WO2006016727A2 - Catalyst for reforming of heavy oil, method of reforming heavy oil and apparatus therefor - Google Patents

Abstract

It is intended to reform heavy oil (Bunker A/Bunker B/Bunker C) and lubrication oil, waste oil, etc. of high environmental load contained in petroleum to fractions of light oil (light oil cut/light oil/kerosene/naphtha/gasoline fraction) of low environmental load to thereby attain effective utilization of petroleum resources and reduction of environmental load. There is provided a heavy oil reforming catalyst comprised of a porous active kaolin catalyst having adsorption activity and catalytic activity obtained by producing a claylike matter from a high-purity purification product of kaolin mineral, working the claylike matter to 6 to 8 mm spheres and firing the spheres at a heating temperature of 700 to 800˚C.

Description

 明 ίΜΜ

 "^ Carbon (carbon compound ¾) carbon in the carbon ¾ bond is activated by porous carbon dioxide, adsorbed and collected by distillation, and heavy oil is removed by residual method. And ί¾ 鹧.

 ε skill field 3

 Κ 0 0 0 1 3

 The present invention is a key skill of petroleum refinement of petroleum (hydrocarbon compounds). In the medium field.

 Background skill 3

 0 0 0 2 3

Conventional petroleum refinery S is a large facility collection of petroleum products made from crude oil. Process of refinement of petroleum S Schematics a attached as heavy oil (A heavy oil, B heavy oil, c heavy oil) Kyoyu to market goods. is also is m environmental impact (global warming) factors co ₂ emissions is high璲境pair镀設Chu (K硫No denitrification / current ffi device) Installation is needed oil, heavy Light oil that consumes a lot of crude oil and has a low environmental impact (light oil fraction. Diesel oil-kerosene. Naphtha. Gasoline component) Refining is effective for the use of limited petroleum resources and ¾ 糙. First, the modified fruit of the present invention will be described with reference to a conventional oil refining process schematic comparison diagram, refining type and schematic diagram.

 ί 0 0 0 3 J

 Heavy oil (light oil, kerosene, gasoline component), etc. with low environmental impact and heavy consumption of heavy fuel oil with high environmental impact, such as waste oil waste (engine waste oil waste, other lubricating oil waste oil), etc. The purpose is to improve the use of finite oil resources and reduce environmental impact.

 [0 0 0 4 1

 Heavy oil (A heavy oil, B heavy oil, C heavy oil) is a petroleum oil that requires environmentally-friendly equipment with high environmental impact. Kerosene Naphtha Gasoline component) The purpose of reforming is to effectively use limited petroleum resources and reduce environmental impact.

 [Problems to be solved by the invention]

 [0 0 0 5]

Conventional oil refining process, heavy oil (A heavy oil * B heavy oil * C heavy oil) with high carbon number in oil (hydrocarbon compound) (c ₁₇ to c ₂₅ ) and lubricating oil waste oil (engine oil waste oil * lubrication Reforming oil with high environmental impact, such as oil waste oil, to light oil with low environmental impact (light oil fraction, light oil, kerosene, naphtha, gasoline component) and making effective use of limited petroleum resources There was a problem that was not solved by the objective, (explanation of oil refining process of conventional technology).

 [0 0 0 6]

The present invention has a high carbon number (C ₁₇ to C _{2 5} ) by catalytic distillation of a carbon-bonded carbon component in petroleum (hydrocarbon compound) by a method of absorption, adsorption, collection, decomposition and removal of a porous active kaolin catalyst. Low-grade oils (A heavy oil, B heavy oil, C heavy oil) and light oils with low environmental impact such as lubricating oil waste oil (light oil fraction · diesel oil · kerosene · naphtha · gasoline component) Reforming to each component, effective use of limited petroleum resources and environmental impact of fuel oil, particulate matter of light oil · reduction of sulfur components, economic effect of saving oil consumption by effective use of petroleum resources, global warming The purpose is to provide a method for refining the environment and safety related to C 0 ₂ reduction.

 【0 0 0 7 3

Petroleum resources are an energy source for fuels ・ Enriching society with petrochemical products, while regional society ・ International issues of global warming beyond the boundaries of the international community ・ Environmental issues of local communities It has both environmental impacts, such as refined petroleum products (fuel oil, petrochemical raw material oil, naphtha), etc., heavy oil, light oil reforming of heavy oil with an economic balance of demand and supply of light oil A summary of the objectives of the invention to solve the economic effects of reducing the amount of petroleum resources consumed, the health effects and environmental safety of fuel oil, the factors of global warming, and efforts to reduce co ₂ by providing methods related to refining.

 [Means for Solving the Problems]

 [0 0 0 8]

In order to achieve the above object, the present invention provides: (Claim 4) 2. Pretreatment catalyst (Claim 1) 1. Catalyst (Claim 5) (Claim 2) 2.1. ~ Catalytic distillation is performed using the catalyst in the contents of j, and the carbon components of carbon bonds in petroleum (hydrocarbon compounds) are absorbed, absorbed, collected, decomposed and removed. Carbon dioxide and if yellow and other 'unsaturated materials are also absorbed in the ¾ medium, and the density of the particles / color ¾ / pH is also neutral). Heavy oil / iii 潘 oil 薩 oil made it possible to make the oil quality.

