WO2006132974A1 - Préparation de soins personnels multiphasique comprenant une préparation de parfum de fleurs - Google Patents

Préparation de soins personnels multiphasique comprenant une préparation de parfum de fleurs Download PDF

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Publication number
WO2006132974A1
WO2006132974A1 PCT/US2006/021474 US2006021474W WO2006132974A1 WO 2006132974 A1 WO2006132974 A1 WO 2006132974A1 US 2006021474 W US2006021474 W US 2006021474W WO 2006132974 A1 WO2006132974 A1 WO 2006132974A1
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WIPO (PCT)
Prior art keywords
phase
personal care
care composition
composition according
cleansing
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PCT/US2006/021474
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English (en)
Inventor
Rebecca Ann Taylor
Karl Shiqing Wei
Jimmie Lee Ward
Robert Richard Dykstra
Julie Anne Mathews
Lois Sara Gallon
Zerlina Guzdar Dubois
Virginia Tzung-Hwei Hutchins
Jianjun Justin Li
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The Procter & Gamble Company
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Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to MX2007015458A priority Critical patent/MX2007015458A/es
Priority to EP06771966A priority patent/EP1888010A1/fr
Publication of WO2006132974A1 publication Critical patent/WO2006132974A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a structured personal care composition comprising a perfume composition.
  • Desirable personal care compositions are well known and widely used. Desirable personal care composition must meet a number of criteria. For example, in order to be acceptable to consumers, a personal care composition must exhibit good cleaning properties, must exhibit good lathering characteristics, must be mild to the skin (not cause drying or irritation) and preferably should even provide a conditioning benefit to the skin. Moreover, odor or scent is a product characteristic which drives consumer acceptance. Some consumers choose a personal care composition for both the odor of the product itself, as well as, the residual odor the composition leaves on the skin or hair. The product odor is the scent of the product in the bottle and the "bloom" or scent during use in the shower or bath. The residual odor is the scent of the product on the consumer's skin. Both are important to the consumers of personal care compositions.
  • Personal care compositions are known and widely used that have a product scent and leave a residual odor of the composition on the skin or hair.
  • some consumers apply after shower products such as, aftershave, colognes, cologne spray, perfumed lotions, or fine fragrances to intentionally leave a distinct residual scent on their skin and hair.
  • consumer prefer personal care compositions that exactly match, compliment or are not stronger than the after shower products.
  • some personal care compositions have strong residual scents that are very different from or stronger than a consumer's after shower product. These strong residual odors from the personal care composition sometime leave the consumer with more than one scent on their hair and skin which is not preferred.
  • One solution to this problem would be to not scent the personal care composition.
  • the multi-phase personal care composition comprises a first phase and a second phase.
  • the personal care composition comprises at least 0.25%, by weight of said multiphase personal care composition of blooming perfume ingredients having a KI of less than about 1500.
  • the blooming perfume compositions comprised of ingredients having a KI of less than about 1500, as disclosed herein, can be formulated into personal care compositions and provide a significantly noticeable scent in the shower to the consumer while leaving little to no residual perfume of the skin and hair.
  • ambient conditions refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25°C.
  • Kovat's Index (KI, or Retention Index) is defined by the selective retention of solutes or perfume raw materials (PRMs) onto a chromatographic column. It is primarily determined by the column stationary phase and the properties of solutes or PRMs. For a given column system, a PRM' s polarity, molecular weight, vapor pressure, boiling point and the stationary phase property determine the extent of retention. To systematically express the retention of an analyte on a given GC column, a measure called Kovat's Index (or retention index) is defined. Kovat's Index (KI) places the volatility attributes of an analyte (or PRM) on a column in relation to the volatility characteristics of n-alkane series on that column. Typical columns used are DB-5 and DB-I.
  • multi-phase or “multi-phase” as used herein, is meant that the phases of the present compositions occupy separate but distinct physical spaces inside the package in which they are stored, but are in direct contact with one another (i.e., they are not separated by a barrier and they are not emulsified or mixed to any significant degree).
  • the "multi-phase" personal care compositions can comprise at least two visually distinct phases which are present within the container as a visually distinct pattern. The pattern results from the combination of the "multi-phase” composition by a process herein described.
  • the "patterns” or “patterned” include but are not limited to the following examples: striped, marbled, rectilinear, interrupted striped, check, mottled, veined, clustered, speckled, geometric, spotted, ribbons, helical, swirl, arrayed, variegated, textured, grooved, ridged, waved, sinusoidal, spiral, twisted, curved, cycle, streaks, striated, contoured, anisotropic, laced, weave or woven, basket weave, spotted, and tessellated.
  • the pattern is selected from the group consisting of striped, geometric, marbled, and combinations thereof.
  • the phases may be various different colors, and/or include particles, glitter or pearlescent agents in at least one of the phases in order to offset its appearance from the other phase(s) present.
  • multi-phase personal care composition refers to compositions intended for topical application to the skin or hair.
  • personal care compositions include skin care lotions, in-shower body moisturizers, body washes, bar soaps, shampoos, and conditioners.
  • a phase is a structured phase, typically it has a Yield Stress of greater than about 0.1 Pascal (Pa), more preferably greater than about 0.5 Pa, even more preferably greater than about 1.0 Pa, still more preferably greater than about 2.0 Pa, still even more preferably greater than about 3 Pa, and even still even more preferably greater than about 5 Pa as measured by the Yield Stress and Zero Shear Viscosity Method described hereafter.
  • Pa Yield Stress
  • a phase When a phase is a structured phase, it may also typically have a Zero Shear Viscosity of at least about 500 Pascal-seconds (Pa-s), preferably at least about 1,000 Pa-s, more preferably at least about 1,500 Pa-s, even more preferably at least about 2,000 Pa-s.
  • Pa-s Pascal-seconds
  • a cleansing phase or a surfactant phase of the multi-phase composition of the present invention when structured, it has a Structured Domain Volume Ratio as measured by the Ultracentrifugation Method described hereafter, of greater than about 40%, preferably at least about 45%, more preferably at least about 50%, more preferably at least about 55%, more preferably at least about 60%, more preferably at least about 65%, more preferably at least about 70%, more preferably at least about 75%, more preferably at least about 80%, even more preferably at least about 85%.
  • surfactant component means the total of all anionic, nonionic, amphoteric, zwitterionic and cationic surfactants in a phase.
