WO2006079564A1 - Ink receptive material, tinted optical lenses and method for manufacturing the same - Google Patents
Ink receptive material, tinted optical lenses and method for manufacturing the same Download PDFInfo
- Publication number
- WO2006079564A1 WO2006079564A1 PCT/EP2006/001147 EP2006001147W WO2006079564A1 WO 2006079564 A1 WO2006079564 A1 WO 2006079564A1 EP 2006001147 W EP2006001147 W EP 2006001147W WO 2006079564 A1 WO2006079564 A1 WO 2006079564A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ink
- ink receptor
- receptor material
- emulsion
- film
- Prior art date
Links
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- 238000000034 method Methods 0.000 title claims abstract description 52
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
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Classifications
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- B41M3/003—Printing processes to produce particular kinds of printed work, e.g. patterns on optical devices, e.g. lens elements; for the production of optical devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5272—Polyesters; Polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5281—Polyurethanes or polyureas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds
Definitions
- the present invention relates to optical lenses and to methods of manufacturing 5 optical lenses. More specifically, the present invention relates to a tinted optical lens and to a method of manufacturing tinted optical lenses.
- lens means ophthalmic elements fitting for spectacles, eyeglasses, sunglasses, goggles or the like, regardless of whether it performs any correcting function.
- tinted lenses are often tinted by introducing colored additives to the molten glass, and similarly polycarbonate lenses are injection-moulded from pre-colored plastic granules.
- a disadvantage associated with these methods is the very limited flexibility in the range of colors that can be offered. 5
- lenses with highly varying thickness also exhibit non-uniform transmittance when colored by this method.
- Another prior art process consists in dipping hard resin lenses into a hot, liquid dye solution.
- the dyes enter into the resin, thus resulting in coloring the lens.
- this process makes it difficult to achieve tint uniformity and shows poor color 0 reproducibility.
- JP3075403 and JP3349116 describe a method of making a tinted plastic lens, comprising the steps of 5 forming a hardening coating of a water-soluble polymer on the surface of the optical substrate of the lens, applying on said coating an ink aqueous solution containing disperse dyes, by means of an ink jet printer, heat treating, and finally removing, by rinsing, the water-soluble polymer coating.
- This invention relates to a method for tinting optical lenses, wherein the composition of the ink receptor material allows to a coating, which is a porous film, capable to absorb the color with high speed and in large quantity, to remain stable after absorption of the color and to have a good adhesion to the substrate ; the method of the invention allows a good transfer of the color to the substrate which represents the support of lens, a good final coloration of the substrate with a good color homogeneity and with high color intensity when needed and then an acceptable cosmetic tinted lens.
- the method allows a good transfer of the color to a primer layer coating onto the substrate of the lens, and then allows also to an acceptable cosmetic tinted lens.
- the invention also relates to said new ink receptor material, to its use for forming a film onto a lens substrate or onto a primer coating the said lens substrate, and to its use for manufacturing tinted lenses.
- the new ink receptor material according to the invention comprises an inorganic filler and a water-based emulsion (which contains a water-dispersed polymer, said polymer being non soluble in the water), which have been mixed and form a solution.
- the ink receptor material of the invention is a solution able to form a porous film, the water-dispersed polymer helping for the adhesion of the film to the substrate.
- the ink material solution can be applied on a three dimensional surface like a convex or concave surface of an optical lens and forms, after evaporation of the solvents, a porous film on the surface of the substrate.
- the inorganic filler plays an important role in the porosity of the film.
- the porous film of the invention will allow a capacity phenomenon to occur, when the liquid ink is applied on it, thus enhancing the quantity of ink capable to penetrate into the film.
- the inorganic filler may be light calcium carbonate, heavy calcium carbonate, kaolin, talc ? titanium dioxide, zinc oxide, zinc carbonate, satin white, magnesium carbonate, magnesium silicate, magnesium sulphate, calcium silicate, aluminium silicate, aluminium hydroxide, alumina sol, colloidal alumina, alumina hydrate, zeolite, silica, colloidal silica and a mixture thereof.
- the inorganic filler is silica, alumina, or calcium carbonate.
- the inorganic filler have a particle size of 0.05 ⁇ m to 8 ⁇ m.