 E 0 0 093

 '(Claim 6) 2. Pretreatment of raw oil decomposition of medium ¾ distillate ... Heavy oil (A heavy oil. B Noble oil. C Noble oil) and 灑 lubricating oil garden oil (engine oil waste oil. Waste oil reforming, etc., except heavy oil A, etc. is a fraction with a low decomposable carbon component of heavy oil. (Claim 8) Distilled by refined secondary a medium distillation (density)

15 ° C / 0. 80 0) The following kerosene fraction is used as a dilute oil (at a density of 15 / 0.84 0). Effective quality by increasing the rate of distilling and distilling oil.

 £ 0 0 1 03

(Claim 15) Medium distillation equipment… 4. Distilled gas purification equipment is the main component of the distillation gas generated during distillation (HCH 2 S. NO x. C OZC 02) produced during distillation. The catalyst of the purification equipment for purification and purification of distilled gas installed in the cooling system at 0 to 2 with neutral gas and free carbon (claim 1) 1. catalyst for preconditioning, (claim 2) 1 Distilled gas that has been absorbed, purified, and refined using a catalyst catalyst and special synthetic activated carbon is a recycle-type environmental safety instru- ment that performs distillation re-reaction in the distillation unit. The effect is CO / C 0 Gas concentration in the distillation process excluding ₂ is removed at β degree of several ppm units. Distilled gas oil is stable without requiring hydrogenation (Claim 7) Pretreatment primary catalytic distillation (Claim 8) Distilled oil produced by secondary catalytic distillation has the effect of improving the quality and quality of density, improving the hue of density, etc., and preventing the distillation mist generated during distillation purification. It is.

 C 0 0 1 11

 (Claim 15) Catalytic distillation equipment ... 5. Catalytic distillation refinement equipment (Claim 7) Pretreatment primary catalyst distillation (Claim 8) Evaporative cooling of distilled oil distilled at the set temperature of secondary catalytic distillation At the same time, it is cooled by the principle of the above, and other impurities are packed in the distillation distillation purification device. (Claim 1) 1. Catalytic distillation purification equipment.

 10 0 1 2]

 (Claim 15) Catalytic distillation equipment ... 2. Distillation fractionator, (Claim 7) Pre-treated primary catalytic distillation gas oil fraction · Saddle heavy oil (Claim 8) Secondary catalytic distillation is diesel oil, kerosene fraction ( Diluted oil) Tertiary catalytic distillation (kerosene, naphtha, gasoline component) Each fraction is fractionated in two stages (Claim 2) 1. Features of the catalyst ... The excess carbon components and vaporized impurities of each fraction are decomposed and removed by the action of absorption and adsorption with a packed catalyst in the distillation heating unit and fractionation unit, and purified (see Fig. 4 Z4)

【0 0 1 33

 (Claim 15) Catalytic distillation equipment ... 1. Catalytic distillation heating equipment is (Claim 4) 2. Pretreatment catalyst ... (Claim 5) 2. Characteristics of catalyst ... (Diesel oil fraction A heavy oil / light oil) reforming (Claim 2 · Kerosene · Naphtha · Gasoline component) Catalyst distillation heating device filled with reforming catalyst etc. (0 0 0 6) Distillation property temperature range as described Catalytic distillation heating device that reforms heavy oil and lubricating oil waste oil by the catalytic action of absorption adsorption collection decomposition removal method of light oil improvement.

 [0 0 1 4]

 (Claim 7) Pre-treatment primary catalytic distillation ... Gas oil fraction ZA heavy oil in the range of 30 to 30 ° C (Claim 5) e. Sulfur components and other impurities contained in e. (Claim 5) Catalytic reforming action of item (i), pre-treatment primary catalytic distillation for absorption, adsorption, collection, decomposition and removal of carbon components of carbon bonds in petroleum (hydrocarbon compounds). 0 0 0 8) (0 0 0 9) (0 0 1 0) (0 0 1 1) (0 0 1 2) (0 0 1 3) The effect is (Density 15 ° CZ 0.8 8 20) Gas oil fraction before and after · Desulfurization sulfur component ratio is 0.05% Quality: Pretreatment primary that can obtain reforming effect Catalytic distillation method.

 【0 0 1 53

(Claim 8) Refining secondary 2. Catalytic distillation ... The light oil fraction of the primary catalytic distillation is secondary in the range of 2700 ~ 290C. 2. Catalytic distillation is performed. (0 0 0 8) (0 0 0 9) (0 0 1 0) (0 0 1 1) (0 0 1 2) (0 0 1 3) (0 0 1 4) Coming at U set temperature 2 7 0 (degree 15 ° CZ 0. 8 0 0) or less Yellow component 0.0 5% or less, oil quality is obtained, distillation set degree 2 8 0 V (Density 15 ° C / 0.8 0 5) Around / Sulfur The component has an oil quality of less than 0.05% @ Oil quality 2 9 0 ¾ (Density 15 / 0.8.10) Around / Sulfur Ingredients: 0.05% or less @Oil quality is obtained, and environmental impact (particulate matter) of residual carbon, etc. I can do it.

