WO2007060089A3 - Alpha-(beta-ketocarbonyl)-functional organo-silicium compounds and the production thereof - Google Patents

Alpha-(beta-ketocarbonyl)-functional organo-silicium compounds and the production thereof Download PDF

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Publication number
WO2007060089A3
WO2007060089A3 PCT/EP2006/068162 EP2006068162W WO2007060089A3 WO 2007060089 A3 WO2007060089 A3 WO 2007060089A3 EP 2006068162 W EP2006068162 W EP 2006068162W WO 2007060089 A3 WO2007060089 A3 WO 2007060089A3
Authority
WO
WIPO (PCT)
Prior art keywords
radical
compounds
ketocarbonyl
production
contain
Prior art date
Application number
PCT/EP2006/068162
Other languages
German (de)
French (fr)
Other versions
WO2007060089A2 (en
Inventor
Christian Herzig
Original Assignee
Wacker Chemie Ag
Christian Herzig
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie Ag, Christian Herzig filed Critical Wacker Chemie Ag
Publication of WO2007060089A2 publication Critical patent/WO2007060089A2/en
Publication of WO2007060089A3 publication Critical patent/WO2007060089A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Polymers (AREA)

Abstract

The invention relates to novel (-ketocarbonyl)-functional organo-silicium compounds, which contain at least one Si-bound radical B which is selected from the group of general formulae -CR12-Y-C(=O)-CHR3-C(=O)-CH2R3 (I) and -CR12-Y-C(=O)-CR3=C(-OH)-CH2R3 (II). In said formulae, Y represents an oxygen atom or a radical of formula NR2-, R1 represents a hydrogen atom or an alkyl-, cycloalkyl-, aryl- or aralkyl radical having 1 - 30 carbon atoms, R2 represents a radical R1 or an organic radical which can contain one or several heteratoms selected from the group comprising B, N, O, P, S, Si, Ti, F, Cl, Br and J, R3 represents a radical R1. The invention also relates to a method for the production thereof, wherein diketens (1) of general formula R3-CH=C-CHR3-C=O (III), or the derivatives thereof, are reacted with organo-silicium compounds (2), which contain, per molecule, at least one Si- bound radical A of general formula -CR12-YH (IV), wherein Y, R1 and R3 have the above mentioned meaning, optionally, in the presence of one or several organic compounds (3), which delay or prevent the reaction of the radical A in (2) with ketocarbonyl compounds.
PCT/EP2006/068162 2005-11-24 2006-11-07 Alpha-(beta-ketocarbonyl)-functional organo-silicium compounds and the production thereof WO2007060089A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005056050A DE102005056050A1 (en) 2005-11-24 2005-11-24 New alpha-(beta-ketocarbonyl)-functional organosilicon compound useful in an aqueous solution together with an aminopolysiloxane in the manufacture of elastomer film
DE102005056050.4 2005-11-24

Publications (2)

Publication Number Publication Date
WO2007060089A2 WO2007060089A2 (en) 2007-05-31
WO2007060089A3 true WO2007060089A3 (en) 2007-08-02

Family

ID=37965117

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/068162 WO2007060089A2 (en) 2005-11-24 2006-11-07 Alpha-(beta-ketocarbonyl)-functional organo-silicium compounds and the production thereof

Country Status (2)

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DE (1) DE102005056050A1 (en)
WO (1) WO2007060089A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006020816A1 (en) * 2006-05-04 2007-11-08 Wacker Chemie Ag Organosilicon compounds containing beta-ketoamide groups and organic polymers bonded via enamine bonds, and methods for their preparation
DE102006020815A1 (en) * 2006-05-04 2007-11-08 Wacker Chemie Ag Process for the preparation of beta-ketocarbonyl-functional organosilicon compounds
DE102006038062A1 (en) * 2006-08-16 2008-02-21 Wacker Chemie Ag Chelatpolymerisation
US10920369B2 (en) 2016-11-16 2021-02-16 Wacker Chemie Ag Dispersions of β-ketocarbonyl-functional organosilicon compounds
KR102407951B1 (en) * 2017-12-06 2022-06-13 와커 헤미 아게 Emulsion of beta-ketocarbonyl-functional organosilicon compound

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU555104A1 (en) * 1975-07-21 1977-04-25 The method of obtaining-silicon-substituted amides of hydroxy acids
EP0010130A1 (en) * 1978-08-28 1980-04-30 Bayer Ag Sila-substituted 1,4-dihydropyridine derivatives, processes for their preparation, pharmaceutical compositions and process for their preparation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU555104A1 (en) * 1975-07-21 1977-04-25 The method of obtaining-silicon-substituted amides of hydroxy acids
EP0010130A1 (en) * 1978-08-28 1980-04-30 Bayer Ag Sila-substituted 1,4-dihydropyridine derivatives, processes for their preparation, pharmaceutical compositions and process for their preparation

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002432299, retrieved from XFIRE Database accession no. Reaction ID 1517264 *
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002432300, retrieved from XFIRE Database accession no. BRN 2414120 *
MIRONOV, V.F. ET AL., J. GEN. CHEM. USSR, vol. 37, 1967, pages 1821 - 1823 *
TACKE R. ET AL.: "Sila-Analoga", ZEITSCHRIFT FÜR NATURFORSCHUNG B ANORG. CHEM., vol. 35, no. 4, 1980, pages 494 - 501, XP009083303 *
WEE A G H ET AL: "The rhodium(II)-catalyzed reaction of N-bis(trimethylsilylmethyl)diazoamides: steric, electronic and conformational effects", TETRAHEDRON LETTERS, ELSEVIER, AMSTERDAM, NL, vol. 43, no. 35, 26 August 2002 (2002-08-26), pages 6173 - 6176, XP004373267, ISSN: 0040-4039 *
WEE, A. ET AL.: "The Bis(trimethylsilyl)methyl Group as an Effective N-Protecting Group and Site-Selective Control Element in Rhodium(II)-Catalyzed Reaction of Diazoamides", J. ORG. CHEM., vol. 70, no. 21, 14 October 2005 (2005-10-14), pages 8372 - 8380, XP002432277 *

Also Published As

Publication number Publication date
DE102005056050A1 (en) 2007-05-31
WO2007060089A2 (en) 2007-05-31

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