WO2007053382A1 - An embedded strain layer in thin soi transistors and a method of forming the same - Google Patents
An embedded strain layer in thin soi transistors and a method of forming the same Download PDFInfo
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- WO2007053382A1 WO2007053382A1 PCT/US2006/041560 US2006041560W WO2007053382A1 WO 2007053382 A1 WO2007053382 A1 WO 2007053382A1 US 2006041560 W US2006041560 W US 2006041560W WO 2007053382 A1 WO2007053382 A1 WO 2007053382A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/031—Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT]
- H10D30/0321—Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT] comprising silicon, e.g. amorphous silicon or polysilicon
- H10D30/0323—Manufacture or treatment of FETs having insulated gates [IGFET] of thin-film transistors [TFT] comprising silicon, e.g. amorphous silicon or polysilicon comprising monocrystalline silicon
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6704—Thin-film transistors [TFT] having supplementary regions or layers in the thin films or in the insulated bulk substrates for controlling properties of the device
- H10D30/6713—Thin-film transistors [TFT] having supplementary regions or layers in the thin films or in the insulated bulk substrates for controlling properties of the device characterised by the properties of the source or drain regions, e.g. compositions or sectional shapes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/6704—Thin-film transistors [TFT] having supplementary regions or layers in the thin films or in the insulated bulk substrates for controlling properties of the device
- H10D30/6727—Thin-film transistors [TFT] having supplementary regions or layers in the thin films or in the insulated bulk substrates for controlling properties of the device having source or drain regions connected to bulk conducting substrates
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/67—Thin-film transistors [TFT]
- H10D30/674—Thin-film transistors [TFT] characterised by the active materials
- H10D30/6741—Group IV materials, e.g. germanium or silicon carbide
- H10D30/6743—Silicon
- H10D30/6744—Monocrystalline silicon
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/791—Arrangements for exerting mechanical stress on the crystal lattice of the channel regions
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/01—Manufacture or treatment
- H10D62/021—Forming source or drain recesses by etching e.g. recessing by etching and then refilling
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/40—Crystalline structures
- H10D62/405—Orientations of crystalline planes
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
- H10D86/01—Manufacture or treatment
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
- H10D86/201—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI
Definitions
- the present invention relates to the formation of integrated circuits, and, more particularly, to the formation of SOI-like transistor types, such as folly and partially depleted transistors, formed in and on a thin semiconductor layer, and having strained channel regions, by using an embedded strain layer to enhance charge carrier mobility in the channel region.
- SOI-like transistor types such as folly and partially depleted transistors
- CMOS complementary metal-oxide-semiconductor
- N-channel transistors and P-channel transistors are formed on a substrate including a crystalline semiconductor layer.
- a MOS transistor irrespective of whether an N- channel transistor or a P-channel transistor is considered, comprises so-called PN junctions that are formed by an interface of highly doped drain and source regions with an inversely doped channel region disposed between the drain region and the source region.
- the conductivity of the channel region i.e., the drive current capability of the conductive channel
- the conductivity of the channel region is controlled by a gate electrode formed above the channel region and separated therefrom by a thin insulating layer.
- the conductivity of the channel region upon formation of a conductive channel due to the application of an appropriate control voltage to the gate electrode, depends on the dopant concentration, the mobility of the majority charge carriers, and, for a given extension of the channel region in the transistor width direction, on the distance between the source and drain regions, which is also referred to as channel length.
- the overall conductivity of the channel region substantially determines the performance of the MOS transistors.
- the reduction of the channel length, and associated therewith the reduction of the channel resistivity renders the channel length a dominant design criterion for accomplishing an increase in the operating speed of the integrated circuits.
- of the transistor dimensions involves a plurality of issues associated therewith that have to be addressed so as to not unduly offset the advantages obtained by steadily decreasing the channel length of MOS transistors.
- One major problem in this respect is the development of enhanced photolithography and etch strategies so as to reliably and reproducibly create circuit elements of critical dimensions, such as the gate electrode of the transistors, for a new device generation.
- epitaxially grown regions are formed with a specified offset to the gate electrode, which are referred to as raised drain and source regions, to provide increased conductivity of the raised drain and source regions, while at the same time maintaining a shallow PN junction with respect to the gate insulation layer.
- One efficient mechanism for increasing the charge carrier mobility is the modification of the lattice structure in the channel region, for instance by creating tensile or compressive stress in the vicinity of the channel region to produce a corresponding strain in the channel region, which results in a modified mobility for electrons and holes, respectively.
- creating tensile strain in the channel region increases the mobility of electrons, wherein, depending on the magnitude and direction of the tensile strain, an increase in mobility of 50% or more may be obtained, which, in turn, may directly translate into a corresponding increase in the conductivity.
- compressive strain in the channel region may increase the mobility of holes, thereby providing the potential for enhancing the performance of P-type transistors.
- the hole mobility of PMOS transistors is enhanced by forming a strained silicon/germanium layer in the drain and source regions of the transistors, wherein the compressively strained drain and source regions create uniaxial strain in the adjacent silicon channel region.
- the drain and source regions of the PMOS transistors are selectively recessed, while the NMOS transistors are masked and subsequently the silicon/germanium layer is selectively formed in the PMOS transistor by epitaxial growth.