 E 0 0 1 63

Kerosene. Naphtha. Gasoline components, etc. (Claim 1) 1 .... Catalyst (Claim 2) 1. Features of the medium ... (0 0 1 3) . Secondary ② 1¾ medium distillate (270-29 0 ^e C) ¾ oil or kerosene fraction (kerosene. Naphtha. Gasoline component) 3 component ί¾ collar distillation or 1-component catalytic distillation Distillation property temperature at each temperature Catalytic distillation is performed at a temperature in the range. The reforming rate for each fraction is about 70% and the residual oil is traded at about 30%. % Reformed skewer Remaining oil is reformed around 30 ¾, however, the reforming rate when catalytic distillation is performed using 2700 C distillation distillate and kerosene distillate for dilution as feedstock is 8 Residual oil treatment improved to 0% or more (Claim 9) (Keose oil. Naphtha. Gasoline component) See (Claims 13) and (Figure 2) for reforming.

 [[0 0? 73

 (Claim 10) (2) Catalytic distillation several oil dilution cracking method ... Primary catalyst distillation, secondary (2) Residue of catalytic distillation Dilution oil of oil cracking and solvent distillation (density 15 ° C / 0.80 0 0) The following is a method of continuously distilling kerosene fractions using dilute oil and m-distilled several oils while performing several oil decomposition by the combined action of the dilute oil and catalytic distillation temperature. The amount of cracked diluted oil and the temperature range at the time of charging can be obtained by considering the temperature drop and the temperature drop at the light oil outlet due to the rate of increase in the residual heavy oil residue (decrease in distillation rate). 2 The amount of cracked diluted oil and the temperature range at the time of charging can be determined by the relationship between the distillation property temperature and density. (Example) The maximum temperature value of the light oil outlet is 1700 V, heavy oil for distillation Increase in residual oil Temperature drop at oil outlet (distillation rate slowing down) If the temperature is 100 ° C and the difference is 70 ° C, the temperature range from 14 2 to 14 9 ° C is diluted oil Input temperature Area range, input of cracked diluent oil reaches the maximum temperature value of light oil outlet, heavy oil residual oil is cracked and distilled by input of cracked diluent oil, distilled oil is injected until the lower temperature of light oil outlet Distilled residue dilute cracking distillation method that can reduce the distillation process and increase productivity by repeating injection and injection. (Example: 2 80 ° C distillation)

 [0 0 1 8]

 (Claim 1 1) Distilled kerosene / catalyst dry distillation ... The treatment method of primary, secondary, and tertiary catalytic distillate, and the catalytic distillate at the set temperature for primary, secondary, and tertiary catalytic distillation Set temperature

A carbon component obtained by performing dry distillation distillation of the catalyst at 3 20 ° C and absorbing and decomposing the soot oil absorbed and decomposed in the catalyst, the self-combustion heating temperature rises to around 3 80 ° C, the catalyst is stirred, and the catalyst is porous The fraction of cocoon oil absorbed inside is vaporized and re-evaporated and distilled, and the distillation rate of the distillation of carbon dioxide drops back and forth at 29.90 to complete the dry distillation of the catalyst. Gas oil fraction with a density of 15 ° CZ 0.8 8 30 Special A heavy oil is distilled by distillation, 5 to 10% is carbon impurities adsorbed to other impurities and catalyst, and the carbonization catalyst is (Claim 2) 1. Features of catalyst ... g. Deoiling property of catalyst, h. Regeneration of catalyst (Claim 5) 2. Features of catalyst ... g. Deoiling property of catalyst, h.

 [0 0 1 93

(Claim 1 2) modifying factor results ... poor quality oil petroleum, carbon atoms _{(C 17 H 36 ~ C 19} H 4.) Heavy oil ZC oil and _{(C 20 H 42 ~ C 25} H 52) , etc. Technology for light oil (light oil) reforming by absorption adsorption, collection, decomposition, and removal of carbon components in petroleum (hydrocarbon compounds) from petroleum (hydrocarbon compounds) by catalytic distillation, which is characterized by a porous active power orin catalyst. The result of the reforming rate is as follows: (C heavy oil) Diesel reforming result, Diesel oil fraction · Diesel oil including special eight heavy oil is around ± 90%, (Lubricating oil and waste oil) Reforming rate, Light oil ± 95%, low-quality oil that can obtain the reforming rate of catalyst absorption adsorption collection free carbon component · other impurities 5 to 10% · Reform of light oil such as lubricating oil and waste oil Effective utilization of petroleum finite resources and environment: The result of reforming of oil with reduced load.

 [0 0 2 03

Gas oil reforming quality ... (Use for dilution) 2 6 0 ¾ Distillation-like kerosene fraction (density 15 ° CZ 0. 7 9 8) or less Sulfur content 0.05% or less, distillate-like light oil ( Density 15 ° CZ 0. 8 0 5) or less Sulfur content 0.05% or less, 2 80 ° C Distillation property gas oil (density 15 ° CZ 0. 8 1 0) or less Sulfur Min 0.05% or less Z 29 (TC distillable 犹 ^ oil (used for dilution) (degree 15 ° CZ0. 8 1 0) or less Z sulfur content 0. 0 5%, less environmental load reduction And health hazards (particulate matter).

