WO2006116778A2 - Prophylactic materials - Google Patents

Prophylactic materials Download PDF

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Publication number
WO2006116778A2
WO2006116778A2 PCT/ZA2006/000062 ZA2006000062W WO2006116778A2 WO 2006116778 A2 WO2006116778 A2 WO 2006116778A2 ZA 2006000062 W ZA2006000062 W ZA 2006000062W WO 2006116778 A2 WO2006116778 A2 WO 2006116778A2
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WO
WIPO (PCT)
Prior art keywords
prophylactic material
prophylactic
product
oil
benzalkonium chloride
Prior art date
Application number
PCT/ZA2006/000062
Other languages
French (fr)
Other versions
WO2006116778A3 (en
Inventor
Douglas James Sutherland
Original Assignee
Douglas James Sutherland
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Filing date
Publication date
Application filed by Douglas James Sutherland filed Critical Douglas James Sutherland
Publication of WO2006116778A2 publication Critical patent/WO2006116778A2/en
Publication of WO2006116778A3 publication Critical patent/WO2006116778A3/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/03—Algae
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/18—Euphorbiaceae [Spurge family], e.g. ricinus [castorbean]
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • This invention relates to prophylactic materials.
  • the invention is concerned with the prophylactic material for the prevention or inhibiting of disease in animals such as pigs and chickens and similar animals.
  • a prophylactic material comprising a carrier, a repellent, a disinfectant, and an anti-viral anti-bactericide, in an alcohol solution.
  • the anti-viral bactericide preferably comprises benzalkonium chloride.
  • Benzalkonium chloride may form part of a halogenated tertiary amine.
  • a convenient form of such amine has the commercial name "DAI”.
  • This product comprises polymeric (hexamethylene) biguanide hydrochloride, benzalkonium chloride and didecyl dimethyl ammonium chloride as active ingredients together with a surfactant, a nano-emulsion surfactant, a sequestriant, a solubiliser an anti oxidant, a preservative and emollument and demineralised water and solubilisers.
  • the benzalkonium chloride normally comprises 2,5% of the DAI; the polymeric (hexamethylene) biguanide hydrochloride 10% and the didecyl dimethyl ammonium chloride 5%.
  • the product material comprises castor oil, preferably a first pressing, as the carrier; citronella oil as a repellent, DAI as an antiviral, bactericide and fungicide, ethyl alcohol as an emulsifier and pine oil acting as a disinfectant.
  • the DAI preferably comprises between 1 ,5% and 4,5% and preferably 3% of the product. (All proportions herein are v/v.)
  • the castor oil is between 30% and 40% and preferably 34% of the product.
  • the citronella oil is between 1,5% and 3,5%; the ethyl alcohol is between 20% and 30% and the pine oil is 33% to 40% of the constituents of the product.
  • additional benzalkonium chloride may also be added.
  • the benzalkonium chloride as well as the didecyl dimethyl ammonium chloride conveniently comprises in total between 0,02% to 2,0% of the constituents, and preferably between 0,4% and 1,5% and more preferably between 0,015% and 1 ,45% of the constituents.
  • the additional constituent comprise tea tree oil which should be pharmacy grade product.
  • the tea tree oil may constitute between 0,1% to 3% of the total constituents and preferably about 2% of the product.
  • the material may further comprise chlorhexidine.
  • the chlorhexidine can be added in the form of Hibitane which is manufactured by Zeneca and which is a 2% aqueous solution of chlorhexidine.
  • benzalkonium chloride constituent of the above product is about 0.075%.
  • benzalkonium chloride constituent of the above product is about 1 ,075%.
  • EXAMPLE 4 The product of Example 1 above was used to treat a growth room containing ten pens each containing twenty three birds as follows. After the chickens in the growth room were removed, the room was cleaned with a commercial disinfectant. Wooden shavings were placed on the floor of the room to a height of about two centimetres. Shortly before the birds - day old chicks - arrived, the floor of the growth room was sprayed with the product of Example 1 at about 1 litre per 20 metres 2 . The day old chicks were placed on to the shavings.
  • a control test in a similar growth room was prepared and disinfected as abovementioned but the shavings were not so sprayed.
  • the product has also been found to be most satisfactory in fighting the following in pigs when applied to the floor of the piggery with about one litre per twenty metres, i.e. Clostridium perfringens, streptococcus suis II, bordetella, bronchis epticum and pasteurella multocida.
  • Example 1 The product of Example 1 further has the characteristic that the constituents will not separate out. I have found that the products have a working life of forty five days without separation.
  • the active ingredients will rise to about one and a half metres or under certain circumstances up to the ceiling of the growth room.
  • the active ingredients will be absorbed in the mucous membrane of the birds. This and generally because the active ingredients are at the above height will protect the birds against bacteria etc.
  • the invention is not limited to the precise constituents described above.
  • the amount of DAI may be reduced to say 1,5% with the Pine Oil constituent correspondingly increased.
  • the amount of DAI may comprise about 4,5% with or without the additional benzalkonium chloride.
  • the benzalkonium chloride constituent will comprise between about 0,1125% to about 1 ,676% of the product.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Pest Control & Pesticides (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

