WO1997025198A9 - Composite honeycomb sandwich structure - Google Patents
Composite honeycomb sandwich structureInfo
- Publication number
- WO1997025198A9 WO1997025198A9 PCT/US1997/000075 US9700075W WO9725198A9 WO 1997025198 A9 WO1997025198 A9 WO 1997025198A9 US 9700075 W US9700075 W US 9700075W WO 9725198 A9 WO9725198 A9 WO 9725198A9
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- die
- core
- laminate
- tiedown
- resin
- Prior art date
Links
- 210000003660 Reticulum Anatomy 0.000 title claims abstract description 57
- 239000002131 composite material Substances 0.000 title claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 73
- 229920005989 resin Polymers 0.000 claims abstract description 73
- 230000001070 adhesive Effects 0.000 claims abstract description 60
- 239000000853 adhesive Substances 0.000 claims abstract description 60
- 210000003491 Skin Anatomy 0.000 claims description 36
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 10
- YVPYQUNUQOZFHG-UHFFFAOYSA-N Diatrizoic acid Chemical compound CC(=O)NC1=C(I)C(NC(C)=O)=C(I)C(C(O)=O)=C1I YVPYQUNUQOZFHG-UHFFFAOYSA-N 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 8
- 230000002093 peripheral Effects 0.000 claims description 7
- 229920001721 Polyimide Polymers 0.000 claims description 4
- 239000004642 Polyimide Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 238000007665 sagging Methods 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000011162 core material Substances 0.000 description 100
- 235000011890 sandwich Nutrition 0.000 description 28
- 239000004744 fabric Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000010192 crystallographic characterization Methods 0.000 description 1
- 239000000789 fastener Substances 0.000 description 1
- 201000002113 hereditary lymphedema I Diseases 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000135 prohibitive Effects 0.000 description 1
- 230000003014 reinforcing Effects 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
Definitions
- the present invention relates to composite honeycomb sandwich structure, and particularly to resin impregnated fabric sheets forming outer skins adhered on opposed surfaces of a honeycomb core with an intermediate barrier to eliminate resin flow from the skins to the core.
- Aerospace honeycomb core sandwich panels having composite laminate skins cocured with adhesives to the core through autoclave processing find widespread use today because of the high stiffhess-to- weight (i.e., "specific stiffness) and strength-to-weight (i.e., specific strength) ratios the panels afford.
- Typical honeycomb core sandwich panels are described in U.S. Patents 5,284,702; 4,622,091; and 4,353,947.
- U.S. Patent 5,445,861 describes composite sandwich structure for sound absorption (acoustic insulation) and other applications.
- the sandwich structures have seven layers as follows:
- microcracking that originated in the migrated resin could propagate to the bond line and degrade mechanical performance. Such microcracking potential poses a catastrophic threat to the integrity ofthe panel and dictates that flow be eliminated or, at least, controlled.
- Controlling core slippage in the present invention allows us to use lighter density honeycomb core to produce structures without costly scrap due to core crush. We reduce manufacturing costs both by saving time, materials, and rework/scrap and by improving the reliability ofthe manufactiiring process to produce aerospace-quality panels having the highest specific strength and specific stiffness.
- the added tiedown ply means that three or more tiedown plys will be included in the final preform of the panel. In conventional practice, there will also be tiedown plys on the outer surfaces of the panel and possibly between the laminate and the adhesive barrier film. Each tiedown ply extends outwardly from the part beyond the net trim line of the finished product. Conventionally, the tiedown plies are secured individually and sequentially to the layup mandrel with tape. Especially when using low density core it is important to fix the relation of the plies to one another and to the mandrel. Failure of the tape results in facesheet ply wrinkles or core crush.
- the present invention relates to an improvement in the manufacture of composite structure, especially composite honeycomb sandwich structure, where tiedown plys are used to secure the part during autoclave curing at elevated temperature and pressure.
- tiedown plys are used to secure the part during autoclave curing at elevated temperature and pressure.
- a lower temperature curing adhesive to cure and to connect the several plys together during the early stages of autoclave curing prior to applying pressure.
- the present invention relates to adhering tiedown plys to one another during the construction of composite structure, especially during the autoclave processing at elevated temperature and pressure of composite honeycomb sandwich structure.
- the conventional practice of taping the tiedown plys to the mandrel alone is unsatisfactory, because the taping must be sufficient to prevent slippage of any ply or of one ply relative to another.
- this film adhesive melts and cures at a lower temperature than the resin in the laminates so that it bonds the tiedown plies together prior to increasing the autoclave pressure at the higher temperature where the laminate resin flows and cures.
- the film adhesive eliminates movement of the tiedown plys relative to one another.
- a bismaleimide (BMI) sandwich panel we prefer to use an adhesive that cures at about 250°F (121°C) for a BMI that cures around 375°F (191°C), and post-cures around 440 °F.
- Fig. 1 illustrates a typical composite honeycomb sandwich structure.
- Fig. 2 is a schematic, partial sectional view of the skin-core interface in sandwich structure having a scrim-supported barrier film to prevent resin flow from the skin to the core.
- Fig. 3 is a schematic, partial sectional view of prior art honeycomb sandwich structure, suffering resin flow to the core, using a supported film adhesive without a barrier film.
- Fig. 4 is another schematic, partial sectional view showing sandwich structure with resin depletion in the skin, but where the resin is prevented from reaching the core with a bulging, unsupported barrier film.
- Fig. 5 is a schematic, sectional elevation showing core crush of a honeycomb sandwich panel caused by core and barrier film slippage.
- Fig. 6 is another schematic, sectional elevation showing the use of a tiedown ply to reduce core crush.
- Fig. 7 is a graph of a typical autoclave curing cycle for making composite honeycomb sandwich panels, showing that our tiedown adhesive cures prior to the application of high pressure in the cycle.
- a composite honeycomb sandwich panel mniimizes, eliininates, or significantly reduces resin flow from the laminates to the core, thereby permitting a simpler processing cycle that is more robust for the manufacture of aerospace structure.
- Such a sandwich panel 100 (Fig. 1) generally has outer facesheets or skins 102 adhered to a central honeycomb core 106.