 ΕEmbodiment 3 of the invention

 '£ 0 0213-

(Claim 15) ¾-distillation installation ... The reforming method sequence of the method of absorption, adsorption, collection, decomposition and removal with carbon-bonded carbon components in petroleum (hydrocarbon compounds) in the porous mechanical medium of the three holes Description (Claim 1 5) ¾ Medium Distillation Equipment… 1. (¾ Distillation Distiller »Equipment 2. Distillation Fractionation Equipment, 5. ί¾ Medium Distillation Segregation Equipment, 3. Distillation Recovery 4 Distilled gas purification unit S (6) Distillation catalyst self-exchanger (1. 2. 5. Absorption and collection of saturated ¾ medium self-exchange unit) 5. ftfe medium absorption Oil dry distillation collection device (utilizing the deoiling properties of ί¾medium and collecting distiller that absorbs adsorbed oil at the time of 1¾medium distillation) 8. 1¾medium regenerating device (1 furnace) Carbon absorbed and adsorbed by ί medium Components Ζ Sulfur components Other impurities etc. within 8 0 0-8 1 0 are removed by thermal decomposition treatment and catalyst regeneration that does not generate waste waste (Claim 2) 1. Features of ί mono ... Item h. (Claim 5) 1. Features of the catalyst ... See item h., 9. Use of exhaust gas heat from catalyst regenerator (heating furnace) Primary / secondary of catalyst distillation unit 7 Energy saving distillation method using waste heat circulation of catalyst distillation heat unit of catalyst absorption oil dry distillation recovery unit B (Distillation unit) Is an assembly method) Exhaust gas treatment (NO x. S 0 _2. C 0 ₂ removal device) (Ministry of national patent application number PTC / JP / 9 9/2 · 0 5 1) etc. Distillation facilities for the purpose of environmental safety that does not generate industrial waste and effective use of petroleum of limited resources.

 [0 0 2 23

Heavy oil in petroleum (hydrocarbon compounds) with a high carbon number (C ₁₇ to C ₄ ) C heavy oil and heavy oil unadjusted heavy oil (Figure 2 4) Reference and lubricating oil residual oil ( (Claim oil waste oil) Engine oil Waste oil, etc. (Claim 1) 1. Catalyst ... (Claim 2) 1. Catalyst length ... (Claim 5) 2. Features of the ... The carbon component of the carbon bond in petroleum (hydrocarbon compound) is absorbed and absorbed, collected, decomposed and removed by the porous porous oil-based medium in the catalytic distillation facility using a catalytic distillation facility composed of a crude oil fraction. The purpose is to provide effective use of finite oil and the provision of fuel oil for reducing the environment by removing the reformed oil from light oil.

 [0 0 2 31

 Pretreatment to perform catalytic distillation ... (Claim 6) · See Fig. 2/4, Distilled by secondary distillation by catalytic distillation (0.85 at a density of 15) Use the following kerosene fraction, heavy Dilute with oil (C heavy oil / lubricated oil waste oil) etc. (Density 15 / 0.884) Adjust to the dilution adjustment oil before and after.

 [0 0 2 43

Washing and precipitating decomposed impurities by pretreatment of diluted adjustment oil with an ultrasonic sensor.

 [0 0 2 5]

 See Fig. 2Z4, Fig. 2/9 with dilution adjustment oil. — Perform primary catalytic distillation in the range of 3 2 0 to 3 30 ° C in the component catalytic distillation unit. Fig. 2 1 1. Through the catalyst purification unit Fig. 2 / 1 3. Distillation fraction recovery unit (density 15 ° C / 0.8 8 20) Gas oil fraction before and after ・ Heavy oil recovered, diesel oil reforming rate 70 to 75%, fuel oil rate 2 Reformed at 5-30%.

 [0 0 2 61

 Fig. 2 X 1 0. Distillation set temperature 2 60 Z 2 component catalyst Distillation in distillation unit, Fig. 2Z1 2. Through catalyst purification unit Fig. 2 Z1 4. Distillate kerosene fraction (density 15 ° CZ 0.80 0 0) or less in the distillate collection unit · Sulfur component Z 0. 0 5% and light oil (density 15 V / 0.80 0 0) Diluted oil kerosene fraction with a sulfur content of 0.5% · Diesel quality product is distilled, and is modified at a dilute oil kerosene fraction · diesel oil product reforming rate of around 80% and a kerosene rate of around 20%.

 [0 0 2 7]

 Kerosene fraction for dilution at a set temperature of 2700 (less than Z0.80) at a density of 15 · Sulfur component Z 0.05% and light oil (density 15 ° CZ 0.80 0 5) Around · Sulfur Ingredient No. 0.05% dilute oil · Gas oil quality product is distilled, reformed at a light oil product reforming rate of around 80%, and a kerosene rate of around 20%.

 [0 0 2 8]

Kerosene fraction for dilution (density Ι δ ^ Ζθ. 8 0 0) or less when the set temperature is 2 80 ° C · Sulfur component / 0. 0 5 Oiliness 1 5 ^D C /. 8 1 0) Around. Sulfur component / 0.05% quality diluent oil

. ffi Oil quality assault is distilled ¾ oil product reforming rate around 80% S oil rate is reformed at 20% upfront. fk'O 0 2 93

 When the set temperature is 2900 ° C Distillation kerosene fraction (density 15 is 0.8 0 0) or less ° Sulfur component '0.05% and ¾ oil (density 15 is 0.8 1 5) Around . Sulfur 'component / 0.05% quality diluted oil. S oil quality product is reformed at Shiodome S oil product reforming rate around 80% and S oil rate around 20%.

