WO2007048565A1 - Al-cu-mg alloy suitable for aerospace application - Google Patents
Al-cu-mg alloy suitable for aerospace application Download PDFInfo
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- WO2007048565A1 WO2007048565A1 PCT/EP2006/010216 EP2006010216W WO2007048565A1 WO 2007048565 A1 WO2007048565 A1 WO 2007048565A1 EP 2006010216 W EP2006010216 W EP 2006010216W WO 2007048565 A1 WO2007048565 A1 WO 2007048565A1
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- aluminium alloy
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- alloy product
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- alloy
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/16—Alloys based on aluminium with copper as the next major constituent with magnesium
Definitions
- the invention relates to an aluminium wrought alloy, in particular an Al-Cu- Mg type alloy (or AA2000 series aluminium alloy as designated by the Aluminium
- the present invention relates to an aluminium alloy product having high strength, high fracture toughness exhibiting low crack propagation and high resistance to intergranular corrosion.
- Products made from the aluminium alloy according to the invention are very suitable for aerospace applications but not limited thereto.
- the alloy can be processed to various product forms such as sheet, thin plate or an extruded product, a forged product, or a welded product.
- the aluminium alloy product can be uncoated or coated or plated with another aluminium alloy in order to improve desired properties even further.
- AA2000 series aluminium alloys in aeroplanes is as fuselage or skin plate, for which purpose typically AA2024 in the T351 temper is used or as lower wing plate for which purpose typically AA2024 in the T351 temper and AA2324 in the T39 temper is used.
- Intergranular corrosion of an aluminium alloy not only affects the integrity of the structure for which it is used, in which may corroded grain boundaries may act as a nucleus for cracks which propagate under the influence of the alternating load during operation of the structure. Therefore, the occurrence of intergranular corrosion sets limits to the use of aluminium alloys of the AA2000 series with high levels of the mentioned alloying elements.
- the most commonly used aluminium alloys form the AA2000 series for aerospace application are AA2024, AA2024HDT ("High Damage Tolerant") and AA2324.
- the present invention is directed to a AA2000 series aluminium alloy having the capability of achieving a balance of properties in any relevant product made of the alloy that is better than the balance of properties of the variety of commercially available aluminium alloys of the AA2000 series, nowadays used for such a product or of AA2000 series aluminium alloys disclosed so far.
- One object of the present invention is to provide an aluminium alloy wrought product, in particular suitable for aerospace application within the AA2000 series alloys having an improved balance of high strength and fracture toughness and high resistance to intergranular corrosion.
- Another object of the present invention is to provide an aluminium alloy wrought product as referred to above which shows a high resistance to exfoliation corrosion and stress corrosion cracking.
- a further object of the present invention is to provide an aluminium alloy wrought product as referred to above which is tolerant to the usual variation in process parameters during its manufacturing process.
- Yet another object of the present invention is to provide an aluminium alloy wrought product as referred to above which is weldable and suitable for use in welded constructions.
- Yet another object of the present invention is to provide an aluminium wrought product as referred to above in a form which is suitable for use in an aerospace structure.
- a further object of the present invention is to provide a method of manufacturing an aluminium alloy wrought product as mentioned hereinabove.
- an aluminium alloy wrought product having high strength and high fracture toughness and high resistance to intergranular corrosion, the aluminium alloy comprising in weight %:
- Fig. 1 shows a Cr-Ti diagram setting out the Cr-Ti range for the invention together with narrower preferred ranges.
- Figs. 2a, 2b show micrographs of a cross section of a sample of an alloy according to the invention in T3 temper and of a comparative alloy after corrosion testing.
- Figs. 3a, 3b show micrographs of a cross section of a sample of an alloy according to the invention in T6 temper and of a comparative alloy after corrosion testing.
- the present invention provides an aluminium alloy wrought product having high strength and high fracture toughness and high resistance to intergranular corrosion, the aluminium alloy comprising in weight %:
- composition of the aluminium alloy according to our invention leads to an alloy product having a high resistance to intergranular corrosion while maintaining a higher strength and higher toughness as compared to the conventional AA2024 alloy.
