WO2006083663A2 - Method and apparatus for controlled production of a gas - Google Patents

Method and apparatus for controlled production of a gas Download PDF

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Publication number
WO2006083663A2
WO2006083663A2 PCT/US2006/002749 US2006002749W WO2006083663A2 WO 2006083663 A2 WO2006083663 A2 WO 2006083663A2 US 2006002749 W US2006002749 W US 2006002749W WO 2006083663 A2 WO2006083663 A2 WO 2006083663A2
Authority
WO
WIPO (PCT)
Prior art keywords
oxygen
gas
chamber
reaction
container
Prior art date
Application number
PCT/US2006/002749
Other languages
French (fr)
Other versions
WO2006083663A3 (en
Inventor
Julian Ross
Charles R. Keyes, Jr.
Original Assignee
Oxysure Systems, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/158,377 external-priority patent/US20060171860A1/en
Application filed by Oxysure Systems, Inc. filed Critical Oxysure Systems, Inc.
Priority to CA002596247A priority Critical patent/CA2596247A1/en
Publication of WO2006083663A2 publication Critical patent/WO2006083663A2/en
Publication of WO2006083663A3 publication Critical patent/WO2006083663A3/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B21/00Devices for producing oxygen from chemical substances for respiratory apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2445Stationary reactors without moving elements inside placed in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/02Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00Apparatus for generating gases
    • B01J7/02Apparatus for generating gases by wet methods
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0203Preparation of oxygen from inorganic compounds
    • C01B13/0207Water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0203Preparation of oxygen from inorganic compounds
    • C01B13/0211Peroxy compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00029Batch processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00038Processes in parallel