 κ 0 0 3 0 a-Kerosene. Naphtha. Gasoline component and mass fll medium distillation ... The modified feedstock is (0 0 2 6) (0 0 2 7) (0 0 2 8) (0 0 2 9) (density 15; CZ 0.80 5) Using the following distillate reforming oil, set the distillation property temperature of the component required in the three-component catalyst distillation device → catalyst soot production device → distillation fraction recovery device or one-component catalyst distillation device. (Claim 2) 1. Distilling after exchanging with the characteristics of ¾ medium. Three-component total reforming rate ^ 5% or more / Oil rate 15% or less. ·

 10 0 3 13

 (Fig. 2) 9. — Secondary catalytic distillation Distillation gas generated during secondary catalytic distillation and tertiary catalytic distillation (Claim 15) 3. Separation by distillation fraction collector (Claim 15) 4. Distillation Vaporized gas cleaning agent After purification through a purification unit, 9. Sulfur is sent to the catalytic distillation unit and re-distilled. A circulation-type purification method that stabilizes quality by removing free carbon. ·

 10 0 323

 Distilled soot oil Z catalyst dry distillation Distilled oil during secondary catalyst distillation, secondary catalyst distillation, and tertiary catalyst distillation is subjected to re-primary catalytic distillation according to the procedure of (claim 9) (claim 1 1) (0 0 1 8) Distilled kerosene Catalyst Dry distillation Third distillation: Perform catalytic dry distillation using reference. Decomposition rate of kerosene ranges from 90 to 95%, density is 15. C / 0. 8 3 0 輕 Oil fraction 特 Special A Heavy oil is distilled by distillation. 5 to 10% is carbon impurities adsorbed to other impurities and catalyst. (Claim 2) 1-Features of catalyst ... g. Catalyst deoiling properties, h. Catalyst regeneration (Claim 5) 2. Features of the catalyst ... g. Catalyst deoiling properties, h.

 I 0 0 ° 33

(Claim 1 5) 8. Catalyst regeneration unit (heating furnace) ... (0 0 2 1) (Claim 2) 1. Features of catalyst ... h. (Claim 5) 1. Features of catalyst ... h. 9. Recycled catalyst self-combustion combustion heat + Heated exhaust gas heat from the catalyst regeneration equipment (heating furnace) Reuse of 8 0 0 to 8 1 0 ° C, primary / secondary / tertiary / catalyst absorption oil for catalytic distillation equipment Energy saving distillation method using waste heat circulation as a heat source for catalytic distillation such as dry distillation recovery equipment, etc. (Distillation equipment assembly method) Exhaust gas treatment (N 0 _X · S 0 ₂ · C 02 removal device) International patent application number PT CZJ P / g szs os 1 Distillation equipment for the purpose of energy saving with a compact assembly system composed of environmental equipment, environmental safety without industrial waste generation, and effective use of petroleum of limited resources, see Figure 5

【The invention's effect】

 [0 0 34]

 Since the present invention is configured as described above, the following effects can be obtained.

 [0 0 3 5]

Absorption of carbon components of carbon bonds in petroleum (hydrocarbon compounds) with a porous active kaolin catalyst Carbon number of petroleum (C ₁₇ H ₃₆ to C ₂₅ H ₅₂ ) Oil (C heavy oil · lubricating oil and lubricating oil waste oil) carbon number (C ₁₄ H ₃ Q ~ C ₁₇ H ₃₆ ) Kerosene fraction · Light oil fraction, (C 7 H ₁₆ ~ C ₁₃ H ₂₆ ) Kerosene · Naphtha Made it possible to effectively use limited oil resources that are modified into light oil.

 [0 0 3 63

Heavy oil (C heavy oil · lubricating oils and lubricating oil waste oil) is a light oil reforming to reduce the environmental impact.

 [0 0 3 7]

Economic effects of heavy oil (C heavy oil · lubricating oil and lubricating oil waste oil) light oil reforming.

 [0 0 3 81

A catalytic distillation method capable of obtaining a high reforming ratio of heavy oil to light oil with a reforming ratio of 90 to 95%. β

£ 00393

 High temperature and high pressure using conventional technology. In the case of cracking and reforming by hydrogenation, the carbon components in the coal (hydrocarbon compound) in the petroleum (hydrocarbon compound) by the present active kaolin f¾ are absorbed and collected by the as-distilling method. Distillation properties of the product are characterized by distillation at a temperature within the range (low-temperature distillate g?), And the danger of refining can be reduced. -

[[00402

 This is a catalyst that has a long-lasting cost-effective catalyst in the steaming equipment of the energy-saving distillation method. Distillery.

 ® Simple explanation of surface 3

 εFig. 1〗 (Conventional technology) Petroleum »Manufacturing process overview

K Fig. 23 Absorption and collection part removal method modification process ϋ¾ diagram.

 [[FIG. 33 is an explanatory view of β¾medium action].

 {[Figure 43 Demonstrative installation explanatory diagram!

 [Explanation of symbols]

 1-18. (FIG. 2) Explanatory drawing with description of numerals.

 19 (Fig. 3) 2. Catalysis B.

 2 0 (Figure 3) 1. Catalytic action diagram.

 9 1 ". (^ |

) 1. 2. Catalyst absorption oil dry distillation extraction.

 27 28. (Fig. 4) Distillation fractionator.

 23-24. (Fig. 4) Distillation fractionator (Fig. 3) Packing 1. Catalyst.

 30… 33 (Fig. 4) Filling with distillation heating device 1. Catalyst 2.

 [Others] ·

 1 ... Inspection result table (result of analysis of sulfur component in feedstock).

