the at least one fuel cell or fuel cell layer

In another example, the fuel cell system includes a fuel reservoir, a system cover, an enclosed region, and at least one fuel cell The fuel reservoir is configured to store fuel or a fuel storage material The system cover is configured to be attachable with the fuel reservoir, thereby forming an enclosed region therein The at least one fuel cell includes one or more flexible walls comprising an anode or a cathode of the fuel cell The flexible walls are structurally arranged to form a reactant plenum and are supported, when pressurized, by a portion of one or both of the fuel reservoir or the system cover

Embodiments of the present subject matter also relate to methods of fabricating a fuel cell system One method includes forming a fuel cell or a fuel cell layer, coupling a fuel reservoir with a first portion of the fuel cell or fuel cell layer such that a fuel plenum is formed therebetween, disposing a current collecting circuit adjacent to a second portion of the fuel cell or fuel cell layer; disposing a system cover having at least one air access port over one or more of the current collecting circuit, the fuel cell or fuel cell layer, or a portion of the fuel reservoir, including positioning the at least one air access port near the second portion of the fuel cell or the fuel cell layer; and coupling the system cover with the fuel reservoir.

Another method includes forming a fuel reservoir configured to store fuel therein; forming a system cover; coupling the system cover with a portion of the fuel reservoir including forming an enclosed region; and disposing at least one fuel cell in the enclosed region including arranging one or more flexible fuel cell walls to form at least one reactant plenum. In various examples, forming the fuel reservoir and system cover includes forming a support for the one or more flexible fuel cell walls.

These and other aspects, advantages, and features of the present systems and methods will become apparent from a consideration of the following description and associated drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

In the drawings, which are not necessarily drawn to scale, like numerals describe similar components throughout the several views. Like numerals having different letter suffixes represent different instances of similar components. The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present patent document.

FIG. 1 illustrates an exploded view of a fuel cell system, as constructed in accordance with at least one embodiment. FIG. 2 illustrates a cross-sectional view of a fuel cell system, such as along line 2-2 of FIG. 1, as constructed in accordance with at least one embodiment.

FIGS. 3A-3D illustrate cross-sectional views of portions of a fuel cell system, including one or more fuel cells and a fuel reservoir, as constructed in accordance with various embodiments. FIG 4 illustrates a method of fabricating a fuel cell system, such as the fuel cell system illustrated in FIG 1, as constructed in accordance with at least one embodiment

FIGS 5A-5B illustrate cross-sectional views of portions of a fuel cell system, including one or more fuel cells, a fuel reservoir, and a system cover, as constructed in accordance with various embodiments

FIG 6 illustrates a method of fabricating a fuel cell system, such as the fuel cell system illustrated in FIG 5B, as constructed in accordance with at least one embodiment

DETAILED DESCRIPTION

The following detailed description includes references to the accompanying drawings, which form a part of the detailed description The drawings show, by way of illustration, specific embodiments in which the present systems and methods may be practiced These embodiments, which are also referred to herein as "examples," are described in enough detail to enable those skilled in the art to practice the present systems and methods The embodiments may be combined, other embodiments may be utilized, or structural and logical changes may be made without departing from the scope of the present systems and methods The following detailed descπption is, therefore, not to be taken in a limiting sense, and the scope of the present systems and methods are defined by the appended claims and their equivalents

In this document, the terms "a" or "an" are used to include one or more than one, and the term "or" is used to refer to a nonexclusive or unless otherwise indicated In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of descπption only and not of limitation

