WO2007021554A3 - A desulfurization system and method for desulfurizing a fuel stream - Google Patents
A desulfurization system and method for desulfurizing a fuel stream Download PDFInfo
- Publication number
- WO2007021554A3 WO2007021554A3 PCT/US2006/030125 US2006030125W WO2007021554A3 WO 2007021554 A3 WO2007021554 A3 WO 2007021554A3 US 2006030125 W US2006030125 W US 2006030125W WO 2007021554 A3 WO2007021554 A3 WO 2007021554A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fuel stream
- desulfurizing
- desulfurization system
- hydrocarbon fuel
- sulfur adsorbent
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0222—Compounds of Mn, Re
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
- C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/08—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one sorption step
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
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- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1124—Metal oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
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- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/308—Carbonoxysulfide COS
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
Abstract
A method for producing a substantially desulfurized hydrocarbon fuel stream at temperatures less than 1000C including providing a nondesulfurized fuel cell hydrocarbon fuel stream and passing the fuel stream through a sequential sulfur adsorbent system containing calcium exchanged zeolite, hydrated alumina and a selective sulfur adsorbent placed in sequence to produce a substantially desulfurized hydrocarbon fuel stream.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/207,154 US20060043001A1 (en) | 2004-09-01 | 2005-08-18 | Desulfurization system and method for desulfurizing afuel stream |
US11/207,154 | 2005-08-18 | ||
US11/484,224 US20060283780A1 (en) | 2004-09-01 | 2006-07-11 | Desulfurization system and method for desulfurizing a fuel stream |
US11/484,224 | 2006-07-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2007021554A2 WO2007021554A2 (en) | 2007-02-22 |
WO2007021554A3 true WO2007021554A3 (en) | 2007-05-03 |
Family
ID=37605705
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/030125 WO2007021554A2 (en) | 2005-08-18 | 2006-08-02 | A desulfurization system and method for desulfurizing a fuel stream |
Country Status (2)
Country | Link |
---|---|
US (1) | US20060283780A1 (en) |
WO (1) | WO2007021554A2 (en) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8323603B2 (en) | 2004-09-01 | 2012-12-04 | Sud-Chemie Inc. | Desulfurization system and method for desulfurizing a fuel stream |
US7780846B2 (en) * | 2004-09-01 | 2010-08-24 | Sud-Chemie Inc. | Sulfur adsorbent, desulfurization system and method for desulfurizing |
JP4907391B2 (en) * | 2007-03-07 | 2012-03-28 | Jx日鉱日石エネルギー株式会社 | Desulfurization method for hydrocarbon fuel |
KR100884534B1 (en) * | 2007-04-30 | 2009-02-18 | 삼성에스디아이 주식회사 | Desulfurizing device for fuel cell, and fuel cell system comprising the same |
CN101434862B (en) * | 2007-11-15 | 2013-06-05 | 中国石油化工股份有限公司 | Method for reducing sulfide in light hydrocarbon oil |
CN101433817B (en) * | 2007-11-15 | 2012-05-09 | 中国石油化工股份有限公司 | Desulphurization sorbent |
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EP2679656B1 (en) * | 2008-04-17 | 2016-12-14 | Univation Technologies, LLC | Method for removing impurities from a feed liquid |
DK200801093A (en) * | 2008-08-13 | 2010-02-14 | Topsoe Haldor As | Process and system for removing impurities from a gas stream |
AU2011258422C1 (en) | 2010-05-24 | 2017-03-30 | Lummus Technology Llc | Nanowire catalysts |
WO2012162526A2 (en) | 2011-05-24 | 2012-11-29 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
MX358123B (en) | 2011-10-24 | 2018-08-06 | Aditya Birla Nuvo Ltd | An improved process for the production of carbon black. |
EP2785458A2 (en) | 2011-11-29 | 2014-10-08 | Siluria Technologies, Inc. | Nanowire catalysts and methods for their use and preparation |
