WO2006096216A1 - Reduced shear cellulose reactive sizing agent for wet end applications - Google Patents
Reduced shear cellulose reactive sizing agent for wet end applications Download PDFInfo
- Publication number
- WO2006096216A1 WO2006096216A1 PCT/US2005/038609 US2005038609W WO2006096216A1 WO 2006096216 A1 WO2006096216 A1 WO 2006096216A1 US 2005038609 W US2005038609 W US 2005038609W WO 2006096216 A1 WO2006096216 A1 WO 2006096216A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- emulsion
- paper
- cationic
- sizing
- alkenylsuccinic anhydride
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
- D21H17/15—Polycarboxylic acids, e.g. maleic acid
- D21H17/16—Addition products thereof with hydrocarbons
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/26—Agents rendering paper transparent or translucent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
Definitions
- sizing refers to a fibrous substrate's ability to resist wetting or penetration of a liquid into a paper sheet.
- Aqueous dispersions of alkenylsuccinic anhydride cellulose- reactive sizing agent have been widely used in the paper and board making industry for many years, for sizing a wide variety of grades which include printing and writing grades and bleached and unbleached board grades.
- Cellulose-reactive alkenylsuccinic anhydride imparts hydrophobic properties to the paper and board products.
- Internal sizes can be either rosin-based or synthetic sizes such as alkenylsuccinic anhydride, or other materials. Internal sizes are added to the paper pulp prior to sheet formation. Surface sizes are sizing agents that are added after the paper sheet has formed, most generally at the size press, although spraying applications may also be used. Alkenylsuccinic anhydride sizing agent is ordinarily applied by dispersing it in a cationic or amphoteric hydrophilic substance such as a starch or a polymer.
- the starch or polymer-dispersed alkenylsuccinic anhydride sizing emulsion is added to the pulp slurry before the formation of a paper web.
- This type of addition of alkenylsuccinic anhydride sizing emulsions to the papermaking system is commonly called wet-end addition or internal addition of alkenylsuccinic anhydride.
- ASA emulsification in cationic starch needs a high starch/size ratio for emulsification.
- the starch needs to be an high quality starch suitable for producing a stable, high quality ASA emulsion.
- ASA emulsification in cationic polymer or starch-grafted polymer also uses a lower polymer/size ratio than for starch, but a polymer that provides a stable, high quality ASA emulsion is needed for emulsification.
- the invention relates to method for sizing a paper product that involves the steps of: (a) providing a paper stock system; (b) forming, in the absence of high shearing forces, an aqueous sizing emulsion comprising an alkenyl succinic anhydride component; (c) submitting the emulsion formed from step b to a post-dilution step in the presence of a cationic component under conditions, in the absence of high shearing forces, that produce a post-diluted emulsion having improved sizing efficacy; (d) adding the post-diluted emulsion to the paper stock; and (e) forming a paper web.
- the invention relates to a paper made by the above-mentioned process. In one embodiment, the invention relates to a method for sizing a paper product comprising:
- the emulsion prepared prior to the post-dilution step includes an alkenylsuccinic anhydride-containing emulsion, which when subjected to a post-dilution step, improves sizing efficacy as compared to an emulsion that is not subjected to a post-dilution step.
- the emulsion can include an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles suspended in a starch component containing emulsifying starch selected from the group consisting of non-ionic starches, anionic starches, cationic starches and mixtures thereof.
- Starches that are used for the emulsification can be based on corn, potato, wheat, tapioca, or sorghum, and they could be modified through the use of enzymes, high temperature or chemical/thermal converting techniques.
- the emulsion can include an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles suspended in an aqueous polymer solution selected from the group of cationic polymers, nonionic polymers, anionic polymers, vinyl addition polymers, condensation polymers, and mixtures thereof.
- the invention includes an alkenylsuccinic anhydride component containing (i) alkenylsuccinic anhydride particles and (ii) surfactant component; suspended in water.
- the emulsion of step (b) can be made by any suitable method.
- the emulsion is made with an emulsifying agent, e.g., a surfactant.
- an emulsifying agent e.g., a surfactant.
- Cationic polymer or cationic starch may be present, but they are not required.
- the weight ratio of the alkenylsuccinic anhydride to polymer or starch solids generally ranges from 1 to 0.02 to 1 :1, or from 1 to 0.05 to 1 to 0.5, or from 1 to 0.1 to 1 to 0.2.
- the emulsion in step (b) can be made by emulsifying an alkenylsuccinic anhydride component containing (i) alkenylsuccinic anhydride and (ii) a surfactant component, with water; and thereby forming an emulsion having an alkenylsuccinic anhydride component containing (i) alkenylsuccinic anhydride particles and (ii) a surfactant component; suspended in water.
- the emulsion in step (b) can be made by emulsifying an alkenylsuccinic anhydride component, optionally containing a surfactant, with an aqueous polymer solution, and thereby forming the emulsion.
- the sizing emulsion can be formed with a polyoxyalkylene alkyl ether or one surfactant selected from the group consisting of sulfosuccinates, alkyl and aryl amides and primary, secondary and tertiary amines and their corresponding quaternary salts, fatty acids, ethoxylated fatty acids, fatty alcohols, ethoxylated fatty alcohols, fatty esters, ethoxylated fatty esters, ethoxylated triglycerides, certain ethoxylated lanolin, sulfonated amines, sulfonated amides, ethoxylated polymers, propoxylated polymers, ethoxylated/ propoxylated copolymers, polyethylene glycols, phosphate esters, phosphonated fatty acid ethoxylates, phosphonated fatty alcohol ethoxylates, alkyl sulfonates, ary
- the polymer used to emulsify the alkenylsuccinic anhydride can be any polymer, which when used in accordance with the invention, can produce an emulsion in accordance with the invention.