- the finished skins 102 comprise laminates of layers of fiber-reinforced organic matrix resin in a cured and consolidated composite form.
- the core 106 can be paper, synthetic paper, metal, composite, or the like, as appropriate for the application.
- an unsupported film adhesive 108 (Fig. 2), a barrier film 110, and a scrim-supported film adhesive 112 between the skin 102 and the core 106 to keep resin out of the cells 1 14 of the core 106.
- Fig. 3 illustrates the core-filling problems that can result when a film adhesive 112 is used alone without the barrier film 1 10 and film adhesive 108.
- Cells 114 of the honeycomb fill with resin 118 which migrates from the laminates and which thereby depletes the resin in the skin 102. Resin depletion impacts structural performance because it reduces ply thickness. Resin depletion increases total weight since the cell resin 118 is simply waste. In all cases, uncontrolled resin flow and depletion makes the panel suspect, especially to microcracking that can begin in the cell resin 118 during thermal cycling and migrate to the fiber-reinforced skin 102, especially at the bond line between the skin 102 and core 106.
- Fig. 4 illustrates undesirable bulging that can occur if a barrier film 110 is used without a scrim-supported film adhesive 112 to try to eliminate cell resin 118.
- a waste resin bulge 120 protrudes downwardly into the cells 114 of die honeycomb core 106. While the resin is contained in the bulge 120, the skin 102 is still depleted in resin.
- the flow of resin to bulge 120 imposes structural performance and weight penalties comparable to the uncontrolled condition illustrated in Fig. 3.
- Fig. 2 with the film adhesive 108, barrier film 110, and scrim-supported film adhesive 12, resin flow is checked without cell resin 118 or resin bulges 120.
- the film adhesive 108 preferably is 0.015 psf METLBOND® 2550U adhesive, also available from Cytec.
- the film adhesive provides additional resin to promote a quality bond between the laminate and barrier film 110.
- the barrier film 110 preferably is a 0.001 inch thick, bondable grade, surface treated KAPTON® polyimide barrier film capable of withstanding the cure cycle to provide a resin impermeable membrane between the skin 102 and core 106.
- the scrim preferably is fiberglass, "Style 104" fiber cloth and the film adhesive 1 12 is 0.06 psf METLBOND® 2550G adhesive, available from Cytec. The scrim-supported film adhesive prevents the barrier film from bulging into the core cells, thereby retaining the resin in the laminate (i.e., skin layers) so that the cured ply thickness is maximized and thereby, we achieve maximum performance at minimum weight for the panels.
- the film adhesive 108, barrier film 110, and film adhesive 112 can be purchased as a single item from Cytec as METLBOND® 2550B-.082 36".
- the plys of the skin 102 typically are prepregs of carbon fiber impregnated with bismaleimide thermoset resin, although the present invention applies to other resin systems. Tows might be used in place of the prepreg.
- the film adhesive 108 should be tailored to achieve an adequate bond between the skin 102 and barrier film 110.
- the honeycomb core generally is HRP Fiberglass Reinforced Phenolic honeycomb available from Hexcel.
- the supported film adhesive and barrier film layers in the sandwich structure also function as corrosion barriers between the skin 102 and core 106 in the case where the core is metal, such as aluminum, and the skin includes a galvanically dissimilar material, such as carbon fiber.
- the Hartz-type panels provide mechanical and physical edgeband properties equivalent to solid BMI/carbon laminate (cured at 0.59 MPa (85 psig)).
- Our tests confirm that in our panels die edgeband cured-ply-thickness is equivalent to a solid laminate and mat the edgeband 160 (Figs. 5 & 6) met die requirements of die solid laminate nondestructive inspection specification.
- the edgeband and facesheet mechanical performance improved over results we achieved widi sandwich structure lacking the scrim-supported adhesive, barrier film, adhesive combination.
- the flatwise tensile mechanical performance also met design requirements.
- Core crush 200 occurs in the chamfer region 155 when the barrier film 110 and core 106 slip relative to die facesheets 102 when autoclave pressure is applied and when tiie resin is melted. As shown in Fig. 5, me barrier films 100 and core 106 have moved toward the right to compress die core in die chamfer region 155 to produce die core crush 200. The skin 102 has sagged in die edgeband region 160 where die core moved away.
- the improved honeycomb sandwich panel includes at least one tiedown ply 150 in contact witii die core 106 along a chamfer 155.
- a chamfer i.e. an angled transition in die core, often at die edgeband 160
- Such a chamfer typically occurs around die periphery of die panel, but it might also occur intermediate of die panel at join lines or hard points where fasteners or pass-diroughs might be necessary in the assembled structure.
- a single ply 150 of carbon fiber or fiberglass fabric widi a conventional 0/90 fiber orientation in die fabrication of bismaleimide panels having 5 or 8 lb/ft ⁇ HRP core, like Hartz et al. describe.
- the tiedown ply 150 functions to prohibit or to limit slippage of die skin relative to die core so as to reduce core crush otherwise attributable to die slippage.
- the tiedown ply 150 anchors die core widi die inherent roughness of die fabric when die preform is heated during die autoclave processing cycle and die matrix resin softens, melts, and, for high flow resins, essentially liquefies.
- Widi diese panels we can save between 2.5-4 lb/ft-* of core because we can use lighter density honeycomb core widiout suffering core crush. For a fighter, tiiis change can save as much as 25 lbs per vehicle.
- the tiedown ply 150 is a narrow, peripheral strip diat contacts die core 106 along at least a portion ofthe chamfer 155 for about 1 inch overlap widi die core 106 and extends outward into die edgeband 160 beyond die trimline 165 of die part.
- the tiedown ply 150 might be on either me flat side of die chamfer or die angled surface (which is how we show it in Fig. 6).
- the key factor is diat die tiedown ply 150 contact die core beneath die adhesive and barrier film 110 which is used to bond die laminate skin to die core.
- the tiedown ply 150 is cutaway everywhere in die body of the part otiier tiian a narrow peripheral area in die chamfer region, and forms a peripheral frame around die edge of die panel. In tiiis way, die tiedown ply 150 allows an adhesive interface between die core 106 and die skins 102 in die panel region.
