WO2007011890A2 - Conditioning system for activated sludge wastewater treatment processes - Google Patents

Conditioning system for activated sludge wastewater treatment processes Download PDF

Info

Publication number
WO2007011890A2
WO2007011890A2 PCT/US2006/027736 US2006027736W WO2007011890A2 WO 2007011890 A2 WO2007011890 A2 WO 2007011890A2 US 2006027736 W US2006027736 W US 2006027736W WO 2007011890 A2 WO2007011890 A2 WO 2007011890A2
Authority
WO
WIPO (PCT)
Prior art keywords
activated sludge
stream
tank
sludge stream
bioreactor
Prior art date
Application number
PCT/US2006/027736
Other languages
French (fr)
Other versions
WO2007011890A3 (en
Inventor
Marc Eric Roehl
Original Assignee
Siemens Water Technologies Corp.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Water Technologies Corp. filed Critical Siemens Water Technologies Corp.
Priority to US12/161,846 priority Critical patent/US7993522B2/en
Priority to PCT/US2007/001815 priority patent/WO2007089481A2/en
Publication of WO2007011890A2 publication Critical patent/WO2007011890A2/en
Publication of WO2007011890A3 publication Critical patent/WO2007011890A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1215Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1221Particular type of activated sludge processes comprising treatment of the recirculated sludge
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • the present invention relates to the treatment of wastewaters comprising biochemical oxygen demand (BOD), nitrogen and phosphorus, such as from municipal, commercial and industrial sources. More particularly, the invention relates to activated sludge wastewater treatment processes.
  • BOD biochemical oxygen demand
  • nitrogen nitrogen
  • phosphorus such as from municipal, commercial and industrial sources. More particularly, the invention relates to activated sludge wastewater treatment processes.
  • a conventional activated sludge process typically begins with the removal of course materials such as grit, large particulate matter and other suspended solids from the wastewater.
  • the wastewater is then sent to a primary clarifier to separate sludge from a clear supernatant.
  • the sludge is removed for disposal or further treated in a digester, where a clear liquid is recycled back to the primary clarifier and the unconsumed sludge is sent off for disposal.
  • the clear supernatant from the primary clarifier is combined in an aeration tank with bacteria- laden sludge, also referred to as activated sludge, from a downstream process.
  • the clear supernatant and activated sludge form a mixed liquor that is aerated in the aeration tank to reduce the BOD.
  • the mixed liquor is then sent to a secondary clarifier or membrane system to settle and/or thicken the sludge and leave a clear effluent.
  • the clear effluent is removed, disinfected and typically discharged into a local waterway.
  • a portion of the sludge is returned to the aeration tank as return activated sludge (RAS), while the remainder is usually concentrated and sent off for disposal as waste activated sludge (WAS).
  • RAS return activated sludge
  • WAS waste activated sludge
  • the invention provides a method for treating wastewater comprising combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor, separating the mixed liquor into a clear effluent and activated sludge stream, pretreating at least a portion of the activated sludge stream in a conditioning tank, transferring at least a portion of the activated sludge stream in the conditioning tank to a bioreactor, processing the activated sludge stream within the bioreactor by selecting desired growth conditions to cultivate at least one type of bacteria in the activated sludge stream, and returning at least a portion of the activated sludge stream in the bioreactor to the activated sludge tank.
  • the invention provides a method for treating wastewater comprising combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor, separating the mixed liquor into a clear effluent and activated sludge stream, pretreating at least a portion of the activated sludge stream in a conditioning tank, transferring at least a portion of the activated sludge stream in the conditioning tank to the bioreactor, processing the activated sludge stream within the bioreactor by converting phosphorus in the activated sludge stream into soluble phosphates in the bioreactor, transferring at least a portion of the activated sludge stream from the bioreactor to a sidestream reactor, adding a source of multivalent metal ions to the activated sludge stream in the sidestream reactor to precipitate phosphate solids, separating and removing the phosphate solids from the activated sludge stream, and returning at least a portion of the activated sl
  • FIG. 1 is a schematic view of an improved wastewater treatment system embodying the invention.
  • FIG. 2 is a schematic view of the conditioning tank and the bioreactor in the improved wastewater treatment system.
  • FIG. 3 is a schematic view of an alternative embodiment of the improved wastewater treatment system in Fig. 1.
  • FIG. 4 is a schematic view of an alternative embodiment of the improved wastewater treatment system in Fig. 3.
  • FIG. 1 illustrates a schematic view of an improved wastewater treatment system embodying the invention.
  • the wastewater treatment system minimizes WAS by employing an activated sludge tank 10 in combination with a secondary separator 12 and an interchange bioreactor 14.
  • a conditioning tank 16 is added upstream of the bioreactor 14 and adds operational flexibility to the treatment process by providing a controlled system for conditioning the wastewater before it is sent to the interchange bioreactor 14 and/or activated sludge tank 10.
  • untreated wastewater comprising BOD, nitrogen and phosphorus may be pretreated in a primary separator 18.
  • Wastewater is transported by conduit 20 to the primary separator 18 where solids, such as grit and large particulate matter, are separated from a primary effluent.
  • the solids may be removed from the system by conduit 21 and/or added to the activated sludge downstream of a secondary separator 12 by conduit 28.
  • the primary effluent, or untreated wastewater if no pretreatment is used, is transported by conduit 22 to the activated sludge tank 10 where it is mixed with a bacterial-laden sludge, or an activated sludge, to form a mixed liquor.
  • the activated sludge tank 10 subjects the mixed liquor to one or more biological growth conditions that cultivate microorganisms to reduce BOD and ammonia originating from the wastewater.
  • the activated sludge tank 10 typically comprises one or more reactor zones, each of which operates under anaerobic, anoxic or aerobic conditions.
  • An anaerobic zone cultivates anaerobic microorganisms that thrive in an oxygen-free environment.
  • An anoxic zone supplies oxygen or nitrate to the mixed liquor at a rate insufficient to create a measurable dissolved oxygen level, thus resulting in an oxygen deficit.
  • An aeration zone cultivates aerobic microorganisms that thrive under a continuous oxygen surplus.
  • anoxic zone microorganisms take up and store simple carbon compounds, using energy derived from the hydrolysis and release of phosphates.
  • Anoxic zone microorganisms typically use oxygen to oxidize BOD and/or ammonia. When the oxygen supply is less than the demand, anoxic microorganisms can use the nitrates generated from the oxidation of ammonia to further oxidize BOD and generate nitrogen gas. Aerobic zone microorganisms oxidize BOD and simultaneously absorb and store phosphates. Aerobic zone microorganisms also oxidize ammonia.
  • the activated sludge tank 10 may be specifically tailored to reduce BOD and ammonia in wastewater by varying the number and sequence of reactor zones.
  • the activated sludge tank 10 may be divided into a finite number of discrete zones defined by distinct boundaries.
  • the activated sludge tank 10 comprises three reactor zones, where the mixed liquor is first subjected to an aerobic zone, followed by an anoxic zone and an aerobic zone.
  • the activated sludge tank 10 comprises two reactor zones, where the mixed liquor is first subjected to an anaerobic zone followed by an aerobic zone.
  • the activated sludge tank 10 has four reactor zones, where the mixed liquor is first subjected to an anaerobic zone, followed by an anoxic zone and two aerobic zones.
  • the listed embodiments serve as examples only. It should be understood that the activated sludge tank 10 may comprise one or more reactor zones arranged in any sequence. Furthermore, the activated sludge tank 10 may run as a batch process or a continuous process.
  • the activated sludge tank 10 may also have a long plug flow design where there are no discrete boundaries and the conditions change gradually over the length of the tank.
  • the tank environment gradually transitions from an anoxic environment at the upstream end to an aerobic environment at the downstream end.
  • the tank environment gradually transitions from an aerobic environment at the upstream end, to an anoxic environment at the middle, and to an aerobic environment at the downstream end.
