CN105208858A - Compounds, compositions, and methods for repelling an insect from an area, article, and/or structure - Google Patents
Compounds, compositions, and methods for repelling an insect from an area, article, and/or structure Download PDFInfo
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- CN105208858A CN105208858A CN201480028521.6A CN201480028521A CN105208858A CN 105208858 A CN105208858 A CN 105208858A CN 201480028521 A CN201480028521 A CN 201480028521A CN 105208858 A CN105208858 A CN 105208858A
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Abstract
The disclosure provides for methods of repelling, directing, altering the behavior, and/or controlling an insect by utilizing a compound or composition described herein. The disclosure also provides for methods of repelling or directing an insect from an organism, article, or structure by utilizing a compound or composition described herein. The disclosure also provides for an article or structure treated with a composition including at least one repellent, controlling, or directing compound described herein.
Description
the mutual reference of related application
The U.S. Provisional Application the 61/791st that this application requirement was submitted on March 15th, 2013, the rights and interests of No. 662, its full content is included in herein in the mode quoted as proof at this.
Technical field
The invention provides and utilize compound described herein or composition expeling insect, guide insect, change the compound of the behavior of insect and/or control insect, composition and method.Present invention also offers and utilize compound described herein or composition drive away from organism, article or structure or guide the compound of insect, composition and method, described insect such as, honeybee, wasp (yellowjacket) or wasp (wasp).Present invention also offers the article or structure that adopt the compositions-treated comprising the compound that at least one described herein is driven away, controls or guided to cross.
Background technology
The problem of insect to human and animal population proposes already.Known insect is carried various diseases and propagate these diseases between human and animal population.By insect-borne a large amount of disease by record well, and carry out a lot of trial in the health problem that the effective product of exploitation is relevant to insect with antagonism.
Except cause problem, except the serious disease that is attributable to insect, insect is also caused the mankind attempting to be busy with outdoor activities that are social and leisure and generally creates disturbances to.Such as, insect is common disagreeable thing in family's outing and outdoor exercises.When individual be busy with camping, hunt and other outdoor activities many time also experience creating disturbances to of insect consumingly.On the other hand, many insects provide helpful and the effect of strengthening.Such as, honeybee is responsible for the critical function of each Plants pollination.
Due to the problem relevant to insect, develop many countermeasures and attempted driven away by expellent or disperse insect.But many insect repellants have a lot of shortcoming, be included in the sufficient time period and lack effect.In addition, many insect repellants drive away insect widely, and in some cases, wish the insect type selected by only driving away.Therefore, need to develop such expellent, it in some cases effectively and optionally drive away insect from unwanted region.For this purpose, disclosed expeling, the solving these problems with and related methods with the compound of guided bone, composition and there is expeling in longer time section, control and/or change the ability of behavior of insect of controlling, and the larger effect had than previously having generally acknowledged, in certain embodiments, the insect of particular type is only optionally driven away.
Summary of the invention
On the one hand, the invention provides and drive away or guide insect away from the method for article, structure and/or organism, compound or composition, its by adopt at least one from following formula I-XIII compound treatment described in article, structure and/or organism.In another embodiment, described compound, composition and/or method are driven away or are guided the insect of at least 80% away from structure, article and/or organism at least 8 hours.On the other hand, the insect of extraordinary type is driven away on described compound, composition and/or method choice ground.
On the other hand, the invention provides and comprise the bait composition of at least one from the compound of formula I – XIII.
In another, the invention provides adopt at least one to cross from the compound treatment of formula I-XIII structure, article and/or organism.On the one hand, described organism is mammal, domestic animal, domestic animal or the mankind.
On the other hand, the compound of expeling described herein or guiding comprises at least one C
7– C
15ketonic compound.
On the other hand, described C
7– C
15ketone is selected from sulphur (or sulfo-) analog of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone (cyclodeconone) and 2-decanone and relevant oxidation state.
On the one hand, to be purged and/or the insect that shifts is insect pollinator and is optionally honeybee.
On the one hand, the article adopting compound described herein or compositions-treated to cross are made into bait, bait mechanical device or holder (holder), clothes (garment), waistband, air freshener, candle, fiber, bedding, sheet (sheet), fabric, clothes (clothing), net, insect net, fabric, paper, glass, paint, ink, clay, cotton, timber, furniture, carpet, plastics, polymer, biology or synthetic material, spray product, atomizing system, foam, gel, evaporator product, particle and dust.
On the other hand, structure of the present invention or commodity or article comprise inside or the outside of building, the inside of commercial establishment or outside, vehicle, ship, balcony, deck, furniture, window, container, design the container in order to splendid attire insect, design in order to drive away, guide or control the container of insect, dustbin or refuse container, the interior space, the exterior space (includes but not limited to place, parking lot, golf course etc.), tree, shrub (bush), clover, shrub (shrub), flowering plant, lawn, the structure that canopy can be contacted by insect with any other or invade and harass, article, region.
In another, the invention provides the composition comprising the reagent being selected from camphor, camphorated oil, camphor powder, tea oil, tea tree ethereal oil, pine tar, rosemary, Xue MingRosma rinus officinalis powder and rosemary oil.On the one hand, compound described herein or composition are encapsulated.On the other hand, formula I-XIII compound is extremely encapsulated in the form of a powder, and such as, natural powder is as rosemary, Xue MingRosma rinus officinalis powder.
On the one hand, described compound or composition drive away the insect at least 8 hours of at least 95%.
Accompanying drawing explanation
Fig. 1 illustrates the feeding station arrangement repelling experiment for honeybee of embodiment 1.The left side that picture (panel) (A) illustrates picture (A) is the position of honeycomb, and the right of picture (A) is the position of random feeding station.(B) illustrate the arrangement of random feeding station position, and the distance between feeding station is 2 meters.
Fig. 2 has the bee feeding station of the 2-decanone solution containing 50% sucrose solution after illustrating 8 hours.
Fig. 3 has the bee feeding station of 50% sucrose solution after illustrating 8 hours.
After Fig. 4 illustrates the time period of 8 hours, (A) is containing 2-decanone (left picture) and (B) 50% control sucrose (right picture) comparing side by side the repulsion characteristic of honeybee of 50% sucrose solution.
Fig. 5 illustrates within the time period of change, the quantity of the honeybee of access feeding station T1 (contrast), T2 (contrast), T3 (contrast), T4 (camphorated oil), T5 (ajowan oil), T6 (camphor powder), T7 (rosemary oil) and T8 (2-decanone).Containing 50% sucrose in T4 (camphorated oil), T5 (ajowan oil), T6 (camphor powder), T7 (rosemary oil) and T8 (2-decanone).
Fig. 6 illustrates within the time period of 4 hours, the par of the honeybee of access T1 (contrast), T2 (contrast), T3 (contrast), T4 (camphorated oil), T5 (ajowan oil), T6 (camphor powder), T7 (rosemary oil) and T8 (2-decanone) feeding station.Containing 50% sucrose in T4 (camphorated oil), T5 (ajowan oil), T6 (camphor powder), T7 (rosemary oil) and T8 (2-decanone).
Fig. 7 illustrates honeybee and accesses first and the index of the time of back-call accumulated delay as initial expeling ability.
Fig. 8 illustrates the quantity filling the honeybee of the feeding station of 50% control sucrose in multiple time point access.
Fig. 9 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (0.1 % by weight) solution in multiple time point access.
Figure 10 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (0.5 % by weight) solution in multiple time point access.
Figure 11 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (1.0 % by weight) solution in multiple time point access.
Figure 12 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (2.0 % by weight) solution in multiple time point access.
Figure 13 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (2.0 % by weight) solution and camphorated oil (2.0 % by weight) in multiple time point access.
Figure 14 illustrates the quantity filling the honeybee of the feeding station of 2-decanone (2.0 % by weight) solution and rosemary oil (2.0 % by weight) in multiple time point access.
Figure 15 illustrates the quantity filling the honeybee of the feeding station of rosemary, Xue MingRosma rinus officinalis powder (2.0 % by weight) in multiple time point access.
Figure 16 illustrates the quantity filling the honeybee of the feeding station of tea oil (2.0 % by weight) solution in multiple time point access.
Figure 17 illustrates the quantity filling the honeybee of the feeding station of pine oil solution (2%) in multiple time point access.
Figure 18 illustrates the quantity filling the honeybee of the feeding station of methyln nonyl ketone solution (2.0 % by weight) in multiple time point access.
Figure 19 illustrates the quantity filling the honeybee of the feeding station of methyl n-heptyl ketone solution (2.0 % by weight) in multiple time point access.
Figure 20 illustrates the quantity filling the honeybee of the feeding station of rosemary, Xue MingRosma rinus officinalis powder (1.0%) and 2-decanone solution (1.0%) in multiple time point access.
Figure 21 illustrates the quantity filling the honeybee of the feeding station of tea oil (0.5%), 2-decanone solution (0.5%) and pine tar (0.5%) solution in multiple time point access.
Figure 22 illustrates the quantity filling the honeybee of the feeding station of rosemary, Xue MingRosma rinus officinalis powder (1.0%) composition in multiple time point access.
Figure 23 illustrates the quantity filling the honeybee of the feeding station of camphor powder (2.0%) composition in multiple time point access.
Figure 24 illustrates the quantity filling the honeybee of the feeding station of water in multiple time point access.
Figure 25 illustrates access in the time range of specifying and has the quantity of the honeybee of the feeding station of the bond of Imidacloprid and active agent.
Figure 26 illustrates access in the time range of specifying in digital form and has the quantity of the honeybee of the feeding station of the bond of Imidacloprid and active agent.
Figure 27 illustrates fondant attractant to the visual representation impinging upon 2.5 little honeybee countings constantly.
Figure 28 illustrates (A) graphite (10g) and fondant attractant (500g) are in the visual representation of 3.25 constantly little and (B) graphite (10g), 2-decanone (0.5%) and fondant attractants (500g) at 3.25 little honeybees countings constantly.
Figure 29 illustrates (A) talcum (10g) and fondant attractant (500g) are in the visual representation of 5.25 constantly little and (B) talcum (10g), 2-decanone (0.5%) and fondant attractants (500g) at 5.25 little honeybees countings constantly.
Figure 30 illustrates (A) Tissuemat E (10g) and fondant attractant (500g) are in the visual representation of 7 constantly little and (B) Tissuemat E (10g), 2-decanone (0.5%) and fondant attractants (500g) at 7 little honeybees countings constantly.
Figure 31 illustrates access in the time range of specifying and fills the quantity of the honeybee of the feeding station of the bond of dustfall agent (dustreducingagent) and active agent.
Figure 32 illustrates access in the time range of specifying and fills the quantity of the honeybee of the feeding station of the bond of dustfall agent and active agent.
Figure 33 describes access in the time point of specifying and fills the quantity of the honeybee of the feeding station of various active reagent.
Figure 34 describes access in the time point of specifying and fills the quantity of the honeybee of the feeding station of various active reagent.
Figure 35 describes access in the time point of specifying and fills the quantity of the honeybee of the feeding station of various active reagent.
Figure 36 describes access in the time point of specifying with the form of line chart and fills the quantity of the wasp of the feeding station of various active reagent.
Figure 37 (A) and (B) describe access in the time point of specifying and fill the quantity of the wasp of the feeding station of various active reagent.
Figure 38 describes access in the time point of specifying with the form of line chart and fills the quantity of the wasp of the feeding station of various active reagent.
Figure 39 describes access in the time point of specifying in digital form and fills the quantity of the wasp of the feeding station of various active reagent.
Figure 40 describes various active reagent in the time point of specifying and is using the validity in fondant matrix expeling honeybee.
Figure 41 describes various active reagent in the time point of specifying and is using the validity in fondant matrix expeling honeybee.
Embodiment
drive away, control or guide the compound of insect
The invention provides expeling, control and/or guide compound or the composition of insect.On the other hand, the compound of expeling described herein, control and/or guiding or composition drive away insect that is all or wide region.On the other hand, compound or the composition of expeling described herein, control and/or guiding drive away some but not every insect.
On the one hand, expeling described herein, control or guide the compound of insect or composition can control or change the behavior of insect, described insect such as insect pollinator, as honeybee.On the other hand, the invention provides expeling, the compound of control and guidance or composition and by utilizing formula I to drive away, controlling or guide the method for insect:
On the one hand, R
1and R
2independently selected from the phenyl of alkyl, aryl, phenyl, replacement, the phenyl condensed, heterocycle, aryl alkyl, vinyl, acetyl group, vinyl alkyl, propargyl and pi-allyl.
On the other hand, R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl.
On the other hand, R
1for H and R
2for alkyl or aryl or R
1for alkyl or aryl and R
2for H.On the other hand, R
1for H and R
2be selected from any group described herein.In another, R
1for H and R
2be selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl.
On the other hand, alkyl be straight chain, side chain, ring-type, optionally by cycloalkyl that following radicals replaces: halogen (as F, Cl, Br, I), oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C; Nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino; SH, alkylthio group and oxidation state, arylthio and oxidation state; Acylamino-, alkyl monosubstituted amino, dialkyl amido and urea groups.
