Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J11/00—Recovery or working-up of waste materials
  • C08J11/04—Recovery or working-up of waste materials of polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
  • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P20/00—Technologies relating to chemical industry
  • Y02P20/141—Feedstock
  • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W30/00—Technologies for solid waste management
  • Y02W30/50—Reuse, recycling or recovery technologies
  • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

• Polyesters are polymeric materials made from the esterification of polybasic organic acids with polyhydric acids. Perhaps the most commonly made and used polyester is polyethylene terephthalate (PET), which can be manufactured by reacting terephthalic acid with ethylene glycol.
• PET polyethylene terephthalate
• Polyesters are currently being used in increasing amounts in various applications. For instance, polyesters are commonly used to make many types of beverage and food containers, photographic films, X-ray films, magnetic recording tapes, electrical insulation, surgical aids such as synthetic arteries, fabrics and other textile products.
• polyesters can be remelted and reformed, ongoing efforts are underway to efficiently recycle as much polyester as possible after use. Before polyester can be recycled, however, it is necessary to separate the post-consumer polyester from contaminants, i.e., materials that may be found mixed with or attached to the polyester. For instance, contaminants can be loose and mixed with the polyester materials, can be attached to the surface of the polyester materials, as with labels attached to the surface of the materials, or can be within the polyester materials, as in the case of embedded or entrained materials.
• contaminants i.e., materials that may be found mixed with or attached to the polyester.
• contaminants can be loose and mixed with the polyester materials, can be attached to the surface of the polyester materials, as with labels attached to the surface of the materials, or can be within the polyester materials, as in the case of embedded or entrained materials.
• the disclosed invention is directed to methods for separating contaminants from polyester.
• the disclosed process can separate polyester from contaminants that are embedded or entrained in the polyester, contaminants that are attached to the surface of the polyester, and/or contaminants that are merely mixed with the polyester.
• the method can be described as a multi-stage process including a preparation stage and a reaction stage.
• the preparation stage can include an operation for chopping the polyester and forming a mixture including polyester and contaminants.
• the polyester can be chopped to a flake size of less than about 15mm.
• the preparation stage can include various operations for physically removing a portion of the contaminants from the polyester mixture including, for instance one or more elutriation processes, in which various loose contaminants, including contaminants such as metals and paper, can be removed from the mixture or a dry-cleaning operation, in which contaminants can be removed from the substantially dry mixture by fluidizing the dry mixture and spinning the dry mixture about the axis of the cleaning chamber such that a portion of the mixture collides with a mesh wall as the mixture spins about the axis, and passing a portion of the contaminants through the mesh.
• Another dry separation process that can be included in the preparation stage is a color-sorting process.
• a color sorting process during the preparation stage can remove various contaminants including, for example, metals and colored PET, such as Ti ⁇ 2 -containing PET.
• the mixture can be subjected to a high quality metal detection and removal operation.
• multiple metal detectors can be placed in series and/or parallel combination to form banks of metal detectors.
• the mixture can then be fed through one or more banks of metal detectors for the removal of metal contaminants.
• the stream can be split into accepted materials (those that pass on to the next step in the process) and rejected materials (those containing metal).
• materials can be recycled back through the metal removal operation.
• the sensitivity of the metal detectors in series can be increased with progression of the series.
• a high quality metal detection and removal operation can not only increase the amount of metal removed from the product stream as compared to previously known processes, but can also, with the addition of the recycle stream, reduce the amount of polyester that can be lost from the stream during the separation process.
• the preparation stage of the process can include one or more aqueous separation operations.
• one or more aqueous separation operations such as high intensity washing operations and sink/float operations can be utilized.
• the process can be further improved by recirculating the water used in the aqueous separation operations through a recirculation tank.
• the mixture can be processed according to a reaction stage that can include a high energy mixing operation as well as a heat setting operation.
• a slurry including the polyester/contaminant mixture and an alkaline composition can be formed within or optionally prior to being fed into a high-energy mixer.
• the alkaline composition can include sodium hydroxide, calcium hydroxide, magnesium hydroxide, potassium hydroxide, lithium hydroxide, or mixtures thereof.
• the amount of alkaline composition added to the slurry can include an amount of alkaline so as to react with less than all of the polyester.
• the alkaline composition that can be combined with the mixture in one embodiment can be an amount sufficient to react with less than about 20% by weight of the polyester.
• the slurry can be formed in a more conventional mixer prior to being fed to the high-energy mixer for reaction.
• the alkaline composition and the dry polyester mixture can first be combined in a low-energy mixer prior to being fed to the high-energy mixer.
• the polyester flakes contained in the slurry can be coated with the alkaline composition.
• the energy input to the slurry while contained in the low-energy mixer can be controlled such that the alkaline composition can react with certain impurities that may be included in the polyester mixture.
• the low-energy mixer can be maintained so as to promote the reaction of aluminum contaminants with the alkaline composition while the slurry is in the low-energy mixer.
• the high-energy mixer used can be a mixer in which sufficient energy can be imparted to the slurry from the mixing action itself so as to promote a saponification reaction between a portion of the polyester and the alkaline composition. In particular, during the high energy mixing operation any heat added to the high-energy mixer will not independently provide sufficient energy to promote the saponification reaction.
• the mixture can be further processed, for example, in those embodiments wherein food-grade polyester materials are desired for the polyester product of the process.
• the slurry can be heated to a temperature that is not greater than the melting point of the polyester. In particular, the mixture can be heated in an environment including less than about 80 ppm water content.
• the mixture can be heated in an oxygen- starved environment. This is not a requirement of the invention, however, and in other embodiments, the mixture can be heating in an oxygen-rich environment.
• the mixture can be pre-heated prior to the heating step, for instance to dry the mixture. According to this embodiment, the mixture can be preheated to a temperature less than about 160 0 C.
• the method can also include operations for recovery of various byproducts produced during the separation and/or reaction operations.
• ethylene glycol can be produced in the saponification reaction. If desired, the ethylene glycol can be recovered following the saponification reaction.
• the method can beneficially be utilized to remove many hard-to- separate contaminants from polyester. For instance, in one embodiment in which the contaminants include polyvinyl chloride, a portion of the alkaline composition can react with the polyvinyl chloride, causing the polyvinyl chloride to become dechlorinated during the reaction.
