WO2007052961A1 - Bonding method between secondary gas barrier and insulation panel using heating pad - Google Patents

Bonding method between secondary gas barrier and insulation panel using heating pad Download PDF

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Publication number
WO2007052961A1
WO2007052961A1 PCT/KR2006/004530 KR2006004530W WO2007052961A1 WO 2007052961 A1 WO2007052961 A1 WO 2007052961A1 KR 2006004530 W KR2006004530 W KR 2006004530W WO 2007052961 A1 WO2007052961 A1 WO 2007052961A1
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive
heating
insulation panel
gas barrier
secondary gas
Prior art date
Application number
PCT/KR2006/004530
Other languages
French (fr)
Inventor
Seong-Uk Lee
Original Assignee
Seong-Uk Lee
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seong-Uk Lee filed Critical Seong-Uk Lee
Priority to ES06812369T priority Critical patent/ES2385164T3/en
Priority to CN2006800047533A priority patent/CN101120068B/en
Priority to EP06812369A priority patent/EP1951832B1/en
Priority to JP2007556984A priority patent/JP2008531941A/en
Priority to AT06812369T priority patent/ATE550599T1/en
Publication of WO2007052961A1 publication Critical patent/WO2007052961A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00—Details of vessels or of the filling or discharging of vessels
    • F17C13/001—Thermal insulation specially adapted for cryogenic vessels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0345—Fibres
    • F17C2203/035—Glass wool
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0354—Wood
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0358—Thermal insulations by solid means in form of panels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0375—Thermal insulations by gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602—Wall structures; Special features thereof
    • F17C2203/0607—Coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0636—Metals
    • F17C2203/0639—Steels
    • F17C2203/0643—Stainless steels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0658—Synthetics
    • F17C2203/066—Plastics
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00—Vessel construction, in particular methods of manufacturing
    • F17C2209/22—Assembling processes
    • F17C2209/227—Assembling processes by adhesive means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F17C2221/03—Mixtures
    • F17C2221/032—Hydrocarbons
    • F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146—Two-phase
    • F17C2223/0153—Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/06—Controlling or regulating of parameters as output values
    • F17C2250/0605—Parameters
    • F17C2250/0631—Temperature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0102—Applications for fluid transport or storage on or in the water
    • F17C2270/0105—Ships
    • F17C2270/0107—Wall panels