  • the mixed liquor is transferred by conduit 24 to the secondary separator 12 where solids are separated from the mixed liquor, leaving behind sludge and a clear effluent.
  • the activated sludge tank 10 and the secondary separator 12 are separate units. Li an alternative embodiment, the activated sludge tank 10 and the secondary separator 12 are combined into a sequencing batch reactor.
  • the secondary separator 12 may be any device that separates solids from liquids by, for example, gravity, differential settling velocity, or size-exclusion.
  • Examples of secondary separators 12 include, but are not limited to, settling ponds, clarifiers, hydrocyclones, centrifuges, and membrane filters or separators.
  • the clear effluent is removed along path 26 and may be disinfected and discharged into a local waterway.
  • the remaining sludge, or activated sludge (AS) stream comprising live bacteria, expired bacteria and other organic matter, is diverted to a sidestream by conduit 30.
  • AS activated sludge
  • the AS stream may be transferred to various locations in the wastewater treatment process. As shown in Fig. 1, the AS stream may be transported by conduit 32 to the interchange bioreactor 14 where a second bacteria population is cultivated under one or more growth conditions to decompose the sludge in the AS stream.
  • a suitable interchange bioreactor 14 is described below and in U.S. Pat. No. 6,660,163 issued to Miklos, which is hereby fully incorporated by reference.
  • the bacteria population within the AS stream typically comprises one or more classes of bacteria.
  • classes of bacteria include, but are not limited to, obligate aerobes, facultative aerobes, nitrifiers, obligate anaerobes, and facultative anaerobes.
  • Each bacteria performs a certain function. For example, some bacteria convert particulate BOD into soluble BOD for utilization, some reduce high solids yield organisms, and some improve nitrification/denitrification efficiency.
  • Each bacteria also thrives within a narrow range of conditions. Aerobic bacteria thrive in an oxygen environment, anaerobic bacteria thrive in an oxygen depleted environment, and facultative bacteria typically thrive in both environments.
  • Bacteria within a population may be selectively activated by changing the growth conditions to which the population is subjected. Desired growth conditions may be achieved by effecting a selected order of aerobic, anoxic, and anaerobic conditions for varied lengths of time and repetitively controlling those conditions by measurement and reproduction of the oxidation- reduction potential (ORP), specific oxygen uptake rate (SOUR), and/or specific nitrogen uptake rate (SNUR). Therefore, within the interchange bioreactor 14 it is possible to treat more than one component in the wastewater by selectively varying the conditions of the interchange bioreactor 14 to sequentially activate the individual types of bacteria. [0021] In one embodiment, the interchange bioreactor 14 is run under anaerobic conditions to promote the growth and activity of anaerobic bacteria.
  • Such bacteria may include obligate anaerobes and/or facultative anaerobes. Under anaerobic conditions, bacteria that accumulated quantities of phosphorus in excess of that required for simple cell growth and reproduction during aeration, now take up and store simple carbon compounds, using energy derived from the hydrolysis and release of phosphates. When the AS stream is eventually returned to the activated sludge tank 10, these bacteria are able to metabolize the absorbed carbon compounds in an aerobic zone.
  • the interchange bioreactor 14 is a sequencing facultative digester (SFD) favoring a low solids yield.
  • SFD sequencing facultative digester
  • the AS stream comprising facultative bacteria is subjected to a sequence of anoxic and anaerobic conditions designed to break down the organic matter in the AS stream.
  • the SFD can operate as a batch process, where the entire contents of the SFD are under anoxic conditions or anaerobic conditions.
  • the SFD can operate as a continuous process where the SFD is divided into one or more separate compartments, each compartment operating under anoxic or anaerobic conditions.
  • the sequence of conditions may take on any order.
  • the AS stream is either returned to the activated sludge tank 10 by conduit 34 or recycled back to the conditioning tank 16 by conduit 36. Alternatively, a portion of the AS stream is recycled back to the conditioning tank 16 and the remainder is returned to the activated sludge tank 10.
  • the AS stream may be transferred to the conditioning tank 16 by conduit 38.
  • the conditioning tank 16 improves the operation of the wastewater treatment process by providing a flexible mechanism for pretreating the AS stream prior to processing in the interchange bioreactor 14 and/or returning the AS stream to the activated sludge tank 10.
  • the conditioning tank 16 may be used to treat solids from highly loaded aeration basins, to thicken the AS stream prior to transport to the interchange bioreactor 14, and/or to optimize the biological or chemical reactions required for solids reduction.
  • the conditioning tank 16 is designed to meet a wide variety of processing conditions.
  • the conditioning tank 16 includes provisions for adding air 40, provisions for drawing off supernatant 42, provisions for adding a return liquid/solids stream from the interchange bioreactor 36, provisions for flow through of the AS stream 44, and provisions for mixing of the tank contents by conventional means 46.
  • the ability to control for any or all of these conditions offers the potential to greatly improve the performance of the wastewater treatment process for site specific wastewater requirements and for adjusting to diurnal, seasonal, or long- term variations that may occur at a wastewater treatment facility.
  • the conditioning tank 16 allows a wastewater treatment plant to adjust to highly loaded aeration basins. Highly loaded aeration basins tend to produce an AS stream that is too reactive, or not stable enough, to be treated properly in the interchange bioreactor 14. Therefore, the AS stream is routed to the conditioning tank 16 for additional aeration and stabilization before being sent to the interchange bioreactor 14. Within the conditioning tank 16, the AS stream may be aerated for all, or a significant portion, of each day, depending upon the composition of the AS stream. Air may be introduced into the conditioning tank 16 by any conventional means of aeration known to those skilled in the art. The source of aeration may include, but is not limited to, pure oxygen, compressed air and mechanical aeration.
  • the conditioning tank 16 is used to re-aerate the sludge from the AS line 38, followed by interchanging a portion of the AS stream from the conditioning tank 16 to the interchange bioreactor 14 by conduit 47.
  • the conditioning tank 16 is used as a gravity thickening tank to concentrate the solids in the AS stream prior to treatment in the interchange bioreactor 14.
  • the interchange bioreactor 14 may operate more effectively if the solids are concentrated prior to feeding into the interchange bioreactor 14. This method is particularly useful for a wastewater treatment plant where the influent loadings have increased to a point that the size of the interchange bioreactor 14 is marginal and additional detention time in the interchange bioreactor 14 could be realized through the treatment of an AS stream with a high solids concentration. Additionally, desirable chemistry and/or biochemistry occurring within the side stream interchange bioreactor 14 may be optimized by treating the AS stream with a higher solids concentration.
  • the AS stream is routed to the conditioning tank 16 where the solids are allowed to settle and the supernatant is drawn off, thus concentrating the solids in the AS stream. The AS stream is then sent to the interchange bioreactor 14 for further processing.
  • the AS stream is re-circulated from the interchange bioreactor 14 to the conditioning tank 16 by conduit 36 to improve the performance of the wastewater treatment process.
  • the conditioning tank 16 is typically designed to adjust to the composition of the incoming waste stream.
  • the above features may be applied individually or in combination.
  • the conditioning tank 16 may function as an aeration tank when the AS stream is highly loaded or function as a thickening tank when the influent loadings have increased to a certain level.
  • the conditioning tank 16 may be used to simultaneously aerate and thicken the AS stream (e.g. air flotation).
  • the conditioning tank 16 may operate as a continuous flow process or as a batch process.
  • the detention time in the conditioning tank 16 is typically between 1 hour and 5 days, depending on the desired performance and/or flexibility for a given installation.
  • the contents of the conditioning tank 16 may or may not be mechanically mixed during operation.
  • the AS stream may be fed to the interchange bioreactor 14 by conduit 47 and/or returned to the activated sludge tank 10 by conduit 44.
  • the AS stream from the secondary separator 12 can be returned to the activated sludge tank 10 by conduit [0033]