AU2013207783B2 (en) | 2012-01-13 | 2017-07-13 | Lummus Technology Llc | Process for providing C2 hydrocarbons via oxidative coupling of methane and for separating hydrocarbon compounds |
US9446397B2 (en) | 2012-02-03 | 2016-09-20 | Siluria Technologies, Inc. | Method for isolation of nanomaterials |
US9410042B2 (en) | 2012-03-30 | 2016-08-09 | Aditya Birla Science And Technology Company Ltd. | Process for obtaining carbon black powder with reduced sulfur content |
US20140121433A1 (en) | 2012-05-24 | 2014-05-01 | Siluria Technologies, Inc. | Catalytic forms and formulations |
AU2013266250B2 (en) | 2012-05-24 | 2017-07-06 | Lummus Technology Llc | Oxidative coupling of methane systems and methods |
US9969660B2 (en) | 2012-07-09 | 2018-05-15 | Siluria Technologies, Inc. | Natural gas processing and systems |
US9370757B2 (en) | 2012-08-21 | 2016-06-21 | Uop Llc | Pyrolytic reactor |
US8927769B2 (en) | 2012-08-21 | 2015-01-06 | Uop Llc | Production of acrylic acid from a methane conversion process |
US9656229B2 (en) | 2012-08-21 | 2017-05-23 | Uop Llc | Methane conversion apparatus and process using a supersonic flow reactor |
US9205398B2 (en) | 2012-08-21 | 2015-12-08 | Uop Llc | Production of butanediol from a methane conversion process |
US9707530B2 (en) | 2012-08-21 | 2017-07-18 | Uop Llc | Methane conversion apparatus and process using a supersonic flow reactor |
US8937186B2 (en) | 2012-08-21 | 2015-01-20 | Uop Llc | Acids removal and methane conversion process using a supersonic flow reactor |
US20140058089A1 (en) * | 2012-08-21 | 2014-02-27 | Uop Llc | Sulfur removal and methane conversion process using a supersonic flow reactor |
US9689615B2 (en) | 2012-08-21 | 2017-06-27 | Uop Llc | Steady state high temperature reactor |
US8933275B2 (en) | 2012-08-21 | 2015-01-13 | Uop Llc | Production of oxygenates from a methane conversion process |
US9434663B2 (en) | 2012-08-21 | 2016-09-06 | Uop Llc | Glycols removal and methane conversion process using a supersonic flow reactor |
US9023255B2 (en) | 2012-08-21 | 2015-05-05 | Uop Llc | Production of nitrogen compounds from a methane conversion process |
US9308513B2 (en) | 2012-08-21 | 2016-04-12 | Uop Llc | Production of vinyl chloride from a methane conversion process |
US9327265B2 (en) | 2012-08-21 | 2016-05-03 | Uop Llc | Production of aromatics from a methane conversion process |
CA2893948C (en) | 2012-12-07 | 2022-12-06 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to ethylene and conversion of ethylene to higher hydrocarbon products |
US20160107143A1 (en) | 2013-03-15 | 2016-04-21 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
US10047020B2 (en) | 2013-11-27 | 2018-08-14 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
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US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
US9956544B2 (en) | 2014-05-02 | 2018-05-01 | Siluria Technologies, Inc. | Heterogeneous catalysts |
EP3194070B1 (en) | 2014-09-17 | 2020-12-23 | Lummus Technology LLC | Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ethane |
JP6607387B2 (en) * | 2015-02-02 | 2019-11-20 | パナソニックIpマネジメント株式会社 | Desulfurization method and desulfurizer |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
US9687779B2 (en) * | 2015-07-30 | 2017-06-27 | Baker Hughes Incorporated | Control of carbonyl sulfide with sodium borohydride in caustic towers for petroleum/petrochemical processes |
EP3786138A1 (en) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative coupling of methane |
CA3019396A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
EP3554672A4 (en) | 2016-12-19 | 2020-08-12 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
CN106693632B (en) * | 2017-01-13 | 2020-07-03 | 上海化工研究院有限公司 | Zinc oxide-based normal-temperature deep desulfurizing agent and preparation method and application thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098684A (en) * | 1976-11-29 | 1978-07-04 | Gulf Research & Development Company | Purification of liquid n-paraffins containing carbonyl sulfide and other sulfur compounds |
US4795545A (en) * | 1987-09-17 | 1989-01-03 | Uop Inc. | Process for pretreatment of light hydrocarbons to remove sulfur, water, and oxygen-containing compounds |
