WO2007044473A3 - High gain selective preconcentrators - Google Patents

High gain selective preconcentrators Download PDF

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Publication number
WO2007044473A3
WO2007044473A3 PCT/US2006/038998 US2006038998W WO2007044473A3 WO 2007044473 A3 WO2007044473 A3 WO 2007044473A3 US 2006038998 W US2006038998 W US 2006038998W WO 2007044473 A3 WO2007044473 A3 WO 2007044473A3
Authority
WO
WIPO (PCT)
Prior art keywords
mofs
micropreconcentrator
preconcentrators
sorbents
surface area
Prior art date
Application number
PCT/US2006/038998
Other languages
French (fr)
Other versions
WO2007044473A2 (en
Inventor
Richard I Masel
Zheng Ni
Mark A Shannon
Original Assignee
Univ Illinois
Richard I Masel
Zheng Ni
Mark A Shannon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Illinois, Richard I Masel, Zheng Ni, Mark A Shannon filed Critical Univ Illinois
Priority to EP06825517A priority Critical patent/EP1948353A2/en
Priority to CA002624959A priority patent/CA2624959A1/en
Publication of WO2007044473A2 publication Critical patent/WO2007044473A2/en
Publication of WO2007044473A3 publication Critical patent/WO2007044473A3/en

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/40—Concentrating samples
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/40—Concentrating samples
    • G01N1/405—Concentrating samples by adsorption or absorption
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N2030/022—Column chromatography characterised by the kind of separation mechanism
    • G01N2030/025—Gas chromatography
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/04—Preparation or injection of sample to be analysed
    • G01N30/06—Preparation
    • G01N30/08—Preparation using an enricher

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

Novel metal organic framework (MOF) molecules and methods of synthesizing them are described. MOFs are organometallic crystalline structures that have high sorption capacity due to high surface area, tailorable selectivity, an inert nature, and thermal stability at high temperatures. MOFs may be used as sorbents in preconcentrators for analytical devices to provide orders of magnitude of improved sensitivity in analyte detection. MOFs are also useful as sorbents in new compact and portable micropreconcentrator designs such as a modified purge and trap system and a multi-valve microelectromechanical system (MEMS) to achieve high gain in analyte detection. Further, MOFs may be used as coatings for novel microstructure arrays in micropreconcentrators where the microstructures are designed to increase the surface area to volume ratio inside the micropreconcentrator while minimizing the pressure drop across the micropreconcentrator.
PCT/US2006/038998 2005-10-06 2006-10-06 High gain selective preconcentrators WO2007044473A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06825517A EP1948353A2 (en) 2005-10-06 2006-10-06 High gain selective preconcentrators
CA002624959A CA2624959A1 (en) 2005-10-06 2006-10-06 High gain selective preconcentrators

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US72431305P 2005-10-06 2005-10-06
US60/724,313 2005-10-06
US79198806P 2006-04-14 2006-04-14
US60/791,988 2006-04-14

Publications (2)

Publication Number Publication Date
WO2007044473A2 WO2007044473A2 (en) 2007-04-19
WO2007044473A3 true WO2007044473A3 (en) 2007-08-09

Family

ID=37943381

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/038998 WO2007044473A2 (en) 2005-10-06 2006-10-06 High gain selective preconcentrators

Country Status (3)

Country Link
EP (1) EP1948353A2 (en)
CA (1) CA2624959A1 (en)
WO (1) WO2007044473A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9492785B2 (en) 2013-12-16 2016-11-15 Sabic Global Technologies B.V. UV and thermally treated polymeric membranes
US9522364B2 (en) 2013-12-16 2016-12-20 Sabic Global Technologies B.V. Treated mixed matrix polymeric membranes