  • each of the AS stream pathways has been described individually, it should be recognized that the AS stream may be entirely diverted along one of the pathways or alternatively split among two or more pathways. Additionally, the selected pathways and the amount of the AS stream sent to each pathway may be adjusted as needed to most efficiently and effectively treat the wastewater entering the treatment plant at any given time.
  • the AS stream may optionally pass through a solids separation module 50.
  • Wastewater typically comprises a variety of solids, including small organic materials such as microorganisms critical to wastewater treatment, larger organic matter such as trash, and small and large inorganic particles such as sand. Removal of trash and inorganic solids from the wastewater substantially increases the efficiency of the wastewater treatment process. Therefore, it is often beneficial to include a solids separation module 50 in the treatment process.
  • a suitable solids separation module 50 is described below and in U.S. Pat. Nos. 5,658,458, 5,626,755 and 5,824,222 issued to Keyser et al., which are hereby fully incorporated by reference.
  • a suitable solids separation module 50 includes one or more screens 52, in series or parallel, having a suitable opening size to remove large organic and inorganic particles, and one or more mechanical separators 54, in series or parallel, for removing small inorganic particles similar in size to the microorganisms.
  • screens 52 include, but are not limited to, drum screens and flat screens.
  • mechanical separators 54 include, but are not limited to, a gravity separator, a hydrocyclone and a centrifuge. The screens 52 and mechanical separators 54 may be employed in any order.
  • the AS stream flows through a screen 52 in the solids separation module 50.
  • the screen 52 blocks passage of large inorganic and organic matter which is later removed as solid waste along path 56.
  • the AS stream is then fed by conduit 58 to a sump 60.
  • a pump 62 transfers the AS stream from the sump 60 to the mechanical separator 54.
  • Small, inert solids are separated from the AS stream and removed from the solids separation module 50 along path 64 as solid waste.
  • the remainder of the AS stream is returned to the sump 60 where it can be transported by conduit 49 to the activated sludge tank 10, sent by conduit 38 to the conditioning tank 16, transferred to the interchange bioreactor 14 and/or pumped back through the mechanical separator 54.
  • the solids separation module 50 is located between the secondary separator 12 and the interchange bioreactor 14. However, the solids separation module 50 may be located elsewhere, such as downstream of the activated sludge tank 10 and upstream of the secondary separator 12.
  • the wastewater treatment system may also optionally include a process for removing phosphates from the wastewater.
  • phosphates typically remain in the wastewater stream and are removed from the plant along with the clear effluent. If the phosphates are in high enough concentration, the clear effluent must be treated to remove the phosphates prior to discharging the effluent into a local waterway. Any process capable of removing phosphates from the wastewater may be employed.
  • the AS stream may be transported by conduit 72 to a sidestream reactor 70 where soluble phosphates are removed from the sludge stream as solid phosphates.
  • a sidestream reactor 70 where soluble phosphates are removed from the sludge stream as solid phosphates.
  • an acid or base is typically added to adjust the pH of the AS stream to slightly alkaline, and a source of multivalent metal ions is added to precipitate the phosphates.
  • Any multivalent metal ion that forms an insoluble phosphate having a specific gravity greater than the organic matter making up the sludge may be used.
  • the multivalent metal ions comprise calcium and/or magnesium.
  • other reagents, such as ammonia may be added as needed to form the desired precipitate.
  • reagents are fed into the sidestream reactor 70 through a series of conduits 74.
  • one conduit 74 may supply a base to adjust the pH of the sludge stream.
  • Another conduit 74 may supply a multivalent metal ion used to precipitate the phosphate.
  • Yet another may supply a source of ammonia or raw wastewater.
  • a mechanical mixer (not shown) can be used to insure adequate mixing of all materials.
  • the sidestream reactor 70 may operate as a continuous, semi-continuous or batch process, and may be employed continuously or periodically. In the case of periodic use, the level of soluble phosphates in the sludge stream is allowed to build up over a period of time before the sludge stream is diverted to the sidestream reactor 70 for treatment.
  • soluble phosphates are precipitated in the sidestream reactor 70 as struvite, MgNH 4 PO 4 -6H 2 0.
  • struvite MgNH 4 PO 4 -6H 2
  • a standard base such as, but not limited to, NaOH, KOH, NH 4 OH and Mg(OH) 2 may be added.
  • the pH of the sludge stream in the sidestream reactor 70 is adjusted to about 8 to about 10. More preferably the pH is adjusted to about 8.5 to about 9.5.
  • a source of magnesium ion In addition to adjusting the pH, a source of magnesium ion must be present in the sludge stream.
  • the amount of magnesium ion required is about 100% to about 120% the stoichiometric amount. More preferably the amount of magnesium ion is about 110% the stoichiometric amount. If a sufficient source of magnesium ion exists in solution, no further source need be added. Otherwise, a source of magnesium ion such as, but not limited to, MgCl 2 , MgHCO 3 , MgO, MgSO 4 , and Mg(OH) 2 may be added. Finally, a source of ammonium ion is required.
  • sludge streams by nature have a high ammonia content that can provide an adequate source of ammonium ions.
  • raw wastewater or other sources of ammonia such as, but not limited to, NH 4 OH and NH 4 Cl may be added to the sidestream reactor 70 to provide a sufficient concentration of ammonium ions.
  • the amount of ammonium in the sludge stream is preferably about 100% to about 120% the stoichiometric amount.
  • the contents of the sidestream reactor 70 are mechanically mixed for about 20 minutes to about 2 hours. Soluble phosphates precipitate out of the sludge stream as struvite, MgNH 4 PO 4 -6H 2 0.
  • soluble phosphates are precipitated in the sidestream reactor 70 as calcium phosphate, Ca 3 (PO 4 ) 2 .
  • Favorable reaction conditions require a slightly alkaline sludge stream and an adequate source of calcium ions. Since the pH of the sludge stream is usually neutral when it leaves the bioreactor 14, a standard base such as, but not limited to, NaOH, KOH, NH 4 OH and Mg(OH) 2 may be added.
  • the pH of the sludge stream in the sidestream reactor 70 is adjusted to about 8 to about 10. More preferably the pH is adjusted to about 8.5 to about 9.5.
  • a source of calcium ions must be present in the sludge stream.
  • the amount of calcium ions required is about 100% to about 120% the stoichiometric amount. More preferably the amount of calcium ions is about 110% the stoichiometric amount. If a sufficient source of calcium ions exists in solution, no further source need be added. Otherwise, a source of calcium ions including, but not limited to, CaCl 2 and Ca(OH) 2 may be added.
  • the contents of the sidestream reactor 70 are mechanically mixed for about 20 minutes to about 2 hours. Soluble phosphates precipitate out of the sludge stream as calcium phosphate, Ca 3 (PO 4 ) 2 .
  • the contents of the sidestream reactor 70 are then pumped by conduit 76 to one or more separators 78 to remove the solid phosphates from the AS stream.
  • the solid phosphates can be separated from the AS stream based on differential settling velocity using any number of mechanical means including, but not limited to, a gravity separator, a hydrocyclone and a centrifuge.
  • the solid phosphates may be discharged along path 80 as a concentrated sludge stream relatively low in biological solids.
  • the remainder of the AS stream may be recycled back to the activated sludge tank 10 by conduit 82 for further treatment.
  • a portion of the AS stream can be returned to the sidestream reactor 70 by conduit 84 to facilitate the formation of larger crystals by having the crystals formed earlier acting as seeds for the formation of larger crystals.
  • the mechanical separator 54 used to remove small inorganic particles from the AS stream may also be used to separate the solid phosphates from the AS stream.
  • the AS stream from the sidestream reactor 70 is sent by conduit 84 to the mechanical separator 54 contained within the solids separation module 50.
  • the solid phosphates are separated from the AS stream and disposed as solid waste along path 64 and/or returned to the sidestream reactor 70 by conduit 86 to provide seed crystals.
  • the AS stream is returned to the activated sludge tank 10 by conduit 49, transported to the conditioning tank 16 by conduit 38, transported to the interchange bioreactor 14 by conduit 32, and/or recycled back through the mechanical separator 54.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Activated Sludge Processes (AREA)