• aluminum mixed with the polyester can react with a portion of the alkaline composition and be removed from the mixture, for instance as an aluminum salt or as the brittle aluminum remains of the reaction.
• Figure 1 illustrating a flow diagram of one embodiment of a polyester recycling process according to the present invention
• Figure 2 illustrating a flow diagram of one embodiment of a multi- step, high quality metal removal system according to the present invention.
• the present invention is generally directed to a process for separating and recovering post-consumer polyester from various contaminant materials.
• the invention can be utilized to separate post-consumer polyester from various contaminants including glass, dirt, paper, metal, glue, dye, and the like.
• the disclosed process includes multiple stages, including a preparation stage, in which the a portion of the contaminants can be removed from a mixture containing contaminants and polyester, as well as a reaction stage, in which a portion of the polyester can be saponified thus allowing additional contaminants to be separated from the polyester.
• contaminants that are physically attached to or within the polyester can become detached, so as to be more easily removed from the mixture in separation steps.
• a polyester is defined as an esterification or reaction product between a polybasic organic acid and a polyol. It is believed that any known polyester or copolyester may be used in the process of the present invention. However, in one particular embodiment, the process of the present invention is directed to a class of polyesters referred to herein as polyol polyterephthalates, in which terephthalic acid serves as the polybasic organic acid.
• a polybasic organic acid refers to any organic acid having two or more carboxyl groups (-COOH).
• Most polyesters are derived from dibasic acids, also referred to as dicarboxylic acids.
• Polybasic acids can have a linear or a cyclic conformation.
• linear polybasic acids that can be used to make polyesters include the aliphatic dicarboxylic acids.
• the aliphatic dicarboxylic acids having up to ten carbon atoms in their chains can be used. These acids include adipic acid, glutaric acid, succinic acid, malonic acid, oxalic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, maleic acid, and fumaric acid.
• Cyclic polybasic organic acids include the carbocyclic dicarboxylic acids. These acids include phthalic acid, isophthalic acid, and terephthalic acid. In particular, terephthalic acid is used to make polyethylene terephthalate, which is perhaps the most common commercially available polyester.
• a polybasic organic acid can be reacted with a polyol to produce a polyester.
• Polyols are compounds that contain at least two hydroxyl groups. Many polyesters are synthesized with a diol. Diols are normally prepared from an alkene by the net addition of two hydroxy groups to the double carbon bond in a method known as hydroxylation. Polyols are commonly referred to as glycols and polyhydric alcohols. Examples of polyols used to make polyesters include ethylene glycol, propylene glycol, butylene glycol, and cyclohexane dimethanol.
• Table 1 contains a nonexhaustive list of commercially available polyesters that may be recovered and recycled according to the present invention. For each polyester, the corresponding polybasic organic acid and polyol are provided. Table 1
• the polyester being recovered can be polyethylene terephthalate (PET). Accordingly, much of this discussion is directed to PET, though this should not be considered as limiting the invention in any way to the recovery and decontamination of PET.
• PET polyethylene terephthalate
• the process of the present invention can be considered as a three-stage operation for removing contaminants from polyester and can include a preparation stage, a reaction stage, and a finishing stage.
• each stage of the overall process can include one or more individual operations.
• the preparation stage can include at least one dry separation operation and at least one aqueous separation operation, during which contaminants can be removed from the polyester-containing mixture.
• Following the preparation stage can be a reaction stage in which the mixture containing polyester and contaminants can be combined with an alkaline composition. The alkaline can react with a portion of the polyester in a saponification reaction as well as reacting with various possible contaminants in the mixture so as to degrade or otherwise chemically convert the contaminants to a form more easily separable from polyester.
• This stage of the process can also include the separation and removal of contaminants from the mixture, if desired.
• the reaction stage can also include various heat setting reactions that can, among other benefits, further purify the polyester substrate and improve the physical characteristics of the product material.
• the final finishing stage of the process can include operations to improve the quality of the product through, for example, washing and sorting of the product as well as additional separation operations.
• the process of the present invention can run continuously or can be set up as a batch system. In addition, any particular operation of the process can be run as a continuous or batch system. Practically any material containing a polyester can be processed according to the invention. In one preferred embodiment, the polyester materials can be recovered from the solid waste stream, thus alleviating many environmental concerns and disposal problems.
• the process can be directed to recovery and recycling of food and/or beverage containers made from PET.
• polyesters can be separated, recovered and reused from post- consumer waste, even when the polyesters are found mixed with certain hard-to- separate materials, such as polyvinyl chloride or aluminum, adhered to various coatings, or entrained with either various materials, such as organic and/or inorganic compounds.
• certain hard-to- separate materials such as polyvinyl chloride or aluminum
• Barrier materials removable according to the present invention can include barrier coatings that can be, for example, applied to beverage containers in order to prevent carbon dioxide and/or oxygen flow across the substrate.
• Other barrier materials that can be removed according to the present process can include certain chemical barrier material additives, for example chemical scavenger materials added to the polyester materials during initial formation, and/or the breakdown products formed upon reaction of such additives.
• the disclosed process can be utilized to remove barrier materials applied as coatings for location between layers on multi-layer bottles.
• the process can remove other coatings from the polyester materials as well.
• the process can remove applied labels, including paper and/or polymeric labels, screen-printed labels, and the like.
• screen printed labels generally refers to inks that have been directly applied to polyester containers, such as beverage containers. For instance, many soft drink containers are typically labeled with an epoxy-based ink. In the past, many problems have been encountered in attempting to separate polyester from these types of coatings and inks.
• a non-limiting exemplary list of barrier materials (both coatings and chemical constituents contained throughout the polyester substrate) and non- barrier coatings materials that can be removed from polyester according to the present invention can include, for example, saran, nylon, polyvinylidene chloride, acrylics, epoxy-based polymers, acetaldehyde scavengers, ethyl vinyl alcohol (e.g., EVOH films) and the like.
• the process of the present invention is also effective in removing entrained organic and/or inorganic compounds that may have been absorbed by polyester materials.
• Exemplary compounds can include, for instance, toluene, gasoline, used motor oil, paint, pesticide residues, and other volatile compounds.
