WO2007065064A3 - Inhibiteur de la corrosion - Google Patents

Inhibiteur de la corrosion Download PDF

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Publication number
WO2007065064A3
WO2007065064A3 PCT/US2006/061101 US2006061101W WO2007065064A3 WO 2007065064 A3 WO2007065064 A3 WO 2007065064A3 US 2006061101 W US2006061101 W US 2006061101W WO 2007065064 A3 WO2007065064 A3 WO 2007065064A3
Authority
WO
WIPO (PCT)
Prior art keywords
compound
composition
hydrogen sulfide
corrosion inhibitor
thiophosphorus
Prior art date
Application number
PCT/US2006/061101
Other languages
English (en)
Other versions
WO2007065064A2 (fr
Inventor
Bradley G Harrell
David G Pollard
Michael J Zetlmeisl
Robert J Zeigler
Joseph L Stark
Michael Mcelhinney
Original Assignee
Baker Hughes Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baker Hughes Inc filed Critical Baker Hughes Inc
Priority to BRPI0619195-9A priority Critical patent/BRPI0619195A2/pt
Priority to CN200680044904.8A priority patent/CN101316915B/zh
Priority to EP06846353A priority patent/EP1963462A4/fr
Priority to CA002631572A priority patent/CA2631572A1/fr
Priority to KR1020087012612A priority patent/KR101364325B1/ko
Publication of WO2007065064A2 publication Critical patent/WO2007065064A2/fr
Publication of WO2007065064A3 publication Critical patent/WO2007065064A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C10G7/10—Inhibiting corrosion during distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • C10G75/02—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C10G2300/203—Naphthenic acids, TAN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives

Abstract

L’invention concerne une composition et un procédé pour inhiber la corrosion provoquée par l’acide naphténique dans les fluides et prévoit l’utilisation d’une combinaison d’un composé de thiophosphore et d’un composé d’élimination à base de sulfure d’hydrogène. Le composé d’élimination à base de sulfure d’hydrogène permet d’améliorer la performance du composé de thiophosphore et peut être inclus dans la composition à des concentrations relativement faibles. Le traitement peut être appliqué sur des fluides, notamment des pétroles bruts et leurs fractions plus légères.
PCT/US2006/061101 2005-11-30 2006-11-20 Inhibiteur de la corrosion WO2007065064A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0619195-9A BRPI0619195A2 (pt) 2005-11-30 2006-11-20 inibidor de corrosão
CN200680044904.8A CN101316915B (zh) 2005-11-30 2006-11-20 缓蚀剂
EP06846353A EP1963462A4 (fr) 2005-11-30 2006-11-20 Inhibiteur de la corrosion
CA002631572A CA2631572A1 (fr) 2005-11-30 2006-11-20 Inhibiteur de la corrosion
KR1020087012612A KR101364325B1 (ko) 2005-11-30 2006-11-20 부식 억제제

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74143005P 2005-11-30 2005-11-30
US60/741,430 2005-11-30

Publications (2)

Publication Number Publication Date
WO2007065064A2 WO2007065064A2 (fr) 2007-06-07
WO2007065064A3 true WO2007065064A3 (fr) 2007-12-21

Family

ID=38092918

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/061101 WO2007065064A2 (fr) 2005-11-30 2006-11-20 Inhibiteur de la corrosion

Country Status (7)

Country Link
US (1) US20070119747A1 (fr)
EP (1) EP1963462A4 (fr)
KR (1) KR101364325B1 (fr)
CN (1) CN101316915B (fr)
BR (1) BRPI0619195A2 (fr)
CA (1) CA2631572A1 (fr)
WO (1) WO2007065064A2 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008120236A2 (fr) * 2007-03-30 2008-10-09 Dorf Ketal Chemicals (I) Private Limited Inhibition de la corrosion à haute température par l'acide naphténique au moyen de composés de soufre organo-phosphoreux et de leurs combinaisons
CN101688118B (zh) * 2007-04-04 2014-10-29 多尔夫凯塔尔化学制品（I）私人有限公司 用新的协同增效的含磷化合物来抑制环烷酸腐蚀
US20090061234A1 (en) * 2007-09-04 2009-03-05 Baker Hughes Incorporated Method for Inhibiting Corrosion of Metal in Distillation Units Caused by Organic Acids
ES2614763T3 (es) 2007-09-14 2017-06-01 Dorf Ketal Chemicals (I) Private Limited Aditivo novedoso para inhibir la corrosión por ácido nafténico y procedimiento de uso del mismo
EP2340296B1 (fr) * 2008-08-26 2014-10-08 Dorf Ketal Chemicals (I) Private Limited Nouvel additif pour l'inhibition de la corrosion par les acides et procédé d'utilisation du nouvel additif
MX349928B (es) * 2008-08-26 2017-08-21 Dorf Ketal Chemicals I Pvt Ltd Un aditivo polimerico novedoso y efectivo para inhibir la corrosion de acidos naftenicos y metodo para el uso del mismo.
CN101987973B (zh) * 2009-07-30 2015-04-29 中国石油化工股份有限公司 一种降低含酸烃油腐蚀性的方法
US9260669B2 (en) * 2011-03-24 2016-02-16 Baker Hughes Incorporated Synergistic H2S/mercaptan scavengers using glyoxal
US9068128B2 (en) 2011-10-18 2015-06-30 Baker Hughes Incorporated Method for reducing hydrogen sulfide evolution from asphalt and heavy fuel oils
SG11201502518QA (en) * 2012-11-06 2015-05-28 Exxonmobil Res & Eng Co Method for identifying layers providing corrosion protection in crude oil fractions
US10655232B2 (en) * 2014-09-03 2020-05-19 Baker Hughes, A Ge Company, Llc Additives to control hydrogen sulfide release of sulfur containing and/or phosphorus containing corrosion inhibitors
US20160060520A1 (en) * 2014-09-03 2016-03-03 Baker Hughes Incorporated Scavengers for sulfur species and/or phosphorus containing compounds
EP3737781A4 (fr) * 2018-01-12 2021-04-14 Baker Hughes Holdings LLC Additifs pour limiter la libération de sulfure d'hydrogène à partir d'inhibiteurs de corrosion contenant du soufre et/ou contenant du phosphore

