Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
  • B65D41/02—Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
  • B65D41/04—Threaded or like caps or cap-like covers secured by rotation
  • B65D41/0492—Threaded or like caps or cap-like covers secured by rotation formed by several elements connected together
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
  • B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
  • B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
  • B65D41/348—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt the tamper element being rolled or pressed to conform to the shape of the container, e.g. metallic closures
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D49/00—Arrangements or devices for preventing refilling of containers
  • B65D49/02—One-way valves
  • B65D49/04—Weighted valves

Definitions

• the invention relates to the field of capping capsules intended to seal containers, typically bottles, intended to contain an alcoholic beverage, typically alcohols, aperitifs, digestive.
• the invention relates more particularly to the field of composite closure caps, so called because they are provided with means complementary to the basic means of a "standard" closure cap ", said base means including means for fastening to the neck and sealing means.
• the invention more specifically relates to the field of screw closure caps comprising a threaded insert or a threaded element cooperating with a threaded neck of a container.
• French Patent FR 2,802,181 already discloses a composite closure cap in the name of Pechiney Emballage Alimentaire, former name of Applicant.
• This capsule which comprises a plastic insert with a seal, a threaded skirt and a metal wall covering Pinsert also includes means for giving weight and / or volume to the portion of the capsule located above the seal forming its sealing means.
• the present invention aims, as besides corking capsules according to the French patent FR 2 802 181, to offer the manufacturer of alcohol, spirits and other
• the present invention aims to give the capsules a particular visual appearance that differentiates them from traditional corking capsules.
• the composite closure cap intended to close the neck of a bottle to contain a liquid, typically an alcoholic beverage, said neck comprising a counter-glass ring and an external thread, said composite closure cap having a height H in an axial direction and comprising: a) a metal capsule having a metal head and a metal skirt, of axial height Hc ⁇ H and of average diameter DM, comprising a crimping zone of said metal capsule typically around said neck of the bottle or around a part intended to be fixed on said neck, and a means of easy first opening of said composite closure cap, a lower part of said metal skirt remaining integral with said neck when said composite closure cap is unscrewed during a first opening of said neck, b) a plastic insert integral with an upper part said metal capsule, said insert comprising a head and an internally threaded skirt of axial height Hi ⁇ Hc.
• the capsules according to the invention completely renew the image of traditional corking capsules. They offer with said first and second outer parts, two complementary supports of any type of decoration, this m which offers immense possibilities to differentiate these capsules from traditional capsules, by incorporating presentation elements or decor generally reserved for the packaging of luxury.
• Said composite closure cap comprises a metal cap, which piece is also called a "shell", composed of a head and a metal skirt.
• the metal skirt has a zone, typically annular, for crimping the shell around the shell. lower shoulder of the counter-ring of glassware or crimping around an intermediate piece which is fixed on the neck, as the lower part, referenced 81 and shown in 0 figure 7, a refill device,
• said composite closure cap comprises a second outer piece joined to the metal skirt of the shell, so as to cover and mask the lower part of said metal skirt, said second piece typically having on its outer surface a decoration pattern.
• Said second outer piece may form a cylindrical tubular piece of diameter Ds between Dp and D M , the inside diameter of said cylindrical tubular piece being typically close to DM.
• Said second outer part can also cooperate with the lower part of the metal skirt of the shell, so that said - AT -
• second outer piece remains ⁇ xi ⁇ lement integral with said lower portion during said first opening of said neck.
• Said outer part may be a fixed part, secured axially to the
• Metal skirt of the shell for example at its lower part, typically thanks to a layer of adhesive, its axial height Hs being at least equal to 0.5 times the height HB of the lower part of the skirt of the shell, so as to cover most of said bottom portion while allowing the capping operation.
• This fixed piece is arranged such that it leaves a free access to a crimping zone, typically annular, of said metal skirt.
• Said outer part may also be a moving part, which moves axially and which has, relative to said metal skirt, two positions