In another, R
1and R
2can ring be formed, as cycloalkyl ring, such as, cyclohexyl, suberyl, cyclopenta, cyclopropyl, cyclobutyl, ring octyl group; The alkyl ring condensed, as camphor.On the other hand, R
1and R
2ring is optionally by the phenyl of one or more following group replacement: halogen, OH, alkoxyl, cyano group, aminoalkyl is amino, dialkyl amido, SH, alkylthio group and oxidation state, phenoxy group (pheoxy), formoxyl, alkyl-carbonyl, alkoxy carbonyl, haloalkyl, halogenated alkoxy, multi-haloalkyl, alkyl polyhalides oxygen base, whole haloalkyl, perhaloalkoxy groups, acylamino-, alkyl amino, amino, dialkyl amido, hydroxycarbonyl group, alkyl-carbonyl, aryl carbonyl and alkoxy carbonyl.
On the other hand, R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12(CH
2)
13ring structure.
In another, R
1for methyl or ethyl and R
2be selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl.
On the one hand, the formula II of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula III of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula IV of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula V of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula VI of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula VII of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula VIII of described expeling, control or guiding represents, wherein R
1and R
2definition as above and wherein R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately.On the other hand, R
3and R
4can be above mentioned any alkyl group.
On the one hand, the formula IX of described expeling, control or guiding represents, wherein R
1and R
2define as above:
On the one hand, the formula X of described expeling, control or guiding represents, wherein R
1and R
2definition is as above and n is 0,1 or 2:
R
1-S(O)
n-R
2(X)
On the one hand, the formula XI of described expeling, control or guiding and conjugate thereof and isomer representative, wherein R
1and R
2define as above:
On the one hand, the formula XII of described expeling, control or guiding and conjugate thereof and isomer representative, wherein R
1and R
2define as above:
On the one hand, the formula XIII of described expeling, control or guiding and conjugate thereof and isomer representative:
In another, the invention provides the compound of formula I-XIII, wherein R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryl, aryloxy group, aralkyl, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkyl amido, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure, phenyl, the phenyl of replacement, optionally by the phenyl of one or more following group replacement: halogen, alkyl, nitro, cyano group, alkoxyl, alkylthio group and oxidation state, acylamino-, amino, alkyl-carbonyl, alkoxy carbonyl, hydroxycarbonyl group and hydroxyl.
On the other hand, the invention provides the compound of formula I-XIII, wherein R
1and R
2independently selected from phenyl, the phenyl replaced, optionally by the phenyl of one or more following group replacement: halogen, alkyl, nitro, cyano group, alkoxyl, alkylthio group and oxidation state, acylamino-, amino, alkyl-carbonyl, alkoxy carbonyl, hydroxycarbonyl group and hydroxyl.
On the other hand, the invention provides the optically active isomer of formula I-XIII compound and/or geometric isomer and/or its salt.In another, the invention provides the metabolite of formula I-XIII compound, analog, homologue, isomer, diastereoisomer, conjugated isomers, dynamic isomer and salt thereof.On the other hand, methodology described herein can adopt one or more compounds represented by formula I-XIII to implement.
On the one hand, drive away, control or guide the compound of insect or composition to be selected from ketone, as C
5– C
7ketone, C
6– C
9ketone, C
7– C
10ketone, C
8– C
12ketone, C
10– C
12ketone, C
7– C
15ketone or methyl ketone.On the other hand, drive away, control or guide the compound of insect to be selected from one or more following compounds: 2 pentanone, cyclopentanone, 2-penta imines, methyl-n-butyl ketone, 3-hexanone, cyclohexanone, 2-methyl cyclohexanone, 3-methyl cyclohexanone, 4-methyl cyclohexanone, 2-HEPTANONE, 3-heptanone, 4-heptanone, heptyl, 1-acetyl group, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone (methyl-n-octyl ketone), methyln nonyl ketone (methyl-n-nonyl ketone), 2-dodecane ketone, DOX, 2-methyl-2-octyl group, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, 2-nonane thioketones, ring decanone, decane, 2,2-dimethoxy, the sulfur analogs of 2-decanone, 2-imines in the last of the ten Heavenly stems, (+)-2-decyl alcohol, 2-decyl alcohol, 2,9-decane diketone, 2,11-dodecane diketone, 2,5-dodecane diketone, 2,2-decane glycol, 1-hendecene-2-alcohol, 3-decanone, 4-decanone, 5-decanone, 9-methyl, capraldehyde, ethyl ketone, 1-[3-methyl-4-(trifluoromethyl) phenyl], ethyl ketone, the fluoro-1-phenyl of 2,2,2-tri-, 5,9-11 carbon diene-2-ketone (5,9-undecadien-2-one), 6,10-dimethyl-, (5E)-, 2-pentadecanone, 4-methyl cyclohexanone, melilotal, propiophenone, 2-hydroxy acetophenone, 2,9-decane diketone, 2,11-dodecane diketone, 2,5-dodecane diketone and 2-hydroxy acetophenone.
On the one hand, drive away, control or guide the compound of insect or composition to be selected from the compound of sulphur (or sulfo-) analog of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone and related oxidized state.
On the other hand, the compound driven away, control or guide or composition are selected from table 1:
Table 1
On the other hand, the invention provides composition, its inclusion compound, to be made up of or to be substantially made up of described compound described compound, described compound is selected from following one or more of: CH
3s (O) (CH
2)
7cH
3, CH
3s (O)
2(CH
2)
7cH
3, CH
3s (O) (CH
2)
8cH
3, CH
3s (O)
2(CH
2)
8cH
3, CH
3s (O) (CH
2)
7s (O) CH
3, CH
3s (O) (CH
2)
6s (O) CH
3, CH
3cH
2s (O) (CH
2)
6cH
3, CH
3s (O) (CH
2)
6cH
3, CH
3s (O) Ph, CH
3s (O) CH
2ph, CH
3s (O) (CH
2)
4cH
3, CH
3s (O) (CH
2)
5cH
3, CH
3(rule S (O) .CH herein
2)
3cH
3, CH
3s (O)
2(CH
2)
3cH
3, CH
3s (O) (CH
2)
6c (O) CH
3and CH
3s (O)
2(CH
2)
6c (O) CH
3.On the other hand, one or more above-claimed cpds are combined with any any method described herein or composition.
On the one hand, C
5-C
7methyl ketone have and compare C
8-C
12the lower anthelmintic activity of methyl ketone.On the one hand, C is meant by " lower "
5-C
7methyl ketone relative to C
8-C
12ketone is driven away, control or guide the interested insect of lower percentage.On the other hand, C is meant by " lower "
5-C
7methyl ketone relative to C
8-C
12ketone is driven away within the shorter time period, control or guide insect, drives away, controls or guide less interested insect or the combination of interested insect.On the other hand, C
5-C
7methyl ketone compare C
8-C
12the volatility of methyl ketone higher.
On the other hand, C
5-C
7methyl ketone have and compare C
8-C
15the lower anthelmintic activity of methyl ketone.On the other hand, C
5-C
7methyl ketone compare C
8-C
15the volatility of methyl ketone higher.
In another, the invention provides one or more and be selected from following expeling, control or guide compound or the composition of insect: pine tar, tea oil, the essential oil of tea tree, densifolia leaf essential oil, holy basil (ocimumsantum) essential oil, demeton (systox), phenol, alkaloid, ajowan (carumcopticum) oil, propionic andydride, butyric anhydride, gaultherolin, 6-tri-hexadecene (6-hexatriacontene), stenpcereol, 27,28,29-trisnor-13-15-17-meratriene, samaderin E (samaderineE), phenylacetaldehyde, benzaldehyde, Swertiadensifolia leaf essential oil, linalool (linalool), okra-seed oil, card lamb's-quarters (cascarilla) skin oil, leaf oil, card lamb's-quarters skin oil, rue oil, rue caul-fat, terpineol, stearic acid, quinhydrones and arbricolin, Methyl anthranilate, Methyl anthranilate, creasote, acetic acid and propionic acid, N, N-diethyltoluamide, repefral and Isopropyl cinnamate.The present invention also provides one or more of expeling, control or guide the compound of insect or the bond of compound, being selected from lemongrass (citronella) (such as, Cymbopogon kind (Cymbopogonspp), nardgrass (Cymbopogonnardus), citronella (Cymbopogonwinterianus) and lemon grass (Cymbopogon citratus) (Cymbopogoncitratus)), eucalyptus (eucalyptus) (eucalyptus belongs to kind of (Eucalyptusspp.)), eucalyptus citriodora (lemoneucalyptus) (Corymbiacitriodora), Chinese cassia tree (Ceylon cinnamon (Cinnamomumverum)), castor-oil plant (Ricinuscommunis), rosemary, Xue MingRosma rinus officinalis (Rosmarinusofficinalis), cdear (Cedrus kind (Cedrusspp.)), peppermint (, lavender (Menthapiperita)), cloves (Syzygiumaromaticum), geranium (Pelargonium roseum (Pelargoniumgraveolens)), horsewhip (Verbena kind (Verbenaspp.), Verbena officinalis (Verbenaofficinalis)), pennyroyal (pennyroyal) (european pennyroyal (Menthapulegium)), lavender (lavender belongs to kind of (Lavandulaspp.)), pine tree (Pinus kind (Pinusspp.)), cajeputtree (Melaleuca kind (Melaleucaspp.), cajeputtree (Melaleucaleucadendra)), sweet basil (Ocimumbasilicum), thyme (Thymusvulgaris), aggag (pandan) (fragrant dew pocket (Pandanusamaryllifolius)), allspice (Pimentadioica), soybean (soya bean (Glycinemax)), garlic (Alliumsativum), DEET, Picaridin, to menthyl-3,8-glycol (p-Mentane-3,8-diol), Permethrin (Permethrin), allethrin (Allethrin), metofluthrin (Metofluthrin), geraniol, Eugenol, cinnamic acid (Cinnamaldehyde), alkaloid, p-cymene, linalool, australene, nopinene, sabinene, laurene, α – phellandrene, α-terpinene, alpha-terpineol, α-citrene, 1,8-cineole, y-terpinene, terpinolene, terpinene-4-alcohol and alpha-terpineol, copticum and ajawa oil (Ptychotisoil).
On the one hand, compound described herein and composition in conjunction with time show synergy.On the other hand, formula I-XIII compound in conjunction with time show synergy.On the other hand, the compound 1-33 in table 1 in conjunction with time show synergy.In another, these compounds create one and add and effect.
On the one hand, the invention provides a kind of method described herein, wherein the 2-decanone of the 2-decanone of 0.5 % by weight than 1.0 % by weight and/or 2.0 % by weight the larger expeling of 2-decanone display.On the other hand, the invention provides a kind of method described herein, the expeling that wherein the 2-decanone display of the 2-decanone of 1.0 % by weight than 2.0 % by weight is larger.
On the one hand, drive away, control or guide the compound of insect or the bond of compound to comprise any expeling described herein, the compound of control or guiding or composition, be made up of these compounds or composition or be substantially made up of these compounds or composition.
On the other hand, composition provided by the invention comprises 2-decanone and rosemary oil, is substantially made up of 2-decanone and rosemary oil or is made up of 2-decanone and rosemary oil.On the other hand, composition provided by the invention comprises 2-decanone and camphor, is substantially made up of 2-decanone and camphor or is made up of 2-decanone and camphor.In another, composition provided by the invention comprises 2-decanone, rosemary oil and camphor, is substantially made up of 2-decanone, rosemary oil and camphor, or is made up of 2-decanone, rosemary oil and camphor.On the one hand, these compounds produce synergy.In another, these compounds produce and add and effect.
On the other hand, expeling described herein, control or guide the compound of insect or composition by affect or change insect feel work.On the other hand, the sense of smell of described compound or composition change insect, vision or other physical characteristics or its combine.Such as, when a kind of compound or composition be act on the expeling of sense of smell, the compound of control or guiding or composition time, other compounds or composition can be comprised, or other compounds that can use with the first compound or composition that act on sensation before, after or simultaneously or composition.These can relate to view-based access control model (as color), sense of touch, the sense of taste or other physical characteristics (as sound, vibration) and any aforesaid combination guiding or drive away insect compound or composition.
On the other hand, described expeling, control or guide the compound of insect, the bond of compound or composition not to comprise compound, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, the N of activity of heptanone, 2-HEPTANONE, simulation 2-HEPTANONE, N-diethyl-m-toluamide (" DEET "), benzaldehyde, phenol, or its any combination.
On the one hand, described expeling, control or guide the composition of insect comprise 2-decanone and do not comprise 2-HEPTANONE.On the one hand, described composition comprises 2-decanone and does not comprise methyln nonyl ketone.On the other hand, described composition comprises 2-decanone and does not comprise 2-dodecane ketone.In another, described composition comprises 2-decanone and does not comprise methyl n-undecyl ketone.In another, described composition comprises 2-decanone and does not comprise 2-HEPTANONE, methyln nonyl ketone, 2-dodecane ketone or methyl n-undecyl ketone.
On the one hand, described composition does not comprise print chinaberry plant, its print chinaberry position, neem oil or neem extract.
drive away, control or guide the method for insect from structure, article or organism
The invention provides the method by utilizing compound described herein or composition to drive away, control or guide insect from structure, organism or article.
On the one hand, the invention provides the method for driving away, controlling or guide insect by adopting expeling described herein, the compound of control or guiding or compositions-treated structure, organism or article from structure, organism or article.
On the other hand, the invention provides the method for driving away, controlling or guide insect by adopting one or more of expeling described herein, the compound of control or guiding or composition contact, coating or impregnated structures body, organism or article from structure, organism or article.