- the tiedown plies 150 and 175 extend dirough die edgeband 160 beyond die net trim line 165 to anchoring points diat we tape to die layup mandrel.
- a low curing i.e. 121°C for BMI panels
- the film adhesive 180 eliminates movement of one ply relative to die otiiers when we apply pressure during die autoclave curing cycle. Curing at a temperature of about 100 - 150°F below die curing temperature of die laminate resin, die tiedown adhesive cures before we need to increase die autoclave pressure and die cured adhesive bonds die tiedown plys to one anodier. Using die adhering metiiod eliminates relative movement of die plys and eliminates facesheet wrinkles and core crush that odierwise can occur.
- the tiedown metiiod saves material, reduces cost, and saves weight, because it use the "picture frame" peripheral tiedown ply 150 (with the traditional, internal sheets omitted).
- the normal tiedown procedure entails plys on die outer surfaces of die skins and internally between die skin and underlying adhesive (Fig. 5).
- a traditional tiedown system will fail widiout die "picture frame” ply because die barrier film 110 permits die core to slip.
- the Corbett and Smitii metiiod will fail occasionally widiout die adhering metiiod of die present invention.
- For lightweight core (i.e. 5-8 Ib/ft ⁇ ) widi die bismaleimide prepreg and adhesive system previously described, we hold die chamfer angle to 20° ⁇ 2°.
- chamfer we mean an angled, cut region (a ramp) ofthe honeycomb core tapering from full thickness to no thickness with a steady slope.
- a chamfer is used at die edge band of a composite honeycomb sandwich panel to provide a smootii transition between the structural body of die panel diat has die embedded honeycomb and a connecting edge band lacking any honeycomb core.
- the metiiod ofthe present invention allows us to use much steeper chamfer angles tiian traditional practices often require if one is to avoid core crush widiout one tiedown ply. While we prefer a 20° chamfer, we believe diat we could increase the angle to whatever angle suited die panel design requirements.
- autoclave processing we mean die cycle of elevated temperature and pressure applied to die panel to consolidate and cure resin in the laminate while bonding or otiierwise adhering die cured laminate to die honeycomb core. Our preferred cycle is illustrated in Fig. 7.
- Our adhesive for die tiedown plies cures at about 250°F (121°C) so it cures prior to die increase in autoclave pressure diat can introduce relative motion between layers in die panel.
Abstract
We eliminate resin flow into the cells of honeycomb in sandwich structure by using an unsupported film adhesive (108), a barrier layer (110), and a scrim supported adhesive layer (112) between the composite laminate (102) and the core (106). We produce superior panels with lighter weights, improved mechanical properties, and more predictable structural performance by keeping resin in the laminate rather than losing it to the core cells. We reduce core crush and ply wrinkling in composite honeycomb sandwich structure by preventing slipping of tiedown plies relative to the mandrel and to one another during autoclave curing. We produce superior panels with lighter weights, improved mechanical properties, and more predictable structural performance. The method involves applying a film adhesive to the tiedown plies in the margin of the part outside the net trim line. During heating of the autoclave and prior to the application of high pressure to the composite structure, the film adhesive cures to form a strong bond between the plies and to the mandrel. When pressure is applied, the tiedown plies are locked together and to the mandrel to prevent slippage between any layers in the panel.
Description
COMPOSITE HONEYCOMB SAND WICH STR UCTURE
Technical Field
The present invention relates to composite honeycomb sandwich structure, and particularly to resin impregnated fabric sheets forming outer skins adhered on opposed surfaces of a honeycomb core with an intermediate barrier to eliminate resin flow from the skins to the core.
Background Art
Aerospace honeycomb core sandwich panels (having composite laminate skins cocured with adhesives to the core through autoclave processing) find widespread use today because of the high stiffhess-to- weight (i.e., "specific stiffness) and strength-to-weight (i.e., specific strength) ratios the panels afford. Typical honeycomb core sandwich panels are described in U.S. Patents 5,284,702; 4,622,091; and 4,353,947. Alteneder et al., Processing and Characterization Studies of Honeycomb Composite Structures, 38 th Int'l SAMPE Symposium, May 10-13, 1993 (PCL Internal No. 200-01/93- A WA) discusses common problems with these panels, including core collapse (i.e., core crush), skin laminate porosity, and poor tool surface finish.
U.S. Patent 5,445,861 describes composite sandwich structure for sound absorption (acoustic insulation) and other applications. The sandwich structures have seven layers as follows:
(1) an outer skin;
(2) a small celled honeycomb or foam core;
(3) a frontside inner septum;
(4) a large celled middle honeycomb core;
(5) a backside, inner septum;
(6) a backside, small celled honeycomb or foam core; and
(7) an inner skin. Tuned cavity absorbers in the middle honeycomb core absorb sound. Performance of this structure suffers from resin flow to the cells of the honeycomb cores during fabrication for the reasons already discussed and because such flow alters the resonance ofthe structure.
Summary of the Invention
With a high flow resin system, large amounts of resin can flow into the core during the autoclave processing cycle. Such flow robs resin from the laminate, introduces a weight penalty in the panel to achieve the desired performance, and forces over design ofthe laminate plies to account for the flow losses. The resin loss from the laminate plies also reduces the thickness of the cured plies which compromises the mechanical performance. To achieve the desired performance and the corresponding laminate thickness, additional plies are necessary with resulting cost and weight penalties. Because the weight penalty is severe in terms of the impact on vehicle performance and cost in modern aircraft and because the flow is a relatively unpredictable and uncontrolled process, aerospace design and manufacture dictates that flow into the core be eliminated or significantly reduced. In addition to the weight penalty from resin flow to the core, we discovered that microcracking that originated in the migrated resin could propagate to the bond line and degrade mechanical performance. Such microcracking potential poses a catastrophic threat to the integrity ofthe panel and dictates that flow be eliminated or, at least, controlled.