• a positioning means predetermined stable, thanks to a positioning means. These two positions are a low position, in which said movable part leaves free access a typically annular crimping zone of the metal skirt of the shell, and a high position, in which said movable part, raised axially in the direction of said first outer part after 0 crimping, mask at least the crimped area of said metal skirt.
• said movable part When in the up position, said movable part cooperates with the lower part of the metal skirt of the shell so as to remain attached to said neck after unscrewing the composite closure cap.
• the positioning means used for the second movable outer part may comprise the axial cooperation of axial locking means carried by said moving part, and axial locking means carried by said metal skirt.
• This positioning means may comprise or form a reversible latching means so as to ensure a reversible passage
• This positioning means is designed in such a way that even when the second outer part is in the high position, unscrewing of said composite closure cap can be performed, said second outer part remaining integral with the neck, by means of the axial locking means for the high position. Furthermore, the axial locking means used for said lower position allows said second outer piece to remain attached to the metal skirt of the shell when the capsule is not yet crimped on the neck.
• said positioning means is designed such that said second outer part, after having been kept in a low position to facilitate access of the crimping tools to the crimping zone of the metal skirt of the shell, is placed in position. high and kept locked in this high position, so as to prevent access to the crimped area.
• said second outer part may be made of a material chosen from plastics, metals and metallized plastics.
• it may comprise at least one transparent zone, typically a transparent upper part, so as to reveal the line of weakness or said line of bridges, and thus to make visible said first opening of said neck.
• the capsule according to the invention comprises at least a first outer part assembled to said metal cap by a connecting means, said first outer part having at least one manual gripping peripheral portion of average diameter DP> DM, with a DP report / DM typically ranging from 1.1 to 1.5, said average diameter Dp being that of an axial surface, said envelope surface, surrounding said first outer part, so that when said composite closure cap closes said neck , a manual rotation of said outer part causes that of said metal capsule and that of said insert, thus allowing the unscrewing of said composite closure cap and the opening of said neck.
• said first outer part is made of a material chosen from: a metal, a plastic material, a glass, a ceramic, a refractory material, a composite material, a natural material, a material
• the first outer part forms or comprises means for weighing said composite closure cap
• the peripheral portion of said first outer part may have an envelope surface of revolution. But it can also, to facilitate manual gripping and rotation of the composite closure cap:
• N 0 ranging from 3 to 18, typically angularly distant from 3607N;
• N' typically ranging from 1 to 10, typically equidistant in said axial direction.
• said insert is made integral with said metal cap using a layer of an adhesive material but it can also be made integral with said metal cap by heat-sealing the threaded skirt of said insert on the metal skirt of said metal cap. at least said metal skirt of said metal capsule being coated internally
• said inner layer of said metal cap comprises, in the divided state, said plastic material of said insert, so as to allow said heat-sealing of said insert in said metal cap.
• said first outer part is secured to said metal cap with a layer of an adhesive material.
• the upper part of said metal skirt comprises a plurality of radial orifices, so that said insert and said first outer part can be secured by heat-sealing through said plurality of radial orifices, all or part of said insert and said first outer part being of a chemical nature chosen to allow said heat sealing.
• Said plastic insert advantageously comprises a seal forming an insert, secured to said insert and intended to seal said neck.
• said insert 0 is advantageously secured to a shutter.
• the insert comprises for example a plastic head which comprises at least one annular lip which cooperates with said seal or said shutter, so as to seal said neck.
• the metal skirt of the shell comprises an axial abutment shoulder for said first outer piece, typically for a lower end of said first outer piece, said shoulder dividing said metal skirt into a smaller diameter top portion and in a lower part of larger diameter.
• said first outer part has a lower end which is connected tangentially to the metal skirt of the shell, so that said lower end and said metal skirt are connected without discontinuity by presenting typically the same diameter.