 2. Sulfur content analysis results.

Claims

Request ® ί! © xa © w¾¾ is (κ) high in force line ¾ degree 篛 sa¾ Particle-polar soil 10 ~ m before ϋ is made into a soil shape and processed into a 6-8 mm spherical shape. Temperature 700 ～ 80 Porous warming and warming within 0 ¾ activity and iSiS pores (铋 搔) properties S¾generate activity force “0” medium. Hi§Claim 2〗

1. The length of "" a. Completion of Narutoshi ¾ medium white, b. G¾ pore (¾ hole) Ning: ί¾ medium raw material ¾ molecule distribution ¾ hole (porous) for average particles S up to S ± 10 # m ) Rate c. S Absorption Ning: 飈 水 ίίδ 鲽 SE (H ₂ 0). Warm yield bag ^ value (soil) 3 5% before iU d. Petroleum (Carbonated water «Coal in combination. Elementary ¾ Low region Oil (C ₉ H ₂ Q to C ₁₄ H ₃ ) S Retention temperature 1 5 0 to 25 50 ¾ (kerose oil apportioned) and (C 7 H ₁₆ to C ₂₄ ) Retention ft temperature 1 Absorbs carbon-containing coal components such as (naphtha) and (C ₅ H ₁₂ to C ₇ H ₁₆ ) distillation property temperature 40 to 1 0 0 ¾ (gasoline component) in the range of 0 0 to 2 0 0 C Adsorption / catalysis / removal / removal function of the catalyst by decomposing carbon bonds in the pores (pores) of the working catalyst and adjusting the carbon component to absorption / collection performance e. ί¾A porous active property that neutralizes the collar and a JIS standard component of sulfur and other impurities Catalytic catalyst with the characteristics of porous surface area absorption / absorption / removal of the catalyst) f. ¾ medium shape spherical (on the surface of the catalyst's agglomeration / decomposition ') action catalyst, s. K oil nature of the catalyst ( Recovery method to prevent mass loss during catalytic distillation h. Restoration of the medium regeneration (carbon component absorbed and adsorbed by the soot and other components) Impurities are removed by pyrolysis treatment within 80 to 80 ° C. Catalysts with embedding characteristics of catalyst performance reuse), i. Catalyst reforming action: Petroleum (carbon bonds in hydrocarbon compounds) Warm-up adsorption and decomposition of carbon components (carbon components of each distillation property temperature are decomposed by the absorption and adsorption activity of the catalyst, and the carbon components that have been decomposed are absorbed and collected by the catalyst, and are removed by absorption and decomposition. An active catalyst having a high quality characteristic), j. Porous activated kaolin catalyzed distillation stone The absorption, collection, decomposition, and removal of carbon components of carbon bonds in oil (hydrocarbon compounds) are not affected by the bond properties of organic compounds (single bond s double bond * benzene ring), etc. Catalytic distillation in the temperature range of fractional distillation properties, and a catalytic catalyst that has the characteristics of absorption, adsorption, collection, decomposition, and removal of carbon-bonded carbon components, h. 1.

2. Distillation catalyst has the active feature of promoting distillation rate reduction / decomposition.

 [Claim '3]

(Claim 2) 1. Features of the catalyst: catalytic distillation, low carbon number in petroleum (hydrocarbon compounds) (C ₉ H _2. To C ₁₄ H ₃₀ ) Distillation property temperature 1 5 0 to 2 5 0 Kerosene fraction, (C ₇ HC uH ^) Distillation property temperature range from 1 0 0 to 2 0 0 naphtha, (C ₅ H _{12 to} C ₇ H ie) Distillation property temperature 4 0 to 1 0 0 ° C Gaso The reforming of the phosphorus component was carried out in (Claim 7) (Claim 8) and the kerosene fraction for dilution (density 15 ° C / 0.800) or less (density 15 ° C / 0). 8 0 5) Using the following light oil, reforming is performed by catalytic distillation within the distillation property temperature range of each fraction. (Claim 2) 1. Features of the catalyst i. Catalyst reforming action e. Sulfur The portion is removed by the catalyst absorption removal action, and the density / hue is also improved at the same time. The reforming rate is around 80% soil, the oil rate is around ± 20%, and the oil is re-catalyst (Claim 9). Catalytic distillation method characterized by distilling and reforming the diesel oil / kerosene fraction.

 [Claim 4]

2. Pretreatment catalyst: heavy oil fraction with high carbon number in petroleum (hydrocarbon compounds) (C ₁₇ H ₃₆ 〜C

19 H 40) Lubricating oil. Waste oil (C ₁₇ H ₃₆ to C ₂₅ H ₅₂ ) has a high absorption, absorption, decomposition and collection rate of carbon components. Is the Kaolin mineral

Using high-purity purified products such as kaolin clay / aluminum galeic acid, kaolin kaolinite, norosite, kaolin knight / kaolin clay, kaolinite), etc. Adjustment,

2. Pretreated calcined activated kaolin catalyst with porous absorption / adsorption activity and catalytic porosity particle size characteristics, processed into a spherical shape of 6-8 mm and calcined at a temperature of 70 ° -800 ° C.

