WO2007012756A3 - Traitement du gaz résiduaire d'un procédé fischer-tropsch - Google Patents

Traitement du gaz résiduaire d'un procédé fischer-tropsch Download PDF

Info

Publication number
WO2007012756A3
WO2007012756A3 PCT/FR2006/001824 FR2006001824W WO2007012756A3 WO 2007012756 A3 WO2007012756 A3 WO 2007012756A3 FR 2006001824 W FR2006001824 W FR 2006001824W WO 2007012756 A3 WO2007012756 A3 WO 2007012756A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
tropsch process
residue gas
major part
hydrocarbon
Prior art date
Application number
PCT/FR2006/001824
Other languages
English (en)
Other versions
WO2007012756A2 (fr
Inventor
Martine Schneider
Souza Guillaume De
Paul Wentink
Original Assignee
Air Liquide
Martine Schneider
Souza Guillaume De
Paul Wentink
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide, Martine Schneider, Souza Guillaume De, Paul Wentink filed Critical Air Liquide
Priority to EP06794222A priority Critical patent/EP1913119A2/fr
Priority to AU2006273920A priority patent/AU2006273920A1/en
Priority to US11/996,847 priority patent/US20080300326A1/en
Publication of WO2007012756A2 publication Critical patent/WO2007012756A2/fr
Publication of WO2007012756A3 publication Critical patent/WO2007012756A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/18—Noble gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/41—Further details for adsorption processes and devices using plural beds of the same adsorbent in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

L'invention concerne un procédé de conversion de gaz hydrocarbonés en liquides hydrocarbonés dans lequel le procédé Fischer-Tropsch est mis en oeuvre, ledit procédé Fischer-Tropsch produisant des liquides hydrocarbonés et un gaz résiduaire comprenant au moins de l'hydrogène, du monoxyde de carbone, du dioxyde de carbone et des hydrocarbures présentant un nombre de carbone d'au plus 6, dans lequel le gaz résiduaire est soumis à un procédé de séparation produisant : - au moins un flux gazeux comprenant majoritairement de l'hydrogène, - au moins un flux comprenant majoritairement du méthane, - au moins un flux gazeux comprenant majoritairement des inertes (dioxyde de carbone, azote, argon) et des hydrocarbures présentant un nombre de carbone d'au moins 2.
PCT/FR2006/001824 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch WO2007012756A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP06794222A EP1913119A2 (fr) 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch
AU2006273920A AU2006273920A1 (en) 2005-07-28 2006-07-26 Processing residue gas of a fischer-tropsch process
US11/996,847 US20080300326A1 (en) 2005-07-28 2006-07-26 Processing Residue Gas of a Fischer-Tropsch Process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0552354 2005-07-28
FR0552354A FR2889199A1 (fr) 2005-07-28 2005-07-28 Traitement de gaz residuaire d'un procede fischer-tropsch

Publications (2)

Publication Number Publication Date
WO2007012756A2 WO2007012756A2 (fr) 2007-02-01
WO2007012756A3 true WO2007012756A3 (fr) 2007-03-22

Family

ID=36273391

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2006/001824 WO2007012756A2 (fr) 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch

Country Status (6)

Country Link
US (1) US20080300326A1 (fr)
EP (1) EP1913119A2 (fr)
AU (1) AU2006273920A1 (fr)
FR (1) FR2889199A1 (fr)
RU (1) RU2008107589A (fr)
WO (1) WO2007012756A2 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9698439B2 (en) 2008-02-19 2017-07-04 Proton Power, Inc. Cellulosic biomass processing for hydrogen extraction
US8303676B1 (en) 2008-02-19 2012-11-06 Proton Power, Inc. Conversion of C-O-H compounds into hydrogen for power or heat generation
US7988765B2 (en) * 2008-02-20 2011-08-02 Gtlpetrol Llc Systems and processes for processing hydrogen and carbon monoxide
EP2771093B1 (fr) 2011-10-25 2015-12-09 Shell Internationale Research Maatschappij B.V. Procédé pour traiter un gaz de dégagement de fischer-tropsch
MY186999A (en) 2011-10-25 2021-08-26 Shell Int Research Method for processing fischer-tropsch off-gas
US10005961B2 (en) 2012-08-28 2018-06-26 Proton Power, Inc. Methods, systems, and devices for continuous liquid fuel production from biomass
AU2013369184B2 (en) 2012-12-31 2016-06-23 Shell Internationale Research Maatschappij B.V. Method for processing Fischer-Tropsch off-gas
WO2014102395A1 (fr) 2012-12-31 2014-07-03 Shell Internationale Research Maatschappij B.V. Procédé pour traiter un effluent gazeux du procédé fischer-tropsch
US9382482B2 (en) 2014-03-05 2016-07-05 Proton Power, Inc. Continuous liquid fuel production methods, systems, and devices
GB2527372A (en) * 2014-06-21 2015-12-23 Inventure Fuels Ltd Synthesising hydrocarbons
CN106660790A (zh) 2014-06-30 2017-05-10 国际壳牌研究有限公司 处理气体混合物的方法
CN107257775A (zh) 2015-02-10 2017-10-17 国际壳牌研究有限公司 用于获得富氢气的方法和系统
PE20171551A1 (es) 2015-03-03 2017-10-27 Shell Int Research Metodo para el tratamiento de gas residual y la produccion de hidrogeno
US9890332B2 (en) 2015-03-08 2018-02-13 Proton Power, Inc. Biochar products and production
DE102015004213A1 (de) * 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren und eine Anlage zur Erzeugung von Synthesegas
US10351780B2 (en) * 2015-07-28 2019-07-16 Shell Oil Company Process for preparing a paraffin product