- suitable polymers used in the emulsion of this sizing composition include polymeric stabilizers that include vinyl addition and condensation polymers having anionic, cationic, non-ionic and amphoteric charge characteristics with a charge substitution range varying from 0 to about 90%, and more preferably from 0 to about 10%.
- the molecular weight of aforementioned synthetic polymeric stabilizer generally falls within the value ranging from about 10,000 to about 10 million daltons, or from about 100,000 to about two million or from about 200,00 to about 1 million daltons. All molecular weights mentioned herein are weight average.
- suitable water-soluble polymers of this instant invention are cationic vinyl addition polymers, anionic vinyl addition polymers, neutral polymers, ampholytic polymers and condensation polymers.
- suitable polymers include, water-soluble polymers having molecular weights ranging from 10,000 daltons to 3,000,000 daltons.
- the substantially water-soluble polymers to be used in this invention are comprised of but not limited to homopolymers and copolymers, and combinations thereof leading to terpolymers, and tetrapolymers comprised of the following monomers: acrylamide, diallyldimethylammonium chloride, dimethylaminoethylacrylate, dimethylaminoethylacrylate quaternaries, diethylaminoethyl acrylate, diethylaminoethylacrylate quaternaries, dimethylaminoethylmethacrylate, dimethylaminoethylmethacrylate quaternaries, dimethylaminoethylmethacrylate and its quaternaries, methacrylamidopropyltrimethyl ammonium chloride, acrylic acid.
- Suitable polymers also include polymers and copolymers of acrylamide that have been subjected to the "Mannich" reaction. Also, in one embodiment, the corresponding Mannich quaternaries are possible water-soluble polymers. Examples of other water-soluble polymers include copolymers comprised of substantially water-soluble and water dispersible styrene-alkylacrylates, styrene alkylacrylics, styrene maleic acid, styrene-maleic acid amide, styrene maleic acid esters, styrene maleic acid amide ester, and their corresponding salts.
- suitable polymers include aqueous dispersions containing combinations of the reaction products of the above monomers, polyurethane dispersions with polyvinyl alcohol, poly vinylalcohol-vinylamine), their corresponding acetates or formamates or partially hydrolyzed polymers, or polyvinylamine.
- Examples include copolymers of N,N-dialkylamino-alkyl(meth) acrylates and/or amides and/or alkyl(meth)acrylates , styrene, isobutylene, diisobutylene, vinyl acetate and/or acrylonitrile.
- Examples include condensation polymers of trimethlyene diamine and 1 ,2-dichloroethane or 1 ,3 dichloropropane; adipic acid with diethylenetriamine, tetraethylenepentamine or similar polyalkylene; polyamides; subsequent reaction products with epichlorohydrin; dimethylamine-epichlorohydrin; ethylenediamine polyacrylamide.
- Examples include polyvinyl pyridine, poly-N-methyl pyridinium chloride; poly-p-chlorostyrene quaternized with trialkylamine. Examples of such suitable polymers are described in U.S. Pat. Nos. 4,657,946, 4,784,727, 3,445,330, 6,346,554, incorporated herein by reference in their entirety.
- Natural polymers, gums, and their extracts included in the embodiments of the invention may be taken from the following list: guar, acacia, agar, algin, carrageenan, cellulose and its derivatives, chitin, chitosan, damar, dextran, dextrin, ethylcellulose, gelatin, gellan, jalap, karaya, kelp, locust bean, methlycellulose, olibanum, pectin, rhamsan, sandarac, tragacanth, welan, and xanthan.
- the polymers may be in their natural state or derivatized thereafter to form salts or other derivatives (e.g. hydroxyethylated).
- the products may be anionic, cationic, amphoteric, or neutral.
- the emulsion may be made in the absence of high shearing forces (low shear conditions), e.g., those shearing conditions are created by a device selected from the group of centrifugal pumps, static in-line mixers, peristaltic pumps, and combinations thereof.
- low shear conditions those shearing conditions are created by a device selected from the group of centrifugal pumps, static in-line mixers, peristaltic pumps, and combinations thereof.
- the alkenylsuccinic anhydride component generally includes alkenylsuccinic anhydride compounds composed of mono unsaturated hydrocarbon chains containing pendant succinic anhydride groups.
- the alkenylsuccinic anhydride compounds are generally liquid and may be derived from maleic anhydride and suitable olefins.
- the alkenylsuccinic anhydride compounds may be solid.
- the alkenylsuccinic anhydride compounds may be made by reacting an isomerized C 1 4 - C 2 o mono olefin, preferably an excess of an internal olefin, with maleic anhydride, at a temperature and for a time sufficient to form the alkenylsuccinic anhydride compound.
- the olefin to be employed in the preparation of the alkenylsuccinic anhydride compounds is not an internal olefin as is the case for example, with ⁇ -olefins, it may be preferable to first isomerize the olefins to provide internal olefins.
- the olefins that may be used in the preparation of the alkenylsuccinic anhydride compounds may be linear or branched.
- the olefins may contain at least about 14 carbon atoms.
- Typical structures of alkenylsuccinic anhydride compounds are disclosed, for example, in U.S. Pat. No. 4,040,900, incorporated herein by reference in its entirety.
- the alkenylsuccinic anhydride component may contain some hydrolyzed alkenylsuccinic anhydride.