 [Contract- ^: J

2. Features of the catalyst ... a. The catalyst after calcination is white, b. Catalyst porosity (pore) rate: catalyst raw material particle content Cloth 2 ± 2 0 iK m up to average ¾ child ¾ hole (porous) c c. Ί¾ 鹧 Warm yield: 汆 1¾ collar weight S (H ₂ 0) Suction rate 土3 6 to 40. d. Carbon in petroleum (carbonized * elemental compound ¾) ¾Τ ^ (C ₁₇ H ₃₆ 〜 C ₂₅ H ₅₂ ) heavy oil (C oil 涵 lubricating oil) etc. Absorbs the composition s ¾ 分 minutes 作用 の 隐 隐 隐 隐 隐 隐 n i i i i i i i i i i i i i i 誥 i i 誥 i 誥 i 炭 誥 炭 炭 炭 成分 component @ ¾ ^ Medium. Sulfur content ¾ 鏺 ¾ Coarsely removed a beam The action of the hole decay surface ¾ with a length of 嗞 convergent w) f, f. ¾ medium shape (collected adsorbed content of ί Ι5 0 K on the surface ¾2) Action l¾ g. Recovery method to prevent fission medium S retention and to prevent dredging h. Ili Regeneration ¾ (ί The charcoal component / sulfur component and other impurities that are warmly settled in the medium 8

0 0 to 8 1 0. Addition within the following. ^ ¾ Final processing 12 ί¾Ι3 ί¾ medium with holding characteristics for performance re-stool) _¾

1. IS 改 甩 ： ': The carbon component of the carbon compound in petroleum (hydrocarbon K compound ¾) is the warm-collected adsorbed fraction m (the carbon component の catalyst adsorption absorption activity at each distillation property temperature). Decomposition of carbon composites Coal components are removed by absorption, adsorption, and decomposition by the catalyst, and the density is also improved at the same time. J j. Petroleum of porous active kaolin catalytic distillation ( Hydrocarbon compounds) Absorption, adsorption, decomposition, and removal of carbon components in the carbon content is compound properties of single compounds (single bonds, double bonds, .benzene s), etc. Catalyzed soot in the distillation distillation soot temperature range to absorb, absorb, warm, trap, decompose and remove carbon components of carbon bonds Action ¾ medium h. 1. 2. 'Catalyst with activity features that promote degree / degradation.

 [Request 62 ..

2. Pre-catalyst cracking ® Heavy oil in petroleum (hydrocarbon compounds), heavy oil fraction (C ₁₇ H ₃₆ to C ₂ SH ₅₂ ) with a large number of carbon atoms (A heavy oil, B heavy oil C Oil heavy oil) Fuel oil Fuel oil (Engine oil-Fuel oil deer oil), etc. A fuel oil is excluded, Fuel oil reforming (density 15 ° C / 0.80 0 0) Use, (Density 15 / 0.84 0) to the front and rear adjustment oils—after adjustment (Claim 4) 2. Catalyst (for preparatory use) and (Claim 5) 2. Claim 1 5) 4. Distilled gas purification and purification equipment 5. Using catalytic distillation purification equipment, kerosene fraction of diluted oil is reformed by primary ^β secondary catalytic distillation 輕 Oil 輕 Oil fraction is reformed Catalytic distillation method characterized by the above, see (Fig. 2)

 [Claim 7]

Preprocessing primary 2. A heavy oil 3 2 0~3 3 0 ^e C range in a catalytic distillation ... including (claim 5) e. Absorption adsorption removal and sulfur other containing impurities (claim 5) i. Catalyst Reforming action: primary absorption, collection, decomposition and removal of carbon components of carbon bonds 2. Catalyzed distillation, distillate (density 15 CZ 0. 8 2 0) before and after the light oil fraction is distilled, light oil The distillate is reformed and distilled at around 75% and the residual oil rate is around 25%.

 r Claim 81

 Refining secondary 2. Catalytic distillation ... Primary 2. Gas oil fraction of catalytic distillation is secondary in the range of 2 70 to 29. 2. Catalytic distillation is performed. (Claim 5) e. Sulfur content and other contained impurities (Claim 5) i. Catalyst reforming action: The carbon fraction of carbon bonds is absorbed, adsorbed, collected, and removed. 0. 8 0 0) The following kerosene fractions for diluent oil (density 15 C /0.8 8 1 5) and before and after light oil distilled, 2 80 0 fractions of catalytic distillation (no density 15 0.80 0) The following kerosene fractions for dilution and (density 15 ° CZ 0. 8 1 0) The following diesel oils are distilled, the 2700 ° C catalytic distillation fraction is a low residual carbon environment Light oil with low load (density 15 ° C 0. 8 0 5) or less and kerosene fraction for dilution (density 15 ° CX 0.80 0 0) or less are distilled, modification of light oil / kerosene fraction The rate of reforming is around 80% and the residual oil rate is around 20%, see (Figure 2).

 r 猜 1

Primary · Secondary. Re-distillation of tertiary catalytic distillation residue decomposition… Primary · Secondary. Secondary catalyst distillation residual oil rate is around 25%, Primary · Secondary. Average of tertiary catalytic distillation residue (density 15 " C / 0. 8 7 5) Before and after, secondary 2. 'The following kerosene fraction obtained by catalytic distillation (density 15 ° CZ 0.80 0 0) was used as cracked diluent oil (density 15 ¾ / 0. 8 4 0) After adjusting to the front and rear adjustment oils, the primary of (Claim 7) 2. Performing catalytic distillation, reforming rate is improved at 80% or more, Perform distilled distillation oil Z catalyst dry distillation in Item 1 1). S claim 103

 2. ί¾ 擦 S¾¾ 油 稀 ^ 分 £? S 酱 方法… (Claim 7) —Next ② 0¾ rub S retention (claim 8) Secondary 2

As the heavy oil component of s 窗 oil increases, s Secondary 2. & u sa¾minute Oil outlet temperature drops Primary secondary a 嫘 Distillation κ / s 蕾 heavy oil Partial addition outlet Find the temperature at the outlet , Secondary ② Degree obtained in ί¾ ¾¾ 1 5 X / 0. 80 0).