If they are going to be used to power electrical devices, such as cellular phones, satellite phones, laptop computers, computer accessories, displays, personal audio or video players, medical devices, televisions, transmitters, receivers, lighting devices including outdoor lighting or flashlights, electronic toys, power tools or any device conventionally used with batteries, it is desirable and even necessary for fuel cell systems to occupy only a small volume of the overall electrical device volume, maintain high energy density, and provide sufficient power output. However, current fuel cell systems are either too large to be use in the electrical devices or fail to maintain the high energy density and provide the energy required to power the electrical devices for a sufficient period of time. Advantageously, the present subject matter provides a fuel cell system that is able to maintain a high energy density and provide sufficient power output, yet still occupy a relatively small volume of the overall electrical device volume. In addition, the present fuel cell systems may operate passively, requiring no pumps, valves or heaters, and may instantly startup without having to rely on any supplemental battery or other power source. Referring now to the drawings, particularly to FIG. 1, there is illustrated a fuel cell system 100, including, among other things, a fuel cell layer 102 and a fuel reservoir (e.g., a fuel tank) 104. The fuel cell layer 102 includes one or more fuel cells each comprising an anode 107, a cathode 108, and an electrolyte 109 (e.g., an ion-exchange membrane) interposed therebetween. The fuel cell layer 102 utilized in the system 100 may be a planar fuel cell, such as an electrochemical cell structure having an electrical current-carrying structure which, at least in part, underlies an electrochemical reaction layer. In one such example, the cell includes an ion- exchange membrane with a catalyst layer on each side thereof. In another such example, the electrochemical cell structure includes a plurality of individual unit cells formed on a sheet of the ion-exchange membrane. In the fuel cell system 100, the cathode 108 of each cell is supplied with an air containing oxygen as an oxidizing agent, and the anode 107 of each cell is supplied with a fuel, such as hydrogen.

Many structural options are available for the fuel reservoir 104. For instance, in one example, the fuel reservoir 104 may comprise a cellular fuel tank in which a first and a second cellular component are interconnected and arranged to substantially fill an available electrical device space. In such an example, one or more internal ports fluidly connect the first and second cellular components, while one or more end caps are coupled to the ends of the components. In another example, the fuel reservoir 104 may comprise a structural filler and an outer enclosure wall conformably coupled to the structural filler. In yet another example, the fuel reservoir 104 may comprise an irregular shape (e.g., a non-circular, a non- rectangular, or a non-triangular shape), which substantially conforms to an available volume of an allotted space. The allotted space may be located in, among other things, a cellular phone, a satellite phone, a laptop computer, a computer accessory, a display, a personal audio or video player, a medical device, a television, a transmitter, a receiver, a lighting device including an outdoor light or a flashlight, an electronic toy, or a power tool. In a further example, and as illustrated in FIG. 1, the fuel reservoir 104 may comprise a void 152 to house optional components, such as a supplemental energy battery 122 or an electronic conditioning circuit 120.

In each of these structural examples, the fuel reservoir 104 encloses a fuel, such as hydrogen, or a fuel storage material, such as a hydrogen storage material. In one example, the fuel reservoir 104 encloses a composite hydrogen storage material comprising one or more active material particles and a binder, wherein the binder immobilizes the active material particles sufficient to maintain a relative spatial relationship between the active material particles. In one such example, the hydrogen storage material includes a metal hydride. Among other techniques, the hydrogen storage material may store hydrogen using one or both of physisorption or chemisorption. Power from the fuel cell layer 102 may be gathered by a current collecting circuit 106, which collects the current generated by the fuel cell layer 102 and routes it out of the system 100 via a power output connector 116 or alternatively into the conditioning electronics section 120 (e.g., an electronic conditioning circuit). In the example shown, but as may vary, the power output connector 116 is attached to both the current collector circuit 106 and the optional conditioning electronics section 120 The current collecting circuit 106 may be flexible to conform to a shape or location of the fuel cell layer 102 or other fuel cell system component In one example, the fuel cell system 100 provides a peak power output of up to about 4 Watts, while in other examples, the fuel cell system 100 may provide a peak power output of about 2-3 Watts In various examples, the average power output of the fuel cell system is between about 0 2-1 8 Watts, such about 0 5-1 5 Watts, about 0 75-1 25 Watts, or about 1 Watt In various examples, the fuel cell system 100 provides an energy density of about 200-600 Watt-hr/L or more, such as about 250- 350 Watt-hr/L or about 300 Watt-hr/L In various examples, the fuel cell system 100 includes a size of about 25 cubic centimeters or less In certain examples, the size of the fuel cell system 100 is about 10 cubic centimeter or less

In various examples, the fuel reservoir 104 includes a refueling port 112 and a pressure regulator 110 The refueling port 112 may be a pressure activated valve that allows a flow of fluid, for example, fluid fuel, into the fuel reservoir 104 In one example, the refueling port 112 includes a fuel inlet and at least one compressible member having a first sealing position and a second fueling position In such an example, the at least one compressible member is sealingly coupled with the fuel inlet port when the at least one compressible member is in the first sealing position In the example shown, the refueling valve 112 is coupled with a lower wall 114 of the fuel reservoir 104

