WO2006027209A1 - Combinaison de principes actifs fongicides - Google Patents

Combinaison de principes actifs fongicides Download PDF

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Publication number
WO2006027209A1
WO2006027209A1 PCT/EP2005/009560 EP2005009560W WO2006027209A1 WO 2006027209 A1 WO2006027209 A1 WO 2006027209A1 EP 2005009560 W EP2005009560 W EP 2005009560W WO 2006027209 A1 WO2006027209 A1 WO 2006027209A1
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WO
WIPO (PCT)
Prior art keywords
species
active ingredient
active
compound
formula
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Application number
PCT/EP2005/009560
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German (de)
English (en)
Inventor
Anne Suty-Heinze
Markus Heldt
Burkhard SCHÜTZ
Peter Dahmen
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Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Priority to EP05783853A priority Critical patent/EP1791429A1/fr
Priority to AU2005281832A priority patent/AU2005281832A1/en
Priority to NZ553660A priority patent/NZ553660A/en
Publication of WO2006027209A1 publication Critical patent/WO2006027209A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • the present invention relates to a novel active ingredient combination which contains a known oxime ether derivative on the one hand and two known triazole derivatives on the other hand and is very well suited for controlling phytopathogenic fungi.
  • the oxime derivative is 3- [1- [2- (4- ⁇ 2-chlorophenoxy> 5-fluoropyrimidin-6-yloxy) -phenyl] -1- (methoximino) -methyl] -5 , 6-dihydro-1,4,2-dioxazine (fluoxastrobin) has fungicidal properties (see DE-A-196 02 095). The effectiveness of this substance is good, but it leaves little to be desired at low application rates in some cases. The preparation of this compound is likewise known from DE-A-196 02 095.
  • the triazole derivative is 3- (2,4-dichlorophenyl) -6-fluoro-2- (1H-1,2,4-triazol-1-yl) -4 (3H) -quinazolinone (fluquinconazole ) has fungicidal properties (see EP-A-183458).
  • the effectiveness of this substance is good; However, at low application rates, it leaves something to be desired in some cases.
  • the preparation of this compound is also known from EP-A-183 458.
  • the triazole derivative is 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) -butan-2-ol fungicidal properties has (see DE-A-23 24010).
  • the effectiveness of this substance is good; However, at low application rates, it leaves something to be desired in some cases.
  • the preparation of this compound is also known from DE-A-2324 010.
  • the active ingredient of the formula (I) is known (cf., for example, DE-A-196 02 095).
  • the active compounds of the formulas (II) and (III) are likewise known (see the references given).
  • the compounds can be present as E or Z isomer.
  • the compound (I) can therefore be present as a mixture of different isomers or else in the form of a single isomer.
  • the compounds have two asymmetric carbon atoms. They can therefore be present in the R or in the S form.
  • the compounds of the formula (III) are preferably present as mixtures.
  • the active ingredient combination according to the invention contains the active compounds of the formulas (I), (II) and (III). It can also contain other fungicidal Zumischkomponenten beyond.
  • the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced.
  • the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range. In general, 1 part by weight of active compound of the formula (I)
  • the active compound combinations according to the invention have very good fungicidal properties and can be used for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
  • Xanthomonas species such as Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans; Erwinia species, such as Erwinia amylovora;
  • Blumeria species such as Blumeria graminis
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as Gymnosporangium sabinae Hemileia species, such as Hemileia vastatrix
  • Phakopsora species such as Phakopsora pachyrhizi and
  • Puccinia species such as Puccinia recondita
  • Uromyces species such as Uromyces appendiculatus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species such as Plasmopara viticola
  • Pseudoperonospora species such as Pseudoperonospora humuli or
  • Pseudoperonospora cubensis Pythium species such as Pythium ultimum;
  • Alternaria species such as Alternaria solani;
  • Cercospora species such as Cercospora beticola
  • Cladiosporum species such as Cladiosporium cucumerinum
  • Cochliobolus species such as Cochliobolus sativus
  • Colletotrichum species such as Colletotrichum lindemuthanium
  • Cycloconium species such as cycloconium oleaginum; Diaporthe species, such as Diaporthe citri;
  • Elsinoe species such as Elsinoe fawcettii
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as Glomerella cingulata
  • Guignardia species such as Guignardia bidwelli
  • Leptosphaeria species such as Leptosphaeria maculans
  • Magnaporthe species such as Magnaporthe grisea
  • Mycosphaerella species such as Mycosphaerelle graminicola
  • Phaeosphaeria species such as Phaeosphaeria nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as Ramularia collo-cygni
  • Rhynchosporium species such as Rhynchosporium secalis
  • Septoria species such as Septoria apii
  • Typhula species such as Typhula incarnata
  • Venturia species such as Venturia inaequalis
  • Corticium species such as Corticium graminearum
  • Fusarium species such as Fusarium oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases including corncob caused by e.g.
  • Alternaria species such as Alternaria spp .;
  • Aspergillus species such as Aspergillus flavus
  • Cladosporium species such as Cladosporium spp .
  • Claviceps species such as Claviceps purpurea
  • Fusarium species such as Fusarium culmorum