  • surfactant component water and electrolyte are excluded from the calculations involving the surfactant component, since surfactants as manufactured typically are diluted and neutralized.
  • a phase generally occupies a space or spaces having dimensions larger than the colloidal or sub- colloidal components it comprises.
  • a phase may also be constituted or re-constituted, collected, or separated into a bulk phase in order to observe its properties, e.g., by centrifugation, filtration or the like.
  • the multi-phase personal care composition comprises a first phase and a second phase.
  • the first phase comprises at least 0.25%, by weight of the composition, of blooming perfume ingredients having a Kovat's Index of less than about 1500.
  • the multi-phase personal care composition of the present invention is typically extrudable or dispensible from a package.
  • the multi-phase personal care compositions typically exhibit a viscosity of from about 1,500 centipoise (cP) to about 1,000,000 cP, as measured by the Viscosity Method as described in copending application serial number 10/841174 filed on May 7, 2004 titled "Multi-phase Personal Care Compositions.”
  • each individual phase is evaluated prior to combining, unless otherwise indicated in the individual methodology.
  • each phase can be separated by centrifugation, ultracentrifugation, pipetting, filtering, washing, dilution, concentration, or combination thereof, and then the separate components or phases can be evaluated.
  • the separation means is chosen so that the resulting separated components being evaluated is not destroyed, but is representative of the component as it exists in the multi-phase personal care composition, i.e., its composition and distribution of components therein is not substantially altered by the separation means.
  • multi-phase compositions comprise domains significantly larger than colloidal dimensions so that separation of the phases into the bulk is relatively easy to accomplish while retaining the colloidal or microscopic distribution of components therein.
  • the compositions of the present invention are rinse-off formulations, by which is meant the product is applied topically to the skin or hair and then subsequently (i.e., within minutes) the skin or hair is rinsed with water, or otherwise wiped off using a substrate or other suitable removal means with deposition of a portion of the composition.
  • the multi-phase personal care compositions of the present invention can comprise at least two visually distinct phases, wherein the composition can have a first structured phase, a second phase, a third phase, a fourth phase and so on.
  • the ratio of a first phase to a second phase is preferably from about 1 :99 to about 99:1, preferably from about 90:10 to about 10:90, more preferably from about 80:20 to about 20:80, even more preferably from about 70:30 to about 30:70, still even more preferably from about 60:40 to about 40:60, even still even more preferably about 50:50.
  • the preferred pH range of the multi-phase personal care composition is from about 5 to about 8.
  • Each phase could be one or more of the following nonlimiting examples including: a cleansing phase, a benefit phase, and a non-lathering structured aqueous phase, which are described in greater detail hereinafter.
  • the multi-phase composition comprises at least 0.25%, by weight of said personal care composition, of blooming perfume ingredients having a KI of less than about 1500. In some embodiments, the multi-phase composition comprises at least 0.35%, by weight of said personal care composition, of blooming perfume ingredients having a KI of less than about 1500. In other embodiments, the multi-phase composition comprises at least 0.40%, by weight of said personal care composition, of blooming perfume ingredients having a KI of less than about 1500.
  • the blooming perfume ingredients have a boiling point of less than about 260°C, a ClopP of from about 1.5 to about 4.0 preferably from about 2.0 to about 4.0, more preferably 2.3 from about to about 4.0, most preferably from about 2.5 to about 4.0. Examples of blooming ingredients are illustrated in Table 1.
  • the multi-phase, personal care composition comprising comprises a blooming perfume composition comprising preferably at least 20% by weight of the blooming perfume composition, more preferably at least 30% by weight of the blooming perfume composition, more preferably at least 50% by weight of the blooming perfume composition, more preferably at least 70% by weight of the blooming perfume composition, more preferably least 80% by weight of the blooming perfume composition, most preferably least 90% by weight of the blooming perfume composition., of blooming perfume ingredients KI of less than about 1500.
  • a blooming perfume ingredient is characterized by its boiling point (B.P.) and its octanol/water partition coefficient (P).
  • the octanol/water partition coefficient of a perfume ingredient is the ratio between its equilibrium concentrations in octanol and in water.
  • the preferred perfume ingredients of this invention have a B. P., determined at the normal, standard pressure of about 760 mm Hg, of about 260°C or lower, preferably less than about 255°C; and more preferably less than about 250°C, and an octanol/water partition coefficient P of about 1,000 or higher. Since the partition coefficients of the preferred perfume ingredients of this invention have high values, they are more conveniently given in the form of their logarithm to the base 10, logP.
  • the preferred perfume ingredients of this invention have ClogP at 25 0 C of about 1.5 to about 4.0, preferably from about 2.0 to about 4.0, more preferably from about 2.3 to about 4.0, and most preferably 2.5 - 4.0.
  • the boiling points of many perfume compounds can be found using the SciFinder (http://scifinder.cas.org/). When unreported, the 760 mm boiling points of perfume ingredients can be obtained through SciFinder where the calculated values of boiling point using Advanced Chemistry Development (ACD/Labs) Software Solaris V4.67 are listed.
  • ACD/Labs calculated boiling point values which are the most reliable and widely used estimates for this property, are preferably used instead of the experimental boiling point values in the selection of perfume ingredients which are useful in the present invention.
  • the logP of many perfume ingredients has been reported; for example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc. (Daylight CIS), Irvine, Calif, contains many, along with citations to the original literature. However, the logP values are most conveniently obtained through SciFinder where the calculated values of log P using Advanced Chemistry Development (ACD/Labs) Software Solaris V4.67 are listed. The ClogP values, which are the most reliable and widely used estimates for this physicochemical property, are preferably used instead of the experimental logP values in the selection of perfume ingredients which are useful in the present invention. The ClogP values were obtained through SciFinder where the calculated values of log P using Advanced Chemistry Development (ACD/Labs) Software Solaris V4.67 are listed.
  • the blooming perfume compositions of the present invention contain at least 5, preferably at least 6, more preferably at least 7, even more preferably at least 8 or 9 or even 10 or more different blooming perfume ingredients.
  • Most common perfume ingredients which are derived from natural sources are composed of a multitude of components. For example, orange terpenes contain about 90% to about 95% d-limonene, but also contain many other minor ingredients. When each such material is used in the formulation of blooming perfume compositions of the present invention, it is counted as one ingredient, for the purpose of defining the invention. Synthetic reproductions of such natural perfume ingredients are also comprised of a multitude of components and are counted as one ingredient for the purpose of defining the invention.