- the present invention is directed to a technique that enables the formation of SOI transistors, such as fully or partially depleted transistors, in which an enhanced strain generating mechanism is provided to create a desired strain substantially throughout the entire active region located below a gate electrode structure. Consequently, an efficient strain generating mechanism is provided for thin SOI transistors, in which a channel may form at an interface between a gate insulation layer and the active layer and also at an interface between a buried insulation layer and the overlying semiconductor layer. Consequently, a significant performance gain may be achieved in fully and partially depleted SOI transistors.
- a transistor device comprises a substrate having formed thereon a first crystalline semiconductor layer and a buried insulating layer formed on the first crystalline semiconductor layer. Moreover, the device comprises a second crystalline semiconductor layer formed on the buried insulating layer and a gate electrode, which is formed above the second crystalline semiconductor layer. Finally, the transistor device comprises a drain and source region that comprises a strained semiconductor material that extends into the first semiconductor layer.
- a semiconductor device comprises a substrate having formed thereon a first crystalline semiconductor layer, a buried insulating layer formed on the first crystalline semiconductor layer and a second crystalline semiconductor layer formed on the buried insulating layer.
- the semiconductor device further comprises a first transistor having a first drain and source region that is formed in the second semiconductor layer.
- the semiconductor device comprises a second transistor having a second drain and source region that comprises a strained semiconductor material, wherein the second drain and source region extends from the second semiconductor layer into the first semiconductor layer.
- a method comprises forming a recess adjacent to a first gate electrode of a first transistor, wherein the first gate electrode is formed above a substrate comprising a first crystalline semiconductor layer, a buried insulating layer formed on the first crystalline semiconductor layer and a second crystalline semiconductor layer formed on the buried insulating layer. Moreover, the recess extends into the first crystalline semiconductor layer. Furthermore, the method comprises epitaxially growing a strained semiconductor material in the recess.
- Figures Ia-Ig schematically show cross-sectional views of a transistor element during various manufacturing stages, in which a strained semiconductor material is formed through a buried insulating layer in order to create strain continuously along substantially the entire depth in the channel region of the transistor element in accordance with illustrative embodiments of the present invention.
- FIGS 2a-2f schematically show cross-sectional views of a semiconductor device including SOI transistors of different conductivity types, one of which receives a strained semiconductor material for providing strain at an interface between a buried insulating layer and the overlying semiconductor material in accordance with still further illustrative embodiments of the present invention.
- the present invention is directed to a technique that contemplates the generation of strain in channel regions of SOI-like transistors by providing a strained semiconductor material in the vicinity of the channel regions.
- the strained semiconductor material is formed in such a way that it may also efficiently provide a required strain in the vicinity of an interface between the active semiconductor layer and the buried insulating layer, thereby providing the potential for efficiently using this interface as an additional channel for charge carrier transportation in sophisticated fully and partially depleted SOI transistors.
- SOI-type transistors may receive a very thin active semiconductor layer, such as a silicon-based layer, having a thickness of 100 nm and even significantly less so that not only the region immediately below the corresponding gate insulation layer may be used as a channel but also the interface between the active layer and the buried insulating layer may be used for charge carrier transport.
- active semiconductor layer such as a silicon-based layer
- conventional strain-inducing mechanisms by means of a strained semiconductor material may not allow an efficient generation of strain in the vicinity of the buried insulating layer, since during the epitaxial growth of the embedded strained semiconductor material, a significant portion of the original semiconductor material has to be maintained to provide a respective growth template for the subsequent growth process.
- the crystalline material below the buried insulating layer may be efficiently used as a template for the epitaxial growth process, thereby enabling the growth of a strained semiconductor material also in the vicinity of the interface between the buried insulating layer and the active semiconductor layer formed thereon.
- dd!(HMteili ' ty"ih : -idJ££sffl ⁇ lhe transistor characteristics may also be provided, since the crystalline characteristics of the epitaxially grown strained semiconductor material may be decoupled to a high degreed from the crystalline characteristics of the active semiconductor layer formed on the buried insulating layer.
- the crystalline characteristics, such as crystalline orientation, material composition and the like, of the semiconductor material acting as a growth template may be selected with respect to enhancing the characteristics of the epitaxially grown strained semiconductor material, while the initial characteristics of the active semiconductor layer formed on the buried insulating layer may be selected in accordance with other process and device requirements, such as increased mobility of charge carriers for other transistors, which may not receive the strained semiconductor material.
- the present invention may be applied to any SOI-like transistors in which strain is generated by embedded strained semiconductor material, even if the active semiconductor layer may not be appropriate for the formation of thin SOI-like transistors, in which a second channel region is formed in the vicinity of the buried insulating layer.
- a highly efficient strain mechanism may be provided wherein additionally crystalline characteristics of the strained semiconductor material may be adapted, for instance in terms of crystalline orientation, to obtain an overall enhanced performance compared to conventional approaches with embedded strain layers not extending through the buried insulating layer and into a crystalline substrate material. Consequently, unless otherwise explicitly stated in the description and in the appended claims, the present invention should not be considered to be restricted to a specific SOI architecture.