  • Gibberella species such as Gibberella zeae
  • Monographella species such as Monographella nivalis
  • Sphacelotheca species such as Sphacelotheca reiliana
  • Tilletia species such as Tilletia caries
  • Urocystis species such as Urocystis occulta
  • Ustilago species such as Ustilago nuda
  • Aspergillus species such as Aspergillus flavus
  • Botrytis species such as Botrytis cinerea
  • Penicillium species such as Penicillium expansum
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Verticilium species such as Verticilium alboatrum
  • Fusarium species such as Fusarium culmorum
  • Phytophthora species such as Phytophthora cactorum
  • Pythium species such as Pythium ultimum
  • Rhizoctonia species such as Rhizoctonia solani
  • Sclerotium species such as Sclerotium rolfsii
  • Nectria species such as Nectria galligena
  • Botrytis species such as Botrytis cinerea
  • Rhizoctonia species such as Rhizoctonia solani
  • the combination of active substances according to the invention is particularly suitable for combating cereal diseases, such as Erysiphe, Cochliobolus, Pyrenophora, Rhynchosporium, Septoria, Fusarium, Pseudocercosporella, Leptosphaeria and Pyricularia and for combating fungal infestations on non-cereal crops such as wine, fruit, peanut, vegetables, for example Phythophthora, Plasmopara, Pythium and powdery mildews such as Sphaerotheca or Uncinula and leaf spot exciters such as Venturia, 5 Alternaria and Septoria and Rhizoctonia, Botrytis, Sclerotinia and Sclerotium.
  • the good plant compatibility of the active ingredient combinations in the concentrations necessary for controlling plant diseases allows treatment of aboveground plant parts, of planting and seed, and of the soil.
  • the active compound combinations according to the invention can be used for foliar application or as a mordant.
  • the active compound combinations according to the invention are also suitable for increasing crop yield. They are also low toxicity and have good plant tolerance.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant variety protection rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, o stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes .
  • the plant parts also include crops as well as vegetative and generative propagation material, For example, cuttings, tubers, rhizomes, offshoots and seeds.
  • plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars obtained by genetic engineering if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the term “parts” or “parts of plants” or “plant parts” has been explained above.
  • Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted.
  • Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CrylllB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
  • Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits that are further emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example Imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants.
  • SAR systemic acquired resistance
  • PAT phosphinotricin
  • Bt plants are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • YIELD GARD® eg corn, cotton, soya
  • KnockOut® eg maize
  • StarLink® eg maize
  • Bollgard® Cotton
  • Nucotn® cotton
  • NewLeaf® potato
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), (MI® (tolerance against imidazolinone) and STS® (tolerance to sulphonylureas, eg maize)
  • the herbicide-resistant plants (grown conventionally for herbicide-tolerance) also include the varieties sold under the name Clearfield® (eg maize) in the future developed or future on the market coming plant varieties with these or future developed genetic traits ("Traits").
  • the listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention.
  • the preferred ranges given above for the active compounds or mixtures also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
  • the treatment according to the invention of the plants and plant parts with the active ingredients is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, for example by dipping, spraying, evaporating, atomizing, spreading, brushing and propagating material, in particular in the case of seeds single or multi-layer coating.
  • the active compound combinations according to the invention can be converted into the customary formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, very fine encapsulations in polymeric substances and in coating compositions for seeds, as well as ULV formulations.
  • formulations are prepared in a known manner, for example by mixing the active compounds or the active compound combinations with extenders, ie liquid solvents, liquefied gases under pressure and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or or foaming agents.
  • extenders ie liquid solvents, liquefied gases under pressure and / or solid carriers
  • surface-active agents ie emulsifiers and / or dispersants and / or or foaming agents.
  • organic solvents can also be used as auxiliary solvents.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, alcohols, such as butanol or glycol and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • aromatics such as xylene, toluene or alkylnaphthalenes
  • chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride
  • liquefied gaseous diluents or carriers liquids which are gaseous at normal temperature and under atmospheric pressure, for example aerosol propellants, such as butane, propane, nitrogen and carbon dioxide.
  • Suitable solid carriers are: for example ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates.
  • solid carriers for granules are: for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours, and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks.
  • Suitable emulsifying and / or foam-forming agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers,
  • Alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolysates are e.g. Lignin-sulphite liquors and methylcellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers may be used in the formulations, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins, and synthetic phospholipids.
  • Other additives may be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • the formulations generally contain between 0.1 and 95% by weight of active ingredients, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be used as such or in their formulations also in admixture with known fungicides, bactericides, acaricides, nematicides or insecticides, for example in order to broaden the activity spectrum or to prevent development of resistance. In many cases, one obtains synergistic effects, ie the effectiveness of the mixture is greater than the effectiveness of the Individual components.
  • Azoxystrobin Cyazofamide, Dimoxystrobin, Enestrobin, Famoxadone, Fenamidon, Fluoxastrobin, Kresoximmethyl, Metominostrobin, Orysastrobin, Pyraclostrobin, Picoxystrobin
  • Fentin acetate Fentin chloride, fentin hydroxide, silthiofam 4. Inhibition of amino acid and protein biosynthesis
  • Sodium Channel Modulators / Voltage Dependent Sodium Channel Blockers 2.1 Pyrethroids (eg, acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentyl isomer, bioethanomethrin , Biopermethrin, bioresmethrin, chlovaporthrin, cis-cypermethrin, cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin, Cyfluthrin, cyhalothrin, cypermethrin (alpha, beta, theta, zeta), cyphenothrin, DDT, deltamethrin, empenthrin (1R isomer), esfenvalerate, e
  • chloronicotinyls / neonicotinoids e.g., acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiazines, thiacloprid, thiamethoxam
  • Acetylcholine Receptor Modulator 4.1 Spinosyn (e.g., Spinosad)
  • Fiproles e.g., acetoprole, ethiprole, fipronil, vaniliprole
  • Mectins e.g., abamectin, avermectin, emamectin, emamectin benzoate, ivermectin, milbemectin, milbemycin
  • diacylhydrazines e.g., chromafenozides, halofenozides, methoxyfenozides,
  • Benzoylureas e.g., bistrifluron, chlofluazuron, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron
  • Organotins e.g., azocyclotin, cyhexatin, fenbutatin oxides
  • METI's e.g., Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad, Tolfenpyrad
  • Tetronic acids e.g., spirodiclofen, spiromesifen
  • 16.2 tetramic acids [e.g. 3- (2,5-Dimethylphenyl) ⁇ 8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl ethyl carbonate (also known as: Carbonic acid, 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl ethyl ester, CAS Reg.
  • Carboxamides e.g., flonicamid
  • Octopaminergic agonists e.g., Amitraz
  • fumigants e.g., aluminum phosphides, methyl bromides, sulfuryl fluorides
  • Selective feeding inhibitors e.g., cryolites, flonicamid, pymetrozines
  • mite growth inhibitors e.g., clofentezines, etoxazoles, hexythiazox
  • a mixture with other known active ingredients, such as herbicides, safeners or semiochemicals or with fertilizers and growth regulators is possible.
  • the compounds (I), (II) and (III) can be applied simultaneously, either jointly or separately, or in succession, the sequence in the case of separate application generally having no effect on the control result.
  • the active ingredient combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettable powders, soluble powders and granules become.
  • the application is done in a conventional manner, for example by pouring, spraying, spraying, scattering, spreading, dry pickling, wet pickling, wet pickling, slurry pickling or encrusting.
  • the application rates can be varied within a substantial range, depending on the mode of administration.
  • the application rates of active ingredient combination are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha.
  • the application rates of active compound combination are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed.
  • the application rates of active ingredient combination are generally between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.
  • a synergistic effect is always present in fungicides when the fungicidal action of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • Y means the efficiency when using the active ingredient B in an application rate of n ppm
  • the efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infestation is observed.
  • the actual observed efficiency must be greater than the calculated value for the above formula the expected efficiencies Ei and E2.
  • the microtest is performed in microtiter plates with Potato Dextrose Broth (PDB) as a liquid test medium.
  • PDB Potato Dextrose Broth
  • the application of the active substances takes place as technical a.L, dissolved in acetone.
  • For inoculation is a
  • 0% means an efficiency equivalent to the growth in the controls, while an efficiency of 100% means that no fungal growth is observed.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Nouvelle combinaison de principes actifs qui contient d'une part un dérivé connu d'oxime éther et d'autre part deux dérivés connus de triazole. La nouvelle combinaison selon la présente invention est très bien adaptée à la lutte contre les champignons phytopathogènes.
PCT/EP2005/009560 2004-09-10 2005-09-06 Combinaison de principes actifs fongicides WO2006027209A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP05783853A EP1791429A1 (fr) 2004-09-10 2005-09-06 Combinaison de principes actifs fongicides
AU2005281832A AU2005281832A1 (en) 2004-09-10 2005-09-06 Fungicidal active ingredient combination
NZ553660A NZ553660A (en) 2004-09-10 2005-09-06 Fungicidal active ingredient combination of fluoxastrobin, fluquinconazole and triadimenol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200410043819 DE102004043819A1 (de) 2004-09-10 2004-09-10 Fungizide Wirkstoffkombination
DE102004043819.6 2004-09-10