Definitions

  • the present invention relates generally to a gas delivery system and, more particularly, to a system that provides an activation method and apparatus as well as a method and apparatus for improving and controlling the gas yield, flow rates and gas production duration .
  • the resultant reaction reaches a flow rate of 2 liters per minute after 30 minutes .
  • Other devices create a tablet out of an oxygen generating agent, which similarly produces a low reaction onset (the flow rate at which the reaction commences) and low flow rates over the reaction period.
  • These prior attempted solutions may not be suitable for emergency applications, usually medical in nature or situations where life-threatening factors are present where high flow rates of at least 2 liters per minute to 6 liters per minute or higher are required almost instantly .
  • conventional generators have had limited adoption in commerce and in industry . There are several possible factors contributing to this lack of adoption .
  • These factors may include one or a ' combination of unfavorable characteristics relating to reusability, safety, ease of use/operation, speed of use, heat management, cost, weight, aesthetic design, environmental impact, manufacturability, portability, medical efficacy, effectiveness , flow rate , gas yield, reaction stability, and purity of the gas . Some or all of these characteristics are not addressed, or are inadequately addressed, by the designs in the prior art .
  • the present invention provides an apparatus for generating gas from a plurality of separated chemicals .
  • a plurality of reaction chambers operate cooperatively when the separated chemicals are combined to generate the gas .
  • the flow rate and the total yield can then be varied based on the proportion of separated chemicals in each reaction chamber .
  • FIGURE 1 is a diagram, partly in section, depicting an exploded side view of gas activation, production, dispensing and control vessel in accordance with an embodiment of the present invention
  • FIGURE 2 is a diagram, partly in section, depicting a side view of a primed gas activation, production, dispensing and control vessel;
  • FIGURE 3 is a schematic sectional view of the gas activation, production, dispensing and control vessel, in use, with the spiked plungers inserted;
  • FIGURE 4A is a plan view of an example of a screen
  • FIGURE 4B is a sectional view of the screen depicted in FIGURE 4A;
  • FIGURE 5A depicts a plan view of a foam breaker, taken along the lines 5B, 5C;
  • FIGURE 5B depicts a cross sectional view of the foam breaker of FIGURE 5A;
  • FIGURE 5C depicts a cross sectional view of the foam breaker of FIGURES 5A and 5B when compressed;
  • FIGURE 6A depicts a plan cross sectional view of a handle useful in connection with the present invention;
  • FIGURE 6B depicts a side cross sectional view of a handle useful in connection with the present invention, taken along the line 6B;
  • FIGURE 7 of the drawings is a partially cross sectioned view of a female connector useful in connection with the present invention.
  • FIGURE 8 depicts a cross sectional view of a male connector adapted to fit with the female connector depicted in FIGURE 7 ;
  • FIGURE 9 depicts a side view, partly in cross section, of one embodiment of the connectable spiked plunger, as connected to the female connector depicted in FIGURE 7 ;
  • FIGURE 1OA depicts a side cross sectional view of a spiked plunger;
  • FIGURE 1OB depicts a side cross sectional view of a spiked plunger in its female connector housing, with the spiked plunger disconnected
  • FIGURE 1OC depicts a side cross sectional view of a spiked plunger in its female connector housing, with the spiked plunger connected to it;
  • FIGURE 11 depicts a side cross sectional view of a spring loaded spiked plunger and release mechanism
  • FIGURE 12 depicts a side cross sectional view of a cartridge filled with initially separated chemicals and having a pressure relief system
  • FIGURE 13A depicts a side cross sectional view of an activation system for one reaction chamber of the gas activation, production, dispensing and control vessel depicted in FIGURES 1 and 2 , having a spike, with the spike withdrawn for clarity;
  • FIGURE 13B depicts a side cross sectional view of an activation system for one reaction chamber of the gas activation, production, dispensing and control vessel depicted in FIGURES 1 and 2 , having a spike inserted into the container holding the water to rupture it and allow mixing the the other chemicals to create a flow of gas , with the flow of gas produced indicated by arrows ;
  • FIGURE 14 depicts a side cross sectional view of an activation system with dual reaction chambers having spikes as depicted in FIGURES 1OA, 1OB and 1OC, and having a hanging catalyst bag, with the spike withdrawn and primed for activation;
  • FIGURE 15 depicts a side cross sectional view of an another embodiment of an activation system with dual reaction chambers having spikes as depicted in FIGURE 9, the male connectors depicted in FIGURE 8 , and compartments for retaining the catalyst and water as depicted in FIGURE l ⁇ Awith the spike withdrawn and primed for activation;
  • FIGURE 16A depicts a cross-sectional side view of the water containment housing and an adj acent catalyst dispersal housing depicted in FIGURE 15 ;
  • FIGURE 16B depicts cross-sectional side view of a modified version of the catalyst dispersal housing depicted in FIGURE 16A;
  • FIGURE 17A depicts a side cross sectional view of another embodiment of an activation system for one reaction chamber, having a fixed activation member, in the primed position;
  • FIGURE 17B depicts a side cross sectional view of the embodiment of an activation system for one reaction chamber depicted in FIGURE 17A, after activation, the arrows indicating flow of the water and catalyst;
  • FIGURE 18A depicts a front view, partly in phantom, of a powder release pouch cartridge assembly
  • FIGURE 18B is a sectional side view of the powder release pouch cartridge assembly depicted in FIGURE 18A, taken along line 18A-A;
  • FIGURE 19 is a partially diagrammatic side view of a bubbler
  • FIGURE 20 is a diagram depicting a heat exchanger/ radiator
  • FIGURE 21 depicts a side cross sectional view of an embodiment of a cartridge for one reaction chamber, showing different locations for the catalyst and gas/oxygen producing agent
  • FIGURE 22 depicts a side cross sectional view of another embodiment of a cartridge for one reaction chamber
  • FIGURE 23A depicts a cross-sectional front view of a container for containing pouch-type reaction chambers as depicted in FIGURES 26A and 2 ⁇ B, utilizing a mechanical lever to initiate the gas-generating reaction;
  • FIGURE 23B depicts a cross-sectional side view of the container depicted in FIGURE 23A, taken along the line 23A- 23A.
  • FIGURE 24A is a diagram contrasting the flow rate of two gas producing reactions ;
  • FIGURE 24B is a diagram showing the combined flow rate of two gas producing reactions of FIGURE 24A;
  • FIGURE 25A is a diagram contrasting the flow rate of two gas producing reactions initiated at different times ; and FIGURE 25B is a diagram showing the combined flow rate of two gas producing reactions of FIGURE 25A.
  • FIGURE 26A depicts a pouch-type, self-contained, reaction chamber including separate compartments for the catalyst, gas/oxygen producing agent and water
  • FIGURE 26B depicts another embodiment of a pouch-type, self-contained, reaction chamber including differently shaped, separate compartments for the catalyst, gas/oxygen producing agent and water .
  • the reference numeral 100 generally designates an exploded view of a gas activation, production, dispensing and control assembly using a manual reaction activation method in accordance with an embodiment of the present invention .
  • the assembly 100 comprises support housing 102 , removable reaction chambers 106, screens 108 , filters 110 , lids 112 , and a handle 122.
  • the main body of the assembly 100 is the support housing 102.
  • the support housing 102 There are a number of configurations that can be employed, but a convenient design is a vessel having vertically extending side walls and a bottom surface connecting the side walls .
  • the support housing 102 also has an opening in the top where other members can be inserted.
  • the support housing 102 can also be a smooth, continuous surface or it can be several j oined, flat surfaces .
  • the support housing has a compartment for each reaction chamber and can have curved surfaces such that it curves around the reaction chambers 106 in approximately the shape of a figure eight, as viewed from above .
  • the gas activation, production, dispensing and control assembly 100 can be- conveniently worn on the hip, by clip-on or otherwise of say, a miner, construction worker or emergency service personnel .
  • the support housing 102 can employ two guides 104 that protrude outwardly from the side walls of the support housing 102 to interface with and/or slidably receive the guided members 114 of the handle 122.
  • the two guide members 104 allow the user to activate the chemical reaction producing the oxygen or other gas, by pushing the handle 122 in a direction toward the housing 102.
  • the two guide members 104 allow for this to be a smooth and easy process .
  • the two guide members 104 Upon completion of the chemical reaction, the two guide members 104 similarly allow for a smooth and easy disengagement of the handle 122 in a direction away from the housing 102 utilizing a quick release mechanism 720 (depicted in FIGURE 7 , but not shown in FIGURE 1) .
  • the support housing 102 can also act as an additional insulating material to act as a heat shield for any excess heat being generated in the reaction chambers .
  • Each of the reaction chambers 106 can be placed within the support housing 102 such that access can be gained to each reaction chamber 106.
  • the reaction chambers 106 can be made of a durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat .
  • the reaction chambers 106 can be made of polycarbonate or polytetrafluoroethylene .
  • the lids 112 can be attached to the reaction chambers 106.
  • reaction chambers 106 can have internal female threads and the lids 112 can have corresponding external male threads .
  • the lids 112 can be attached to the reaction chambers 106 by clip in, lock in or click in designs .
  • Screens 108 and filters 110 can be seated on a flange 107 inside reaction chambers 106, but such is not essential to the design .
  • screens 108 and filters 110 can also simply be maintained in position by mechanical pressure, or glued, as depicted in FIGURE 3.
  • the reaction chambers 106 are typically cylindrically shaped, but can be any other shape .
  • the reaction chambers 106 can be coupled to the lids 112 prior to insertion into the support housing 102.
  • the reference numeral 200 generally designates a primed gas production control vessel .
  • gas production can be initiated by engaging the handle 122.
  • the guide members 104 (of support housing 102 ) can contain and guide the arms 114 of the handle 122. By allowing the arms 114 to freely slide within the guides 104 a user would simply place pressure on the handle 122 in a direction toward the support housing 102.
  • each of the spiked plungers 118 can be aligned with an opening 116 of a lid 112. Therefore, when engaged, each of the spiked plungers 118 can be slidably inserted into each of the reaction chambers 106 to initiate the reaction and carry out the resultant gas .
  • the reference numeral 300 generally designates a cut-away of a gas activation, production, dispensing and control vessel in use .
  • reaction chambers 106 When fully assembled, control of the gas production is achieved through the use of multiple reaction chambers 106. Two reaction chambers are depicted, but there can be more reaction chambers depending on the desired flow rate and yield. One reaction chamber can also be used. Chemical reactions occur in the lower portions 210 of the reaction chambers 106. By varying the proportion, amounts and/or composition of the reactants within the vessel, two different reaction rates (and yields ) can be maintained independently in each of the reaction chambers 106. Hence, each reaction chamber 106 can contribute a fractional gas output of the total gas output of the vessel, allowing for a variety of gas yields and flow rates . Moreover, the reactants in each reaction chamber 106 can vary, as well , to achieve a desired gas yield and gas flow rate .
  • Each of the reaction chambers 106 rests within the support housing 102.
  • Each of two guided members 114 of the handle 122 are inserted through one of two guide members 104.
  • Each of the reaction chambers 106 are then coupled to the handle 122 by mechanical couplers 206.
  • the mechanical couplers 206 can be a variety of mechanical coupler types , such as threaded couplers or couplers employing snapping edges .
  • the combination of use of the guide members 104 and the couplers 206 allow for a good mechanical connection during use .
  • spiked plungers 118 can be employed to allow gas transmission from the reaction chambers 106 to the gas transmission channel 202 of the handle 122.
  • the spiked plungers 118 can each be coupled to the handle 122 within the gas transmission channel 202 of the handle 122 and can each be inserted into a reaction chamber 106.
  • Each spiked plunger 118 can contact both the filter 110 and the screen 108.
  • the screens 108 can be located at positions adj acent to the lower portions 210, which allow gas to pass and provide mechanical support for the filters 110. Because of the mechanical constraints of the mechanical couplers 206 and the guide members 104 , the spiked plungers 118 can each maintain mechanical contact between the filter 110 and the screen 108.
  • Gas produced within the lower portions of the reaction chamber 106 can then pass around the tip of the plunger 118 , through the screens 108 , the filters 110 , and into transmission openings 224 in spiked plungers 118.
  • each of the reaction chambers 106 and the lids 112 , along with the reaction chambers' contents such as the gas/oxygen generating material, catalyst, water, screen and filter forms a self-contained cartridge 109 that can be disposable .
  • Each self-contained cartridge 109 is therefore easily replaceable if a user requires additional oxygen or gas (as the case may be) upon completion of a use .
  • the gas activation, production, dispensing and control assembly 300 can be designed to produce 15 minutes of oxygen for emergency or short-duration purposes .
  • Self-contained cartridges can be attached to each other to form one removable, self-contained cartridge .
  • the lids 112 can each have a cap to close the respective openings 116, after the completion of the reaction . Closing the openings 116 facilitates the prevention of any leakage of the reaction residue and thereby facilitates convenient disposal of the cartridges .
  • the gas/oxygen releasing agent, the catalyst and the water comprising the ingredients used to make the reaction in the current invention work .
  • the gas/oxygen releasing agent, the catalyst and the water remain separated until a reaction is reguired.
  • the gas/oxygen releasing agent and the catalyst can remain inert and can have an indefinite shelf life if they are kept dry and moisture free .
  • One configuration example is to have the gas/oxygen releasing agent located at the base of the cartridge (in reaction chambers 106) , the catalyst located above the gas/oxygen releasing agent, and the water located above the catalyst, such as for example in the plenums 111 of the lids 112.
  • the water Upon activation, the water is released and can flow in toward the lower portion of the reaction chamber 106, where the gas/oxygen producing agent (not shown) is disposed, carrying the catalyst along with it through a flushing action, to mix with the gas/oxygen releasing agent at the base of the cartridge .
  • the gas/oxygen producing agent (not shown) is disposed, carrying the catalyst along with it through a flushing action, to mix with the gas/oxygen releasing agent at the base of the cartridge .
  • the gas/oxygen producing agent (not shown) is disposed, carrying the catalyst along with it through a flushing action, to mix with the gas/oxygen releasing agent at the base of the cartridge .
  • a different cartridge configuration is one where the gas/oxygen releasing agent is located above the water and the catalyst .
  • the gas/oxygen releasing agent and/or the catalyst is/are released to mix with the water in order to activate the reaction .
  • this cartridge configuration as a chemical releasing cartridge .
  • the resultant gas can carry small airborne droplets of the gas production solution, or can carry small particles from the reactants .
  • These airborne particles can be undesirable to the equipment attached to the gas generator or to the lungs of an individual . Therefore, there is a need to filter these undesirable particles .
  • Methods that can be used include selecting appropriate materials to capture the undesirable particles , and to select an appropriate configuration by locating the selected materials in an appropriate location, relative to other components in the invention . Therefore, material selection and placement can be important factors .
  • the filter material employed depends on the gas produced, the composition of the solution, and the usage of the gas .
  • the filters 110 can be sponge-like materials to capture the undesirable particles , while allowing the gas to flow through at desirable flow rates .
  • Other effective filter materials can be polytetrafluoroethylene or can be Nylon®, which is available from DuPont .
  • filters can also be useful in extracting some heat out of the gas being produced, either in their untreated form, or by being treated with various substances .
  • FIGURE 4 depicts an example of a screen that can be used.
  • the screens 108 can serve to support the filters 110 , while allowing the water to rapidly and evenly disperse into the reaction chambers 106, in order to activate the chemical reaction that produces the oxygen or gas , as the case may be .
  • the screen 108 In order to allow fluid transfer through the screen 108 , several opening can be provided. The edges of the screen 108 would rest against the inner walls of a reaction chamber 106 or on a surface within the reaction chamber 106. Fluids would then be allowed to pass through the openings 404 , 402 , and 406. Additionally, when engaged, the spiked plungers 118 would at least partially reside within the opening 402.
  • FIGURE 5A depicts a cross sectional view of the foam breaker 500 , where the opening 502 would allow the spiked plunger 118 to reside when engaged.
  • FIGURE 5B depicts a side view of the foam breaker 500
  • FIGURE 5C depicts a side view of the foam breaker 500 when compressed.
  • Chemical reactions can produce foam, and a foam breaker 500 can counteract this effect .
  • a steel mesh with an appropriate mesh size can be used.
  • Another material that can be used as a foam breaker is a commonly used pot scourer or scrub sponge material, or durable foam material .
  • the foam breaker can be optionally placed within the same fluid transmission path in which both the screens 108 and the filters 110 reside .
  • the screens 108 can also act as foam breakers, and the filters 110 can also act as foam breakers .
  • the screens 108 and filters 110 , acting together can also act as foam breakers .
  • Another method is to apply a defoaming agent or surfactant to the walls and/or the screen and/or the lid and filter .
  • Defoaming agents that can be used include silicone based, polymer based or mineral oil based agents , as well as other surfactants .
  • the filter should follow the foam breaker or defoaming agent (as considered in the direction of the gas flow) .
  • the reference numeral 122 generally designates the handle .
  • the handle 122 effectively operates as a manifold. Especially in situations where multiple reaction chambers are used, it is desirable to have a manifold or similar method of combining the gas flow from each individual reaction chamber 106.
  • the manifold gas transmission channel 202 performs the function of combining gases , and the gas flows from each reaction chamber 106 into the ports 602. The gases are then combined in the manifold gas transmission channel 202.
  • the spiked plungers 118 Upon activation, however, the spiked plungers 118 should provide a continuous gas transmission to the manifold gas transmission channel 202.
  • the mechanical coupler 206 can secure lids 112 in such a manner as to seal off the opening 116 of the lids 112 and maintain the connection between the spiked plunger 118 and the handle 122.
  • the mechanical coupler 206 can be a simple coupler 206 to which the nozzle 116 of the self-contained cartridge 109 is inserted, as depicted in FIGURE 3
  • the couple 206 or can comprise a cooperatively designed male connector adapted to fit over the nozzle 116, as depicted in FIGURE 8 , and a female connector adapted to fit into the male connection, as depicted in FIGURES 7 , 9, 1OB and 1OC .
  • the reference numeral 700 refers to the female connector .
  • the female connector 700 is typically attached to the spiked plunger 118 , where the spiked plunger 118 is inserted into the opening 704 of the female connector 700. Additionally, as depicted in FIGURES 14 and 15 , the female connector couples to the ports 602 of the handle 122. When engaged, the female connector 700 snaps into place .
  • the female connector 700 comprises an arm 702 that possesses an engagement edge that allows for coupling to a male connector .
  • the female connector 700 can be made of various materials , including, without limitation polypropylene, polyethylene , polycarbonate, HDPE, ABS, Acetal , or Polysulfone .
  • FIGURE 8 is a side view of the male connector 800 , with the O-ring seal shown in cross- section for clarity .
  • the male connector 800 is a cylindrical tube that is able to engage the female connector 700.
  • the male connector can comprise an O-ring 802, an upper edge 804 , and a lower edge 806.
  • the O-ring 802 is responsible for providing a gas seal between the male connector 800 to the female connector 700 the male connector 800 is inserted into the female connector during use .
  • the 0-ring can be made of various materials, including, without limitation, silicone or platinum-cured silicone . Platinum-cured silicone can allow for repeated usage of more than one thousand times .
  • the lower edge 806 can engage the edge of the arm 702 by a clicking action .
  • a slanted engaging face 808 is employed.
  • the upper edge 804 prevents excessive play by providing a stop for the edge of the arm 702.
  • the male connector can also be made of various materials , including, without limitation polypropylene, polyethylene, polycarbonate, HDPE, ABS , acetal, or polysulfone .
  • the male connector 800 can then be secured to the lid 112 by using threads .
  • the lid 112 is coupled to the male connector through the opening 810. Therefore, female threads would be contained on the inner walls of the male connector 800 while the male threads would be contained on the lid 112.
  • the quick release mechanism 720 can be coupled to the arm 702 of the female coupler 700. By pressing the quick release mechanism 720 in the direction toward the plane created by the azimuthal axes of the spiked plungers 118 , the male connector and the female connector can be disengaged. Additionally, the quick release mechanism 720 can be configured to disengage the female connectors 700 from the male connectors 800 by simply gripping the quick release lever 128 in a direction toward the handle 122. For applications such as emergency applications it is desirable to have an efficient and easy activation method, which is simultaneously manufacturable and economical .
  • the activation method should be such as to commence the chemical reaction instantaneously or near instantaneously with typically one easy step .
  • activation can be achieved by a single push-down action that applies pressure to the handle 122.
  • a system can also be electronic or a sensor, such as for example a system used to detect decompression in aircraft, thereby triggering the deployment of emergency oxygen in the aircraft cabin .
  • the spiked plungers 118 ' are each inserted into lids 112.
  • the spiked plunger 118 and 118 ' are typically hollow cylindrically-shaped members that have a tip that is suitable for and utilized to puncture a material .
  • the reference numeral 900 generally designates one embodiment of the connectable spiked plunger .
  • the connectable spiked plunger 900 comprises a female connector 700 and a spiked plunger 118.
  • the spiked plunger 118 can comprise a cylindrically-shaped shaft 906 with a spiked end 904.
  • a gas transmission channel 902 along the azinvuthal axis of the spiked plunger 118 that allows gas to travel through the plunger 900.
  • transmission openings 224 are employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118.
  • the plunger 900 is designed to puncture a material container or containment bag to initiate a chemical reaction .
  • the spiked plunger 118 can puncture a container or bag that contains water, or the spiked plunger 118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be .
  • the spiked plungers 118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat .
  • the spiked plungers 118 can be made of polycarbonate .
  • an extended spiked plunger can be employed.
  • the reference numeral 1000 generally designates an extended spiked plunger 118 ' .
  • the plunger 118 ' can comprise a female connector 700 and a spiked plunger 118 ' .
  • the spiked plunger 118 ' is different in that it is extended.
  • the spiked plunger 118 comprises a torso 1002 and an extension shaft 1004 with a sharp tip 1006.
  • the torso 1002 can be cylindrically shaped and employ a gas transmission channel 902 along the azimuthal axis of the torso 1002 that allows gas to travel through the plunger 118 ' .
  • transmission openings 224 can be employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118' .
  • the extension shaft 1004. can be cylindrically- shaped with one end inserted into the female receptive aperture 1008 at the end of the torso 1002.
  • the sharp tip 1006 can then be attached to the other end of the extension shaft 1004.
  • the plunger 1000 is designed to puncture a material containment container or bag to initiate a chemical reaction .
  • the spiked plunger 118 can puncture a container or bag that contains water, or the spiked plunger 118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be .