US5106484A (en) * | 1990-12-19 | 1992-04-21 | Exxon Chemical Patents Inc. | Purifying feed for reforming over zeolite catalysts |
WO2004108273A1 (en) * | 2003-06-06 | 2004-12-16 | Zeochem Ag | Method for sulfur compounds removal from contaminated gas and liquid streams |
WO2006028686A1 (en) * | 2004-09-01 | 2006-03-16 | Sud-Chemie Inc. | A desulfurization system and method for desulfurizing a fuel stream |
Family Cites Families (80)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882243A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US2882244A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US2927063A (en) * | 1957-10-28 | 1960-03-01 | Consolidation Coal Co | Process for maintaining high level of activity for supported manganese oxide acceptors for hydrogen sulfide |
US2950229A (en) * | 1957-10-28 | 1960-08-23 | Consolidation Coal Co | Method for maintaining high level of activity for supported manganese oxide acceptors for hydrogen sulfide |
US2950231A (en) * | 1958-02-13 | 1960-08-23 | Consolidation Coal Co | Manganese ore acceptors for hydrogen sulfide |
US3063936A (en) * | 1958-08-22 | 1962-11-13 | Ici Ltd | Desulfurization of hydrocarbon oils |
NL258555A (en) * | 1959-11-30 | |||
US3058800A (en) * | 1960-04-28 | 1962-10-16 | Dow Chemical Co | Catalytic hydrolysis of carbonyl sulfide |
US3101303A (en) * | 1960-04-29 | 1963-08-20 | Consolidation Coal Co | Process for regenerating manganese oxide acceptors for hydrogen sulfide |
BE759979A (en) * | 1965-02-10 | 1971-06-07 | Grillo Werke Ag | PROCESS FOR ELIMINATION OF SULFUR IN RESIDUAL GASES |
US3723598A (en) * | 1970-11-05 | 1973-03-27 | Kennecott Copper Corp | Dry cyclic process utilizing a manganous oxide absorbent for removal of dilute sulfur values from gas streams |
US3760029A (en) * | 1971-05-06 | 1973-09-18 | Chevron Res | Dimethylsulfide removal in the isomerization of normal paraffins |
GB1404855A (en) * | 1971-07-28 | 1975-09-03 | Mitsui Mining & Smelting Co | Catalytic purification of exhaust gases |
US3890120A (en) * | 1972-04-18 | 1975-06-17 | Aquitaine Petrole | Process to recover sulphur from the sulphur compounds contained in residual gases |
US4098694A (en) * | 1972-11-13 | 1978-07-04 | United States Steel Corporation | Methods and compositions for dispersing oil films |
US3816975A (en) * | 1972-11-14 | 1974-06-18 | Union Carbide Corp | Purification of hydrocarbon feedstocks |
US4059418A (en) * | 1973-08-23 | 1977-11-22 | Exxon Research & Engineering Co. | Flue gas desulfurization sorbent and process |
US4329160A (en) * | 1974-07-08 | 1982-05-11 | Union Carbide Corporation | Suppression of COS formation in molecular sieve purification of hydrocarbon gas streams |
US4177203A (en) * | 1976-02-12 | 1979-12-04 | Schering Aktiengesellschaft | Process for the production of hydrocarbons and oxygen-containing compounds and catalysts therefor |
US4180549A (en) * | 1976-08-27 | 1979-12-25 | United States Steel Corporation | Desulfurization of hot reducing gas |
US4113604A (en) * | 1977-05-23 | 1978-09-12 | Uop Inc. | Process for treating a sour petroleum distillate with anion exchange resin and with metal phthalocyanine catalyst |
US4225417A (en) * | 1979-02-05 | 1980-09-30 | Atlantic Richfield Company | Catalytic reforming process with sulfur removal |
US4233276A (en) * | 1979-03-30 | 1980-11-11 | Standard Oil Company (Indiana) | Process for the desulfurization of waste gases |
US4358297A (en) * | 1980-01-02 | 1982-11-09 | Exxon Research And Engineering Company | Removal of sulfur from process streams |
US4283374A (en) * | 1980-02-21 | 1981-08-11 | Erickson Donald C | Regenerable manganese oxide hot gas desulfurization process |
DE3029187C2 (en) * | 1980-08-01 | 1986-04-17 | Bergwerksverband Gmbh, 4300 Essen | Process for removing hydrogen sulfide from oxygen-free or oxygen-containing gas mixtures |
US4486298A (en) * | 1981-05-28 | 1984-12-04 | Mobil Oil Corporation | Adsorptive demetalation of heavy petroleum residua |