- the amount of hydrolyzed alkenylsuccinic anhydride may range from about 1 to about 30 wt.%, based on the total weight of the alkenylsuccinic anhydride component.
- the alkenylsuccinic anhydride component can include: a. from 80 to 97 parts of substituted cyclic dicarboxylic acid anhydride corresponding to the formula
- R represents a dimethylene or trimethylene radical and wherein R 1 is a hydrophobic group containing more than 5 carbon atoms which may be selected from the class consisting of alkyl, alkenyl, aralkyl, or aralkenyl groups;
- R x is an alkyl radical containing at least 5 carbon atoms and Ry is an alkyl radical containing at least 5 carbon atoms, and R x and R y are interchangeable; wherein R x is an alkyl radical containing at least 5 carbon atoms and R y is an alkyl radical containing at least 5 carbon atoms and R x and R y are interchangeable; and b. from 3 to 20 parts of a polyoxyalkylene alkyl or polyoxyalkylene alkyl-aryl ether or the corresponding mono- or diester selected from the group consisting of: i)
- the alkenylsuccinic anhydride component is generally present in the emulsion in an amount that is at least about 0.01 wt.%, or from about 0.1 to about 20 wt.%, or from about 0.3 wt.% to about 15 wt. %, based on the total weight of the emulsion.
- the emulsion generally contains alkenylsuccinic anhydride particles ranging from 0.5 microns to less than 3 microns.
- the surfactant component When a surfactant is used to make the emulsion, the surfactant component includes surfactants, which when used to make an emulsion in accordance with the invention, produces an emulsion that minimizes coalescing and imparts useful sizing properties to a fibrous substrate after the emulsion contacts the fibrous substrate.
- the surfactant component functions as an emulsifying agent when the emulsion is made.
- the surfactant component facilitates the emulsification of the alkenylsuccinic anhydride with the water component when the emulsion is made.
- the surfactants are anionic or nonionic or can be cationic and can have a wide range of HLB values.
- Suitable surfactants include but are not limited to alkyl and aryl primary, secondary and tertiary amines and their corresponding quaternary salts, sulfosuccinates, fatty acids, ethoxylated fatty acids, fatty alcohols, ethoxylated fatty alcohols, fatty esters, ethoxylated fatty esters, ethoxylated triglycerides, sulfonated amides, sulfonated amines, ethoxylated polymers, propoxylated polymers or ethoxylated/ propoxylated copolymers, polyethylene glycols, phosphate esters, phosphonated fatty acid ethoxylates, phosphonated fatty alcohol ethoxylates, and alkyl and aryl sulfonates and sulfates.
- surfactants include but are not limited to amides; ethoxylated polymers, propoxylated polymers or ethoxylated/propoxylated copolymers; fatty alcohols, ethoxylated fatty alcohols, fatty esters, carboxylated alcohol or alkylphenol ethoxylates; carboxylic acids; fatty acids; diphenyl sulfonate derivatives; ethoxylated alcohols; ethoxylated fatty alcohols; ethoxylated alkylphenols; ethoxylated amines; ethoxylated amides; ethoxylated aryl phenols; ethoxylated fatty acids; ethoxylated triglycerides; ethoxylated fatty esters; ethoxylated glycol esters; polyethylene glycols; fatty acid esters; glycerol esters; glycol esters; certain lanolin-based derivatives; monog
- the surfactant component includes an amine selected from the group consisting of trialkyl amine of the formula (I):
- the surfactant excludes this amine.
- the surfactant levels can range from about 0.1 weight % up to about
- the post-dilution step generally involves mixing the emulsion with a cationic component at autogenous conditions.
- the cationic component can be selected from the group consisting of cationic starches, cationic polymers, cationic starch-grafted polymers, and mixtures thereof.
- the cationic component can be selected from the group consisting of cationic vinyl addition polymers, cationic condensation polymers, and combinations thereof.
- Starches that are used for the post-dilutation step can be based on com, potato, wheat, tapioca, or sorghum, and they could be modified through the use of enzymes, high temperature or chemical/thermal converting techniques.
- the starches that are used for the post-dilution have to be cationic.
- the ratio of the cationic component solids to the alkenylsuccinic anhydride in the post-dilution step should range from 0.1 :1 to 4:1 , but in some cases could be as high as 50:1. This ratio will depend on the requirements for a specific paper production application.
- the temperature at which the process of the invention can be carried out is generally less than 50°C.
- the pH at which the process of the invention is practiced varies, depending on the application.
- the pH for instance, can range from 4 to 8 or from 6 to 8.
- the post-dilution step is generally carried out under low shear conditions e.g., those shearing conditions are created by a device such as selected from the group of centrifugal pumps static in-line mixers, peristatic pumps, magnetic stirring bar in a beaker, overhead stirrer, and combinations thereof.
- the post dilution step is typically carried out, in one embodiment, if alkenyl succinic anhydride is emulsified in a cationic component than the post-dilution with a second cationic component is optional.
- the duration of the mixing in step(c) generally occurs less than one minute.
- the mixing in step(c) can occur from 1 to 20 seconds.
- the stability of the post-diluted composition varies.
- the stability of the post-diluted composition can be stable from 1 to 6 hours.
- the paper sized in accordance with the invention generally exhibits a sizing efficiency that is more than 20% higher, as compared to paper made with a composition that is not subjected to a post-dilution step.
- the paper that can be sized with the method of the invention can be selected from the group consisting of paperboard papers, fine papers, newsprint papers, and combinations thereof. As such, the invention can also be directed to the papers treated with Applicants' invention.