The present invention also provides and adopts expeling described herein, the compound of control or guiding or compositions-treated first structure or article and adopt insect attractant immunomodulator compounds or compositions-treated second structure or article or its part (and/or part of described first structure) (namely simultaneously or at different time, on the one hand, be strategically placed on the optimum distance place of described part of distance the first structure or article or the described first or second article or structure) method.Such methodology can drive away from the first structure or article when attract insect to the second structure or article or its part, controls or guide insect.
Provided below is so methodological limiting examples:
(1) one or more of expeling described herein, the compound of control or guiding or compositions-treated first " structure 1 " or " article 1 " or its part is adopted; And
(2) one or more of expeling described herein, the compound of control or guiding or compositions-treated second " structure 2 " or " article 2 " or its part or combination is adopted;
(3) wherein said first " structure 1 " or " article 1 " or its part are placed on the optimum distance place apart from described second " structure 2 " or " article 2 " or its part.
In another, adopt at least one expeling described herein, the compound of control or guiding or compositions-treated two or more, three kinds or more kind or four kinds or more plant " structure " or " article " or its part.
In another, the distance of " structure 1 " or " article 1 " distance " structure 2 " or " article 2 " is about 0.1 meter, about 0.5 meter, about 1 meter, about 3 meters, about 5 meters, about 10 meters, about 25 meters, about 50 meters, about 100 meters, about 200 meters or about 300 meters.On the other hand, the distance that " structure 1 " or " article 1 " separates be enough to drive away, guide or control from " structure 1 " or " article 1 " insect and lure insect on " structure 2 " or " article 2 ".
On the other hand, can adopt one or more of expeling, the compound of control or guiding or compositions-treated one or more, two or more, three or more or four or more " structure " or " article ".
On the one hand, the percentage of described compound in any composition or preparation drives away validity, the medium carrying described compound or other components of property, interaction between application process and pending region (expressing in the mode of surface area or volume) and determining by compound.Such as, when surface be dull and stereotyped or wall time, surface area determination rate of application can be used; When region be room or other spaces time, volume determination rate of application can be used.
drive away, control or guide the method for insect
On the one hand, compound described herein or composition are driven away, are controlled or guide interested insect that is all or wide region, such as honeybee.On the other hand, compound described herein or composition are optionally driven away, are controlled or guide insect.In another, guide insect by contacting with compound described herein or composition.On the other hand, interested insect (such as, honeybee) does not directly contact with the material adopting the compound driving away, control or guide or compositions-treated to cross.On the other hand, compound described herein or composition are driven away, are controlled or guide interested insect (such as, honeybee) to such an extent as to the insect only minimally material crossed of contact pairs.
On the other hand, compound described herein or composition drive away, control or guide interested insect to make insect at least about 10 minutes, about 30 minute, about 1 hour, about 4 hours, about 8 hours, about 12 hours, about 24 hours, about 2 days, about 3 days, about 7 days, about 14 days, about 21 days, about 1 month, about 2 months or about directly do not contact with the object processed (as structure, article or organism) in 3 months or longer time.In another, compound described herein or composition drive away, control or guide interested insect with make insect at the appointed time in (such as sow, grow or the harvest season) directly do not contact with the object processed.
On the other hand, compound described herein or composition drive away, control or guide interested insect with make insect away from the object processed (as structure, article or organism) at least about 1cm, at least about 5cm, at least about 10cm, at least about 100cm, at least about 0.2 meter, at least about 0.5 meter, at least about 1 meter, at least about 2 meters, at least about 5 meters, at least about 10 meters, at least about 25 meters, at least about 50 meters, at least about 100 meters, at least about 200 meters or at least about 300 meters or longer distance.In another, compound described herein or composition are driven away, control or guide interested insect to make insect at least about 10 minutes, about 30 minutes, about 1 hour, about 4 hours, about 8 hours, about 12 hours, about 24 hours, about 2 days, about 3 days, about 7 days, about 14 days, about 21 days, about 1 month, about 2 months or about 3 months or longer time or the time limit of specifying or in the season of growth away from the object processed (as structure, article or organism) at least about 1cm, at least about 5cm, at least about 10cm, at least about 100cm, at least about 0.2 meter, at least about 0.5 meter, at least about 1 meter, at least about 2 meters, at least about 5 meters, at least about 10 meters, at least about 25 meters, at least about 50 meters, at least about 100 meters, at least about 200 meters or at least about 300 meters or longer distance.
On the other hand, compound described herein or composition drive away, control or guide interested insect with make insect away from object process (as structure, article or organism) at least about 1cm to about 10cm, about 10cm to about 100cm, about 100cm extremely about 500cm, about 1 meter to about 5 meters, about 5 meters to about 10 meters, about 10 meters to about 50 meters, about 50 meters to about 100 meters, about 100 meters extremely about 250 meters and about 250 meters to about 500 meters or farther distances.In another, compound described herein or composition drive away interested insect to make insect at least about 10 minutes, about 30 minutes, about 1 hour, about 4 hours, about 8 hours, about 12 hours, about 24 hours, about 2 days, about 3 days, about 7 days, about 14 days, about 21 days, about 1 month, about 2 months or about in 3 months or longer time or season of growth of specifying away from the object processed (as structure, article or organism) at least about 1cm to about 10cm, about 10cm to about 100cm, about 100cm to about 500cm, about 1 meter to about 5 meters, about 5 meters to about 10 meters, about 10 meters to about 50 meters, about 50 meters to about 100 meters, about 100 meters to about 250 meters and about 250 meters to about 500 meters or longer distance.
On the other hand, compound described herein or composition are at least about 10 minutes, about 30 minute, about 1 hour, about 4 hours, about 8 hours, about 12 hours, about 24 hours, about 2 days, about 3 days, about 7 days, about 14 days, about 21 days, about 1 month, about 2 months, about 3 months or longer time, or the time limit of specifying or growth or harvest season control or guide interested insect, as honeybee.
On the other hand, the one or more of compound that other are driven away, control or guide can be added in expeling composition described herein or composition changes or strengthens expeling property to make the mode via addition, synergy and combination thereof.Also compound described herein or composition can be formulated as delayed release dosage forms or the Co ntrolled release formulation of the release that can postpone or control described expeling compound or composition.On the other hand, compound described herein or composition can be formulated as the quick-release formulation of the release that can promote described expeling compound or composition.
On the one hand, the behavior that the method for " expeling " refers to compound described herein or composition impact or changes insect (such as, honeybee) makes it the ability away from region, place, structure, article or interested material.According to an aspect of the present invention, in order to be classified as " expeling ", the insect of 100% is not guided away from region, mammal, place, structure, article or interested material by mandatory requirement.In another, if the insect of at least 50%, at least 75%, at least 90%, at least 95% or at least 98% is guided away from region, organism, place, structure, article or interested material, then insect " is purged ".
On the other hand, the method for " guiding " refers to compound described herein or composition affects the ability that the behavior of insect (such as, honeybee) or action make it the direction tending to specify.According to an aspect of the present invention, in order to be classified as " guiding ", not mandatory requirement by the insects of 100% away from region, mammal, place, structure, article or interested material.In another, if the insects of at least 50%, at least 75%, at least 90%, at least 95% or at least 98% is away from region, organism, place, structure, article or interested material, then insect " by drawing away ".
On the one hand, the method for " control " refers to the ability of the behavior of compound described herein or composition control or change insect (such as, honeybee).According to an aspect of the present invention, in order to be classified as " control ", mandatory requirement does not control the insect of 100% relative to region, mammal, place, structure, article or interested material.In another, if relative to region, organism, place, structure, article or interested material, the behavior of the insect of at least 50%, at least 90%, at least 95% or at least 98% is changed or controls, then insect " by controlling ".
structure, article, organism and domestic animal
A.
structure
On the one hand, compound described herein or composition have from structure expeling or the ability guiding insect.Without restriction, " structure " can contact insect or by the region of insect infestations or place.On the other hand, " structure " can be artificial or natural.Without restriction, " structure " can be building, such as commercial establishment or residential building, the inside of building or outside, and the exterior space includes but not limited to place, garden, golf course etc.; Vehicle; Ship; Balcony; Deck; Desk; Chair; Window; Container, design to preserve insect container, design container in order to drive away, to guide or control insect; Dustbin or refuse container; The interior space, as the room in commercial establishment or residential building; The exterior space, or the structure being often present in the exterior space, as tree, shrub, clover, shrub, flowering plant, lawn, canopy; Or other such structures.
B.
article
On the one hand, compound described herein or composition have from article expeling or the ability guiding insect.Without restriction, " article " are the assemblies that can be contacted by insect, affect or attack.On the other hand, without restriction, " article " can be bait, bait mechanical device or holder, device, clothes, waistband, air freshener, candle, other dulcet article, fiber, bedding, sheet, fabric, clothes, net, insect net, fabric, paper, glass, paint, ink, clay, cotton, timber, furniture, carpet, hygienic article, plastics, polymer, biology or synthetic material, spray product, atomizing system, fogger, foam, gel, evaporator product, evaporator system, particle and dust.
On the other hand, compound described herein or compositions-treated, sprinkling or dipping articles can be adopted.
C.
organism
On the one hand, organism is animals or humans.On the other hand, compound described herein or composition have expeling or guide insect away from the ability of organism (such as animals or humans).On the other hand, compound described herein or composition have the ability of the behavior the Region control insect having animals or humans.On the one hand, can any minimizing honeybee-mankind interact or the interactional application method in honeybee-place and use compound described herein or composition.On the other hand, compound described herein or composition can be applied to individuality or place individually, or are combined use with other active component, reagent or medicines supplemented.
D.
domestic animal
On the other hand, expeling described herein, control can be adopted or guide the compound of insect or compositions-treated domestic animal.On the one hand, without restriction, compound described herein or composition are used for drive away, control or guide and contact with domestic animal or close to the insect of domestic animal.On the other hand, " domestic animal " can comprise any can by the animal of insect infestations, such as, ox, sheep, goat, horse, pig, rabbit, chicken, turkey, duck, goose, and pet, as dog, cat, cage bird, hamster, cavy, rat and mouse.
the process of structure, article and organism
On the one hand, compound described herein or composition with single step of applying be applied to structure, article or organism all or part of.On the other hand, composition described herein with multiple step of applying (step of applying as two, three, four, five or more) be applied to structure, article or organism all or part of.On the other hand, described second, third, the step of applying of the 4th or the 5th or more can adopt identical or different composition.
On the other hand, compound described herein or composition be enough to drive away, control or guide the mode of insect be applied to structure, article or organism all or part of.
On the other hand, compound described herein or composition are between the insect infestation emergence period or be applied to all or part of of structure or article afterwards.In another, compound described herein or composition before and after, during invasion occurs or its other combine, be applied to all or part of of structure or article.On the other hand, compound described herein or composition be applied to when needed structure, article or organism all or part of, such as, with about 5 minutes, about 15 minutes, about 30 minutes, about 1 hour, about 2 hours, about 6 hours, about 8 hours, about 12 hours, about 1 day, about 5 days, about 7 days, about 10 days, about 12 days, about 14 days, about 21 days, about 28 days, the interval of about 1 month, about 2 months, about 3 months or use each season until insect is purged or insect infestations processed or weaken.In another, compound described herein or composition with about 30 minutes to about 1 hour, about 2 little up to about 4 hours, about 4 little of about 12 hours, about 1 little interval up to about 1 day, about 1 day to about 5 days, about 5 days to about 10 days, about 10 days to about 20 days, about 15 days to about 30 days, about 30 to about 100 days or be applied to structure, article or organism at regular intervals until insect is purged or insect infestations processed or weaken within given season.
the compound of expeling, control and guidance and composition character
On the one hand, expeling described herein, control or guiding compound or composition can at least about 10 minutes, about 30 minute, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about 3 months or expeling in the longer time, control or guide insect described herein away from structure, article or organism.
On the other hand, relative to not comprising the expeling of effective dose described herein, control or the compound of guiding or the compound of composition or composition, expeling described herein, control or guiding compound or composition drive away, control or guide insect at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, about 98% or more or about 99% or more.On the other hand, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, expeling described herein, control or guide compound or composition at least about 5 minutes, about 10 minutes, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about in 3 months or longer time or drive away within whole season or part season, control or guide at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, the insect of about 98% or more or about 99% or more.In another, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, expeling described herein, control or guide compound or composition at least about 5 minutes, about 10 minutes, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about in 3 months or longer time or the time limit (as within whole season or part season) of specifying drive away or control at least 95% or more, 96% or more, 97% or more, 98% or more, the insect (as honeybee) of 99% or more or 100%.
In another, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, expeling described herein, the compound controlled or guide or composition are driven away, control or guide about 10% to about 100%, about 20% to about 100%, about 30% to about 100%, about 40% to about 100%, about 50% to about 100%, about 60% to about 100%, about 70% to about 100%, about 80% to about 100%, about 10% to about 90%, about 20% to about 90%, about 30% to about 90%, about 40% to about 90%, about 50% to about 90%, about 60% to about 90%, about 70% to about 90%, about 10% to about 80%, about 20% to about 80%, about 30% to about 80%, about 40% to about 80%, about 50% to about 80% or about 60% to about 80%, about 10% to about 70%, about 20% to about 70%, about 30% to about 70%, about 40% to about 70% or the insect of about 50% to about 70%.