- Figure Ia schematically shows a transistor device 100 comprising a substrate 101, which may represent any appropriate substrate or a carrier material for forming thereabove SOI-like transistors:
- the substrate 101 may represent a bulk semiconductor substrate having formed thereon a crystalline semiconductor layer 102 or a silicon-based bulk substrate having formed thereon the semiconductor layer 102 followed by a buried insulating layer 103 and a second crystalline semiconductor layer 104, which may also be referred to as an "active" layer.
- the substrate 101 in combination with the layers 102, 103 and 104, may represent an SOI-like architecture, wherein the active layer 104 may not necessarily be comprised of silicon and, hence, the term SOI-like transistor or architecture needs to be understood as a generic term without restricting the layer 104 to a silicon material.
- the first semiconductor layer 102 maybe comprised of silicon and the second semiconductor layer 1(104 ttleMsfeH ⁇ 'epfeS'd ⁇ it ⁇ a's ⁇ liis'feft ⁇ ased material, such as a doped silicon material, a silicon/germanium material and the like.
- the semiconductor layers 102 and 104 may differ in at least one characteristic, such as crystal orientation, material composition and the like.
- the first and second semiconductor layers 102 and 104 may represent silicon-based layers having a different crystalline orientation, wherein, for instance, the layer 102 may have a (110) or (100) orientation while the layer 104 may have a (100) or (110) orientation.
- a corresponding arrangement may be highly advantageous in applications in which different types of transistors are to be formed and the charge carrier mobility may be different for the respective crystalline orientations. Illustrative embodiments with different transistor types will be described with reference to Figures 2a-2f in more detail later on.
- the transistor device 100 further comprises a gate electrode 105 formed above the second semiconductor layer 104 and separated therefrom by a gate insulation layer 106.
- the gate electrode 105 may be comprised, in this stage of manufacture, of doped polysilicon or any other appropriate material.
- the gate insulation layer 106 may be comprised of silicon dioxide, silicon nitride, silicon oxynitride and the like or any other appropriate material, wherein any high-k dielectric materials may also be used, possibly in combination with one or more of the materials specified before.
- the gate electrode 105 may have a length, i.e., in Figure Ia, the horizontal extension of the gate electrode 105, of 100 nm and significantly less or even 50 nm and even less for devices of the 90 nm technology, the 65 nm technology and the like.
- the gate electrode 105 may have formed thereon a capping layer 107, which may be comprised of silicon nitride, silicon oxynitride, silicon dioxide, a combination of any of the previous materials and the like.
- a liner 109 for instance comprised of silicon dioxide, may be formed so as to enclose the gate electrode 105 including the capping layer 107 and the second semiconductor layer 104.
- a spacer layer 108 for instance comprised of silicon nitride or any other appropriate material that may be used in a subsequent etch and epitaxial growth process as a corresponding hard mask, is formed substantially conformally on the device 100.
- a typical process flow for forming the transistor device 100 as shown in Figure Ia may comprise the following processes.
- a gate dielectric material may be formed by deposition and/or oxidation, followed by the deposition of a gate electrode material layer such as doped or undoped polysilicon.
- highly advanced photolithography and etch techniques may be used to pattern the deposited layer stack, wherein any anti-reflective coating (ARC) layers may also have been formed which may represent the f ⁇ pp&glt ⁇ i ⁇ lf ⁇ Pail 107.
- the patterning process for the gate electrode 105 and the gate insulation layer 106 may be based on a hard mask which may be maintained so as to act as the capping layer 107 in a subsequent manufacturing process.
- a separate capping layer may be formed and may be patterned along with the gate electrode material and the gate insulation dielectric.
- the liner 109 may be deposited on the basis of well-established recipes followed by the deposition of the spacer layer 108, which may be accomplished by plasma enhanced chemical vapor deposition (PECVD).
- PECVD plasma enhanced chemical vapor deposition
- an anisotropic etch process may be performed to pattern the spacer layer 108 in accordance with well-established spacer formation techniques, thereby removing the material on horizontal portions, while substantially maintaining the material formed on the sidewalls of the gate electrode 105. Thereafter, exposed portions of the liner 109 may be removed, for instance by highly selective etch processes as are well established in the art.
- Figure Ib schematically shows the transistor device 100 in a further advanced manufacturing stage, in which the device 100 is subjected to an etch process 110.
- the gate electrode 105 is encapsulated by spacers 108A, i.e., the residuals of the preceding anisotropic spacer etch process, and the capping layer 107 so that the etch process 110 results in a recess or cavity 111, whose lateral offset to the gate electrode 105 is substantially determined by the spacer 108 A and the residual of the liner, now referred to as
- the etch process 110 is designed to etch through the active layer 104, the buried insulating layer 103 and into the first semiconductor layer 102.
- the etch process 110 is designed to etch through the active layer 104, the buried insulating layer 103 and into the first semiconductor layer 102.
- etching process 110 may be performed with different etch chemistries to provide the desired etch behavior.
- highly selective and anisotropic etch recipes are well established for a plurality of materials such as silicon with respect to silicon dioxide, silicon nitride and the like.
- well-established recipes may be used to etch through the layer 104, wherein, depending on the etch recipe used, this phase of the etch process 110 may stop at the buried insulating layer 103.
- the etch chemistry may be appropriately selected for etching through the buried insulating layer 103, which may, for instance, be provided in the form of a silicon dioxide layer, wherein well-established recipes may be used.