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100680767B1 (en) 2006-02-07 2007-02-09 한국화학연구원 A preparation method of porous organic inorganic hybrid materials
KR100806586B1 (en) * 2006-03-10 2008-02-28 한국화학연구원 Absorbent for water adsorption and desorption
WO2009024171A1 (en) * 2007-08-22 2009-02-26 Sls Micro Technology Gmbh Miniaturized gas chromatography module with pre-stage miniaturized unit
US8178045B2 (en) 2007-12-17 2012-05-15 University Of Louisville Research Foundation, Inc. Interchangeable preconcentrator connector assembly
US8771613B2 (en) 2008-07-31 2014-07-08 University Of Louisville Research Foundation, Inc. Large volume analyte preconcentrator
US8448532B2 (en) 2009-03-18 2013-05-28 The United States Of America As Represented By The Secretary Of The Navy Actively cooled vapor preconcentrator
US8569691B2 (en) 2009-11-24 2013-10-29 University Of Louisville Research Foundation Preconcentrator for analysis instruments
ES2547729T3 (en) * 2009-11-30 2015-10-08 Basf Se Organometallic structure materials based on 2,5-furandicarboxylic acid or 2,5-thiophenedicarboxylic acid
CN102070660B (en) * 2010-12-17 2012-11-28 沈阳化工大学 Synthesis method of rare earth coordination polymer with calcium ion fluorescent probe function
FR2988620B1 (en) 2012-03-29 2014-04-25 Commissariat Energie Atomique DEVICE AND METHOD FOR EXTRACTING COMPOUNDS CONTAINED IN A LIQUID SAMPLE FOR ANALYSIS
CN105622675B (en) * 2014-10-28 2018-02-09 中国石油化工股份有限公司 A kind of preparation method of high activity metal organic framework material
CN106267300B (en) * 2015-05-14 2020-09-15 北京化工大学 Multifunctional material with sterilization and hemostasis performance and biochemical warfare agent protection performance and preparation method thereof
CN107556484B (en) * 2017-08-14 2020-11-10 常州大学 Zinc coordination polymer with glycolide ring-opening polymerization catalysis performance and preparation method thereof
CN109456495B (en) * 2018-12-10 2020-10-09 山东大学 Method for preparing zeolite imidazole ester framework material ZIF-8 nano hexapod by using seed growth synthesis
CN109593209B (en) * 2018-12-10 2020-10-09 山东大学 Method for preparing zeolite imidazole ester framework material ZIF-8 nano octapods through seed growth synthesis
CN110736823A (en) * 2019-10-24 2020-01-31 常州大学 micro-nano micro-fluidic preconcentrator device for oil gas leakage detection
CN111533921A (en) * 2020-05-28 2020-08-14 南京工业大学 Preparation method of ZIF-8 nano platelet and ultrathin film thereof
CN111740056B (en) * 2020-06-28 2021-10-26 上海交通大学 Adsorption type battery thermal management system based on metal organic framework material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6527835B1 (en) * 2001-12-21 2003-03-04 Sandia Corporation Chemical preconcentrator with integral thermal flow sensor
US20030222023A1 (en) * 2002-05-30 2003-12-04 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks
US6719828B1 (en) * 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
US6930193B2 (en) * 2001-04-30 2005-08-16 The Regents Of The University Of Michigan Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
US20060099398A1 (en) * 2004-11-09 2006-05-11 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6719828B1 (en) * 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
US6930193B2 (en) * 2001-04-30 2005-08-16 The Regents Of The University Of Michigan Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage
US6527835B1 (en) * 2001-12-21 2003-03-04 Sandia Corporation Chemical preconcentrator with integral thermal flow sensor
US20030222023A1 (en) * 2002-05-30 2003-12-04 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks
US20060099398A1 (en) * 2004-11-09 2006-05-11 Basf Aktiengesellschaft Shaped bodies containing metal-organic frameworks

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9492785B2 (en) 2013-12-16 2016-11-15 Sabic Global Technologies B.V. UV and thermally treated polymeric membranes
US9522364B2 (en) 2013-12-16 2016-12-20 Sabic Global Technologies B.V. Treated mixed matrix polymeric membranes

Also Published As

Publication number Publication date
EP1948353A2 (en) 2008-07-30
CA2624959A1 (en) 2007-04-19
WO2007044473A2 (en) 2007-04-19

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