Flow from the laminates to the core occurs because of viscosity reduction of the resin (i.e., thinning) at the elevated processing temperatures. Therefore, prior art attempts to solve the flow problem have generally focused on retaining the ambient temperature viscosity ofthe resin at the curing temperatures. For example, one might alter the processing cycle to initiate
curing of the resin during a slow heat-up, low pressure step to induce resin chain growth before high temperature, high pressure completion. In this staged cure cycle, one would try to retain the resin's viscosity by building molecular weight at low temperatures. Higher molecular weight resins have inherently higher viscosity so they remain thicker and are resistant to damaging flow to the core. Unfortunately, with a staged cure cycle, too much flow still occurs, and the potential problems of microcracking still abound. Also, facesheet porosity might increase beyond acceptable limits. Furthermore, a modified cure cycle increases autoclave processing time. Increased processing time translates to a significant fabrication cost increase with risk of rejection of high value parts at the mercy of uncontrolled and inadequately understood factors.
We eliminate resin (matrix) flow into the honeycomb core for sandwich structure using high flow resin systems and results in reproducibility and predictability in sandwich panel fabrication and confidence in the structural performance ofthe resulting panel. We use a scrim-supported barrier film between the fiber-reinforced resin composite laminates and the honeycomb core. This sandwich structure is lighter for the same performance characteristics than prior art panels because the resin remains in the laminate (skin) where it provides structural strength rather than flowing to the core where it is worthless, introducing excess weight and potential panel failure. We also generally use an unsupported film adhesive between the barrier film and the laminates to bond the laminates to the barrier film. With these layers (which might be combined into one product), they achieved improved performance, retained the resin in the laminates and thereby reduced excess resin that designers otherwise needed to design into the panels to account for resin flow into the core, and reliably fabricated panels in which they had structural confidence.
Core crush frequently occurred in the chamfer region of honeycomb core when we cured a panel having a scrim-supported barrier film, particularly
when they tried to use lighter weight core materials. We can reduce core crush in these panels by including a tiedown ply in contact with the core beneath the barrier film (and adhesive) because the tiedown ply reduced slippage ofthe barrier film relative to the core during curing.
Controlling core slippage in the present invention allows us to use lighter density honeycomb core to produce structures without costly scrap due to core crush. We reduce manufacturing costs both by saving time, materials, and rework/scrap and by improving the reliability ofthe manufactiiring process to produce aerospace-quality panels having the highest specific strength and specific stiffness.
The added tiedown ply means that three or more tiedown plys will be included in the final preform of the panel. In conventional practice, there will also be tiedown plys on the outer surfaces of the panel and possibly between the laminate and the adhesive barrier film. Each tiedown ply extends outwardly from the part beyond the net trim line of the finished product. Conventionally, the tiedown plies are secured individually and sequentially to the layup mandrel with tape. Especially when using low density core it is important to fix the relation of the plies to one another and to the mandrel. Failure of the tape results in facesheet ply wrinkles or core crush. Core crush could still occasionally occur when the tiedown ply in contact with the core pulled away from the tape securing it to the mandrel, slipping relative to the other tiedown plies. The adhering strength of the tape alone was insufficient to overcome the forces acting on the core in a panel when we applied autoclave pressure. We discovered how to adhere the tiedown plies to each other reliably, easily, and inexpensively. Adhering the plies to each other distributes the forces acting on any individual ply among all the tiedown plies, reducing the maximum force seen by the tape adhering the tiedown plies to the mandrel. While described with respect to a composite honeycomb sandwich structure,
the adhering method is generally applicable to all applications involving tiedown plies in composite construction.
Thus, in one aspect, the present invention relates to an improvement in the manufacture of composite structure, especially composite honeycomb sandwich structure, where tiedown plys are used to secure the part during autoclave curing at elevated temperature and pressure. To lock the tiedown plies together so that there is no movement of one ply relative to another, we use a lower temperature curing adhesive to cure and to connect the several plys together during the early stages of autoclave curing prior to applying pressure. We apply the adhesive outside the net trim line for the part, so that it is removed during finishing ofthe part.
In another aspect, the present invention relates to adhering tiedown plys to one another during the construction of composite structure, especially during the autoclave processing at elevated temperature and pressure of composite honeycomb sandwich structure. The conventional practice of taping the tiedown plys to the mandrel alone is unsatisfactory, because the taping must be sufficient to prevent slippage of any ply or of one ply relative to another. We discovered that we could adhere the plies effectively to one another to reduce maximum forces on the tape by applying a low temperature curing film adhesive between the tiedown plys just outside the net trim line for the part. In the autoclave, this film adhesive melts and cures at a lower temperature than the resin in the laminates so that it bonds the tiedown plies together prior to increasing the autoclave pressure at the higher temperature where the laminate resin flows and cures. The film adhesive eliminates movement of the tiedown plys relative to one another. In our preferred embodiment for a bismaleimide (BMI) sandwich panel, we prefer to use an adhesive that cures at about 250°F (121°C) for a BMI that cures around 375°F (191°C), and post-cures around 440 °F.
Brief Description of the Drawings.
Fig. 1 illustrates a typical composite honeycomb sandwich structure.
Fig. 2 is a schematic, partial sectional view of the skin-core interface in sandwich structure having a scrim-supported barrier film to prevent resin flow from the skin to the core.
Fig. 3 is a schematic, partial sectional view of prior art honeycomb sandwich structure, suffering resin flow to the core, using a supported film adhesive without a barrier film.
Fig. 4 is another schematic, partial sectional view showing sandwich structure with resin depletion in the skin, but where the resin is prevented from reaching the core with a bulging, unsupported barrier film.
Fig. 5 is a schematic, sectional elevation showing core crush of a honeycomb sandwich panel caused by core and barrier film slippage.
Fig. 6 is another schematic, sectional elevation showing the use of a tiedown ply to reduce core crush.
Fig. 7 is a graph of a typical autoclave curing cycle for making composite honeycomb sandwich panels, showing that our tiedown adhesive cures prior to the application of high pressure in the cycle.
Detailed Description of a Preferred Embodiment
As a frame of reference for this description, we will initially describe typical composite honeycomb sandwich structure. Then, we will turn to our invention of a method of reliably adhering the tiedown plies together.