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4259091A (en) * 1978-09-16 1981-03-31 Linde Aktiengesellschaft Adiabatic adsorption method for gas purification or separation
WO2002038699A1 (fr) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production de produits à base d'hydrocarbures liquides
WO2004092306A1 (fr) * 2003-04-15 2004-10-28 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede de production de liquides hydrocarbones mettant en oeuvre un procede fischer-tropsch

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4259091A (en) * 1978-09-16 1981-03-31 Linde Aktiengesellschaft Adiabatic adsorption method for gas purification or separation
WO2002038699A1 (fr) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production de produits à base d'hydrocarbures liquides
WO2004092306A1 (fr) * 2003-04-15 2004-10-28 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede de production de liquides hydrocarbones mettant en oeuvre un procede fischer-tropsch

Also Published As

Publication number Publication date
AU2006273920A1 (en) 2007-02-01
EP1913119A2 (fr) 2008-04-23
WO2007012756A2 (fr) 2007-02-01
US20080300326A1 (en) 2008-12-04
RU2008107589A (ru) 2009-09-10
FR2889199A1 (fr) 2007-02-02

Similar Documents

Publication Publication Date Title
WO2007012756A3 (fr) Traitement du gaz résiduaire d'un procédé fischer-tropsch
GB2446755A (en) Production of hydrocarbons from natural gas
WO2006134471A3 (fr) Procede de preparation et de conversion de gaz de synthese
WO2007000545A3 (fr) Procede pour la production simultanee d'hydrogene et de monoxyde de carbone
CA2930263C (fr) Procede de fabrication de gaz ammoniac et de co2 pour une synthese d'uree
WO2006123158A3 (fr) Procede permettant la conversion de gaz de synthese en composes oxygenes
MY144780A (en) Improvements relating to coal to liquid processes
WO2010004425A3 (fr) Elimination du carbone d’un procédé de récupération thermique intégré
GB0605232D0 (en) Oxygen removal
WO2010033846A3 (fr) Catalyseur de méthanisation de charbon de bois et son utilisation dans des procédés de gazéification
SG144835A1 (en) Purification of carbon dioxide
WO2008067360A3 (fr) Systèmes et procédés pour produire de l'hydrogène et du dioxyde de carbone
WO2001010979B1 (fr) Processus integre permettant de convertir un gaz hydrocarbone en liquides
GB201115929D0 (en) Improved hydrocarbon production process
WO2003087264A3 (fr) Reduction des emissions de dioxyde de carbone emanant d'un equipement gtl fischer-tropsch
EA200800325A1 (ru) Извлечение моноксида углерода и водорода из углеводородных потоков
US20080249196A1 (en) Method for Converting Hydrocarbon-Containing Gases Into Liquids Using a Syngas with Low H2/Co Ratio
WO2008113766A3 (fr) Procédé de préparation d'un hydrocarbure
EA200702047A1 (ru) Способ получения синтез-газа
WO2008113494A3 (fr) Procédé et dispositif d'extraction de produits gazeux et de méthane liquide à partir de gaz de synthèse
WO2008093012A3 (fr) Procede de production d'un gaz de synthese purifie a partir de biomasse incluant une etape de purification en amont de l'oxydation partielle
WO2006135378A3 (fr) Procede et dispositif pour la production d'hydrogene a partir de nanotubes en carbone satures de gaz a effet de serre et synthese correspondante de nanostructures en carbone
DK1348685T3 (da) Fremgangsmåde til fremstilling af carbonmonoxid og methanol
MY139077A (en) Processing natural gas to form longer-chain hydrocarbons.
WO2011138809A8 (fr) Procédé de production de gaz de synthèse, syngas, et d'hydrogène à partir de fragments comprenant des hydrocarbures liquides, gazeux, et/ou des composés oxygénés, dérivant également de biomasses, par le biais d'un réacteur à membrane non intégrée

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 2006794222

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: DZP2007000839

Country of ref document: DZ

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2006273920

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2008107589

Country of ref document: RU

ENP Entry into the national phase

Ref document number: 2006273920

Country of ref document: AU

Date of ref document: 20060726

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2006273920

Country of ref document: AU

WWP Wipo information: published in national office

Ref document number: 2006794222

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 11996847

Country of ref document: US