Publications (1)

Publication Number Publication Date
WO2006027209A1 true WO2006027209A1 (fr) 2006-03-16

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PCT/EP2005/009560 WO2006027209A1 (fr) 2004-09-10 2005-09-06 Combinaison de principes actifs fongicides

Country Status (6)

Country Link
EP (1) EP1791429A1 (fr)
AU (1) AU2005281832A1 (fr)
DE (1) DE102004043819A1 (fr)
NZ (1) NZ553660A (fr)
WO (1) WO2006027209A1 (fr)
ZA (1) ZA200701934B (fr)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998025465A1 (fr) * 1996-12-10 1998-06-18 Bayer Aktiengesellschaft Combinaisons de principes actifs fungicides
WO2005011379A1 (fr) * 2003-07-30 2005-02-10 Bayer Cropscience Aktiengesellschaft Combinaisons fongicides ternaires de principes actifs

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998025465A1 (fr) * 1996-12-10 1998-06-18 Bayer Aktiengesellschaft Combinaisons de principes actifs fungicides
WO2005011379A1 (fr) * 2003-07-30 2005-02-10 Bayer Cropscience Aktiengesellschaft Combinaisons fongicides ternaires de principes actifs

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AU2005281832A1 (en) 2006-03-16
ZA200701934B (en) 2008-08-27
DE102004043819A1 (de) 2006-03-30
EP1791429A1 (fr) 2007-06-06
NZ553660A (en) 2010-09-30

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