  • the spiked plungers 118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat .
  • the spiked plungers 118 can be made of polycarbonate .
  • an initiator can be employed as a push-button, lever or pin .
  • An initiation system can also be electronic or a sensor, such as for example a system used to detect decompression in aircraft, thereby triggering the deployment of emergency oxygen in the aircraft cabin .
  • the reference numeral 1100 depicts a spring loaded spiked plunger 1118.
  • the spring loaded spiked plunger 1118 then can utilize potential energy stored in a spring to extend its sharp tip 1110 into the containers of water and/or chemicals to begin the chemical reaction that produces the gas .
  • the spring 1106 can be maintained within the spring housing 1114 and held in place by a retainer 1104.
  • the process of initiating the chemical reaction would involve the utilization of an actuator 1102 , which is shown as a push-button actuator .
  • the actuator 1102 causes the retainer 1106 a lever arm 1107 to pivot about pivot 1109, pulling out pin 1104 to release the spring 1106.
  • the spring 1106 then exerts a force on the spiked plunger 1118.
  • the spiked plunger 1118 can comprise a cylindrically shaped shaft with a spiked end 1110. Within the spiked plunger 1118 is a gas transmission channel 902 along the azimuthal axis of the spiked plunger 1118 that allows gas to travel through the plunger 1118. Additionally, transmission openings 224 can be employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118.
  • the plunger 1118 is designed to puncture a material containment container or bag to initiate a chemical reaction .
  • the spiked plunger 1118 can puncture a container or bag that contains water, or the spiked plunger 1118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be .
  • the spiked plungers 1118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat .
  • the spiked plungers 1118 can be made of polycarbonate .
  • An actuator can utilize the pressure associated with a chemical release cartridge .
  • a pressure supply can also be achieved by supplying air pressure to the activation system.
  • Another type can be a mechanical or electro-mechanical source , such as can be provided by a mechanical or electro-mechanical pump or motor .
  • Yet another type can be a pneumatic source , such as for example a pneumatic pump or motor, or a hydraulic source .
  • pressures in the reaction chamber 106 can be high and dangerous .
  • the reference numeral 1200 generally designates a cartridge with a relief system.
  • the cartridge 1200 comprises a reaction chamber 106, a screen 108 , a containment bag 1202 , a filter 110 , and a lid 112.
  • the reaction chamber 106 When in storage or not in use, the reaction chamber 106 contains “dry” reactants .
  • the “dry” reactants typically include an oxygen rich powder reactant, such as sodium carbonate or sodium percarbonate, as the gas/oxygen generating agent .
  • the dry reactants can be liquid reactants that require an additional solvent, such as water, or other "wet” chemical to initiate a gas producing reaction .
  • These "dry” reactants can also contain “dry” catalysts that can assist in reducing heat or increase the reaction rate, such as manganese dioxide .
  • the water can include an additive to depress the freezing point of the water, but need not do so .
  • the screen 108 is mechanically supported in a position adj acent to the cavity containing the "dry" reactants .
  • the screen 506 can be mechanically supported in a number of ways, such as by use of threading, snapping edges, and/or taper of the inner walls of the reaction chamber 106.
  • the screen 108 can provide mechanical support for the remaining components contained within the cartridge 1200.
  • a containment bag 1202 is positioned adj acent to the screen 108 , so that, when pierced, the contents of the bag 1202 can be transmitted through the screen to the "dry" chemicals to begin the reaction .
  • the filter 110 is also supported by the screen 108 , so that when gas is produced and transmitted through the screen 506, the gas can be filtered.
  • a variety of filter types can be employed that can be comprised of a variety of materials including, but not limited to, polytetrafluoroethylene .
  • the final component of the cartridge 1200 is the lid 112.
  • the lid 512 can be coupled to the reaction chamber 106. There are a number of ways to couple the lid 112 to the reaction chamber 106, such as threading and an adhesive .
  • a pressure relief valve 1214 An additional feature of the cartridge 1200 , however, is the presence of a pressure relief valve 1214.
  • volatile gases such as oxygen or hydrogen
  • high pressures can be dangerous .
  • gases do not present a fire hazard such as nitrogen
  • high pressures can be an undesirable because the high pressure gas can exploit defects or fractures in the cartridge 1200 to cause the cartridge to rupture .
  • a relief valve 1214 can be employed to relieve pressure within the chamber at a calibrated level . For example, pressure relief can occur at 300 psig.
  • pressure relief can occur at 300 psig.
  • pressure relief systems there are a wide variety of pressure relief systems available, such as pop-off valves and rupture discs that can be adequately calibrated to relieve pressure at a desired level .
  • FIGURES 13A and 13B of the drawings depict an activation system primed for activation and the system in use, respectively .
  • the system 1300 comprises a cartridge 1301 , a spiked plunger 118 , and a female connector 700.
  • the cartridge 1301 then comprises a filter 110, water-filled bag 1304 , a screen
  • the bag housing the catalyst 1306 can be made of any number of materials, but can also be made of a water-soluble material .
  • the bag 1304 housing the water can be made of any number of air impermeable and water/moisture impermeable materials, but can also be made of a laminate material consisting of aluminum, polypropylene and woven mesh .
  • the cartridge 1301 typically also has an air-impermeable and water-impermeable seal 1302.
  • the air-impermeable and water-impermeable seal 1302 can be made of various materials, including, without limitation materials such as Mylar, polytetrafluoroethylene or Nylon®. The purpose of the seal
  • spiked plunger 1302 is to maintain an hermetic seal so that the cartridge can have an extended or indefinite shelf life .
  • the spike tip 904 punctures or ruptures the seal 1302 , and the spiked plunger 118 enters the filter aperture 1320.
  • the spike tip 904 punctures or ruptures the water bag 1304 , causing the water to flow into the reaction chamber 106.
  • the spiked plunger 1130 completes the piercing of the water bag 1172 and proceeds through the screen aperture 402 such that the spike tip 1142 protrudes just slightly beyond the screen 108. Once the spiked plunger 1130 has penetrated the water bag 1172 and traversed all the way through, spiked plunger and connector assembly 1140 is secured to the cartridge and sealed by the connector 1180.
  • the water creates an aqueous environment for the reaction to take place .
  • the water dissolves the bag containing the catalyst 1306.
  • the gas generated as a result of the reaction can then be released from the cartridge 1301 through the spiked plunger 118.
  • the reference 1400 generally designates a release system with a hanging catalyst .
  • the system 1400 comprises cartridges 1401 , a handle 122 , and cutting members such as spiked plungers 118.
  • Within the cartridges 1401 there is an upper assembly 1402 , a hanging catalyst 1404 , and a gas generating chemical 1308.
  • the spiked plunger 118 engages the upper assembly 1402. Water then flows into the reaction chamber 106. The water creates an aqueous environment for the reaction to take place, while dissolving or permeating the bag containing the catalyst 1404.
  • the gas generated as a result of the reaction can then be released from the cartridge 1401 through the spiked plunger 118 to the gas transmission channel 202 of the handle 122.
  • the bag housing the catalyst 1404 is suspended slightly above the gas generating material 1308, which facilitates faster dissolution of the bag if the bag is a water-soluble bag, or faster permeation through the bag if the bag is permeable .
  • the reference number 1500 depicts another system primed for activation .
  • the system 1500 is different in that the catalyst is contained in a catalyst dispersal housing 1502 , located j ust below the water containment housing 1504.
  • the water containment housing 1504 can contain a bag with water, or can have water contained inside of it .
  • the system 1500 can comprise self-contained water releasing cartridge 1501 , a spiked plunger 118 , and a connector assembly 700 coupled to the handle 122.
  • the cartridge 1501 comprises a gas or oxygen releasing agent 1308 , the catalyst dispersal housing 1502 , the screen 108 , and the water containment housing 1504.
  • the bag can be made of any number of impermeable materials , but can also be made of a laminate material consisting of aluminum, polypropylene and woven mesh .
  • the spiked plunger 118 engages the water containment housing 1504 and the catalyst dispersal housing 1502. Water then flows into the reaction chamber 106. The water creates an aqueous environment for the reaction to take place . The gas generated as a result of the reaction can then be released from the cartridge 1301 through the spiked plunger 118 to the gas transmission channel 202 of the handle 122.
  • a desirable feature of the system 1500 is the construction of the water containment housing 1504 and the catalyst dispersal housing 1502.
  • the reference numerals 1504 and 1502 generally designate the water containment housing and the catalyst dispersal housing, respectively .
  • water containment housing 1504 and catalyst dispersal housing 1502 assembly can be made as one piece, and can be made of any material .
  • the water containment housing and catalyst dispersal housing assembly can be made of plastic or thermoplastic, including polypropylene, polyethylene, polycarbonate, HDPE, ABS, acetal, polysulfone, or poly vinyl chloride (PVC) .
  • the water containment housing 1504 and the catalyst dispersal housing are designed such that it can be a self- contained unit .
  • the water containment housing 1504 has an upper aperture 1602 covered by an upper sealing membrane 1604 and has a lower aperture 1606 covered by a lower sealing membrane 1608.
  • a spiked plunger can be inserted through the seals 1604 and 1608 and the apertures 1602 and 1606 upon activation .
  • the catalyst dispersal housing 1502 also has an aperture 1612 covered by a catalyst housing seal 1610 , which allows the spiked plunger 118 to finally exit the catalyst dispersal housing 1502 during the activation process .
  • the water Prior to activation, the water is sealed into the water containment housing 1504 by upper seal 1604 and lower seal 1608.
  • each of the seals 1604 , 1608, and 1610 can be made of air-impermeable and water-impermeable materials , including, without limitation materials such as polytetrafluoroethylene, Mylar®, or Nylon® (both available from DuPont) .
  • the catalyst dispersal housing 1502 can have an angled or beveled surface 1614 , which facilitates faster and more efficient dispersal of the catalyst and/or water .
  • the water containment housing 1504 can also have contain an angled or beveled surface in order to facilitate faster and more efficient dispersal of the water upon activation .
  • the angled or beveled surface 1614 can facilitate better flushing of the catalyst, and/or facilitate faster and more efficient dispersal of the catalyst .
  • the self-contained housings can also include an in-place spike .
  • the reference numeral 1700 generally designates an alternative design of the self-contained housings .
  • a plunger 1702 with an upper seal 1704 , a lower seal 1706, and catalyst housing seal 1708 is employed.
  • the seals 1704 , 1706, and 1708 are attached to the plunger 1702 such that the seals 1704 , 1706, and 708 do not break away from or separate from the plunger 1702 during normal use .
  • the seals 1704 , 1706, and 1708 are attached to the water containment housing 1504 and catalyst dispersal housing 1502 such that the seals 1704 , 1706, and 1708 are breakable, detachable, or removable upon activation .
  • FIGURE 17A depicts the self-contained housings 1700 in a primed position .
  • the downward force transferred by the pressure source rips, tears, dislodges or otherwise detaches the seals 1704 , 1706, and 1708 , causing the contents to flow into the reaction chamber 106.
  • Stoppers 1710 allow the plunger 1702 to travel only a specified distance .
  • an alternative activation method can involve a chemical release cartridge bag configuration .
  • the reference numeral 1800 generally designates a pouch that employs a method for storing the gas/oxygen releasing agent and the catalyst .
  • planar sealed pouch 1800 formed of air- and water-impermeable sheet material 1802 which is resistant to the basic chemicals commonly used.
  • the sheet material 1802 supports the gas/oxygen releasing agent 1804 and has a web seam 1806 whose apex points upwardly towards the gas/oxygen releasing agent 1804.
  • the sheet material 1802 has a base seam 1808 parallel to and below the web seam 1806. The base seam 1808 then seals the pouch 1800.
  • the region between the web seam 1806 and the base seam 1810 forms a compartment
  • the entire contents of the pouch 1800 are designed to be released in a rapid fashion into water contained in an outer container in which the pouch 1800 is contained, such as container 106. Therefore, it is thought that the web material 1810 is to be a non-permeable laminar sheet so that none of the chemical material escapes into the volume below the web material . Additionally, the web seam 1806 is formed with a pressure sensitive seal which is broken when pressure is applied.
  • the pouch 1800 is constructed using a continuous sheet of water- and air-impermeable sheet material 1802 folded such that the fold, situated in the middle of the sheet, fits over and advantageously accommodates the nozzle element 1812.
  • the water- and air-impermeable sheet material 1802 is welded together at side seams 1816 and bottom seam 1808 , and the sheet material 1802 can be a multi-layer laminate .
  • the sheet material 1802 can be a multi-layer laminate .
  • side seams 1816 can also be frangible during use, like seam 1808 , but need not be .
  • the reference numeral 1900 generally designates a bubbler .
  • the bubbler 1900 comprises a liquid holding tank 1902 , an intake tube 1904 , an exhaust tube 1906, and a liquid 1908.
  • the gas is bubbled through the liquid.
  • gas input pressure into the bubbler 1900 is higher than atmospheric pressure, the gas can be forced through the intake tube 1904.
  • Part of the intake tube 1904 is submerged within the fluid 1908 , the exhaust gas bubbles through the liquid 1908.
  • the effect of traveling through the liquid 1908 is that the gas will transfer heat to the liquid 1908 (cooling) or receive heat from the liquid 1908 (warming) .
  • the reference numeral 2000 generally designates a radiator .
  • the radiator comprises fins 2004 and a radiator tube 2002.
  • a heat sink is employed to transfer heat .
  • the gas is input into the radiator tube 2002 to snake through the radiator 2000.
  • heat is transferred to the fins 2004.
  • the fins 2004 then transfer heat to a larger heat sink .
  • the larger heat sink can be a variety of heat sinks which includes, but is not limited to, the atmosphere .
  • One of the features of the above referenced devices is the ability to utilize multiple reactions chambers . Having multiple reaction chambers creates the ability to increase the performance of the gas dispenser, without the associated increase in pressure and temperature if only one reaction chamber is used. For example, a reaction that produces 90 liters of oxygen in 15 minutes can experience an exponential increase in pressure, especially after a certain internal (to the reaction) temperature is reached. By splitting this same reaction into two reactions , completely isolated from each other in separate chambers (say, of each producing 45 liters over 15 minutes ) , a stable delivery of gas is produced without the exponential increase in pressure and/or temperature that can result from the same 90 liter reaction over 15 minutes contained in one chamber with one reaction .
  • any multiple of reaction chambers can be combined to create any desired output of volume, flow rate and/or delivery time .
  • 3 reaction chambers each producing 30 liters of oxygen can be combined to produce the same 90 liter reaction, but with lowered pressure inside each reaction chamber and reduced temperature increase of the generated gas , relative to using the same quantity of reactants and catalyst in only one or two chambers , for example .
  • Variations in both flow rate and yield can also be varied or dictated by the compositions of the contents in the reaction chambers 106. For example, by varying the amount of a limiting reactant in each chamber and/or by varying the amount and/or composition of the catalyst contained in each cartridge, different flow rates and gas yields can be achieved. For example, by varying the amount of the sodium percarbonate in an oxygen generation reaction in each of the chambers, a yield of 90 liters with a flow rate of 6 liters per minute for 15 minutes or a yield of 30 liters and a flow rate of 3 liters per minute for 10 minutes can be achieved.
  • the flow rates and yields can be varied depending on the desired usage and can be for different situations , such as emergency oxygen for aircraft or mines . While there are many- possible or acceptable flow rate profiles applicable to the aviation industry, one example may be to have a reaction that produces approximately 4 liters per minute for 4 minutes and then drops to 1 liter per minute for 8 minutes . Using 2 reaction chambers can achieve this general performance profile .
  • the reference numeral 2100 generally designates a cartridge 2100.
  • the cartridge 2100 comprises a lid 1126 and a reaction chamber 106.
  • the reaction chamber 106 and the lid 112 contain a filter 110 , a foam breaker 500 , a screen 108 , water 2104 , a gas producing agent 2102 , and a catalyst 2106.
  • the filter 110 and the foam breaker 500 are layered on top of the screen 108 , and the chemicals 2106, 2102 , and 2104 are contained within the lower portion of the reaction chamber 106.
  • the water 2104 rests at the bottom of the reaction chamber 106, being held in place by frangible seal 2108.
  • the catalyst 2106 and the gas producing agent 2102 are each contained on a side of the reaction chamber, held in place by a frangible seal 108.
  • frangible seals 2108 Upon activation, the frangible seals 2108 are broken .
  • the chemicals 2102 , 2104 , and 2106 then mix to create a gas generating reaction .
  • the gas produced traverses the screen 108 , the foam breaker 500, and the filter 110 to exit the cartridge 2100.
  • the reference numeral 2200 generally designates a cartridge .
  • the cartridge 2200 comprises a lid 112 and a reaction chamber 106.
  • reaction chamber 106 and the lid 112 contain a filter 110 , a foam breaker 500 , a screen 108 , water
  • the filter 110 and the foam breaker 500 are layered on top the screen 108 , and the chemicals 2206, 2202 , and 2204 are contained within the lower portion of the reaction chamber
  • the water 2204 , the catalyst 2206, and the gas producing agent 2202 each rest at the bottom of the reaction chamber 106.
  • Each of the chemicals 2202 , 2204 , and 2206 are separated from one another and held in place by a frangible seals 2208.
  • frangible seals 2208 Upon activation, the frangible seals 2208 are broken .
  • the chemicals 2202 , 2204 , and 2206 then mix to create a gas generating reaction .
  • the gas produced traverses the screen 108 , the foam breaker 500 , and the filter 110 to exit the cartridge 2200.
  • the reference numeral 2300 generally designates a self-contained activation system.
  • the system 2300 comprises a container 2302 and an activation handle 2304.
  • the sealed unit 2302 is particularly adapted for containing one or more pouches 26000 or 2600' , depicted in FIGURES 26A and 26B .
  • sealed unit 2302 can also contain a multitude of devices, such as the configurations of FIGURES 1-3 , 12-18 , and 21-22 , capable of releasing a gas .
  • the activation handle 2304 is displaced downwardly into an activation position to apply mechanical pressure to any of the multitude of devices to break any seals and initiate the chemical reaction (s ) .
  • the activation position of the handle 2304 can be reached by being displaced into either an upward or a downward position relative to the container 2302.
  • the reference numeral 2400 generally designates a diagram contrasting two gas producing reactions .
  • the first reaction (REACTION 1) is set up to produce a short reaction that starts high but is only maintained for a short period.
  • the second reaction (REACTION 2 ) is set up to start slow but to be maintained for a longer period.
  • REACTION 1 is set up to produce a short reaction that starts high but is only maintained for a short period.
  • REACTION 2 is set up to start slow but to be maintained for a longer period.
  • the reference numeral 2450 generally the combined output of REACTION 1 and REACTION 2.
  • the combined output 2450 shows the sum of the combined reactions 1 and 2 , and illustrates how the desired profile is achieved using 2 reaction chambers instead of one .
  • one possible flow rate profile is to simply maintain a reaction at an average of 2 liters per minute for 60 minutes .
  • the reference numeral 2500 generally designates a diagram showing two contrasted reactions .
  • the diagram 2500 shows two identical reactions , REACTION 3 and REACTION 4 , each with a reaction onset of 1.75 liters per minute .
  • Each of REACTION 3 and REACTION 4 can take place in respective reaction chambers .
  • the reference numeral 2550 shows a diagram depicting the combined outputs of REACTIONS 3 and 4.
  • REACTION 3 in the first reaction chamber nor REACTION 3 in the second reaction chamber may produce the desired flow rate profile .
  • the output of the combined reactions shown in the diagram 2550 shows a 20-minute production with flow rates in a relatively narrow range , as the trend-line indicates .
  • FIGURE 26A depicts an embodiment of a planar sealed pouch that employs a method for storing the gas/oxygen releasing agent, the catalyst and the water all in one pouch .
  • Planar sealed pouch 2600 is formed of a pair of sheets 2602 of air- and water-impermeable sheet material which is resistant to the basic chemicals commonly used (only the top sheet 2602 being visible in FIGURE 26A) .
  • the sheet material 2602 supports the catalyst in compartment 2604 , the gas/oxygen releasing agent in compartment 2606 and the water in compartment 2608.
  • the sheet material must be resistant to the chemicals of the catalyst, gas/oxygen releasing agent and the water .
  • the sheet material is a laminate material that can be any combination of aluminum, polypropylene, polyethylene terephthalate, polyethylene, high density polyethylene, and any number of materials .
  • the laminate material can also include a layer of insulating material .
  • the pouch 2600 has a peripheral border 2611 which is sealed by convenient means , such as adhesive, ultrasonic welding, or heat sealing and is able to retain the pressures encountered without bursting .
  • Each of the compartments 2604 , 2606 and 2608 also have internal sealed borders 2612 to retain their respective chemicals so that they stay initially separated. Unlike peripheral border 2611 , sealed borders 2612 are sealed with a pressure-frangible adhesive to create "peel areas" between the top and bottom sheet material 2610. In this embodiment, the compartments 2604 , 2606 and 2608 do not take up all of the area of the sheet material 2602 , thus also defining an initially empty compartment 2607. For reasons to be explained, empty compartment 2607 may also be initially filled with air at ambient pressure .
  • the pouch 2600 accommodates nozzle element 2614 , which can be made of suitable plastic such as polypropylene, to permit the release of the oxygen or other gas produced.
  • the gas produced may include entrained droplets of water or particulates from the catalyst and gas/oxygen producing agent
  • the pouch also includes self-contained permeable membrane/screen 2616 and a foam breaker 2618 that is retained by the membrane/screen 2616.
  • the gas/oxygen When the gas/oxygen is produced, it will pass through the membrane/screen 2616 and the foam breaker 2618 , where is effectively filtered, removing any entrained water droplets , bubbles or particulates before being exhausted from nozzle 2614 and directed through an appropriate conduit (not shown) to the user .
  • FIGURE 26B depicts another embodiment of a pouch having compartments for initially separating the catalyst, oxygen producing agent and water .
  • pouch 2600 ' is similar to pouch 2600, the compartments 2604 ' , 2606' and 2608 ' containing, respectively, the catalyst, oxygen producing agent and water, and the initially empty compartment 2607 ' containing air .
  • each of the compartments have different shapes and locations .
  • each of the compartments is separated by pressure- frangible sealed borders 2612' , constructed in the same manner .
  • the pouch 2600' accommodates nozzle element 2614 , which can also be made of suitable plastic such as polypropylene, to permit the release of the oxygen or other gas produced. Because the gas produced may include entrained droplets of water or particulates from the catalyst and gas/oxygen producing agent, the pouch also includes self-contained permeable membrane/screen 2616 and a foam breaker 2618 that is retained by the membrane/screen 2616, to filter the gas generated. Otherwise, the construction and operation of the pouch 2600 ' is the same as pouch 2600 and need not be further described.
  • each of the pouches 2600 and/or 2600' may be connected to a common conduit and used together .
  • Each of the pouches 2600 and/or 2600' can contain different compositions or proportions of the water, catalyst and gas/oxygen producing agent, as previously described, in order to create various flow profiles such as are depicted in FIGURES 24B and 25B .
  • the present invention can take many forms and embodiments . Accordingly, several variations may be made in the foregoing without departing from the spirit or the scope of the invention .
  • the capabilities outlined herein allow for the possibility of a variety of implementations .