  • the blooming perfume ingredients have a gas chromatographic Kovat's Index (as determined on 5% phenyl-methylpolysiloxane as non-polar silicone stationary phase) of less than 1500.
  • the blooming perfume composition of the present invention can optionally contain "non-blooming" perfume ingredients.
  • the optional non-blooming perfume ingredients of this invention have a KI value greater than 1500, a boiling point measured at the normal, standard pressure, of about 260°C or higher, and a ClogP of greater than about 2.5.
  • KI value greater than 1500
  • boiling point measured at the normal, standard pressure
  • ClogP of greater than about 2.5.
  • Non-blooming perfume ingredients are used primarily in applications where the water will evaporate, thus liberating the perfume. Table 2 illustrates examples of non-blooming ingredients.
  • the multiphase composition comprises a total perfume composition is comprised of the blooming perfume ingredients and the non-blooming perfume ingredients (sum of blooming and non-blooming).
  • the weight percentage of blooming perfume ingredients is typically at least 10% by weight of the total perfume composition, at least about 20% by weight of the total perfume composition, preferably at least about 50% by weight of the total perfume composition and more preferably at 100% by weight of the total perfume composition.
  • auxiliary materials having no odor, or a low odor are used, e.g., as solvents, diluents, extenders or fixatives.
  • Non- limiting examples of these materials are ethyl alcohol, carbitol, dipropylene glycol, diethyl phthalate, triethyl citrate, isopropyl myristate, and benzyl benzoate. These materials are used for, e. g., solubilizing or diluting some solid or viscous perfume ingredients to, e. g., improve handling and/or formulating. These materials are useful in the blooming perfume compositions, but are not counted in the calculation of the limits for the definition/formulation of the blooming perfume compositions of the present invention.
  • the non-blooming perfume ingredients of present invention also comprise from about 0% to about 80%, preferably from about 10% to about 50%, more preferably from about 20% to about 40%, and most preferably from about 25% to about 35%, of non- blooming perfume ingredients having a KI value greater than 1500, a B.P. of more than about 260°C and having a ClogP of greater than about 2.5.
  • some non- blooming perfume ingredients can be used in small amounts, e.g., to improve overall perfume odor. These ingredients are particularly effective at masking base odors from surfactants and/or other detergent ingredients. When used at the low levels herein, an improved blooming perfume composition is obtained that betters masks base odors while still minimizing residual perfume on skin and hair.
  • the first phase or second phase of the multi-phase personal care composition of the present invention can be a cleansing phase.
  • the surfactant component comprises a mixture of surfactants.
  • the multi-phase personal care composition typically comprises from about 1 % to about 99 %, by weight of the composition, of said cleansing phase.
  • the surfactant component preferably comprises a lathering surfactant or a mixture of lathering surfactants.
  • the surfactant component comprises surfactants suitable for application to the skin or hair.
  • Suitable surfactants for use herein include any known or otherwise effective cleansing surfactant suitable for application to the skin, and which are otherwise compatible with the other essential ingredients in the multi-phase personal care composition including water.
  • These surfactants include anionic, nonionic, cationic, zwitterionic, amphoteric surfactants, soap, or combinations thereof.
  • anionic surfactant comprises at least 40% of the surfactant component, more preferably from about 45% to about 95% of the surfactant component, even more preferably from about 50% to about 90%, still more preferably from about 55% to about 85%, and even still most preferably at least about 60% of the surfactant component comprises anionic surfactant.
  • the multi-phase personal care composition preferably comprises a surfactant component at concentrations ranging from about 2% to about 40%, more preferably from about 3% to about 30%, even more preferably from about 4% to about 25%, still more preferably from about 5% to about 20%, still even more preferably from about 10% to about 20%, and even still even more preferably from about 15% to about 20%, by weight of the first phase.
  • the surfactant component is preferably a structured domain comprising surfactants.
  • the structured domain enables the incorporation of high levels of benefit components in a separate phase that are not emulsified in the composition.
  • the structured domain is an opaque structured domain.
  • the opaque structured domain is preferably a lamellar phase.
  • the lamellar phase produces a lamellar gel network.
  • the lamellar phase can provide resistance to shear, adequate yield to suspend particles and droplets and at the same time provides long term stability, since it is thermodynamically stable.
  • the lamellar phase tends to have a higher viscosity thus minimizing the need for viscosity modifiers.
  • the multi-phase, personal care composition typically provides a Total Lather Volume of at least about 600 ml, preferably greater than about 800ml, more preferably greater than about 1000ml, even more preferably greater than about 1200ml, and still more preferably greater than about 1500ml, as measured by the Lather Volume Test described hereafter.
  • the multi-phase, personal care composition preferably has a Flash Lather Volume of at least about 300 ml, preferably greater than about 400ml, even more preferably greater than about 500ml, as measured by the Lather Volume Test described hereafter.
  • Suitable surfactants are described in McCutcheon's, Detergents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation; and McCutcheon's, Functional Materials, North American Edition (1992); and in U.S. Patent 3,929,678 issued to Laughlin, et al on December 30, 1975.
  • Preferred linear anionic surfactants for use in the surfactant component of the multi-phase, personal care composition include ammonium lauryl sulfate, ammonium laureth sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, potassium lauryl sulfate, and combinations thereof.
  • Branched anioinc surfactants and monomethyl branched anionic surfactants suitable for the present invention are described in commonly owned U.S. Application Serial No. 60/680,149 entitled “Structured Multi-phased Personal Cleansing Compositions Comprising Branched Anionic Surfactants” filed on May 12, 2004 by Smith, et al.
  • Branched anionic surfactants include but are not limited to the following surfactants: sodium trideceth sulfate, sodium tridecyl sulfate, sodium C 12 - 13 alkyl sulfate, and C 12 - 13 pareth sulfate and sodium C 12 - 13 pareth-r ⁇ sulfate.
  • Branched surfactants can be derived from synthetic alcohols such as the primary alcohols from the liquid hydrocarbons produced by Fischer-Tropsch condensed syngas, for example Safol TM 23 Alcohol available from Sasol North America, Houston, TX; from synthetic alcohols such as Neodol TM 23 Alcohol available from Shell Chemicals, USA; from synthetically made alcohols such as those described in U.S. Patent No. 6,335,312 issued to Coffindaffer, et al on January 1, 2002.