The pressure regulator 110 may be designed to reduce a fuel reservoir pressure to a more constant, lower pressure that is acceptable to the fuel cell layer 102 In one example, the pressure regulator 110 is integrated with an upper wall 115 of the fuel reservoir 104 and includes a regulator body, a resilient member, a diaphragm, a regulator valve, and a seal member In such an example, the diaphragm and the regulator valve are movingly responsive to a pressure difference between a first chamber pressure and a second chamber pressure

In example shown, a fuel plenum 212 (FIG 2) is created by positioning the fuel cell layer 102 adjacent to at least one surface 150 of the fuel reservoir 104 A perimeter of the fuel reservoir surface 150 adjacent the fuel cell layer 102 may be sealed by a seal member 126, such as a compressive or elastic gasket or an adhesive, thereby forming the fuel plenum 212. In operation of this example, the fuel reservoir 104 is filled with fuel by pressurizing the refueling port 112. The pressure regulator 110 is then used to reduce or maintain the pressure in the fuel plenum 212 to a level sufficient for the operation and movement of the fuel cell layer 102. The pressure in the fuel plenum 212, in turn, urges or forces the fuel cell layer 102 against the current collecting circuit 106, providing contact between such components. In this way, the fuel cell system 100 can then be activated (i.e., the electrochemical reaction between, for example, hydrogen and oxygen can be initiated) simply by exposing the system 100 to ambient air. In an alternative example, the fuel cell layer 102 may be directly bonded to the current collecting circuit 106 such that current can be collected without pressure activation.

Optionally, the fuel cell system 100 may comprise a system cover 124 or a porous protective member 118. The system cover 124 may be utilized to assist the attachment of such things as the fuel cell layer 102 and the fuel reservoir 104.

Among other things, the system cover 124 may be constructed of a rigid, but ductile material, including steel or aluminum. Other examples of suitable materials for the system cover 124 include rigid plastics, such as Ultem® (a registered trademark of General Electric Company) or polyethylene. In various examples, the system cover 124 includes one or more air access ports 206 (FIG. 2) that allow at least partial access of the fuel cell cathode 108 to ambient air. As shown, the system cover 124 is configured to surround the fuel cell layer 102 and may be attached to the fuel reservoir 104 by any physical or chemical means, such as by welding, soldering, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures (e.g., fasteners or protrusions). The mechanical structure may optionally be releasable.

The porous protective member 118 may provide protection to the fuel cell cathode 108 while still allowing air to flow thereto. In one example, the porous protective member 118 protects the cathode 108 from interferents in the ambient air. In certain examples, the porous protective member 118 may be disposed adjacent to the fuel cell layer 102 on the anode side to provide protection to the anode 107 while still allowing fuel to flow therethrough.

FIG. 2 is a cross-sectional view, such as along line 2-2 of FIG. 1, of a fuel cell system 100 according to one example. In this example, a first fuel reservoir surface 150 contacts a first side of a seal member 126 on a perimeter thereof. A first side 250 of a fuel cell layer 102 contacts a second side of the seal member 126, such that a fuel plenum 212 is thereby created. A second side 252 of the fuel cell layer 102 contacts a current collecting circuit 106. A protective member 118 shields the fuel cell layer 102 and its components from interferents from the environment. A system cover 124 surrounds the fuel cell layer 102 and other components of the fuel cell system 100 (e.g., the protective porous member 118, the current collecting circuit 106, and the fuel plenum 212) and attaches to the fuel reservoir 104. The system cover 124 includes air access ports 206, which allow for ambient air to access the fuel cell layer 102 components, such as the cathode 108 (FIG. 1). Air flows in direction 208 through the air access ports 206 and the porous protective member 118 to provide oxygen to the cathode 108 of fuel cell layer 102.