On the one hand, the compound of expeling disclosed herein, control or guiding or composition decrease the interaction of insect and mammal, structure and/or article.On the one hand, the compound of expeling described herein, control or guiding or composition can at least about 5 minutes, about 10 minute, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about 3 months or minimizing insect and structure in the longer time or in the time range of specifying (as growth or harvest season), article and/or organism interaction.On the other hand, relative to not comprising the expeling of effective dose described herein, control or the compound of guiding or the compound of composition or composition, the compound of expeling described herein, control or guiding or composition can reduce insect and mammal, structure and/or article interaction at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, about 98% or more or about 99% or more.On the other hand, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, expeling described herein, the compound controlled or guide or composition are at least about 5 minutes, about 10 minutes, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about within 3 months or interior for more time, reduce insect (as honeybee) and mammal, the interaction of structure and/or article is at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, about 98% or more or about 99% or more.In another, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, expeling described herein, the compound controlled or guide or composition are at least about 5 minutes, about 10 minutes, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about in 3 months or longer time or the time limit (as the season of growth) of specifying reduce insect and structure, interaction at least 95% of article and/or organism or more, 96% or more, 97% or more, 98% or more, 99% or more or 100%.
On the one hand, relative to one or more of following substances: camphorated oil, ajowan oil, camphor powder or rosemary oil, expeling disclosed herein, control or guiding compound or the larger expeling impact of composition display.In another, relative to one or more of following substances: camphorated oil, ajowan oil, camphor powder or rosemary oil, the dispel effect that 2-decanone disclosed herein, expeling compound or composition display are larger, this is consistent with embodiment and Fig. 5-6.
In another, relative to one or more of following substances: camphorated oil, ajowan oil, camphor powder or rosemary oil, the compound of expeling disclosed herein, control or guiding or composition at least about 5 minutes, about 10 minute, about 30 minutes, about 1 hour, about 2 hours, about 3 hours, about 4 hours, about 8 hours, about 10 hours, about 15 hours, about 24 hours, about 48 hours, about 72 hours, about 7 days, about two weeks, about 1 month, about 2 months, about 3 months or expeling, control that in the longer time, display is larger or guide affects.On the other hand, relative to one or more of following substances: camphorated oil, ajowan oil, camphor powder, rosemary oil, expeling, control that the compound of expeling disclosed herein, control or guiding or composition display strengthen or guide effect, strengthen at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, about 98% or more or about 99% or more.On the other hand, relative to one or more of following substances: camphorated oil, ajowan oil, camphor powder, rosemary, Xue MingRosma rinus officinalis, expeling disclosed herein, the compound controlled or guide or composition were at least 30 minutes, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 10 hours, 15 hours, 20 hours, 24 hours, 48 hours, 72 hours, 7 days, two weeks, 1 month or the longer time interior expeling showing enhancing, control or guide effect, strengthen at least about 20% or more, about 30% or more, about 40% or more, about 50% or more, about 60% or more, about 75% or more, about 90% or more, about 95% or more, about 98% or more or about 99% or more.In another, relative to the expeling not comprising effective dose described herein, the compound of control or the compound guided or composition or composition, drive away, control or guide compound or composition at least 30 minutes, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 10 hours, 15 hours, 20 hours, 24 hours, 48 hours, 72 hours, 7 days, two weeks, 1 month or longer time in reduce insect (as, honeybee) ability of food and/or nectar is obtained from plant, reduction at least 95% or more, 96% or more, 97% or more, 98% or more, 99% or more or 100%.
On the one hand, expeling disclosed herein, control or guiding compound or composition may compare C
6– C
9ketone, C
7– C
10ketone, C
8– C
12ketone, 2-HEPTANONE, methyln nonyl ketone, 2-dodecane ketone or methyl n-undecyl ketone more stable (and/or less volatility).
On the other hand, the sulfur analogs of 2-decanone is than one or more of C
6– C
9ketone, C
7– C
10ketone, C
8– C
12ketone, 2-HEPTANONE, methyln nonyl ketone, 2-dodecane ketone or methyl n-undecyl ketone more stable (and/or less volatility).In another, the sulfur analogs of 2-decanone is more stable than 2-decanone (and/or less volatility).
In other, expeling described herein, control or guiding compound or half life period of composition be about 4 hours, about 8 hours, about 12 hours, about one day, about three days, about five days, about one week, about two weeks, about three weeks, about 1 month, about 2 months or about 3 months.On the other hand, expeling described herein, control or guiding compound or half life period of composition be about 4 hours, about 8 hours, about 12 hours, at least one sky, at least three days, at least five days, at least one week, at least two weeks, at least three weeks, at least 1 month, at least 2 months or at least 3 months.In another, expeling described herein, control or guiding compound or half life period of composition be about 4 hours, about 8 hours, about 12 little up to one day, about one day to about seven days, about three days to about seven days, about five days to about seven days, about one thoughtful about surrounding, about two thoughtful about surroundings, about three thoughtful about surroundings, about 1 month to about 4 months, about 2 months extremely about 4 months or about 3 months to about 4 months.
insect
On the one hand, insect can be insect pollinator.On the other hand, insect is that be purged, controlled or directed non-insect pollinator.
On the one hand, insect is Hymenoptera.In another, insect is honeybee.On the other hand, described honeybee is honeybee (Apis (Apis)).On the other hand, described honeybee is European honeybee (Apismellifera) or Africanized honeybee.The example of common honeybee is hornet (Bomzbus), little carpenter bee (Ceratina), large carpenter bee (Xylocopa), paper wasp (Polistes), wasp (Vespula) and bald-faced wasp (baldfacedhornets) (Vespula (Vespula)).As used herein, term " honeybee " can refer to any member of Hymenoptera (Hymeoptera) Apidae, include but not limited to black apis florea (Apisandreniformis), Eastern bee (Apiscerana), apis dorsata (Apisdorsata), apis florea (Apisflorae), apis mellifera Linnaeus (Apismellifera), Sabah honeybee (Apiskoschevnikovi), black apis dorsata (Apislaboriosa), Su Weilaxi honeybee (Apisnigrocincta), Apisrorea, its subspecies and strain (strain) thereof, mutation and hybrid.
In another, described insect is butterfly.Butterfly is lepidopterous insect.On the one hand, butterfly is real butterfly (Papilionoidea (superfamilyPapilionoidea)), hesperid (skipper) (Hesperioidea (superfamilyHesperioidea)) or moth-butterfly (moth-butterflies) (happiness butterfly Superfamily (superfamilyHedyloidea)).The example of common butterfly is swallowtail butterfly (Swallowtails) and pinion butterfly (Birdwings) (Papilionidae (FamilyPapilionidae)), as smaller citrus dog (CommonYellowSwallowtail, smaller citrus dog (Papiliomachaon)), North America crow camphor tree swallowtail butterfly (SpicebushSwallowtail, PapilioTroilus), Bodhidharma swallowtail butterfly (LimeButterfly, Papiliodemoleus); Pinion swallowtail butterfly belongs to (Ornithoptera), white butterfly and yellow butterfly (WhitesandYellows) (Sulfur butterfly (FamilyPieridae)), as imported cabbageworm (Pierisrapae), green arteries and veins imported cabbageworm (Green-veinedWhite, Pierisnapi), CommonJezebel (Deliaseucharis); Little hairstreak (BluesandCoppers) or hairstreak (Gossamer-WingedButterflies) (little Lycaenidae (FamilyLycaenidae), as RedPierrot (Talicadanyseus)), Riodinidae Metalmark butterfly (Riodinidae (FamilyRiodinidae), as DukeofBurgundy (garden sorrel a species of small clam living in fresh water butterfly (Hamearislucina)), the brown a species of small clam living in fresh water butterfly (PlumJudy, Abisaraecherius) of snake order; An a kind of butterfly harmful to crop plants (Brush-footedbutterflies) (Nymphalidae), as little pyrameis indica (PaintedLady) or a little red a kind of butterfly harmful to crop plants (Cosmopolitan, Vanessacardui), black lode gold Ursula butterfly (Monarchbutterfly) (monarch butterfly, Danausplexippus), Morpho (Morpho), spot wood butterfly (SpeckledWood) (handkerchief satyrid, Parargeaegeria); Hesperid (Skippers) (Hesperiidae, FamilyHesperiidae) as MallowSkipper (flower card is hesperided (Carcharodusalceae)) and ZabulonSkipper (Poaneszabulon).
On the other hand, insect described herein is ant.In another, described ant is carpented ant, fiery ant, little red ant, terrible ant (ghostant) and black ant.
Discussing for simplifying, the present invention relates to " insect ", but should be understood that and the present invention is not limited thereto.Optionally utilize the present invention to guide, to drive away and/or to control anyly have on insect or other biological body any organism that the analog of similar impact or analogue compounds and/or composition have response on compound of the present invention or composition and any expection thereof.And, hereinafter discussion in many cases will refer to " interested insect ", unless clearly illustrated from this paper other places about having the context of its purposes, otherwise this word will be used to refer to the aspect of the present invention of the specific subgroup (subset) allowing Selective Control, guiding or drive away insect or other biological body.In other words, when user's desired control of the present invention, guiding or the subgroup of driving away organism (as insect) simultaneously do not guide, control or drive away other biological body, the subgroup of the insect being controlled, guide and/or drive away becomes or is called as " interested insect ".
On the other hand, the behavior of the insect (such as honeybee) of a type or subgroup is optionally driven away, guides, controls or changed to compound described herein or composition, and do not affect other insects.Such as, in one embodiment, the compound driven away, control or guide or composition are combined with insecticidal mixtures, such as, are combined together with insecticidal mixtures by expeling, control or the compound guided or composition.On the other hand, drive away, control or guide compound or composition use insecticidal mixtures while, before or after be sequentially applied to such as region, seed, plant parts or plant.In another, attractant compound or composition are applied to the zones of different or material that are intended to lure interested insect.
On the other hand, compound described herein or composition optionally drive away honeybee and wasp.In another, compound described herein or composition optionally drive away honeybee, wasp and wasp.
On the one hand, attractant described herein is the corresponding oxime of ketone, such as, methyl-n-butyl ketone oxime, 2-HEPTANONE oxime, 3-heptanone oxime, 4-heptanone oxime, cycloheptanone oxime, methyln-hexyl ketone oxime, 3-octanone oxime, cyclooctanone oxime, methyl n-heptyl ketone oxime, cyclononanone oxime, 2-decanone oxime, 3-decanone oxime, 4-decanone oxime, 5-decanone oxime, methyln nonyl ketone oxime, 2-dodecane ketoxime, methyl n-undecyl ketone oxime, 2-tetradecane ketoxime, 2-pentadecane ketoxime, 2-hexadecane ketoxime, 2-heptadecane ketoxime.
As limiting examples, (1) 2-decanone is used to disposal field, garden or structure as the compound driven away, control or guide, (2) clothianidin (clothianidin) is as insecticidal compounds, and (3) sucrose is used to disposal field, garden or structure as attractant compound or composition.As an example, the place of all or Part I, garden or structure (1) 2-decanone and (2) clothianidin process, the simultaneously place of the place of remainder, garden or structure or the second part or more part, garden or structure attractant compound or composition (as (3) sucrose) process.Under such scheme, the compound selective being purged, controlling or guide is driven away, controls or is guided by the insect (as honeybee) being purged as target, controlling or guiding, in the case, the compound of described expeling, control or guiding is (1) 2-decanone and (2) clothianidin composition/bond, and attractant compound or composition are lured or be attracted to the described insect being purged as target, controlling or guiding simultaneously, in the case, described attractant compound or composition are (3) sucrose.Such method will make interested insect (such as, honeybee) selectively repel or control, and make insecticide (being clothianidin in the case) can process any undesired insect or insect simultaneously.Like this, honeybee optionally will be driven away, controlled or is guided away from (1) 2-decanone and (2) clothianidin composition/bond, be attracted to (3) sucrose, the invasion and attack problem of any residue insect or insect is solved simultaneously.
In another, compound described herein or composition are optionally driven away, guide or control or change the behavior of honeybee, such as any member of Hymenoptera (Hymeoptera) Apidae, include but not limited to black apis florea (Apisandreniformis), Eastern bee (Apiscerana), apis dorsata (Apisdorsata), apis florea (Apisflorae), apis mellifera Linnaeus (Apismellifera), Sabah honeybee (Apiskoschevnikovi), black apis dorsata (Apislaboriosa), Su Weilaxi honeybee (Apisnigrocincta), Apisrorea, its subspecies and strain thereof, mutation and hybrid.
Present invention provides such as, by utilizing compound described herein or composition and driving away, control or lure the method for wasp, shown in Figure 36,37 (A) (B), 38 and 39.On the one hand, the invention provides by adopting any methodology described herein to utilize camphor, camphorated oil, camphor powder or its combination to lure the method for wasp.In another, the invention provides by utilizing based on composition weight meter at least about 0.01%, at least about 0.025%, at least about 0.05%, at least about 0.1%, at least about 0.25%, at least about 0.5%, at least about 1%, at least about 2%, at least about 2.5%, at least about 5%, at least about 7.5%, at least about 10%, at least about 25% or lure the method for wasp at least about camphor, camphorated oil, camphor powder or its combination of 50%.