- a highly selective etch process for removing material of the buried insulating layer 103 in relation to the material of the semiconductor layer 102 may be used so that the corresponding etch process may be reliably stopped at the layer 102, thereby ensuring a high degree of etch uniformity across the entire substrate 101.
- a final etch step of the process 110 may be performed to etch into the semiconductor ikyeAlfeidfaJths b'asMr ⁇ - ⁇ B'lRsi ⁇ blished recipes.
- the final etch step may be performed in a highly uniform manner, especially as only a small penetration into the layer 102 is required. Consequently, a high degree of uniformity of the depth of the recess 111 across the substrate 101 may be obtained.
- the residuals 104A, 103A of the layers 104 and 103 are maintained under the masked gate electrode 105.
- the device 100 may now be prepared for a subsequent epitaxial growth process for forming a strained semiconductor material in the recess
- Figure Ic schematically shows the device 100 after the completion of the selective epitaxial growth process, thereby forming a strained semiconductor material 112 in the recess 111.
- Selective epitaxial growth processes i.e., a selective growth of the semiconductor material 112 on a crystalline "template" having a similar lattice spacing without a substantial adhesion of semiconductor material 112 on dielectric materials, such as the spacers 108A and the capping layer 107, may be established on the basis of well-known recipes or may be obtained on the basis of test runs.
- the crystalline semiconductor layer 102 may be comprised of silicon having a specified surface orientation with respect to surface orientation of the substrate 101, i.e., in Figure Ic, the horizontal orientation, and a material having a similar lattice spacing such as silicon/germanium, silicon/carbon and the like may be grown on the exposed semiconductor layer 102, thereby forming substantially the same lattice structure. Accordingly, the semiconductor material 112 may be considered as a strained semiconductor material, since the "natural" lattice spacing of silicon/germanium or silicon/carbon is different from the lattice spacing of substantially pure silicon.
- the natural lattice spacing is greater compared to silicon and, therefore, if the material 112 is grown with the same lattice spacing as the underling template of the layer 102, a strained material is formed which tends to provide compressive stress to adjacent materials, such as the active layer 104A, which may include the channel region or regions of the transistor 100.
- the transistor 100 may represent a P-channel transistor, the active area of which, i.e., the layer 104 A, is to receive a compressive strain so as to enhance the mobility of holes, which represent the majority charge carriers.
- the compressively strained semiconductor material may represent a P-channel transistor, the active area of which, i.e., the layer 104 A, is to receive a compressive strain so as to enhance the mobility of holes, which represent the majority charge carriers.
- the material 112 may be formed as a material having a tensile strain, thereby also creating a tensile strain in the region 104A.
- the material 112 may be provided in the form of silicon/carbon and the like.
- the strained material layer 112 may not necessarily extend down into the layer 102, as long as the material 112 is formed at least along substantially the entire thickness of the layer 104 A.
- the same material as provided in the layer 102 may be deposited and thereafter the deposition atmosphere may be adjusted to deposit the strained material 112.
- silicon when the layer 102 is comprised of silicon, in a first stage, silicon may be deposited up to a height that is anywhere below the interface 114 between the layers 104A and 103 A, and, thereafter, a silicon/germanium or silicon/carbon, depending on the device requirements, may be deposited to form the strained semiconductor material 112.
- Figure Id schematically shows a transistor device 100 according to other illustrative embodiments, wherein, starting from the device as shown in Figure Ib, a spacer 113 may be formed on the sidewalls of the recess 111 to minimize the influence of the exposed sidewall portions 104S of the layer 104A with respect to the epitaxial growth process.
- an appropriate spacer layer for instance comprised of silicon dioxide, may be deposited in a conformal fashion on the basis of well-established recipes and thereafter an anisotropic etch process may be performed to remove the material of the spacer layer from horizontal device portions.
- the spacer elements 113 may be formed on the spacers 108 A and on sidewalls 104S of the layers 104A, 103A, thereby encapsulating the layer 104A during the subsequent epitaxial growth process.
- a first portion 112A may be formed in the recess 111 on the basis of an appropriate epitaxial growth process, wherein only the material of the semiconductor layer 102 acts as a growth template, since any other crystalline regions, such as the sidewalls 104S of the layer 104 A are covered by the spacer 113.
- a corresponding arrangement may be advantageous in embodiments in which the layers 104A and 102 may differ in crystalline orientation, material composition and the like, since now the epitaxial growth process forming the material 112A is determined by the crystalline characteristic of the layer 102 only.
- Figure Ie schematically shows the transistor device 100 in a further advanced manufacturing stage according to further illustrative embodiments, wherein a portion of the spacer elements 113 is removed to expose the sidewall 104S of the layer 104A.
- a corresponding partial removal of the spacer elements 113 to leave a residual 113A may be accomplished by a highly selective isotropic etch process, wherein corresponding recipes ⁇ 'Wld&l ⁇ eMifiS'Mbiilklldfeaillt ⁇ of materials. For instance, silicon dioxide may be efficiently removed in a highly selective manner by diluted hydrofluoric acid and the like.
- the epitaxial growth process may be continued, wherein the crystalline growth is substantially determined by the material portion 112A and, therefore, the exposed crystalline surface 104S may not substantially affect the overall crystalline structure of the strained semiconductor material.