A prophylactic material for use in animal shelters and in particular piggeries and chicken housing for the protection of the animals is described. The prophylactic material comprises a carrier, a repellent, a disinfectant, and an anti-viral anti-bactericide, in an alcohol solution including alkyl dimethyl benzyl ammonium chloride (benzalkonium chloride). The material may further comprise tea tree oil.

Description

PROPHYLACTIC MATERIALS
This invention relates to prophylactic materials.
The invention is concerned with the prophylactic material for the prevention or inhibiting of disease in animals such as pigs and chickens and similar animals.
In the specification of South African Patent No. 1999/5234 there is described a particular prophylactic material. This comprises an aqueous solution of a carrier (consisting of Seaweed Oil, and Castor Oil), a disinfectant (comprising pine oil), a repellant (consisting of Camphor Oil and Citronella Oil), a binder (comprising Kotillen Ll Oil) and broad spectrum anti virals and bactericides (comprising Chlorohexiden, Delvosid, SH 12/18 and Distilled Water). Although this material is relatively satisfactory, I have found that the material can be significantly improved especially for use with chicken batteries but also for piggeries.
According to one aspect of the invention, there is provided a prophylactic material comprising a carrier, a repellent, a disinfectant, and an anti-viral anti-bactericide, in an alcohol solution. The anti-viral bactericide preferably comprises benzalkonium chloride. Benzalkonium chloride may form part of a halogenated tertiary amine. A convenient form of such amine has the commercial name "DAI". This product comprises polymeric (hexamethylene) biguanide hydrochloride, benzalkonium chloride and didecyl dimethyl ammonium chloride as active ingredients together with a surfactant, a nano-emulsion surfactant, a sequestriant, a solubiliser an anti oxidant, a preservative and emollument and demineralised water and solubilisers. The benzalkonium chloride normally comprises 2,5% of the DAI; the polymeric (hexamethylene) biguanide hydrochloride 10% and the didecyl dimethyl ammonium chloride 5%. One detailed description of the DAI is given below. Preferably the product material comprises castor oil, preferably a first pressing, as the carrier; citronella oil as a repellent, DAI as an antiviral, bactericide and fungicide, ethyl alcohol as an emulsifier and pine oil acting as a disinfectant. The DAI preferably comprises between 1 ,5% and 4,5% and preferably 3% of the product. (All proportions herein are v/v.)
Conveniently the castor oil is between 30% and 40% and preferably 34% of the product. The citronella oil is between 1,5% and 3,5%; the ethyl alcohol is between 20% and 30% and the pine oil is 33% to 40% of the constituents of the product.
If desired additional benzalkonium chloride may also be added. The benzalkonium chloride as well as the didecyl dimethyl ammonium chloride conveniently comprises in total between 0,02% to 2,0% of the constituents, and preferably between 0,4% and 1,5% and more preferably between 0,015% and 1 ,45% of the constituents. Preferably however the additional constituent comprise tea tree oil which should be pharmacy grade product. The tea tree oil may constitute between 0,1% to 3% of the total constituents and preferably about 2% of the product.
The material may further comprise chlorhexidine. The chlorhexidine can be added in the form of Hibitane which is manufactured by Zeneca and which is a 2% aqueous solution of chlorhexidine.
A number of non-limiting examples will now be described by way of illustration. EXAMPLE 1
Constituent Percentage
Castor Oil 34,0
Citronella Oil 2,5
DAI 3,0
Ethyl alcohol 25,0
Pine Oil 34,5
Tea Tree Oil 2,0
100,0
It will be seen that the benzalkonium chloride constituent of the above product is about 0.075%.
EXAMPLE 2
Constituent Percentage
Castor Oil 34,5
Citronella Oil 2,5 DAI 3,0