Abstract

An apparatus is provided to generate a gas by mixing chemicals with water. Typically, the production of gas, particularly oxygen, by combining water with powders and other dry chemicals has not been widely employed. There have existed a number of preexisting barriers such as undesirable flow rates and yields. However, by utilizing multiple reaction chambers the flow rates and yields can be more precisely tailored for a variety of situations that may call for particular flow rates and yields. Additionally, the use of the dry chemicals would allow for a long self-life allowing the apparatus to be particularly useful in emergency situations .

Description

METHOD AND APPARATUS FOR CONTROLLED PRODUCTION OF A GAS
CROSS-REFERENCED APPLICATIONS
This application is a continuation of U . S . Patent Application No . 11/045 , 805 entitled "METHOD AND APPARATUS FOR CONTROLLED PRODUCTION OF A GAS" (Docket No . ROSS 3050000) filed January 28 , 2005 , which relates to and claims priority from co-pending U . S . Patent Application No . 10/718 , 131 entitled "METHOD AND APPARATUS FOR GENERATING OXYGEN" (Docket No . ROSS 2864000 ) , filed November 20 , 2003 , and co-pending U . S . Patent Application No . 10/856, 591 , entitled "APPARATUS AND DELIVERY OF MEDICALLY PURE OXYGEN" (Docket No . ROSS 2934000 ) , filed May 28 , 2004 , the contents of each of which are hereby incorporated by reference for all purposes . This application further claims priority to the following U . S . Patent Applications filed June 22 , 2005 : Serial no . 11/045 , 805; Serial no . 11/158 , 993 ; Serial no . 11/159 , 016; Serial no . 11/158 , 377 ; Serial no . 11/158 , 362 ; Serial no . 11/158 , 618 ; Serial no . 11/158 , 989; Serial no . 11/158 , 696 ; Serial no . 11/158 , 648 ; Serial no . 11/159, 079; Serial no . 11/158 , 763 ; Serial no . 11/158 , 865 ; Serial no . 11/158 , 958 ; and Serial no . 11/158 , 867 ; all entitled Method and Apparatus for Controlled Production of a Gas, and filed June 22 , 2005. FIELD OF THE INVENTION
The present invention relates generally to a gas delivery system and, more particularly, to a system that provides an activation method and apparatus as well as a method and apparatus for improving and controlling the gas yield, flow rates and gas production duration .
DESCRIPTION OF THE RELATED ART Oxygen and other gas generators using chemical reactions have been known for some time . However, none of the conventional devices relating to chemical gas generators have resulted in variable control of the gas generation, while providing higher outputs of gas volume and flow rate, and simultaneously maintaining or improving control of pressure, temperature, and so forth . Gas volume and flow rate are particularly important in emergency oxygen markets . For example, institutions such as the Food & Drug Administration, the American Heart Association and the American Medical Association have required or recommended, as the case may be, a delivery of 90 liters over a 15 minute period, or alternatively an average or minimum flow rate of 6 liters per minute over a 15 minute period. Some attempts to control the flow rate of oxygen have included a catalyst with a gum Arabic solution . The resultant reaction reaches a flow rate of 2 liters per minute after 30 minutes . Other devices create a tablet out of an oxygen generating agent, which similarly produces a low reaction onset (the flow rate at which the reaction commences) and low flow rates over the reaction period. These prior attempted solutions may not be suitable for emergency applications, usually medical in nature or situations where life-threatening factors are present where high flow rates of at least 2 liters per minute to 6 liters per minute or higher are required almost instantly . In addition, conventional generators have had limited adoption in commerce and in industry . There are several possible factors contributing to this lack of adoption . These factors may include one or a ' combination of unfavorable characteristics relating to reusability, safety, ease of use/operation, speed of use, heat management, cost, weight, aesthetic design, environmental impact, manufacturability, portability, medical efficacy, effectiveness , flow rate , gas yield, reaction stability, and purity of the gas . Some or all of these characteristics are not addressed, or are inadequately addressed, by the designs in the prior art .
Designs in the prior art have not adequately addressed flow rate and total gas yield. Depending on the situation, such as for oxygen production in emergency situations , high flow rates may be required. For example, the United States Food and Drug Administration (FDA) has long required a flow rate performance for oxygen generators of at least 6 liters per minute over 15 minutes in order to obtain market clearance for over the counter purchase, resulting in at least a total oxygen yield requirement of 90 liters . High pressures generated inside the reaction chamber generally accompany higher flow rate outputs or requirements . High pressure, such as can be created by confined gases can be particularly dangerous .
Therefore, a need exists for a method and/or apparatus for activating gas production and controlling gas production from a chemical reaction that addresses at least some of the problems associated with conventional methods and apparatus for producing gases, and more specifically medically pure oxygen .
SUMMARY OF THE INVENTION
The present invention provides an apparatus for generating gas from a plurality of separated chemicals . In one embodiment, a plurality of reaction chambers operate cooperatively when the separated chemicals are combined to generate the gas . The flow rate and the total yield can then be varied based on the proportion of separated chemicals in each reaction chamber . BRIEF DESCRIPTION OF THE DRAWINGS
For a more complete understanding of the present invention and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings , in which :
FIGURE 1 is a diagram, partly in section, depicting an exploded side view of gas activation, production, dispensing and control vessel in accordance with an embodiment of the present invention; FIGURE 2 is a diagram, partly in section, depicting a side view of a primed gas activation, production, dispensing and control vessel;
FIGURE 3 is a schematic sectional view of the gas activation, production, dispensing and control vessel, in use, with the spiked plungers inserted;
FIGURE 4A is a plan view of an example of a screen;
FIGURE 4B is a sectional view of the screen depicted in FIGURE 4A;
FIGURE 5A depicts a plan view of a foam breaker, taken along the lines 5B, 5C;
FIGURE 5B depicts a cross sectional view of the foam breaker of FIGURE 5A;
FIGURE 5C depicts a cross sectional view of the foam breaker of FIGURES 5A and 5B when compressed; FIGURE 6A depicts a plan cross sectional view of a handle useful in connection with the present invention;
FIGURE 6B depicts a side cross sectional view of a handle useful in connection with the present invention, taken along the line 6B;
FIGURE 7 of the drawings is a partially cross sectioned view of a female connector useful in connection with the present invention;
FIGURE 8 depicts a cross sectional view of a male connector adapted to fit with the female connector depicted in FIGURE 7 ;
FIGURE 9 depicts a side view, partly in cross section, of one embodiment of the connectable spiked plunger, as connected to the female connector depicted in FIGURE 7 ; FIGURE 1OA depicts a side cross sectional view of a spiked plunger;
FIGURE 1OB depicts a side cross sectional view of a spiked plunger in its female connector housing, with the spiked plunger disconnected; FIGURE 1OC depicts a side cross sectional view of a spiked plunger in its female connector housing, with the spiked plunger connected to it;
FIGURE 11 depicts a side cross sectional view of a spring loaded spiked plunger and release mechanism; FIGURE 12 depicts a side cross sectional view of a cartridge filled with initially separated chemicals and having a pressure relief system;
FIGURE 13A depicts a side cross sectional view of an activation system for one reaction chamber of the gas activation, production, dispensing and control vessel depicted in FIGURES 1 and 2 , having a spike, with the spike withdrawn for clarity;
FIGURE 13B depicts a side cross sectional view of an activation system for one reaction chamber of the gas activation, production, dispensing and control vessel depicted in FIGURES 1 and 2 , having a spike inserted into the container holding the water to rupture it and allow mixing the the other chemicals to create a flow of gas , with the flow of gas produced indicated by arrows ;
FIGURE 14 depicts a side cross sectional view of an activation system with dual reaction chambers having spikes as depicted in FIGURES 1OA, 1OB and 1OC, and having a hanging catalyst bag, with the spike withdrawn and primed for activation;
FIGURE 15 depicts a side cross sectional view of an another embodiment of an activation system with dual reaction chambers having spikes as depicted in FIGURE 9, the male connectors depicted in FIGURE 8 , and compartments for retaining the catalyst and water as depicted in FIGURE lβAwith the spike withdrawn and primed for activation;
FIGURE 16A depicts a cross-sectional side view of the water containment housing and an adj acent catalyst dispersal housing depicted in FIGURE 15 ;
FIGURE 16B depicts cross-sectional side view of a modified version of the catalyst dispersal housing depicted in FIGURE 16A;
FIGURE 17A depicts a side cross sectional view of another embodiment of an activation system for one reaction chamber, having a fixed activation member, in the primed position;
FIGURE 17B depicts a side cross sectional view of the embodiment of an activation system for one reaction chamber depicted in FIGURE 17A, after activation, the arrows indicating flow of the water and catalyst;
FIGURE 18A depicts a front view, partly in phantom, of a powder release pouch cartridge assembly;
FIGURE 18B is a sectional side view of the powder release pouch cartridge assembly depicted in FIGURE 18A, taken along line 18A-A;
FIGURE 19 is a partially diagrammatic side view of a bubbler;
FIGURE 20 is a diagram depicting a heat exchanger/ radiator; FIGURE 21 depicts a side cross sectional view of an embodiment of a cartridge for one reaction chamber, showing different locations for the catalyst and gas/oxygen producing agent; FIGURE 22 depicts a side cross sectional view of another embodiment of a cartridge for one reaction chamber;
FIGURE 23A depicts a cross-sectional front view of a container for containing pouch-type reaction chambers as depicted in FIGURES 26A and 2 βB, utilizing a mechanical lever to initiate the gas-generating reaction;
FIGURE 23B depicts a cross-sectional side view of the container depicted in FIGURE 23A, taken along the line 23A- 23A.
FIGURE 24A is a diagram contrasting the flow rate of two gas producing reactions ;
FIGURE 24B is a diagram showing the combined flow rate of two gas producing reactions of FIGURE 24A;
FIGURE 25A is a diagram contrasting the flow rate of two gas producing reactions initiated at different times ; and FIGURE 25B is a diagram showing the combined flow rate of two gas producing reactions of FIGURE 25A.
FIGURE 26A depicts a pouch-type, self-contained, reaction chamber including separate compartments for the catalyst, gas/oxygen producing agent and water; and FIGURE 26B depicts another embodiment of a pouch-type, self-contained, reaction chamber including differently shaped, separate compartments for the catalyst, gas/oxygen producing agent and water .
DETAILED DESCRIPTION
In the following discussion, numerous specific details are set forth to provide a thorough understanding of the present invention . However, those skilled in the art will appreciate that the present invention may be practiced without such specific details . In other instances , well-known elements have been illustrated in schematic or block diagram form in order not' to obscure the present invention in unnecessary detail . Additionally, for the most part, details concerning network communications , electro-magnetic signaling techniques, and the like, have been omitted inasmuch as such details are not considered necessary to obtain a complete understanding of the present invention, and are considered to be within the understanding of persons of ordinary skill in the relevant art .
Referring to FIGURE 1 of the drawings, the reference numeral 100 generally designates an exploded view of a gas activation, production, dispensing and control assembly using a manual reaction activation method in accordance with an embodiment of the present invention . The assembly 100 comprises support housing 102 , removable reaction chambers 106, screens 108 , filters 110 , lids 112 , and a handle 122.
The main body of the assembly 100 is the support housing 102. There are a number of configurations that can be employed, but a convenient design is a vessel having vertically extending side walls and a bottom surface connecting the side walls . The support housing 102 also has an opening in the top where other members can be inserted. The support housing 102 can also be a smooth, continuous surface or it can be several j oined, flat surfaces . For example, the support housing has a compartment for each reaction chamber and can have curved surfaces such that it curves around the reaction chambers 106 in approximately the shape of a figure eight, as viewed from above . In such a configuration the gas activation, production, dispensing and control assembly 100 can be- conveniently worn on the hip, by clip-on or otherwise of say, a miner, construction worker or emergency service personnel . Additionally, the support housing 102 can employ two guides 104 that protrude outwardly from the side walls of the support housing 102 to interface with and/or slidably receive the guided members 114 of the handle 122. In the manual activation device shown in FIGURE 1, the two guide members 104 allow the user to activate the chemical reaction producing the oxygen or other gas, by pushing the handle 122 in a direction toward the housing 102. The two guide members 104 allow for this to be a smooth and easy process . Upon completion of the chemical reaction, the two guide members 104 similarly allow for a smooth and easy disengagement of the handle 122 in a direction away from the housing 102 utilizing a quick release mechanism 720 (depicted in FIGURE 7 , but not shown in FIGURE 1) . The support housing 102 can also act as an additional insulating material to act as a heat shield for any excess heat being generated in the reaction chambers .
Each of the reaction chambers 106 can be placed within the support housing 102 such that access can be gained to each reaction chamber 106. The reaction chambers 106 can be made of a durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat . For example, the reaction chambers 106 can be made of polycarbonate or polytetrafluoroethylene . The lids 112 can be attached to the reaction chambers 106. For example, reaction chambers 106 can have internal female threads and the lids 112 can have corresponding external male threads . Alternatively, the lids 112 can be attached to the reaction chambers 106 by clip in, lock in or click in designs . Screens 108 and filters 110 can be seated on a flange 107 inside reaction chambers 106, but such is not essential to the design . For example, screens 108 and filters 110 can also simply be maintained in position by mechanical pressure, or glued, as depicted in FIGURE 3. The reaction chambers 106 are typically cylindrically shaped, but can be any other shape . The reaction chambers 106, however, can be coupled to the lids 112 prior to insertion into the support housing 102.
Referring to FIGURE 2 of the drawings , the reference numeral 200 generally designates a primed gas production control vessel .
When the vessel 200 is in the primed position, gas production can be initiated by engaging the handle 122. The guide members 104 (of support housing 102 ) can contain and guide the arms 114 of the handle 122. By allowing the arms 114 to freely slide within the guides 104 a user would simply place pressure on the handle 122 in a direction toward the support housing 102.
From the primed position, it is evident that alignment can be an advantageous feature . Each of the spiked plungers 118 can be aligned with an opening 116 of a lid 112. Therefore, when engaged, each of the spiked plungers 118 can be slidably inserted into each of the reaction chambers 106 to initiate the reaction and carry out the resultant gas . Referring to FIGURE 3 of the drawings, the reference numeral 300 generally designates a cut-away of a gas activation, production, dispensing and control vessel in use .
When fully assembled, control of the gas production is achieved through the use of multiple reaction chambers 106. Two reaction chambers are depicted, but there can be more reaction chambers depending on the desired flow rate and yield. One reaction chamber can also be used. Chemical reactions occur in the lower portions 210 of the reaction chambers 106. By varying the proportion, amounts and/or composition of the reactants within the vessel, two different reaction rates (and yields ) can be maintained independently in each of the reaction chambers 106. Hence, each reaction chamber 106 can contribute a fractional gas output of the total gas output of the vessel, allowing for a variety of gas yields and flow rates . Moreover, the reactants in each reaction chamber 106 can vary, as well , to achieve a desired gas yield and gas flow rate .
Each of the reaction chambers 106 rests within the support housing 102. Each of two guided members 114 of the handle 122 are inserted through one of two guide members 104. Each of the reaction chambers 106 are then coupled to the handle 122 by mechanical couplers 206. The mechanical couplers 206 can be a variety of mechanical coupler types , such as threaded couplers or couplers employing snapping edges . Thus, the combination of use of the guide members 104 and the couplers 206 allow for a good mechanical connection during use .
Also while in use, spiked plungers 118 can be employed to allow gas transmission from the reaction chambers 106 to the gas transmission channel 202 of the handle 122. The spiked plungers 118 can each be coupled to the handle 122 within the gas transmission channel 202 of the handle 122 and can each be inserted into a reaction chamber 106. Each spiked plunger 118 can contact both the filter 110 and the screen 108. The screens 108 can be located at positions adj acent to the lower portions 210, which allow gas to pass and provide mechanical support for the filters 110. Because of the mechanical constraints of the mechanical couplers 206 and the guide members 104 , the spiked plungers 118 can each maintain mechanical contact between the filter 110 and the screen 108. Gas produced within the lower portions of the reaction chamber 106 can then pass around the tip of the plunger 118 , through the screens 108 , the filters 110 , and into transmission openings 224 in spiked plungers 118. Once closed, each of the reaction chambers 106 and the lids 112 , along with the reaction chambers' contents such as the gas/oxygen generating material, catalyst, water, screen and filter forms a self-contained cartridge 109 that can be disposable . Each self-contained cartridge 109 is therefore easily replaceable if a user requires additional oxygen or gas (as the case may be) upon completion of a use . For example, the gas activation, production, dispensing and control assembly 300 can be designed to produce 15 minutes of oxygen for emergency or short-duration purposes . If the user requires additional oxygen at the end of that 15-minute period, he/she can simply replace one or both the cartridges 109 to have an additional 15 minutes of oxygen availability . Each used cartridge 109 is simply discarded or recycled ( if applicable) after use, allowing for simplicity and ease of use . Self-contained cartridges can be attached to each other to form one removable, self-contained cartridge . The lids 112 can each have a cap to close the respective openings 116, after the completion of the reaction . Closing the openings 116 facilitates the prevention of any leakage of the reaction residue and thereby facilitates convenient disposal of the cartridges .
In reference to the self-contained cartridges 109 there are various configurations possible in regards to the relative locations of the gas/oxygen releasing agent, the catalyst and the water, comprising the ingredients used to make the reaction in the current invention work . The gas/oxygen releasing agent, the catalyst and the water remain separated until a reaction is reguired. The gas/oxygen releasing agent and the catalyst can remain inert and can have an indefinite shelf life if they are kept dry and moisture free . One configuration example is to have the gas/oxygen releasing agent located at the base of the cartridge (in reaction chambers 106) , the catalyst located above the gas/oxygen releasing agent, and the water located above the catalyst, such as for example in the plenums 111 of the lids 112. Upon activation, the water is released and can flow in toward the lower portion of the reaction chamber 106, where the gas/oxygen producing agent (not shown) is disposed, carrying the catalyst along with it through a flushing action, to mix with the gas/oxygen releasing agent at the base of the cartridge . We refer to this cartridge configuration as a water releasing cartridge . In this invention we will discuss different designs for water releasing cartridges . A different cartridge configuration, however, is one where the gas/oxygen releasing agent is located above the water and the catalyst . In this cartridge configuration, the gas/oxygen releasing agent and/or the catalyst is/are released to mix with the water in order to activate the reaction . We refer to this cartridge configuration as a chemical releasing cartridge . In either cartridge configuration, once a chemical reaction is initiated, the resultant gas can carry small airborne droplets of the gas production solution, or can carry small particles from the reactants . These airborne particles can be undesirable to the equipment attached to the gas generator or to the lungs of an individual . Therefore, there is a need to filter these undesirable particles . There are several methods that can be used to filter such undesirable particles . Methods that can be used include selecting appropriate materials to capture the undesirable particles , and to select an appropriate configuration by locating the selected materials in an appropriate location, relative to other components in the invention . Therefore, material selection and placement can be important factors . However, the filter material employed depends on the gas produced, the composition of the solution, and the usage of the gas . In reference to FIGURE 1, the filters 110 can be sponge-like materials to capture the undesirable particles , while allowing the gas to flow through at desirable flow rates . Other effective filter materials can be polytetrafluoroethylene or can be Nylon®, which is available from DuPont . In addition to absorbing or filtering out undesirable particles , filters can also be useful in extracting some heat out of the gas being produced, either in their untreated form, or by being treated with various substances . FIGURE 4 depicts an example of a screen that can be used. The screens 108 can serve to support the filters 110 , while allowing the water to rapidly and evenly disperse into the reaction chambers 106, in order to activate the chemical reaction that produces the oxygen or gas , as the case may be . In order to allow fluid transfer through the screen 108 , several opening can be provided. The edges of the screen 108 would rest against the inner walls of a reaction chamber 106 or on a surface within the reaction chamber 106. Fluids would then be allowed to pass through the openings 404 , 402 , and 406. Additionally, when engaged, the spiked plungers 118 would at least partially reside within the opening 402.
Referring to FIGURES 5A, 5B, and 5C of the drawings the reference numeral 500 generally designates a foam breaker . FIGURE 5A depicts a cross sectional view of the foam breaker 500 , where the opening 502 would allow the spiked plunger 118 to reside when engaged. FIGURE 5B depicts a side view of the foam breaker 500, and FIGURE 5C depicts a side view of the foam breaker 500 when compressed. Chemical reactions can produce foam, and a foam breaker 500 can counteract this effect . For example, a steel mesh with an appropriate mesh size can be used. Another material that can be used as a foam breaker is a commonly used pot scourer or scrub sponge material, or durable foam material . The foam breaker can be optionally placed within the same fluid transmission path in which both the screens 108 and the filters 110 reside . The screens 108 can also act as foam breakers, and the filters 110 can also act as foam breakers . The screens 108 and filters 110 , acting together can also act as foam breakers .
Another method is to apply a defoaming agent or surfactant to the walls and/or the screen and/or the lid and filter . Defoaming agents that can be used include silicone based, polymer based or mineral oil based agents , as well as other surfactants . Regardless of where the foam breaker or defoaming agent is placed in the device, the filter should follow the foam breaker or defoaming agent (as considered in the direction of the gas flow) .
Referring to FIGURE 6 of the drawings, the reference numeral 122 generally designates the handle . The handle 122 effectively operates as a manifold. Especially in situations where multiple reaction chambers are used, it is desirable to have a manifold or similar method of combining the gas flow from each individual reaction chamber 106. The manifold gas transmission channel 202 performs the function of combining gases , and the gas flows from each reaction chamber 106 into the ports 602. The gases are then combined in the manifold gas transmission channel 202.
Upon activation, however, the spiked plungers 118 should provide a continuous gas transmission to the manifold gas transmission channel 202. The mechanical coupler 206 can secure lids 112 in such a manner as to seal off the opening 116 of the lids 112 and maintain the connection between the spiked plunger 118 and the handle 122. Specifically, the mechanical coupler 206 can be a simple coupler 206 to which the nozzle 116 of the self-contained cartridge 109 is inserted, as depicted in FIGURE 3
In another embodiment, the couple 206 or can comprise a cooperatively designed male connector adapted to fit over the nozzle 116, as depicted in FIGURE 8 , and a female connector adapted to fit into the male connection, as depicted in FIGURES 7 , 9, 1OB and 1OC .
With initial reference to FIGURE 7 , e the reference numeral 700 refers to the female connector . The female connector 700 is typically attached to the spiked plunger 118 , where the spiked plunger 118 is inserted into the opening 704 of the female connector 700. Additionally, as depicted in FIGURES 14 and 15 , the female connector couples to the ports 602 of the handle 122. When engaged, the female connector 700 snaps into place . The female connector 700 comprises an arm 702 that possesses an engagement edge that allows for coupling to a male connector . Additionally, the female connector 700 can be made of various materials , including, without limitation polypropylene, polyethylene , polycarbonate, HDPE, ABS, Acetal , or Polysulfone .
Referring to FIGURE 8 of the drawings , the reference numeral depicts a male connector . FIGURE 8 is a side view of the male connector 800 , with the O-ring seal shown in cross- section for clarity . The male connector 800 is a cylindrical tube that is able to engage the female connector 700. The male connector can comprise an O-ring 802, an upper edge 804 , and a lower edge 806. The O-ring 802 is responsible for providing a gas seal between the male connector 800 to the female connector 700 the male connector 800 is inserted into the female connector during use . The 0-ring can be made of various materials, including, without limitation, silicone or platinum-cured silicone . Platinum-cured silicone can allow for repeated usage of more than one thousand times . The lower edge 806 can engage the edge of the arm 702 by a clicking action . To more conveniently allow for the clicking action to take place, a slanted engaging face 808 is employed. Additionally, the upper edge 804 prevents excessive play by providing a stop for the edge of the arm 702. The male connector can also be made of various materials , including, without limitation polypropylene, polyethylene, polycarbonate, HDPE, ABS , acetal, or polysulfone .
The male connector 800 can then be secured to the lid 112 by using threads . Typically, the lid 112 is coupled to the male connector through the opening 810. Therefore, female threads would be contained on the inner walls of the male connector 800 while the male threads would be contained on the lid 112.
Once the reaction is completed, the female connector 700 and the male connector 800 can be easily and quickly disengaged. The quick release mechanism 720 can be coupled to the arm 702 of the female coupler 700. By pressing the quick release mechanism 720 in the direction toward the plane created by the azimuthal axes of the spiked plungers 118 , the male connector and the female connector can be disengaged. Additionally, the quick release mechanism 720 can be configured to disengage the female connectors 700 from the male connectors 800 by simply gripping the quick release lever 128 in a direction toward the handle 122. For applications such as emergency applications it is desirable to have an efficient and easy activation method, which is simultaneously manufacturable and economical . For such emergency applications , the activation method should be such as to commence the chemical reaction instantaneously or near instantaneously with typically one easy step . For example, activation can be achieved by a single push-down action that applies pressure to the handle 122. A system can also be electronic or a sensor, such as for example a system used to detect decompression in aircraft, thereby triggering the deployment of emergency oxygen in the aircraft cabin .
In one embodiment, during activation of the chemical reaction, the spiked plungers 118 ' are each inserted into lids 112. The spiked plunger 118 and 118 ' are typically hollow cylindrically-shaped members that have a tip that is suitable for and utilized to puncture a material . Referring to FIGURE 9 of the drawings, the reference numeral 900 generally designates one embodiment of the connectable spiked plunger .
Specifically, the connectable spiked plunger 900 comprises a female connector 700 and a spiked plunger 118. The spiked plunger 118 can comprise a cylindrically-shaped shaft 906 with a spiked end 904. Within the spiked plunger 118 is a gas transmission channel 902 along the azinvuthal axis of the spiked plunger 118 that allows gas to travel through the plunger 900. Additionally, transmission openings 224 are employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118.
In particular the plunger 900 is designed to puncture a material container or containment bag to initiate a chemical reaction . For example, the spiked plunger 118 can puncture a container or bag that contains water, or the spiked plunger 118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be . The spiked plungers 118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat . For example, the spiked plungers 118 can be made of polycarbonate .
In another embodiment, an extended spiked plunger can be employed. Referring to FIGURES 1OA, 1OB, and 1OC, the reference numeral 1000 generally designates an extended spiked plunger 118 ' .
Specifically, the plunger 118 ' can comprise a female connector 700 and a spiked plunger 118 ' . However, the spiked plunger 118 ' is different in that it is extended. The spiked plunger 118 comprises a torso 1002 and an extension shaft 1004 with a sharp tip 1006. The torso 1002 can be cylindrically shaped and employ a gas transmission channel 902 along the azimuthal axis of the torso 1002 that allows gas to travel through the plunger 118 ' . Additionally, transmission openings 224 can be employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118' .
Attached at the end of the torso 1002 is the extension shaft 1004. The extension shaft 1004 can be cylindrically- shaped with one end inserted into the female receptive aperture 1008 at the end of the torso 1002. The sharp tip 1006 can then be attached to the other end of the extension shaft 1004.
In particular, the plunger 1000 is designed to puncture a material containment container or bag to initiate a chemical reaction . For example, the spiked plunger 118 can puncture a container or bag that contains water, or the spiked plunger 118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be . The spiked plungers 118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat . For example, the spiked plungers 118 can be made of polycarbonate .