- the crystalline structure of the portion 112A differs from that of the layer 104 A, only a slight mismatch will occur during the further epitaxial growth process in the vicinity of the exposed surface 104S, while the essential part of the grown material may exhibit the desire crystalline characteristics.
- Figure 112B shows the transistor 100 after the completion of the epitaxial growth process, thereby forming a second portion 112B of strained semiconductor material above the portion 112A.
- the portions 112A, 112B may not necessarily be provided completely in the form of a strained semiconductor material, but may also include portions of substantially unstrained semiconductor material.
- the first portion 112A may be grown up to a height well below the exposed surface 104S on the basis of a non-strained material and, thereafter, the second portion 112B may be grown partially as non-strained material and partially as strained material or as a completely strained material.
- a part of the portion 112B may be provided in the form of a non-strained material or a strained material, depending on the process and device requirements.
- the epitaxial growth process may be discontinued without providing any raised portions, when raised drain and source regions are considered inappropriate. Thereafter, the further manufacturing process may be continued, in some illustrative embodiments, on the basis of well-established techniques, including the removal of the spacers 108 A, the liner 109 A and the capping layer 107, the formation of an appropriate sidewall spacer structure and intermittent corresponding implantation processes for providing the required dopant profile to define drain and source regions.
- the above described process sequence may be altered in that appropriate dopant profiles may be provided so as to enable the operation of the device 100 as a transistor device, fully depleted or partially depleted, having two channel regions to enhance performance of the device 100.
- appropriate dopant profiles may be provided so as to enable the operation of the device 100 as a transistor device, fully depleted or partially depleted, having two channel regions to enhance performance of the device 100.
- a thickness of the layer 104 A may be approximately 100 nm and even significantly less
- the interface 114 between the layer 104A and the buried insulating layer 103 A may also be used as a channel region and, thus, the corresponding implantation processes may be adapted to provide an appropriate connection, i.e., PN junction, to this further channel region.
- the " IWfe ⁇ yhBfclfeid ⁇ viSyU ⁇ lp'Wle'tis'yicture, i.e., the width of the individual sidewall spacers within the sidewall spacer structure and the corresponding implantation parameters may be re-adjusted to obtain the desired dopant profile.
- Figure Ig schematically shows the transistor 100 after the completion of the above described process sequence.
- the transistor 100 comprises a sidewall spacer structure 115 adjacent to the gate electrode 105, wherein the spacer structure 115 may include a plurality of individual spacers 115A, 115B, the number and dimension of which depends on the required horizontal dopant profile of a respective drain and source region 118.
- two individual spacer elements i.e., the spacers 115A, 115B, are provided to obtain a specified dopant profile in the drain and source region 118, wherein a corresponding PN junction 119 is appropriately located in the layer 104A to appropriately connect to corresponding channel regions, which may be located in the vicinity of the interfaces 121 and 114.
- metal suicide regions 116 and 117 may be formed in and on the drain and source region 118 and the gate electrode 105. Since the region 104A is laterally enclosed by the strained semiconductor material 112, a corresponding strain 120 is efficiently formed in the layer 104A in the vicinity of the interface 121 as well as in the vicinity of the interface 114, In the example shown, the strain 120 is illustrated as a compressive strain to enhance the hole mobility within the layer 104A and particularly within any channels that may form at the interfaces 121, 114 during the operation of the transistor 100.
- the transistor 100 may be formed on the basis of well-established process techniques, wherein, in some illustrative embodiments, at least the design of the spacer structure 115 and the corresponding implantation cycles is correspondingly adapted to locate the PN junction 119 in an appropriate manner in order to connect to both channel regions at the interfaces 121 and 114. Thereafter, the metal suicide regions 116, 117 may be formed on the basis of well-established techniques, such as the deposition of a refractory metal and a subsequent heat treatment for initiating the conversion into metal suicide, when the gate electrode 105 and the drain and the source regions 118 comprise a significant amount of silicon.
- the configuration of the device 100 as shown in Figure Ig is highly advantageous for a P-channel transistor, since, in this case, a compressive strain in the region 104A may significantly increase the hole mobility, thereby also enhancing the drive current capability of the device 100.
- a tensile strain may be generated by providing a correspondingly strained semiconductor material in the drain and source region 118 as is previously explained.
- the crystalline structure in the drain and source region 118 is substantially defined by the epitaxial growth of the which in turn is based on the crystalline template provided by the semiconductor layer 102 and, therefore, a crystalline structure in the drain and source region 118 may be adjusted substantially independently from the crystalline configuration of the layer 104A, which may be highly advantageous when different types of transistors are to be formed on the basis of the second semiconductor layer 104A, as will be described in more detail with reference to Figures 2a-2f.
- Figure 2a schematically shows a cross-sectional view of a semiconductor device 250 comprising a first transistor 200N and a second transistor 200P.
- the transistors 200N, 200P may represent transistors provided on different substrate areas or die areas and/or may represent transistors of different configuration and/or may represent transistors of different conductivity types.
- the transistor 200N may represent an N- channel transistor
- the transistor 200P may represent a P-channel transistor.