Definitions

  • the present invention relates to a method for bonding a secondary gas barrier to an insulation panel in a liquefied natural gas (LNG) carrier or storage tank, and more particularly, to a method for bonding a secondary gas barrier to an insulation panel wherein curing of an adhesive is perfectly carried out, thereby expecting the reduction of a construction period and the improvement of productivity, and thereby reducing the installation costs of the bonding equipment and the repairing costs for the uncuring and defective bonding of the adhesive.
  • LNG liquefied natural gas
  • an LNG container of an LNG carrier or an LNG storage tank includes a primary gas barrier 10, an insulation panel 20, and a secondary gas barrier 30, for the purpose of stably preventing LNG at a liquefaction temperature of -163 0 C or less from leaking to the outside under any bad conditions, and of enduring the impact and pressure of the internal LNG or external impacts.
  • the primary gas barrier 10 is configured to be in direct contact with the primary gas barrier 10
  • the insulation panel 20 is made by attaching a plywood onto both surfaces of a heat insulating material formed of a reinforced polyurethane foam (R-PUF), so as to endure the impact and pressure of LNG and maintain the temperature of LNG of -163 0 C at the liquefied state.
  • R-PUF reinforced polyurethane foam
  • the secondary gas barrier 30 has a property of secondarily preventing the
  • Such a conventional bonding method entails problems in that the surface temperature of the insulation panel 20 is not constantly maintained well and the environmental conditions of a working place are not made constantly, thereby failing to obtain constant strengths of the adhesive. This causes the adhesive to remain in an uncuring or incomplete curing state, which yields defective bonding results. Thus, it may reduce the lifespan of the LNG carrier or storage tank or even may cause an accident therefrom. More especially, the bonding strength of the adhesive varies depending on a low temperature in the winter season and a high temperature difference in a change of season.
  • a method for bonding a secondary gas barrier to an insulation panel in an LNG carrier or an LNG storage tank including the steps of: applying an adhesive onto the surface of the insulation panel; sequentially laminating the secondary gas barrier, a release film, a cushion pad, a heating pad, and a rigid plate on the adhesive applied on the surface of the insulation panel; heating the adhesive up to a temperature approaching best bonding characteristics by using the heating pad; pressurizing through a pressurizing device the adhesive between the secondary gas barrier and the insulation panel under an even pressure by using the elastic force of the cushion pad and the rigidity of the rigid plate; and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive.
  • the heating pad is formed of a heating means covered with a coating material.
  • the heating means is formed of one selected from a carbon plane heating element, a metal heating wire, and a ceramic heating element
  • the coating material is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
  • the cushion pad is formed of a synthetic resin or rubber.
  • the rigid plate is formed of a plywood, a honeycomb panel, or a laminated board.
  • a method for bonding a secondary gas barrier to an insulation panel thereby obtaining an excellent bonding strength of an adhesive, thereby reducing the curing time period of the adhesive to improve the productivity, thereby reducing the installation costs necessary for bonding the secondary gas barrier, and thereby decreasing the repairing costs for the defective bonding due to the uncuring or semi-curing of the adhesive.
  • FIG.1 is a view showing a method for bonding a secondary gas barrier to an insulation panel according to the present invention
  • FIG.2 is a sectional view showing an example of a heating pad employed in the bonding method according to the present invention.
  • FIG.3 is a sectional view showing another example of a heating pad employed in the bonding method according to the present invention.
  • FIG.4 is a sectional view showing yet another example of a heating pad employed in the bonding method according to the present invention.
  • FIG.5 is a sectional view showing an example where a cushion pad, a heating pad, and a rigid plate that are formed as an integral body in the bonding method according to the present invention.