In this example, as fuel (e.g., hydrogen) flows 210 from the fuel reservoir 104, through the pressure regulator 110, and into the fuel plenum 212, the fuel pressure 202 exerts a force on the fuel cell layer 102 in a direction toward the current collecting circuit 106, providing a contact therebetween. As shown, the mechanical binding of the system cover 124 to the fuel reservoir 104 exerts a cover pressure 204 on the current collecting circuit 106 toward the fuel cell layer 102 (i.e., in the opposite direction of fuel pressure 202), further providing efficient contact between the components of fuel cell system 100. There are many options for the fuel cell system 100. For instance, in certain examples, the fuel plenum 212 includes a size less than about lmm in width (wherein the width is the distance substantially perpendicular to the fuel reservoir 104 and extending from the fuel reservoir 104 to the fuel cell layer 102), while in other examples, the fuel plenum 212 includes a width greater than lmm. In certain examples, the current collecting circuit 106 may be disposed underneath the fuel cell layer 102, integrated with the fuel cell layer 102, or within the fuel plenum 212, rather than contacting a second side 252 of the fuel cell layer 102 In such examples, the connection between the fuel cell layer 102 and the current collecting circuit 106 may not be activated by the outward force 202 created through the fuel pressure, but rather through a more positive means of connection (e g , a bonding process)

FIGS 3A-3D illustrate cross-sectional views of portions of a fuel cell system 100, including, among other things, one or more fuel cell layers 102, a fuel reservoir 104, such as a hydrogen fuel reservoir, and one or more seal members 126 In FIG 3A, one fuel cell layer 102 is disposed adjacent the fuel reservoir 104 In FIG 3B, two fuel cell layers 102 are oppositely disposed around the fuel reservoir 104 In FIG 3C, three fuel cell layers 102 are disposed on three separate surfaces of the fuel reservoir 104 In FIG 3D, two fuel cell layers 102 are disposed on two separate surfaces of an irregularly-shaped (e g , a non-square or non-rectangular shape) fuel reservoir 104 The fuel cell systems shown in FIGS 1-2 can utilize the configurations shown in FIGS 3A-3B, among others As discussed in association with FIG 2, one or more seal members 126 may be disposed between the fuel cell layer 102 and the fuel reservoir 104 thereby forming a fuel plenum 212 into which fuel may flow 210 from the reservoir 104

FIG 4 illustrates one method 400 of fabricating a fuel cell system, such as the portable fuel cell system 100 shown in FIG 1 At 402, at least one fuel cell is formed In various examples, multiple fuel cells are formed to create a fuel cell layer Each fuel cell includes an anode, a cathode, and an electrolyte interposed therebetween At 404, a fuel reservoir is coupled with a first portion of the at least one fuel cell, thereby forming a fuel plenum therebetween In one example, the fuel reservoir is coupled with the first portion of the at least one fuel cell using a non- conductive adhesive In another example, a seal member is disposed between the fuel reservoir and the first portion of the at least one fuel cell

At 406, a current collecting circuit is disposed adjacent to a second portion of the at least one fuel cell In one example, the current collecting circuit is electrically coupled with a portable electronic device In another example, the current collecting circuit is electrically coupled with an electronic conditioning circuit

Further, at 408, a system cover having at least one air access port is disposed over one or more of the current collecting circuit, the at least one fuel cell, or a portion of the fuel reservoir, in which the at least one air access port is positioned near the second portion of the at least one fuel cell In one example, a protective porous member is disposed between the at least one air access port and the second portion of the at least one fuel cell At 410, the system cover is coupled with the fuel reservoir In one example, the system cover is coupled to the fuel reservoir by welding, soldeπng, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures (e.g , fasteners or protrusions) The mechanical structure may optionally be releasable

Referring now to FIGS 5A-5B, there is illustrated, in cross-section, a fuel cell system 100 including, among other things, a fuel cell layer 102 including one or more flexible walls 502, a fuel reservoir 104 configured to store fuel or a fuel storage material, a system cover 124, and an enclosed region 504 The fuel cell layer 102 includes one or more fuel cells each comprising an anode 107, a cathode 108, an electrolyte (not expressly shown) interposed between anode 107 and cathode 108, and a current collecting circuit 106