- the water-based emulsion may be a vinyl acetate emulsion, an ethylene vinyl acetate emulsion, an acrylic emulsion, a silica acrylic emulsion, an urethane emulsion, a polyester emulsion, a chloroprene rubber latex, a butadiene latex, an isoprene rubber latex, an epoxy resin emulsion, a polyolefin emulsion, a fluorocarbon resin emulsion, or an acrylic silicone emulsion.
- the water-based emulsion is a urethane emulsion.
- the water-based emulsion has an anchoring effect, and plays a role in the adhesion of the film to the substrate.
- the ink receptor material comprises the inorganic filler and the water-based emulsion in a ratio of 1: 0.1 to 1: 50 by weight.
- the ink receptor material according to the invention may optionally comprise a water-soluble polymer.
- the water soluble polymer when is present, contribute to provide a good adhesion between the water-based emulsion and the inorganic filler and act as a protective colloid in the ink receptor.
- the water soluble polymer contained in the ink receptor material is carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, polyvinyl alcohol, polyacrylic acid, polyacrylic acid metal salt, polyacrylamide, polyvinyl pyrrolidone, or polyethylene glycol.
- the water soluble polymer is polyvinyl alcohol.
- the ink receptor material comprises at least one inorganic filler, at least one water-based emulsion and at least one water soluble polymer in a ratio inorganic filler/water-based emulsion/ water soluble polymer of 1 / 0.1 to 50 / 0 to 50 respectively.
- the ink receptor material may also comprise one or more carrier(s) able to accelerate the absorption of the ink into the substrate.
- carrier(s) included in the ink receptor material is (are) o-phenylphenol, chlorobenzene, methylsalicylate, dimethylterephthalate, butyl benzoate, benzyl alcohol, or phenethyl alcohol.
- the ink receptor material may also comprise a modified cationic polymer, which helps preventing the migration and/or the clogging in the film, of the dispersed dye particles present in the ink receptor material.
- the modified cationic polymer contained in the ink receptor material is obtained from the polymerisation or copolymerisation of the monomers having a quaternary ammonium side chain.
- the preferred monomers are a quaternary ammonium derivative of amino-alkyl-ester-acrylate or amino-alkyl-ester-methacrylate, a quaternary ammonium derivative of N,N-dimethylaminoethyl acrylate which is modified with methyl chloride or dimethyl sulfate.
- More preferred monomers are quaternary ammonium derivative of N-[3-(dimethylamino)propyl]acrylamide modified with methyl chloride, dimethyl sulfate, benzyl chloride or monochloroacetate, quaternary ammonium derivative of acrylamido-3-methyl-butyl-dimethylamine, and the monomer of vinyl-benzyl-ammonium salt or diallyl dimethyl ammonium salt having a quaternary ammonium side chain.
- Other preferred monomers are polyallylamine, polyethyleneimine, polyamine sulfone, polyamine-polyamide epichlorohydrin, copolymer of cationic polystyrene, cationic starch and vinyl monomer.
- the ink receptor material comprises (a) an aqueous urethane resin, (b) a polyvinyl alcohol, (c) a modified cationic polymer, and (d) an inorganic filler.
- the proportions of each component on a solid basis are : (a) aqueous urethane resin : 10 to 50%; (b) polyvinyl alcohol: 0 to 60%; (c) modified cationic polymer: 0 to 30%; and the ratio of the amount of all polymers (a) - (c) and the inorganic filler is from 100:10 to 100:500 by weight.
- the ink receptor material comprises (a) an aqueous urethane resin, (b) a polyvinyl alcohol, (c) a modified cationic polymer, (d) an inorganic filler, and (e) one or more carrier(s).
- the proportions of each component on a solid basis may be : (a) aqueous urethane resin: 10 to 50% ; (b) polyvinyl alcohol: 0 to 60%; (c) modified cationic polymer: 0 to 30%; (d) the ratio of the amount of all polymers (a) - (c) and the inorganic filler is from 100:10 to 100:500 by weight; and (e) carrier(s): the proportion of carrier(s) to total components is from 0 to 3%.
- the invention also relates to a method for tinting optical lenses, and more specifically to a method for tinting the substrates of lenses.
- the invention relates to a method for tinting optical lenses by tinting a primer coating applied onto the substrate of the lenses.
- the invention also relates to tinted lenses obtainable by the methods of the invention.
- the method according to the invention is a method for tinting optical lenses, including:
- the lenses, susceptible to be tinted according to the present invention are optical lenses that mean ophthalmic lenses, which have a substrate made of an organic glass commonly used for organic ophthalmic lenses.