A composite honeycomb sandwich panel mniimizes, eliininates, or significantly reduces resin flow from the laminates to the core, thereby permitting a simpler processing cycle that is more robust for the manufacture of aerospace structure. Such a sandwich panel 100 (Fig. 1) generally has outer facesheets or skins 102 adhered to a central honeycomb core 106. The finished skins 102 comprise laminates of layers of fiber-reinforced organic matrix resin
in a cured and consolidated composite form. The core 106 can be paper, synthetic paper, metal, composite, or the like, as appropriate for the application. In panels of the present invention, we obtain higher specific strengths and higher specific stiffnesses because we reduce core crush during autoclave curing by incorporating at least one tiedown ply between the core 106 and skin 102 to reduce damaging slippage between the core and skin that otherwise often occurs.
To prevent flow of resin from the composite laminate skin to the core, we use an unsupported film adhesive 108 (Fig. 2), a barrier film 110, and a scrim-supported film adhesive 112 between the skin 102 and the core 106 to keep resin out of the cells 1 14 of the core 106.
Fig. 3 illustrates the core-filling problems that can result when a film adhesive 112 is used alone without the barrier film 1 10 and film adhesive 108. Cells 114 of the honeycomb fill with resin 118 which migrates from the laminates and which thereby depletes the resin in the skin 102. Resin depletion impacts structural performance because it reduces ply thickness. Resin depletion increases total weight since the cell resin 118 is simply waste. In all cases, uncontrolled resin flow and depletion makes the panel suspect, especially to microcracking that can begin in the cell resin 118 during thermal cycling and migrate to the fiber-reinforced skin 102, especially at the bond line between the skin 102 and core 106.
Fig. 4 illustrates undesirable bulging that can occur if a barrier film 110 is used without a scrim-supported film adhesive 112 to try to eliminate cell resin 118. Here, a waste resin bulge 120 protrudes downwardly into the cells 114 of die honeycomb core 106. While the resin is contained in the bulge 120, the skin 102 is still depleted in resin. The flow of resin to bulge 120 imposes structural performance and weight penalties comparable to the uncontrolled condition illustrated in Fig. 3.
As shown in Fig. 2 with the film adhesive 108, barrier film 110, and scrim-supported film adhesive 12, resin flow is checked without cell resin 118 or resin bulges 120. We discovered, however, that the barrier film produced a slip plane between the laminate skins and the core which often resulted in core crush during the autoclave processing cycle. In 22 of 31 test panels, in fact, we experienced core crush in our initial trials. This rate of failure was unacceptable from a cost and schedule perspective. Our tiedown plys in the chamfer region reduce the frequency of or eliminate damaging core slippage and the core crush attributable to such slippage.
For bismaleimide laminated skins made with RIGIDITE® 5250-4-W- IM7-GP-CSW, RIGIDITE® 5250-4- W-IM7-GP-CSX, and RIGIDITE® 5250- 4-W-IM7-GP-PW prepreg from Cytec Engineered Materials, Inc. (Cytec), the film adhesive 108 preferably is 0.015 psf METLBOND® 2550U adhesive, also available from Cytec. The film adhesive provides additional resin to promote a quality bond between the laminate and barrier film 110. The barrier film 110 preferably is a 0.001 inch thick, bondable grade, surface treated KAPTON® polyimide barrier film capable of withstanding the cure cycle to provide a resin impermeable membrane between the skin 102 and core 106. The scrim preferably is fiberglass, "Style 104" fiber cloth and the film adhesive 1 12 is 0.06 psf METLBOND® 2550G adhesive, available from Cytec. The scrim- supported film adhesive prevents the barrier film from bulging into the core cells, thereby retaining the resin in the laminate (i.e., skin layers) so that the cured ply thickness is maximized and thereby, we achieve maximum performance at minimum weight for the panels.
The film adhesive 108, barrier film 110, and film adhesive 112 can be purchased as a single item from Cytec as METLBOND® 2550B-.082 36".
The plys of the skin 102 typically are prepregs of carbon fiber impregnated with bismaleimide thermoset resin, although the present invention applies to other resin systems. Tows might be used in place of the prepreg.
The film adhesive 108 should be tailored to achieve an adequate bond between the skin 102 and barrier film 110. The honeycomb core generally is HRP Fiberglass Reinforced Phenolic honeycomb available from Hexcel.
The supported film adhesive and barrier film layers in the sandwich structure also function as corrosion barriers between the skin 102 and core 106 in the case where the core is metal, such as aluminum, and the skin includes a galvanically dissimilar material, such as carbon fiber.
Additional information concerning preferred panels is presented in the technical paper: Hartz et al., "Development of a Bismaleimade/Carbon Honeycomb Sandwich Structure," SAMPE, March, 1996, which we incorporate by reference. This paper describes both the Hartz et al. barrier film improvement, the tiedown ply method, and the adhering method ofthe present invention.
The Hartz-type panels provide mechanical and physical edgeband properties equivalent to solid BMI/carbon laminate (cured at 0.59 MPa (85 psig)). Our tests confirm that in our panels die edgeband cured-ply-thickness is equivalent to a solid laminate and mat the edgeband 160 (Figs. 5 & 6) met die requirements of die solid laminate nondestructive inspection specification. The edgeband and facesheet mechanical performance improved over results we achieved widi sandwich structure lacking the scrim-supported adhesive, barrier film, adhesive combination. The flatwise tensile mechanical performance also met design requirements.
Preconditioning die core to eliminate volatile evolution during curing by heating die core to about 235° C (455° F), prior to laying up die sandwich panel, especially for phenolic core, eliminates core-laminate disbonding otiierwise caused by outgassing from me core.
Core crush 200 (Fig. 5) occurs in the chamfer region 155 when the barrier film 110 and core 106 slip relative to die facesheets 102 when autoclave pressure is applied and when tiie resin is melted. As shown in Fig. 5, me
barrier films 100 and core 106 have moved toward the right to compress die core in die chamfer region 155 to produce die core crush 200. The skin 102 has sagged in die edgeband region 160 where die core moved away.
Referring now to Fig. 6, the improved honeycomb sandwich panel includes at least one tiedown ply 150 in contact witii die core 106 along a chamfer 155. Such a chamfer (i.e. an angled transition in die core, often at die edgeband 160) typically occurs around die periphery of die panel, but it might also occur intermediate of die panel at join lines or hard points where fasteners or pass-diroughs might be necessary in the assembled structure.