In yet another embodiment, an initiator can be employed as a push-button, lever or pin . An initiation system can also be electronic or a sensor, such as for example a system used to detect decompression in aircraft, thereby triggering the deployment of emergency oxygen in the aircraft cabin . Referring to FIGURE 11 of the drawings , the reference numeral 1100 depicts a spring loaded spiked plunger 1118. The spring loaded spiked plunger 1118 then can utilize potential energy stored in a spring to extend its sharp tip 1110 into the containers of water and/or chemicals to begin the chemical reaction that produces the gas . The spring 1106 can be maintained within the spring housing 1114 and held in place by a retainer 1104. The process of initiating the chemical reaction would involve the utilization of an actuator 1102 , which is shown as a push-button actuator . The actuator 1102 causes the retainer 1106 a lever arm 1107 to pivot about pivot 1109, pulling out pin 1104 to release the spring 1106. The spring 1106 then exerts a force on the spiked plunger 1118.
The spiked plunger 1118 can comprise a cylindrically shaped shaft with a spiked end 1110. Within the spiked plunger 1118 is a gas transmission channel 902 along the azimuthal axis of the spiked plunger 1118 that allows gas to travel through the plunger 1118. Additionally, transmission openings 224 can be employed to allow the gas transmission channel 902 to be in fluid contact with gas outside of the spiked plunger 118. In particular, the plunger 1118 is designed to puncture a material containment container or bag to initiate a chemical reaction . For example, the spiked plunger 1118 can puncture a container or bag that contains water, or the spiked plunger 1118 can be used to puncture a membrane or other material, causing the release of water or chemicals , as the case may be . The spiked plungers 1118 can be made of durable thermoplastic with high tensile strength, high resistance to chemical reactions and high resistance to heat . For example, the spiked plungers 1118 can be made of polycarbonate .
There are several other types of systems that can be employed to initiate a gas generating chemical reaction . An actuator can utilize the pressure associated with a chemical release cartridge . A pressure supply can also be achieved by supplying air pressure to the activation system. Another type can be a mechanical or electro-mechanical source , such as can be provided by a mechanical or electro-mechanical pump or motor . Yet another type can be a pneumatic source , such as for example a pneumatic pump or motor, or a hydraulic source . Depending on the type of gas producing reaction, pressures in the reaction chamber 106 can be high and dangerous . Referring to FIGURE 12 of the drawings the reference numeral 1200 generally designates a cartridge with a relief system. The cartridge 1200 comprises a reaction chamber 106, a screen 108 , a containment bag 1202 , a filter 110 , and a lid 112.
When in storage or not in use, the reaction chamber 106 contains "dry" reactants . The "dry" reactants typically include an oxygen rich powder reactant, such as sodium carbonate or sodium percarbonate, as the gas/oxygen generating agent . However, the dry reactants can be liquid reactants that require an additional solvent, such as water, or other "wet" chemical to initiate a gas producing reaction . These "dry" reactants can also contain "dry" catalysts that can assist in reducing heat or increase the reaction rate, such as manganese dioxide . There are also be a number of other catalysts that can be employed for a variety of other purposes . In addition, it should be noted that the water can include an additive to depress the freezing point of the water, but need not do so . Inserted into the reaction chamber 106 is the screen 108. The screen 108 is mechanically supported in a position adj acent to the cavity containing the "dry" reactants . The screen 506 can be mechanically supported in a number of ways, such as by use of threading, snapping edges, and/or taper of the inner walls of the reaction chamber 106.
The screen 108 can provide mechanical support for the remaining components contained within the cartridge 1200. A containment bag 1202 is positioned adj acent to the screen 108 , so that, when pierced, the contents of the bag 1202 can be transmitted through the screen to the "dry" chemicals to begin the reaction . The filter 110 is also supported by the screen 108 , so that when gas is produced and transmitted through the screen 506, the gas can be filtered. A variety of filter types can be employed that can be comprised of a variety of materials including, but not limited to, polytetrafluoroethylene . The final component of the cartridge 1200 is the lid 112. The lid 512 can be coupled to the reaction chamber 106. There are a number of ways to couple the lid 112 to the reaction chamber 106, such as threading and an adhesive .
An additional feature of the cartridge 1200 , however, is the presence of a pressure relief valve 1214. In cases where high pressure, volatile gases are produced, such as oxygen or hydrogen, high pressures can be dangerous . Even in situations where gases do not present a fire hazard, such as nitrogen, high pressures can be an undesirable because the high pressure gas can exploit defects or fractures in the cartridge 1200 to cause the cartridge to rupture . To relieve pressure within the cartridge 1200 , a relief valve 1214 can be employed to relieve pressure within the chamber at a calibrated level . For example, pressure relief can occur at 300 psig. There are a wide variety of pressure relief systems available, such as pop-off valves and rupture discs that can be adequately calibrated to relieve pressure at a desired level .
There are also alternative arrangements for containing the materials employed to sustain the chemical reaction . Referring to FIGURES 13A and 13B of the drawings, the reference numerals 1300 and 1350 depict an activation system primed for activation and the system in use, respectively .
The system 1300 comprises a cartridge 1301 , a spiked plunger 118 , and a female connector 700. The cartridge 1301 then comprises a filter 110, water-filled bag 1304 , a screen
108, a catalyst filled bag 1306, and a gas releasing agent
1308 contained within a reaction chamber 106 and a lid 112.
The bag housing the catalyst 1306 can be made of any number of materials, but can also be made of a water-soluble material . The bag 1304 housing the water can be made of any number of air impermeable and water/moisture impermeable materials, but can also be made of a laminate material consisting of aluminum, polypropylene and woven mesh .
The cartridge 1301 typically also has an air-impermeable and water-impermeable seal 1302. The air-impermeable and water-impermeable seal 1302 can be made of various materials, including, without limitation materials such as Mylar, polytetrafluoroethylene or Nylon®. The purpose of the seal
1302 is to maintain an hermetic seal so that the cartridge can have an extended or indefinite shelf life . Upon activation, the spike tip 904 punctures or ruptures the seal 1302 , and the spiked plunger 118 enters the filter aperture 1320. At that point, the spike tip 904 punctures or ruptures the water bag 1304 , causing the water to flow into the reaction chamber 106. The spiked plunger 1130 completes the piercing of the water bag 1172 and proceeds through the screen aperture 402 such that the spike tip 1142 protrudes just slightly beyond the screen 108. Once the spiked plunger 1130 has penetrated the water bag 1172 and traversed all the way through, spiked plunger and connector assembly 1140 is secured to the cartridge and sealed by the connector 1180.
Once released, the water creates an aqueous environment for the reaction to take place . The water dissolves the bag containing the catalyst 1306. The gas generated as a result of the reaction can then be released from the cartridge 1301 through the spiked plunger 118.
Another embodiment of the cartridge 1301 includes a hanging catalyst bag. Referring to FIGURE 14 of the drawings, the reference 1400 generally designates a release system with a hanging catalyst . The system 1400 comprises cartridges 1401 , a handle 122 , and cutting members such as spiked plungers 118. Within the cartridges 1401 , there is an upper assembly 1402 , a hanging catalyst 1404 , and a gas generating chemical 1308. Upon activation, the spiked plunger 118 engages the upper assembly 1402. Water then flows into the reaction chamber 106. The water creates an aqueous environment for the reaction to take place, while dissolving or permeating the bag containing the catalyst 1404. The gas generated as a result of the reaction can then be released from the cartridge 1401 through the spiked plunger 118 to the gas transmission channel 202 of the handle 122. The bag housing the catalyst 1404 is suspended slightly above the gas generating material 1308, which facilitates faster dissolution of the bag if the bag is a water-soluble bag, or faster permeation through the bag if the bag is permeable .
Referring to FIGURE 15 , the reference number 1500 depicts another system primed for activation . The system 1500 is different in that the catalyst is contained in a catalyst dispersal housing 1502 , located j ust below the water containment housing 1504. The water containment housing 1504 can contain a bag with water, or can have water contained inside of it . The system 1500 can comprise self-contained water releasing cartridge 1501 , a spiked plunger 118 , and a connector assembly 700 coupled to the handle 122. The cartridge 1501 comprises a gas or oxygen releasing agent 1308 , the catalyst dispersal housing 1502 , the screen 108 , and the water containment housing 1504. If the water is contained in a bag, the bag can be made of any number of impermeable materials , but can also be made of a laminate material consisting of aluminum, polypropylene and woven mesh .
Upon activation, the spiked plunger 118 engages the water containment housing 1504 and the catalyst dispersal housing 1502. Water then flows into the reaction chamber 106. The water creates an aqueous environment for the reaction to take place . The gas generated as a result of the reaction can then be released from the cartridge 1301 through the spiked plunger 118 to the gas transmission channel 202 of the handle 122.
A desirable feature of the system 1500 is the construction of the water containment housing 1504 and the catalyst dispersal housing 1502. Referring to FIGURE 16A of the drawings , the reference numerals 1504 and 1502 generally designate the water containment housing and the catalyst dispersal housing, respectively . Specifically, water containment housing 1504 and catalyst dispersal housing 1502 assembly can be made as one piece, and can be made of any material . Without limitation, the water containment housing and catalyst dispersal housing assembly can be made of plastic or thermoplastic, including polypropylene, polyethylene, polycarbonate, HDPE, ABS, acetal, polysulfone, or poly vinyl chloride (PVC) .
The water containment housing 1504 and the catalyst dispersal housing are designed such that it can be a self- contained unit . The water containment housing 1504 has an upper aperture 1602 covered by an upper sealing membrane 1604 and has a lower aperture 1606 covered by a lower sealing membrane 1608. A spiked plunger can be inserted through the seals 1604 and 1608 and the apertures 1602 and 1606 upon activation . The catalyst dispersal housing 1502 also has an aperture 1612 covered by a catalyst housing seal 1610 , which allows the spiked plunger 118 to finally exit the catalyst dispersal housing 1502 during the activation process . Prior to activation, the water is sealed into the water containment housing 1504 by upper seal 1604 and lower seal 1608. While the upper seal 1604 and the lower seal 1608 are shown as having been placed on top of each respective adhesion surface, each can be also be placed on the bottom side of each respective adhesion surface . Catalyst housing seal 1610 can also be placed on either side of the adhesion surface . Each of the seals 1604 , 1608, and 1610 can be made of air-impermeable and water-impermeable materials , including, without limitation materials such as polytetrafluoroethylene, Mylar®, or Nylon® (both available from DuPont) .
During activation, the water is released from the water containment housing 1504 and proceeds in a direction towards the reaction chamber 106, flushing the catalyst with it . Referring to FIGURE 16B, the catalyst dispersal housing 1502 can have an angled or beveled surface 1614 , which facilitates faster and more efficient dispersal of the catalyst and/or water . Additionally, the water containment housing 1504 can also have contain an angled or beveled surface in order to facilitate faster and more efficient dispersal of the water upon activation . The angled or beveled surface 1614 can facilitate better flushing of the catalyst, and/or facilitate faster and more efficient dispersal of the catalyst .
The self-contained housings can also include an in-place spike . Referring to FIGURES 17A and 17B of the drawings, the reference numeral 1700 generally designates an alternative design of the self-contained housings . Specifically, a plunger 1702 with an upper seal 1704 , a lower seal 1706, and catalyst housing seal 1708 is employed. The seals 1704 , 1706, and 1708 are attached to the plunger 1702 such that the seals 1704 , 1706, and 708 do not break away from or separate from the plunger 1702 during normal use . The seals 1704 , 1706, and 1708 are attached to the water containment housing 1504 and catalyst dispersal housing 1502 such that the seals 1704 , 1706, and 1708 are breakable, detachable, or removable upon activation .
FIGURE 17A depicts the self-contained housings 1700 in a primed position . Upon activation, the downward force transferred by the pressure source rips, tears, dislodges or otherwise detaches the seals 1704 , 1706, and 1708 , causing the contents to flow into the reaction chamber 106. Stoppers 1710 allow the plunger 1702 to travel only a specified distance .
An alternative activation method can involve a chemical release cartridge bag configuration . Referring to FIGURES 18A and 18B, the reference numeral 1800 generally designates a pouch that employs a method for storing the gas/oxygen releasing agent and the catalyst .
Accordingly, there is a planar sealed pouch 1800 formed of air- and water-impermeable sheet material 1802 which is resistant to the basic chemicals commonly used. The sheet material 1802 supports the gas/oxygen releasing agent 1804 and has a web seam 1806 whose apex points upwardly towards the gas/oxygen releasing agent 1804. The sheet material 1802 has a base seam 1808 parallel to and below the web seam 1806. The base seam 1808 then seals the pouch 1800. The region between the web seam 1806 and the base seam 1810 forms a compartment
1810 into which catalyst 1809 is disposed.
The entire contents of the pouch 1800 are designed to be released in a rapid fashion into water contained in an outer container in which the pouch 1800 is contained, such as container 106. Therefore, it is thought that the web material 1810 is to be a non-permeable laminar sheet so that none of the chemical material escapes into the volume below the web material . Additionally, the web seam 1806 is formed with a pressure sensitive seal which is broken when pressure is applied.
The pouch 1800 is constructed using a continuous sheet of water- and air-impermeable sheet material 1802 folded such that the fold, situated in the middle of the sheet, fits over and advantageously accommodates the nozzle element 1812. The water- and air-impermeable sheet material 1802 is welded together at side seams 1816 and bottom seam 1808 , and the sheet material 1802 can be a multi-layer laminate . such as (from inside to outside) polyester, aluminum foil, polyester and polypropylene . It should be noted that side seams 1816 can also be frangible during use, like seam 1808 , but need not be .
During use, water or air is introduced into the pouch cartridge by means of a hollow inj ector inserted into the delivery channel 1814 through membrane 1805. The pressure causes the web material to evert inside-out to vent by rupturing the pressure-sensitive seal at 1806. Thus , the gas/oxygen releasing agent 1804 is released through an opening made in the web seam 1806. The catalyst is simultaneously released through the web seam 1806. Because of the geometrical shape of area 1810 , the rupturing of seal 1806 occurs in a predictable and reproducible manner . Once the gas has been produced, humidification and/or cooling/warming of the gas may be required. Referring to FIGURE 19 of the drawings , the reference numeral 1900 generally designates a bubbler . The bubbler 1900 comprises a liquid holding tank 1902 , an intake tube 1904 , an exhaust tube 1906, and a liquid 1908. During the operation, the gas is bubbled through the liquid. Because gas input pressure into the bubbler 1900 is higher than atmospheric pressure, the gas can be forced through the intake tube 1904. Part of the intake tube 1904 is submerged within the fluid 1908 , the exhaust gas bubbles through the liquid 1908. The effect of traveling through the liquid 1908 is that the gas will transfer heat to the liquid 1908 (cooling) or receive heat from the liquid 1908 (warming) .
Once the gas has bubbled to the surface, the gas can then exit through the exhaust tube 1906. When the gas exists , it is likely that small droplets of the liquid can be carried with the gas . Additionally, vapors of the liquid can also be carried. In the case of oxygen production, the oxygen can be cooled or warmed through water . Once bubbled, the oxygen would carry water vapor, thus, producing humidified oxygen . Another design to cool or warm a gas is by use of a radiator . Referring to FIGURE 20 of the drawings , the reference numeral 2000 generally designates a radiator . The radiator comprises fins 2004 and a radiator tube 2002.
As gas is output, a heat sink is employed to transfer heat . The gas is input into the radiator tube 2002 to snake through the radiator 2000. As the gas progresses through the radiator 2000 , heat is transferred to the fins 2004. The fins 2004 then transfer heat to a larger heat sink . The larger heat sink can be a variety of heat sinks which includes, but is not limited to, the atmosphere .
One of the features of the above referenced devices is the ability to utilize multiple reactions chambers . Having multiple reaction chambers creates the ability to increase the performance of the gas dispenser, without the associated increase in pressure and temperature if only one reaction chamber is used. For example, a reaction that produces 90 liters of oxygen in 15 minutes can experience an exponential increase in pressure, especially after a certain internal (to the reaction) temperature is reached. By splitting this same reaction into two reactions , completely isolated from each other in separate chambers (say, of each producing 45 liters over 15 minutes ) , a stable delivery of gas is produced without the exponential increase in pressure and/or temperature that can result from the same 90 liter reaction over 15 minutes contained in one chamber with one reaction .
Similarly, a much higher degree of control is possible over the increase in temperature of the gas by splitting the reaction into multiple reactions . Normally, reactions such as the exothermic reactions that generate oxygen, create heat and a concomitant increase in pressure in a static volume (i . e . there is a direct correlation between temperature and pressure) . A further benefit of using multiple reaction chambers is that a higher reaction onset can be achieved.
Specifically, any multiple of reaction chambers can be combined to create any desired output of volume, flow rate and/or delivery time . For example, 3 reaction chambers , each producing 30 liters of oxygen can be combined to produce the same 90 liter reaction, but with lowered pressure inside each reaction chamber and reduced temperature increase of the generated gas , relative to using the same quantity of reactants and catalyst in only one or two chambers , for example .
Variations in both flow rate and yield can also be varied or dictated by the compositions of the contents in the reaction chambers 106. For example, by varying the amount of a limiting reactant in each chamber and/or by varying the amount and/or composition of the catalyst contained in each cartridge, different flow rates and gas yields can be achieved. For example, by varying the amount of the sodium percarbonate in an oxygen generation reaction in each of the chambers, a yield of 90 liters with a flow rate of 6 liters per minute for 15 minutes or a yield of 30 liters and a flow rate of 3 liters per minute for 10 minutes can be achieved.
The flow rates and yields can be varied depending on the desired usage and can be for different situations , such as emergency oxygen for aircraft or mines . While there are many- possible or acceptable flow rate profiles applicable to the aviation industry, one example may be to have a reaction that produces approximately 4 liters per minute for 4 minutes and then drops to 1 liter per minute for 8 minutes . Using 2 reaction chambers can achieve this general performance profile .
Additionally, there are several other configurations that can be employed to store the chemicals . Referring to FIGURE 21 of the drawings, the reference numeral 2100 generally designates a cartridge 2100. The cartridge 2100 comprises a lid 1126 and a reaction chamber 106.
When combined, the reaction chamber 106 and the lid 112 contain a filter 110 , a foam breaker 500 , a screen 108 , water 2104 , a gas producing agent 2102 , and a catalyst 2106. The filter 110 and the foam breaker 500 are layered on top of the screen 108 , and the chemicals 2106, 2102 , and 2104 are contained within the lower portion of the reaction chamber 106. The water 2104 rests at the bottom of the reaction chamber 106, being held in place by frangible seal 2108. The catalyst 2106 and the gas producing agent 2102 are each contained on a side of the reaction chamber, held in place by a frangible seal 108.
Upon activation, the frangible seals 2108 are broken . The chemicals 2102 , 2104 , and 2106 then mix to create a gas generating reaction . The gas produced traverses the screen 108 , the foam breaker 500, and the filter 110 to exit the cartridge 2100.
Referring to FIGURE 22 of the drawings, the reference numeral 2200 generally designates a cartridge . The cartridge 2200 comprises a lid 112 and a reaction chamber 106.
When combined, the reaction chamber 106 and the lid 112 contain a filter 110 , a foam breaker 500 , a screen 108 , water
2204 , a gas producing agent 2202 , and a catalyst 2206. The filter 110 and the foam breaker 500 are layered on top the screen 108 , and the chemicals 2206, 2202 , and 2204 are contained within the lower portion of the reaction chamber
106. The water 2204 , the catalyst 2206, and the gas producing agent 2202 each rest at the bottom of the reaction chamber 106. Each of the chemicals 2202 , 2204 , and 2206 are separated from one another and held in place by a frangible seals 2208.
Upon activation, the frangible seals 2208 are broken .
The chemicals 2202 , 2204 , and 2206 then mix to create a gas generating reaction . The gas produced traverses the screen 108 , the foam breaker 500 , and the filter 110 to exit the cartridge 2200.
Referring to FIGURES 23A and 23B of the drawings, the reference numeral 2300 generally designates a self-contained activation system. The system 2300 comprises a container 2302 and an activation handle 2304. The sealed unit 2302 is particularly adapted for containing one or more pouches 26000 or 2600' , depicted in FIGURES 26A and 26B . However, sealed unit 2302 can also contain a multitude of devices, such as the configurations of FIGURES 1-3 , 12-18 , and 21-22 , capable of releasing a gas . To initiate the release of a gas , the activation handle 2304 is displaced downwardly into an activation position to apply mechanical pressure to any of the multitude of devices to break any seals and initiate the chemical reaction (s ) . Additionally, the activation position of the handle 2304 can be reached by being displaced into either an upward or a downward position relative to the container 2302.
Referring to FIGURE 24A of the drawing, the reference numeral 2400 generally designates a diagram contrasting two gas producing reactions . The first reaction (REACTION 1) is set up to produce a short reaction that starts high but is only maintained for a short period. The second reaction (REACTION 2 ) is set up to start slow but to be maintained for a longer period. Considered individually, neither REACTION 1 in the first reaction chamber nor REACTION 2 in the second reaction chamber produce the desired flow rate profile . However, referring to FIGURE 23B of the drawings , the reference numeral 2450 generally the combined output of REACTION 1 and REACTION 2. The combined output 2450 shows the sum of the combined reactions 1 and 2 , and illustrates how the desired profile is achieved using 2 reaction chambers instead of one .
Similarly, other profiles can be achieved by two reaction chambers or multiple reaction chambers . For mining applications , for example, one possible flow rate profile is to simply maintain a reaction at an average of 2 liters per minute for 60 minutes .
Another advantage of multiple reaction chambers is that the reactions can be staged to commence at different times in order to achieve a desired output . Referring to FIGURE 25A of the drawings , the reference numeral 2500 generally designates a diagram showing two contrasted reactions . The diagram 2500 shows two identical reactions , REACTION 3 and REACTION 4 , each with a reaction onset of 1.75 liters per minute . Each of REACTION 3 and REACTION 4 can take place in respective reaction chambers . In this case, the reactions are staged such that Reaction 3 commences at time=0 and runs for 12 minutes , while Reaction 4 commences at time=10 minutes .
Referring to FIGURE 25B of the drawings , the reference numeral 2550 shows a diagram depicting the combined outputs of REACTIONS 3 and 4. Considered individually, neither REACTION 3 in the first reaction chamber nor REACTION 3 in the second reaction chamber may produce the desired flow rate profile . However, the output of the combined reactions, shown in the diagram 2550 shows a 20-minute production with flow rates in a relatively narrow range , as the trend-line indicates .
By using multiple reaction chambers and/or staging reactions to commence at different times , a wide variety of flow rates , volume, time periods and performance profiles can be achieved, which allows for superior performance flexibility . This makes it possible for the current invention to cater effectively to a very broad range of applications , such as mining, aviation, emergency medical services, the military, emergency home use or any number of other applications on a worldwide basis , and to customize the flow rate profile that is optimum for the particular application .
FIGURE 26A depicts an embodiment of a planar sealed pouch that employs a method for storing the gas/oxygen releasing agent, the catalyst and the water all in one pouch . Planar sealed pouch 2600 is formed of a pair of sheets 2602 of air- and water-impermeable sheet material which is resistant to the basic chemicals commonly used (only the top sheet 2602 being visible in FIGURE 26A) . The sheet material 2602 supports the catalyst in compartment 2604 , the gas/oxygen releasing agent in compartment 2606 and the water in compartment 2608. The sheet material must be resistant to the chemicals of the catalyst, gas/oxygen releasing agent and the water . In one embodiment, the sheet material is a laminate material that can be any combination of aluminum, polypropylene, polyethylene terephthalate, polyethylene, high density polyethylene, and any number of materials . The laminate material can also include a layer of insulating material . The pouch 2600 has a peripheral border 2611 which is sealed by convenient means , such as adhesive, ultrasonic welding, or heat sealing and is able to retain the pressures encountered without bursting .
Each of the compartments 2604 , 2606 and 2608 also have internal sealed borders 2612 to retain their respective chemicals so that they stay initially separated. Unlike peripheral border 2611 , sealed borders 2612 are sealed with a pressure-frangible adhesive to create "peel areas" between the top and bottom sheet material 2610. In this embodiment, the compartments 2604 , 2606 and 2608 do not take up all of the area of the sheet material 2602 , thus also defining an initially empty compartment 2607. For reasons to be explained, empty compartment 2607 may also be initially filled with air at ambient pressure .
The pouch 2600 accommodates nozzle element 2614 , which can be made of suitable plastic such as polypropylene, to permit the release of the oxygen or other gas produced. Because the gas produced may include entrained droplets of water or particulates from the catalyst and gas/oxygen producing agent, the pouch also includes self-contained permeable membrane/screen 2616 and a foam breaker 2618 that is retained by the membrane/screen 2616. When the gas/oxygen is produced, it will pass through the membrane/screen 2616 and the foam breaker 2618 , where is effectively filtered, removing any entrained water droplets , bubbles or particulates before being exhausted from nozzle 2614 and directed through an appropriate conduit (not shown) to the user .
To use pouch 2600 , force is applied to the outside of the pouch 2600, either directly or by means of the mechanism depicted in FIGURE 23A and 23B . This force causes internal pressure in the pouch, much like attempting to pop a balloon . Because the peripheral seal 2611 is pressure-resistant, seal 2611 does not burst . However, this internal pressure tends to cause sealed borders 2612 to peel apart, allowing the top and bottom sheets of the sheet material 2602 to separate and allowing the initially separated catalyst, gas/oxygen releasing agent and water to combine to create gas . It is believed that having some degree of air in initially empty compartment 2607 will tend to facilitate the peeling apart of these sealed borders 2612 by more evenly distributing the pressure, but this is not necessary to the invention . FIGURE 26B depicts another embodiment of a pouch having compartments for initially separating the catalyst, oxygen producing agent and water . In FIGURE 26B, pouch 2600 ' is similar to pouch 2600, the compartments 2604 ' , 2606' and 2608 ' containing, respectively, the catalyst, oxygen producing agent and water, and the initially empty compartment 2607 ' containing air . In pouch 2600' , however, each of the compartments have different shapes and locations . As in pouch 2600 , each of the compartments is separated by pressure- frangible sealed borders 2612' , constructed in the same manner .
The pouch 2600' accommodates nozzle element 2614 , which can also be made of suitable plastic such as polypropylene, to permit the release of the oxygen or other gas produced. Because the gas produced may include entrained droplets of water or particulates from the catalyst and gas/oxygen producing agent, the pouch also includes self-contained permeable membrane/screen 2616 and a foam breaker 2618 that is retained by the membrane/screen 2616, to filter the gas generated. Otherwise, the construction and operation of the pouch 2600 ' is the same as pouch 2600 and need not be further described.
It should be noted that, as is the case with the multiple reaction chambers 106 depicted in FIGURE 1 , for example, multiple ones of pouches 2600 and/or 2600 ' may be connected to a common conduit and used together . Each of the pouches 2600 and/or 2600' can contain different compositions or proportions of the water, catalyst and gas/oxygen producing agent, as previously described, in order to create various flow profiles such as are depicted in FIGURES 24B and 25B . It is understood that the present invention can take many forms and embodiments . Accordingly, several variations may be made in the foregoing without departing from the spirit or the scope of the invention . The capabilities outlined herein allow for the possibility of a variety of implementations . This disclosure should not be read as preferring any particular embodiments, but is instead directed to the underlying mechanisms on which these embodiments can be built . Having thus described the present invention by reference to certain of its preferred embodiments , it is noted that the embodiments disclosed are illustrative rather than limiting in nature and that a wide range of variations , modifications , changes , and substitutions are contemplated in the foregoing disclosure and, in some instances, some features of the present invention may be employed without a corresponding use of the other features . Many such variations and modifications may be considered desirable by those skilled in the art based upon a review of the foregoing description of preferred embodiments . Accordingly, it is appropriate that the appended claims be construed broadly and in a manner consistent with the scope of the invention .