• Such compounds can often be absorbed by polyester upon mere contact.
• polyester food and beverage containers are often misused by consumers after the food or beverage has been consumed.
• the containers are sometimes used to hold various organic and/or inorganic compounds and solvents.
• it is necessary to remove substantially all of the absorbed organic and inorganic compounds so that the polyester can be once again reused as a beverage or food container.
• the process of the present invention can include a first preparation stage including removing a portion of the contaminants via one or more physical separation processes followed by a reaction stage involving, in one embodiment, contacting the mixture containing polyester with an alkaline composition, mixing the alkaline composition and the polyester containing mixture together such that the solids of the mixture are substantially and evenly coated by the composition and partial saponification of the polyester occurs, heating the materials in a one or multi-step process to a temperature sufficient to complete the saponification reaction, if necessary, as well as to, among other possible benefits, preserve and/or enhance the physical properties of the polyester, and then purifying the polyester-containing mixture through various possible separation operations including, for example, washing the materials with a fluid, such as water.
• a fluid such as water
• FIG. 1 A recovery process according to one embodiment of the invention will now be described in terms of one preferred example thereof which is set forth in Figure 1.
• the disclosed process can be conveniently referenced by delineation of the process into three stages, i.e., a preparation stage, a reaction stage, and a finishing stage. It should be understood, however, that this particular delineation is for convenience in describing this embodiment, and is not to be considered a requirement of the disclosed process.
• the contaminated polyester materials can be, if desired, chopped or ground into flake form, for instance in a sizing operation.
• polyester flake refers to polyester materials that have been chopped or ground into smaller pieces. Flaking of the materials can be done for the purpose of facilitating handling. It should be understood that all different sizes and shapes of material may be used in the process of the present invention and no one size or shape is required.
• the polyester can be in a discrete form, e.g., finely divided or pelletized.
• post-sizing piece size can include, for example, pieces having a size of between about 1 and about 15 mm. In one embodiment, the pieces can have a size of between about 0.125 and about 0.75 in. The precise form of the pieces is not critical to the present invention.
• the polyester can be ground or chopped while the mixture containing the polyester is dry. While not wishing to be bound by any particular theory, it is believed that chopping the materials while in a dry state can improve the separation of certain contaminants from the polyester substrates. For example, it is believed that when multi-layered bottles are treated according to the disclosed process, dry grinding can facilitate the separation of the layers and the removal of the coating material located between layers of polyester in the multi-layered bottles. [0039] Following any chopping or flaking of the polyester substrate, the dry mixture containing polyester and contaminants can be subjected to one or more operations for the removal of contaminants heavier than the polyester.
• the mixture can be subjected to an elutriation process specifically designed for the removal of heavy contaminants, and in particular, metal contaminants.
• Elutriation is simply a process for separating heavier materials from lighter materials by use of a directed stream of fluid flow (i.e., gas or liquid).
• Elutriation has been used in many processes including recycling processes in the past to remove lighter contaminants from polyester.
• elutriation operations are known throughout recycling processes for removing lighter label materials, such as paper, for example, from a mixture.
• elutriation operations can be used at various beneficial points throughout the process of the present invention for the removal of fines from the mixture.
• an elutriation process can be utilized to remove contaminants from the mixture that are heavier than the polyester materials being recovered. More specifically, whereas in the past, it has been known to pull lighter contaminants off of the polyester mixture via an elutriation process, according to this particular embodiment of the present invention, the mixture containing the polyester can be the lighter stream separated during the elutriation operation, and heavier contaminants, such as metal, rock, dirt, and the like, can be removed from the mixture in the heavy stream pulled off of the elutriator.
• the elutriation fluid flow rate can be higher than that used in previously known processes for separating lighter materials from a polyester-containing stream in order to separate heavier contaminants the from the polyester-containing mixture.
• a fluid stream e.g., air
• cfm cubic feet/minute
• 4600 cfm can be utilized in an elutriation process with an incoming solids flow of between about 2500 pounds/hour (Ib/hr) and about 3500 Ib/hr in order to separate the heavier solids from the mixture containing polyester.
• the incoming solids flow can be about 3000 Ib/hr.
• the mixture containing contaminants and polyester can be charged to a dry-cleaning vessel.
• the mixture of materials charged to the cleaning vessel will contain at least some post-consumer polyester and the mixture will be dry. That is, the mixture will not be in a slurry form.
• the dry mixture of materials need not be excessively dry, however.
• the mixture need not be pre-treated to remove all moisture from the mixture, and the mixture can be charged to the vessel at an atmospheric level of humidity.
• the dry-cleaning vessel can include a cleaning chamber to which the dry mixture is charged.
• this chamber can be at least partially surrounded by a mesh with a predetermined mesh size. It may be preferred in some embodiments that the majority of the individual polyester pieces charged to the dry-cleaning vessel be larger than the openings of the mesh material in the cleaning vessel, to facilitate handling of the mixture. Sizing of the materials prior to charging the materials to the dry-cleaning vessel can also help to insure that at least some contaminants are of a size to pass through the mesh, although many contaminants can be degraded within the dry-cleaning vessel, as described below. [0043] In one embodiment, the chamber can include a series of blades spaced along the axial length of the chamber.
• the materials can be induced to revolve or spin about the chamber axis, for instance due to the rotating action of the blades.
• the motion of the materials can be enough to fluidize the dry mixture.
• the blades can rotate at a speed greater than about 20 m/sec, so as to fluidize the charged mixture.
• the blades can rotate at greater than about 2000 rpm.
• the tip speed of the blades can be between about 40 m/sec and about 100 m/sec, for instance, about 50 m/sec.
• the tip speed of the blades can be between about 60 m/sec and about 80 m/sec.
• the rotation of the mixture caused by the rotating blades can also encourage dynamic collisions between the materials in the mixture and the chamber wall. Collision of materials contained in the mixture with the wall can lead to the degradation of contaminants in the mixture, and in particular, degradation of the contaminants to the point that the individual pieces can be smaller than the mesh size of the surrounding wall.