Abstract

Wastewater is treated by an activated sludge system having a primary separator (18), an activated sludge tank (10), a secondary separator (12), a conditioning tank (16), a bioreactor (14) and a sidestream reactor (70).

Description

CONDITIONING SYSTEM FOR ACTIVATED SLUDGE WASTEWATER TREATMENT PROCESSES
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority under 35 U.S .C. § 119(e) to U.S . Provisional Application Serial No. 60/700,166, filed on July 18, 2005. This application claims priority to and fully incorporates the subject matter of the application mentioned above.
FIELD OF THE INVENTION
[0002] The present invention relates to the treatment of wastewaters comprising biochemical oxygen demand (BOD), nitrogen and phosphorus, such as from municipal, commercial and industrial sources. More particularly, the invention relates to activated sludge wastewater treatment processes.
BACKGROUND OF THE INVENTION
[0003] Many wastewater treatment plants employ an activated sludge process to break down the organic matter in wastewater. A conventional activated sludge process typically begins with the removal of course materials such as grit, large particulate matter and other suspended solids from the wastewater. The wastewater is then sent to a primary clarifier to separate sludge from a clear supernatant. The sludge is removed for disposal or further treated in a digester, where a clear liquid is recycled back to the primary clarifier and the unconsumed sludge is sent off for disposal. The clear supernatant from the primary clarifier is combined in an aeration tank with bacteria- laden sludge, also referred to as activated sludge, from a downstream process. The clear supernatant and activated sludge form a mixed liquor that is aerated in the aeration tank to reduce the BOD. The mixed liquor is then sent to a secondary clarifier or membrane system to settle and/or thicken the sludge and leave a clear effluent. The clear effluent is removed, disinfected and typically discharged into a local waterway. A portion of the sludge is returned to the aeration tank as return activated sludge (RAS), while the remainder is usually concentrated and sent off for disposal as waste activated sludge (WAS).
[0004] Current wastewater treatment processes exhibit two important drawbacks. First, many wastewater treatment processes generate large amounts of WAS that must be sent off-site for disposal. Handling and disposal of WAS is typically the largest single cost component in the operation of a wastewater treatment plant. Second, most wastewater treatment processes cannot effectively respond to diurnal, seasonal, or long- term variations in the composition of wastewater. A treatment process that may be effective in treating wastewater during one time of the year may not be as effective at treating wastewater during another time of the year. Therefore, a need exists within the industry for a wastewater treatment process that both lowers WAS and adjusts effectively to fluctuations in wastewater composition.
SUMMARY
[0005] In one embodiment, the invention provides a method for treating wastewater comprising combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor, separating the mixed liquor into a clear effluent and activated sludge stream, pretreating at least a portion of the activated sludge stream in a conditioning tank, transferring at least a portion of the activated sludge stream in the conditioning tank to a bioreactor, processing the activated sludge stream within the bioreactor by selecting desired growth conditions to cultivate at least one type of bacteria in the activated sludge stream, and returning at least a portion of the activated sludge stream in the bioreactor to the activated sludge tank.
[0006] In another embodiment, the invention provides a method for treating wastewater comprising combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor, separating the mixed liquor into a clear effluent and activated sludge stream, pretreating at least a portion of the activated sludge stream in a conditioning tank, transferring at least a portion of the activated sludge stream in the conditioning tank to the bioreactor, processing the activated sludge stream within the bioreactor by converting phosphorus in the activated sludge stream into soluble phosphates in the bioreactor, transferring at least a portion of the activated sludge stream from the bioreactor to a sidestream reactor, adding a source of multivalent metal ions to the activated sludge stream in the sidestream reactor to precipitate phosphate solids, separating and removing the phosphate solids from the activated sludge stream, and returning at least a portion of the activated sludge stream to the activated sludge tank.
BRIEF DESCRIPTION OF THE DRAWINGS
[0007] FIG. 1 is a schematic view of an improved wastewater treatment system embodying the invention.
[0008] FIG. 2 is a schematic view of the conditioning tank and the bioreactor in the improved wastewater treatment system.
[0009] FIG. 3 is a schematic view of an alternative embodiment of the improved wastewater treatment system in Fig. 1.
[0010] FIG. 4 is a schematic view of an alternative embodiment of the improved wastewater treatment system in Fig. 3.
[0011] Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. Also, it is to be understood that the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of "including," "comprising," or "having" and variations thereof herein is meant to encompass the items listed thereafter and equivalents thereof as well as additional items. The word "conduit" is used broadly to represent a pathway, and is not meant to be restricted to any particular physical or mechanical device.
DETAILED DESCRIPTION
[0012] Fig. 1 illustrates a schematic view of an improved wastewater treatment system embodying the invention. The wastewater treatment system minimizes WAS by employing an activated sludge tank 10 in combination with a secondary separator 12 and an interchange bioreactor 14. A conditioning tank 16 is added upstream of the bioreactor 14 and adds operational flexibility to the treatment process by providing a controlled system for conditioning the wastewater before it is sent to the interchange bioreactor 14 and/or activated sludge tank 10.
[0013] As shown in Fig. 1, untreated wastewater comprising BOD, nitrogen and phosphorus may be pretreated in a primary separator 18. Wastewater is transported by conduit 20 to the primary separator 18 where solids, such as grit and large particulate matter, are separated from a primary effluent. The solids may be removed from the system by conduit 21 and/or added to the activated sludge downstream of a secondary separator 12 by conduit 28. The primary effluent, or untreated wastewater if no pretreatment is used, is transported by conduit 22 to the activated sludge tank 10 where it is mixed with a bacterial-laden sludge, or an activated sludge, to form a mixed liquor.
[0014] The activated sludge tank 10 subjects the mixed liquor to one or more biological growth conditions that cultivate microorganisms to reduce BOD and ammonia originating from the wastewater. The activated sludge tank 10 typically comprises one or more reactor zones, each of which operates under anaerobic, anoxic or aerobic conditions. An anaerobic zone cultivates anaerobic microorganisms that thrive in an oxygen-free environment. An anoxic zone supplies oxygen or nitrate to the mixed liquor at a rate insufficient to create a measurable dissolved oxygen level, thus resulting in an oxygen deficit. An aeration zone cultivates aerobic microorganisms that thrive under a continuous oxygen surplus. Although the invention should in no way be limited, it is believed that in the anaerobic zone microorganisms take up and store simple carbon compounds, using energy derived from the hydrolysis and release of phosphates. Anoxic zone microorganisms typically use oxygen to oxidize BOD and/or ammonia. When the oxygen supply is less than the demand, anoxic microorganisms can use the nitrates generated from the oxidation of ammonia to further oxidize BOD and generate nitrogen gas. Aerobic zone microorganisms oxidize BOD and simultaneously absorb and store phosphates. Aerobic zone microorganisms also oxidize ammonia. [0015] The activated sludge tank 10 may be specifically tailored to reduce BOD and ammonia in wastewater by varying the number and sequence of reactor zones. The activated sludge tank 10 may be divided into a finite number of discrete zones defined by distinct boundaries. In one embodiment, the activated sludge tank 10 comprises three reactor zones, where the mixed liquor is first subjected to an aerobic zone, followed by an anoxic zone and an aerobic zone. In another embodiment, the activated sludge tank 10 comprises two reactor zones, where the mixed liquor is first subjected to an anaerobic zone followed by an aerobic zone. In a further embodiment, the activated sludge tank 10 has four reactor zones, where the mixed liquor is first subjected to an anaerobic zone, followed by an anoxic zone and two aerobic zones. The listed embodiments serve as examples only. It should be understood that the activated sludge tank 10 may comprise one or more reactor zones arranged in any sequence. Furthermore, the activated sludge tank 10 may run as a batch process or a continuous process.
[0016] The activated sludge tank 10 may also have a long plug flow design where there are no discrete boundaries and the conditions change gradually over the length of the tank. In one embodiment, the tank environment gradually transitions from an anoxic environment at the upstream end to an aerobic environment at the downstream end. In an alternative embodiment, the tank environment gradually transitions from an aerobic environment at the upstream end, to an anoxic environment at the middle, and to an aerobic environment at the downstream end.