  • Sulfates can be prepared by conventional processes to high purity from a sulfur based SO 3 air stream process, chlorosulfonic acid process, sulfuric acid process, or Oleum process. Preparation via SO 3 air stream in a falling film reactor is a preferred sulfation process.
  • Amphoteric surfactants suitable for use in the multi-phase, personal care composition include those that are broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water solubilizing group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
  • Examples of compounds falling within this definition are sodium 3-dodecyl-aniinopropionate, sodium 3-dodecylaminopropane sulfonate, sodium lauryl sarcosinate, and N-alkyltaurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of U.S. Patent No. 2,658,072 issued to Kosmin, et al. Amphoacetates and diamphoacetates, may also be used. Sodium lauroamphoacetate, sodium cocoamphoactetate, disodium lauroamphoacetate, and disodium cocodiamphoacetate are preferred in some embodiments.
  • Zwitterionic surfactants suitable for use in the multi-phase, personal care composition include those that are broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
  • zwitterionic surfactants suitable for use in the multi-phase, personal care composition include betaines, including high alkyl betaines such as, coco dimethyl carboxymethyl betaine, cocoamidopropyl betaine, cocobetaine. and carboxymethyl betaine.
  • Non-limiting examples of preferred nonionic surfactants for use herein are those selected form the group consisting OfC 8 -C 14 glucose amides, C 8 -C 14 alkyl polyglucosides, sucrose cocoate, sucrose laurate, alkanolamides, ethoxylated alcohols and mixtures thereof.
  • the nonionic surfactant is selected from the group consisting of glyceryl monohydroxystearate, steareth-2, isosteareth-2, hydroxy stearic acid, propylene glycol stearate, PEG-2 stearate, sorbitan monostearate, glyceryl stearate, glyceryl laurate, laureth-2, cocamide monoethanolamine, lauramide nionoethanolamine, and mixtures thereof.
  • anionic surfactants may be used in some embodiments, including mixtures of linear and branched surfactants, and anionic surfactants with nonionic, amphoteric, and/or zwitterionic surfactants.
  • the electrolyte can be added per se to the multi-phase personal care composition or it can be formed in situ via the counterions included in one of the raw materials.
  • the electrolyte preferably includes an anion comprising phosphate, chloride, sulfate or citrate and a cation comprising sodium, ammonium, potassium, magnesium or mixtures thereof.
  • Some preferred electrolytes are sodium chloride, ammonium chloride, sodium or ammonium sulfate.
  • the electrolyte is preferably added to the surfactant component of the composition in the amount of from about 0.1% to about 15% by weight, preferably from about 1% to about 6% by weight of the multi-phase personal care composition, but may be varied if required.
  • the multi-phase, personal care composition comprises a surfactant component comprising a mixture of at least one nonionic surfactant, at least one anionic surfactant and at least one amphoteric surfactant, and an electrolyte.
  • the surfactant can comprise a mixtures of surfactants, water, at least one anionic surfactant, an electrolyte, and at least one alkanolamide.
  • the amount of alkanolamide in the composition is typically from about 0.1% to about 10%, preferably from about 2% to about 5%, by weight of the cleansing phase.
  • the first phase or second phase of the multi-phase, personal care compositions of the present invention can be a benefit phase.
  • the benefit phase in the present invention is preferably anhydrous.
  • the benefit phase typically comprises hydrophobic materials.
  • the benefit phase comprises from about 1% to about 100%, preferably at least about 35%, most preferably at least about 50%, by weight of the benefit phase, of a hydrophobic material.
  • the hydrophobic materials suitable for use in the present invention preferably have a Vaughan Solubility Parameter of from about 5 to about 15 (cal/cm 3 ) 1/2 , as defined by Vaughan in Cosmetics and Toiletries, Vol. 103.
  • Non-limiting examples of hydrophobic materials having VSP values ranging from about 5 to about 15 include the following: Cyclomethicone 5.92, Squalene 6.03, Petrolatum 7.33, Isopropyl Palmitate 7.78, Isopropyl Myristate 8.02, Castor Oil 8.90, Cholesterol 9.55, as reported in Solubility, Effects in Product, Package, Penetration and Preservation, C D. Vaughan, Cosmetics and Toiletries, Vol. 103, October 1988.
  • the hydrophobic compositions are preferably selected among those having defined rheological properties as described hereinafter, including selected Consistency value (K) and Shear Index (n). These preferred rheological properties are especially useful in providing the multi-phase, personal care compositions with improved deposition of hydrophobic materials.
  • the benefit phase has a Consistency Value (K) from about 20 to about 2,000 Pa-s, preferably from about 25 to about 500 Pa-s, more preferably from about 30 to about 450 Pa-s, still more preferably from about 30 to about 400 Pa-s and even still more preferably from about 30 to about 350 Pa-s.
  • the benefit phase has a Shear Index from about 0.025 to about 0.99, preferably from about 0.05 to about 0.70 and more preferably from about 0.09 to about 0.60.
  • hydrophobic material suitable for use herein can include a variety of hydrocarbons, oils and waxes, silicones, fatty acid derivatives, cholesterol, cholesterol derivatives, diglycerides, triglycerides, vegetable oils, vegetable oil derivatives, acetoglyceride esters, alkyl esters, alkenyl esters, polyglycerin fatty acid esters, lanolin and its derivatives, wax esters, beeswax derivatives, sterols and phospholipids, and combinations thereof.
  • the benefit phase of the composition preferably can comprise one or more hydrophobic materials, wherein at least 1% by weight of the hydrophobic materials are selected from petrolatum, mineral oil, sunflower seed oil, alkyl siloxanes, polymethylsiloxanes and methylphenylpolysiloxanes, and combinations thereof. More preferably, at least about 20% by weight of the hydrophobic materials are selected from the groups of petrolatum, mineral oil, paraffins, polyethylene, polydecene, dimethicones, alkyl siloxanes, lanolins. More preferably, at least about 50% by weight of the hydrophobic materials are selected from the groups of petrolatum, mineral oil, paraffins, polyethylene, polydecene, dimethicones, alkyl siloxanes, lanolins.
  • the first phase or second phase of the multi-phase personal care compositions of the present invention can comprise a structured aqueous phase that comprises a water structurant and water.
  • the structured aqueous phase can be hydrophilic and in a preferred embodiment the structured aqueous phase is a hydrophilic, non-lathering gelled water phase.
  • the structured aqueous phase typically comprises less than about 5%, preferably less than about 3%, and more preferably less than about 1%, by weight of the structured aqueous phase, of a surfactant.