• the composite closure cap according to the invention may comprise a device, called “pouring device”, intended to facilitate the flow of said liquid, said pouring device comprising a flexible annular lip, and being able to be removably secured to said composite closure cap, typically through a rubbing contact with an axial projection of said insert, and an inner skirt adapted to cooperate with the interior of said neck, typically with at least one circular fin, so as to be secured to said neck waterproof.
• pouring device intended to facilitate the flow of said liquid
• said pouring device comprising a flexible annular lip, and being able to be removably secured to said composite closure cap, typically through a rubbing contact with an axial projection of said insert, and an inner skirt adapted to cooperate with the interior of said neck, typically with at least one circular fin, so as to be secured to said neck waterproof.
• the composite closure cap according to the invention may also comprise a device, called “non-refill device", intended to prevent any fraudulent filling of said bottle by said neck, said refilling device being provided with reversible securing means to said 0 composite closure cap, so that the refill device is attached to the neck during the capping operation and remains attached to said neck when the composite closure cap is unscrewed.
• this device can be fixed directly irreversibly on the glass ring.
• the external thread of the neck is not on the glass ring but in the upper part of this filling device irreversibly fixed to the neck, the latter having a screw thread complementary to that of Pinsert threaded .
• Figures la and Ib illustrate a first variant of the composite capsule
• tubular piece (6 ') is a fixed part
• FIG. 1a shows the capsule (1) placed on the neck (2) before crimping the capsule
• FIG. 1b shows the capsule (1) after crimping
• said skirt (31) then comprising a crimped annular zone (36 ' ) formed by a radial compression of a crimping wheel, said compression having been represented by a radial arrow in Figure 1b.
• FIGS. 2a to 3d illustrate another variant, in which the tubular piece
• FIG. 2a is a view of the capsule (1), the tubular member (6 1 ) being in the so-called "high" position.
• Figure 2b shows the capsule (1) of Figure 2a placed on the neck (2) to be crimped.
• FIG. 2c represents the capsule (1) of FIG. 2b after
• FIG. 2d represents the capsule (1) of FIG. 2c after rising upwards in the so-called high position of said tubular piece (6 '), so that the
• FIG. 3a shows the capsule (1) crimped at the neck (2) as in FIG. 2d, before a first opening by unscrewing the upper part (19) of the capsule (1), said unscrewing being represented by an arrow placed above the capsule (1).
• Figure 3b shows the part
• Figure 3o upper (19) separated by unscrewing, while Figure 3c shows the lower portion (19 ') remaining integral with the neck (2).
• Figure 3d similar to FIG. 3b shows another variant of capsule in which the line of weakness (330) is not masked by the lower end (55) of said first outer part (5) but by the upper end (62) of said second outer piece (6).
• FIG. 4 is a side view of a neck (2) on which has been crimped a capsule (1) of the same type as that shown in FIGS. 2a to 3d, said second outer part (6), represented in the up position , comprising an upper part (03), typically transparent so as to make possible a visual inspection of said weakening line (330), said upper part comprising two ribs (630) facilitating a possible manual gripping of said second outer part ( 6).
• FIG. 5 illustrates the case of a capsule of the same type as those represented w in FIGS. 2a to 3d and 4 including a pouring device (9), temporarily secured to said insert (4) by means of an axial projection (45) of hooking comprising a plurality of hooking lugs, said pouring device (9) comprising at its upper part a flexible annular lip (90) and an inner skirt (91) adapted to enter the neck (2) and to be assembled 0 force said neck (2), sealingly, through a plurality of fins (910), the radial height is such that the radial distance from their ends relative to the axis is greater than the internal diameter of the neck.
• These fins are here represented schematically, “entering” into the neck glass and not inclined upwards.
• the pouring device (9) is a pouring device (9 ') comprising a non-refillable means comprising an inner cage (92) capable of housing a ball (94) intended to rest on a circular lip lower (93) when said capsule (1) is in a vertical position, so as to close the central orifice delimited by said circular lip (93), but to let the contents of the bottle when the latter is sufficiently inclined.
• its skirt (91) comprises at its upper end an outer radial projection forming an axial stop (911) of said spout against the rim (22) of the neck (2 ).
• Figure ⁇ a is a half-axial left section of the capsule crimped on the neck (2).
• Figure ⁇ b is a sectional view of the pouring device (9 ').
• Figure ⁇ c is a side view of the pouring device (9 ').
• FIGS. 7a and 7b illustrate the case of another capsule (1), still of the same type as those of FIGS. 2a to 3c, 4, 5 and 6a to 6c, comprising an infrabability device (8).