[0017] From the activated sludge tank 10, the mixed liquor is transferred by conduit 24 to the secondary separator 12 where solids are separated from the mixed liquor, leaving behind sludge and a clear effluent. In the embodiment shown in Fig. 1, the activated sludge tank 10 and the secondary separator 12 are separate units. Li an alternative embodiment, the activated sludge tank 10 and the secondary separator 12 are combined into a sequencing batch reactor.
[0018] The secondary separator 12 may be any device that separates solids from liquids by, for example, gravity, differential settling velocity, or size-exclusion. Examples of secondary separators 12 include, but are not limited to, settling ponds, clarifiers, hydrocyclones, centrifuges, and membrane filters or separators. The clear effluent is removed along path 26 and may be disinfected and discharged into a local waterway. The remaining sludge, or activated sludge (AS) stream, comprising live bacteria, expired bacteria and other organic matter, is diverted to a sidestream by conduit 30.
[0019] The AS stream may be transferred to various locations in the wastewater treatment process. As shown in Fig. 1, the AS stream may be transported by conduit 32 to the interchange bioreactor 14 where a second bacteria population is cultivated under one or more growth conditions to decompose the sludge in the AS stream. A suitable interchange bioreactor 14 is described below and in U.S. Pat. No. 6,660,163 issued to Miklos, which is hereby fully incorporated by reference.
[0020] The bacteria population within the AS stream typically comprises one or more classes of bacteria. Such classes of bacteria include, but are not limited to, obligate aerobes, facultative aerobes, nitrifiers, obligate anaerobes, and facultative anaerobes. Each bacteria performs a certain function. For example, some bacteria convert particulate BOD into soluble BOD for utilization, some reduce high solids yield organisms, and some improve nitrification/denitrification efficiency. Each bacteria also thrives within a narrow range of conditions. Aerobic bacteria thrive in an oxygen environment, anaerobic bacteria thrive in an oxygen depleted environment, and facultative bacteria typically thrive in both environments. Bacteria within a population may be selectively activated by changing the growth conditions to which the population is subjected. Desired growth conditions may be achieved by effecting a selected order of aerobic, anoxic, and anaerobic conditions for varied lengths of time and repetitively controlling those conditions by measurement and reproduction of the oxidation- reduction potential (ORP), specific oxygen uptake rate (SOUR), and/or specific nitrogen uptake rate (SNUR). Therefore, within the interchange bioreactor 14 it is possible to treat more than one component in the wastewater by selectively varying the conditions of the interchange bioreactor 14 to sequentially activate the individual types of bacteria. [0021] In one embodiment, the interchange bioreactor 14 is run under anaerobic conditions to promote the growth and activity of anaerobic bacteria. Such bacteria may include obligate anaerobes and/or facultative anaerobes. Under anaerobic conditions, bacteria that accumulated quantities of phosphorus in excess of that required for simple cell growth and reproduction during aeration, now take up and store simple carbon compounds, using energy derived from the hydrolysis and release of phosphates. When the AS stream is eventually returned to the activated sludge tank 10, these bacteria are able to metabolize the absorbed carbon compounds in an aerobic zone.
[0022] In a second embodiment, the interchange bioreactor 14 is a sequencing facultative digester (SFD) favoring a low solids yield. Within an SFD, the AS stream comprising facultative bacteria is subjected to a sequence of anoxic and anaerobic conditions designed to break down the organic matter in the AS stream. The SFD can operate as a batch process, where the entire contents of the SFD are under anoxic conditions or anaerobic conditions. Alternatively, the SFD can operate as a continuous process where the SFD is divided into one or more separate compartments, each compartment operating under anoxic or anaerobic conditions. The sequence of conditions may take on any order.
[0023] After processing in the interchange bioreactor 14, the AS stream is either returned to the activated sludge tank 10 by conduit 34 or recycled back to the conditioning tank 16 by conduit 36. Alternatively, a portion of the AS stream is recycled back to the conditioning tank 16 and the remainder is returned to the activated sludge tank 10.
[0024] Instead of, or in addition to, sending the AS stream directly to the interchange bioreactor 14, the AS stream may be transferred to the conditioning tank 16 by conduit 38. The conditioning tank 16 improves the operation of the wastewater treatment process by providing a flexible mechanism for pretreating the AS stream prior to processing in the interchange bioreactor 14 and/or returning the AS stream to the activated sludge tank 10. The conditioning tank 16 may be used to treat solids from highly loaded aeration basins, to thicken the AS stream prior to transport to the interchange bioreactor 14, and/or to optimize the biological or chemical reactions required for solids reduction.
[0025] The conditioning tank 16 is designed to meet a wide variety of processing conditions. In one embodiment, as shown in Fig. 2, the conditioning tank 16 includes provisions for adding air 40, provisions for drawing off supernatant 42, provisions for adding a return liquid/solids stream from the interchange bioreactor 36, provisions for flow through of the AS stream 44, and provisions for mixing of the tank contents by conventional means 46. The ability to control for any or all of these conditions offers the potential to greatly improve the performance of the wastewater treatment process for site specific wastewater requirements and for adjusting to diurnal, seasonal, or long- term variations that may occur at a wastewater treatment facility.
[0026] In one embodiment, the conditioning tank 16 allows a wastewater treatment plant to adjust to highly loaded aeration basins. Highly loaded aeration basins tend to produce an AS stream that is too reactive, or not stable enough, to be treated properly in the interchange bioreactor 14. Therefore, the AS stream is routed to the conditioning tank 16 for additional aeration and stabilization before being sent to the interchange bioreactor 14. Within the conditioning tank 16, the AS stream may be aerated for all, or a significant portion, of each day, depending upon the composition of the AS stream. Air may be introduced into the conditioning tank 16 by any conventional means of aeration known to those skilled in the art. The source of aeration may include, but is not limited to, pure oxygen, compressed air and mechanical aeration.
[0027] In an alternative embodiment, the conditioning tank 16 is used to re-aerate the sludge from the AS line 38, followed by interchanging a portion of the AS stream from the conditioning tank 16 to the interchange bioreactor 14 by conduit 47.
[0028] In another embodiment, the conditioning tank 16 is used as a gravity thickening tank to concentrate the solids in the AS stream prior to treatment in the interchange bioreactor 14. In some cases, the interchange bioreactor 14 may operate more effectively if the solids are concentrated prior to feeding into the interchange bioreactor 14. This method is particularly useful for a wastewater treatment plant where the influent loadings have increased to a point that the size of the interchange bioreactor 14 is marginal and additional detention time in the interchange bioreactor 14 could be realized through the treatment of an AS stream with a high solids concentration. Additionally, desirable chemistry and/or biochemistry occurring within the side stream interchange bioreactor 14 may be optimized by treating the AS stream with a higher solids concentration. In operation, the AS stream is routed to the conditioning tank 16 where the solids are allowed to settle and the supernatant is drawn off, thus concentrating the solids in the AS stream. The AS stream is then sent to the interchange bioreactor 14 for further processing.
[0029] In yet another embodiment, the AS stream is re-circulated from the interchange bioreactor 14 to the conditioning tank 16 by conduit 36 to improve the performance of the wastewater treatment process.
[0030] The conditioning tank 16 is typically designed to adjust to the composition of the incoming waste stream. The above features may be applied individually or in combination. For example, the conditioning tank 16 may function as an aeration tank when the AS stream is highly loaded or function as a thickening tank when the influent loadings have increased to a certain level. Alternatively, the conditioning tank 16 may be used to simultaneously aerate and thicken the AS stream (e.g. air flotation). The conditioning tank 16 may operate as a continuous flow process or as a batch process. The detention time in the conditioning tank 16 is typically between 1 hour and 5 days, depending on the desired performance and/or flexibility for a given installation. The contents of the conditioning tank 16 may or may not be mechanically mixed during operation.
[0031] After processing in the conditioning tank 16, the AS stream may be fed to the interchange bioreactor 14 by conduit 47 and/or returned to the activated sludge tank 10 by conduit 44.