- the device 250 further comprises a substrate 201 having formed thereon a first crystalline semiconductor layer 202, followed by a buried insulating layer 203 on which is formed a second crystalline semiconductor layer 204.
- the first and second transistors 200N, 200P may comprise a gate electrode 205 formed on a gate insulation layer 206, wherein the gate electrodes 205 are encapsulated by a corresponding capping layer 207 and sidewall spacers 208A.
- an isolation structure 221 may be provided to separate the first and second transistors 200N, 200P.
- the first transistor 200N may be covered by a hard mask 222, which may be comprised of silicon nitride, silicon dioxide or any other appropriate material.
- the difference in one or more characteristics of the transistors 200N, 200P may require that the performance of these transistors be individually enhanced, for instance by individually generating strain in the channel region(s) of one of the transistors 200N, 200P or by any other appropriate strategies.
- the transistor 200N may represent an N-channel transistor, in which the electron mobility may be maintained at a moderately high level by providing the layer 204 as a silicon-based layer having a surface orientation (100).
- the second transistor 200P may represent a P-channel transistor, whose reduced hole mobility, owing to the reduced mobility of holes in a (100) silicon, may be enhanced by locally applying strain in the respective channel region by an embedded strained semiconductor material in the respective drain and source region, as is described with reference to Figure Ia-Ig for the transistor 100. Additionally, the junction resistance of the drain and source region to be formed in the second transistor 200P may be enhanced by providing a (110) orientation to enhance the hole mobility, at least in this transistor area.
- ICpii ⁇ tt ⁇ dH ⁇ ha ⁇ iVfeyiHsHelilMelhtation of the first semiconductor layer 202 may be selected as a (110) orientation, thereby providing a crystal template for the subsequent processing which is highly advantageous for enhancing the series resistance of the transistor 200P.
- the device 250 as shown in Figure 2a may be manufactured on the basis of well-established process techniques as are also described with reference to Figure Ia. Additionally, the hard mask 222 may be formed on the basis of well-established photolithography and etch techniques, for example, after encapsulating the gate electrodes 205 on the basis of a technique as is also described in Figure Ia. For example, a thin liner layer (not shown) may be deposited followed by the hard mask material, which is then etched on the basis of a corresponding photolithography mask, wherein the liner may act as an etch stop layer. Thereafter, the liner may be removed from the exposed transistor 200P to obtain the configuration as shown in Figure 2a.
- a cavity or recess etch process may be performed in order to selectively etch the exposed portions of the transistor 200P, thereby forming a recess through the layer 204, the layer 203 and into the semiconductor layer 202.
- a cavity or recess etch process may be performed in order to selectively etch the exposed portions of the transistor 200P, thereby forming a recess through the layer 204, the layer 203 and into the semiconductor layer 202.
- an interference of the layer 204 may be reduced especially when the layer 204 differs in crystal orientation, material composition and the like with respect to the layer 202.
- a spacer layer may be formed prior to the epitaxial growth process.
- Figure 2b schematically shows the device 250 after the anisotropic etch process for forming a recess 211 adjacent to the encapsulated gate electrode 205 of the second transistor 200P, wherein, additionally, a spacer layer 213 is conformally formed on the device 250.
- the spacer layer 213 may be comprised of silicon dioxide, silicon oxynitride or any other appropriate dielectric material that substantially inhibits the deposition of semiconductor material during the subsequent epitaxial growth process.
- an extremely thin material layer may be formed by any appropriate deposition technique, such as chemical vapor deposition (CVD), atomic layer deposition (ALD) for depositing a conductive material, such as a highly doped semiconductor of quite different crystalline characteristics compared to the layer 202, or any refractory metal or material compounds exhibiting a moderate conductivity, while reducing the deposition rate in a subsequent epitaxial growth process.
- CVD chemical vapor deposition
- ALD atomic layer deposition
- a thickness of the layer 213 may be less than approximately 1 nm so as to reduce an effect of the layer 213 on the device behavior, when this layer is not removed prior to completing the subsequent epitaxial growth process.
- "lhl- I . ⁇ fevSetell2ife ⁇ may be subjected to an anisotropic etch process in accordance with well- established process recipes for removing the material of the layer 213 from horizontal device portions.
- Figure 2c schematically shows the device 250 after the completion of the above-described spacer formation process.
- the device 250 comprises a spacer 213A formed on sidewall portions of the recess 211.
- the spacer 213 A may be formed of a material that may avoid or at least reduce the deposition of semiconductor material during the subsequent epitaxial growth process, while on the other hand may exhibit a moderately high conductivity so that the spacer 213 A may not have to be removed during the subsequent epitaxial growth process.
- a highly doped semiconductor material of different characteristics and with a significantly different lattice spacing may be used.
- the recess 211 may be filled by a strained semiconductor material 212, the characteristics of which are substantially determined by the layer 202, wherein any influence from the layer 204 A may be significantly suppressed due to the spacer 213 A.
- the material 212 may comprise strained silicon/germanium having a (110) orientation.
- further processing may be continued, as is also described with reference to Figure Ic, by performing a multiple step epitaxial growth process.
- Figure 2d schematically shows the device 250 after a first step of epitaxial growth, wherein a first portion 212A of semiconductor material, which may be a strained material or a non-strained material, is formed in the recess 211. Moreover, the spacer 213A may be partially removed to form a spacer 213B that exposes the sidewalls 204S of the region 204 A. The partial removal of the spacer 213 A may be accomplished by an isotropic etch process, as is previously described with reference to the spacer 113 A.