- ASA alkenylsuccinic anhydride
- ASA Alkenylsuccinic anhydride
- 5% Brij ® 98 surfactant was emulsified in water with a single impeller, open-feed, 1-horespower centrifugal pump at a speed of 1700 rpm.
- the low shear centrifugal pump was connected to a tap water supply and the pump was operated using the pressure from the tap water supply. No pH or temperature adjustment was made to the tap water prior to emulsification.
- ASA was supplied to the centrifugal pump from a calibration column via a gear pump. ASA entered the water inlet just before the centrifugal pump.
- the water flow rate was approximately 1 L/min and ASA flow rate was approximately 240 mL/min.
- the centrifugal pump was a single- pass emulsification process with no recirculation.
- the resulting ASA emulsion contained 19 weight percent ASA.
- the emulsification of ASA containing 5% Brij 98 surfactant in polymer or starch solution was done as the emulsification in water, except that polymer or starch were added to a water line using a variable speed gear pump, and it was mixed using an in-line static mixer before it was combined with ASA flow.
- the centrifugal pump was run at a speed between 1700 and 3600 rpm.
- the concentration of ASA in the emulsion varied from about 3 to about 10 wt %, depending on particular study.
- the total flow rate of water, ASA and polymer or starch was about 1L/min.
- Em unification of ASA with Hi ⁇ h Shear A high shear ASA, BAYSIZE ® I 18 size (LANXESS Corporation) emulsion were prepared with a polymer or starch solution using a household blender on high speed for 90 -180 sec. See details in examples.
- Emulsion Particle Size Analysis A commercially available, light scattering, particle analyzer, Horiba LA-
- Handsheet Preparation Process Used in Examples 1-10 Handsheets were prepared using a furnish of a 50/50 mixture of bleached hardwood and softwood kraft pulp refined to a Canadian Standard Freeness (CSF) of 500 mL to which 10 % by weight of precipitated calcium carbonate was added, and pH was adjusted to 7.8.
- CSF Canadian Standard Freeness
- Deionized water was used for furnish preparation and additional 80 ppm of sodium sulfate and 50 ppm of calcium chloride were added.
- the sizing of handsheets was tested using a 2-min Cobb test. The test was performed according to TAPPI Test Method T441 om-90. A 100-cm 2 ring was utilized in this test.
- Ink Penetration Holdout was measured using a method similar to that described in TAPPI Method T 530 pm-89 except that an instrument was used as described in U.S. Pat. No. 5,483,078.
- the test measures the time (in seconds) for the reflectance of the paper on the side opposite that contacting the ink to decreases to 80% of the initial value.
- the ink consists of 1.25% Napthol Green B dye buffered to pH 7.
- the test values were normalized for basis weight of the paper assuming that the values vary as the cube of the basis weight. Results were expressed in units of seconds.
- ASA containing 5 wt % of Brij 98 surfactant was emulsified in an aqueous solution of the high molecular weight cationic acrylamide polymer, BAYSIZE ® E LS polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.1.
- the emulsification was done according to Method 2, using a centrifugal pump at a speed of 3000 rpm. During the emulsification process, the ASA flow was 53 mL/min, the 10.8 % (w/w) polymer solution flow was 47 mL/min, and water flow was 1030 mL/min.
- the sizing agent concentration in the emulsion was 4.88 % (w/w).
- the emulsion particle size was 1.18 microns.
- the handsheets were prepared with this emulsion and the sizing of these handsheets was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size (LANXESS Corporation) was emulsified in the aqueous solution of the high molecular weight cationic acrylamide polymer BAYSIZE E LS polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.1. During the emulsification process, 20.2g of BAYSIZE 1 18 size (LANXESS Corporation) was added to 100 g of 2.02(w/w) polymer solution and mixed in a household blender on high speed for 3 min. The emulsion particle size was 0.72 microns. The handsheets were prepared with this emulsion and the sizing of these handsheets was measured using a 2-min Cobb test.
- the emulsion of a low shear ASA (Example 1 ) provided worse paper sizing than the high shear ASA emulsion (Example 2) at a low sizing agent dose, but as the dose was increased or as 5 Ib/t of alum was applied, the sizing performance of both sizing agents was equivalent.
- ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in the aqueous solution of the low molecular weight cationic acrylamide polymer
- BAYSIZE ® E HE polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.15.
- the emulsification was done according to Method 2, using a centrifugal pump at a speed of 1700 rpm.
- the ASA flow was 50 mL/min
- the 26-wt. % polymer solution flow was 26 mL/min
- water flow was 1909 mL/min.
- the sizing agent concentration in the emulsion was 4.8 wt. %.
- the emulsion particle size was 2.3 microns.
- the handsheets were prepared with this emulsion, and the sizing of these handsheets was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size (LANXESS Corporation) was emulsified in the aqueous solution of the low molecular weight cationic acrylamide polymer BAYSIZE E HE polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.15.
- BAYSIZE I 18 size (LANXESS Corporation) was added to 101 g of 3% (w/w) polymer solution and mixed in a household blender on high speed for 3 min.
- the emulsion particle size was 1.1 microns.
- the handsheets were prepared with this emulsion, and the sizing of these handsheets was measured using a 2- min Cobb test.
- the sizing performance of the low shear ASA emulsified with the low molecular weight cationic polymer matched the performance of the high shear ASA emulsified with the same low molecular cationic polymer (Example 4) when a higher dose of sizing agent was used.
- the sizing performance was also matched when a lower dose of sizing agent was used in conjunction with alum.
- EXAMPLE 5 ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in a solution of Hi-Cat CWS pregelatinized starch (Roquette) at a sizing agent to starch solids ratio of 1/1.