- the alloy product of the invention also exhibits a high resistance to exfoliation corrosion and stress corrosion cracking.
- Good results are also obtained in a preferred embodiment of the invention wherein 0.03% ⁇ Ti ⁇ 0.3%, preferably 0.05% ⁇ Ti ⁇ 0.2%. According to this embodiment good properties can also be achieved with a lower concentration of Ti.
- Another embodiment has the range wherein 0.05% ⁇ Cr ⁇ 0.3%, preferably
- a further embodiment has the range wherein 0.1% ⁇ Ti + Cr ⁇ 0.4%. It has been found that within the given range Ti and Cr can be substituted by each other while maintaining good resistance against intergranular corrosion and good mechanical properties.
- the Cu level is selected in the range wherein 4.4% ⁇ Cu ⁇ 5.5%, more preferably 4.7% ⁇ Cu ⁇ 5.3%.
- the Mg level is selected in the range wherein 0.3% ⁇ Mg ⁇ 1.2%, more preferably 0.4% ⁇ Mg ⁇ 0.75%.
- Iron can be present in the range of up to 0.20% and preferably is kept to a maximum of 0.15%, more preferably to a maximum of 0.1%.
- a typical preferred iron level would be in the range of 0.03% to 0.08%.
- Silicon can be present in a range of up to 0.20% and preferably is kept to a maximum of 0.15%, more preferably to a maximum of 0.1%.
- a typical preferred silicon level would be as low as possible and would typically be for practical reasons in a range of 0.02% to 0.07%.
- Zirconium can be present in the alloy product according to the invention in an amount of up to 0.20%.
- a suitable Zr level is a range of 0.04% to 0.15%.
- a more preferred upper limit for the Zr level is 0.13%, and even more preferably not more than 0.11%.
- Manganese can be added alone or in combination with other dispersoid formers.
- a preferred maximum for the Mn level is 0.80% and a preferred minimum level is 0.15%.
- a preferred range for the Mn level is in the range of wherein 0.2% ⁇ Mn ⁇ 0.5%.
- a second drawback is that also in relation to the price of Ag, any scrap of the alloy should be carefully handled and recycled to reclaim the Ag.
- the alloy is free of Ag.
- the alloy is substantially free of Ag. With “substantially free” is meant that no purposeful addition of Ag was made to the chemical composition but that due to impurities and/or leaking from contact with manufacturing equipment, trace quantities of Ag may nevertheless find their way into the aluminium alloy product.
- the alloy has a composition consisting of, in wt.%:
- Si ⁇ 0.15% preferably ⁇ 0.1%, and the balance being aluminium and other impurities or incidental elements each ⁇ 0.05%, total ⁇ 0.15%, and is substantially free of Ag. More preferred narrower ranges for the various alloying elements are set out in this specification and claims.
- the aluminium alloy product according to the invention is in the T3x, T6x or T8x temper.
- the appropriate temper is selected to give the alloy product desired properties. Temper designations are according to the Aluminium Association.
- the product is preferably provided in the form of a sheet, plate, forging or extrusion for use in an aerospace structure.
- the aluminium alloy product according to the invention shows an excellent balance of properties for application as plate over a wide variety of thickness, preferably in the form of a plate having a thickness in the range of 0.7 to 80 mm. In the plate thickness range of 0.6 to 1.5 mm the aluminium alloy product is also of particular interest as automotive body sheet.
- the properties of the aluminium alloy product will be excellent for fuselage sheet and preferably the thickness is up to 25 mm.
- the properties are excellent for wing plates, e.g. lower wing plate, when tensile strength and fatigue properties are of great importance.
- the aluminium alloy products can also be used for stringers or to form an integral wing panel and stringer for use in an aircraft wing structure.