- Figure 2e schematically shows the semiconductor device 250 after the completion of the epitaxial growth process and the removal of the encapsulations for the gate electrodes 205 and the removal of the hard mask 222.
- the device 250 comprises an upper portion 212B of strained semiconductor material, which begins at an interface 214 or at any lower-lying location, which now exerts a desired stress to the region 204A via the sidewall 204S to create a desired type of strain therein.
- a compressive strain may be created by the portion 212B when the transistor 200P represents a P-channel transistor.
- a desired degree of overgrowth may be provided in accordance with design requirements, when a transistor architecture with raised drain and source regions is to be formed.
- the portions 212B and 212 A may have crystallographic characteristics that are substantially determined by the semiconductor layer 202 as is also previously explained. Due to the "late" exposure of the sidewall 204S during a final phase of the epitaxial growth process, the influence, i.e., lattice mismatch, of the layer 204 A on the portion 212B is s ⁇ gnifMfit ⁇ KSiaiidHMsrfli ⁇ Mdfctrical characteristics of the portion 212B are substantially determined by the layer 202.
- the portion 212B may also have substantially a (110) orientation with an acceptable amount of lattice irregularities in the vicinity of the surface 204S.
- the overall resistance of the portion 212B that is the hole mobility, may be significantly enhanced, thereby additionally increasing current drive capability of the transistor 200P.
- Figure 2f schematically shows the device 250 in a further advanced manufacturing stage.
- the first and second transistors 200N, 200P each comprise a respective spacer structure 215 with one or more individual spacer elements 215A, 215B, wherein the spacer structure 215 is dimensioned so as to obtain a required dopant profile in drain and source regions 218 of the transistors 200N, 200P, as is also described with reference to Figure Ig.
- the dopant profile and the location of corresponding PN junctions 219 which may be of different conductivity type, when N- and P-channel transistors are considered, may be defined such that a double channel configuration may be established for partially or fully deplete SOI-like transistors in which the active layer 204A has a thickness in the above-specified range.
- corresponding metal suicide regions may be defined such that a double channel configuration may be established for partially or fully deplete SOI-like transistors in which the active layer 204A has a thickness in the above-specified range.
- 217 and 216 may be formed in the gate electrodes 205 and the drain and source regions 218.
- the transistor 200P comprises a drain and source region 218, which provides a desired type of strain 220, which prevails at an interface 221 between the gate insulation layer 206 and the layer 204A and also at the interface 214 between the buried insulating layer 203 A and the layer 204 A.
- the transistor 200N may have an enhanced electron mobility due to appropriately selected crystalline orientation of the layer 204A, while the second transistor 200P may be enhanced in performance by providing the strain 220 and providing an optimal crystal orientation within the drain and source region 218.
- additional strain-inducing mechanisms are provided, for instance in the form of the sidewall spacer structure 215 and/or by means of a contact etch stop layer (not shown) to be formed over the first and second transistor 200N, 200P.
- an embedded strained semiconductor layer may also be provided in the first transistor 200N to further enhance the performance of the first transistor 200N.
- I'JOi ll ⁇ esiilFj'ltEfe ⁇ lil-feyi invention provides a technique that enables an improved strain-creating mechanism in SOI devices and SOI-like devices, in that an embedded strained semiconductor layer is formed on the basis of a recess that extends through the buried insulating layer, thereby using the underlying crystalline material as a growth template. Consequently, the strained semiconductor layer may be formed adjacent to the entire active semiconductor region formed on the buried insulating layer, thereby improving the stress transfer mechanism.
- the crystalline characteristics of the strained semiconductor layer may be substantially decoupled from the crystalline characteristics of the active semiconductor layer, thereby providing additional design flexibility in obtaining enhanced performance, especially when transistors of different conductivity types have to be formed as is the case in advanced CMOS techniques.
- both interfaces i.e., the interface between the gate insulation layer and the interface between the active region and the buried insulating layer, may be used as channel regions, wherein both channels may be efficiently strained on the basis of the embedded semiconductor material.