• FIG. 7a shows, on its left half-part, a side view similar to FIG. 4, and on its right half-section, an axial sectional view of said capsule (1) provided with said unconfillable device (8).
• Figure 7b shows the capsule snapped to the neck (2).
• FIG. 7c illustrates the sealing of the neck (2) by radial compression of the periphery (70) of the seal (7), thanks to a radial compression ring (46) formed inside the skirt (41, 41 '). ) of said insert (4).
• the metal cap (3) is a metal cap (3 1 ) whose metallic skirt (31) comprises a shoulder (310) forming an axial stop for said outer piece (5, 5 "), typically for a lower end (55) of said outer piece (5, 5 ").
• Figures 9b to 9e are top views of various shape variants of said first outer member (5).
• Figure 9a shows in section, the upper part of the composite capsule.
• Figure 9b the first outer part
• the first outer part illustrated in FIG. 9c has a principal direction in a longitudinal plane comprising said axial direction.
• FIGS. 9d and 9e are variants of FIG. 9b according to which said first outer skirt (52) comprises a plurality of axial grooves (53), as illustrated in FIG. 9d, or axial ribs (53 ') as illustrated on FIG. figure 9e,
• Plastic moldings were made of PP or PE. These same pieces of PA or PET have also been manufactured. We also used second outer piece (6) of metal tube portions with relief embossed surface,
• capsule (1) According to the type of capsule (1), the various parts of said capsule (1) have been assembled, either as indicated in the description, or in a manner that is self-evident, namely:
• the insert (4) and said first outer part (5) which can be bonded in particular by adhesive layers.
• said first (5) and second ( ⁇ ) outer parts have been decorated either before assembly or after assembly, once said capsule (1) formed.
• Example 3 illustrated in FIG. 5, knowing that this capsule comprises common features of the invention, which can be detailed and / or referenced in other figures.
• the composite closure cap 1 of this example comprises a pouring device 9 comprising in its upper part a flexible annular lip 90 and an inner skirt 91 adapted to enter the neck 2 and be force-fitted to said neck, in a sealed manner, thanks to a plurality of fins 910.
• the composite closure cap 1 comprises a metal cap (or
• Figure 5 illustrates the skirt 31 crimped at 36 'on the shoulder 210 of the counter ring 21
• a line ⁇ ff ⁇ iblatorium 330 used as a means of easy first opening of said composite closure cap.
• the composite closure cap 1 comprises an insert 4 made of plastics material, integral with an upper part 32 of the shell 3, said insert comprising a sealing head 40 and an internally threaded skirt 4V, here particularly thin, of axial height Hi ⁇ Hc.
• the composite closure cap 1 comprises a first outer part 5, assembled to the metal cap 3, having a manual gripping peripheral portion 50 of average diameter Dp> DM, so that when said composite closure cap closes said neck , a manual rotation of said outer part causes that of said metal capsule and that of said insert, thus allowing the unscrewing of said composite closure cap and the opening of said neck.
• the composite closure cap 1 comprises a second outer piece 6 assembled to the metal skirt 31 so as to cover and mask the lower part 35 of said metal cap.
• This second outer part 6 is a movable part 61, which moves axially and which has, relative to the metal skirt 31, two predetermined stable positions: a low position in which the movable part 61 leaves free access to the crimping zone annular of the metal skirt of the shell, and a high position in which said movable part 61, raised axially in the direction of the first outer part 5 after crimping, masks at least the crimped area 36 "of said metal skirt.
• the positioning means 18 used for the second movable outer part 61 uses the axial cooperation of axial locking means 64 and 631 carried by said moving part, and axial locking means 311 and 312 carried by the metal skirt 31.
• This means of positioning could form a reversible latching means so as to ensure a reversible passage from one position, high or low, to the other position, respectively low or high, but here, the positioning means 18 is designed so that said second movable outer part 61, after having been kept in the low position to facilitate access of the crimping tools to the crimping zone of the metal skirt of the shell, is placed in the high position and kept locked in this upper position, to prevent access to the crimped area 36 '.
• the second outer part 61 is held in the raised position by the cooperation of the axial locking means 64 and 311. It is kept in a low position thanks to the cooperation of the axial locking means 631 and 312. axial locking means used for the low position allows said second outer piece 61 to remain attached to the metal skirt 31 of the shell 3 when the capsule is not yet crimped on the neck.