- aluminium alloy product according to the invention can also be used as tooling plate or mould plate, e.g. for moulds for manufacturing formed plastic products for example via die-casting or injection moulding.
- higher Fe and Si levels up to 0.4% for each of these elements are acceptable.
- the invention is also embodied in a method for the manufacture of an aluminium alloy product having high strength and high fracture toughness and a high resistance to intergranular corrosion comprising the steps of: a. casting an ingot having a composition according to the invention; b. homogenising and/or pre-heating the ingot after casting; c. hot working the ingot into a worked product by one of more methods selected from the group consisting of rolling, extruding and forging; d. optional reheating the worked product, and e. optional further hot working and/or cold working to a desired work piece form; f. solution heat treating said formed work piece at a temperature and time sufficient to place into solid solutions substantially all soluble constituents in the alloy; g.
- the method according to the invention yields aluminium alloy product having excellent resistance to intergranular corrosion and having high strength and excellent fatigue properties.
- the alloy products of the present invention are regularly prepared by melting and alloying an aluminium alloy product and may be direct chill (“D. C") cast into ingots or other suitable casting techniques. Homogenisation treatment is typically carried out in one or more steps, each step having a temperature preferably in the range of 46O 0 C to 535 0 C.
- the pre-heat temperature involves heating the ingot to the hot working temperature which is typically in a temperature range of 400 0 C to 48O 0 C.
- Working the alloy product can be done by one or more methods selected from the group consisting of rolling, extruding and forging. For the present alloy product hot rolling is preferred. Solution heat treatment is typically carried out in the same temperature range as used for homogenisation although somewhat shorter soaking times can be selected.
- artificial ageing preferably comprises an ageing step at a temperature in the range of 135 0 C to 21O 0 C, preferably for 5 to 20 hours.
- the natural ageing preferably comprises a step of ageing at room temperature during 1 to 10 days.
- the aluminium alloy product is aged to a temper selected from the group comprising T3, T351 , T39, T6, T651 , and T87.
- the aluminium alloy product is processed to fuselage sheet, preferably to fuselage sheet having a thickness of less then 30 mm.
- the aluminium alloy product is processed to lower wing plate.
- the aluminium alloy product is processed to upper wing plate.
- the aluminium alloy product is processed to an extruded product.
- the aluminium alloy product is processed to a forged product. In yet another embodiment the aluminium alloy product is processed to a thin plate having a thickness in the range of 15 to 40 mm.
- the aluminium alloy product is processed to a thick plate having a thickness up to 300 mm.
- Fig. 1 shows a Cr-Ti diagram setting out the Cr-Ti range for the invention together with narrower preferred ranges.
- Fig. 1 shows schematically the ranges for the Cr and Ti content for the alloy according to the invention. The broadest range is identified by a rectangular box with angular points A, B, C, D.
- Fig. 1 also shows schematically a preferred range of a balanced content of both Cr and Ti.
- the broadest range thereof is identified by a quadrangular box with angular points E, F, G, H.
- the point P indicates the Cr and Ti content of a sample of an alloy according to the invention which was used for testing (also referred to as Alloy 3 in the following examples).
- alloys 1 and 2 indicate the Cr and Ti content of two comparative alloys, also used for testing and also referred to as alloys 1 and 2. Alloys 1 and 2 fall outside the invention.
- Alloy 2 has, with the exception of the Cr and Ti content, the same chemical composition as Alloy 3 according to the invention.
- Alloy 1 has a chemical composition typical for a conventional AA2024 alloy.
- the alloys listed in Table 1 were processed as follows: Casting an ingot;
- Alloy 1 homogenising the ingot at a heating rate of 30 °C/h to 465 0 C, soaking at that temperature for 2 hours followed by further heating at a rate of 15 °C/h to 495 0 C and soaking at that temperature for 24 hours followed by air cooling to room temperature.
- Quenching the cold rolled plate by either direct water quenching or quenching in water after holding 10 sec. in still air.