- the coating can be performed by any method known by the skilled person, and preferably by a method selected from spin coating, dip coating and spraying.
- the ink receptor material comprises an inorganic filler and a water-based emulsion ; more preferably, the ink receptor material is as herein described.
- the evaporation of solvents may be performed by any method known by the skilled person, but preferably comprises the following steps: (1) air-drying at room temperature; (2) heating at a temperature comprised from 40 °C to 100°C for 0.5 min to lO min.
- the ink receptor film resulting from step 2 has a thickness of 0.1 ⁇ m to 50 ⁇ m, preferably of 2 ⁇ m to 25 ⁇ m, more preferably 5 ⁇ m.
- the distance between the substrate and the inkjet nozzle of the inkjet machine is from 0.5 mm to 5 mm, preferably from 1 mm to 2 mm. It is observed that the ink receptor material according to the invention is not dissolved into or by the solvent of the ink, contrary to the prior art water-soluble polymer coating.
- the term "ink” means any colored solution in which the color transferred into the substrate by heating; more preferably the ink solution according to the invention is a solution containing dispersed dyes.
- the ink solution used in the invention is an aqueous solution containing dyes dispersed therein, said dyes being sublimated when heated at the appropriate temperature.
- the heating step allows the sublimation of the dyes contained in the ink and the transfer of the color into the substrate; the heating step includes applying a temperature of 9O 0 C to 240°C during 10 seconds to 2 hours, preferably 120°C to 180°C during 30 min to 60 min, at normal pressure or under vacuum pressure. According to an embodiment of the invention, the heating step is carried at the pressure equal or less than 300 Pa, preferably equal or less than 100 Pa.
- the use of vacuum conditions allows the sublimation conditions of dyes to occur at a lower temperature than when normal pressure is used; disadvantages that may occur at high temperatures, for example deformation and yellowing of the substrate may thus be avoided.
- the heating step is carried out in a heating device, for example air oven, far- infrared radiation oven, infrared oven, halogen lamp heater, autoclave and the like.
- a heating device for example air oven, far- infrared radiation oven, infrared oven, halogen lamp heater, autoclave and the like.
- the removal of the coating includes wiping it or washing it in presence of water, acid solution or basic solution and optionally may be combined with ultrasonic cleaning.
- the method according to the invention is a method for tinting optical lens comprising the following step: 1. coating the substrate of said optical lens with a transparent primer coating film;
- the transparent primer coating comprises: a self-emulsifiable emulsion of a linear polyurethane and/or water-compatible polyester resin; and metal oxide colloid particles which are fine particles of at least one is selected from aluminium oxide, iron oxide, tin oxide, zirconium oxide silica oxide, titanium oxide, tungsten oxide, antimony oxide, and their composite oxides.
- the metal colloid particles are modified by an organic silane compound of formula: R(ROaSiXb wherein:
- - R represents a linear or branched (Q-C ⁇ alkyl group which may be optionally substituted by a group selected from methacryloxy and glycidyloxy;
- R 1 represents a linear or branched (CrC 6 )alkyl group; - a is selected from 0, 1 and 2; and
- the transparent primer coating has a film thickness comprised from 0.1 ⁇ m to 100 ⁇ m. This primer coating has the advantage to protect the substrate of the lens, which can be for example very sensitive to the abrasion like polycarbonate substrate.
- Water-dispersed polyurethane 100 g of "Superflex® 420", Ester/ether type, (Dai-ichi kogyo seiyaku co., Ltd.)
- Inorganic filer 15 g of wet type silica powder "Finesil® X-30",
- Inorganic filer 15 g of wet type silica powder "Finesil® X-30",
- Water-dispersed polyurethane 100 g of "Superflex® 610", Ester/ether type, (Dai-ichi kogyo seiyaku co., Ltd.)