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5484542A (en) * 1992-09-04 1996-01-16 The Lubrizol Corporation Sulfurized overbased compositions
US5712230A (en) * 1997-03-10 1998-01-27 The Lubrizol Corporation Additive compositions having reduced sulfur contents for lubricants and functional fluids
US5863415A (en) * 1996-05-30 1999-01-26 Baker Hughes Incorporated Control of naphthenic acid corrosion with thiophosporus compounds

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2643227A (en) * 1950-02-21 1953-06-23 Cities Service Oil Co Method of inhibiting corrosion of metals
US3595790A (en) * 1969-10-22 1971-07-27 Lubrizol Corp Oil soluble highly basic metal salts of organic acids
US3711403A (en) * 1971-01-18 1973-01-16 Petrolite Corp Corrosion inhibitors employing phosphate esters of cyclic amidines
US3909447A (en) * 1972-07-17 1975-09-30 Petrolite Corp Mixtures of thiophosphates, oxygen phosphates and pyrophosphates
US4339349A (en) * 1980-02-11 1982-07-13 Petrolite Corporation Corrosion inhibitors for limited oxygen systems
US4443609A (en) * 1980-05-19 1984-04-17 Petrolite Corporation Tetrahydrothiazole phosphonic acids or esters thereof
US4511481A (en) * 1983-08-31 1985-04-16 Mobil Oil Corporation Multifunctional additives
US4842716A (en) * 1987-08-13 1989-06-27 Nalco Chemical Company Ethylene furnace antifoulants
US5169411A (en) * 1989-03-03 1992-12-08 Petrolite Corporation Suppression of the evolution of hydrogen sulfide gases from crude oil, petroleum residua and fuels
GB8906406D0 (en) * 1989-03-21 1989-05-04 Bp Chem Int Ltd Removal of sulphides
US4941994A (en) * 1989-07-18 1990-07-17 Petrolite Corporation Corrosion inhibitors for use in hot hydrocarbons
CA2017047C (fr) * 1989-08-01 1999-08-17 Jerry J. Weers Methode d'elimination du sulfure d'hydrogene des hydrocarbures
US5266185A (en) * 1990-09-10 1993-11-30 Petrolite Corporation Method of suppression of hydrogen sulfide with heterocyclic-amine aldehyde reaction products
US5500107A (en) * 1994-03-15 1996-03-19 Betz Laboratories, Inc. High temperature corrosion inhibitor
US5552085A (en) * 1994-08-31 1996-09-03 Nalco Chemical Company Phosphorus thioacid ester inhibitor for naphthenic acid corrosion
US5630964A (en) * 1995-05-10 1997-05-20 Nalco/Exxon Energy Chemicals, L.P. Use of sulfiding agents for enhancing the efficacy of phosphorus in controlling high temperature corrosion attack
US6267938B1 (en) * 1996-11-04 2001-07-31 Stanchem, Inc. Scavengers for use in reducing sulfide impurities
US5863445A (en) * 1997-03-27 1999-01-26 Control Screening L.L.C. Etched coil unibody digital detector
US6063346A (en) * 1998-06-05 2000-05-16 Intevep, S. A. Process for scavenging hydrogen sulfide and mercaptan contaminants from a fluid
GB0031710D0 (en) * 2000-12-27 2001-02-07 Dyno Oil Field Chemicals Process for the reduction or elimination of hydrogen sulphide
US7255796B2 (en) * 2004-07-08 2007-08-14 General Electric Company Method of preventing hydrogen sulfide odor generation in an aqueous medium

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5484542A (en) * 1992-09-04 1996-01-16 The Lubrizol Corporation Sulfurized overbased compositions
US5863415A (en) * 1996-05-30 1999-01-26 Baker Hughes Incorporated Control of naphthenic acid corrosion with thiophosporus compounds
US5712230A (en) * 1997-03-10 1998-01-27 The Lubrizol Corporation Additive compositions having reduced sulfur contents for lubricants and functional fluids

Also Published As

Publication number Publication date
EP1963462A4 (fr) 2012-01-04
EP1963462A2 (fr) 2008-09-03
BRPI0619195A2 (pt) 2011-09-20
CN101316915B (zh) 2015-07-22
US20070119747A1 (en) 2007-05-31
KR101364325B1 (ko) 2014-02-18
CN101316915A (zh) 2008-12-03
CA2631572A1 (fr) 2007-06-07
WO2007065064A2 (fr) 2007-06-07
KR20080070833A (ko) 2008-07-31

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