- the em unification was done according to Method 2, using a centrifugal pump at a speed of 2400 rpm.
- the ASA flow was 44.5 mL/min
- the 4.19% (w/w) starch solution flow was 955.5 ml_/min, and there was no water flow.
- the sizing agent concentration in the emulsion was 4.21 % (w/w).
- the emulsion particle size was 3.6 microns.
- the handsheets were prepared with this emulsion, and the sizing of these handsheets was measured using a 2-min Cobb test.
- ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in tap water.
- the emulsification was done according to Method 1 , using a centrifugal pump at a speed of 1700 rpm. During the emulsification process, the ASA flow was 44.5 mL ⁇ nin, the water flow was 955.5 mL/min. The sizing agent concentration in the emulsion was 4.2 % (w/w). The emulsion particle size was 1.5 microns. The emulsion was post-diluted with the 4.19% (w/w) solution of Hi-Cat CWS pregelatinized starch (Roquette). The sizing agent to starch solids ratio in the post-diluted emulsion was 1/1. The handsheets were prepared with this emulsion, and the sizing of these handsheets was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size was emulsified in an aqueous solution of Hi-Cat CWS pregelatinized starch (Roquette) at a sizing agent to starch solids ratio of 1/1.
- BAYSIZE 1 18 size (LANXESS Corporation) was added to 191.92 g of the 4.19% (w/w) starch solution and mixed in a household blender on high speed for 90 seconds.
- the emulsion particle size was 0.62 microns.
- the handsheets were prepared with this emulsion, and the sizing of these handsheets was measured using a 2-min Cobb test.
- the low shear ASA emulsified in a cationic starch solution provided similar performance to the high shear ASA emulsified in the same starch solution (Example 7). Worse performance was achieved when the low shear ASA was emulsified in water and post-diluted with starch solution to provide the sizing agent to starch solids ratio of 1/1.
- the amount of 6.0 g of ASA containing 5 wt % of Brij 98 surfactant was emulsified with 114 g of 0.53 % (w/w) aqueous solution BAYSIZE ® E HE polymer (LANXESS Corporation), using a household blender on low speed for 30 second.
- the emulsion particle size was 1.3 microns.
- the handsheets were prepared with this emulsion. During the handsheets making process, each set was treated with 5 Ib/t of alum. The sizing of these handsheets was measured using a 2-min Cobb test.
- ASA 6.0 g, containing 5 % (w/w) of Brij 98 surfactant was emulsified in 114.O g of tap water, using a household blender on low speed for 30 second.
- the emulsion particle size was 0.95 microns.
- Ten grams of the emulsion was post-diluted with 190 g of 0.026-wt. % aqueous solution of the low molecular weight cationic acr ⁇ lamide polymer BAYSIZE E HE polymer (LANXESS Corporation).
- the handsheets were prepared with this emulsion. During the handsheets making process, each set was treated with 5 Ib/t of alum. The sizing of these handsheets was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size (LANXESS Corporation) was emulsified in the aqueous solution of the low molecular weight cationic acrylamide polymer BAYSIZE E HE polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.1. During the emulsification process, 20 g of BAYSIZE 1 18 size (LANXESS Corporation) was added to 100 g of 2%(w/w) polymer solution and mixed in a household blender on high speed for 3 min. The emulsion particle size was 1.0 micron. The handsheets were prepared with this emulsion. During the handsheets making process, each set was treated with 5 Ib/t of alum. The sizing of these handsheets was measured using a 2- min Cobb test.
- the application of alum in the handsheets making process improved the performance of a low shear ASA.
- the performance of the low shear ASA emulsified in the low molecular weight cationic polymer (Example 8) provided comparable performance to the high shear ASA (Example 10) over the broad dose range.
- the low shear ASA that was emulsified in water and post-diluted with the polymer solution (Example 9) provided worse sizing than ASA emulsified with the polymer, but the difference in the performance was rather small.
- ASA 6.0 g, containing 5 % (w/w) of Brij 98 surfactant was emulsified in 114.0 g of tap water, using a household blender on low speed for 30 second.
- the emulsion particle size was 1.03 microns.
- the emulsion was post-diluted to 0.25 % (w/w) with tap water, and than mixed with a 1% (w/w) cationic starch solution.
- the 82 g/m 2 basis weight handsheets were prepared with this emulsion. Handsheets were made with the recycled furnish obtained from a board mill. During the handsheet-making process, each set was first treated with polyaluminum chloride at a dose of 12 Ib/t of dry fiber.
- ASA emulsion and starch were added to the furnish.
- the mixture of ASA emulsion provided 20 Ib of dry starch per ton of dry fiber.
- an anionic retention aid was added at a dose of 1 Ib/t of dry fiber, and mixing continued for 15 sec. Ink Penetration Holdout was used to evaluate the paper sizing.
- This example was like Example 11 , except that the ASA emulsion and the starch solution was added separately to the furnish.
- ASA 6.0 g, containing 5 % (w/w) of Brij 98 surfactant was emulsified in 114.0 g of tap water, using a household blender on low speed for 30 sec.
- the emulsion particle size was 1.03 microns.
- the handsheets were prepared with this emulsion. Handsheets were made with recycled furnish. During the handsheet-making process, each set was first treated with polyaluminium chloride at a dose of 12 Ib per ton of dry fiber.
- ASA low shear alkenylsuccinic anhydride
- PAPER FURNISH A 30/70 blend of bleached northern softwood Kraft refined to 420 mL
- CSF and bleached northern hardwood Kraft refined to 350 mL CSF was applied in the pilot machine papermaking process.