Typically we use a single ply 150 of carbon fiber or fiberglass fabric widi a conventional 0/90 fiber orientation in die fabrication of bismaleimide panels having 5 or 8 lb/ft^ HRP core, like Hartz et al. describe. The tiedown ply 150 functions to prohibit or to limit slippage of die skin relative to die core so as to reduce core crush otherwise attributable to die slippage. The tiedown ply 150 anchors die core widi die inherent roughness of die fabric when die preform is heated during die autoclave processing cycle and die matrix resin softens, melts, and, for high flow resins, essentially liquefies. Widi diese panels, we can save between 2.5-4 lb/ft-* of core because we can use lighter density honeycomb core widiout suffering core crush. For a fighter, tiiis change can save as much as 25 lbs per vehicle.
As shown in Fig. 6, the tiedown ply 150 is a narrow, peripheral strip diat contacts die core 106 along at least a portion ofthe chamfer 155 for about 1 inch overlap widi die core 106 and extends outward into die edgeband 160 beyond die trimline 165 of die part. The tiedown ply 150 might be on either me flat side of die chamfer or die angled surface (which is how we show it in Fig. 6). The key factor is diat die tiedown ply 150 contact die core beneath die adhesive and barrier film 110 which is used to bond die laminate skin to die core. The tiedown ply 150 is cutaway everywhere in die body of the part otiier tiian a narrow peripheral area in die chamfer region, and forms a peripheral
frame around die edge of die panel. In tiiis way, die tiedown ply 150 allows an adhesive interface between die core 106 and die skins 102 in die panel region.
Traditionally, in making a Hartz-type panel, we use four complete cover sheet tiedown plies 175 in an effort to anchor die layers and die core, and we show all diese plies in Fig. 6. These traditional plies 175 were commonly used in sandwich panel fabrication prior to introducing die Hartz-type barrier film, and we commonly use diem all, altiiough we believe we can now eliminate all but die outer plies and die peripheral, core contacting tiedown ply 150. That is, we would use tiiree total plies radier tiian five, as Fig. 6 shows.
The tiedown plies 150 and 175 extend dirough die edgeband 160 beyond die net trim line 165 to anchoring points diat we tape to die layup mandrel. To further prevent slippage of die tiedown plies, we have incoφorated a low curing (i.e. 121°C for BMI panels) film adhesive 180 between die tiedown plies just outside die net trim line of die part. The film adhesive 180 eliminates movement of one ply relative to die otiiers when we apply pressure during die autoclave curing cycle. Curing at a temperature of about 100 - 150°F below die curing temperature of die laminate resin, die tiedown adhesive cures before we need to increase die autoclave pressure and die cured adhesive bonds die tiedown plys to one anodier. Using die adhering metiiod eliminates relative movement of die plys and eliminates facesheet wrinkles and core crush that odierwise can occur.
The tiedown metiiod saves material, reduces cost, and saves weight, because it use the "picture frame" peripheral tiedown ply 150 (with the traditional, internal sheets omitted). The normal tiedown procedure entails plys on die outer surfaces of die skins and internally between die skin and underlying adhesive (Fig. 5). A traditional tiedown system will fail widiout die "picture frame" ply because die barrier film 110 permits die core to slip. The Corbett and Smitii metiiod will fail occasionally widiout die adhering metiiod of die present invention.
For lightweight core (i.e. 5-8 Ib/ft^) widi die bismaleimide prepreg and adhesive system previously described, we hold die chamfer angle to 20° ± 2°.
By "chamfer" we mean an angled, cut region (a ramp) ofthe honeycomb core tapering from full thickness to no thickness with a steady slope. A chamfer is used at die edge band of a composite honeycomb sandwich panel to provide a smootii transition between the structural body of die panel diat has die embedded honeycomb and a connecting edge band lacking any honeycomb core. The metiiod ofthe present invention allows us to use much steeper chamfer angles tiian traditional practices often require if one is to avoid core crush widiout one tiedown ply. While we prefer a 20° chamfer, we believe diat we could increase the angle to whatever angle suited die panel design requirements.
By "autoclave processing" we mean die cycle of elevated temperature and pressure applied to die panel to consolidate and cure resin in the laminate while bonding or otiierwise adhering die cured laminate to die honeycomb core. Our preferred cycle is illustrated in Fig. 7. Our adhesive for die tiedown plies cures at about 250°F (121°C) so it cures prior to die increase in autoclave pressure diat can introduce relative motion between layers in die panel.
If core crush occurs, the damage to the panel is generally so extensive tiiat repair is impossible so die part is scrapped. The cost of today's advanced composite resins and reinforcing fibers requires a process tiiat virtually eliminates core crush. Otiierwise, die processing costs are prohibitive. Widi panels being designed as close to the design edge as possible, core crush is a significant issue. The metiiod of die present invention reduces cores crush and ply movement or wrinkling.
While we have described preferred embodiments, tiiose skilled in the art will readily recognize alterations, variations, and modifications, which might be made widiout departing from the inventive concept. Therefore, interpret die claims liberally with the support of the full range of equivalents known to those
of ordinary skill based upon tiiis description. The examples are given to illustrate die invention and are not intended to limit it. Accordingly, define die invention by the claims and limit die claims only as necessary in view of die pertinent prior art.
Claims
1. Composite honeycomb sandwich structure, comprising:
(a) a honeycomb core, having core cells;
(b) at least one composite laminate having plies of fiber-reinforced matrix resin adhered to die core;
(c) a film barrier layer between die laminate and the core to bond die laminate and core and to eliminate resin flow from the laminate into the core cell; and
(d) a film adhesive with supporting scrim between die barrier layer and die core to eliminate resin flow to or sagging of die barrier film into the core cells.
2. The structure of claim 1 wherein die laminate includes bismaleimide matrix resin.
3. The structure of claim 1 wherein die barrier layer is a bondable grade, polyimide.
4. The structure of claim 2 wherein die film adhesive includes bismaleimide.
5. The structure of claim 4 further comprising an unsupported film adhesive layer between die barrier layer and die laminate.