- Cationic polymer 10 g of UNISENCE FPA IOOL (Senka) - polymer of DADMAC (Diallyl dimethyl ammoniumchloride)
- Carrier 3 g of Benzyl alcohol
- the composition of the MZ-480 is:
- the coated lens is placed on a height adjustable stage of an inkjet printer "GP-604" (Mimaki Engineering Corp.);
- a figure having, the same diameter than the substrate with color is drawn with a drawing software, Adobe® Illustrator® and printed on the concave surface of the lens with the inkjet printer;
Landscapes
- Physics & Mathematics (AREA)
- Ophthalmology & Optometry (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Eyeglasses (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Coloring (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007551645A JP4829251B2 (en) | 2005-01-25 | 2006-01-25 | Ink receiving agent, colored optical lens and method for producing the same |
CA002595685A CA2595685A1 (en) | 2005-01-25 | 2006-01-25 | Ink receptive material, tinted optical lenses and method for manufacturing the same |
US11/814,140 US20090047424A1 (en) | 2005-01-25 | 2006-01-25 | Ink receptive material, tinted optical lenses and method for manufacturing the same |
CN2006800030212A CN101119852B (en) | 2005-01-25 | 2006-01-25 | Optical lens tinting method |
AU2006208704A AU2006208704B8 (en) | 2005-01-25 | 2006-01-25 | Ink receptive material, tinted optical lenses and method for manufacturing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05290166.7 | 2005-01-25 | ||
EP05290166A EP1683645B1 (en) | 2005-01-25 | 2005-01-25 | Method for making tinted optical lenses |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006079564A1 true WO2006079564A1 (en) | 2006-08-03 |
Family
ID=34941905
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2006/001147 WO2006079564A1 (en) | 2005-01-25 | 2006-01-25 | Ink receptive material, tinted optical lenses and method for manufacturing the same |
Country Status (10)
Country | Link |
---|---|
US (1) | US20090047424A1 (en) |
EP (1) | EP1683645B1 (en) |
JP (1) | JP4829251B2 (en) |
KR (1) | KR20070114724A (en) |
CN (1) | CN101119852B (en) |
AT (1) | ATE488377T1 (en) |
AU (1) | AU2006208704B8 (en) |
CA (1) | CA2595685A1 (en) |
DE (1) | DE602005024760D1 (en) |
WO (1) | WO2006079564A1 (en) |
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EP4147863A1 (en) | 2021-09-10 | 2023-03-15 | Carl Zeiss Vision International GmbH | Method and composition for tinting a spectacle lens substrate |
EP4238748A1 (en) | 2022-03-02 | 2023-09-06 | Carl Zeiss Vision International GmbH | Method and lens holder for tinting a spectacle lens |
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FR2952440A1 (en) * | 2009-11-12 | 2011-05-13 | Essilor Int | METHOD FOR MANUFACTURING PLASTIC ANTI-UV FILM WITH NON-UNIFORM SPATIAL DISTRIBUTION OF UV ABSORBER AND OPTICAL PHOTOCHROMIC ELEMENTS COATED WITH SUCH A PLASTIC FILM |
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AU2010318078B2 (en) * | 2009-11-12 | 2014-12-18 | Essilor International | Method for producing an anti-UV plastic film with non-uniform spatial distribution of the UV absorber and photochromic optical elements covered with such a plastic film |
EP4147863A1 (en) | 2021-09-10 | 2023-03-15 | Carl Zeiss Vision International GmbH | Method and composition for tinting a spectacle lens substrate |
WO2023036768A1 (en) | 2021-09-10 | 2023-03-16 | Carl Zeiss Vision International Gmbh | Method and composition for tinting a spectacle lens substrate |
EP4238748A1 (en) | 2022-03-02 | 2023-09-06 | Carl Zeiss Vision International GmbH | Method and lens holder for tinting a spectacle lens |
WO2023165997A1 (en) | 2022-03-02 | 2023-09-07 | Carl Zeiss Vision International Gmbh | Method and lens holder for tinting a spectacle lens |
Also Published As
Publication number | Publication date |
---|---|
EP1683645A1 (en) | 2006-07-26 |
CA2595685A1 (en) | 2006-08-03 |
AU2006208704A1 (en) | 2006-08-03 |
KR20070114724A (en) | 2007-12-04 |
JP4829251B2 (en) | 2011-12-07 |
DE602005024760D1 (en) | 2010-12-30 |
JP2008528317A (en) | 2008-07-31 |
AU2006208704B8 (en) | 2011-01-06 |
CN101119852A (en) | 2008-02-06 |
US20090047424A1 (en) | 2009-02-19 |
EP1683645B1 (en) | 2010-11-17 |
ATE488377T1 (en) | 2010-12-15 |
AU2006208704B2 (en) | 2010-11-25 |
CN101119852B (en) | 2010-05-19 |
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