[0032] Instead of, or in addition to, sending AS directly to the interchange bioreactor 14 and the conditioning tank 16, as illustrated in Fig. 1, the AS stream from the secondary separator 12 can be returned to the activated sludge tank 10 by conduit [0033] Although each of the AS stream pathways has been described individually, it should be recognized that the AS stream may be entirely diverted along one of the pathways or alternatively split among two or more pathways. Additionally, the selected pathways and the amount of the AS stream sent to each pathway may be adjusted as needed to most efficiently and effectively treat the wastewater entering the treatment plant at any given time.
[0034] In an alternative embodiment of the invention, as shown in Fig. 3, the AS stream may optionally pass through a solids separation module 50. Wastewater typically comprises a variety of solids, including small organic materials such as microorganisms critical to wastewater treatment, larger organic matter such as trash, and small and large inorganic particles such as sand. Removal of trash and inorganic solids from the wastewater substantially increases the efficiency of the wastewater treatment process. Therefore, it is often beneficial to include a solids separation module 50 in the treatment process. A suitable solids separation module 50 is described below and in U.S. Pat. Nos. 5,658,458, 5,626,755 and 5,824,222 issued to Keyser et al., which are hereby fully incorporated by reference.
[0035] A suitable solids separation module 50 includes one or more screens 52, in series or parallel, having a suitable opening size to remove large organic and inorganic particles, and one or more mechanical separators 54, in series or parallel, for removing small inorganic particles similar in size to the microorganisms. Examples of screens 52 include, but are not limited to, drum screens and flat screens. Examples of mechanical separators 54 include, but are not limited to, a gravity separator, a hydrocyclone and a centrifuge. The screens 52 and mechanical separators 54 may be employed in any order.
[0036] In one embodiment, as illustrated in the embodiment of Fig. 3, the AS stream flows through a screen 52 in the solids separation module 50. The screen 52 blocks passage of large inorganic and organic matter which is later removed as solid waste along path 56. The AS stream is then fed by conduit 58 to a sump 60. A pump 62 transfers the AS stream from the sump 60 to the mechanical separator 54. Small, inert solids are separated from the AS stream and removed from the solids separation module 50 along path 64 as solid waste. The remainder of the AS stream is returned to the sump 60 where it can be transported by conduit 49 to the activated sludge tank 10, sent by conduit 38 to the conditioning tank 16, transferred to the interchange bioreactor 14 and/or pumped back through the mechanical separator 54. In some embodiments, such as the illustrated embodiment in Fig. 3, the solids separation module 50 is located between the secondary separator 12 and the interchange bioreactor 14. However, the solids separation module 50 may be located elsewhere, such as downstream of the activated sludge tank 10 and upstream of the secondary separator 12.
[0037] The wastewater treatment system may also optionally include a process for removing phosphates from the wastewater. In a low WAS treatment system, phosphates typically remain in the wastewater stream and are removed from the plant along with the clear effluent. If the phosphates are in high enough concentration, the clear effluent must be treated to remove the phosphates prior to discharging the effluent into a local waterway. Any process capable of removing phosphates from the wastewater may be employed.
[0038] In one embodiment, as shown in Fig. 3, at least a portion of the AS stream may be transported by conduit 72 to a sidestream reactor 70 where soluble phosphates are removed from the sludge stream as solid phosphates. Within the sidestream reactor 70, an acid or base is typically added to adjust the pH of the AS stream to slightly alkaline, and a source of multivalent metal ions is added to precipitate the phosphates. Any multivalent metal ion that forms an insoluble phosphate having a specific gravity greater than the organic matter making up the sludge may be used. Preferably, the multivalent metal ions comprise calcium and/or magnesium. Additionally, other reagents, such as ammonia, may be added as needed to form the desired precipitate. In some embodiments, such as the illustrated embodiment of Fig. 3, reagents are fed into the sidestream reactor 70 through a series of conduits 74. For example, one conduit 74 may supply a base to adjust the pH of the sludge stream. Another conduit 74 may supply a multivalent metal ion used to precipitate the phosphate. Yet another may supply a source of ammonia or raw wastewater. A mechanical mixer (not shown) can be used to insure adequate mixing of all materials. The sidestream reactor 70 may operate as a continuous, semi-continuous or batch process, and may be employed continuously or periodically. In the case of periodic use, the level of soluble phosphates in the sludge stream is allowed to build up over a period of time before the sludge stream is diverted to the sidestream reactor 70 for treatment.
[0039] In one preferred embodiment, soluble phosphates are precipitated in the sidestream reactor 70 as struvite, MgNH4PO4-6H20. Favorable reaction conditions require a slightly alkaline sludge stream and an adequate source of magnesium ions and ammonium ions. Since the pH of the sludge stream is usually neutral when it leaves the bioreactor 14, a standard base such as, but not limited to, NaOH, KOH, NH4OH and Mg(OH)2 may be added. Typically, the pH of the sludge stream in the sidestream reactor 70 is adjusted to about 8 to about 10. More preferably the pH is adjusted to about 8.5 to about 9.5. In addition to adjusting the pH, a source of magnesium ion must be present in the sludge stream. The amount of magnesium ion required is about 100% to about 120% the stoichiometric amount. More preferably the amount of magnesium ion is about 110% the stoichiometric amount. If a sufficient source of magnesium ion exists in solution, no further source need be added. Otherwise, a source of magnesium ion such as, but not limited to, MgCl2, MgHCO3, MgO, MgSO4, and Mg(OH)2 may be added. Finally, a source of ammonium ion is required. Many sludge streams by nature have a high ammonia content that can provide an adequate source of ammonium ions. However, if necessary, raw wastewater or other sources of ammonia such as, but not limited to, NH4OH and NH4Cl may be added to the sidestream reactor 70 to provide a sufficient concentration of ammonium ions. The amount of ammonium in the sludge stream is preferably about 100% to about 120% the stoichiometric amount. The contents of the sidestream reactor 70 are mechanically mixed for about 20 minutes to about 2 hours. Soluble phosphates precipitate out of the sludge stream as struvite, MgNH4PO4-6H20.
[0040] In a second preferred embodiment, soluble phosphates are precipitated in the sidestream reactor 70 as calcium phosphate, Ca3(PO4)2. Favorable reaction conditions require a slightly alkaline sludge stream and an adequate source of calcium ions. Since the pH of the sludge stream is usually neutral when it leaves the bioreactor 14, a standard base such as, but not limited to, NaOH, KOH, NH4OH and Mg(OH)2 may be added. Typically, the pH of the sludge stream in the sidestream reactor 70 is adjusted to about 8 to about 10. More preferably the pH is adjusted to about 8.5 to about 9.5. In addition to adjusting the pH, a source of calcium ions must be present in the sludge stream. The amount of calcium ions required is about 100% to about 120% the stoichiometric amount. More preferably the amount of calcium ions is about 110% the stoichiometric amount. If a sufficient source of calcium ions exists in solution, no further source need be added. Otherwise, a source of calcium ions including, but not limited to, CaCl2 and Ca(OH)2 may be added. The contents of the sidestream reactor 70 are mechanically mixed for about 20 minutes to about 2 hours. Soluble phosphates precipitate out of the sludge stream as calcium phosphate, Ca3(PO4)2.
[0041] The contents of the sidestream reactor 70 are then pumped by conduit 76 to one or more separators 78 to remove the solid phosphates from the AS stream. The solid phosphates can be separated from the AS stream based on differential settling velocity using any number of mechanical means including, but not limited to, a gravity separator, a hydrocyclone and a centrifuge. The solid phosphates may be discharged along path 80 as a concentrated sludge stream relatively low in biological solids. The remainder of the AS stream may be recycled back to the activated sludge tank 10 by conduit 82 for further treatment. Alternatively, a portion of the AS stream can be returned to the sidestream reactor 70 by conduit 84 to facilitate the formation of larger crystals by having the crystals formed earlier acting as seeds for the formation of larger crystals.
[0042] In an alternative embodiment of the invention, such as in the illustrated embodiment of Fig. 4, the mechanical separator 54 used to remove small inorganic particles from the AS stream may also be used to separate the solid phosphates from the AS stream. The AS stream from the sidestream reactor 70 is sent by conduit 84 to the mechanical separator 54 contained within the solids separation module 50. The solid phosphates are separated from the AS stream and disposed as solid waste along path 64 and/or returned to the sidestream reactor 70 by conduit 86 to provide seed crystals. The AS stream is returned to the activated sludge tank 10 by conduit 49, transported to the conditioning tank 16 by conduit 38, transported to the interchange bioreactor 14 by conduit 32, and/or recycled back through the mechanical separator 54.