6. A method for elύninating die flow of resin from laminate skins of a composite honeycomb sandwich panel to cells of die honeycomb comprising tiie step of: containing die resin in die skin witii a scrim supported barrier film tiiat is impermeable to die resin and diat is adhered between die skin and honeycomb.
7. A method for adhering tiedown plies togedier in die manufacture of composite structure, comprising the steps of:
(a) assembling on the layup mandrel a composite preform in the shape of die composite structure, the preform having at least one resin-impregnated laminate and at least two tiedown plys; and
(b) adhering die tiedown plys to one anodier with a film adhesive applied to die plys outside a net trim line of die composite structure.
wherein die film adhesive cures at a temperature lower than the resin in the laminate.
8. The metiiod of claim 7 wherein die laminate includes bismaleimide matrix resin.
9. The metiiod of claim 7 wherein die preform includes a barrier film made from a bondable grade, polyimide adjacent die laminate.
10. The metiiod of claim 8 wherein die preform includes a honeycomb core and an adhesive between die barrier film and core.
11. The metiiod of claim 10 wherein die preform includes a film adhesive layer between die barrier film and die laminate.
12. The method of claim 10 wherein die preform includes a supporting scrim between the barrier film adhesive and the core to prevent sagging of die barrier film into die core cells.
13. The metiiod of claim 12 wherein die preform includes a tiedown ply in contact witii die core between die adhesive and core.
14. A metiiod for reducing core crush in a chamfered composite honeycomb sandwich panel having a resin-impregnated laminate adhered to a honeycomb core, die core having a chamfer, comprising die steps of:
(a) contacting a tiedown ply widi die honeycomb core of tiie panel in the region of die chamfer to prevent slippage between the core and die laminate; and
(b) assembling tiedown plies over outer surfaces of the laminate;
(c) adhering die tiedown plies togedier and to die layup mandrel widi a lower temperature curing adhesive applied to die tiedown plies outside a net trim line of die panel,
wherein die adhesive melts and cures prior to die application of autoclave pressure and prior to die melt and flow of die resin in the laminate.
15. The method of claim 14 wherein die laminate includes a barrier film to prevent resin flow from facesheets of die laminate to the core cells, and wherein one tiedown ply is between die barrier film and core.
16. Composite honeycomb sandwich structure having improved resistance to core crush, comprising:
(a) a honeycomb core, having core cells and a peripheral chamfer;
(b) at least one composite laminate having plies of fiber-reinforced matrix resin adhered to die core;
(c) a barrier film adhesive between die laminate and die core to bond die laminate and core and to eliminate resin flow from die laminate into die core cells; and
(d) a peripheral tiedown ply in contact widi die chamfer of die core beneatii the adhesive to eliminate slippage of the barrier film relative to die core and, in so doing, to reduce core crush.
17. The structure of claim 16 wherein the laminate includes bismaleimide matrix resin.
18. The structure of claim 16 wherein the barrier film is a bondable grade, polyimide.
19. The structure of claim 17 wherein the adhesive includes bismaleimide.
20. The structure of claim 19 further comprising a film adhesive layer between die barrier film and die laminate.
21. The structure of claim 16 further comprising a supporting scrim between die barrier film adhesive and die core to prevent sagging of die barrier film into die core cells.
22. Composite honeycomb sandwich structure resistant to core crush caused by slippage of a composite laminate along a chamfer of a honeycomb core, comprising:
(a) a honeycomb core having a chamfer;
(b) a tiedown ply contacting die chamfer; and
(c) at lease one laminate adhered to die core tiirough die tiedown ply at die chamfer wherein die tiedown ply prevents damaging slippage of die laminate relative to die core diat would produce core crush during autoclave curing of the structure to adhere die core to die laminate.
23. A metiiod for reducing core crush in a chamfered composite honeycomb sandwich panel having a laminate adhered to a honeycomb core, die core having a chamfer, comprising tiie step of: contacting a tiedown ply widi die honeycomb core ofthe panel in the region of the chamfer to prevent slippage between die core and die laminate.
24. The metiiod of claim 23 wherein die laminate includes a barrier film to prevent resin flow from die laminate to die core cells.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU18229/97A AU1822997A (en) | 1996-01-11 | 1997-01-06 | Composite honeycomb sandwich structure |
CA002242050A CA2242050C (en) | 1996-01-11 | 1997-01-06 | Composite honeycomb sandwich structure |
JP52529497A JP3913275B2 (en) | 1996-01-11 | 1997-01-06 | Composite honeycomb sandwich structure |
EP97903737A EP0883484A1 (en) | 1996-01-11 | 1997-01-06 | Composite honeycomb sandwich structure |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/587,160 US5604010A (en) | 1996-01-11 | 1996-01-11 | Composite honeycomb sandwich structure |
US08/587,160 | 1996-01-11 | ||
US08/616,903 | 1996-03-15 | ||
US08/616,903 US5895699A (en) | 1996-03-15 | 1996-03-15 | Tiedown ply for reducing core crush in composite honeycomb sandwich structure |
US08/620,829 US5685940A (en) | 1996-03-20 | 1996-03-20 | Adhering tiedown plies in composite construction |
US08/620,829 | 1996-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1997025198A1 WO1997025198A1 (en) | 1997-07-17 |