• these dynamic collisions can facilitate physical detachment of embedded or otherwise attached contaminants from the polyester. Upon collision between suitably small contaminants (smaller than the mesh size of the wall) with the mesh, the contaminants can pass through the surrounding mesh, and the polyester can remain in the chamber.
• the rotation of the blades can also facilitate airflow through the chamber and the movement of the materials from one end of the chamber to the other.
• the dry-cleaning operation can physically separate polyester from attached contaminants, including embedded contaminants, as well as degrade many brittle contaminants, without substantial degradation of the polyester.
• coating materials such as paper label materials or vapor barrier coatings, and embedded materials, such as embedded glass and dirt
• the polyester flakes themselves can remain essentially the same size and shape as originally charged to the vessel.
• contaminants can be separated from the polyester and pass through the surrounding mesh
• the polyester can remain within the cleaning chamber. Even in those embodiments in which the polyester includes polyester flakes of a size smaller than the mesh openings, the bulk of the small polyester fines can remain suspending in the cleaning chamber and not be lost with the contaminants during the separation process.
• the materials within the mixture can separate, with the denser materials, and in particular, contaminants such as glass, metal, paper, and the like, moving to the outside of the mass, while the lighter materials, and particularly the small polyester fines, can remain suspended closer to the center of the chamber. Accordingly, glass-like materials and fibrous materials can degrade and pass through the screen at the outer edge of the mass, while elastomeric materials, such as PET can remain behind. As such, even PET particles smaller than the screen orifice can remain with the main rotating body, and very few polyester fines will pass through the screen, and high yield of polyester can exit the dry-cleaning operation.
• the dry-cleaning operation can be particularly effective at removing glass from a mixture including both glass and polyester.
• Glass has often been considered to be one of the most difficult materials to separate from post- consumer polyester during a polyester recycling process and can be detrimental to the process if not completely removed.
• Glass that is not removed during the recycling process can not only cause serious damage to processing equipment during the recycling process, but it can also destroy the materials to be formed from the recycled polyester.
• glass that is not removed during the recycling process can become incorporated with the polyester during a subsequent material formation process (e.g., a beverage container formation process) and can destroy the materials to be formed from the polyester through, for instance, the formation of holes in the polyester products.
• a subsequent material formation process e.g., a beverage container formation process
• more than about 97% of the glass in a mixture containing both glass and polyester can be removed from the mixture during the disclosed dry-cleaning operation. In one embodiment, more than about 98% of the glass in a mixture can be removed. In another embodiment, more than about 99% of the glass can be removed during the dry-cleaning operation.
• the mixture can be further processed according to one or more additional dry separation operations.
• the mixture can be subjected to an elutriation operation for removing light contaminants from the mixture.
• the airflow through the elutriator can be between about 1500 cfm and about 3000 cfm for a solids flow of about 3000 Ib/hr and at least a portion of the lighter contaminants can be removed from the mixture.
• dry separation operations that can optionally be included at one or more locations in the preparation stage include any separation operations generally known in the art such as, for instance, screening operations utilizing vibratory screens for separation of contaminants larger or smaller than the polyester, depending upon the mesh size of the screen and the size of the polyester flakes.
• the mixture can also be subjected to one or more aqueous separation operations.
• an intensive washing operation can follow the dry-cleaning operation and the elutriation operation.
• the aqueous separation operations e.g., the intensive wash operation, that can follow can describe lower contamination levels in the wash water, and hence less wastewater treatment processing can be required by the process.
• the wash water can show a decrease in chemical oxygen demand of at least about 15%, as compared to wash water used directly on the contaminated polyester materials.
• the total dissolved solids level of the wash water can decrease by about 30%, total suspended solids can decrease by at least about 50%, and oil and grease can decrease by about 15%.
• An intensive washing step can include adding water to the mixture and subjecting the materials contained in the aqueous mixture to high shear so as to facilitate the removal of certain contaminants, such as oligomers, and other organic and inorganic compositions from the surface of the polyester.
• a high shear wash can include those in which the turbulence of the wash water during the operation is greater than a standard wash, but low enough to prevent excessive flake damage and/or fines formation.
• a high shear wash according to the present invention can include those in which the wash rotors rotate with a tip speed of between about 500 and about 1000 feet per second (fps).
• fps feet per second
• the materials containing the polyester can be immersed in water such that the less dense or lighter materials can be separated from the heavier materials, and specifically from the polyester. More particularly, it is known that polyester sinks in water while other polymers, such as polyolefins, and paper products are water buoyant. Thus, the lighter materials can be easily separated from the heavier materials when contacted with a suitable amount of water. Subjecting the materials to a sink/float separation step and removal from the mixture of some of the contaminants not only can reduce the quantity of materials in the mixture being processed but can also help to clean the materials prior to further processing.
• the preparation stage of the process can also include a recirculation tank for recirculating the water used in, for example, the intensive washer and/or the sink/float tank.
• any water used in the aqueous operations of the preparation stage, as well as any water removed from the materials during any drying operations at any stage of the process, can be recirculated through the recirculation tank.
• the recirculation tank can include an agitator, if desired, so as to maintain in suspension any polyester fines carried over into the recirculation tank, and thus facilitate the reintroduction of these polyester fines back into the main stream of the decontamination process.
• aqueous separation operations that can optionally be utilized in the preparation stage of the process can include, for example, utilization of one or more hydrocyclone separators as are generally known in the art.
• hydrocyclone separators as are generally known in the art.
• a single hydrocyclone, double hydrocyclones, or multiple hydrocyclones can be utilized in series for separating contaminants from the mixture containing polyester.
• the mixture containing polyester and remaining contaminants can be dried and optionally subjected to additional dry separation operations prior to being combined with an alkaline material during the reaction stage of the process.
• This drying operation can, for example, occur at temperatures not greater than about 16O 0 C.
• drying can occur at between about 13O 0 C and about 16O 0 C, and can generally be carried out according to any method as is generally known in the art.
• the mixture can be dried and then subjected to a color sorting operation.
• Utilization of a color sorting operation prior to the reaction stage of the process has been found beneficial in certain embodiments of the present invention as the operation can essentially function as another cleaning step in the process, removing various contaminants from the mixture and thus 'cleaning' the mixture prior to the reaction stage.