On the other hand, compound described herein or composition optionally drive away any insect described herein.On the other hand, compound described herein or composition optionally drive away some insect, and do not drive away other insects.
composition
On the one hand, compound or the composition of expeling described herein, control or guiding can exist effectively to drive away, to control or to guide the amount of the motion of interested insect (effective dose).On the other hand, expeling described herein, control or the compound of guiding or the amount of composition can be effectively drive away, control or guide insect away from the amount of structure, article or organism.
On the other hand, composition comprises the expeling of following amount, the compound of control or guiding or composition: at least about 0.01%, at least about 0.025%, at least about 0.05%, at least about 0.1%, at least about 0.25%, at least about 0.5%, at least about 1%, at least about 2% at least about 2.5%, at least about 5%, at least about 7.5%, at least about 10%, at least about 25% or at least about 50%, based on the weighing scale of composition.In another, composition comprises the expeling of following amount, the compound of control or guiding or composition: at the most about 0.01%, at the most about 0.025%, at the most about 0.05%, at the most about 0.1%, at the most about 0.25%, at the most about 0.5%, at the most about 1%, at the most about 2.0%, at the most about 2.5%, at the most about 5%, at the most about 7.5%, at the most about 10%, at the most about 25%, at the most about 50%, based on the weighing scale of composition.
On the other hand, composition comprises the expeling of following amount, the compound controlled or guide or composition: 0.001% to about 0.1%, about 0.025%, about 0.0025% to about 0.25%, about 0.1% to about 1%, about 0.1% to about 2.5%, about 0.5% to about 2.5%, about 1% to about 2%, about 1% to about 3%, about 1% to about 5%, about 1% to about 10%, about 2% to about 10%, about 5% to about 10%, about 5% to about 20%, about 10% to about 25%, about 10% to about 50%, about 25% to about 50% or about 20% to about 80%, and about 95% or more, based on the weighing scale of composition.
On the other hand, composition described herein comprises the compound described herein of following amount: at least about 0.01%, at least about 0.025%, at least about 0.05%, at least about 0.1%, at least about 0.25%, at least about 0.5%, at least about 1%, at least about 2%, at least about 2.5%, at least about 5%, at least about 7.5%, at least about 10%, at least about 25% or at least about 50%, based on the weighing scale of composition.In another, composition comprises the compound described herein of following amount: at the most about 0.01%, at the most about 0.025%, at the most about 0.05%, at the most about 0.1%, at the most about 0.25%, at the most about 0.5%, at the most about 1%, at the most about 2.0%, at the most about 2.5%, at the most about 5%, at the most about 7.5%, at the most about 10%, at the most about 25%, at the most about 50%, based on the weighing scale of composition.
In another, composition described herein comprise following amount compound described herein: 0.001% to about 0.1%, about 0.025%, about 0.0025% to about 0.25%, about 0.1% to about 1%, about 0.1% to about 2.5%, about 0.5% to about 2.5%, about 1% to about 2%, about 1% to about 3%, about 1% to about 5%, about 1% to about 10%, about 2% to about 10%, about 5% to about 10%, about 5% to about 20%, about 10% to about 25%, about 10% to about 50%, about 25% to about 50%, or about 20% to about 80% and about 95% or more, based on the weighing scale of composition.
On the other hand, compound described herein or composition are applied to " structure " or " article " until moist or saturated.On the other hand, by compound described in the invention or composition in liquid application mode, be applied to " structure " or " article " with following concentration: about 0.1mg/L – is about 20mg/L, about 0.1mg/L – is about 50mg/L, about 1mg/L – is about 20mg/L, about 5mg/L – is about 50mg/L, about 10mg/L – is about 40mg/L, about 10mg/L – is about 30mg/L, about 10mg/L – is about 50mg/L, about 5mg/L, about 10mg/L, about 10mg/L, about 20mg/L, about 30mg/L, about 40mg/L, about 50mg/L or about 100mg/L or higher.
On the one hand, the compound of expeling described herein, control or guiding or composition can with another kind of activating agent conbined usage, described another kind of agents as, insecticide, weed killer herbicide and/or sterilization processing agent.
On the one hand, the invention provides composition, it comprises one or more of expeling disclosed herein, the compound of control or guiding or composition, be made up of the compound of one or more of expeling disclosed herein, control or guiding or composition, or be substantially made up of the compound of one or more of expeling disclosed herein, control or guiding or composition.On the other hand, the invention provides composition, it comprises single expeling disclosed herein, the compound of control or guiding or composition, be made up of the compound of single expeling disclosed herein, control or guiding or composition, or be substantially made up of the compound of single expeling disclosed herein, control or guiding or composition.In another, the invention provides composition, it comprises two kinds, three kinds, four kinds or five kinds or more and plants the compound or composition driving away, control or guide, by two kinds, three kinds, four kinds or five kinds or more plant drive away, control or guide compound or composition form, or substantially by two kinds, three kinds, four kinds or five kinds or more plant drive away, control or guide compound or composition form.On the other hand, the invention provides composition, it comprise two kinds at the most, three kinds at the most, at the most four kinds or at the most five kinds or more plant the compound or composition driving away, control or guide, by two kinds at the most, at the most three kinds, at the most four kinds or at the most five kinds or more plant the compound driving away, control or guide or composition forms, or substantially by two kinds at the most, at the most three kinds, at the most four kinds or at the most five kinds or more plant the compound driving away, control or guide or composition forms.
preparation
Can prepare and pack compound described herein and composition to send this product in a variety of forms, described various ways comprises as solution, suspension, emulsifiable paste, ointment, gel, film or spray, depends on preferred using method.
In nonrestrictive, composition of the present invention can be prepared in a variety of forms and use, as aerosol dispenser, bait (instant), bait concentrate, block bait, capsule suspension, cold mist concentrate, pulvis, missible oil, oil in water emulsion, water-in-oil emulsion, encapsulated particles agent, granula subtilis, grain bait, granular bait, granule, coarse grain agent, fine granule, oil-dispersing property pulvis, oil-soluble can flow concentrate, oil-soluble liquor, paste, sheet bait, chip bait, smoke candle, smoke cartridge, fogger, smog ball, smog rod, smog sheet, smoke candle, solubility concentrate, soluble powder, suspending concentrate, oil dispersibles agent or oily bag suspension, tracking powder (trackingpowder), ultra low volume (ulv) liquor, ultra low volume (ulv) suspending agent, fumigant, water-dispersible granules or tablet, slurry process water-dispersible powder, water-soluble granular formulation or tablet, or the seed treatment release/controlled release formulation of water dissolvable pulvis and wetting powder or any other form.Also can expect other formulations, such as, describe in No. 2006/0223878th, U.S. Patent application those, it is included in herein in the mode quoted as proof in full.
On the other hand, compound described herein or composition can take any form of multiple dosage form, include but not limited to: suspending concentrate, aerosol, capsule suspension, cold mist concentrate, hot mist concentrate, encapsulated particles agent, granula subtilis, the process seed concentrate that can flow, instant solution, pulvis, missible oil, oil in water emulsion, water-in-oil emulsion, coarse grain agent, fine granule, oil-dispersing property pulvis, oil-soluble can flow concentrate, oil-soluble liquor, foam, paste, scribble the seed of insecticide, outstanding newborn concentrate (suspoemulsionconcentrates), solubility concentrate, suspending agent, wetting powder, soluble powder, pulvis and granule, water-soluble granular formulation or tablet, seed treatment water solube powder, wetting powder, adopt compound described herein or the impregnated natural prodcuts of composition or synthetic, adopt compound described herein or the impregnated net of composition, and the microencapsulation in seed polymeric material and coating material, and the cold mist agent of ULV and thermal fog.Also can expect other formulations, such as, describe in No. 2006/0223878th, U.S. Patent application those, it is included in herein in the mode quoted as proof in full.On the one hand, compound described herein or composition are encapsulatings.On the other hand, the compound of formula I – XIII is encapsulated is powder type, and such as, natural powder is as rosemary, Xue MingRosma rinus officinalis powder.In another, sulphur (or sulfo-) analog of one or more of methyl-n-butyl ketones, 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone and relevant oxidation state encapsulated in powder type, as the form of rosemary, Xue MingRosma rinus officinalis powder.
On the other hand, compound described herein or composition are configured to topical composition, such as, and cologne; Suncream; Lotion; Spray; Emulsion; Gel; Ointment; Froth pulp; Soap composition, such as, hand soaps and bath soap/shower soap.On the one hand, the character of expectation that topical insect drives away property article comprises hypotoxicity, to water logging or ooze out the weak or odorlessness of the resistance of the loss caused, smell, be convenient to use, form dry non-adhesive surface film fast on Host Skin.On the other hand, compound described herein or composition are designed to article to be distributed in air or using compound or composition and disperse as liquid mist or fine dust.In addition, on host, direct coating liquid/semi-solid/solid expelling parasite article are effective ways that the surface of a kind of host of making contacts with the anthelmintic composition of effective dose.
On the other hand, compound disclosed herein or composition optionally can comprise one or more of other compounds providing extra benefit or other useful effects.Described compound include but not limited to the fertilizer of adhesive, solvent, wetting agent, emulsifier, carrier, adjuvant, thinner, dispersant, insecticide, insecticide, fungicide, micronutrient or macronutrient character, weed killer herbicide, feed inhibitor, insect molting inhibitor, insect mating inhibitor, the ripe inhibitor of insect, nematocide, nutrition or gardening freshen replenishers, or its any combination.On the one hand, composition described herein is scentless.
On the other hand, compound described herein or composition can with Fertilizer combination.The example of the fertilizer that can use together with method with composition described herein comprises, such as, the chloride of the nitrate of urea, ammonium nitrate, ammonium sulfate, nitrate of lime, diammonium hydrogen phosphate, carbonic acid ammonium dihydrogen, triple super phosphate, potassium nitrate, potash, potassium chloride, potash, phosphite/phosphatic di-potassium and monopotassium salt.
On the one hand, the compound of expeling described herein, control or guiding is following preparation:
Table 2
EC – missible oil; WP – wetting powder; SC – suspending concentrate;
The compound that " compound " refers to expeling, controls or guide
bait or decoy device
Present invention also offers the bait composition comprising compound described herein or composition.On the other hand, the invention provides and comprise expeling described herein, control or the compound of guiding or the bait composition of composition.Described hereinly comprise expeling, to control or the bait composition of the compound that guides or composition can use with any method described herein and can optionally comprise another kind of active component, as insecticide, weed killer herbicide or insecticide.
On the other hand, the invention provides a kind of process, expeling, guiding or control the method for insect infestations, it adds at least one (1) compound described herein or composition and (2) bait material in supporter (support) material, checkout gear or net, and above support material, device or net is placed on the region being easy to suffer insect infestations.On the other hand, above support material, checkout gear or net are placed on the region after confirming insect infestations.In another, above support material, checkout gear or net are placed on the region before confirming insect infestations.
On the one hand, drive away, control or guide the sense of smell of the compound of insect or composition and change insect, vision, the compound of chemical sensation or other physical features or composition to be combined.On the other hand, compound or the compound described herein of driving away insect can be combined with the compound or composition being changed insect lipids by color, taste or capable other characteristics affecting the sensation of insect.Described composition can be added in bait composition.
On the other hand, the invention provides a kind of composition comprising following substances, be made up of following substances or be substantially made up of following substances: compound or the composition of expeling described herein, control or guiding are combined with the compound described in WO2012151556A2, US2013/0125451 and WO2009036450 or composition, and the full text of described patent document is included in in the application in the mode quoted as proof.
In another, the invention provides a kind of composition comprising following substances, be made up of following substances or be substantially made up of following substances: the compound of at least one (1) expeling described herein, control or guiding or composition and at least one (2) honeybee expellent, the expeling of the expeling chemical sensation clue that described honeybee expellent has simulation or simulates 2-HEPTANONE is substantially active.