 Dilute ^ Return ¾ Oil fil®g Kiwa 犹 Si Degree 15 ° C / 0. 9 0 0) c Heavy oil fraction on H 2. ί 灘? 窗 Residual oil dilute 分 Steam (Claim 7) (»Claim 8) 2. mmm 再 Oil redistribution SP¾Thunder (Claim 9) can be omitted.

 Claim 1 13-Distillation oil / Sensitive dry distillation——Secondary, tertiary, fiii 漦 藿 Oil treatment method (it Claim 9) Item OS oil is steamed at constant temperature 'ft 3 2 0-3 3 (TC Perform “distillation” at HH, fraction of fuel oil distillate (A heavy oil) reformed Kushiho 9 0-9 5% pre-heated, agile absorption K-charcoalization IS component << other 繩 ¾ 繩 澄 5 It will be decomposed at ~ 10%.

 [Requested Items 1 22

 辍 Oil no kerosene thunder (for dilution) Reformation rate and quality… Distillation property temperature / β oil (density 15 ° C / 0.8 8 5) or less at 2 7 0 / sulfur content 0.05% or less. Kerosene fraction (density 1 5 0. 8 0 0) or less / sulfur content 0.05% or less, 2 8 0 ¾ distillation temperature / degree / soil oil (density 1 5 / 0.8 8 0 or less) / Sulfur content: 0.05% or less Kerosene fraction (Density: 15 ¾no 0.80 0 0) or less / Sulfur content: 0.05% or less 2 9 (TC distillation property temperature / Steam oil (Density: 15) / 0.81 5) or less / sulfur content 0.05% or less, kerosene fraction (density 1 5 ¾ no 0.80 00) or less sulfur content 0.05% or less, (C heavy oil) reforming rate Approximately 90% (smooth oil and demon oil) Reformation rate 9 5% Kerosene (Claim 9) is a characteristic of catalytic distillation reforming of redistillation δ.

 '[Claim 1 3]

 Reformation rate and quality of kerosene »naphtha / gasoline components ... feedstock kerosene fraction (density 15 ° C / 0.880) Kerosene * naphtha in the following cases. Gasoline component reforming rate soil around 90%, raw oil 輕 oil (density 15 ° C / 0.80 0 5) Kerosene * naphtha gasoline component soil around 85%, 油 oil is (claim) 9) has the feature of catalytic distillation reforming of redistillation.

 r Quadrature 1 J,,

 Catalytic distillation equipment ... 1. Catalytic distillation heating device, 2. Distillation fractionation device, 3. Distillation fraction collection device, 4. Distillation gas purification and purification device, 5. Catalytic distillation purification device, 6. Distillation catalyst automatic exchange device 7. Catalyst absorption oil dry distillation recovery device,

8. Catalyst regeneration device (heating furnace) 9. Exhaust gas generated during catalyst regeneration S

0 ₂ -N 0 X · C 02 Special features that make it possible to use waste heat with a compact assembly system composed of a removal device, etc., enable environmental safety without generating industrial waste, and effectively use petroleum of limited resources. Catalytic distillation plant.

 r ¾ seeking term 1 p ；】

Features of the main equipment of the equipment ... 1. Catalytic distillation. Heating device at each distillation property temperature (Claim 2) 1. Features of the catalyst, (Claim 5) 2. Features of the catalyst, bcd e. F. i.j Activation-acting catalytic distillation apparatus for each item, 2. Distillation fractionation apparatus is a distillation fractionation apparatus characterized in that a distillation fraction vaporized in the fractionation process is subjected to primary purification through a catalyst, 3. Distillation fraction recovery device is a device that collects the distillation fraction liquefied after distillation through a catalytic distillation purification device and sends it to the distillation gas purification and purification device. 4. The distillation gas purification and purification device is Harmful gas such as distillative vaporization (hydrocarbon, hydrogen sulfide, nitrogen oxide) and acidic vapor generated by cooling at 0 1 1 0 to remove H ₂ 0, recovery of kerosene fraction in the cooling temperature range At the same time, after passing through the catalyst packed in the distillation gas purification and purification equipment, the low-temperature vaporized gas is absorbed and adsorbed, and then recirculated with the catalyst distillation heating device. A system characterized by re-reaction, a circulation type that does not discharge distilled gas to the outside, a device that features prevention of air pollution and health damage, 6, an automatic distillation catalyst changer is a carbon component Saturated catalyst exchange device that absorbs and absorbs sulfur and other impurities, 7. Catalyst absorption oil dry distillation recovery steam device (Claim 2) (Claim 5) 1. 2. Features of catalyst. Reclaimer (Claim 2) (Claim 5) 1. 2. Features of the catalyst. Contents of the item h. Content of carbon component · Sulfur and other impurities absorption adsorption catalyst

9. Touch ¾ Raw exhaust gas during S regeneration 'N 0 z ° S 0 ₂ . C ◎ ₂ departure (patent garden EI output number PT cz JP / 9 9/2 0 5 1).