• Contaminants that can be removed from the mixture prior to the reaction stage via a color sorting operation can include, for example, metals and colored polymeric components such as polyester materials colored with titanium dioxide.
• any color sorting technique as is generally known in the art can be utilized in the disclosed invention.
• visual inspection or automated optical sorting and separation techniques can be used.
• Examples of commercially available optical color sorting equipment can include those produced by manufacturers such as SRC, Satake, and MSS.
• aqueous separation processes such as additional elutriation processes, additional washing operations, additional screening processes, and/or the utilization of operations specifically designed for the removal of metals from the stream.
• Metal removal processes suitable for use in the present invention can include the use of magnetic separators, such as drum magnets, waterfall style magnets, eddy-current machines, or any other suitable magnetic metal detectors and separators such as those available from Bunting Magnetics, Co. of Newton, Kansas or S&S Recycling GmbH of Germany.
• reaction stage During the reaction stage of the disclosed process, a portion of the polyester in the mixture can be saponified through reaction of the polyester with an alkaline compound. More particularly, the reaction stage of the process can include one or more mixers, at least one of which can be a high-energy mixer. In addition, the reaction stage can optionally include additional reaction operations, such as a high temperature heat setting operation.
• the reaction stage of the process can include a first low-energy mixing operation, in which the mixture containing polyester and contaminants can be combined with an alkaline composition prior to being fed to a high-energy mixing operation, in which a portion of the polyester can be saponified.
• the mixture can be dried and fed to a heat setting operation, for example utilizing a kiln, in which, among other benefits, the saponification reaction can be completed, if necessary.
• a heat setting operation for example utilizing a kiln, in which, among other benefits, the saponification reaction can be completed, if necessary.
• secondary materials can be further reacted with the alkaline composition and the physical properties of the polyester can be preserved and/or enhanced.
• the reaction stage of the process can optionally include one or more processes for the recovery of reaction byproducts.
• the reacted polyester material upon saponification of PET, the reacted polyester material can be converted into a metal terephthalate and ethylene glycol.
• the metal terephthalate that is thus produced can be dissolved in water and the water can be acidified, causing terephthalic acid to precipitate.
• the terephthalic acid can be filtered and recovered as a byproduct of the disclosed process, if desired.
• the polyol that is formed during the reaction process can either remain as a liquid within the mixture for later removal, or can be directly evaporated if the reaction occurs at conditions that facilitate the evaporation of the polyol.
• the polyol can then be recovered, if desired, for instance by use of a condenser.
• the alkaline compound selected for mixing with the materials can be, in one preferred embodiment, sodium hydroxide, known commonly as caustic soda.
• suitable compounds can include calcium hydroxide, magnesium hydroxide, potassium hydroxide, lithium hydroxide or mixtures thereof.
• the metal hydroxide can be combined with water prior to mixing with the materials containing the polyester. For instance, in one embodiment, the metal hydroxide can be mixed with water in about a 1 to 1 ratio.
• the reaction stage of the present invention includes a high-energy mixing step during which the mixture containing contaminants and polyester can be combined with a selected amount of an alkaline solution to form a slurry.
• the amount of the alkaline composition added to the materials containing the polyester will generally depend upon the type and amount of impurities and contaminants present within the materials. Generally, the alkaline composition should be added only in an amount sufficient to separate the impurities from the polyester, so as to minimize the saponification of the polyester. In most applications, the alkaline composition can be added to the materials in a stoichiometric amount sufficient to react with up to about 50% of the polyester. Preferably, the alkaline composition is added in an amount sufficient to react with less than 10% of the polyester and most preferably around 3% of the polyester.
• the slurry can be formed in a first low-energy mixer, but this is not a requirement of the invention. In other embodiments, the slurry can be formed directly in the high-energy mixer, and the low-energy mixer may not be included.
• a surfactant or wetting agent may be added to the mixture and the alkaline composition when forming the slurry. Addition of a surfactant can facilitate the mixing of the alkaline composition with the materials, reducing the amount of the alkaline composition that needs to be added.
• the surfactant should be alkaline stable and can be nonionic or anionic in character.
• An example of a suitable surfactant is ETHAL TDA-3, a nonionic surfactant marketed by Ethox, Inc. of Greenville, South Carolina.
• certain low-energy reactions can also take place in the mixer.
• the mixer can optionally be utilized at operation parameters (for example, with the addition of a small amount of thermal energy, via heating of the mixer) so as to encourage reaction of the alkaline composition with certain contaminants found in the mixture, and in one particular embodiment, with aluminum.
• additional energy is added to the mixture in the low-energy mixer so as to promote reaction between contaminants and the alkaline composition
• the total amount of energy added to the mixture at this point in the process should not be great enough to promote any saponification reaction between the polyester and the alkaline composition.
• the low-energy mixer can be operated at an internal temperature of between about 9O 0 C and about 11O 0 C so as to encourage reaction between any aluminum contained in the mixture and the alkaline composition without promoting a saponification reaction between the polyester contained in the mixture and the alkaline composition.
• the alkaline composition can react with aluminum in the mixture to form, for example, an alkali aluminum salt that can be dissolved in the water of the slurry.
• a low-energy mixer can be utilized prior to any saponification of the polyester contained in the mixture to form a slurry and efficiently coat the solids of the mixture with the alkaline composition as well as to promote reaction of the alkaline composition with various contaminants contained in the mixture.
• a rinsing or washing operation can be included in the process following the low-energy mixer, for instance to remove any reaction products formed in the low-energy mixer.
• the mixture can be rinsed to remove at least a portion of the salt prior to additional operations in the reaction stage of the process.
• the materials can be fed to one or more high-energy mixers. As previously mentioned, in those embodiments not utilizing a low-energy mixer for formation of the slurry, the slurry can be formed in the high-energy mixer itself.
• alkaline composition can be added to the mixture in the high energy mixer, not only in those embodiments when the slurry is formed in the high energy mixer, but also when the alkaline- containing slurry has been rinsed to remove contaminants prior to flow into the high energy mixer or to replace alkaline composition that has reacted with contaminants in the low-energy mixer, whether rinsing has occurred or not.