  • the structured aqueous phase is free of lathering surfactant in the formulation.
  • the structured aqueous phase of the present invention can comprise from about
  • the structured aqueous phase generally comprises more than about 50%, preferably more than about
  • the structured aqueous phase will typically have a pH of from about 5 to about 9.5, more preferably about 7.
  • a water structurant for the structured aqueous phase can have a net cationic charge, net anionic charge, or neutral charge.
  • the structured aqueous phase of the present compositions can further comprise optional ingredients such as, pigments, pH regulators (e.g. triethanolamine), and preservatives.
  • the structured aqueous phase can comprise from about 0.1% to about 30%, preferably from about 0.5% to about 20%, more preferably from about 0.5% to about 10%, and even more preferably from about 0.5% to about 5%, by weight of the structured aqueous phase, of a water structurant.
  • the water structurant is typically selected from the group consisting of inorganic water structurants, charged polymeric water structurants, water soluble polymeric structurants, associative water structurants, and mixtures thereof.
  • inorganic water structurants include silicas, polymeric gellants such as polyacrylates, polyacrylamides, starches, modified starches, crosslinked polymeric gellants, copolymers, and mixtures thereof.
  • Non-limiting examples of charged polymeric water structurants for use in the multi-phase personal care composition include Acrylates/Vinyl Isodecanoate Crosspolymer (Stabylen 30 from 3V), Acrylates/C 10-30 Alkyl Acrylate Crosspolymer (Pemulen TRl and TR2), Carbomers, Ammonium Acryloyldimethyltaurate/VP Copolymer (Aristoflex AVC from Clariant), Ammonium
  • Acryloyldimethyltaurate/Beheneth-25 Methacrylate Crosspolymer (Aristoflex HMB from Clariant), Acrylates/Ceteth-20 Itaconate Copolymer (Structure 3001 from National Starch), Polyacrylamide (Sepigel 305 from SEPPIC), and mixtures thereof.
  • water soluble polymeric structurants for use in the multi-phase personal care composition include cellulose gums and gel, and starches.
  • Non-limiting examples of associative water structurants for use in the multi-phase personal care composition include xanthum gum, gellum gum, pectins, alginates such as propylene glycol alginate, and mixtures thereof.
  • the phases of the multi-phase personal care composition can further comprise a polymeric phase structurant.
  • the compositions of the present invention typically can comprise from about 0.05% to about 10%, preferably from about 0.1% to about 4% and more preferably from about 0.2% to about 2% by weight of the phase, of a polymeric phase structurant.
  • Non-limiting examples of polymeric phase structurant include but is not limited to the following examples: deflocculating polymers, naturally derived polymers, synthetic polymers, crosslinked polymers, block polymers, block copolymers, copolymers, hydrophilic polymers, nonionic polymers, anionic polymers, hydrophobic polymers, hydrophobically modified polymers, associative polymers, oligomers, and copolymers thereof as described in U. S Patent Application No. 60/628,036 filed on November 15, 2003 by Wagner, et al titled "Depositable Solids.”
  • the polymeric phase structurant can be crosslinked.
  • the phase of the present compositions optionally can further comprise a liquid crystalline phase inducing structurant, which when present is at concentrations ranging from about 0.3% to about 15%, by weight of the phase, more preferably at from about 0.5% to about 5% by weight of the phase.
  • Suitable liquid crystalline phase inducing structurants include fatty acids (e.g.
  • the liquid crystalline phase inducing structurant is selected from lauric acid, trihydroxystearin, lauryl pyrrolidone, and tridecanol.
  • the multi-phase personal care compositions of the present invention can additionally comprise an organic cationic deposition polymer in the one or more phases as a deposition aid for the benefit agents described herein.
  • Suitable cationic deposition polymers for use in the compositions of the present invention contain cationic nitrogen- containing moieties such as quaternary ammonium or cationic protonated amino moieties.
  • the cationic protonated amines can be primary, secondary, or tertiary amines depending upon the particular species and the selected pH of the multi-phase personal care composition.
  • Suitable cationic deposition polymers that would be useful in the compositions of the present invention are disclosed in the co-pending and commonly assigned U.S. Patent Application No. 60/628,036 filed on November 15, 2003 by Wagner, et al titled "Depositable Solids.”
  • Nonlimiting examples of cationic deposition polymers for use in compositions include polysaccharide polymers, such as cationic cellulose derivatives.
  • Preferred cationic cellulose polymers are the salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 which are available from Amerchol Corp. (Edison, NJ. , USA) in their Polymer KG, JR and LR series of polymers with the most preferred being KG-30M.
  • CTFA trimethyl ammonium substituted epoxide
  • the multi-phase personal care composition of the present invention can comprise a particle.
  • a water insoluble particle of various shapes and densities can be useful.
  • the particle tends to have a spherical, an oval, an irregular, or any other shape in which the ratio of the largest dimension to the smallest dimension (defined as the Aspect Ratio) is less than about 10, preferably less than about 8, and still more preferably the Aspect Ratio of the particle is less than about 5.
  • the particle will also have physical properties which are not significantly affected by typical processing of the composition.
  • the multi-phase personal care composition of the present invention can comprise an exfoliant particle selected from the group consisting of polyethylene, microcrystalline wax, jojoba esters, oxyphors silica, talc, tracalcium orthophosphate, and mixtures thereof.
  • Exfoliant particles can be comprised in at least one phase of the multi-phase personal care composition at a level of less than about 10%, by weight of the composition.
  • the multi-phase personal care compositions of the present invention can comprise a shiny particle in at least one phase of the multi-phase personal care composition.
  • shiny particles include the following: interference pigment, multi-layered pigment, metallic particle, solid and liquid crystals, and combinations thereof.
  • An interference pigment is a pigment with pearl gloss prepared by coating the surface of a particle substrate material with a thin film.
  • Interference pigments and hydrophobically modified interference pigments that are suitable for use in the compositions of the present invention are those disclosed in U.S. Patent No. 6,395,691 issued to Liang Sheng Tsaur on May 28, 2002, U.S. Patent No. 6,645,511 issued to Aronson, et al., U.S. Patent No.
  • the multi-phase personal care composition of the present invention can comprise beads of any color and may be located in one or more phases of the of the multi-phase personal care composition.
  • Suitable beads include those known in the art, including soft and hard beads.
  • soft beads include Unispheres, made by Induchem, Unispheres NT-2806 (Pink).