The invention provides one and comprise following substances, the composition being made up of following substances or being substantially made up of following substances: at least one (1) expeling described herein, the compound controlled or guide or composition and at least one (2): benzyl-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-[(6-nitro-1,3-benzodioxole-5-base) methyl]-4-phenylpiperazine, 4-[4-nitro-3-(2-phenoxy group) phenyl] morpholine, 1-(3-chlorophenyl)-4-[(6-nitro-1,3-benzodioxole-5-base) methyl] piperazine, 1-(4-methoxy-benzyl)-4-(3-methyl-benzyl) piperazine, 4-(4-methoxyl group-2,3-dimethyl benzyl) morpholine, 1-benzyl-4-(4-methoxyl group-3-methyl-benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(1,3-benzodioxole-5-ylmethyl)-4-(4,5-dimethoxy-2-nitrobenzyl) piperazine, 1-(2,3-3,5-dimethylphenyl)-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-phenylpiperazine, 1-[3-(4-iodine phenoxy group) propyl group] piperidines, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-(4-aminomethyl phenyl) piperazine, 2-{ [(2-methoxy-1-naphthyl) methylene] is amino }-1H-iso-indoles-1,3 (2H)-diketone, 2-[(2-ethoxybenzene methylene) is amino]-1H-iso-indoles-1,3 (the 2H)-diketone replaced, 3-ethyl-5-(4-phenol methylene)-2-sulfo--1,3-thiazoles alkane-4-ketone, 3-butyl-5-(3-phenol methylene)-2-sulfo--1,3-thiazoles alkane-4-ketone, 5-(the bromo-4-methoxybenzylidene of the 3-)-3-methyl-2-sulfo--1,3-thiazoles alkane-4-ketone of optional replacement, 5-(the bromo-2-phenol methylene of 5-)-3-ethyl-2-sulfo--1,3-thiazoles alkane-4-ketone, 2-phenyl-4-(2-thienyl methene)-1,3-oxazole-5 (4H)-one, 5-(4-chlorobenzene methylene)-3-(2-methoxyphenyl)-2-sulfo--1,3-thiazoles alkane-4-ketone, 3-(4-bromophenyl)-5-(4-phenol methylene)-2-sulfo--1,3-thiazoles alkane-4-ketone, 4-[the bromo-4-of 3-(dimethylamino) benzylidene]-2-(2-methoxyphenyl)-1,3-oxazole-5 (4H)-one, 4-[2-(4-nitrobenzophenone) vinyl] phenol, 3-{2-[(4-luorobenzyl) is amino] phenyl }-2 (1H)-quinokysalines, the bromo-3-chlorphenyl of 4-) (4-ethoxybenzene methylene) amine, 4-[(2-chloro-5-nitrobenzene methylene) is amino] phenol, 2-[(2-hydroxyl-3,5-diiodo-benzene methylene) is amino]-4,6-xylenols, (2-methoxy-benzyl) (4-methoxyl group-3-xenyl) amine, 2-{ [(5-ethyl-2-hydroxy phenyl) imino group] methyl }-4,6-iodophenesic acids, 3-methoxyl group-4-(4-nitrophenoxy) benzaldoxime, 1-butyl-4-hydroxyl-2-oxo-N-(2-pyridylmethyl)-1,2-dihydro-3-quinoline formyl amine, 2-acetyl group-4-chlorphenyl 4-methyl benzoic acid ester, N-(2-luorobenzyl)-4-hydroxyl-2-oxo-1-propyl group-1,2-dihydro-3-quinoline formyl amine, 2-(benzoyl-amido)-5-ethyl-thenoic acid ethyl ester, 2-(benzoyl-amido)-N-(2-chlorophenyl) benzamide, 2-(3-aminophenyl)-4-quinoline ethyl formate, 1-(4-benzoyl bromide)-2,2,4-trimethyl-1,2-dihydroquinoline, 2-(1,2,2-trimethyl-3-sulfo--2,3-dihydro-4 (1H)-quinoline subunit)-1,3-dithiole-4,5-dimethyl dicarboxylate, 2-(2,2,7-trimethyl-3-sulfo--2,3-dihydro-4 (1H)-quinoline subunit)-1,3-dithiole-4,5-dimethyl dicarboxylate, N-(4-methoxyl group-2,3-dimethyl benzyl)-N, N', N'-trimethyl-1,2-ethylenediamine, the chloro-4-of 1,2,3-tri-(isopropylamino) anthracene-9,10-quinone, and/or [1-(3-nitrobenzyl)-3-piperidyl] methyl 3-phenyl acrylate, (amino-4, the 6-thioxenes of 3-also [2,3-b] pyrimidine-2-base) (4-chlorphenyl) ketone, (4-bromophenyl) (5-methoxyl group-2-methyl isophthalic acid-benzofuran-3-base) ketone, 1-(4-methoxyphenyl)-3-(2-Methyl-1H-indole-3-base)-2-propylene-1-ketone, and/or 2-[2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-phenyl-4-pyrimidine radicals] phenol.On the other hand, above-mentioned substance is optional replacement.On the other hand, above-mentioned substance is optionally replaced by other substituted radicals that can maintain or strengthen expeling effect.
The invention provides one and comprise following substances, the composition being made up of following substances or being substantially made up of following substances: the expeling of at least one (1) formula I – XIII as described herein, the compound controlled or guide and at least one (2): 1-benzyl-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-[(6-nitro-1,3-benzodioxole-5-base) methyl]-4-phenylpiperazine, 4-[4-nitro-3-(2-phenoxy group) phenyl] morpholine, 1-(3-chlorphenyl)-4-[(6-nitro-1,3-benzodioxole-5-base) methyl] piperazine, 1-(4-methoxy-benzyl)-4-(3-methyl-benzyl) piperazine, 4-(4-methoxyl group-2,3-dimethyl benzyl) morpholine, 1-benzyl-4-(4-methoxyl group-3-methyl-benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(1,3-benzodioxole-5-ylmethyl)-4-(4,5-dimethoxy-2-nitrobenzyl) piperazine, 1-(2,3-3,5-dimethylphenyl)-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-phenylpiperazine, 1-[3-(4-iodine phenoxy group) propyl group] piperidines, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-(4-aminomethyl phenyl) piperazine, or its any combination.On the other hand, above-mentioned substance is optionally replaced by other substituting groups that can maintain or strengthen expeling effect.
The present invention also provides one to comprise following substances, the composition being made up of following substances or being substantially made up of following substances: at least one (1) 2-decanone, rosemary oil, rosemary, Xue MingRosma rinus officinalis powder and/or camphor and at least one (2): 1-benzyl-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-[(6-nitro-1,3-benzodioxole-5-base) methyl]-4-phenylpiperazine, 4-[4-nitro-3-(2-phenoxy group) phenyl] morpholine, 1-(3-chlorphenyl)-4-[(6-nitro-1,3-benzodioxole-5-base) methyl] piperazine, 1-(4-methoxy-benzyl)-4-(3-methyl-benzyl) piperazine, 4-(4-methoxyl group-2,3-dimethyl benzyl) morpholine, 1-benzyl-4-(4-methoxyl group-3-methyl-benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-methyl piperazine, 1-(1,3-benzodioxole-5-ylmethyl)-4-(4,5-dimethoxy-2-nitrobenzyl) piperazine, 1-(2,3-3,5-dimethylphenyl)-4-(4-methoxyl group-2,3-dimethyl benzyl) piperazine, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-phenylpiperazine, 1-[3-(4-iodine phenoxy group) propyl group] piperidines, 1-(4-methoxyl group-2,3-dimethyl benzyl)-4-(4-aminomethyl phenyl) piperazine, or its any combination.On the other hand, above-mentioned substance is optionally replaced by other substituting groups that can maintain or strengthen expeling effect.On the one hand, these compounds produce synergistic effect.In another, these compounds produce additive effect.In another, described composition can comprise the reagent being selected from camphor, camphorated oil, camphor powder, tea oil, tea tree ethereal oil, pine tar, rosemary, Xue MingRosma rinus officinalis powder and/or rosemary oil.
co ntrolled release, prolongation release, fast release and multiple coatings delivery formulations
On the other hand, compound described herein or composition can be formulated as Co ntrolled release, prolongation release, rapid delivery forms or its combination.On the other hand, compound described herein or composition can be formulated as multiple coatings or multi-layer preparation.The present invention also provides such preparation, its be designed within the period of about 5 minutes, about 15 minutes, about 30 minutes, about 1 hour, about 2 hours, about 6 hours, about 12 hours, about 24 hours, about 3 days, about 5 days, about 7 days, about 15 days, about 30 days, about 45 days, about 60 days, about 75 days or about 90 days single release time point or multiple release time point release compound described herein or composition.On the other hand, the present invention also provides such preparation, and it is designed in order to littlely littlely littlely to discharge compound disclosed herein or composition up to 2 days, about 1 to about 7 days, about 7 days to about 15 days, about 10 days to about 30 days or about 30 days to about 60 days or in the period of longer time up to about 12 hours, about 24 up to about 6 hours, about 6 at about 30 minutes to about 1 hour, about 1.
On the one hand, rapid release layer or dressing discharged compound immediately after about 1 minute, about 5 minutes, about 15 minutes, about 30 minutes, about 1 hour or about 2 hours.On the other hand, Co ntrolled release layer or dressing discharged compound after about 3 hours, about 6 hours, about 12 hours or about 18 hours.On the other hand, extend release or delayed release layer or dressing and discharge compound after about 1 day, about 2 days, about 3 days, about 7 days or about 14 days or longer time.
Additionally provide such preparation, it passes through, such as, and degraded, light release or unglazed release or moisture and discharge compound or composition.
Present invention also offers a kind of composition with dressing, as follows:
(1) drive away, control or guide the compound of insect or the outside of composition to discharge dressing fast containing described herein first; And
(2) dressing of the compound of insect or at least one Inner elongate release of composition or Co ntrolled release driven away, control or guides containing described herein second.
The present invention also provides a kind of composition with dressing, as follows:
(1) drive away, control or guide the compound of insect or the external control release dressing of composition containing described herein first; And
(2) dressing of the compound of insect or at least one Inner elongate release of composition or Co ntrolled release driven away, control or guides containing described herein second.
drive away or kill compound or the composition of mite
On the one hand, composition described herein can comprise the compound that can control or kill mite.On the one hand, the compound that can control or kill mite is selected from 1-Aryimidazole, 1-aryl-pyrrolidine and 1-arylpyrazole.
On the other hand, the compound that can control or kill mite is selected from formula XIV – XVI:
Wherein,
X is halogen, Cl, F, Br or I;
A
1, A
2and A
3independent selected from halo, Cl, F, Br, I, alkyl or haloalkyl;
Z is H, CN, halogen or alkyl-carbonyl,
N is 0,1 or 2, and
Y is alkyl, methyl, haloalkyl, whole haloalkyl, multi-haloalkyl, CF
2cl, CF
3or CCl
2f.
On the other hand, the compound of formula XIV – XVI can use according to methodology described herein together with compound described herein or composition.
composition or adopt the supporter of compound described herein or compositions-treated
On the one hand, the invention provides the supporter be combined with compound described herein or composition or carrier material.On the other hand, above support material can adopt compound described herein or composition coating or flood.Also insecticide, weed killer herbicide, fungicide or miticide can be added into adopt compound described herein or composition coating or impregnated buttress material in.The example of the buttress material that can use together with compound described herein comprises absorbent material, timber, cardboard, corrugated board, cotton, wallpaper, paper, plastics, plastic tube and metal.The buttress material with low-thermal conductivity is also suitable.
kit
On the other hand, the invention provides a kind of kit, it comprises any compound disclosed herein or composition, is substantially made up of any compound disclosed herein or composition, or is made up of any compound disclosed herein or composition.On the one hand, described kit comprises embodiment 1-15, the compound of table described in 1-24 or Fig. 1-49 or any bond of composition.On the other hand, described kit provides embodiment 1-15, the composition of table described in 1-24 or Fig. 1-49, and according to the mode applying said compositions consistent with the methodology in these embodiments and figure.On the other hand, described kit provides specification about the purposes of composition described herein or method or guidance.
On the one hand, described kit comprises description methodological specification described herein.On the other hand, described kit comprises any one methodological specification of setting forth in description embodiment 1-15, table 1-24 or Fig. 1-49.On the one hand, described specification is included in kit, separates or be included in kit package with kit.
On the other hand, compound or the composition of expeling disclosed herein, control or guiding are included in device or supporter.On the other hand, device can comprise the device of compound being designed to hold and/or protect expeling disclosed herein, control or guiding.In another, device disclosed herein to can be on it or comprising the container of the compound of expeling disclosed herein, control or guiding or composition, support (holder) or other solid support things.Device disclosed herein can by any biology or synthesis material make, include, but not limited to paper, filter paper, timber, cork, cotton, plastics, polymer, metal or glass.
On the other hand, described kit can comprise single and makes disposable checkout gear, bait, buttress material or net.This kit also can comprise reusable multipurpose checkout gear, bait, buttress material or net.
On the other hand, described kit can comprise the fill-in of checkout gear, bait, buttress material or net.Such as, this complementarity kit can comprise other bait composition or other the fill-in to checkout gear, bait, buttress material or net.On the one hand, described complementarity kit separates with described checkout gear, bait, buttress material or net and packs.On the other hand, described complementarity kit is packed together with described checkout gear, bait, buttress material or net.
Following embodiment contributes to illustrating some aspect of the present invention but being not intended to limit the present invention.
embodiment
embodiment 1
Embodiment 1 illustrates the feeding station arrangement repelling experiment for honeybee described herein.
Fig. 1 describes feeding station arrangement (A and B) repelling experiment for honeybee described herein.As shown in Figure 1, picture (A) illustrates the position of the position of the honeybee cage of picture (A) left-hand component and the randomized feeding station of picture (A) right-hand component.Picture (B) illustrates the arrangement of randomized feeding station position, and the distance wherein between feeding station is two meters.Before respective honeycomb, the distance of 10 meters assesses eight total feeding stations.Feeding station is separated from each other two meters.
Training honeybee removes dark feeding apparatus (8 positions) (respectively comprising 50% sucrose solution) a day.After training honeybee removes each feeding apparatus, replace with the shallow feeding apparatus comprised according to the expeling compound of table 3 and the bond of 50% sucrose solution at the 50% sucrose feeding apparatus at random 1-8 place, position.According to Fig. 5 and Fig. 6, second day time, in feeding apparatus, add the camphorated oil (T4) of 2 % by weight, ajowan oil (T5), camphor powder (T6), rosemary oil (T7) and 2-decanone (T8) in conjunction with 50% saccharose treatment.The honeybee at random site 8 (2-decanone) place littlely shows expeling property constantly 24.
embodiment 2
Examples 2 describe multiple actives and drive away the validity in honeybee.