• the high energy mixer utilized is one that can not only provide substantially complete and even coating of the polyester materials by the alkaline composition, when desired, but also can impart sufficient energy to cause a portion of the polyester to saponify, or, in other words, to hydrolyze, without the necessity of the addition of large amounts (or in certain embodiments, any) heat to the mixer.
• mixers such as those described in U.S. Patent Nos. 4,320,979 to Lucke and 4,189,242 to Luke, which are herein incorporated in their entirety by reference thereto, may be employed in the high-energy mixing operation to promote saponification of at least a portion of the polyester with the alkaline solution.
• a high-energy mixer can be operated at a Froude number greater than about 4.2, particularly greater than 6.6, and more particularly greater that about 9.5.
• the mixer of the present invention not only mixes the slurry but also imparts sufficient energy to the slurry to cause the alkaline composition to react with the polyester.
• high energy mixing can be continued until substantially all of the alkaline composition has been exhausted.
• the high-energy mixer can be operated such that residual (unreacted) metal hydroxide exiting the mixer can be less than about 1% by weight of the slurry.
• residual metal hydroxide exiting the mixer can be less than about 0.5% by weight.
• residual metal hydroxide can be less than about 0.1 % by weight of the slurry, for instance less than about 0.05% by weight.
• the salt reaction product can form a coating on the polyester materials which exit the mixer.
• the outer surface of a PET flake is saponified in the high-energy mixer with a sodium hydroxide composition
• the disodium terephthalate reaction product can coat the remaining PET.
• this coating formed around a polyester piece can serve to protect the polyester during later processing operations.
• the salt coating can protect the polyester from oxidation due to high temperature conditions encountered later in the heat setting operation. Among other benefits, this can provide a polyester product with less discoloration than that obtained in the past.
• the mixture can be dried and proceed to the finishing stage or optionally proceed directly from a high-energy mixer to the finishing stage.
• additional reaction operations and in particular, the heat setting operation discussed below, may not be necessary.
• the process can include at least one heat setting operation.
• the slurry can then be dried and, in certain embodiments, fed to a heat setting operation.
• the mixture can first be dried by heating the mixture to a temperature of between about 15O 0 C and about 16O 0 C, followed by additional heating, after drying, to a heat setting temperature that can encourage additional reaction of the materials.
• the actual temperature to which the mixture is heated during the heat setting operation can depend upon a number of factors.
• the mixture should be heated to as high a temperature as possible without melting the polyester.
• PET has a melting point typically between 25O 0 C to about 27O 0 C. Consequently, when substantial amounts of PET are contained within the materials, the mixture should be heated to a temperature below about 27O 0 C during the heat setting operation.
• the temperature can be within a range of from about100°C to about 27O 0 C.
• the heat setting operation can be carried out in an environment that is at least substantially free of water, for example, in a dry air environment.
• a dry air environment can be preferred in some embodiments, due to, for example, cost considerations, an inert atmosphere such as nitrogen, argon, carbon dioxide, or the like can also be effectively employed, such as in the form of a nitrogen blanket.
• the mixture can also be heated at reduced pressures, which correspond to lower oxygen levels.
• at least substantially free it is meant that the amount of water present in the environment is less than that which results in degradation of the polyester during heating.
• the mixture can preferably be heated in an oxygen-starved environment.
• oxygen-starved refers to an environment in which oxygen is present below about 19% by volume. In combination with the dry atmosphere, maintaining lower oxygen levels during the heat setting phase can further prevent the polyester from being substantially degraded or discolored and also can further prevent against uncontrolled combustion.
• the mixture can also be heated at reduced pressures, which correspond to lower oxygen levels.
• the slurry can generally be heated indirectly such that it does not contact an open flame.
• An oxygen-starved environment is not a requirement of the invention, however, and in other embodiments, it may be preferable to heat the mixture in an oxygen-rich environment, i.e., an environment including oxygen at greater than about 19% by volume.
• the equipment and apparatus used during the heat setting operation of the present invention can vary.
• the heat setting operation can be carried out in a rotary kiln.
• the rotary kiln can be heated by an electrical element, by heated oil or by fossil fuel burners.
• One example of a suitable indirectly heated kiln for use in the process of the present invention is the Rotary Calciner marketed by the Renneburg Division of Heyl & Patterson, Inc.
• a multi-disc thermal processor or an oven can optionally be employed.
• many other similar devices for example, infrared heat processors, microwave heaters, and the like are available that may optionally be utilized in the processes of the present invention.
• the kiln can first be heated to a lower temperature for a desired period of time to dry the materials from the high-energy mixer and then the temperature can be increased to the higher level.
• the slurry exiting the high-energy mixer can first be heated in a dryer, such as, for example, a ConAir dryer, before being transferred to a kiln for the higher temperature heat setting step.
• a kiln can be utilized for relatively rapid temperature increase of the mixture to the desired level, and the hot materials can then be transferred to a larger column dryer or any other suitable solid stating system, where they can be maintained at the desired temperature for the desired period of time.
• the heat setting operation of the disclosed process can provide many beneficial functions. For example, during the heat setting operation, byproducts such as ethylene glycol formed during the saponification reaction in high energy mixing either the high-energy mixer or in the heat setting operation can be evaporated off of the stream. The evaporated materials can then be collected, for instance in a condenser, and sent to a suitable treatment operation, for instance a water treatment operation for recovery, if desired. In addition, during the heat setting operation any remaining unreacted alkaline that has been carried over from the high energy mixing operation can be reacted with either polyester or other reactive contaminants found in the mixture.
• Remaining entrained organic and/or inorganic compounds that may be absorbed into polyester can be removed from the product polymer during the heat setting process. Specifically, any remaining volatile organic and inorganic compounds can be substantially removed during the heat setting step not only from the polyester, but also, and depending upon the nature of the compound, from the stream altogether via the off-gases.
• "food grade" polyester can be recovered which can be used in an unrestricted manner.
• heating the mixture can cause loose, dried impurities to be degraded into a more easily separable form in order to facilitate final separation of the impurities from the polyester product.
• the heat setting operation can also improve the physical characteristics of the polyester in the mixture.
• the heat setting operation is believed to increase the clarity and the intrinsic viscosity of the product polyester materials.
