WO2006041848A2 - Water repellant fiberglass binder comprising a fluorinated polymer - Google Patents

Water repellant fiberglass binder comprising a fluorinated polymer Download PDF

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Publication number
WO2006041848A2
WO2006041848A2 PCT/US2005/035694 US2005035694W WO2006041848A2 WO 2006041848 A2 WO2006041848 A2 WO 2006041848A2 US 2005035694 W US2005035694 W US 2005035694W WO 2006041848 A2 WO2006041848 A2 WO 2006041848A2
Authority
WO
WIPO (PCT)
Prior art keywords
binder
fiberglass
product
polymer
polyol
Prior art date
Application number
PCT/US2005/035694
Other languages
English (en)
French (fr)
Other versions
WO2006041848A3 (en
Inventor
Philip Francis Miele
Original Assignee
Johns Manville
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johns Manville filed Critical Johns Manville
Priority to EP05809963A priority Critical patent/EP1805233A4/en
Priority to JP2007535755A priority patent/JP2008515761A/ja
Priority to CA 2582889 priority patent/CA2582889A1/en
Publication of WO2006041848A2 publication Critical patent/WO2006041848A2/en
Publication of WO2006041848A3 publication Critical patent/WO2006041848A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C09J167/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl - and the hydroxy groups directly linked to aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity

Definitions

  • U.S. Patent No. 5,318,990 discloses a fibrous glass binder which comprises a polycarboxy polymer, a monomeric trihydric alcohol and a catalyst comprising an alkali metal salt of a phosphorous-containing organic acid.
  • thermosetting acrylic resins have been found to be more hydrophilic than the traditional phenolic binders, however. This hydrophilicity can result in fiberglass insulation that is more prone to absorb liquid water, thereby possibly compromising the integrity of the product. Also, the thermosetting acrylic resins now being used as binding agents for fiberglass have been found to not react as effectively with silane coupling agents of the type traditionally used by the industry.
  • the binder composition of the present invention comprises a polycarboxy polymer, a polyol, and a fluorinated polymer. It is also preferred that the binder comprise a catalyst, such as an alkaline metal salt of a phosphorus-containing organic acid.
  • a catalyst such as an alkaline metal salt of a phosphorus-containing organic acid.
  • An important aspect of the binder of the present invention is that the binder composition, in addition to the polycarboxy polymer and the polyol, contains a fluorinated polymer. The presence of the fluorinated polymer in the binder is believed to render the binder, and hence the fiberglass mat to which the binder is applied, essentially waterproof. As a result, fiberglass insulation made with the binder of the present invention avoids the possible problem of coming apart when subjected to water, as the binder of the present invention has been found to repel the water and maintain the integrity of the bond with the fiberglass.
  • the formaldehyde-free curable aqueous binder composition of the present invention also contain a catalyst.
  • the catalyst is a phosphorous-containing accelerator which may be a compound with a molecular weight less than about 1000 such as, for example, an alkali metal polyphosphate, an alkali metal dihydrogen phosphate, a polyphosphoric acid, and an alkyl phosphinic acid or it may be an oligomer or polymer bearing phosphorous-containing groups such as, for example, addition polymers of acrylic and/or maleic acids formed in the presence of sodium hypophosphite, addition polymers prepared from ethylenically unsaturated monomers in the presence of phosphorous salt chain transfer agents or terminators, and addition polymers containing acid-functional monomer residues such as, for example, copolymerized phosphoethyl methacrylate, and like phosphonic acid esters, and copolymerized vinyl sulfonic acid monomers, and their salts.
  • the phosphorous- containing accelerator may be used at a level of from about 1 % to about 40%, by weight based on the combined weight of the polyacid and the polyol. Preferred is a level of phosphorous-containing accelerator of from about 2.5% to about 10%, by weight based on the combined weight of the polyacid and the polyol.
  • the waterborne formaldehyde-free composition of the present invention after it is applied to a nonwoven, is heated to effect drying and curing.
  • the duration and temperature of heating will affect the rate of drying, processability and handleability, and property development of the treated substrate.
  • Heat treatment at about 120DC, to about 400DC, for a period of time between about 3 seconds to about 15 minutes may be carried out; treatment at about 150DC, to about 250DC, is preferred.
  • the drying and curing functions may be effected in two or more distinct steps, if desired.
  • the composition may be first heated at a temperature and for a time sufficient to substantially dry but not to substantially cure the composition and then heated for a second time at a higher temperature and/or for a longer period of time to effect curing.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Nonwoven Fabrics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
PCT/US2005/035694 2004-10-07 2005-10-04 Water repellant fiberglass binder comprising a fluorinated polymer WO2006041848A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP05809963A EP1805233A4 (en) 2004-10-07 2005-10-04 WATER REPELLENT GLASS FIBER BOND, CONTAINING A FLUORIZED POLYMER
JP2007535755A JP2008515761A (ja) 2004-10-07 2005-10-04 フッ素化ポリマーを含む撥水性ガラス繊維バインダー
CA 2582889 CA2582889A1 (en) 2004-10-07 2005-10-04 Water repellant fiberglass binder comprising a fluorinated polymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/960,617 2004-10-07
US10/960,617 US20060078719A1 (en) 2004-10-07 2004-10-07 Water repellant fiberglass binder comprising a fluorinated polymer