Ethyl alcohol 25,0
Pine oil 35,5
100,0
It will be seen that the benzalkonium chloride constituent of the above product is about 0.075%. EXAMPLE 3
Constituent Percentage
Benzalkonium Chloride 1,0
Castor Oil 34,5
Citronella Oil 2,5
DAI 3,0
Ethyl alcohol 25,0
Pine oil 34,5
100,0
It will be seen that the benzalkonium chloride constituent of the above product is about 1 ,075%.
EXAMPLE 4 The product of Example 1 above was used to treat a growth room containing ten pens each containing twenty three birds as follows. After the chickens in the growth room were removed, the room was cleaned with a commercial disinfectant. Wooden shavings were placed on the floor of the room to a height of about two centimetres. Shortly before the birds - day old chicks - arrived, the floor of the growth room was sprayed with the product of Example 1 at about 1 litre per 20 metres2. The day old chicks were placed on to the shavings.
A control test in a similar growth room was prepared and disinfected as abovementioned but the shavings were not so sprayed.
In both growth rooms the same temperature was applied and the birds were provided with the same feed stuff being a mashed starter diet for the first three weeks and a pelleted grower diet until forty days. It was found that the birds in the test room ingested more foodstuff than the birds in the control room. Thus the average mass of the birds in the growth room was greater than that in the control room.
The products mentioned in the examples above were tested in in vitro assay against poultry bacteria in the presence of 300 ppm C3CO3 and 1% skimmed milk. It was found that these products had considerable success in combatting Newcastle's disease and destroying the bacteria of Avian flu infections, Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Salmonella Enteritidis, Ornithobacterium rhinotracheale and Haemophilus paragallinarum.
The product has also been found to be most satisfactory in fighting the following in pigs when applied to the floor of the piggery with about one litre per twenty metres, i.e. Clostridium perfringens, streptococcus suis II, bordetella, bronchis epticum and pasteurella multocida.
The product of Example 1 further has the characteristic that the constituents will not separate out. I have found that the products have a working life of forty five days without separation.
I have also found that due to the presence of the oils in the products, in the heat of the growth rooms, the active ingredients will rise to about one and a half metres or under certain circumstances up to the ceiling of the growth room. The active ingredients will be absorbed in the mucous membrane of the birds. This and generally because the active ingredients are at the above height will protect the birds against bacteria etc. The invention is not limited to the precise constituents described above. For example the amount of DAI may be reduced to say 1,5% with the Pine Oil constituent correspondingly increased. Alternatively the amount of DAI may comprise about 4,5% with or without the additional benzalkonium chloride. Here the benzalkonium chloride constituent will comprise between about 0,1125% to about 1 ,676% of the product.
Detailed list of constituents of DAI
Constituent Composi- Function tion %
Polymeric biguanide hydrochloride 10,0 Active
Alkyl Dimethyl benzyl ammonium chloride (benzalkonium Chloride) 2,5 Active
didecyl Dimethyl Ammonium Chloride 5,0 Active
c9-cl 1 Alcohol ethoxylate 6,0 Surfactant
Disodium Ethylenediaminetetraacetate (EDTA) 2,0 Sequestriant
Isopropanol 5,0 Solubiliser
Butyl hydroxy toluene 0,1 anti-oxidant
5-chloro-2-methyl-3(2h)-isothiazolone with 2 methyl- 3(2h)-isothiazolone ethane-diyl-bis(oxy)-bismethanol
0,3 preservative
Grapefruit seed extract 0,1 emolluent
Trimethylsilyamodimethicone 0,1 nano-emulsion C-1 1-15 Pareth-5 surfactant C-11-15 Pareth-9
Dye as required Q.S. Colour
Fragrance (as required) Q.S. Fragrance
Demineralised water Balance Solubiliser