• the heating step in the presence of a dry atmosphere can be performed for a period of time sufficient to enhance the intrinsic viscosity of the polyester.
• the intrinsic viscosity of a polyester in the feed can increase from about 0.76 dL/g to about 0.82 dL/g.
• the intrinsic viscosity of the feed materials can be increased by between about 5% and about10% according to one embodiment of the presently disclosed invention.
• a minimum time is dependent on, e.g., the water content of the environment and can be as low as 5-10 minutes.
• contaminants such as the now detached coatings materials and/or entrained materials can be further degraded while the materials are processed in subsequent operations.
• solvents and liquids contained within the coatings or removed from the polyester during the heat setting operation can be volatilized and optionally removed from the kiln and recaptured in a condenser similar to the method for recapturing the ethylene glycol product from the saponification reaction described above. Left behind in the mixture can be some relatively smaller sized impurities.
• insoluble impurities can be separated from the larger polyester chips, for instance using an appropriately sized screen that allows passage of the impurities while preventing passage of the polyester.
• certain hard-to-separate contaminants commonly found with post-consumer polyester can be converted into a form that can be more easily separated from the mixture.
• contaminants such as polyvinyl chloride, polylactic acid (PLA) 1 and aluminum can be converted into forms that can be more easily separated from polyester.
• the materials can be converted into a form that is more easily separable from the mixture.
• at least a portion of the PVC can be converted to a form that is darker and thus separable from the mixture via color sorting techniques.
• the PVC contaminants can be converted to a form that floats in water.
• the PVC can be reacted to a form that exhibits increased heat resistance.
• combinations of these characteristics can be exhibited by the reacted PVC.
• the specific reactions of the PVC with the alkaline composition can depend upon the particular characteristics of the PVC contaminants contained in the mixture.
• the PVC upon combination of the mixture with the alkaline composition and addition of suitable energy, the PVC can react to form more easily separable from the polyester contained in the mixture. Consequently, when polyvinyl chloride is present in the materials, it may be preferable to add enough alkaline composition to the slurry sufficient to react with the polyvinyl chloride or, in other words, to convert the polyvinyl chloride into a form separable from the polyester.
• the PVC can optionally be removed from the mixture by heating the mixture to a temperature that is greater than the melting temperature of PVC but less than the melting temperature of the polyester contained in the mixture, upon which the PVC can melt and then be removed from the mixture, for instance by use of a sieve or other suitable separation technique during either the reaction stage or optionally during the finishing stage of the process.
• PLA can be removed from the mixture according to similar processes as that described above for PVC.
• any variations in the process for example, variations in amount of alkaline composition, variation in processing conditions (e.g., temperatures, etc.) that may be different from those described above for PVC are well within the general knowledge of one of ordinary skill in the art, and thus will not be described in detail herein.
• polyester collected from the solid waste stream can also typically be mixed with pieces of aluminum, as mentioned above.
• the aluminum can originate, for instance, from bottle caps utilized with polyester beverage containers or from the imperfect separation of plastic and aluminum cans found in post-consumer waste. Aluminum, similar to polyvinyl chloride, cannot easily be separated from polyester using standard separation processes such as a sink/float separation operation.
• an alkali aluminum salt which is typically water soluble.
• an amount of alkaline composition can be added to the materials containing polyester and aluminum sufficient to completely convert the aluminum to an aluminum salt.
• a fluid such as water, can then be added to the mixture to dissolve the aluminum salt and separate it from the polyester.
• not all of the aluminum contained in the stream entering the reaction stage need be converted into an aluminum salt. Instead, only a portion of the aluminum can be converted to the aluminum salt with the alkaline composition.
• the remaining aluminum pieces can become brittle.
• the materials containing the polyester mixed with the remaining aluminum can then be agitated under shear conditions and the remaining brittle aluminum can be broken into small pieces.
• the small pieces can then be separated from the polyester for instance with a suitable separation operation, for instance, a simple screening process utilizing a screen having a size sufficient to capture the larger polyester chips while allowing the smaller broken aluminum pieces to pass.
• the alkaline composition when aluminum is present within the materials containing the polyester, the alkaline composition can be added to the materials in an amount sufficient to react with at least a portion of the aluminum, sufficient that the remaining aluminum will be brittle.
• the actual amount of alkaline composition added can depend not only upon the quantity of aluminum present in the materials, but also upon the size (e.g., thickness) of the aluminum pieces.
• Additional operations that can be included in the reaction stage can include, for example, additional heating operations, for instance holding the mixture at a suitable temperature for a period of time to further increase the intrinsic viscosity of the product polyester.
• additional heating operations for instance holding the mixture at a suitable temperature for a period of time to further increase the intrinsic viscosity of the product polyester.
• the mixture can be held in one or more ovens for a period of time at a desired temperature to ensure the production of food-grade polyester, to further improve the physical characteristics of the product, to remove additional volatile contaminants, and/or to remove additional non-volatile contaminants, such as paper fibers, for example, via heat convection and/or radiant heat in the oven.
• Any suitable oven can be used in such an embodiment, including infrared type ovens. Finishing Stage
• Particular operations included in the finishing stage of the disclosed process can generally vary depending on the particular contaminants and/or impurities in the starting compositions.
• the invention can not only effectively recover polyester from a variety of contaminants and/or impurities, but can also recover particular contaminants found in the waste stream as by-products of the process.
• polyolefins removed from the stream at a sink/float operation can be dried and recovered.
• the finishing stage of the process can at the very least include at least one washing or rinsing operation, one color sorting operation, for removal of discolored contaminants from the mixture, and at least one elutriation operation, for the removal of fines and any remaining light contaminants from the product.
• the materials can be washed with a cleaning solution.
• the mixture containing the polyester and any remaining contaminants can be mixed with a hot aqueous solution containing a surfactant or with a hot aqueous solution containing an alkaline material and washed. If desired, the mixture can be heated under agitation or in a high intensity wash, such as that described above during the preparation stage.
• Washing the materials can clean the polyester by straight separation of the polyester from the contaminants and can also dissolve and/or break apart some of the contaminants.
• the acid salt or metal salt formed during the saponification reaction can dissolve in the wash water.