• the metal skirt 31 carries, just below the crimping zone 36 or the crimped zone 36 ', a first annular ring 37 whose two slopes 311 and 312 serve as latching means, the first slope 311 serving in the high position, irreversible snap-on abutment to a lip 64 of the movable part 61 and the second 312 serving, in the lower position, a reversible snap-in abutment to the recessed oblique wall 631 of the upper end; of said movable part 61.
• the second outer part 61 is made of polyolefin, typically a polypropylene. It has not been opacified (metallization, lacquering, setting a decor, etc.) in its upper part 63, so that it is transparent and it is possible to see the line of weakness 330 when said second movable outer part 61 is in the up position.
• the second outer part 61 is crystal polystyrene.
• the upper part 63 is provided with annular ribs 630 which facilitate the manual gripping of the second outer part 61.
• the second outer piece 61 must slide a distance large enough to reach its low position, so as to leave access to the crimping zone wide enough so that the knobs or other crimping tools can reach the shoulder 210 of the counter. ring 21 without disturbing the other parts of the capsule.
• This distance is typically between 5 and 15 mm.
• the lower position may correspond to the abutment of the lower end 611 of the second outer part 61 on the neck 2 of the bottle, which is conical at this point.
• the second outer part 61 which has the shape of a cylindrical sleeve, must have an internal diameter typically greater than 1 mm with respect to the diameter of the lower part of the metal skirt 31.
• said metallic skirt 31 is provided with a second annular ring 38, of radial height typically equal to 0.5 mm, which allows the second outer part 61 to slide along the axis 10 while remaining centered.
• the composite closure cap of this example 3 (FIG. 5) comprises a pouring device 9 intended to facilitate the flow of the liquid, which comprises a flexible annular lip 90, and which is able to be secured in a removable manner to the closure cap.
• composite 1 thanks to the insert 4, by rubbing contact on the axial projection 45 of the shutter 47 secured to the insert 4.
• This device pourer 9 also includes an inner skirt 91 adapted to cooperate with the interior of the neck 2, with at least one circular fin 910, so as to be secured to the neck 2 sealingly.
• the fins 910 are shown schematically here, "tucked" into the glass and not inclined upwards.
• a pouring device 9 1 also acting as a refill device. It is also provided with a flexible annular lip 90 and which can be secured with the insert 4. It also comprises an inner skirt 91 which cooperates with the inside of the neck 2 by means of several circular fins 910, deformed by the introduction of the device into the interior of the neck (FIG 6a).
• the sealing is ensured by the action of the annular lip 470 of the shutter 47 which causes the plating of the flexible annular lip 90 on the rim 22 of the neck.
• the composite closure capsules of Examples 4 and 5 ( Figures 6 and 7) have fillers 8 and 9 '.
• the non-refillable devices 8 and 9 ' are intended to prevent any fraudulent filling of the bottle by the neck 2. They are secured to the composite closure cap 1:
• the device 8 comprises a threaded part which makes it possible to screw it on the insert 4 (in this case, the screwing of the composite closure cap is no longer done on the glass ring: the external thread 20 'of the neck belongs to the device 8 irreversibly fixed to the neck),
• the device 9 which also has a pouring device function as in Example 3 is connected to the insert 4 by means of a rubbing contact on an axial projection 45 of the shutter 47 secured Pinsert 4. These devices are attached to the neck 2 during the capping operation and remain attached to said neck when said composite closure cap 1 is unscrewed.
• the non-refillable device 8 of Example 5 comprises: a) a so-called upper part 80 comprising a threaded ring 800 adapted to cooperate with the threaded skirt 41 of the insert 4; b) a so-called lower part 81 comprising a fastening skirt 810 able to cooperate with the glass counter-ring 21, and an inner wall forming a cage 811 comprising a lower orifice 812, c) a movable member 82, here a ball 820, able to move in said cage and to seal, by gravity, said lower orifice 812 when said composite closure cap 1 is in a vertical position, so as to form a non-return means.
• said upper part 80 comprises an upper grid 801
• said lower part 81 comprises a vault 813 provided with lateral orifices allowing the passage of the liquid
• Said non-refill device 8 also comprises a protection piece 83, typically a metal plate portion 83 ', which is housed between the upper grid 801 and the vault 813, so as to form an obstacle to any attempt to reach and move said movable member 82 (the ball 820), while allowing a normal flow of liquid out of said bottle.
• a protection piece 83 typically a metal plate portion 83 ', which is housed between the upper grid 801 and the vault 813, so as to form an obstacle to any attempt to reach and move said movable member 82 (the ball 820), while allowing a normal flow of liquid out of said bottle.
• Composite capping capsule 1 Axial direction 10
• Non-refillable device —
• Airtight fixing flange 910 Axial stopper 91 1