WO1997025198A9 true WO1997025198A9 (en) | 1997-10-23 |
Family
ID=27416496
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/000075 WO1997025198A1 (en) | 1996-01-11 | 1997-01-06 | Composite honeycomb sandwich structure |
Country Status (5)
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EP (1) | EP0883484A1 (en) |
JP (2) | JP3913275B2 (en) |
CN (1) | CN1101751C (en) |
AU (1) | AU1822997A (en) |
WO (1) | WO1997025198A1 (en) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR9911045B1 (en) | 1998-05-22 | 2009-08-11 | use of a stiffness-treated fabric, method for producing a stiffness-treated fabric, stiffness-treated fabric, use of a stiffness-treated fabric raw material, method for producing a stiffness-treated fabric raw material stiffness, use of a stiffness-treated prepreg layer, method for producing a stiffness-treated prepreg layer for a stiffness-treated honeycomb precursor, stiffness-treated honeycomb structure produce a stiffness-treated honeycomb precursor and method of producing a stiffness-treated honeycomb sandwich structure. | |
JP4663174B2 (en) * | 2001-08-03 | 2011-03-30 | 富士重工業株式会社 | Method for forming honeycomb sandwich structure composite material |
DE502004007968D1 (en) | 2003-07-08 | 2008-10-16 | Airbus Gmbh | lightweight structure |
EP1495858B1 (en) | 2003-07-08 | 2019-08-07 | Airbus Operations GmbH | Lightweight material structure made of metal composite material |
JP2007098819A (en) * | 2005-10-06 | 2007-04-19 | Mitsubishi Rayon Co Ltd | Manufacturing method of sandwich panel |
FR2908737B1 (en) * | 2006-11-16 | 2009-12-04 | Airbus France | ACOUSTIC COATING FOR AIRCRAFT INCORPORATING A JELLY EFFECT FROST TREATMENT SYSTEM. |
US8046915B2 (en) * | 2007-12-12 | 2011-11-01 | General Electric Company | Methods for making composite containment casings |
US20090155524A1 (en) * | 2007-12-13 | 2009-06-18 | Rapp Robert A | Composite panel and method of manufacturing the same |
US8343298B2 (en) * | 2007-12-13 | 2013-01-01 | The Boeing Company | Aircraft structures bonded with adhesive including magnetostrictive material |
BE1017910A3 (en) | 2007-12-21 | 2009-11-03 | Sonaca Sociutu Anonyme | METHOD FOR MANUFACTURING A PANEL COMPRISING AT LEAST ONE NANNED BODY AND A FIRST SKIN REALIZED IN COMPOSITE MATERIAL |
US8491743B2 (en) * | 2009-12-15 | 2013-07-23 | The Boeing Company | Composite ply stabilizing method |
JP5619485B2 (en) * | 2010-06-22 | 2014-11-05 | 豊和繊維工業株式会社 | Laminated vehicle interior substrate and manufacturing method thereof |
US8844873B2 (en) * | 2011-09-23 | 2014-09-30 | The Boeing Company | Stabilizer torque box assembly and method |
FR2987307B1 (en) * | 2012-02-29 | 2017-02-10 | Daher Aerospace | METHOD AND DEVICE FOR THE COMPACTION AND CONSOLIDATION OF A HIGH THERMOPLASTIC DIE COMPOSITE PANEL |
CN102700181B (en) * | 2012-05-15 | 2014-09-03 | 西安交通大学 | Light multifunctional composite structure |
US9517594B2 (en) * | 2012-10-04 | 2016-12-13 | The Boeing Company | Composite structure having a stabilizing element |
CN102909899B (en) * | 2012-10-25 | 2015-03-11 | 溧阳二十八所系统装备有限公司 | Production method for waterproof paper honeycomb compound sandwich board |
CN103161391A (en) * | 2013-03-07 | 2013-06-19 | 苏州市江诚人防设备有限公司 | Inorganic protective door |
CA2919440C (en) * | 2013-07-26 | 2023-04-25 | Learjet Inc. | Composite material incorporating water ingress barrier |
US9579875B2 (en) | 2014-02-04 | 2017-02-28 | The Boeing Company | Bonded tab and tooling device |
JP5992946B2 (en) | 2014-03-25 | 2016-09-14 | 富士重工業株式会社 | Honeycomb structure and method for manufacturing honeycomb structure |
CN105539809A (en) * | 2014-10-28 | 2016-05-04 | 哈尔滨飞机工业集团有限责任公司 | Sectional honeycomb sandwich structure |
AU2017348944A1 (en) * | 2016-10-27 | 2019-04-18 | Ruag Schweiz Ag | Fiber reinforced polymer manufacturing |
JP7039401B2 (en) | 2018-06-28 | 2022-03-22 | 三菱重工業株式会社 | Composite material and method of curing composite material |
JP7114367B2 (en) | 2018-06-28 | 2022-08-08 | 三菱重工業株式会社 | Forming method for composite structure |
CN109159518A (en) * | 2018-08-28 | 2019-01-08 | 丹阳丹金航空材料科技有限公司 | A kind of aviation aircraft composite plate |
CN111186147B (en) * | 2020-02-24 | 2021-10-08 | 江苏亨睿碳纤维科技有限公司 | Forming method for preparing lightweight automobile parts by using continuous fiber mixed chopped fibers |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA985151A (en) * | 1972-03-23 | 1976-03-09 | Paul V. Oliva | Honeycomb core structural panels |
FR2198835B1 (en) * | 1972-09-11 | 1975-03-07 | Rhone Poulenc Ind | |
CA1239572A (en) * | 1983-09-21 | 1988-07-26 | Roger A. Stonier | Method for cocuring a composite skin directly to honeycomb core |
US4598007A (en) * | 1985-02-28 | 1986-07-01 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Light weight fire resistant graphite composites |
GB8817669D0 (en) * | 1988-07-25 | 1988-09-01 | Short Brothers Ltd | Means for attenuating sound energy |
US4954382A (en) * | 1988-11-01 | 1990-09-04 | American Cyanamid Company | Interleaf layer in fiber reinforced resin laminate composites |
FR2726500B1 (en) * | 1994-11-09 | 1997-01-10 | Eurocopter France | PROCESS FOR PRODUCING COMPOSITE SANDWICH PANELS AND PANELS OBTAINED THEREBY |
-
1997
- 1997-01-06 EP EP97903737A patent/EP0883484A1/en not_active Withdrawn
- 1997-01-06 CN CN97192447A patent/CN1101751C/en not_active Expired - Lifetime
- 1997-01-06 WO PCT/US1997/000075 patent/WO1997025198A1/en active Application Filing
- 1997-01-06 AU AU18229/97A patent/AU1822997A/en not_active Abandoned
- 1997-01-06 JP JP52529497A patent/JP3913275B2/en not_active Expired - Lifetime
-
2006
- 2006-07-24 JP JP2006200715A patent/JP4407964B2/en not_active Expired - Lifetime
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