• the metal salt can be later recovered from the wash water for disposal or as a by-product of the process. For instance, if the acid salt is a terephthalate, the wash water can first be filtered in order to remove any undissolved impurities and contaminants. Next, the wash water can be acidified causing terephthalic acid to precipitate.
• a mineral acid such as hydrochloric acid, phosphoric acid or sulfuric acid or an organic acid such as acetic acid or carbonic acid can be added to the solution.
• the terephthalic acid precipitates, the terephthalic acid can be filtered, washed and dried, leaving a relatively pure product.
• the mixture can be combined with a fluid such as water during the finishing stage. When placed in water, the polyester will sink while the dechlorinated polyvinyl chloride can float.
• the reaction of PVC with the alkaline composition can also darken the color of the polyvinyl chloride and increase its melting point. Consequently, in another embodiment, the polyvinyl chloride reaction product can be separated from the polyester during the finishing stage via a color sorting operation, such as that described above in the preparation stage. Other contaminants can be separated from the mixture via a color sorting operation during the finishing stage as well.
• the polyester feed product can include certain barrier materials, such as acetaldehyde scavenger barrier materials in either the reacted or unreacted form. According to the present invention, such contaminants can become discolored during the presently disclosed process, for instance during the heat setting operations of the present invention. Upon a color sorting operation during the finishing stage, such contaminants, and in particular, those that can alter in color during the reaction stage of the process, can be removed from the mixture.
• the finishing stage can include neutralization of any remaining alkaline material through the addition of a suitable acid to the mixture such as an inorganic acid including, for example, hydrochloric acid, phosphoric acid and/or sulfuric acid or an organic acid such as acetic acid and/or carbonic acid.
• a suitable acid such as an inorganic acid including, for example, hydrochloric acid, phosphoric acid and/or sulfuric acid or an organic acid such as acetic acid and/or carbonic acid.
• the mixture can be dried prior to any dry separation operations.
• remaining metal contaminants can be removed from the mixture in a metal removal operation.
• a metal removal operation can include multiple metal detectors in series and parallel combination to form a bank of individual metal removal devices so as to provide more complete removal of metal contaminants than obtained in metal separating operations known in the past.
• the process can include multiple banks of two or more metal removal devices in a single operation step.
• the total mixture stream can be split among two or more banks of metal removal devices, so as to create multiple smaller input streams to each bank of devices.
• a single operative step in a polyester recovery process can include one, two, or even more banks of devices.
• the high quality metal removal operation can include anywhere from 1 to 10, 20, 30, or even more banks each containing two or more individual metal detection and removal devices.
• the bank includes five individual metal detection and removal devices, but it should be understood that this particular number is not a requirement of the invention.
• the bank of devices can include additional or optionally fewer individual devices.
• the bank of devices can include as few as two devices and no limit to the upper number of individual devices included in the bank. Though practically speaking, economic considerations can generally be involved in determining the preferred number of individual devices included in a bank as well as the total number of banks included in an operative step of the process.
• the entire input stream fed to the bank is treated in a first metal detection unit 1.
• a portion of the stream including the detected metal is separated and removed from the stream, as rejected stream 10.
• the 'clean' or accepted stream 7 and the rejected stream 10 taken off of metal detection unit 1 then proceed to additional metal detection units 2, 5, respectively.
• the detection and separation process is repeated, with the rejected stream 11 (which includes detected metal) being fed to metal detection unit 5, and the accepted stream 8 being fed to yet another detector and separation unit 3, and then on to final metal detection unit 4.
• the rejected streams 12, 13 from metal detection units 3 and 4 are each fed to the recycle stream 6, and the final accepted stream 18 continues on in the overall process.
• the accepted stream 20 is fed back to recycle stream 6, and the rejected stream 14 is removed from the process as waste material containing metal.
• the individual metal detectors contained in the bank can be set at increasing sensitivity as the stream proceeds through the process, as shown by the side arrow.
• metal detection units 2, 3 and 4 can have increasing sensitivity as compared to each other as well as compared to metal detection unit 1.
• the sensitivity of metal detection unit 5 can be greater than that of metal detection unit 1.
• the finishing stage of the operation can also include one or more elutriation operations for the removal of any remaining light contaminants such as any remaining paper or paper fibers or any polymer fines.
• Other separation operations that can be utilized in the finishing stage as well as between operations in the preparation and/or reaction stage can include physical separation operations such as those described above in regard to the preparation stage as well as any other suitable separation operations as are generally known in the art such as, for instance, the use of one or more destoning operations for the removal of glass, and/or the use of hydrocyclones.
• a double hydrocyclone embodiment can be utilized in which the materials can be pumped to a first hydrocyclone to remove high- density contaminants, such as glass and/or metal, and then sent to a second tank and pumped to a second hydrocyclone to remove lower-density contaminants, such as paper and/or polyolefins, for example.
• One or more vibratory screening methods can also be utilized at various locations throughout the disclosed process to, for example, separate contaminant materials taken off of the top of the sink/float tank from the processing water, for removal of contaminants in powdered form following the heat setting operation, following a high shear washing operation in the preparation and/or finishing stage or following a final washing and drying operation in the finishing stage.
• heavy contaminants can be removed from the mixture at any suitable point in the process by use of a sluice operation.
• any aqueous separation operations in the preparation stage or immediately before or after any aqueous separation operations in the finishing stage it may be beneficial in certain embodiments of the process to include a sluice operation for the removal of certain heavy contaminants from the mixture.
• the treatment method of the disclosed invention is capable of providing a number of significant advantages.
• it is capable of cleaning and/or decontaminating polyester.
• the polyester can be cleaned and/or decontaminated to a level which is sufficient to meet various regulatory guidelines, and in particular, can produce food-grade polyester product.
• the target level of cleaning or decontamination can depend upon the ultimate end use of the polyester.
• the process is capable of providing a recycled polyester product having improved properties, e.g., a high degree of cleanliness, good color and even an improved intrinsic viscosity.
• the disclosed process is capable of providing these products at an acceptable yield and at a lower processing cost since, e.g., it does not require "re-polymerization" of the monomers in contrast to typical depolymerization processes.

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• 2005
  • 2005-03-16 EA EA200701990A patent/EA013407B1/ru not_active IP Right Cessation
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