- Precipitated calcium carbonate was added to the machine chest in the amount of 10 wt. % on dry fiber.
- the basis weight of the paper produced on the pilot machine was 120 gm 2 .
- the pilot machine speed is 85 feet per minute, giving a production rate of about 1.16 Ib/min.
- the pH of the paper furnish was maintained between 7.9 and 8.4.
- the ASA emulsions were diluted with tap water to 0.5 % (w/w) concentration before the addition to the paper furnish.
- An anionic retention aid in the amount of 0.5 Ib per ton of dry paper was applied.
- the paper moisture content was 4 % (w/w) at the reel.
- ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in an aqueous solution of the low molecular weight cationic acrylamide polymer
- BAYSIZE E HE polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.12.
- the emulsification was done according to Method 2, using a centrifugal pump at a speed of 3300 rpm. During the emulsification process, the ASA flow was 50mL/min, the 13.27% (w/w) polymer solution flow was 40 mL/min, and water flow was 810 mL/min. The sizing agent concentration in the emulsion was 5.26 % (w/w). The emulsion particle size was 1.17 microns.
- This emulsion was applied as an internal sizing agent to produce paper on the pilot paper machine.
- the sizing of the felt and wire side of this paper was measured using a 2-min Cobb test.
- ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in tap water.
- the emulsification was done according to Method 1 , using a centrifugal pump at a speed of 1700 rpm.
- the ASA flow was 50.0 mL/min
- the water flow was 850 mL/min.
- the sizing agent concentration in the emulsion was 5.26 % (w/w).
- the emulsion particle size was 1.44 microns.
- the emulsion was post-diluted with the 0.05% (w/w) of BAYSIZE E HE polymer (LANXESS Corporation).
- the sizing agent to polymer solids ratio in the post-diluted emulsion was 1/0.1, and the ASA concentration was 0.5 wt. %.
- This emulsion was applied as an internal sizing agent to produce paper on the pilot paper machine. The sizing of the felt and wire side of this paper was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size (LANXESS Corporation) was emulsified in the aqueous solution of the low molecular weight cationic acrylamide polymer BAYSIZE E HE polymer (LANXESS Corporation) at a sizing agent to polymer solids ratio of 1/0.1.
- BAYSIZE I 18 size (LANXESS Corporation) was added to 180.86 g of a 13.25 % (w/w) polymer solution and 1019.71 g of tap water, and the mixture stirred in an industrial blender on low speed for 1.5 min.
- the emulsion particle size was 1.15 microns.
- Handsheets were prepared with this emulsion. This emulsion was applied as an internal sizing agent to produce paper on the pilot paper machine. The sizing of the felt and wire side of this paper was measured using a 2-min Cobb test.
- the low shear ASA (Example 13) provided slightly better sizing than the high shear ASA (Example 15) over a broad dose range when both sizing agents were applied at the wet-end of paper making process on the pilot machine.
- the low shear ASA emulsified in water and post-diluted with a cationic polymer solution (Example 14) provided a good sizing response, however the sizing was lower than the sizing obtained with the low shear ASA emulsified in the polymer solution (Example 13).
- EXAMPLE 16 ASA containing 5 % (w/w) of Brij 98 surfactant was emulsified in tap water, as it was described in Example 14.
- the emulsion was post-diluted with a 2.2. % (w/w) solution of the Hi-Cat CWS pregelatinized starch (Roquette).
- the sizing agent to starch solids ratio in the post-diluted emulsion was 1/4, and the ASA concentration was 0.5% (w/w).
- This emulsion was applied as an internal sizing agent to produce paper on the pilot paper machine. The sizing of the felt and wire side of this paper was measured using a 2-min Cobb test.
- BAYSIZE 1 18 size (LANXESS Corporation) was emulsified in an aqueous solution of the Hi-Cat CWS pregelatinized starch (Roquette) at a sizing agent to starch solids ratio of 1/1. During the emulsification process, 80 g of BAYSIZE 1 18 size (LANXESS Corporation) was added to 1920 g of 4.17% (w/w) starch solution and mixed in an industrial blender on low speed for 30 sec. The emulsion particle size was 1.37 microns. The emulsion was post-diluted with a 1.7% (w/w) solution of the Hi-Cat CWS pregelatinized starch (Roquette).
- the sizing agent to starch solids ratio in the post-diluted emulsion was 1/4, and the ASA concentration was 0.5% (w/w).