Claims

1. An apparatus for generating gas from a plurality of initially separated chemicals, comprising a plurality of reaction chambers , each containing a set of initially separated chemicals .
2. The apparatus of Claim 1 , wherein at least two of the reaction chambers have different proportions of the separated chemicals in each reaction chamber such that, when a gas generating reaction is commenced to generate gas , each chamber will have a different flow rate as a function of time from the other chamber .
3. The apparatus of Claim 1 , wherein the gas generating apparatus further comprises a relatively movable member configured to cause the initially separated chemicals in each of the plurality of reaction chambers to combine whereby a desired gas is created.
4. The apparatus of Claim 1, wherein the gas generating apparatus further comprises a gas transmission channel to carry the gas from the plurality of reaction chambers .
5. The apparatus of Claim 1, wherein at least two of the reaction chambers have different compositions of the separated chemicals in each reaction chamber such that, when a gas generating reaction is commenced to generate gas, each chamber will have a different flow rate as a function of time from the other chamber .
6. The apparatus of Claim 1 , further comprising a plurality of transmission members , wherein each transmission member is inserted into a reaction chamber to cause combination of the plurality of separated chemicals and to carry away the gas .
7. The apparatus of Claim 6, wherein the flow rate and a gas production time period of the gas that is generated is varied by inserting the transmission members into each reaction chamber at different times .
8. The apparatus of Claim 3, wherein the apparatus further comprises a plunger handle for combining the plurality of initially separated chemicals in the plurality of reaction chambers when the relatively movable member is relatively moved, wherein the plunger handle is at least configured to have a gas transmission channel to carry the gas from the plurality of reaction chambers . 9. The apparatus of Claim 8 , wherein the relatively movable member moves linearly.
10. The apparatus of Claim 8 , wherein the plunger handle comprises a plurality of transmission members , wherein each transmission member is inserted into a reaction chamber to combine the plurality of initially separated chemicals and to carry away the gas .
11. The apparatus of Claim 1 , wherein there are two reaction chambers .
12. The apparatus of Claim 11 , further comprising a support housing for the two reaction chambers, the support housing having a compartment for each reaction chamber .
13. The apparatus of Claim 1 , wherein the apparatus further comprises a temperature adjustment device configured to vary the temperature of the gas .
14. The apparatus of Claim 13 , wherein the temperature adjustment device further comprises a bubbler wherein the gas that exits is bubbled through a liquid. 15. The apparatus of Claim 14 , wherein the bubbler bubbles the gas through water .
16. The apparatus of Claim 9, wherein the cooler further comprises a heat exchanger .
17. The apparatus of Claim 1 , wherein the plurality of separated chemicals comprise an oxygen rich powder and a catalyst and further comprises water .
18. The apparatus of Claim 1 , wherein the gas that is generated is oxygen .
19. The apparatus of Claim 17 , wherein the water comprises an additive to depress the freezing point of the water .
20. The apparatus of Claim 1 , wherein at least one chemical of the plurality of chemicals is contained within a container disposed in each of the reaction chambers .
21. The apparatus of Claim 20 , wherein each of the plurality of gas generating chemicals is contained in a container disposed each of the reaction chambers . 22. The apparatus of Claim 20, wherein each reaction chamber further comprises a container of water .
23. The apparatus of Claim 22 , wherein the gas generating apparatus further comprises a cutting member configured to cut the container of water in at least one reaction chamber .
24. The apparatus of Claim 23 , wherein each cutting member has a gas transmission channel for carrying away the gas generated.
25. The apparatus of Claim 17 , wherein catalyst is contained within a container in each of the reaction chambers .
26. The apparatus of Claim 25 , wherein the container housing the catalyst is water-soluble .
27. The apparatus of Claim 25 , wherein the container housing the catalyst is adj acent the container housing the oxygen rich powder .
28. The apparatus of Claim 25 , wherein the container housing the catalyst is spaced-apart from the container housing the oxygen rich powder . 29. The apparatus of Claim 23, wherein each cutting member further comprises : an actuator for moving the cutting member into the container of water .
30. The apparatus of Claim 29, wherein each cutting member further comprises a gas transmission channel .
31. The apparatus of Claim 29, wherein the actuator comprises a spring .
32. The apparatus of Claim 23 , wherein the cutting member is a puncturing member and further comprises : a gas transmission conduit within the puncturing member; an extension member coupled to one end of the puncturing member for displacing the extension member to cut the container of water in at least one reaction chamber .
33. The apparatus of Claim 1 , wherein sufficient chemicals are disposed within each reaction chamber such that, when reacted together in an aqueous solution, the chemicals will generate at a yield of at least 2.0 liters per minute
(LPM) for at least 2 minutes and at least 0.7 LPM thereafter for at least 8 minutes . 34. An apparatus for generating gas from a plurality of initially separated chemicals, comprising : a plurality of reaction chambers, wherein each reaction chamber contains a set of the plurality of initially separated chemicals ; and a plurality of containment housings within each reaction chamber respectively retaining different ones of the initially separated chemicals and having means for permitting mixing of the plurality of initially separated chemicals .
35. The apparatus of Claim 34 , wherein the containment housing further comprises : a water container; a catalyst container; an oxygen rich power; and a plunger having a breakable seal between the water and the catalyst containers, and a breakable seal between the catalyst container and the oxygen rich powder, such that movement of the plunger causes the seals to break and permit water to flow from the water container through the catalyst container to mix with catalyst from the catalyst container .
36. An apparatus for generating oxygen from a plurality of initially separated chemicals , comprising : a plurality of reaction chambers; a plurality of initially separated chemicals contained in each of the plurality of reaction chambers ; and wherein the each set of the plurality of initially separated chemicals produces oxygen when combined within the reaction chamber containing the set of chemicals .
37. The apparatus of Claim 36, wherein at least two of the reaction chambers have different proportions of the initially separated chemicals in each reaction chamber such that, when an oxygen generating reaction is commenced to generate oxygen, each chamber will have a different flow rate as a function of time from the other chamber .
38. The apparatus of Claim 36, wherein the oxygen generating apparatus further comprises a relatively movable member configured to cause the initially separated chemicals in each of the plurality of reaction chambers to combine whereby oxygen is created.
39. The apparatus of Claim 36, wherein the oxygen generating apparatus further comprises a gas transmission channel to carry the oxygen from the plurality of reaction chambers . 40. The apparatus of Claim 36, wherein at least two of the reaction chambers have different compositions of the initially separated chemicals in each reaction chamber such that, when an oxygen generating reaction is commenced to generate oxygen, each chamber will have a different flow rate as a function of time from the other chamber .
41. The apparatus of Claim 36, further comprising a plurality of transmission members , wherein each transmission member is inserted into a reaction chamber to cause combination of the plurality of initially separated chemicals and to carry away the oxygen .
42. The apparatus of Claim 41 , wherein the flow rate and an oxygen production time period of the oxygen that is generated is varied by inserting the transmission members into each reaction chamber at different times .
43. The apparatus of Claim 38 , wherein the apparatus further comprises a plunger handle for combining the plurality of initially separated chemicals in the plurality of reaction chambers when the relatively movable member is relatively moved, wherein the plunger handle is at least configured to have a gas transmission channel to carry the oxygen from the plurality of reaction chambers . 44. The apparatus of Claim 43 , wherein the relatively movable member moves linearly .
45. The apparatus of Claim 43 , wherein the plunger handle comprises a plurality of transmission members , wherein each transmission member is inserted into a reaction chamber to combine the plurality of initially separated chemicals and to carry away the oxygen .
46. The apparatus of Claim 36, wherein there are two reaction chambers .
47. The apparatus of Claim 46, further comprising a support housing for the two reaction chambers , the support housing having a compartment for each reaction chamber .
48. The apparatus of Claim 36 , wherein the apparatus further comprises a temperature adjustment device configured to vary the temperature of the oxygen .
49. The apparatus of Claim 48 , wherein the temperature adjustment device further comprises a bubbler wherein the oxygen that exits is bubbled through a liquid .
50. The apparatus of Claim 49, wherein the bubbler bubbles the oxygen through water . 51. The apparatus of Claim 44 , wherein the cooler further comprises a heat exchanger .
52. The apparatus of Claim 36, wherein the plurality of initially separated chemicals comprise an oxygen rich powder and a catalyst and further comprises water .
53. The apparatus of Claim 36, wherein the oxygen that is generated is a gas .
54. The apparatus of Claim 52 , wherein the water comprises an additive to depress the freezing point of the water .
55. The apparatus of Claim 36, wherein at least one chemical of the plurality of chemicals is contained within a container disposed in each of the reaction chambers .
56. The apparatus of Claim 55, wherein each of the plurality of oxygen generating chemicals is contained in a container disposed each of the reaction chambers .
57. The apparatus of Claim 55 , wherein each reaction chamber further comprises a container of water . 58. The apparatus of Claim 57 , wherein the oxygen generating apparatus further comprises : a cutting member configured to cut the container of water in at least one reaction chamber .
59. The apparatus of Claim 58 , wherein each cutting member has a gas transmission channel for carrying away the oxygen generated.
60. The apparatus of Claim 52 , wherein the catalyst is contained within a container in each of the reaction chambers .
61. The apparatus of Claim 60 , wherein the container housing the catalyst is soluble .
62. The apparatus of Claim 60 , wherein the container housing the catalyst is adj acent the container housing the oxygen rich powder .
63. The apparatus of Claim 60 , wherein the container housing the catalyst is spaced-apart from the container housing the oxygen rich powder .
64. The apparatus of Claim 58 , wherein each cutting member further comprises : an actuator for moving the cutting member into the container of water .
65. The apparatus of Claim 64 , wherein each cutting member further comprises a gas transmission channel within it .
66. The apparatus of Claim 58 , wherein the cutting member is a puncturing member and further comprises : a gas transmission conduit within the puncturing member; an extension member coupled to one end of the puncturing member for displacing the extension member to cut the container of water in at least one reaction chamber .
67. The apparatus of Claim 36, wherein sufficient chemicals are disposed within each reaction chamber such that, when reacted together in an aqueous solution, the chemicals will generate at a yield of at least 2.0 liters per minute (LPM) for at least 2 minutes and at least 0.7 LPM thereafter for at least 8 minutes .
68. The apparatus of Claim 36, further comprising a solvent for introduction to each of the plurality of reaction chambers to increase the speed of oxygen generation by each set of the initially separated chemicals once the chemicals are combined. 69. The apparatus of Claim 68 , further comprising a solvent container for containing the solvent .
70. The apparatus of Claim 69, further comprising a release mechanism for releasing the solvent for combination with each set of initially separate chemicals .
71. The apparatus of Claim 68 , wherein the solvent comprises water .
72. The apparatus of Claim 71, further comprising a water additive to either raise or lower the freezing point of the water .
73. The apparatus of Claim 71 , further comprising a water additive to either raise or lower the boiling point of the water .
74. An apparatus for producing an oxygen-rich gas , comprising : a container for containing a chemical reaction; at least two primary reactants within the container, the two primary reactants producing an oxygen-rich gas when reacting together, wherein the reaction between the two reactants generates heat; and a compound within the container, for producing an endothermic reaction absorbing heat during the reaction of the two primary reactants .
75. The apparatus of Claim 74 , wherein the compound comprises a hydrated compound.
76. The apparatus of Claim 74 , wherein the compound produces an endothermic reaction without producing any toxic byproducts .
77. The apparatus of Claim 74 , wherein one of the two primary reactants comprises a catalyst and wherein the compound is combined with at least a portion of the catalyst .
78. The apparatus of Claim 77 , wherein the compound comprises a hydrated compound.
79. The apparatus of Claim 77 , wherein the catalyst comprises a metal oxide .
80. The apparatus of Claim 79, wherein the catalyst comprises manganese dioxide .
81. The apparatus of Claim 75, wherein the compound comprises a sodium-based compound or hydrated salt compound. 82. The apparatus of Claim 75 , wherein the compound comprises a sulfate-based compound or hydrated sulfate compound.
83. The apparatus of Claim 74 , wherein one of the two primary reactants comprises an oxygen releasing reactant .
84. The apparatus of Claim 83 , wherein the compound comprises a hydrated compound .
85. The apparatus of Claim 83 , wherein the oxygen releasing reactant comprises sodium percarbonate or sodium perborate .
86. The apparatus of Claim 74 , further comprising a surfactant within the container for reducing foam resulting from the production of oxygen-rich gas by the two primary reactants .
87. The apparatus of Claim 74 , further comprising a solvent within the container for at least partially dissolving one or both of the primary reactants .
88. The apparatus of Claim 86, further comprising a solvent within the container for at least partially dissolving one or both of the primary reactants . 89. A method for producing oxygen, comprising : providing a first reaction chamber; providing a second reaction chamber; reacting at least two chemicals in the first reaction chamber to produce a stream comprising oxygen; reacting at least two chemicals in the second reaction chamber to produce a stream comprising oxygen; combining the streams from the first and second reaction chambers; and providing the combined streams to one or more individuals as a supplemental source of oxygen for breathing .
90. The method of Claim 89, wherein the step of reacting at least two chemicals in the first reaction chamber is initiated before the step of reacting at least two chemicals in the second reaction chamber .
91. The method of Claim 89, wherein the step of reacting at least two chemicals in the first reaction chamber produces a quantity of oxygen during a predetermined time period beginning with the initiation of the reaction in the first reaction chamber that is different than the quantity of oxygen produced by the step of reacting at least two chemicals in the second reaction chamber during the same predetermined time period beginning with the initiation of the reaction in the second reaction chamber .
92. The method of Claim 90 , wherein the step of reacting at least two chemicals in the first reaction chamber is initiated by inserting a first transmission member into the first reaction chamber at a first time , and wherein the step of reacting at least two chemicals in the second reaction chamber is initiated by inserting a second transmission member into the second reaction chamber at a later time .
93. The method of Claim 91 , wherein the first reaction chamber and the second reaction chamber are each provided with different proportions of the at least two chemicals ±-R—such that, when a gas generating reaction commences to generate gas , each chamber will have a different flow rate as a function of time from the other chamber .
94. The method of Claim 91 , wherein the first reaction chamber and the second reaction chamber are each provided with different compositions of the at least two chemicals such that, when a gas generating reaction commences to generate gas-, each chamber will have a different flow rate as a function of time from the other chamber . 95. An apparatus for generating oxygen from a plurality of initially separated chemicals , comprising : a container containing a plurality of initially separated chemical reactants for producing a gas ; a filter through which the gas is directed; a mixing mechanism for combining the reactants within the container to begin a chemical reaction that produces the gas; and one or more sealing surfaces to seal the container during activation of the mixing mechanism and during the chemical reaction that produces the gas .
96. The apparatus of Claim 95, further comprising a cartridge housing the plurality of initially separated chemical reactants within the container, the cartridge being removable from the container following the production of gas .
97. The apparatus of Claim 95, further comprising a cartridge housing the plurality of initially separated chemical reactants, the cartridge being configured for insertion into the container prior to combining the reactants to begin production of the gas . 98. The apparatus of Claim 97 , wherein the cartridge houses the plurality of initially separated chemical reactants prior to and following insertion into the container .
99. An apparatus for generating an oxygen-rich gas, comprising : one or more reaction chambers for containing a chemical reaction producing an oxygen-rich gas ; a plurality of chemical reactants within the reaction chamber for creating a chemical reaction to produce an oxygen- rich gas , wherein at least one of the plurality of chemical reactants comprises a powder .
100. The apparatus of Claim 99, wherein the plurality of chemical reactants each comprises a powder .
101. An apparatus for generating an oxygen-rich gas, comprising : a chamber for containing a chemical reaction to produce an oxygen-rich gas ; and a powder reactant within the chamber for producing the oxygen-rich gas when reacted with a catalyst . 102. The apparatus of Claim 101 , further comprising a solvent for dissolving the powder reactant to increase the speed of reaction that produces an oxygen-rich gas .
103. The apparatus of Claim 102 , further comprising a catalyst for increasing the speed of oxygen-rich gas production by the reactant .
104. An apparatus for generating an oxygen-rich gas , comprising : a chamber for containing a chemical reaction to produce an oxygen-rich gas ; and a powder reactant within the chamber for producing the oxygen-rich gas when reacted with a catalyst, wherein the powder reactant is hermetically sealed within the chamber .
105. The apparatus of Claim 104 , further comprising a solvent for dissolving the powder reactant to increase the speed of reaction that produces an oxygen-rich gas, wherein the solvent is hermetically sealed within the chamber .
106. The apparatus of Claim 105, further comprising a catalyst for increasing the speed of oxygen-rich gas production by the reactant, wherein the catalyst is hermetically sealed within the chamber . 107. An apparatus for producing an oxygen-rich gas , comprising : a chamber for containing a chemical reaction producing at least an oxygen-rich gas ; a reactant within the chamber forming at least a part of the chemical reaction; a quantity of water within the chamber to dissolve at least a portion of the reactant; and an additive to vary the freezing point or boiling point of the water .
108. The apparatus of Claim 107 , wherein the additive increases or decreases the freezing point of the water .
109. The apparatus of Claim 107 , wherein the additive increases or decreases the boiling point of the water .
110. An apparatus for generating an oxygen-rich gas , comprising : a chamber containing a quantity of water and a reactant for use in a chemical reaction within the chamber that produces an oxygen-rich gas, wherein at least a portion of the reactant is capable of dissolving in at least a portion of the quantity of water within the chamber; and a chemical additive within the chamber for varying the freezing point or boiling point of the water .
111. The apparatus of Claim 110 , wherein the additive increases or decreases the freezing point of the water .
112. The apparatus of Claim 110 , wherein the additive increases or decreases the boiling point of the water .
113. (The apparatus of Claim 110 , wherein the reactant and the quantity of water are initially separated within the chamber and further comprising a mechanical actuator allowing at least a portion of the quantity of water and at least a portion of the reactant to come into contact within the chamber in response to actuation of the mechanical actuator .
114. An apparatus for generating an oxygen-rich gas , comprising : a container for containing a chemical reaction producing at least in part an oxygen-rich gas, the chemical reaction occurring in the presence of a liquid; and a surfactant within the container for inhibiting formation of foam in the liquid resulting from the production of oxygen-rich gas . 115. The apparatus of Claim 114 , wherein the container is portable .
116. The apparatus of Claim 115, wherein the container is configured for use as a medical emergency oxygen source .
117. A method of generating an oxygen-rich gas , comprising : generating an oxygen-rich gas in one or more quantities of a liquid at either or both a desired flow rate and a desired quantity; placing a surfactant in contact with at least one of the one or more quantities of liquid to inhibit formation of foam in the liquid resulting from at least the production of oxygen-rich gas .
118. The method of Claim 117 , wherein the step of generating an oxygen-rich gas further comprises generating an oxygen-rich gas in at least two initially separate quantities of liquid.
119. The method of Claim 118 , wherein the step of generating an oxygen-rich gas further comprises simultaneously generating an oxygen-rich gas in each of the at least two initially separate quantities of liquid at a different rate . 120. A method of generating an oxygen-rich gas , comprising : generating an oxygen-rich gas in one or more quantities of a liquid at either or both a desired flow rate and a desired quantity, wherein the at least one powder reactant is dissolved in the one or more quantities of liquid to generate the oxygen-rich gas and wherein the desired flow rate is achieved by varying one or more attributes of at least a portion of the powder, comprising : applying one or more layers of a coating to particles of the powder, selecting a desired thickness for the one or more layers of coating and selecting a desired powder particle size; and placing a surfactant in contact with at least one of the one or more quantities of liquid to inhibit formation of foam in the liquid resulting from at least the production of oxygen-rich gas .