  • FIG.6 is a partly cut perspective view showing a sectional structure of an LNG carrier adopting the bonding method according to the present invention. Best Mode for Carrying Out the Invention [25]
  • an explanation of a method for bonding a secondary gas barrier to an insulation panel according to the present invention will be given with reference to the attached drawings.
  • FIG.1 is a view showing a method for bonding a secondary gas barrier to an insulation panel according to the present invention
  • FIG.2 is a sectional view showing an example of a heating pad employed in the bonding method according to the present invention
  • FIG.3 is a sectional view showing another example of a heating pad employed in the bonding method according to the present invention
  • FIG.4 is a sectional view showing yet another example of a heating pad employed in the bonding method according to the present invention
  • FIG.5 is a sectional view showing an example where a cushion pad, a heating pad, and a rigid plate that are formed as an integral body in the bonding method according to the present invention.
  • the method including the steps of: applying an adhesive 40 onto the surface of the insulation panel 20; sequentially laminating the secondary gas barrier 30, a release film 50, a cushion pad 90, a heating pad 60, and a rigid plate 95 on the adhesive 40 applied on the surface of the insulation panel 20; heating the adhesive 40 up to a temperature approaching best bonding characteristics by using the heating pad 60; pressurizing through a pressurizing device 70 the adhesive 40 provided between the secondary gas barrier 30 and the insulation panel 20 under an even pressure by using the elastic force of the cushion pad 90 and the rigidity of the rigid plate 95; and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive 40, thereby finishing bonding of the secondary gas barrier 30 onto the insulation panel 20.
  • the temperature and heating time period where the adhesive 40 approaches the best bonding characteristics are depending upon the type of an adhesive.
  • an epoxy adhesive or a polyurethane adhesive is heated for 3 to 6 hours at a temperature between 25 0 C and 100 0 C.
  • the insulation panel 20 is made by attaching a plywood 24 on both surfaces of a heat insulating material 22 formed of a reinforced polyurethane foam (R-PUF), and the secondary gas barrier 30 is made by laminating an epoxy/polyamide film and a reinforcing fiber fabric on both surfaces of an aluminum foil, thereby molding them as a unitary body.
  • R-PUF reinforced polyurethane foam
  • the insulation panel 20 and the secondary gas barrier 30 of the present invention are freely made, while not being limited to those as mentioned above.
  • the adhesive 40 is formed of an LNG epoxy adhesive made by Gaztransport
  • the release film 50 is formed of a vinyl film. In this case, they are freely made, while not being limited to those as mentioned above.
  • the heating pad 60 serving to heat the adhesive 40 for fully curing the adhesive 40 is formed of a heating means 62 covered with a coating material 64 that has heating time period and temperature controlled by means of a control unit 80, such that under the controlled heating time and temperature, the adhesive 40 can have a high curing strength, thereby achieving a full curing state.
  • the heating pad 60 is formed of the heating means
  • a carbon plane heating element 62a which is covered with the coating material 64 formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
  • a metal heating wire 62b may be used as the heating means 62, and the coating material 64 of the metal heating wire 62b is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
  • a ceramic heating element 62c may be used as the heating means 62, and the coating material 64 of the metal heating wire 62b is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
  • the cushion pad 90 that is disposed between the release film 50 and the heating pad 60 serves to evenly spread the adhesive 40 to conduct the full bonding between the secondary gas barrier 30 and the insulation pad 20, and it is formed of an elastic material, preferably, a synthetic resin or rubber.
  • the rigid plate 95 is formed of a material having predetermined rigidity capable of evenly transmitting the pressurizing force of the pressurizing device 70, and preferably, it is formed of a plywood, a honeycomb panel, or a laminated board.
  • the adhesive 40 can be more evenly pressurized when compared with those that are separately made.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