NL8105728A (en) * | 1981-10-30 | 1983-05-16 | Tno | PROCESS FOR THE REMOVAL OF HYDROGEN SULFIDE FROM PROCESS GASES USING FIXED ACCEPTORS, PROCESS FOR CYCLICALLY REGENERATING THE ACCEPTORS USED AT HIGH TEMPERATURE, AND METHOD FOR PREPARING THESE PROCESS. |
US4540842A (en) * | 1984-01-16 | 1985-09-10 | El Paso Products Company | Removal of sulfur compounds from pentane |
US4557823A (en) * | 1984-06-22 | 1985-12-10 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
US4729889A (en) * | 1985-03-29 | 1988-03-08 | California Institute Of Technology | High temperature regenerative H2 S sorbents |
US4613724A (en) * | 1985-07-09 | 1986-09-23 | Labofina, S.A. | Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks |
US4835338A (en) * | 1987-08-31 | 1989-05-30 | Aluminum Company Of America | Process for removal of carbonyl sulfide from organic liquid by adsorption using alumina adsorbent capable of regeneration |
US5114689A (en) * | 1987-10-05 | 1992-05-19 | Uop | Integrated process for the removal of sulfur compounds from fluid streams |
US5130115A (en) * | 1988-01-22 | 1992-07-14 | Nippon Oil Co., Ltd. | Process for hydrogen production from kerosene |
US5080867A (en) * | 1988-04-07 | 1992-01-14 | Liquid Air Corporation | Portable carbonyl sulfide analyzer |
DE3825169A1 (en) * | 1988-07-23 | 1990-02-01 | Huels Chemische Werke Ag | METHOD FOR FINE DESULFURATION OF HYDROCARBONS |
US5026536A (en) * | 1988-12-20 | 1991-06-25 | Nippon Oil Co., Ltd. | Hydrogen production from hydrocarbon |
US5302470A (en) * | 1989-05-16 | 1994-04-12 | Osaka Gas Co., Ltd. | Fuel cell power generation system |
US5268091A (en) * | 1989-08-08 | 1993-12-07 | Institut Francais De Petrole | Method for removing arsenic and phosphorus contained in liquid hydrocarbon cuts, nickel based retaining material |
US4992620A (en) * | 1989-11-21 | 1991-02-12 | Phillips Petroleum Company | Removal of trialkyl arsines from fluids |
JPH03201370A (en) * | 1989-12-27 | 1991-09-03 | Sekiyu Sangyo Katsuseika Center | Method of improving process of fuel cell power generation |
US5057473A (en) * | 1990-04-12 | 1991-10-15 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Regenerative Cu La zeolite supported desulfurizing sorbents |
US5157201A (en) * | 1990-06-22 | 1992-10-20 | Exxon Chemical Patents Inc. | Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent |
US5281445A (en) * | 1990-07-30 | 1994-01-25 | Phillips Petroleum Company | Coating of components of sulfur absorbants |
US5085844A (en) * | 1990-11-28 | 1992-02-04 | Phillips Petroleum Company | Sorption of trialkyl arsines |
US5348928A (en) * | 1991-04-22 | 1994-09-20 | Amoco Corporation | Selective hydrotreating catalyst |
GB9120973D0 (en) * | 1991-10-03 | 1991-11-13 | Dytech Corp Ltd | Desulphurisation treatment |
US5322615A (en) * | 1991-12-10 | 1994-06-21 | Chevron Research And Technology Company | Method for removing sulfur to ultra low levels for protection of reforming catalysts |
US5800798A (en) * | 1992-04-06 | 1998-09-01 | Nippon Oil Co., Ltd | Process for producing fuel gas for fuel cell |
FR2690923B1 (en) * | 1992-05-11 | 1994-07-22 | Inst Francais Du Petrole | PROCESS FOR CAPTURING MERCURY AND ARSENIC IN A CUP OF HYDROCARBON. |
US5426083A (en) * | 1994-06-01 | 1995-06-20 | Amoco Corporation | Absorbent and process for removing sulfur oxides from a gaseous mixture |
US5648312A (en) * | 1994-12-29 | 1997-07-15 | Intevep, S.A. | Hydrogenation catalyst with improved attrition resistance and heat dissipation |
US5955393A (en) * | 1995-04-21 | 1999-09-21 | Project Earth Industries, Inc. | Enhanced adsorbent and room temperature catalyst particle and method of making therefor |
US5700439A (en) * | 1995-06-08 | 1997-12-23 | Chemetals Technology Incorporated | Method of removing hydrogen sulfide from hot gas mixtures |
JP3378416B2 (en) * | 1995-08-25 | 2003-02-17 | 新日本石油株式会社 | Desulfurization method of catalytic cracking gasoline |
US5769909A (en) * | 1996-05-31 | 1998-06-23 | International Fuel Cells Corp. | Method and apparatus for desulfurizing fuel gas |
CA2259396C (en) * | 1996-07-02 | 2003-08-19 | Matsushita Electric Works, Ltd. | Fuel-cell power generating system |