The system cover 124 is attachable with a portion of fuel reservoir 104 via, among other things, a weld, a solder, a braze, a cπmp, the use of an adhesive, or one or more mechanical structures, thereby forming the enclosed region 504, as shown The one or more fuel cell layers 102 may be disposed in the enclosed region 504 such that their respective flexible walls 502 are structurally arranged to form at least one reactant plenum 506 The one or more flexible walls 502 are supported by a portion of one or both of the fuel reservoir 104 or the system cover 124 In the example shown, the cathode 108 may be accessible from an outside of the flexible wall 502 and exposed to ambient air via air access ports in the system cover 124, while the anode 107 may be accessible from an inside of the flexible wall 502 and exposed to a reactant, such as hydrogen fuel The current collecting circuit 106 (integral with the fuel cell layer 102) is configured to receive current generated by the fuel cell layer 102 and distribute such current to, for example, a portable electronic device

In various examples, a plenum inlet 550 fluidly connects the reactant plenum 506 and the fuel reservoir 104 or ambient air As reactant enters via the plenum inlet 550, a reactant pressure pressurizes the fuel plenum 506, thus urging the one or more flexible walls 502 of the fuel cell layer 102 toward the supporting portions of one or both of the fuel reservoir 104 or the system cover 124

FlG 6 is a flow diagram illustrating one method 600 of fabricating a fuel cell system, such as the fuel cell system illustrated in FIG 5B At 602, a fuel reservoir configured to store fuel therein is formed At 604, a system cover is formed At 606, the system cover is coupled with a portion of the fuel reservoir such that an enclosed region is formed therein In one example, the system cover is coupled with the fuel reservoir via welding, soldering, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures (e g , fasteners or protrusions) The mechanical structure may optionally be releasable

At 608, at least one fuel cell including an anode, a cathode, and an electrolyte interposed therebetween is disposed in the enclosed region In vaπous examples, multiple fuel cells are formed to create a fuel cell layer In one example, one or more flexible fuel cell walls comprise one or both of the fuel cell anode or the fuel cell cathode Accordingly, in another example, disposing the at least one fuel cell into the enclosed region includes arranging the one or more flexible fuel cell walls to form at least one reactant plenum In various examples, forming the fuel reservoir and the system cover includes forming a support for the one or more flexible fuel cell walls such that when a reactant enters a plenum inlet and pressurizes the reactant plenum, the fuel cell walls expand and conform to a shape of the one or more supports At 610, a current collecting circuit is integrated with the at least one fuel cell In various examples, the current collecting circuit is configured to collect current from the at least one fuel cell and distribute such current to one or more electrical devices, such as portable electrical devices

Fuel cell systems and methods for their manufacture are provided herein Among other things, the present systems and methods provide for a fuel cell system providing sufficient power output and a high energy density, all within a relatively small amount of space The fuel cell system can operate as a stand alone power source or be integrated into an electrical device Further, the fuel cell system need not rely on pumps, valves or heaters for its operation, saving precious energy and electrical device volume

It is to be understood that the above description is intended to be illustrative, and not restrictive For example, the above-descπbed embodiments (and/or aspects thereof) may be used in combination with each other Many other embodiments will be apparent to those of skill in the art upon reviewing the above description The scope of the invention should, therefore, be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled In the appended claims, the terms "including" and "in which" are used as the plain-English equivalents of the respective terms "comprising" and "wherein " Also, in the following claims, the terms "including" and "comprising'^" are open- ended, that is, a system, device, article, or process that includes elements in addition to those listed after such a term in a claim are still deemed to fall within the scope of that claim Moreover, in the following claims, the terms "first," "second," and "third," etc are used merely as labels, and are not intended to impose numerical requirements on their objects

The Abstract of the Disclosure is provided to comply with 37 C F R §1 72(b), requiring an abstract that will allow the reader to quickly ascertain the nature of the technical disclosure It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims In addition, in the foregoing Detailed Descπption, various features may be grouped together to streamline the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed embodiments require more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive subject matter may lie in less than all features of a single disclosed embodiment. Thus the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as a separate embodiment.