Table 3 describes the activating agent and their randomized feeding station position that repel for assessment of honeybee.Described in table 3, T1 (contrast), T2 (contrast), T3 (contrast), T4 (camphorated oil), T5 (ajowan oil), T6 (camphor powder), T7 (rosemary oil) and T8 (2-decanone).
Table 3
| Digital coding | Process | Random site (feeding station numbering) |
| 1 | C (untreated 50% sucrose) | 6 |
| 2 | C (untreated 50% sucrose) | 7 |
| 3 | C (untreated 50% sucrose) | 1 |
| 4 | Camphorated oil 2.18g/100.4g and 50% sucrose | 4 |
| 5 | Ajowan oil 3.25g/101.1g and 50% sucrose | 2 |
| 6 | The camphor powder of 100 fluid g is diluted to 50% sucrose | 5 |
| 7 | Rosemary oil 2.09g/114g 1g and 50% sucrose | 3 |
| 8 | 2-decanone 8.6g/111.83g 1g and 50% sucrose | 8 |
Fig. 5 have evaluated the number of accessing the honeybee of each feeding station within a time interval.Fig. 6 illustrates the average number of the honeybee of accessing feeding station within the time period of four hours.2-decanone is highly expeling property still have expeling after 24 hours within assessment period of whole 4 hours.Rosemary oil shows initial expeling, but this expeling can not maintain the evaluation time of whole 4 hours completely.
embodiment 3
Embodiment 3 illustrates the stability of Poncho together with insect repellants Eugenol.
Table 4 describe room temperature, at 40 DEG C and 54 DEG C zero-time, 3 days and 7 days time assessment Eugenol and the stability test of bond of Poncho, and to be confirmed by high performance liquid chromatography (HPLC).Described in table 4, when with insect and honeybee expellent Eugenol in conjunction with time, the content of clothianidin (it is the activating agent in Poncho) the display chemical stability of 7 days at up to 54 DEG C.
Table 4
Embodiment 4
Embodiment 4 illustrates the stability of Poncho together with insect repellants alpha-terpineol.
Table 5 describe room temperature, at 40 DEG C and 54 DEG C zero-time, 2 days and 8 days time assessment alpha-terpineol and the stability test of bond of Poncho600, and to be confirmed by HPLC.As described in table 5, when with insect and honeybee expellent alpha-terpineol in conjunction with time, the content (it is the activating agent in Poncho) of the clothianidin display chemical stability of 8 days at up to 54 DEG C.
Table 5
embodiment 5
Embodiment 5 illustrates Gao Qiao (Gaucho) stability together with insect repellants alpha-terpineol.
Table 6 describe room temperature, at 40 DEG C and 54 DEG C zero-time, 2 days and 8 days time the alpha-terpineol of assessment and the stability test of the bond of Gao Qiao, and to be confirmed by high performance liquid chromatography (HPLC).Described in table 6, when with insect and honeybee expellent alpha-terpineol in conjunction with time, the content (it is the activating agent in Gaucho) of the Imidacloprid display chemical stability of 8 days at up to 54 DEG C.
Table 6
Embodiment 6
Embodiment 6 illustrates use 50% sucrose solution and assesses the method for honeybee expeling property for experiment first.
In this embodiment, about 10 meters of before honeybee honeycomb built in by feeding station platform.Honeybee is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.Take pictures at each time point and from picture, add up the number of honeybee subsequently.The number of the honeybee added up at each time point represents in Fig. 8-24.
Table 9 describes activating agent and their relevant abbreviations of assessment honeybee repellency, refers in Fig. 8-24.
Table 9
| Numbering | Process type | Process abbreviation |
| 1 | Sucrose (50%)+water | SUC50 |
| 2 | 2-decanone (0.5%)+sucrose (50%) | 2D.5 |
| 3 | 2-decanone (0.1%)+sucrose (50%) | 2D.1 |
| 4 | 2-decanone (1%)+sucrose (50%) | 2D1 |
| 5 | 2-decanone (2%)+sucrose (50%) | 2D2 |
| 6 | 2-decanone (2%) camphorated oil (2%)+sucrose (50%) | 2D2+CAMO |
| 7 | 2-decanone (2%)+rosemary oil (2%)+sucrose (50%) | 2D2+ROSO2 |
| 8 | Rosemary, Xue MingRosma rinus officinalis powder (2%)+sucrose (50%) | ROSP2 |
| 9 | Tea oil (2%)+sucrose (50%) | TT |
| 10 | Pine tar (0.5%)+sucrose (50%) | PO |
| 11 | Methyln nonyl ketone (2%) (11 carbon)+sucrose (50%) | 2UD |
| 12 | Methyl n-heptyl ketone (2%) (9 carbon)+sucrose (50%) | 2NON |
| 13 | Rosemary, Xue MingRosma rinus officinalis powder (1%)+2-decanone (1%)+sucrose (50%) | ROSP1+2D1 |
| 14 | 2-decanone (0.5%) tea oil (0.5%)+pine tar (0.5%)+sucrose | 2D.5+TT+PO |
| 15 | Rosemary, Xue MingRosma rinus officinalis powder (1%)+sucrose (50%) | ROSP1 |
| 16 | Camphor powder (2%)+sucrose (50%) | CAMP |
| 17 | Water | Water |
The preparation of embodiment sample is represented by following method: 50% sucrose solution prepared of 500 grams weighs in suitable 500ml bottle, adds the expeling material of the expectation of 2 % by weight (10 grams), as in Fig. 8-24 characterize.This 500ml bottle is closed and jolting.When Efficacy, violent jolting sample fast sampling.
For 50% sucrose solution, 1000 grams of sugar are mixed together with 1000 grams of deionized waters in 2 liters of glass jars.
embodiment 7
Embodiment 7 describe multiple actives with kill insect active agent (as Imidacloprid) in conjunction with time driving away the validity in honeybee.
In this embodiment, feeding station platform is built in before honeybee honeycomb.Honeybee is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.Take pictures at each time point and from picture, add up the number of honeybee subsequently.The number of the honeybee added up at each time point represents in Figure 25 and 26.
Table 10 describes and kills insect active agent (as Imidacloprid) and combine activating agent for assessment of honeybee repellency.
Table 10
| Process numbering | Explanation | Abbreviation |
| 1 | 2-decanone (0.5 % by weight)+20ppb Imidacloprid+sugar (50%), in water | 2D.5+20imid |
| 2 | 2-decanone (0.5 % by weight)+10ppb Imidacloprid+sugar (50%), in water | 2D.5+10imid |
| 3 | 2-decanone (2 % by weight)+20ppb Imidacloprid+sugar (50%), in water | 2D2+20imid |
| 4 | 2-decanone (2 % by weight)+10ppb Imidacloprid+sugar (50%), in water | 2D2+10imid |
| 5 | Rosemary, Xue MingRosma rinus officinalis powder (2 % by weight)+20ppb Imidacloprid+sugar (50%), in water | Ros2+20imid |
| 6 | Rosemary, Xue MingRosma rinus officinalis powder (2 % by weight)+10ppb Imidacloprid+sugar (50%), in water | Ros2+10imid |
| 7 | 20ppb Imidacloprid+sugar (50%), in water---in contrast | 20imid |
| 8 | 10ppb Imidacloprid+sugar (50%), in water---in contrast | 10imid |
Table 11 describes the expeling of 20ppb Imidacloprid+sugar (50 % by weight) compared with 2-decanone (0.5 % by weight)+20ppb Imidacloprid+sugar (50 % by weight).
Table 11
embodiment 8
Embodiment 8 illustrates the described herein active expellent together with fluency/planter lubricant described herein.
In this embodiment, feeding station platform is built in before honeybee honeycomb.Training honeybee removes fondant base, and it has moldable denseness and it comprises the mixture of rock sugar, honey and water and serves as the attractant of insect and honeybee.Honeybee is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.Take pictures at each time point and from picture, add up the number of honeybee subsequently.The number of the honeybee added up at each time point represents in Figure 31-32.
In this embodiment, according to table 12, activating agent 2-decanone is added together with Tissuemat E with graphite, talcum.
Table 12 describes and each dustfall agent or the lubricant activating agent for assessment of honeybee repellency.
Table 12
Table 13 describes the average number (" X " hour/" X " minute) of honeybee, and this average number is the mean value of three independent experiments of activating agent and each dustfall agent or lubricant.
Table 13
| Interval | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
| TA+2D | GR+2D | PE+2D | TA+F | GR+F | PE+F | FC | |
| 0H15 | 1.3 | 1.3 | 4.3 | 2.0 | 79.3 | 22.7 | 425.0 |
| 0H30 | 1.0 | 0.7 | 18.7 | 6.0 | 164.0 | 86.0 | 600.0 |
| 0H45 | 1.3 | 1.0 | 20.7 | 9.7 | 214.0 | 89.7 | 650.0 |
| 1H00 | 1.7 | 1.7 | 24.3 | 17.3 | 273.0 | 127.7 | 691.7 |
| 1H15 | 0.7 | 1.3 | 26.0 | 18.3 | 298.3 | 115.0 | 691.7 |
| 1H30 | 0.7 | 1.3 | 23.3 | 19.0 | 338.7 | 137.0 | 708.3 |
| 1H45 | 0.7 | 1.0 | 29.3 | 23.3 | 440.7 | 153.3 | 708.3 |
| 2H00 | 1.3 | 1.7 | 27.7 | 27.3 | 466.3 | 187.0 | 708.3 |
| 2H15 | 0.7 | 1.3 | 34.0 | 34.7 | 503.0 | 211.7 | 708.3 |
| 2H30 | 1.7 | 1.3 | 29.3 | 42.3 | 534.3 | 207.7 | 708.3 |
| 2H45 | 1.3 | 2.0 | 37.0 | 44.3 | 549.3 | 221.7 | 666.7 |
| 3H00 | 0.7 | 2.0 | 30.7 | 55.0 | 616.7 | 187.0 | 650.0 |
| 3H15 | 0.3 | 3.3 | 36.3 | 66.3 | 616.7 | 215.7 | 633.3 |
| 5H15 | 1.3 | 22.3 | 34.0 | 144.0 | 519.0 | 252.7 | 464.0 |
| 7H00 | 18.7 | 108.7 | 33.0 | 186.7 | 396.0 | 235.0 | 318.7 |
| 24H00 | 323.3 | 341.3 | 172.7 | 317.7 | 275.3 | 261.7 | 51.7 |
Table 14 describes the average number of honeybee, and this average number is the mean value of three independent experiments of activating agent and each dustfall agent or lubricant.
Table 14
| Interval | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
| TA+2D | GR+2D | PE+2D | TA+F | GR+F | PE+F | FC | |
| 0H15 | 1.3 | 1.3 | 4.3 | 2.0 | 79.3 | 22.7 | 425.0 |
| 0H30 | 1.0 | 0.7 | 18.7 | 6.0 | 164.0 | 86.0 | 600.0 |
| 0H45 | 1.3 | 1.0 | 20.7 | 9.7 | 214.0 | 89.7 | 650.0 |
| 1H00 | 1.7 | 1.7 | 24.3 | 17.3 | 273.0 | 127.7 | 691.7 |
| 1H15 | 0.7 | 1.3 | 26.0 | 18.3 | 298.3 | 115.0 | 691.7 |
| 1H30 | 0.7 | 1.3 | 23.3 | 19.0 | 338.7 | 137.0 | 708.3 |
| 1H45 | 0.7 | 1.0 | 29.3 | 23.3 | 440.7 | 153.3 | 708.3 |
| 2H00 | 1.3 | 1.7 | 27.7 | 27.3 | 466.3 | 187.0 | 708.3 |
| 2H15 | 0.7 | 1.3 | 34.0 | 34.7 | 503.0 | 211.7 | 708.3 |
| 2H30 | 1.7 | 1.3 | 29.3 | 42.3 | 534.3 | 207.7 | 708.3 |
| 2H45 | 1.3 | 2.0 | 37.0 | 44.3 | 549.3 | 221.7 | 666.7 |
| 3H00 | 0.7 | 2.0 | 30.7 | 55.0 | 616.7 | 187.0 | 650.0 |
| 3H15 | 0.3 | 3.3 | 36.3 | 66.3 | 616.7 | 215.7 | 633.3 |
| 5H15 | 1.3 | 22.3 | 34.0 | 144.0 | 519.0 | 252.7 | 464.0 |
| 7H00 | 18.7 | 108.7 | 33.0 | 186.7 | 396.0 | 235.0 | 318.7 |
| 24H00 | 323.3 | 341.3 | 172.7 | 317.7 | 275.3 | 261.7 | 51.7 |
Figure 27 illustrates after 2.5 hours by the visual representation of number of honeybee of luring to the contrast of 500g fondant.
In Figure 28, constantly little 3.25, the expeling of 10g graphite and 500g fondant (A) and (B) 10g graphite, intuitively the comparing of 500g fondant and expellent 2-decanone (0.5 % by weight).
In Figure 29, constantly little 5.25, the expeling of 10g talcum and 500g fondant (A) and (B) 10g talcum, intuitively the comparing of 500g fondant and expellent 2-decanone (0.5 % by weight).
In fig. 30, constantly little 7, the expeling of 10g talcum and 500g fondant (A) and (B) 10g talcum, intuitively the comparing of 500g fondant and expellent 2-decanone (0.5 % by weight).
embodiment 9
Embodiment 9 describes and uses the multiple actives of fondant base driving away the validity in honeybee.