- Stretching and ageing the cold rolled plate by either: o Stretching and natural ageing for 5 days at room temperature to T3x tempers (viz. T3, T351 , and T39); or o Stretching and artificial ageing for 12 hours at 175 0 C to T6x and T8x tempers (viz. T6, T651 , 187).
- Table 2 shows that a balanced addition of Cr and Ti according to an embodiment of the invention gives rise to outstanding intergranular corrosion free properties in the T3x tempers with a markedly lower pit depth compared with the other alloys.
- Figs. 2a, 2b, 3a and 3b show micrographs of a cross section of a sample of an alloy according to the invention in T3 temper and of a comparative alloy after corrosion testing.
- Fig. 2a shows a micrograph of a cross section of a sample of comparative alloy 1 (Ref. AA2024) in T3 temper after corrosion testing.
- the micrograph clearly shows pitting corrosion and intergranular corrosion to a depth of more than 150 ⁇ m.
- Fig. 2b shows a micrograph of a cross section of a sample of an alloy according to the invention (alloy 3) also in T3 temper after corrosion testing. The samples show only slight pitting, with a maximum depth of 60 ⁇ m and no intergranular corrosion.
- Figs. 3a, 3b show micrographs of a cross section of sample of an alloy according to the invention in T6 temper and of a comparative alloy after corrosion testing.
- Fig. 3a shows a micrograph of a cross section of a sample of a comparative alloy 1 (Ref. AA2024) in T6 temper after corrosion testing.
- the micrograph clearly shows local intergranular corrosion, extending to a depth of about 220 ⁇ m.
- Fig. 3b shows a micrograph of a cross section of a sample of an alloy according to the invention (alloy 3) also in T6 temper after corrosion testing.
- the sample exhibits pitting with only slight intergranular corrosion to a depth of less than 160 ⁇ m.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
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- Organic Chemistry (AREA)
- Extrusion Of Metal (AREA)
- Metal Rolling (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06818278.1A EP1945825B1 (en) | 2005-10-25 | 2006-10-24 | Al-cu-mg alloy suitable for aerospace application |
CA2627070A CA2627070C (en) | 2005-10-25 | 2006-10-24 | Al-cu-mg alloy suitable for aerospace application |
BRPI0617699-2A BRPI0617699A2 (en) | 2005-10-25 | 2006-10-24 | al-cu-mg alloy suitable for aerospace application |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05077448 | 2005-10-25 | ||
EP05077448.8 | 2005-10-25 |
Publications (1)
Publication Number | Publication Date |
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WO2007048565A1 true WO2007048565A1 (en) | 2007-05-03 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2006/010216 WO2007048565A1 (en) | 2005-10-25 | 2006-10-24 | Al-cu-mg alloy suitable for aerospace application |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1945825B1 (en) |
CN (1) | CN101297054A (en) |
BR (1) | BRPI0617699A2 (en) |
CA (1) | CA2627070C (en) |
RU (1) | RU2418876C2 (en) |
WO (1) | WO2007048565A1 (en) |
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CN103748246A (en) * | 2011-08-17 | 2014-04-23 | 奥托福克斯两合公司 | Heat-resistant Al-Cu-Mg-Ag alloy and process for producing a semifinished part or product composed of such an aluminium alloy |
WO2017215098A1 (en) * | 2016-06-16 | 2017-12-21 | 江苏大学 | Method for designing major components of high-hardenability and high-strength aluminium alloys |
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CN105002408A (en) * | 2015-07-12 | 2015-10-28 | 河北钢研德凯科技有限公司 | High-quality, high-strength cast aluminum alloy material and preparation method |