  • hard beads include polyethylene or oxidized polyethylene, preferably those made by Accutech.
  • One or more of the phases of the multi-phase personal care composition can comprise a variety of additional optional ingredients.
  • Such optional ingredients are most typically those materials approved for use in cosmetics and that are described in reference books such as the CTFA Cosmetic Ingredient Handbook, Second Edition. The Cosmetic, Toiletries, and Fragrance Association, Inc. 1988, 1992.
  • vitamins and derivatives thereof e.g., ascorbic acid, vitamin E, tocopheryl acetate, and the like
  • sunscreens e.g., polyol alkoxy ester, available as Crothix from Croda
  • thickening agents e.g., polyol alkoxy ester, available as Crothix from Croda
  • preservatives for maintaining the anti microbial integrity of the cleansing compositions e.g., anti-acne medicaments (resorcinol, salicylic acid, and the like), antioxidants, skin soothing and healing agents such as aloe vera extract, allantoin and the like, chelators and sequestrants, skin lightening agents, and agents suitable for aesthetic purposes such as fragrances, essential oils, skin sensates, pigments, pearlescent agents (e.g., mica and titanium dioxide), lakes, colorings, and the like (e.g., clove oil, menthol, camphor, eucalyptus oil, and eugenol).
  • the Yield Stress and Zero Shear Viscosity of a phase of the present composition can be measured either prior to combining in the composition, or after combining in the composition by separating the phase by suitable physical separation means, such as centrifugation, pipetting, cutting away mechanically, rinsing, filtering, or other separation means.
  • a controlled stress rheometer such as a TA Instruments AR2000 Rheometer is used to determine the Yield Stress and Zero Shear Viscosity. The determination is performed at 25°C with the 4 cm diameter parallel plate measuring system and a 1 mm gap. The geometry has a shear stress factor of 79580 m '3 to convert torque obtained to stress.
  • phase is obtained and placed in position on the rheometer base plate, the measurement geometry (upper plate) moving into position 1 mm above the base plate. Excess phase at the geometry edge is removed by scraping after locking the geometry. If the phase comprises particles discernible to the eye or by feel (beads, e.g.) which are larger than about 150 microns in number average diameter, the gap setting between the base plate and upper plate is increased to the smaller of 4 mm or 8-fold the diameter of the 95 th volume percentile particle diameter. If a phase has any particle larger than 5 mm in any dimension, the particles are removed prior to the measurement.
  • the determination is performed via the programmed application of a continuous shear stress ramp from 0.1 Pa to 1,000 Pa over a time interval of 5 minutes using a logarithmic progression, i.e., measurement points evenly spaced on a logarithmic scale. Thirty (30) measurement points per decade of stress increase are obtained. Stress, strain and viscosity are recorded. If the measurement result is incomplete, for example if material flows from the gap, results obtained are evaluated and incomplete data points excluded.
  • the Yield Stress is determined as follows. Stress (Pa) and strain (unitless) data are transformed by taking their logarithms (base 10). Log(stress) is graphed vs. log(strain) for only the data obtained between a stress of 0.2 Pa and 2.0 Pa, about 30 points.
  • a predicted value of log(strain) is obtained using the coefficients m and b obtained, and the actual stress, using Equation (1).
  • a predicted strain at each stress is obtained by taking the antilog (i.e., 10 x for each x). The predicted strain is compared to the actual strain at each measurement point to obtain a %variation at each point, using Equation (2).
  • the Yield Stress is the first stress (Pa) at which %variation exceeds 10% and subsequent (higher) stresses result in even greater variation than 10% due to the onset of flow or deformation of the structure.
  • the Zero Shear Viscosity is obtained by taking a first median value of viscosity in Pascal-seconds (Pa-sec) for viscosity data obtained between and including 0.1 Pa and the Yield Stress. After taking the first median viscosity, all viscosity values greater than 5-fold the first median value and less than 0.2x the median value are excluded, and a second median viscosity value is obtained of the same viscosity data, excluding the indicated data points. The second median viscosity so obtained is the Zero Shear Viscosity.
  • Lather volume of a cleansing phase, a surfactant component or a structured domain of a multi-phase personal care composition is measured using a graduated cylinder and a rotating apparatus.
  • a 1,000 ml graduated cylinder is used which is marked in 10 ml increments and has a height of 14.5 inches at the 1,000 ml mark from the inside of its base (for example, Pyrex No. 2982).
  • Distilled water 100 grams at 25 0 C) is added to the graduated cylinder.
  • the cylinder is clamped in a rotating device, which clamps the cylinder with an axis of rotation that transects the center of the graduated cylinder.
  • the first lather volume the lowest height at which it is possible to see halfway across the graduated cylinder. If the lather is so coarse that a single or only a few foam cells which comprise the lather ("bubbles") reach across the entire cylinder, the height at which at least 10 foam cells are required to fill the space is the first lather volume, also in ml up from the base. Foam cells larger than one inch in any dimension, no matter where they occur, are designated as unfilled air instead of lather.
  • Foam that collects on the top of the graduated cylinder but does not drain is also incorporated in the measurement if the foam on the top is in its own continuous layer, by adding the ml of foam collected there using a ruler to measure thickness of the layer, to the ml of foam measured up from the base.
  • the maximum lather height is 1,000 ml (even if the total lather height exceeds the 1,000 ml mark on the graduated cylinder).
  • a second rotation sequence is commenced which is identical in speed and duration to the first rotation sequence.
  • the second lather volume is recorded in the same manner as the first, after the same 15 seconds of drainage time.
  • a third sequence is completed and the third lather volume is measured in the same manner, with the same pause between each for drainage and taking the measurement.
  • the Flash Lather Volume is the result after the first rotation sequence only, in ml, i.e., the first lather volume.
  • Compositions according to the present invention perform significantly better in this test than similar compositions in conventional emulsion form.
  • Ultracentrifu g ation Method The Ultracentrifugation Method is used to determine the percent of a structured domain or an opaque structured domain that is present in a multi-phase personal care composition that comprises a cleansing phase comprising a surfactant component. The method involves the separation of the composition by ultracentrifugation into separate but distinguishable layers.
  • the multi-phase personal care composition of the present invention can have multiple distinguishable layers, for example a non-structured surfactant layer, a structured surfactant layer, and a benefit layer.
  • the relative phase volume by measuring the height of each layer visually using an Electronic Digital Caliper (within 0.01mm).