121. An apparatus for generating an oxygen-rich gas , comprising : first and second chambers , each for containing a chemical reaction producing an oxygen-rich gas / and a plurality of reactants within each of the first and second chambers for simultaneously producing an oxygen-rich gas within the first and second chambers at different rates . 122. The apparatus of Claim 121, wherein the plurality of reactants in each of the first and second chambers- is dissolved in a liquid to promote the production of an oxygen- rich gas, and wherein the rates at which at least one reactant in the first chamber and at least one reactant in the second chamber dissolve in the liquid within their respective chambers differs , thereby contributing to the simultaneous production of oxygen-rich gas in the first and second chambers at different rates .
123. An apparatus for generating an oxygen-rich gas , comprising : a first chamber containing a first chemical reaction generating an oxygen-rich gas stream at a first flow rate; a second chamber containing a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein the first and second flow rates of oxygen-rich gas streams differ .
124. The apparatus of Claim 123 , further comprising one or more channels for directing both the oxygen-rich gas stream of the first chamber and the oxygen-rich gas stream of the second chamber to a location external to the first and second chambers . 125. The apparatus of Claim 123 , wherein the sum or the first and second flow rates of oxygen-rich gas streams is at least ninety liters during a period of fifteen minutes .
126. The apparatus of Claim 123 , wherein the first chemical reaction initiates before the second chemical reaction .
127. The apparatus of Claim 123 , wherein the rate of the second chemical reaction is slower than the first chemical reaction .
128. The apparatus of Claim 123, further comprising a chemical additive for retarding or delaying the rate of the second chemical reaction with respect to the first chemical reaction .
129. The apparatus of Claim 123, wherein the first flow rate of oxygen-rich gas is greater than the second flow rate of oxygen-rich gas during a first time period and wherein the first flow rate of oxygen-rich gas is less that the second flow rate of oxygen-rich gas during a second time period.
130. An apparatus for generating an oxygen-rich gas , comprising: a first chamber containing a first chemical reaction generating an oxygen-rich gas stream at a first flow rate; a second chamber containing a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein at least the first chemical reaction generating an oxygen-rich gas stream comprises a powder reactant for controlling either or both the initiation and the rate of the reaction, the powder reactant further comprising : one or more layers of a coating on at least a portion of the powder particles for slowing or delaying the chemical reaction .
131. The apparatus of Claim 130 , wherein either or both the initiation and the rate of the first chemical reaction is related to the thickness of at least one of the coating layers on the powder reactant particles .
132. The apparatus of Claim 130 , wherein either or both the initiation and the rate of the first chemical reaction is related to the number of coating layers on the powder reactant particles .
134. An apparatus for generating an oxygen-rich gas , comprising : a first chamber containing a first chemical reaction generating an oxygen-rich gas stream at a first flow rate; a second chamber containing a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein at least the first chemical reaction generating an oxygen-rich gas stream comprises a powder reactant for controlling either or both the initiation and the rate of the reaction, at least a portion of the powder reactant comprising powder particles having a size related to at least the rate of the first chemical reaction .
135. An apparatus for generating an oxygen-rich gas, comprising : a first chamber containing a first chemical reaction generating an oxygen-rich gas stream at a first flow rate, the first chemical reaction comprising at least one limiting chemical reactant; a second chamber containing a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein the limiting reactant of the first chemical reaction limits the first flow rate of the oxygen-rich gas generated in the first chemical reaction to less than the second flow rate of the oxygen-rich gas generated in the second chemical reaction .
136. An apparatus for generating an oxygen-rich gas, comprising : a first chamber containing a first chemical reaction generating an oxygen-rich gas stream at a first flow rate, the first chemical reaction comprising at least one limiting reaction catalyst; a second chamber containing a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein the limiting reaction catalyst of the first chemical reaction limits the first flow rate of the oxygen- rich gas generated in the first chemical reaction to less than the second flow rate of the oxygen-rich gas generated in the second chemical reaction .
137. An apparatus for generating an oxygen-rich gas , comprising : a first chemical reaction generating an oxygen-rich gas stream at a first flow rate; a second chemical reaction generating an oxygen-rich gas stream at a second flow rate; and wherein the first flow rate of the oxygen-rich gas generated in the first chemical reaction is less than the second flow rate of the oxygen-rich gas generated in the second chemical reaction .
138. An apparatus for generating an oxygen-rich gas , comprising : a container for containing a chemical reaction producing at least in part an oxygen-rich gas ; and wherein the container comprises a thermoplastic material .
139. The apparatus of Claim 138 , wherein the thermoplastic material comprises one or more of the attributes of durability, high tensile strength, high resistance to chemical reactions and high resistance to heat .
140. The apparatus of Claim 138 , wherein at least a portion of the container comprises polycarbonate, polytetrafluoroethylene, acrylonitrile butadiene styrene, polypropylene or polyethylene .
141 An apparatus for generating an oxygen-rich gas , comprising : a chamber for containing a chemical reaction that produces an oxygen-rich gas; and a pressure relief device operatively associated with the chamber for relieving pressure within the chamber once a preset limit is reached within the chamber .
142. The apparatus of Claim 141 , wherein the pressure relief device comprises a pressure relief valve .
143. The apparatus of Claim 141 , wherein the pressure relief device comprises a pop-off valve .
144. The apparatus of Claim 141 , wherein the pressure relief device comprises a rupture disc .
145. An apparatus for producing an oxygen-rich gas , comprising : a container, wherein the container holds a plurality of reactants in an initially separated position; a plurality of reactants within the container that will react when mixed to produce an oxygen-rich gas, wherein the reactants are held by the container in initially separated positions ; and an actuator mechanism for at least initiating mixing at least a portion of the plurality of reactants together within the container in response to actuation of the mechanism, wherein at least a portion of the actuator mechanism is manually accessible from outside the container to actuate the mechanism without opening the container .
146. An apparatus for producing an oxygen-rich gas , comprising : a container, wherein the container holds a plurality of reactants in an initially separated position; a plurality of reactants within the container that will react when mixed to produce an oxygen-rich gas , wherein the reactants are held by the container in initially separated positions; and an actuator mechanism for at least initiating mixing at least a portion of the plurality of reactants together within the container, wherein at least an outer portion of the actuator mechanism is accessible from outside the container and at least initiates mixing of the plurality of reactants in response to movement of the outer portion of the actuator mechanism.
147. The apparatus of Claim 146, wherein the outer portion of the actuator mechanism is configured to be at least manually accessible .
148. The apparatus of Claim 146, wherein the outer portion of the actuator mechanism at least initiates mixing of the plurality of reactants in response to movement from an initial position to a fully actuated position .
149. The apparatus of Claim 148 , wherein the movement from an initial position to a fully actuated position is in a substantially continuous movement .
150. The apparatus of Claim 149, wherein the movement is in substantially the same rotational or linear direction .
151. An apparatus for generating oxygen from a plurality of initially separated chemicals , comprising : a plurality of reaction chambers , each chamber containing a plurality of initially separated chemical reactants for producing oxygen; wherein each set of the plurality of initially separated chemical reactants produces oxygen when combined within the respective reaction chamber containing the set of chemical reactants ; a mixing mechanism for combining the reactants within the container to begin a chemical reaction that produces the oxygen; and one or more sealing surfaces to seal the container during activation of the mixing mechanism and during the chemical reaction that produces the oxygen . 152. An apparatus for generating an oxygen-rich gas, comprising : a chamber for containing a chemical reaction to produce an oxygen-rich gas and allowing the oxygen-rich gas produced to be delivered to a location external to the chamber; a powder reactant within the chamber for producing at least a substantial portion of the oxygen-rich gas / and a filter for separating the powder reactant from the produced oxygen-rich gas before delivery to the location external to the chamber .
153. An apparatus for generating an oxygen-rich gas , comprising: a first chamber for containing a quantity of water; a second chamber for containing a catalyst or reactant for generating an oxygen-rich gas ; a third chamber for allowing mixing of the quantity of water from the first chamber and the catalyst or reactant from the second chamber; wherein a first port for providing fluid communication between the first and second chambers and a second port for providing fluid communication between the second and third chambers ; a first seal for seating on the first port to prevent fluid communication between the first and second chambers ; a second seal for seating on the second port to prevent fluid communication between the second and third chambers ; and an actuator operative to simultaneously at least partially unseat both the first and second seals to allow simultaneous fluid communication between the first, second and third chambers, thereby allowing mixing in the third chamber of at least a portion of the contents of the first and second chambers to initiate generation of an oxygen-rich gas .
154. The apparatus of Claim 153, wherein the actuator comprises a linear actuator secured to both of the first and second seals for simultaneously at least partially unseating both seals when actuated.
155. The apparatus of Claim 154 , wherein the linear actuator extends through each of the first and second ports .
156. The apparatus of Claim 155, wherein the linear actuator is a rod.
157. The apparatus of Claim 153 , further comprising : a third port for providing fluid communication with the first chamber at a location separate from the first port; and a third seal for seating on the third port to prevent fluid communication through the third port . 158. The apparatus of Claim 157 , wherein the actuator is further operative to simultaneously at least partially unseat both the first, second and third seals to allow simultaneous fluid communication through the first, second and third ports .
159. The apparatus of Claim 158, wherein the actuator comprises a linear actuator secured to the first, second and third seals for simultaneously at least partially unseating the seals when actuated .
160. The apparatus of Claim 159, wherein the linear actuator extends through each of the first, second and third ports .
161. The apparatus of Claim 160 , wherein the linear actuator is a rod.
162. The apparatus of Claim 153 , wherein the actuator comprises a linear actuator that is operatively connected to both the first and second seals to simultaneously at least partially unseat both seals from the first and second ports, respectively, in response to actuation in one linear direction . 163. The apparatus of Claim 157 , wherein the actuator comprises a linear actuator that is operatively connected to the first, second and third seals to simultaneously at least partially unseat the seals from the first, second and third ports, respectively, in response to actuation in one linear direction .
164. An apparatus for containing a chemical reaction generating an oxygen-rich gas, comprising : a chamber having one or more flexible walls capable of being displaced inwardly with respect to the chamber without breaking or tearing/ one or more containers within the chamber having a wall comprising a frangible material and configured to contain a chemical reactant; a chemical reactant for generating oxygen contained by the one or more containers; and wherein at least a portion of the one or more chamber walls severs at least a portion of the frangible material comprising the wall of the one or more containers when the chamber wall is displaced inwardly, releasing or exposing at least a portion of the chemical reactant within the chamber .
165. The apparatus of Claim 164 , wherein at least a portion of the flexible walls of the chamber comprise a laminate material, sealed along at least a portion of the periphery of the chamber, the flexible walls of the chamber configured to transfer pressure to the one or more containers within the chamber to sever at least a portion of the frangible material comprising the one or more containers , releasing or exposing at least a portion of the chemical reactant within the chamber .
166. The apparatus of Claim 165 , wherein at least one or more portions of the laminate material is selected from among the group of aluminum, polypropylene, polyethylene terephthalate, and polyethylene/high-density polyethylene .
167. The apparatus of Claim 164 , further comprising a plurality of containers within the chamber containing a plurality of chemical reactants for generating oxygen within the chamber when the plurality of chemical reactants is released by the plurality of containers within the chamber .
168. The apparatus of Claim 164 , wherein a plurality of the containers are within the chamber and at least one of the containers does not contain a chemical reactant . 169. The apparatus of Claim 168 , wherein the container that does not contain a chemical reactant contains a quantity of air at ambient pressure .
170. The apparatus of Claim 164 , wherein at least a portion of the flexible walls of the chamber comprise a laminate material , and at least one of the one or more containers within the chamber comprises one or more seals further comprising a pressure-frangible adhesive .
171. The apparatus of Claim 164 , wherein the one or more containers within the chamber comprise one or more walls secured together with a seal that opens in response to increasing the pressure within the one or more containers .
172. An apparatus for generating an oxygen-rich gas , comprising : a container having an initially closed discharge end that at least partially opens in response to increasing pressure within the container; a first reactant within the container, at least a portion of which is discharged through the at least partially open end as pressure within the container increases ; and a second reactant positioned to react with the first reactant following discharge of the first reactant from the container, to begin generation of an oxygen-rich gas .
173. The apparatus of Claim 172 , further comprising a releasable adhesive initially closing the discharge end of the container and releasing the container end to be at least partially open in response to increasing pressure within the container 174. The apparatus of Claim 173 , wherein the releasable adhesive is applied to the initially closed discharge end of the container in a manner allowing the discharge end to open in a predictable manner in response to increasing pressure within the container .
175. The apparatus of Claim 174 , wherein the initially closed discharge end of the container opens in response to the pressure of a quantity of water introduced to the container .
176. The apparatus of Claim 175, wherein the container discharges at least a portion of the first reactant and at least a portion of the quantity of water through the open discharge end. 177. The apparatus of Claim 176, further comprising a chamber enclosing at least the discharge end of the container and the second reactant, the chamber receiving the portion of the first reactant and the portion of the quantity of water discharged through the at least partially open discharge end of the container and containing at least a portion of the oxygen-rich gas generated by the first and second reactants .
178. A reaction chamber for containing a gas producing reaction from a plurality of initially separated chemicals , comprising : a first chamber for containing at least one separated chemical of the plurality of separated chemicals and for containing the gas producing reaction when the plurality of separated chemicals are mixed; and a screen that separates at least one separated chemical from the remaining separated chemicals of the plurality of separated chemicals , wherein the screen is at least configured to provide fluid transmission for the gas that is generated.
179. The apparatus of Claim 178 , wherein the reaction chamber further comprises a lid having a neck that is connectable to a gas transmission channel for the gas that is generated. 180. The apparatus of Claim 178 , wherein the reaction chamber further comprises a pressure relief device that will release at least some of the gas that is generated if a pressure within the reaction chamber exceeds a predetermined threshold.
181. The apparatus of Claim 178 , wherein the reaction chamber further comprises a foam breaker through which at least a portion of gas that is generated passes .
182. The apparatus of Claim 181 , wherein the foam breaker further comprises polytetrafluoroethylene or NYLON .
183. An apparatus for generating gas from a plurality of initially separated chemicals , comprising : a plurality of reaction chambers , each further containing a pouch having at least one pressure-frangible seal, such that force applied to the pouch causes the pressure-frangible seal to rupture, thus permitting the plurality of initially separated chemicals to mix .
184. The apparatus of Claim 183, wherein the force is fluid pressure applied to the inside of the pouch . 185. The apparatus of Claim 183 , wherein the at least one pressure-frangible seal is disposed to evert inside-out to permit mixing of the initially separated chemicals .
186. The apparatus of Claim 183 , wherein the force is applied externally to the pouch, causing the at least one pressure-frangible seal to rupture .
187. The apparatus of Claim 183, wherein the at least one pressure-seal in each of the pouches is a peel-away type, internal to its pouch .
188. The apparatus of Claim 183, wherein the pouch includes internal compartments respectively containing initially separated catalyst and oxygen rich powder .
189. The apparatus of Claim 188 , wherein the pouch further includes an internal compartment containing water .
190. The apparatus of Claim 189, further comprising a compartment initially containing air .
191. The apparatus of Claim 189 , further comprising a screen and a foam breaker through which generated gas will pass . 192. An apparatus for generating gas , comprising: a plurality of initially separated gas generating chemicals; a reaction chamber containing a set of the plurality of gas generating chemicals ; and a puncturing member, wherein the puncturing member is inserted into the reaction chamber .
193. The apparatus of Claim 192, wherein the puncturing member has a gas transmission channel for carrying away the gas generated.
194. The apparatus of Claim 192 , wherein the apparatus further comprises : a female coupling member coupled to the puncturing member; and a male coupling member coupled to the reaction chamber, the male coupling member being adapted to sealably receive the female coupling member .
195. The apparatus of Claim 194 , wherein the male coupling member further comprises a platinum-cured silicone 0- ring to provide a seal . 196. The apparatus of Claim 192 , wherein the reaction chamber is treated with a defoaming agent .
197. The apparatus of Claim 192 , wherein the apparatus further comprises a temperature adjustment device to cool the gas as the gas exits .
198. The apparatus of Claim 192 , wherein the temperature adjustment device further comprises a bubbler wherein the gas that exits is bubbled through a liquid.
199. The apparatus of Claim 192 , wherein the bubbler bubbles the gas through water .
200. The apparatus of Claim 197 , wherein the cooler further comprises a heat exchanger .
201. The apparatus of Claim 192 , wherein the plurality of separated chemicals comprise water, an oxygen rich powder, and a catalyst .
202. The apparatus of Claim 201, wherein the gas that is generated is oxygen . 203. An apparatus for generating gas from a plurality of initially separated chemicals comprising a plurality of reaction chambers that cooperatively operate when the separated chemicals are combined, such that a combined flow rate and total yield are varied based on the proportion of separated chemicals in each respective reaction chamber .
204. The apparatus of Claim 203, wherein the gas generating apparatus further comprises a gas transmission channel to carry the gas from the plurality of reaction chambers .
205. The apparatus of Claim 203 , wherein at least two of the reaction chambers have different proportions or compositions of the separated chemicals in each reaction chamber such that each chamber has a different flow rate as a function of time from the other chamber .
206. The apparatus of Claim 203, further comprising a plurality of transmission members , wherein each transmission member is inserted into a reaction chamber to cause combination of the plurality of separated chemicals and to carry away the gas . 207. The apparatus of Claim 203 , wherein the flow rate and a gas production time period of the gas that is generated is varied by inserting the transmission members into each reaction chamber at different times .
208. The apparatus of Claim 203, wherein the apparatus further comprises a plunger handle for combining the plurality of initially separated chemicals in the plurality of reaction chambers when relatively moved, wherein the plunger handle is at least configured to have a gas transmission channel to carry the gas from the plurality of reaction chambers .
209. The apparatus of Claim 208 , where the plunger handle comprises a plurality of transmission members, wherein each transmission member is inserted into a reaction chamber to combine the plurality of initially separated chemicals and to carry away the gas .
210. The apparatus of Claim 203 , wherein the apparatus further comprises a temperature adjustment device to cool the gas as the gas exits .
211. The apparatus of Claim 210, wherein the temperature adjustment device further comprises a bubbler wherein the gas that exits is bubbled through a liquid. 212. The apparatus of Claim 211, wherein the bubbler bubbles the gas through water .
213. The apparatus of Claim 210, wherein the cooler further comprises a heat exchanger .
214. The apparatus of ,Claim 203, wherein the gas that is generated is oxygen .
215. The apparatus of Claim 214 , wherein the plurality of initially separated chemicals comprise water, an oxygen rich powder, and a catalyst .
216. An apparatus for generating gas from a plurality of initially separated chemicals comprising : a first set of a plurality of initially separated chemicals for generating a gas ; a second set of a plurality of initially separated chemicals for generating a gas ; a plurality of reaction chambers, each containing one of the first and second sets of initially separated chemicals , wherein the first and second sets of initially separated chemicals and the plurality of reaction chambers cooperatively operate when the separated chemicals are combined to produce either or both a flow rate and total yield of the gas from each of the plurality of chambers that differ .
PCT/US2006/002749 2005-01-28 2006-01-26 Method and apparatus for controlled production of a gas WO2006083663A2 (en)