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CN115821131B (en) * | 2022-12-05 | 2024-05-14 | 山东南山铝业股份有限公司 | Low fatigue crack growth rate 2-series aluminum alloy section bar and manufacturing method thereof |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5652063A (en) * | 1995-03-22 | 1997-07-29 | Aluminum Company Of America | Sheet or plate product made from a substantially vanadium-free aluminum alloy |
US20010006082A1 (en) * | 1999-12-28 | 2001-07-05 | Timothy Warner | Aircraft structure element made of an Al-Cu-Mg alloy |
WO2004018723A1 (en) * | 2002-08-20 | 2004-03-04 | Corus Aluminium Walzprodukte Gmbh | HIGH DAMAGE TOLERANT Al-Cu ALLOY |
WO2004018722A1 (en) * | 2002-08-20 | 2004-03-04 | Corus Aluminium Walzprodukte Gmbh | Al-Cu-Mg-Si ALLOY AND METHOD FOR PRODUCING THE SAME |
WO2004111282A1 (en) * | 2003-06-06 | 2004-12-23 | Corus Aluminium Walzprodukte Gmbh | High-damage tolerant aluminium alloy product in particular for aerospace applications |
FR2858984A1 (en) * | 2003-08-19 | 2005-02-25 | Corus Aluminium Walzprod Gmbh | Aluminum-copper rolled product for aircraft fuselage sheet or aircraft lower-wing sheet, contains copper, magnesium, manganese, zirconium, chromium, silicon, iron, and aluminum and incidental elements and impurities |
-
2006
- 2006-10-24 CN CNA2006800395315A patent/CN101297054A/en active Pending
- 2006-10-24 BR BRPI0617699-2A patent/BRPI0617699A2/en not_active Application Discontinuation
- 2006-10-24 EP EP06818278.1A patent/EP1945825B1/en active Active
- 2006-10-24 WO PCT/EP2006/010216 patent/WO2007048565A1/en active Application Filing
- 2006-10-24 RU RU2008115928/02A patent/RU2418876C2/en active
- 2006-10-24 CA CA2627070A patent/CA2627070C/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5652063A (en) * | 1995-03-22 | 1997-07-29 | Aluminum Company Of America | Sheet or plate product made from a substantially vanadium-free aluminum alloy |
US20010006082A1 (en) * | 1999-12-28 | 2001-07-05 | Timothy Warner | Aircraft structure element made of an Al-Cu-Mg alloy |
WO2004018723A1 (en) * | 2002-08-20 | 2004-03-04 | Corus Aluminium Walzprodukte Gmbh | HIGH DAMAGE TOLERANT Al-Cu ALLOY |
WO2004018722A1 (en) * | 2002-08-20 | 2004-03-04 | Corus Aluminium Walzprodukte Gmbh | Al-Cu-Mg-Si ALLOY AND METHOD FOR PRODUCING THE SAME |
WO2004111282A1 (en) * | 2003-06-06 | 2004-12-23 | Corus Aluminium Walzprodukte Gmbh | High-damage tolerant aluminium alloy product in particular for aerospace applications |
FR2858984A1 (en) * | 2003-08-19 | 2005-02-25 | Corus Aluminium Walzprod Gmbh | Aluminum-copper rolled product for aircraft fuselage sheet or aircraft lower-wing sheet, contains copper, magnesium, manganese, zirconium, chromium, silicon, iron, and aluminum and incidental elements and impurities |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103748246A (en) * | 2011-08-17 | 2014-04-23 | 奥托福克斯两合公司 | Heat-resistant Al-Cu-Mg-Ag alloy and process for producing a semifinished part or product composed of such an aluminium alloy |
WO2017215098A1 (en) * | 2016-06-16 | 2017-12-21 | 江苏大学 | Method for designing major components of high-hardenability and high-strength aluminium alloys |
Also Published As
Publication number | Publication date |
---|---|
CN101297054A (en) | 2008-10-29 |
EP1945825B1 (en) | 2014-06-25 |
BRPI0617699A2 (en) | 2011-08-02 |
EP1945825A1 (en) | 2008-07-23 |
RU2008115928A (en) | 2009-10-27 |
CA2627070C (en) | 2014-07-29 |
RU2418876C2 (en) | 2011-05-20 |
CA2627070A1 (en) | 2007-05-03 |
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