The present invention relates to a method for bonding a secondary gas barrier to an insulation panel in an LNG carrier or an LNG storage tank, the method including the steps of: applying an adhesive onto the surface of the insulation panel; sequentially laminating the secondary gas barrier, a release film, a cushion pad, a heating pad, and a rigid plate on the adhesive applied on the surface of the insulation panel; heating the adhesive up to a temperature approaching best bonding characteristics by using the heating pad; pressurizing through a pressurizing device the adhesive provided between the secondary gas barrier and the insulation panel under an even pressure by using the elastic force of the cushion pad and the rigidity of the rigid plate; and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive.

Description

Description
BONDING METHOD BETWEEN SECONDARY GAS BARRIER AND INSULATION PANEL USING HEATING PAD
Technical Field
[1] The present invention relates to a method for bonding a secondary gas barrier to an insulation panel in a liquefied natural gas (LNG) carrier or storage tank, and more particularly, to a method for bonding a secondary gas barrier to an insulation panel wherein curing of an adhesive is perfectly carried out, thereby expecting the reduction of a construction period and the improvement of productivity, and thereby reducing the installation costs of the bonding equipment and the repairing costs for the uncuring and defective bonding of the adhesive. Background Art
[2] As shown in FIG. 6, an LNG container of an LNG carrier or an LNG storage tank includes a primary gas barrier 10, an insulation panel 20, and a secondary gas barrier 30, for the purpose of stably preventing LNG at a liquefaction temperature of -1630C or less from leaking to the outside under any bad conditions, and of enduring the impact and pressure of the internal LNG or external impacts.
[3] At this time, the primary gas barrier 10 is configured to be in direct contact with the
LNG in the LNG carrier or storage tank, while enduring the contraction stresses and impacts due to a very low temperature, which is generally formed of a stainless steel membrane (STS).
[4] The insulation panel 20 is made by attaching a plywood onto both surfaces of a heat insulating material formed of a reinforced polyurethane foam (R-PUF), so as to endure the impact and pressure of LNG and maintain the temperature of LNG of -1630C at the liquefied state.
[5] Further, the secondary gas barrier 30 has a property of secondarily preventing the
LNG from leaking to the outside, if the primary gas barrier 10 is damaged, and it is made by laminating synthetic rubber and glass fiber fabric on both surfaces of an aluminum foil so as to mold them as a unitary body, or by laminating an epoxy/ polyamide film and a reinforcing fiber fabric on both surfaces of an aluminum foil so as to mold them as a unitary body.
[6] Conventionally, an adhesive is applied on the insulation panel 20, and a triplex strip is placed thereon. After that, the insulation panel 20 is pressurized by using an air bag and is cured at a room temperature. Then, the secondary gas barrier 30 is bonded to the insulation panel 20.
[7] Such a conventional bonding method, however, entails problems in that the surface temperature of the insulation panel 20 is not constantly maintained well and the environmental conditions of a working place are not made constantly, thereby failing to obtain constant strengths of the adhesive. This causes the adhesive to remain in an uncuring or incomplete curing state, which yields defective bonding results. Thus, it may reduce the lifespan of the LNG carrier or storage tank or even may cause an accident therefrom. More especially, the bonding strength of the adhesive varies depending on a low temperature in the winter season and a high temperature difference in a change of season.
[8] Since an uneven pressure is applied to the insulation panel 20 during a pressurizing step, also, loose spaces between the insulation panel 20 and the secondary gas barrier 30 are partially formed, which fails to obtain perfect bonding results. Disclosure of Invention Technical Problem
[9] Accordingly, it is an object of the present invention to provide a method for bonding a secondary gas barrier to an insulation panel wherein a temperature higher than a room temperature is provided under curing conditions of an adhesive applied for bonding the secondary gas barrier to the insulation panel, thereby obtaining a best bonding strength, and thereby preventing the uncuring or semi-curing of the adhesive, even though a relatively long time period is elapsed during the curing of the adhesive.
[10] It is another object of the present invention to provide a method for bonding a secondary gas barrier to an insulation panel wherein no partial loose space is formed between the insulation panel and the secondary gas barrier, thereby obtaining perfect bonding results. Technical Solution
[11] To achieve the above objects, according to the present invention, there is provided a method for bonding a secondary gas barrier to an insulation panel in an LNG carrier or an LNG storage tank, the method including the steps of: applying an adhesive onto the surface of the insulation panel; sequentially laminating the secondary gas barrier, a release film, a cushion pad, a heating pad, and a rigid plate on the adhesive applied on the surface of the insulation panel; heating the adhesive up to a temperature approaching best bonding characteristics by using the heating pad; pressurizing through a pressurizing device the adhesive between the secondary gas barrier and the insulation panel under an even pressure by using the elastic force of the cushion pad and the rigidity of the rigid plate; and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive.
[12] At this time, the heating pad is formed of a heating means covered with a coating material. [13] Also, the heating means is formed of one selected from a carbon plane heating element, a metal heating wire, and a ceramic heating element, and the coating material is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
[14] Further, the cushion pad is formed of a synthetic resin or rubber.
[15] Further, the rigid plate is formed of a plywood, a honeycomb panel, or a laminated board.
[16] The above and other objects and features of the present invention will be better understood from the following description of the preferred embodiment with reference to the drawings.
Advantageous Effects
[17] According to the present invention, there is provided a method for bonding a secondary gas barrier to an insulation panel, thereby obtaining an excellent bonding strength of an adhesive, thereby reducing the curing time period of the adhesive to improve the productivity, thereby reducing the installation costs necessary for bonding the secondary gas barrier, and thereby decreasing the repairing costs for the defective bonding due to the uncuring or semi-curing of the adhesive.