- the handsheets were prepared with this emulsion. This emulsion was applied as an internal sizing agent to produce paper on the pilot paper machine. The sizing of the felt and wire side of this paper was measured using a 2-min Cobb test. Table 6. Performance of Sizing Agents Emulsified in Starch or Post- diluted with Starch.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007557994A JP2008531864A (en) | 2005-03-03 | 2005-10-27 | Low shear cellulose reactive sizing agent for wet end application |
CA002599882A CA2599882A1 (en) | 2005-03-03 | 2005-10-27 | Reduced shear cellulose reactive sizing agent for wet end applications |
US11/817,722 US20100307706A1 (en) | 2005-03-03 | 2005-10-27 | Reduced shear cellulose reactive sizing agent for wet end applications |
EP05821038A EP1866480A1 (en) | 2005-03-03 | 2005-10-27 | Reduced shear cellulose reactive sizing agent for wet end applications |
BRPI0520060-1A BRPI0520060A2 (en) | 2005-03-03 | 2005-10-27 | method for bonding a paper and paper product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65835905P | 2005-03-03 | 2005-03-03 | |
US60/658,359 | 2005-03-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006096216A1 true WO2006096216A1 (en) | 2006-09-14 |
Family
ID=36102589
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/038609 WO2006096216A1 (en) | 2005-03-03 | 2005-10-27 | Reduced shear cellulose reactive sizing agent for wet end applications |
Country Status (11)
Country | Link |
---|---|
US (1) | US20100307706A1 (en) |
EP (1) | EP1866480A1 (en) |
JP (1) | JP2008531864A (en) |
KR (1) | KR20080006546A (en) |
CN (1) | CN101228315A (en) |
AR (1) | AR056272A1 (en) |
BR (1) | BRPI0520060A2 (en) |
CA (1) | CA2599882A1 (en) |
TW (1) | TW200636126A (en) |
WO (1) | WO2006096216A1 (en) |
ZA (1) | ZA200601754B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010054419A1 (en) * | 2008-11-14 | 2010-05-20 | Kemira Chemie Gesmbh | Composition for sizing paper |
WO2011123215A1 (en) * | 2010-04-02 | 2011-10-06 | International Paper Company | Method and system using surfactants in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
FR2991685A1 (en) * | 2012-06-12 | 2013-12-13 | Roquette Freres | PROCESS FOR PRODUCING SUCCINIC ALKENYL ANHYDRIDE (ASA) EMULSION IN AQUEOUS SOLUTION OF CATIONIC AMYLACEOUS MATERIAL, EMULSION OBTAINED AND USE THEREOF |
WO2014053788A1 (en) * | 2012-10-04 | 2014-04-10 | Roquette Freres | Process for producing a stable emulsion of alkenyl succinic anhydride (asa) in an aqueous solution of cationic amylaceous material, emulsion obtained and use thereof |
US11554353B2 (en) | 2009-08-04 | 2023-01-17 | Solenis Technologies, L.P. | Apparatus, system and method for emulsifying oil and water |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007301532A (en) * | 2006-05-15 | 2007-11-22 | Seiko Pmc Corp | Method for preparing dispersion of substituted cyclic dicarboxylic acid anhydride and dispersion |
US8013041B2 (en) * | 2006-12-01 | 2011-09-06 | Akzo Nobel N.V. | Cellulosic product |
CN101778976B (en) * | 2007-07-26 | 2012-11-07 | 播磨化成株式会社 | Internal sizing agent for papermaking and use thereof |
CN104746388B (en) * | 2013-12-25 | 2018-05-08 | 艺康美国股份有限公司 | A kind of method of the sizing efficiency for the ASA lotions for improving macromolecule emulsifier emulsification |
FI126960B (en) * | 2014-02-06 | 2017-08-31 | Kemira Oyj | Stabilized adhesive formulation |
FR3100814B1 (en) * | 2019-09-17 | 2021-11-05 | S N F Sa | AQUEOUS DISPERSION OF WATER-SOLUBLE OR WATER-INFLATABLE POLYMER |
CN113355947B (en) * | 2021-04-13 | 2022-11-29 | 宁波亚洲浆纸业有限公司 | Alkenyl succinic anhydride emulsion for pulp treatment, method for preparing same and paper |
CN114573755B (en) * | 2022-05-05 | 2022-07-29 | 山东奥赛新材料有限公司 | Preparation method of cationic emulsifier for rosin size |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3105903A1 (en) * | 1981-02-18 | 1982-09-09 | Basf Ag, 6700 Ludwigshafen | Process for pulp sizing paper |
US4606773A (en) * | 1984-12-10 | 1986-08-19 | Nalco Chemical Company | Emulsification of alkenyl succinic anhydride sizing agents |
US4657946A (en) * | 1984-06-25 | 1987-04-14 | Nalco Chemical Company | Paper sizing method and emulsion |
EP0257772A1 (en) * | 1986-07-22 | 1988-03-02 | Seiko Kagaku Kogyo Co., Ltd. | A process for making paper using a substituted succinic anhydride as a sizing agent |
WO1997005330A1 (en) * | 1995-07-27 | 1997-02-13 | Cytec Technology Corp. | Synthetic cationic polymers as promoters for asa sizing |
US6165259A (en) * | 1997-02-05 | 2000-12-26 | Akzo Nobel N.V. | Aqueous dispersions of hydrophobic material |
US6576049B1 (en) * | 2000-05-18 | 2003-06-10 | Bayer Corporation | Paper sizing compositions and methods |
WO2004059082A1 (en) * | 2002-12-17 | 2004-07-15 | Lanxess Corporation | Alkenylsuccinic anhydride compositions and method for using the same |
-
2005
- 2005-10-27 WO PCT/US2005/038609 patent/WO2006096216A1/en active Application Filing
- 2005-10-27 US US11/817,722 patent/US20100307706A1/en not_active Abandoned
- 2005-10-27 CN CNA2005800496769A patent/CN101228315A/en active Pending
- 2005-10-27 EP EP05821038A patent/EP1866480A1/en not_active Withdrawn
- 2005-10-27 KR KR1020077022714A patent/KR20080006546A/en not_active Application Discontinuation
- 2005-10-27 JP JP2007557994A patent/JP2008531864A/en not_active Withdrawn
- 2005-10-27 BR BRPI0520060-1A patent/BRPI0520060A2/en not_active IP Right Cessation