Claims

WHAT IS CLAIMED IS

1 A fuel cell system comprising a fuel reservoir configured to store a fuel therein, a system cover attachable with one or more portions of the fuel reservoir, an enclosed region formed by the attachment of the fuel reservoir with the system cover, and at least one fuel cell disposed in the enclosed region, each fuel cell including one or more flexible walls structurally arranged to form a reactant plenum, wherein the one or more flexible walls are supported by a portion of one or both of the fuel reservoir or the system cover

2 The fuel cell system of claim 1 , further comprising a current collecting circuit in contact with the at least one fuel cell, the current collecting circuit configured to receive and distribute current generated by the at least one fuel cell

3 The fuel cell system of claim 2, wherein the current collecting circuit is integral with the at least one fuel cell

4 The fuel cell system of claim 2, wherein the current collecting circuit is configured to distnbute the fuel cell generated current to a portable electronic device

5 The fuel cell system of claim 4, wherein the portable electronic device includes a cellular phone, a satellite phone, a laptop computer, a computer accessory, a display, a personal audio or video player, a medical device, a television, a transmitter, a receiver, a lighting device, an electronic toy, or a power tool

6 The fuel cell system of any of claims 1-5, further comprising an inlet fluidly connecting the reactant plenum and the fuel reservoir

7. The fuel cell system of claim 6, wherein a pressure regulator is disposed within the inlet

8. The fuel cell system of any of claims 1 -7, further comprising a protective porous member disposed adjacent the at least one fuel cell.

9 The fuel cell system of any of claims 1-8, wherein a reactant pressure urges the one or more flexible walls towards the supporting portions of one or both of the fuel reservoir or the system cover

10. The fuel cell system of any of claims 1-9, wherein the attachment of the system cover and the fuel reservoir includes a weld, a solder, a braze, a crimp, the use of an adhesive, or a mechanical structure.

11. The fuel cell system of any of claims 1 -10, wherein the fuel reservoir comprises a refueling port.

12. A method of fabricating a fuel cell system, the method comprising, forming a fuel reservoir configured to store fuel therein; forming a system cover having one or more air access ports; coupling the system cover with one or more portions of the fuel reservoir, including forming an enclosed region, and disposing at least one fuel cell in the enclosed region, including arranging one or more flexible fuel cell walls to form at least one reactant plenum; wherein forming the fuel reservoir and the system cover includes forming a support for the one or more flexible fuel cell walls.

13. The method of claim 12, further compπsing contacting a current collecting circuit with the at least one fuel cell

14 The method of claims 12 or 13, further comprising disposing a protective porous member adjacent the at least one fuel cell

15 The method of any of claims 12-14, wherein coupling the system cover with the fuel reservoir includes welding, soldering, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures

16 A fuel cell system comprising at least one fuel cell including an anode, a cathode, and an electrolyte interposed therebetween, a fuel or fuel storage material, a fuel reservoir including at least one surface positioned adjacent a first portion of the at least one fuel cell, the fuel reservoir configured to store the fuel or the fuel storage material, a current collecting circuit in contact with a second portion of the at least one fuel cell, the current collecting circuit configured to receive and distribute power generated by the fuel cell, and a fuel plenum interposed between the at least one fuel reservoir surface and the first portion of the at least one fuel cell

17 The fuel cell system of claim 16, wherein a pressure in the fuel plenum urges the second portion of the at least one fuel cell against a portion of the current collecting circuit

18 The fuel cell system of claims 16 or 17, wherein the fuel plenum is at least partially surrounded by a seal member, the seal member providing a seal between the at least one fuel reservoir surface and the first portion of the at least one fuel cell

19. The fuel cell system of any of claims 16-18, wherein the at least one fuel reservoir surface and the first portion of the at least one fuel cell are coupled using an adhesive.

20. The fuel cell system of any of claims 16-19, further comprising a protective porous member positioned adjacent the at least one fuel cell.

21. The fuel cell system of any of claims 16-20, further comprising a system cover including at least one air access port, the system cover attachable to one or more portions of the fuel reservoir.

22. The fuel cell system of claim 21 , wherein a connection between the system cover and the fuel reservoir includes a weld, a solder, a braze, a crimp, an adhesive, or one or more mechanical structures.

23. The fuel cell system of claim 21 , wherein the system cover houses one or more of a protective porous member, the current collecting circuit, the at least one fuel cell, the fuel plenum, or a portion of the fuel reservoir.

24. The fuel cell system of claim 21 , wherein the system cover comprises steel, aluminum, or a rigid plastic.

25. The fuel cell system of any of claims 16-24, wherein the current collecting circuit is configured to distribute the power generated by the at least one fuel cell to a portable electronic device.

26. The fuel cell system of claim 25, wherein the current collecting circuit comprises a connection member attachable with the portable electronic device.