  • H a the total height
  • H b the height of the benefit layer
  • H 0 the structured surfactant layer
  • the benefit layer is determined by its low moisture content (less than 10% water as measured by Karl Fischer Titration). It generally presents at the top of the centrifuge tube.
  • the total surfactant layer height (H 8 ) can be calculated by this equation:
  • the structured surfactant layer components may comprise several layers or a single layer.
  • This clear isotropic layer typically represents the non-structured micellar surfactant layer.
  • the layers above the isotropic phase generally comprise higher surfactant concentration with higher ordered structures (such as liquid crystals). These structured layers are sometimes opaque to naked eyes, or translucent, or clear. There is generally a distinct phase boundary between the structured layer and the non-structured isotropic layer.
  • the physical nature of the structured surfactant layers can be determined through microscopy under polarized light.
  • the structured surfactant layers typically exhibit distinctive texture under polarized light.
  • Structured surfactant layer display multiple lines that are often associated primarily with the long spacings of the liquid crystal structure. There may be several structured layers present, so that H c is the sum of the individual structured layers. If a coacervate phase or any type of polymer-surfactant phase is present, it is considered a structured phase.
  • H s H a .
  • the multi-phase personal care compositions of the present invention are preferably applied topically to the desired area of the skin or hair in an amount sufficient to provide effective delivery of the skin cleansing agent, hydrophobic material, and particles to the applied surface.
  • the compositions can be applied directly to the skin or indirectly via the use of a cleansing puff, washcloth, sponge or other implement.
  • the compositions are preferably diluted with water prior to, during, or after topical application, and then subsequently the skin or hair rinsed or wiped off, preferably rinsed off of the applied surface using water or a water-insoluble substrate in combination with water.
  • the present invention is therefore also directed to methods of cleansing the skin through the above-described application of the compositions of the present invention.
  • the multi-phase personal care compositions of the present invention may be prepared by any known or otherwise effective technique, suitable for making and formulating the desired multi-phase product form. It is effective to combine toothpaste-tube filling technology with a spinning stage design. Additionally, the present invention can be prepared by the method and apparatus as disclosed in U.S. Patent No. 6,213,166 issued to
  • the method and apparatus allows two or more compositions to be filled in a spiral configuration into a single container using at least two nozzles which fill the container, which is placed on a static mixer and spun as the composition is introduced into the container.
  • the present invention can be prepared by a method disclosed in commonly owned U.S. Patent Application No. 10/837,214 Publication No. 2004/0219119 Al entitled "Visually distinctive multiple liquid phase compositions" filed by Wei, et al. on April 30, 2004, published on November 18, 2004.
  • the method and apparatus allows two separate compositions to be combined in predetermined amounts, blended into a single resultant composition with visually distinct phases, and filled by one nozzle into a single container that is lowered and rotated during filling. .
  • the multi-phase personal care compositions are patterned, it can be desirable to package these compositions in a transparent or translucent package such that the consumer can view the pattern through the package. Because of the viscosity of the subject compositions it may also be desirable to include instructions to the consumer to store the package upside down, on its cap to facilitate dispensing.
  • the compositions described above can be prepared by conventional formulation and mixing techniques.
  • the lathering cleansing phase composition can be prepared by forming the following premixes: adding citric acid into water at 1 :1 ratio to form a citric acid premix, add polyox WSR-301 into glycerin at 1 :3 ratio to form a polyox-glycerin premix, and add cosmetic pigment into glycerin at 1 :20 ratio to form a pigment-glycerin premix and mix well using a high shear mixer. Then, add the following ingredient in the main mixing vessel in the following sequence: water, polyox premix, citric acid premix, disodium EDTA, and Mira ⁇ are SLB-365.
  • the non-lathering structured phase (Ex 1) can be prepared by slowly adding
  • the non-lathering structured phase (Ex 2) can be prepared by adding petrolatum into a mixing vessel. Heat the vessel to 88C. Then add mineral oil with agitation. Once homogenous, allow the vessel to cool down with slow agitation.
  • the lathering cleansing and non-lathering structured aqueous phases can be combined by first placing the separate phases in separate storage tanks having a pump and a hose attached. The phases are then pumped in predetermined amounts into a single combining section. Next, the phases are moved from the combining sections into the blending sections and the phases are mixed in the blending section such that the single resulting product exhibits a distinct pattern of the phases. The pattern is selected from the group consisting of striped, marbled, geometric, and mixtures thereof. The next step involves pumping the product that was mixed in the blending section via a hose into a single nozzle, then placing the nozzle into a container and filing the container with the resulting product.
  • the stripe size is about 6 mm in width and 100 mm in length.
  • NA2-S Commercially available under the tradename D&C Violet 2.
  • the first and second phases of the multiphase personal care composition exemplified above are both opaque.
  • the viscosity of the first phase of the in-shower body lotion is about 8,500 Pa-s.
  • the viscosity of the second phase of the in-shower body lotion is about 8,000 Pa-s.
  • the first and second phases are both oil-in-water emulsions and are both non-Newtonian.
  • the first and second phases are combined as described below and form a visually distinct striped pattern.
  • the multi-phase personal care composition exemplified above which is an in- shower body lotion, is made by separately making the first phase and the second phase, and then combining them according to the process described in US 2004/0219119 Al (Case 9218) to form the finished multi-phase personal care composition.
  • the first phase is made according to the following procedure. Add about 300 grams of water to a first beaker and heat the water to about 85-90 0 C. In a second beaker, add about 66 grams of melted petrolatum and heat to about 85-90 0 C. Add about 7.2 grams of POLAWAX to the second beaker and mix. Add about 10.5 grams of STRUCTURE XL to the second beaker and mix.
  • the second phase is made according to the following procedure. Add about 300 grams of water to a third beaker and heat the water to about 85-9O 0 C. In a fourth beaker, add about 66 grams of melted petrolatum and heat to about 85-9O 0 C. Add about 0.008 grams of colorant to the fourth beaker and mix until the colorant is dissolved in the petrolatum. Add about 7.2 grams of POLAWAX to the fourth beaker and mix. Add about 10.5 grams of STRUCTURE XL to the fourth beaker and mix. Take about 199.884 grams of heated water from the third beaker, add it to the fourth beaker, and mix.