- 2005-10-27 CA CA002599882A patent/CA2599882A1/en not_active Abandoned
-
2006
- 2006-02-28 ZA ZA200601754A patent/ZA200601754B/en unknown
- 2006-03-02 AR ARP060100789A patent/AR056272A1/en unknown
- 2006-03-02 TW TW095107012A patent/TW200636126A/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3105903A1 (en) * | 1981-02-18 | 1982-09-09 | Basf Ag, 6700 Ludwigshafen | Process for pulp sizing paper |
US4657946A (en) * | 1984-06-25 | 1987-04-14 | Nalco Chemical Company | Paper sizing method and emulsion |
US4606773A (en) * | 1984-12-10 | 1986-08-19 | Nalco Chemical Company | Emulsification of alkenyl succinic anhydride sizing agents |
EP0257772A1 (en) * | 1986-07-22 | 1988-03-02 | Seiko Kagaku Kogyo Co., Ltd. | A process for making paper using a substituted succinic anhydride as a sizing agent |
WO1997005330A1 (en) * | 1995-07-27 | 1997-02-13 | Cytec Technology Corp. | Synthetic cationic polymers as promoters for asa sizing |
US6165259A (en) * | 1997-02-05 | 2000-12-26 | Akzo Nobel N.V. | Aqueous dispersions of hydrophobic material |
US6576049B1 (en) * | 2000-05-18 | 2003-06-10 | Bayer Corporation | Paper sizing compositions and methods |
WO2004059082A1 (en) * | 2002-12-17 | 2004-07-15 | Lanxess Corporation | Alkenylsuccinic anhydride compositions and method for using the same |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010054419A1 (en) * | 2008-11-14 | 2010-05-20 | Kemira Chemie Gesmbh | Composition for sizing paper |
RU2511385C2 (en) * | 2008-11-14 | 2014-04-10 | Кемира Хеми Гезмбх | Composition for paper pasting |
AU2009316222B2 (en) * | 2008-11-14 | 2016-06-02 | Kemira Chemie Gesmbh | Composition for sizing paper |
US10513828B2 (en) | 2008-11-14 | 2019-12-24 | Kemira Chemie Ges.Mbh | Composition for sizing paper |
US11554353B2 (en) | 2009-08-04 | 2023-01-17 | Solenis Technologies, L.P. | Apparatus, system and method for emulsifying oil and water |
WO2011123215A1 (en) * | 2010-04-02 | 2011-10-06 | International Paper Company | Method and system using surfactants in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
US8440053B2 (en) | 2010-04-02 | 2013-05-14 | International Paper Company | Method and system using surfactants in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
FR2991685A1 (en) * | 2012-06-12 | 2013-12-13 | Roquette Freres | PROCESS FOR PRODUCING SUCCINIC ALKENYL ANHYDRIDE (ASA) EMULSION IN AQUEOUS SOLUTION OF CATIONIC AMYLACEOUS MATERIAL, EMULSION OBTAINED AND USE THEREOF |
WO2013186491A1 (en) * | 2012-06-12 | 2013-12-19 | Roquette Freres | Method for producing an emulsion of alkenyl succinic anhydride (asa) in an aqueous solution of a cationic amylaceous substance, resulting emulsion, and use thereof |
US9567711B2 (en) | 2012-06-12 | 2017-02-14 | Roquette Freres | Method for producing an emulsion of alkenyl succinic anhydride (ASA) in an aqueous solution of a cationic amylaceous substance, resulting emulsion, and use thereof |
WO2014053788A1 (en) * | 2012-10-04 | 2014-04-10 | Roquette Freres | Process for producing a stable emulsion of alkenyl succinic anhydride (asa) in an aqueous solution of cationic amylaceous material, emulsion obtained and use thereof |
FR2996555A1 (en) * | 2012-10-04 | 2014-04-11 | Roquette Freres | PROCESS FOR THE PRODUCTION OF A STABLE EMULSION OF SUCCINIC ALKENYL ANHYDRIDE (ASA) IN AQUEOUS CATIONIC AMYLACEOUS SOLUTION, EMULSION OBTAINED AND USE THEREOF |
Also Published As
Publication number | Publication date |
---|---|
AR056272A1 (en) | 2007-10-03 |
BRPI0520060A2 (en) | 2009-04-14 |
ZA200601754B (en) | 2007-03-28 |
CA2599882A1 (en) | 2006-09-14 |
US20100307706A1 (en) | 2010-12-09 |
JP2008531864A (en) | 2008-08-14 |
EP1866480A1 (en) | 2007-12-19 |
CN101228315A (en) | 2008-07-23 |
KR20080006546A (en) | 2008-01-16 |
TW200636126A (en) | 2006-10-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20100307706A1 (en) | Reduced shear cellulose reactive sizing agent for wet end applications | |
AU2003301017B2 (en) | Alkenylsuccinic anhydride surface-applied system and method for using the same | |
US20090277355A1 (en) | Alkenylsuccinic anhydride surface-applied system and uses thereof | |
US5759249A (en) | Sizing emulsion | |
US20090281212A1 (en) | Alkenylsuccinic anhydride surface-applied system and uses thereof | |
KR20030042445A (en) | Process for sizing paper | |
EP0151994B1 (en) | Method of preparing an improved sizing agent and novel paper sizing method | |
US20140069600A1 (en) | Method for the emulsification of asa with polyamidoamine epihalohydrin (pae) | |
EP2691572A1 (en) | Sizing compositions | |
US7943789B2 (en) | Alkenylsuccinic anhydride composition and method of using the same | |
AU2003301019B2 (en) | Alkenylsuccinic anhydride compositions and method for using the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200580049676.9 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2599882 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007557994 Country of ref document: JP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005821038 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: RU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 7599/DELNP/2007 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020077022714 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2005821038 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: PI0520060 Country of ref document: BR Kind code of ref document: A2 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11817722 Country of ref document: US |