27. The fuel cell system of any of claims 16-26, further comprising an electronic conditioning circuit; and wherein the current collecting circuit is configured to distribute the power generated by the at least one fuel cell to the electronic conditioning circuit.

28. The fuel cell system of claim 27, wherein the electronic conditioning circuit is disposed in a void of the fuel reservoir.

29. The fuel cell system of any of claims 16-28, further comprising a supplemental energy battery; and wherein the supplemental energy battery is disposed, at least in part, in a void of the fuel reservoir.

30. The fuel cell system of any of claims 16-29, wherein the fuel comprises hydrogen.

31. The fuel cell system of any of claims 16-30, wherein the fuel storage material comprises a hydrogen storage material.

32. The fuel cell system of claim 31 , wherein the hydrogen storage material stores hydrogen by physiosorption.

33. The fuel cell system of claim 31 , wherein the hydrogen storage material stores hydrogen by chemiosorption.

34. The fuel cell system of any of claims 16-33, wherein the fuel storage material comprises a metal hydride.

35. The fuel cell system of any of claims 16-34, wherein the fuel reservoir includes a first cellular component interconnected with at least a second cellular component, the interconnected cellular components arranged to substantially fill an allotted space.

36. The fuel cell system of claim 35, wherein the allotted space is located in a portion of a cell phone, a personal digital assistant, a laptop computer, a digital camera, a game device, a portable television, or a flashlight.

37. The fuel cell system of any of claims 16-36, wherein the fuel reservoir comprises a structural filler and an outer enclosure wall conformably coupled to the structural filler.

38. The fuel cell system of any of claims 16-37, wherein the fuel reservoir includes one or both of a pressure regulator or a refueling port.

39. The fuel cell system of any of claims 16-38, wherein the fuel reservoir and the at least one fuel cell comprise a combined volume of about 25 cubic centimeters or less.

40. The fuel cell system of any of claims 16-39, wherein the at least one fuel cell is configured to generate an average electrical power of about 1 Watt or more and a peak power of about 3 Watts or more.

41. The fuel cell system of any of claims 16-40, wherein a system energy density comprises about 500 Watt-hours/liter.

42. A fuel cell system providing portable power, the system comprising: a fuel cell assembly, including at least one fuel cell including an anode on a first surface, a cathode on a second surface, and an electrolyte interposed therebetween; a protective porous member positioned near the fuel cell second surface; a current collecting circuit configured to receive and distribute power generated by the at least one fuel cell; a hydrogen reservoir including a surface positioned adjacent the fuel cell first surface, the hydrogen reservoir configured to store hydrogen fuel; a fuel plenum interposed between the hydrogen reservoir and the fuel cell first surface; and a system cover including at least one air access port, the system cover sized and shaped to house one or more of the protective porous member, the current collector circuit, the at least one fuel cell, the fuel plenum, or a portion of the hydrogen reservoir; wherein a fuel pressure in the plenum and a cover-generated pressure urge contact between the at least one fuel cell and the current collecting circuit.

43. The fuel cell system of claim 42, wherein the current collecting circuit distributes the power generated by the at least one fuel cell to a portable electronic device.

44. A method of fabricating a portable fuel cell system, the method comprising: forming a fuel cell; coupling a fuel reservoir with a first portion of the fuel cell, including forming a fuel plenum therebetween; disposing a current collecting circuit adjacent a second portion of the fuel cell; disposing a system cover having at least one air access port over one or more of the current collecting circuit, the fuel cell, or a portion of the fuel reservoir, including positioning the at least one air access port near the second portion of the fuel cell; and coupling the system cover with the fuel reservoir.

45. The method of claim 44, wherein coupling the fuel reservoir with the first portion of the fuel cell includes using an adhesive.

46. The method of claims 44 or 45, wherein coupling the system cover with the fuel reservoir includes welding, soldering, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures.

47. The method of any of claims 44-46, further comprising disposing a seal member between the fuel reservoir and the first portion of the fuel cell.

48. The method of any of claims 44-47, further comprising disposing a protective porous member between the at least one air access port and the second portion of the fuel cell.

49. The method of any of claims 44-48, further comprising electrically coupling the current collecting circuit with a portable electronic device.

50. The method of any of claims 44-49, further comprising electrically coupling the current collecting circuit with an electronic conditioning circuit.