US5686196A (en) * | 1996-10-09 | 1997-11-11 | Westinghouse Electric Corporation | System for operating solid oxide fuel cell generator on diesel fuel |
US5928980A (en) * | 1997-02-06 | 1999-07-27 | Research Triangle Institute | Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts |
US5990372A (en) * | 1998-01-12 | 1999-11-23 | United Catalysts Inc. | Adsorbent for the removal of trace quantities from a hydrocarbon stream and process for its use |
US6579347B1 (en) * | 1998-04-28 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Method for removing sulfur compound present in city gas |
US6156084A (en) * | 1998-06-24 | 2000-12-05 | International Fuel Cells, Llc | System for desulfurizing a fuel for use in a fuel cell power plant |
US6083379A (en) * | 1998-07-14 | 2000-07-04 | Phillips Petroleum Company | Process for desulfurizing and aromatizing hydrocarbons |
DE19845397C2 (en) * | 1998-10-02 | 2000-09-14 | Daimler Chrysler Ag | Method for desulfurizing a motor fuel on board a motor vehicle |
US6162267A (en) * | 1998-12-11 | 2000-12-19 | Uop Llc | Process for the generation of pure hydrogen for use with fuel cells |
US6210821B1 (en) * | 1998-12-28 | 2001-04-03 | International Fuel Cells Co, Llc | System for implementing operation and start-up of a vehicle which is powered by electricity from a fuel cell power plant |
US6190623B1 (en) * | 1999-06-18 | 2001-02-20 | Uop Llc | Apparatus for providing a pure hydrogen stream for use with fuel cells |
US6383981B1 (en) * | 1999-07-20 | 2002-05-07 | Süd-Chemie Inc. | Adsorbent for the removal of trace quantities from a hydrocarbon stream and process for its use |
US6274533B1 (en) * | 1999-12-14 | 2001-08-14 | Phillips Petroleum Company | Desulfurization process and novel bimetallic sorbent systems for same |
US6875410B2 (en) * | 2000-02-01 | 2005-04-05 | Tokyo Gas Co., Ltd. | Adsorbent for removing sulfur compounds from fuel gases and removal method |
US6683024B1 (en) * | 2000-03-15 | 2004-01-27 | Conocophillips Company | Desulfurization and novel sorbents for same |
WO2002022763A1 (en) * | 2000-09-11 | 2002-03-21 | Research Triangle Institute | Process for desulfurizing hydrocarbon fuels and fuel components |
US20020159939A1 (en) * | 2001-04-27 | 2002-10-31 | Plug Power Inc. | Gas purification system |
US6563940B2 (en) * | 2001-05-16 | 2003-05-13 | New Jersey Institute Of Technology | Unauthorized user prevention device and method |
US7094333B2 (en) * | 2001-09-04 | 2006-08-22 | The Regents Of The University Of Michigan | Selective sorbents for purification of hydrocarbons |
US7105140B2 (en) * | 2002-03-04 | 2006-09-12 | Conocophillips Company | Desulfurization compositions |
US20040063576A1 (en) * | 2002-09-30 | 2004-04-01 | Sud-Chemie Inc. | Catalyst adsorbent for removal of sulfur compounds for fuel cells |
CA2511998C (en) * | 2002-12-26 | 2011-11-22 | Idemitsu Kosan Co., Ltd. | Method for removing sulfur compound in hydrocarbon-containing gas |
US7063732B2 (en) * | 2003-07-28 | 2006-06-20 | Fuelcell Energy, Inc. | High-capacity sulfur adsorbent bed and gas desulfurization method |
-
2006
- 2006-07-11 US US11/484,224 patent/US20060283780A1/en not_active Abandoned
- 2006-08-02 WO PCT/US2006/030125 patent/WO2007021554A2/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098684A (en) * | 1976-11-29 | 1978-07-04 | Gulf Research & Development Company | Purification of liquid n-paraffins containing carbonyl sulfide and other sulfur compounds |
US4795545A (en) * | 1987-09-17 | 1989-01-03 | Uop Inc. | Process for pretreatment of light hydrocarbons to remove sulfur, water, and oxygen-containing compounds |
US5106484A (en) * | 1990-12-19 | 1992-04-21 | Exxon Chemical Patents Inc. | Purifying feed for reforming over zeolite catalysts |
WO2004108273A1 (en) * | 2003-06-06 | 2004-12-16 | Zeochem Ag | Method for sulfur compounds removal from contaminated gas and liquid streams |
WO2006028686A1 (en) * | 2004-09-01 | 2006-03-16 | Sud-Chemie Inc. | A desulfurization system and method for desulfurizing a fuel stream |
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US20060283780A1 (en) | 2006-12-21 |
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