[18] As the adhesive that is applied between the secondary gas barrier and the insulation panel is pressurized through a pressurizing device under an even pressure by using the elastic force of the cushion pad and the rigidity of the rigid plate, no partial loose space is formed between the insulation panel and the secondary gas barrier, thereby obtaining perfect bonding results. Brief Description of the Drawings
[19] FIG.1 is a view showing a method for bonding a secondary gas barrier to an insulation panel according to the present invention;
[20] FIG.2 is a sectional view showing an example of a heating pad employed in the bonding method according to the present invention;
[21] FIG.3 is a sectional view showing another example of a heating pad employed in the bonding method according to the present invention;
[22] FIG.4 is a sectional view showing yet another example of a heating pad employed in the bonding method according to the present invention;
[23] FIG.5 is a sectional view showing an example where a cushion pad, a heating pad, and a rigid plate that are formed as an integral body in the bonding method according to the present invention; and
[24] FIG.6 is a partly cut perspective view showing a sectional structure of an LNG carrier adopting the bonding method according to the present invention. Best Mode for Carrying Out the Invention [25] Hereinafter, an explanation of a method for bonding a secondary gas barrier to an insulation panel according to the present invention will be given with reference to the attached drawings.
[26] FIG.1 is a view showing a method for bonding a secondary gas barrier to an insulation panel according to the present invention, FIG.2 is a sectional view showing an example of a heating pad employed in the bonding method according to the present invention, FIG.3 is a sectional view showing another example of a heating pad employed in the bonding method according to the present invention, FIG.4 is a sectional view showing yet another example of a heating pad employed in the bonding method according to the present invention, and FIG.5 is a sectional view showing an example where a cushion pad, a heating pad, and a rigid plate that are formed as an integral body in the bonding method according to the present invention.
[27] As shown in FIG.l, there is provided a method for bonding a secondary gas barrier
30 to an insulation panel 20 according to the present invention, the method including the steps of: applying an adhesive 40 onto the surface of the insulation panel 20; sequentially laminating the secondary gas barrier 30, a release film 50, a cushion pad 90, a heating pad 60, and a rigid plate 95 on the adhesive 40 applied on the surface of the insulation panel 20; heating the adhesive 40 up to a temperature approaching best bonding characteristics by using the heating pad 60; pressurizing through a pressurizing device 70 the adhesive 40 provided between the secondary gas barrier 30 and the insulation panel 20 under an even pressure by using the elastic force of the cushion pad 90 and the rigidity of the rigid plate 95; and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive 40, thereby finishing bonding of the secondary gas barrier 30 onto the insulation panel 20.
[28] At this time, the temperature and heating time period where the adhesive 40 approaches the best bonding characteristics are depending upon the type of an adhesive. For example, an epoxy adhesive or a polyurethane adhesive is heated for 3 to 6 hours at a temperature between 250C and 1000C.
[29] In the preferred embodiment of the present invention, the insulation panel 20 is made by attaching a plywood 24 on both surfaces of a heat insulating material 22 formed of a reinforced polyurethane foam (R-PUF), and the secondary gas barrier 30 is made by laminating an epoxy/polyamide film and a reinforcing fiber fabric on both surfaces of an aluminum foil, thereby molding them as a unitary body. In this case, the insulation panel 20 and the secondary gas barrier 30 of the present invention are freely made, while not being limited to those as mentioned above.
[30] Also, the adhesive 40 is formed of an LNG epoxy adhesive made by Gaztransport
& Technigaz in France, and the release film 50 is formed of a vinyl film. In this case, they are freely made, while not being limited to those as mentioned above.
[31] On the other hand, the heating pad 60 serving to heat the adhesive 40 for fully curing the adhesive 40 is formed of a heating means 62 covered with a coating material 64 that has heating time period and temperature controlled by means of a control unit 80, such that under the controlled heating time and temperature, the adhesive 40 can have a high curing strength, thereby achieving a full curing state.
[32] At this time, the heating pad 60, as shown in FIG.2, is formed of the heating means
62 containing a carbon plane heating element 62a, which is covered with the coating material 64 formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile. However, as shown in FIG.3, a metal heating wire 62b may be used as the heating means 62, and the coating material 64 of the metal heating wire 62b is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile. On the other hand, a ceramic heating element 62c may be used as the heating means 62, and the coating material 64 of the metal heating wire 62b is formed of one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
[33] While the secondary gas barrier 30 is being pressurized under an even pressure through the pressurizing device 70, the cushion pad 90 that is disposed between the release film 50 and the heating pad 60 serves to evenly spread the adhesive 40 to conduct the full bonding between the secondary gas barrier 30 and the insulation pad 20, and it is formed of an elastic material, preferably, a synthetic resin or rubber.
[34] Also, the rigid plate 95 is formed of a material having predetermined rigidity capable of evenly transmitting the pressurizing force of the pressurizing device 70, and preferably, it is formed of a plywood, a honeycomb panel, or a laminated board.
[35] On the other hand, as shown in FIG.5, if the cushion pad 90, the heating pad 60, and the rigid plate 95 are formed integrally to one another, the adhesive 40 can be more evenly pressurized when compared with those that are separately made.
[36] This invention having been disclosed, a number of variations will now become apparent to those skilled in the art. Whereas the invention is intended to encompass the foregoing preferred embodiments as well as a reasonable range of equivalents, reference should be made to the appended claims rather than the foregoing discussion of examples, in order to assess the scope of the invention in which exclusive rights are claimed.
Industrial Applicability
[37] According to the present invention, there is provided a method for bonding a secondary gas barrier to an insulation panel wherein curing of an adhesive is perfectly carried out, thereby causing the reduction of a construction period and the improvement of productivity, and thereby reducing the installation costs of the bonding equipment and the repairing costs for the uncuring and defective bonding of the adhesive.