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- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thin Film Transistor (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008538920A JP2009514249A (en) | 2005-10-31 | 2006-10-23 | Strained layer embedded in thin SOI transistor and method for forming the same |
| KR1020087013019A KR101290819B1 (en) | 2005-10-31 | 2006-10-23 | An embedded strain layer in thin soi transistor and a method of forming the same |
| CN2006800404441A CN101300670B (en) | 2005-10-31 | 2006-10-23 | Embedded strained layer in thin SOI transistor and method of forming same |
| GB0807434A GB2445511B (en) | 2005-10-31 | 2006-10-23 | An embedded strain layer in thin soi transistors and a method of forming the same |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005052055.3 | 2005-10-31 | ||
| DE102005052055A DE102005052055B3 (en) | 2005-10-31 | 2005-10-31 | Transistor and semiconductor components and production process for thin film silicon on insulator transistor has embedded deformed layer |
| US11/466,572 US7399663B2 (en) | 2005-10-31 | 2006-08-23 | Embedded strain layer in thin SOI transistors and a method of forming the same |
| US11/466,572 | 2006-08-23 |
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| Publication Number | Publication Date |
|---|---|
| WO2007053382A1 true WO2007053382A1 (en) | 2007-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/US2006/041560 Ceased WO2007053382A1 (en) | 2005-10-31 | 2006-10-23 | An embedded strain layer in thin soi transistors and a method of forming the same |
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| Country | Link |
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| GB (1) | GB2445511B (en) |
| WO (1) | WO2007053382A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009212413A (en) * | 2008-03-06 | 2009-09-17 | Renesas Technology Corp | Semiconductor device and method of manufacturing semiconductor device |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030057416A1 (en) * | 2001-09-21 | 2003-03-27 | Amberwave Systems Corporation | Semiconductor structures employing strained material layers with defined impurity gradients and methods for fabricating same |
| WO2004001798A2 (en) * | 2002-06-25 | 2003-12-31 | Advanced Micro Devices, Inc. | A silicon-on-insulator device with strained device film and method for making the same with partial replacement of isolation oxide |
| US20040104447A1 (en) * | 2002-11-26 | 2004-06-03 | Kim Sung-Min | Integrated circuit structures including epitaxial silicon layers in active regions and methods of forming same |
| US20040108559A1 (en) * | 2002-10-02 | 2004-06-10 | Renesas Technology Corp. | Insulated-gate field-effect transistor, method of fabricating same, and semiconductor device employing same |
| US20040188760A1 (en) * | 2002-04-03 | 2004-09-30 | Thomas Skotnicki | Strained-channel isolated-gate field effect transistor, process for making same and resulting integrated circuit |
| US20050082531A1 (en) * | 2003-10-17 | 2005-04-21 | International Business Machines Corporaton | Double silicon-on-insulator (SOI) metal oxide semiconductor field effect transistor (MOSFET) structures |
| US20050116290A1 (en) * | 2003-12-02 | 2005-06-02 | De Souza Joel P. | Planar substrate with selected semiconductor crystal orientations formed by localized amorphization and recrystallization of stacked template layers |
| WO2006052379A1 (en) * | 2004-11-10 | 2006-05-18 | Advanced Micro Devices, Inc. | Strained fully depleted silicon on insulator semiconductor device and manufacturing method therefor |
| EP1734568A2 (en) * | 2005-06-17 | 2006-12-20 | Commissariat A L'energie Atomique | Method of fabricating an insulated transistor having a strained channel |
-
2006
- 2006-10-23 WO PCT/US2006/041560 patent/WO2007053382A1/en not_active Ceased
- 2006-10-23 GB GB0807434A patent/GB2445511B/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030057416A1 (en) * | 2001-09-21 | 2003-03-27 | Amberwave Systems Corporation | Semiconductor structures employing strained material layers with defined impurity gradients and methods for fabricating same |
| US20040188760A1 (en) * | 2002-04-03 | 2004-09-30 | Thomas Skotnicki | Strained-channel isolated-gate field effect transistor, process for making same and resulting integrated circuit |
| WO2004001798A2 (en) * | 2002-06-25 | 2003-12-31 | Advanced Micro Devices, Inc. | A silicon-on-insulator device with strained device film and method for making the same with partial replacement of isolation oxide |
| US20040108559A1 (en) * | 2002-10-02 | 2004-06-10 | Renesas Technology Corp. | Insulated-gate field-effect transistor, method of fabricating same, and semiconductor device employing same |
| US20040104447A1 (en) * | 2002-11-26 | 2004-06-03 | Kim Sung-Min | Integrated circuit structures including epitaxial silicon layers in active regions and methods of forming same |
| US20050082531A1 (en) * | 2003-10-17 | 2005-04-21 | International Business Machines Corporaton | Double silicon-on-insulator (SOI) metal oxide semiconductor field effect transistor (MOSFET) structures |
| US20050116290A1 (en) * | 2003-12-02 | 2005-06-02 | De Souza Joel P. | Planar substrate with selected semiconductor crystal orientations formed by localized amorphization and recrystallization of stacked template layers |
| WO2006052379A1 (en) * | 2004-11-10 | 2006-05-18 | Advanced Micro Devices, Inc. | Strained fully depleted silicon on insulator semiconductor device and manufacturing method therefor |
| EP1734568A2 (en) * | 2005-06-17 | 2006-12-20 | Commissariat A L'energie Atomique | Method of fabricating an insulated transistor having a strained channel |
Non-Patent Citations (1)
| Title |
|---|
| MALGORZATA JURCZAK ET AL: "Silicon-on-Nothing (SON)-an Innovative Process for Advanced CMOS", IEEE TRANSACTIONS ON ELECTRON DEVICES, IEEE SERVICE CENTER, PISACATAWAY, NJ, US, vol. 47, no. 11, November 2000 (2000-11-01), XP011017406, ISSN: 0018-9383 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009212413A (en) * | 2008-03-06 | 2009-09-17 | Renesas Technology Corp | Semiconductor device and method of manufacturing semiconductor device |
Also Published As
| Publication number | Publication date |
|---|---|
| GB0807434D0 (en) | 2008-05-28 |
| GB2445511B (en) | 2009-04-08 |
| GB2445511A (en) | 2008-07-09 |
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