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US4580505A 2005-01-28 2005-01-28
US11/045,805 2005-01-28
US15886705A 2005-06-22 2005-06-22
US11/158,377 2005-06-22
US11/158,377 US20060171860A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,958 2005-06-22
US11/158,618 US20070003452A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,618 2005-06-22
US11/158,958 US20070053810A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/159,016 2005-06-22
US11/158,993 US20060171862A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/159,079 2005-06-22
US11/159,079 US20060171863A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,989 2005-06-22
US11/158,648 2005-06-22
US11/158,989 US20060171861A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,648 US20070053801A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,993 2005-06-22
US11/158,865 2005-06-22
US11/158,696 2005-06-22
US11/158,865 US20070003454A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,362 2005-06-22
US11/158,763 2005-06-22
US11/159,016 US7381377B2 (en) 2005-01-28 2005-06-22 Method for controlled production of a gas
US11/158,763 US7465428B2 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,362 US20070003451A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas
US11/158,867 2005-06-22
US11/158,696 US20070053802A1 (en) 2005-01-28 2005-06-22 Method and apparatus for controlled production of a gas

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3323471A1 (en) * 2016-11-18 2018-05-23 Goodrich Lighting Systems GmbH Device for generating oxygen
EP3323470A1 (en) * 2016-11-18 2018-05-23 Goodrich Lighting Systems GmbH Oxygen generator using ionic liquids
US10549993B2 (en) 2016-11-18 2020-02-04 Diehl Aviation Gilching Gmbh Method for generating oxygen from compositions comprising ionic liquids
US10589995B2 (en) 2016-11-18 2020-03-17 Diehl Aviation Gilching Gmbh Methods using ionic liquids for decomposing peroxides
US10800656B2 (en) 2016-11-18 2020-10-13 Diehl Aviation Gilching Gmbh Compositions comprising ionic liquids for decomposing peroxides

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6267114B1 (en) * 1998-05-14 2001-07-31 Hoshiko Inc. Handy oxygen generator
US20020135172A1 (en) * 2001-03-21 2002-09-26 Takata Corporation Gas generator

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6267114B1 (en) * 1998-05-14 2001-07-31 Hoshiko Inc. Handy oxygen generator
US20020135172A1 (en) * 2001-03-21 2002-09-26 Takata Corporation Gas generator

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3323471A1 (en) * 2016-11-18 2018-05-23 Goodrich Lighting Systems GmbH Device for generating oxygen
EP3323470A1 (en) * 2016-11-18 2018-05-23 Goodrich Lighting Systems GmbH Oxygen generator using ionic liquids
CN108069399A (en) * 2016-11-18 2018-05-25 古德里奇照明系统有限责任公司 For using the oxygen generator of ionic liquid
CN108069397A (en) * 2016-11-18 2018-05-25 古德里奇照明系统有限责任公司 For generating the equipment of oxygen
US10544044B2 (en) 2016-11-18 2020-01-28 Diehl Aviation Gilching Gmbh Oxygen generator using ionic liquids
US10544511B2 (en) 2016-11-18 2020-01-28 Diehl Aviation Gilching Gmbh Device for generating oxygen
US10549993B2 (en) 2016-11-18 2020-02-04 Diehl Aviation Gilching Gmbh Method for generating oxygen from compositions comprising ionic liquids
US10589995B2 (en) 2016-11-18 2020-03-17 Diehl Aviation Gilching Gmbh Methods using ionic liquids for decomposing peroxides
US10800656B2 (en) 2016-11-18 2020-10-13 Diehl Aviation Gilching Gmbh Compositions comprising ionic liquids for decomposing peroxides
CN108069397B (en) * 2016-11-18 2023-01-24 迪尔航空吉尔兴有限责任公司 Device for generating oxygen
CN108069399B (en) * 2016-11-18 2023-01-24 迪尔航空吉尔兴有限责任公司 Oxygen generator for using ionic liquid

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