Claims

Claims
[1] A method for bonding a secondary gas barrier to an insulation panel in an LNG carrier or an LNG storage tank, the method comprising the steps of: applying an adhesive (40) onto the surface of the insulation panel (20); sequentially laminating the secondary gas barrier (30), a release film (50), a cushion pad (90), a heating pad (60), and a rigid plate (95) on the adhesive (40) applied on the surface of the insulation panel (20); heating the adhesive (40) up to a temperature having best bonding characteristics by using the heating pad (60); pressurizing through a pressurizing device (70) the adhesive provided between the secondary gas barrier (30) and the insulation panel (20) under an even pressure by using the elastic force of the cushion pad (90) and the rigidity of the rigid plate (95); and maintaining the heating temperature under the pressurizing state at a given constant level to conduct full curing of the adhesive (40).
[2] The method according to claim 1, wherein the heating pad (60) is formed of a heating means (62) covered with a coating material (64).
[3] The method according to claim 2, wherein the heating means (62) is formed of any one selected from a carbon plane heating element (62a), a metal heating wire (62b), and a ceramic heating element (62c), and the coating material (64) is formed of any one selected from a thermosetting resin, a thermal plastic resin, and a composite material made of a fabric or an organic or inorganic textile.
[4] The method according to any one of claims 1 to 3, wherein the cushion pad (90) is formed of a synthetic resin or rubber.
[5] The method according to any one of claims 1 to 3, wherein the rigid plate (95) is formed of a plywood, a honeycomb panel, or a laminated board.
PCT/KR2006/004530 2005-11-03 2006-11-02 Bonding method between secondary gas barrier and insulation panel using heating pad WO2007052961A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES06812369T ES2385164T3 (en) 2005-11-03 2006-11-02 Adhesion procedure between a secondary gas barrier and an insulation panel using a heating pad
CN2006800047533A CN101120068B (en) 2005-11-03 2006-11-02 Bonding method between secondary gas barrier and insulation panel using heating pad
EP06812369A EP1951832B1 (en) 2005-11-03 2006-11-02 Bonding method between secondary gas barrier and insulation panel using heating pad
JP2007556984A JP2008531941A (en) 2005-11-03 2006-11-02 Secondary gas barrier bonding method using a heating pad
AT06812369T ATE550599T1 (en) 2005-11-03 2006-11-02 METHOD FOR BINDING SECONDARY GAS BARRIER AND INSULATING PANELS USING A HEATING PAD

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2005-0104755 2005-11-03
KR1020050104755A KR100553017B1 (en) 2005-04-20 2005-11-03 Bonding method between secondary gas barrier and insulation panel using heating pad

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WO2007052961A1 true WO2007052961A1 (en) 2007-05-10

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EP (1) EP1951832B1 (en)
JP (1) JP2008531941A (en)
KR (1) KR100553017B1 (en)
CN (1) CN101120068B (en)
AT (1) ATE550599T1 (en)
ES (1) ES2385164T3 (en)
WO (1) WO2007052961A1 (en)

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FR2903758A1 (en) * 2006-07-12 2008-01-18 Korea Advanced Inst Sci & Tech STRUCTURE AND METHOD FOR BONDING THERMAL INSULATION PROTECTION WALLS OF A LIQUEFIED NATURAL GAS TRANSPORT DEVICE.
US20120305524A1 (en) * 2008-06-19 2012-12-06 Samsung Heavy Ind. Co., Ltd. Insulation structure of lng carrier cargo tank and method for constructing the same
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FR2942540A1 (en) * 2009-02-20 2010-08-27 Hutchinson Adhering parameter verifying system for e.g. secondary barrier of tank of methane carrier, has indicator placed in contact with laminates of barrier, where parameters are selected from group of temperature, pressure and adhering duration
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WO2017220865A1 (en) * 2016-06-23 2017-12-28 Metsäliitto Osuuskunta Wall structure of heat insulating box
RU2761702C1 (en) * 2017-11-06 2021-12-13 Газтранспорт Эт Технигаз Sealed and heat-insulating tank

Also Published As

Publication number Publication date
ES2385164T3 (en) 2012-07-19
EP1951832A1 (en) 2008-08-06
EP1951832A4 (en) 2011-02-09
CN101120068B (en) 2010-10-13
JP2008531941A (en) 2008-08-14
KR100553017B1 (en) 2006-02-15
EP1951832B1 (en) 2012-03-21
ATE550599T1 (en) 2012-04-15
CN101120068A (en) 2008-02-06

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