  • the first and second phases combined to form a multi-phase personal care composition according to a process similar to that described in U.S. Patent Application No. 10/837,214 Publication No. 2004/0219119 Al entitled "Visually distinctive multiple liquid phase compositions" filed by Wei, et al. on April 30, 2004, published on November 18, 2004, except that a static mixer is not utilized.
  • the first phase is pumped from the first storage tank into a receiving cavity.
  • the second phase is pumped from the second storage tank into the same receiving cavity.
  • the first and second phases are then pumped out of the receiving cavity and through a filling nozzle to form the multi-phase personal care composition.
  • a plastic bottle, or other package is placed directly underneath the filling nozzle to receive the multi-phase personal care composition from the filling nozzle.
  • the plastic bottle is positioned on a bottle holding stand that lowers and rotates the bottle during filling.
  • the bottle holding stand lowers and rotates the bottle during filling at about 250 rpm.
  • the process is complete.
  • the phases in the multi-phase personal care composition form a visually distinct pattern.
  • AMIDO AMINE MPS obtained from Nikko;
  • L-glutamic acid L-GLUTAMIC ACID (cosmetic grade) obtained from Ajinomoto; 5(5) Cetyl Alcohol: KONOL series obtained from New Japan Chemical;
  • Examples 7 of cleansing phase by first creating the following premixes: citric acid in water premix at about 1 :3 ratio, Guar polymer premix with N-Hance 3196 in water at about 1 :10 ratio, and Polyox premix with PEG-14M in Glycerin at about 1 :2 ratio. Then, add the following ingredients into the main mixing vessel: ammonium lauryl sulfate, ammonium laureth-3 sulfate, citric acid premix, Miranol L-32 ultra, sodium chloride, sodium benzoate, disodium EDTA, lauric acid, Thixcin R, Guar premix, Polyox Premix, Monasil PLN, and the rest of water.
  • Cleansing Phase /Benefit Phase Compositions In an appropriate vessel, add distilled water and stir at an appropriate speed (100- 200 ppm) using an appropriate sized stir blade. If needed, add the anionic polymer (Carbopol Aqua SF-I), cationic polymers (Polyquaternium-10, Polycare 133) and stir briefly and slowly to wet and disperse the polymer. While continuing to stir, if needed, add the citiric acid solution (50%) drop wise to the mix vessel to reduce pH until solution becomes clear. Add surfactants (ALS, AE3S, CAPB 3 ) to the mixture. Heat the mixture to 6O 0 C and while stirring add CMEA 5 EGDS, and Cetyl alcohol to the mixture. Mix until homogeneous.
  • anionic polymer Carbopol Aqua SF-I
  • cationic polymers Polyquaternium-10, Polycare 133
  • citiric acid solution 50%) drop wise to the mix vessel to reduce pH until solution becomes clear.
  • surfactants ALS, AE3
  • Match the densities of the cleansing and benefit phases within 0.05 g/cm 3 Combine these phases by first placing the separate phases in separate storage tanks having a pump and a hose attached. Then, pump the phases in predetermined amounts into a single combining section. Next, move the phases from the combining sections into blending sections and mix the phases in the blending section such that the single resulting product exhibits a distinct pattern of phases. Next, pump the product that was mixed in the blending section via a hose into a single nozzle into a spinning container, and fill the container from the bottom to the top with the resulting product.
  • Combine these phases by first placing the separate phases in separate storage tanks having a pump and a hose attached. Then, pump the phases in predetermined amounts into a single combining section. Next, move the phases from the combining sections into blending sections and mix the phases in the blending section such that the single resulting product exhibits a distinct pattern of phases. Select the pattern from the group consisting of striped, marbled, geometric, and mixtures thereof. Next, pump the product that was mixed in the blending section via a hose into a single nozzle into a spinning container, and fill the container from the bottom to the top with the resulting product.

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Abstract

La présente invention décrit une préparation de soins personnels multiphasique qui comprend une première phase et une seconde phase. Ladite préparation de soins personnels comprend au moins 0,25 % en masse, par rapport à la masse totale de la préparation, de composants de parfum de fleurs dont le KI est inférieur à environ 1500.
PCT/US2006/021474 2005-06-07 2006-06-02 Préparation de soins personnels multiphasique comprenant une préparation de parfum de fleurs WO2006132974A1 (fr)

Priority Applications (2)

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MX2007015458A MX2007015458A (es) 2005-06-07 2006-06-02 Composicion para el cuidado personal de fases multiples que comprenden una composicion perfumada.
EP06771966A EP1888010A1 (fr) 2005-06-07 2006-06-02 Préparation de soins personnels multiphasique comprenant une préparation de parfum de fleurs

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WO2009121757A2 (fr) * 2008-04-04 2009-10-08 Unilever Plc Savonnette d’hygiène personnelle

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CN102293604A (zh) * 2011-07-20 2011-12-28 天津鎏虹科技发展有限公司 采用天然植物清洗剂制作湿巾的方法
CN107530245B (zh) * 2015-04-23 2021-05-04 宝洁公司 浓缩型个人清洁组合物和用途
MX369415B (es) 2015-04-23 2019-11-07 Procter & Gamble Composiciones de limpieza personal concentradas.
CN107530248B (zh) 2015-04-23 2021-03-12 宝洁公司 浓缩型个人清洁组合物及方法
CN107530249B (zh) 2015-04-23 2021-09-07 宝洁公司 浓缩型个人清洁组合物及方法
CN108348783B (zh) * 2015-11-17 2021-05-14 荷兰联合利华有限公司 氯咪巴唑微囊和包含表面活性剂和氯咪巴唑的毛发护理组合物
EP3528777B1 (fr) 2016-10-21 2021-09-01 The Procter & Gamble Company Compositions de nettoyage de la peau et procédés
US11185486B2 (en) 2016-10-21 2021-11-30 The Procter And Gamble Company Personal cleansing compositions and methods
US10675231B2 (en) 2017-02-17 2020-06-09 The Procter & Gamble Company Packaged personal cleansing product

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WO2004041219A2 (fr) * 2002-11-01 2004-05-21 The Procter & Gamble Company Compositions hygieniques de rinçage contenant des particules polymeres anioniques et/ou non ioniques de parfum
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WO2007052224A2 (fr) * 2005-11-01 2007-05-10 The Procter & Gamble Company Composition de soins personnels multiphase renfermant une composition de parfum stabilisante
WO2007052224A3 (fr) * 2005-11-01 2007-11-15 Procter & Gamble Composition de soins personnels multiphase renfermant une composition de parfum stabilisante
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