Publications (2)

Publication Number Publication Date
WO2006041848A2 true WO2006041848A2 (en) 2006-04-20
WO2006041848A3 WO2006041848A3 (en) 2006-12-07

Family

ID=36145713

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/035694 WO2006041848A2 (en) 2004-10-07 2005-10-04 Water repellant fiberglass binder comprising a fluorinated polymer

Country Status (7)

Country Link
US (1) US20060078719A1 (zh)
EP (1) EP1805233A4 (zh)
JP (1) JP2008515761A (zh)
KR (1) KR20070088596A (zh)
CN (1) CN101039968A (zh)
CA (1) CA2582889A1 (zh)
WO (1) WO2006041848A2 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109280496A (zh) * 2018-11-22 2019-01-29 华美节能科技集团玻璃棉制品有限公司 农用棉胶黏剂、农用棉及其制备方法
US11401639B2 (en) 2016-09-06 2022-08-02 Owens Corning Intellectual Capital, Llc Corrosion-resistant non-woven for pipe liner pultrusion applications

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JP4796836B2 (ja) * 2005-12-26 2011-10-19 旭ファイバーグラス株式会社 無機繊維用水性バインダー及び無機繊維断熱吸音材
DE102008062765A1 (de) 2008-12-18 2010-07-01 Vb Autobatterie Gmbh & Co. Kgaa Textiles flächiges Material für eine Batterieelektrode
CN105355863B (zh) 2009-02-26 2019-04-02 约翰逊控制技术公司 电池电极及其制造方法
JP5421730B2 (ja) * 2009-10-28 2014-02-19 日本無機株式会社 ガラス繊維フィルタの製造方法
US8114197B2 (en) * 2009-12-22 2012-02-14 Hollingsworth & Vose Company Filter media and articles including dendrimers and/or other components
CN101880965A (zh) * 2010-06-30 2010-11-10 李世安 玻纤增强改性胶的生产工艺
JP6418847B2 (ja) * 2014-08-25 2018-11-07 株式会社日本触媒 ノニオン性多価アルコール含有結合剤
CN105887487B (zh) * 2016-05-17 2018-06-08 江西国桥实业有限公司 拒水拒油改性丙烯酸酯类胶粘剂的制备方法
WO2018017262A1 (en) * 2016-07-20 2018-01-25 Super Insulation, LLC Hydrophobic fiberglass thermal insulation materials
RU2020112200A (ru) 2017-10-09 2021-11-12 ОУЭНС КОРНИНГ ИНТЕЛЛЕКЧУАЛ КАПИТАЛ, ЭлЭлСи Водные связующие композиции
CA3075644A1 (en) 2017-10-09 2019-04-18 Owens Corning Intellectual Capital, Llc Aqueous binder compositions
US20220298689A1 (en) * 2019-08-23 2022-09-22 Nissin Chemical Industry Co., Ltd. Binder for inorganic fibers and inorganic fiber mat
US11813833B2 (en) 2019-12-09 2023-11-14 Owens Corning Intellectual Capital, Llc Fiberglass insulation product

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US11401639B2 (en) 2016-09-06 2022-08-02 Owens Corning Intellectual Capital, Llc Corrosion-resistant non-woven for pipe liner pultrusion applications
US11970801B2 (en) 2016-09-06 2024-04-30 Owens Corning Intellectual Capital, Llc Corrosion-resistant non-woven for pipe liner pultrusion applications
CN109280496A (zh) * 2018-11-22 2019-01-29 华美节能科技集团玻璃棉制品有限公司 农用棉胶黏剂、农用棉及其制备方法

Also Published As

Publication number Publication date
JP2008515761A (ja) 2008-05-15
EP1805233A2 (en) 2007-07-11
WO2006041848A3 (en) 2006-12-07
EP1805233A4 (en) 2008-01-16
CA2582889A1 (en) 2006-04-20
US20060078719A1 (en) 2006-04-13
CN101039968A (zh) 2007-09-19
KR20070088596A (ko) 2007-08-29

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