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Closures For Containers (AREA)
• Mechanical Treatment Of Semiconductor (AREA)
• Diaphragms For Electromechanical Transducers (AREA)
• Cosmetics (AREA)
• Paper (AREA)
• Road Signs Or Road Markings (AREA)

Priority Applications (8)

Applications Claiming Priority (2)

Publications (1)

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Family Applications (1)

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Cited By (1)

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Citations (4)

Family Cites Families (5)

• 2006
  • 2006-11-22 ES ES06831155T patent/ES2328284T3/es active Active
  • 2006-11-22 WO PCT/FR2006/002567 patent/WO2007060325A1/fr active Application Filing
  • 2006-11-22 DE DE602006007622T patent/DE602006007622D1/de active Active
  • 2006-11-22 CN CNA2006800439991A patent/CN101312891A/zh active Pending
  • 2006-11-22 AU AU2006316388A patent/AU2006316388A1/en not_active Abandoned
  • 2006-11-22 EP EP06831155A patent/EP1973794B1/fr active Active
  • 2006-11-22 CA CA002627991A patent/CA2627991A1/fr not_active Abandoned
  • 2006-11-22 RU RU2008125128/12A patent/RU2404096C2/ru not_active IP Right Cessation
  • 2006-11-22 PL PL06831155T patent/PL1973794T3/pl unknown
  • 2006-11-22 US US12/093,401 patent/US20080272086A1/en not_active Abandoned
  • 2006-11-22 AT AT06831155T patent/ATE435167T1/de not_active IP Right Cessation
  • 2006-11-22 JP JP2008541789A patent/JP2009516627A/ja not_active Abandoned
  • 2006-11-22 ZA ZA200804721A patent/ZA200804721B/xx unknown
  • 2006-11-23 CL CL2006003249A patent/CL2006003249A1/es unknown

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