Claims

CLAMSWe Claim:
1. A method for treating wastewater comprising: combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor; separating the mixed liquor into a clear effluent and activated sludge stream; pretreating at least a portion of the activated sludge from the activated sludge stream in a conditioning tank; transferring at least a portion of the pretreated activated sludge in the conditioning tank to a bioreactor; processing the pretreated activated sludge within the bioreactor by selecting desired growth conditions to cultivate at least one type of bacteria in the pretreated activated sludge; and returning at least a portion of the activated sludge in the bioreactor to the activated sludge tank.
2. The method of claim 1, wherein the method is one of a batch process, a continuous process and combination thereof.
3. The method of claim 1, wherein at least a portion of solids are removed from the wastewater prior to treatment in the activated sludge tank.
4. The method of claim 1, wherein at least a portion of the mixed liquor within the activated sludge tank is subjected to an aerobic environment.
5. The method of claim 1, wherein at least a portion of the mixed liquor within the activated sludge tank is subjected to an anaerobic environment followed by at least one of an anoxic environment and an aerobic environment.
6. The method of claim 1, wherein pretreating the activated sludge stream comprises one of aerating the activated sludge stream, concentrating the activated sludge stream, and a combination thereof.
7. The method of claim 1, wherein pretreating the activated sludge stream in the conditioning tank comprises aerating the activated sludge stream.
8. The method of claim 1, wherein pretreating the activated sludge in the conditioning tank comprises concentrating the activated sludge stream.
9. The method of claim 8, wherein concentrating the activated sludge stream comprises sufficiently settling the sludge stream to form a supernatant and drawing off the supernatant from the conditioning tank.
10. The method of claim 1, wherein pretreating the activated sludge stream in the conditioning tank enhances solid reduction in the wastewater treatment process.
11. The method of claim 1 , wherein pretreating the activated sludge stream in the conditioning tank comprises detaining the activated sludge stream in the conditioning tank for about 1 hour to about 5 days.
12. The method of claim 1, wherein pretreating the activated sludge stream in the conditioning tank is one of a batch process and a continuous process.
13. The method of claim 1, wherein the bioreactor comprises a facultative sequencing digester.
14. The method of claim 1, further comprising passing the activated sludge stream through a solids separation module upstream of the conditioning tank to remove at least a portion of trash and inorganic solids from the activated sludge stream.
15. The method of claim 1 , wherein at least a portion of the activated sludge stream in the bioreactor is cycled to the conditioning tank before being returned to the activated sludge tank.
16. The method of claim 1, wherein at least a portion of the activated sludge stream in the conditioning tank is directly returned to the activated sludge tank.
17. The method of claim 1, wherein at least a portion of the activated sludge separated from the mixed liquor is directly returned to the activated sludge tank.
18. A method for treating wastewater comprising: combining wastewater with bacteria-laden sludge in an activated sludge tank to form a mixed liquor; separating the mixed liquor into a clear effluent and activated sludge stream; pretreating at least a portion of the activated sludge stream in a conditioning tank; transferring at least a portion of the activated sludge stream in the conditioning tank to the bioreactor; processing the activated sludge stream within the bioreactor by converting phosphorus in the activated sludge stream into soluble phosphates in the bioreactor; transferring at least a portion of the activated sludge stream from the bioreactor to a sidestream reactor; adding a source of multivalent metal ions to the activated sludge stream in the sidestream reactor to precipitate phosphate solids; separating and removing the phosphate solids from the activated sludge stream; and returning at least a portion of the activated sludge stream to the activated sludge tank.
19. The method of claim 18, wherein the method is one of a batch process, a continuous process and combination thereof.
20. The method of claim 18, wherein the mixed liquor within the activated sludge tank is subjected to an aerobic environment.
21. The method of claim 18, wherein the mixed liquor within the activated sludge tank is subjected to an anaerobic environment followed by at least one of an anoxic environment and an aerobic environment.
22. The method of claim 18, wherein pretreating the activated sludge stream in the conditioning tank comprises aerating the activated sludge stream.
23. The method of claim 18, wherein pretreating the activated sludge stream in the conditioning tank comprises concentrating the activated sludge stream.
24. The method of claim 18, wherein the bioreactor comprises a facultative sequencing digester.
25. The method of claim 18, further comprising passing the activated sludge stream through a solids separation module upstream of the conditioning tank to remove at least a portion of trash and inorganic solids from the activated sludge stream.
26. The method of claim 18, wherein at least a portion of the activated sludge stream in the bioreactor is cycled to the conditioning tank before being returned to the activated sludge tank.
27. The method of claim 18, wherein the multivalent metal ions are selected from the group consisting of Mg and Ca .
28. The method of claim 18, wherein the phosphate solids comprise struvite.
29. The method of claim 1, wherein the activated sludge stream in the sidestream reactor has a pH of about 8 to about 10.
30. The method of claim 18, wherein the phosphate solids are separated from the sludge stream by mechanical means based upon differential settling velocity.
31. The method of claim 18, wherein the phosphate solids are separated from the activated sludge stream by at least one of a gravity separator, a hydrocyclone and a centrifuge.
32. The method of claim 18, wherein separating and removing the phosphate solids from the sludge steam occurs without significant removal of organic matter having a specific gravity less than that of the phosphate solids.
PCT/US2006/027736 2005-07-18 2006-07-18 Conditioning system for activated sludge wastewater treatment processes WO2007011890A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/161,846 US7993522B2 (en) 2006-01-25 2007-01-24 Conditioning system for activated sludge wastewater treatment processes
PCT/US2007/001815 WO2007089481A2 (en) 2006-01-25 2007-01-24 Conditioning system for activated sludge wastewater treatment processes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US70016605P 2005-07-18 2005-07-18
US60/700,166 2005-07-18