In this embodiment, feeding station platform is built in before honeybee honeycomb.Training honeybee goes to comprise sugar mixture and is the fondant base of insect and honeybee attractant.Honeybee is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.Take pictures at each time point and from photo, count the number of honeybee subsequently.The number of the honeybee counted at each time point represents in Figure 33-35.
Table 15 describes activating agent for assessment of honeybee repellency and relevant abbreviation.
Table 15
embodiment 10
Embodiment 10 describes and uses the multiple actives of fondant base driving away the validity in wasp.
In this embodiment, feeding station platform is built in before wasp honeycomb.Training wasp removes fondant base.Wasp is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.Take pictures at each time point and from photo, count the number of honeybee subsequently.The number of the wasp counted at each time point represents in Figure 36,37 (A) and (B), 38 and 39.
embodiment 11
Embodiment 11 describes and uses the multiple actives of fondant base driving away the validity in honeybee.
In this embodiment, feeding station platform is built in before honeybee honeycomb.Training honeybee removes fondant base.Honeybee is trained to remove feeding apparatus in the precontract implementing Efficacy in 24 hours subsequently.After training 24 hours, untreated feeding apparatus is replaced with at random the feeding apparatus of the process of specifying.The expeling characteristic of assessment activating agent, described in table 16 and Figure 41.Take pictures at each time point and from photo, count the number of honeybee subsequently.The number of the honeybee counted at each time point represents in Figure 40-41.
Table 16 describes the activating agent for assessment of honeybee repellency.
Table 16
| Position | Process | Explanation | Abbreviation |
| 1 | 3 | Corn seed (400g)+fondant (500g) | CS |
| 2 | 9 | Fondant (500g) contrasts | FC |
| 3 | 5 | 1-methylsulfinyl octane (0.5 % by weight)+fondant (500g) | MSO |
| 4 | 2 | 3-decanone (1 % by weight)+fondant (500g) | 3D1 |
| 5 | 6 | Rosemary, Xue MingRosma rinus officinalis powder (2 % by weight)+fondant (500g) | ROSP2 |
| 6 | 1 | 2-dodecane ketone (1 % by weight)+fondant (500g) | 2DOD1 |
| 7 | 4 | Corn seed (400G)+fondant (500g)+2-decanone (0.5 % by weight) | CS+2D.5 |
| 8 | 8 | Rosemary, Xue MingRosma rinus officinalis powder (1 % by weight)+fondant (500g) | ROSP1 |
| 9 | 7 | Rosemary, Xue MingRosma rinus officinalis powder (1.5 % by weight)+fondant (500g) | ROSP1.5 |
Claims (34)
1. one kind for driving away or guiding insect away from the method for structure, article and/or organism, comprise and adopt compositions-treated structure, article and/or organism, described composition comprise about 0.1 to about 2.5 % by weight one or more of be selected from formula (compound of I) – (IX):
Wherein,
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure;
R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately.
2. method according to claim 1, wherein R
1for methyl or ethyl and R
2be selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl.
3. method according to claim 1, wherein said one or more of compound is C
7– C
15ketone.
4. method according to claim 3, wherein said C
7– C
15ketone is selected from the sulfur analogs of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone.
5. method as claimed in one of claims 1-4, wherein said insect is insect pollinator and described insect pollinator is optionally honeybee, wasp or wasp.
6. method as claimed in one of claims 1-5, wherein said one or more of compound is driven away or is guided the insect of at least 95% away from described structure, article and/or organism at least 24 hours.
7. method as claimed in one of claims 1-6, wherein said one or more of compound is configured to the composition comprising the reagent being selected from camphor, camphorated oil, camphor powder, tea oil, pine tar, rosemary, Xue MingRosma rinus officinalis powder, rosemary oil and rosemary, Xue MingRosma rinus officinalis powder.
8. method according to claim 3, wherein with the Compound Phase ratio being selected from camphorated oil, ajowan oil, camphor powder and rosemary oil of suitable percentage by weight, described C
7– C
15ketonic compound is driven away or is guided the insect of higher percentage.
9. method as claimed in one of claims 1-8, wherein said structure is selected from commercial establishment or residential building, the inside of commercial establishment or residential building or outside, house, vehicle, ship, balcony, deck, furniture, window, container, designs the container preserving insect, designs the container in order to drive away, to guide or control insect, dustbin or refuse container, the interior space, the exterior space, tree, shrub, lawn, canopy, clover, shrub, the structure that flowering plant can be contacted by insect with other or invade and harass.
10. method as claimed in one of claims 1-8, wherein said article are selected from bait, bait mechanical device or holder, clothes, waistband, air freshener, candle, fiber, bedding, sheet, fabric, clothes, net, insect net, fabric, paper, glass, paint, ink, clay, cotton, timber, furniture, carpet, plastics, polymer, biology or synthetic material, spray product, atomizing system, foam, gel, evaporator product, particle and dust.
11. 1 kinds of bait composition, comprise
(a) about 0.1 to about 2.5 % by weight one or more of be selected from formula (compound of I) – (IX):
Wherein,
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure;
R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately; And
B () is selected from the reagent of camphorated oil, ajowan oil, camphor powder and rosemary oil.
12. bait composition according to claim 11, wherein said one or more of compound comprises C
7– C
15ketone.
13. bait composition according to claim 12, wherein said C
7– C
15compound is selected from the sulfur analogs of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone.
14. bait composition any one of claim 11-13, wherein said insect be insect pollinator and optional be honeybee, wasp or wasp.
15. bait composition any one of claim 11-14, wherein said bait composition is driven away or is guided the insect at least 8 hours of at least 90%.
16. bait composition any one of claim 11-15, wherein said bait composition comprises
(a) C
7– C
15ketone, and
(b) camphorated oil, camphor powder, rosemary, Xue MingRosma rinus officinalis powder and/or rosemary oil.
17. bait composition any one of claim 12 or 16, wherein with containing being selected from camphorated oil, ajowan oil, camphor powder compare with the composition of the compound of rosemary oil, described C
7– C
15ketonic compound is driven away, control or guide the insect of higher percentage.
18. bait composition any one of claim 11-17, wherein said bait composition is configured to Co ntrolled release composition, delayed release compositions, fast release composition and combination thereof.
19. bait composition any one of claim 11-18, wherein said composition also comprises and is selected from insecticide, fungicide, insecticide and acaricidal reagent treatment.
20. bait composition according to claim 19, wherein said miticide is selected from 1-Aryimidazole, 1-aryl-pyrrolidine and 1-arylpyrazole.
21. 1 kinds of structure or article can driving away, control or guide insect from structure or article, wherein adopt containing have an appointment 0.1 to about 2.5 % by weight the one or more of compound treatment being selected from formula (I) – (IX) described in structure or article:
Wherein,
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure; And
R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately.
22. structure or the article can driving away, control or guide insect from structure or article, wherein said composition is driven away or is guided the targeted insect of at least 60% away from described structure, article and/or organism at least 3 hours, preferably, wherein said composition is driven away or is guided the targeted insect of at least 80% away from described structure, article and/or organism at least 8 hours.
23. comprise about 0.1 to about 2.5 % by weight one or more of be selected from formula (purposes of the composition of the compound of I) – (IX):
Wherein,
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure;
R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately;
Wherein said composition is driven away or is guided insect away from structure, article and/or organism.
24. purposes according to claim 23, wherein R
1for methyl or ethyl and R
2be selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl.
25. purposes according to claim 23, wherein one or more of compound is C
7– C
15ketone.
26. purposes according to claim 25, wherein said C
7– C
15ketone is selected from the sulfur analogs of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone.
27. purposes any one of claim 23-26, wherein said insect is insect pollinator and described insect pollinator is optionally honeybee, wasp or wasp.
The purposes of 28. bait composition, described bait composition comprises
(a) about 0.1 to about 2.5 % by weight one or more of be selected from formula (compound of I) – (IX):
Wherein,
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryloxy group, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure;
R
3and R
4be selected from H, alkyl, methyl, ethyl, propyl group or butyl separately; And
B () is selected from the reagent of camphorated oil, ajowan oil, camphor powder and rosemary oil;
Wherein said bait composition is from structure, article or organism expeling, control or guiding target insect.
The purposes of 29. bait composition according to claim 28, wherein one or more of compound comprises C
7– C
15ketone.
The purposes of 30. bait composition according to claim 29, wherein said C
7– C
15compound is selected from the sulfur analogs of 3-heptanone, 4-heptanone, cycloheptanone, methyln-hexyl ketone, 3-octanone, cyclooctanone, methyl n-heptyl ketone, cyclononanone, 2-decanone, 3-decanone, 4-decanone, 5-decanone, methyln nonyl ketone, 2-dodecane ketone, methyl n-undecyl ketone, 2-tetradecane ketone, 2-pentadecanone, 2-hexadecane ketone, 2-heptadecanone, ring decanone and 2-decanone.
The purposes of 31. bait composition any one of claim 28-30, wherein said insect is insect pollinator and is optionally honeybee, wasp or wasp.
32. 1 kinds for driving away or guiding insect away from the method for structure, article and/or organism, comprise adopt containing have an appointment 0.1 to about 2.5 % by weight one or more of formula X compound compositions-treated described in structure, article and/or organism, described formula X compound is selected from:
R
1-S(O)
n-R
2(X)
Wherein,
N is 0,1 or 2; And
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryl, aryloxy group, aryl alkyl, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure, phenyl, substituted-phenyl, optionally by phenyl that one or more of halogen, alkyl, nitro, cyano group, alkoxyl, alkylthio group and oxidation state, acylamino-, amino, alkyl-carbonyl, alkoxy carbonyl, hydroxycarbonyl group and hydroxyl replace.
32. 1 kinds of bait composition, it comprises
The one or more of compounds being selected from formula (X) of (a) about 0.1 to about 2.5 % by weight:
R
1-S(O)
n-R
2(X)
Wherein,
N is 0,1 or 2; And
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryl, aryloxy group, aryl alkyl, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure, phenyl, the phenyl of replacement, optionally by phenyl that one or more of halogen, alkyl, nitro, cyano group, alkoxyl, alkylthio group and oxidation state, acylamino-, amino, alkyl-carbonyl, alkoxy carbonyl, hydroxycarbonyl group and hydroxyl replace; And
B () is selected from the reagent of camphorated oil, ajowan oil, camphor powder and rosemary oil.
The purposes of 33. 1 kinds of bait composition, described composition comprises
A the compound of the one or more of formulas (X) of () about 0.1 to about 2.5 % by weight, is selected from:
R
1-S(O)
n-R
2(X)
Wherein,
N is 0,1 or 2; And
R
1and R
2independently selected from methyl, ethyl, propyl group, isopropyl, cyclopropyl, butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl and replacement or unsubstituted C
2-C
14-alkyl, replacement or unsubstituted C
2-C
14thiazolinyl, replacement or unsubstituted C
2-C
14-alkynyl, the alkyl by following group replaces: halogen, F, Cl, Br, I, oxygen, hydroxyl, alkoxyl, cyano group, aryl, aryloxy group, aryl alkyl, C=C, C ≡ C, nitrogen, NH
2, alkyl amino, dialkylamine, trialkylamino, SH, alkylthio group, or R
1and R
2be joined together to form replacement or unsubstituted (CH
2)
3, (CH
2)
4, (CH
2)
5, (CH
2)
6, (CH
2)
7, (CH
2)
8, (CH
2)
9, (CH
2)
10, (CH
2)
11, (CH
2)
12, (CH
2)
13ring structure, phenyl, substituted-phenyl, optionally by phenyl that one or more of halogen, alkyl, nitro, cyano group, alkoxyl, alkylthio group and oxidation state, acylamino-, amino, alkyl-carbonyl, alkoxy carbonyl, hydroxycarbonyl group and hydroxyl replace; And
B () is selected from the reagent of camphorated oil, ajowan oil, camphor powder and rosemary oil;
Wherein said bait composition is from structure, article or organism expeling, control or guiding target insect.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2014/033802 WO2014146143A2 (en) | 2013-03-15 | 2014-04-11 | Compounds, compositions, and methods for repelling an insect from an area, article, and/or structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105208858A true CN105208858A (en) | 2015-12-30 |
Family
ID=55023803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480028521.6A Pending CN105208858A (en) | 2014-04-11 | 2014-04-11 | Compounds, compositions, and methods for repelling an insect from an area, article, and/or structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105208858A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109805011A (en) * | 2019-03-21 | 2019-05-28 | 穗港(广州)生物科技有限公司 | A kind of domestic hygiene insecticide and preparation method thereof |
| CN116789574A (en) * | 2022-03-17 | 2023-09-22 | 南京林业大学 | Preparation method and application of camphorsulfonamide compound containing diphenyl ether group |
-
2014
- 2014-04-11 CN CN201480028521.6A patent/CN105208858A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109805011A (en) * | 2019-03-21 | 2019-05-28 | 穗港(广州)生物科技有限公司 | A kind of domestic hygiene insecticide and preparation method thereof |
| CN116789574A (en) * | 2022-03-17 | 2023-09-22 | 南京林业大学 | Preparation method and application of camphorsulfonamide compound containing diphenyl ether group |
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Application publication date: 20151230 |