Claims

1. A prophylactic material comprising a carrier, a repellent, a disinfectant, and an anti-viral anti-bactericide, in an alcohol solution.
2. A prophylactic material as claimed in claim 1 wherein the anti-viral bactericide comprises benzalkonium chloride.
3. A prophylactic material as claimed in claim 2 wherein the benzalkonium chloride forms part of a halogenated tertiary amine.
4 A prophylactic material as claimed in claim 3 wherein the said amine comprises polymeric (hexamethylene) biguanide hydrochloride, benzalkonium chloride and didecyl dimethyl ammonium chloride as active ingredients.
5 A prophylactic material as claimed in claim 4 wherein the amine further comprises a surfactant, a nano-emulsion surfactant, a sequestriant, a solubiliser an anti oxidant, a preservative and emollument and demineralised water and solubilisers.
6 A prophylactic material as claimed in claim 2, 3, 4 or 5 wherein the benzalkonium chloride comprises 2,5% of the said amine.
7 A prophylactic material as claimed in any one of the preceding claims wherein the material comprises castor oil, preferably a first pressing, as the carrier; citronella oil as a repellent, DAI as an antiviral, bactericide and fungicide, ethyl alcohol as an emulsifϊer and pine oil acting as a disinfectant. 8 A prophylactic material as claimed in claim 3 and any one of claims 4 to 7 wherein the amine comprises between 1 ,5% and 4,5% and preferably 3% of the product.
9 A prophylactic material as claimed in claim 8 wherein the amine comprises about 3% of the product.
10 A prophylactic material as claimed in any one of the preceding claims wherein the castor oil comprises between 30% and 40% and preferably 34% of the product.
11 A prophylactic material as claimed in any one of the preceding claims wherein the citronella oil is between 1,5% and 3,5% of the product.
12 A prophylactic material as claimed in any one of the preceding claims wherein the ethyl alcohol is between 20% and 30% of the product.
13 A prophylactic material as claimed in any one of the preceding claims wherein the pine oil comprises 33% to 40% of the constituents of the product.
14 A prophylactic material as claimed in any one of the preceding claims wherein additional benzalkonium chloride is added.
15 A prophylactic material as claimed in any one of the preceding claims 1 to 13 further comprising tea tree oil. 16 A prophylactic material as claimed in claim wherein the tea tree oil is a pharmacy grade product.
17 A prophylactic material as claimed in claim 15 or 16 wherein the tea tree oil constitutes between 0,1% to 3% of the total constituents of the product.
18 A prophylactic material as claimed in claim 17 wherein the tea tree oil constitutes about 2% of the product.
19 A prophylactic material as claimed in any one of the preceding claims further comprising chlorhexidine.
PCT/ZA2006/000062 2005-04-26 2006-04-26 Prophylactic materials WO2006116778A2 (en)

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Application Number Priority Date Filing Date Title
ZA200503354 2005-04-26
ZA2005/03354 2005-04-26

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Cited By (7)

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WO2008035101A2 (en) * 2006-09-21 2008-03-27 Mainsani As Disinfectant emulsions containing an antimicrobial compound in each phase
WO2010043863A2 (en) * 2008-10-15 2010-04-22 Byotrol Plc Anti-microbial composition
WO2010144950A1 (en) * 2009-06-15 2010-12-23 Hurstwell Pty Ltd Insect and disease control
WO2011050857A3 (en) * 2009-11-02 2011-08-11 Alpha-Biocare Gmbh Compositions comprising citrus flavonoids and specific cationic surface active agents for treating infestations with head lice
WO2015028806A1 (en) * 2013-09-02 2015-03-05 Scoones Robert Cleaning liquid
WO2015157388A1 (en) * 2014-04-08 2015-10-15 Lonza, Inc. Fast acting disinfection composition
FR3041504A1 (en) * 2015-09-25 2017-03-31 Berkem Dev BIOCIDAL COMPOSITION FOR THE TREATMENT OF WOOD

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