Publications (2)

Publication Number Publication Date
WO2007011890A2 true WO2007011890A2 (en) 2007-01-25
WO2007011890A3 WO2007011890A3 (en) 2007-11-22

Family

ID=37669478

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/027736 WO2007011890A2 (en) 2005-07-18 2006-07-18 Conditioning system for activated sludge wastewater treatment processes

Country Status (1)

Country Link
WO (1) WO2007011890A2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014022489A1 (en) * 2012-07-31 2014-02-06 R N Industries, Inc. Methods and systems for maintaining the temperature of wastewater in a treatment facility
US20150108065A1 (en) * 2013-10-22 2015-04-23 Jiangxi Jdl Environmental Protection Co., Ltd. Method for wastewater treatment
CN110436712A (en) * 2012-11-27 2019-11-12 汉普顿道路环境卫生区 Method and apparatus for the wastewater treatment for using weight to select
US20220162106A1 (en) * 2017-06-26 2022-05-26 Monsanto Technology Llc Phosphorus control for waste streams from glyphosate manufacturing processes
US11999641B2 (en) 2021-03-12 2024-06-04 Hampton Roads Sanitation District Method and apparatus for multi-deselection in wastewater treatment

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6830690B2 (en) * 2002-09-16 2004-12-14 Lawrence A. Schmid Two-stage high synthesis activated sludge system with intermediate bio-solids removal

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6830690B2 (en) * 2002-09-16 2004-12-14 Lawrence A. Schmid Two-stage high synthesis activated sludge system with intermediate bio-solids removal

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014022489A1 (en) * 2012-07-31 2014-02-06 R N Industries, Inc. Methods and systems for maintaining the temperature of wastewater in a treatment facility
CN110436712A (en) * 2012-11-27 2019-11-12 汉普顿道路环境卫生区 Method and apparatus for the wastewater treatment for using weight to select
US20150108065A1 (en) * 2013-10-22 2015-04-23 Jiangxi Jdl Environmental Protection Co., Ltd. Method for wastewater treatment
EP2865654A1 (en) * 2013-10-22 2015-04-29 Jiangxi JDL Environmental Protection Co., Ltd. Method for wastewater treatment
US20220162106A1 (en) * 2017-06-26 2022-05-26 Monsanto Technology Llc Phosphorus control for waste streams from glyphosate manufacturing processes
US11964892B2 (en) * 2017-06-26 2024-04-23 Monsanto Technology Llc Phosphorus control for waste streams from glyphosate manufacturing processes
US11999641B2 (en) 2021-03-12 2024-06-04 Hampton Roads Sanitation District Method and apparatus for multi-deselection in wastewater treatment

Also Published As

Publication number Publication date
WO2007011890A3 (en) 2007-11-22

Similar Documents

Publication Publication Date Title
US7344643B2 (en) Process to enhance phosphorus removal for activated sludge wastewater treatment systems
US7993522B2 (en) Conditioning system for activated sludge wastewater treatment processes
US8894857B2 (en) Methods and systems for treating wastewater
US7008538B2 (en) Single vessel multi-zone wastewater bio-treatment system
AU2011225849B2 (en) Method for the biological purification of ammonium-containing wastewater
AU731280B2 (en) Process, using ammonia rich water for the selection and enrichment of nitrifying micro-organisms for nitrification of wastewater
EP3863977B1 (en) Mainstream deammonification process employing bypass primary effluent and step feeding
EP2496531A1 (en) Simultaneous anoxic biological phosphorus and nitrogen removal
WO2011106621A2 (en) Hybrid aerobic and anaerobic wastewater and sludge treatment systems and methods
CN100348517C (en) Municipal wastewater treatment apparatus and process with a continuous feed and cyclic aeration
CN103068748A (en) Contact-stabilization/prime-float hybrid
US20160130164A1 (en) Devices, Systems and Methods for Facilitating Nutrient Removal by Anaerobic Ammonia Oxidation
KR19980051067A (en) Simultaneous Biological and Nitrogen Eliminators
WO2007011890A2 (en) Conditioning system for activated sludge wastewater treatment processes
CA2300719A1 (en) Membrane supported biofilm process
KR20210040632A (en) Wastewater treatment system using anaerobic ammonium oxidation system in mainstream of mwtp by nitrification reaction of various high concentration waste liquid and microorganism culture reinforcement
KR100517095B1 (en) Wastewater Treatment Apparatus and Method
CN105731619B (en) The processing method of nitrogen fertilizer production waste water
KR100416693B1 (en) Method for removing nutrients of domestic sewage using 2 step aeration and an apparatus used therefor
KR20020089085A (en) Apparatus for treating Nitrogen and Phosphorus in wastewater and A Treatment method thereof
KR100748596B1 (en) Waste water treatment apparatus using high concentrated organic compound comprising waste water and waste water treatment method using the apparatus
KR200172808Y1 (en) Bacteria group of bacillus spp in treating equipmentd for sewage and waste water
KR20040083123A (en) System and method for wastewater treatment using partition type anoxic basin and membrane basin
Chevakidagarn et al. Optimum Carbon/Nitrogen Ratio for upgrading single-stage activated sludge process in the Frozen Seafood Industry
KR20030076547A (en) Treatment system and Method for Purifying Wastewater using Media Separator

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 06787624

Country of ref document: EP

Kind code of ref document: A2