WO2006008308A1 - Method for fastening an accessory in a plastic fuel tank - Google Patents
Method for fastening an accessory in a plastic fuel tank Download PDFInfo
- Publication number
- WO2006008308A1 WO2006008308A1 PCT/EP2005/053519 EP2005053519W WO2006008308A1 WO 2006008308 A1 WO2006008308 A1 WO 2006008308A1 EP 2005053519 W EP2005053519 W EP 2005053519W WO 2006008308 A1 WO2006008308 A1 WO 2006008308A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- accessory
- tank
- plastic
- orifice
- moulding
- Prior art date
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 56
- 239000004033 plastic Substances 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000002828 fuel tank Substances 0.000 title claims abstract description 19
- 238000000465 moulding Methods 0.000 claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 229920001903 high density polyethylene Polymers 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000000071 blow moulding Methods 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 7
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 5
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 238000007872 degassing Methods 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 description 22
- 229920001169 thermoplastic Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- -1 polyacetal (and Chemical class 0.000 description 4
- 229920006324 polyoxymethylene Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012768 molten material Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K15/03177—Fuel tanks made of non-metallic material, e.g. plastics, or of a combination of non-metallic and metallic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/20—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor of articles having inserts or reinforcements ; Handling of inserts or reinforcements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/56—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
- B29C65/60—Riveting or staking
- B29C65/606—Riveting or staking the rivets being integral with one of the parts to be joined, i.e. staking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/20—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines
- B29C66/21—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being formed by a single dot or dash or by several dots or dashes, i.e. spot joining or spot welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/53—Joining single elements to tubular articles, hollow articles or bars
- B29C66/532—Joining single elements to the wall of tubular articles, hollow articles or bars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/61—Joining from or joining on the inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81427—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single ridge, e.g. for making a weakening line; comprising a single tooth
- B29C66/81429—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single ridge, e.g. for making a weakening line; comprising a single tooth comprising a single tooth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81431—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single cavity, e.g. a groove
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D22/00—Producing hollow articles
- B29D22/003—Containers for packaging, storing or transporting, e.g. bottles, jars, cans, barrels, tanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/20—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor of articles having inserts or reinforcements ; Handling of inserts or reinforcements
- B29C2049/2008—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor of articles having inserts or reinforcements ; Handling of inserts or reinforcements inside the article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/20—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor of articles having inserts or reinforcements ; Handling of inserts or reinforcements
- B29C2049/2021—Inserts characterised by the material or type
- B29C2049/2034—Attachments, e.g. hooks to hold or hang the blown article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/001—Shaping in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/12—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor of articles having inserts or reinforcements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/26—Component parts, details or accessories; Auxiliary operations
- B29C51/266—Auxiliary operations after the thermoforming operation
- B29C51/267—Two sheets being thermoformed in separate mould parts and joined together while still in the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
- B29C66/723—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered
- B29C66/7234—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being multi-layered comprising a barrier layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81411—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat
- B29C66/81415—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being bevelled
- B29C66/81417—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being bevelled being V-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7172—Fuel tanks, jerry cans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/737—Articles provided with holes, e.g. grids, sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K2015/03328—Arrangements or special measures related to fuel tanks or fuel handling
- B60K2015/03447—Arrangements or special measures related to fuel tanks or fuel handling for improving the sealing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K2015/03328—Arrangements or special measures related to fuel tanks or fuel handling
- B60K2015/03453—Arrangements or special measures related to fuel tanks or fuel handling for fixing or mounting parts of the fuel tank together
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K2015/03486—Fuel tanks characterised by the materials the tank or parts thereof are essentially made from
- B60K2015/03493—Fuel tanks characterised by the materials the tank or parts thereof are essentially made from made of plastics
Definitions
- the present invention relates to a method for fastening an accessory in a plastic fuel tank.
- Fuel tanks on board vehicles of various kinds generally have to meet imperviousness and permeability standards in relation to the type of use for which they are designed and the environmental requirements that they have to satisfy. Both in Europe and throughout the world we are currently experiencing a considerable tightening of the requirements concerned with limiting the emissions of pollutants into the atmosphere and into the environment in general.
- the design of fuel tanks is therefore evolving quickly towards techniques capable of better guaranteeing the imperviousness and safety under varying conditions of use.
- attempts are also being made to minimize the losses originating from the pipes and various accessories associated with the tanks.
- One means sometimes used is to incorporate certain accessories and pipe work within the tanks, thus eliminating their interface with the external surroundings. As a preference, these elements are fixed to the internal wall of the tank and do not pass through it, so as to avoid damaging the barrier layer often present in these tanks and so as to eliminate the risk of leakage associated with recourse to sealing devices.
- Patent Application WO 01/60592 in the name of the applicant company discloses a method of manufacturing a plastic fuel tank from two shells formed by moulding, that are assembled, the moulding of at least one shell being performed by compressing part of a sheet of plastic between a mould and a punch and by blowing the remaining part of the sheet in the region not compressed.
- the advantage of this method is that it allows one or more accessories easily to be included inside the tank, preferably by welding onto the internal face of the tank, for the permeability reasons mentioned hereinbelow.
- This fastening technique is simple but, unfortunately, limited to accessories having at least part of their basic surface made of the same plastic as the tank (generally HDPE) or, at least, of a plastic compatible therewith.
- the invention is based on the idea of benefiting from the fact that a parison is melted during its moulding, and that it can be opened up (i.e. split or made up of two independent parts that can be parted from one another) so that an accessory can be stake-fastened in it.
- This fastening technique is used in application US 5,308,427, but in order to fasten an accessory in an existing (already manufactured) fuel tank that has to be locally heated (using hot gas or the injection of molten material). As the fastening occurs after production, it is not possible to benefit from a local flux of material. In consequence, that technique requires an external addition of material, with the inherent risks of non-homogeneity.
- a multilayer tank typically, made of high density polyethylene (HDPE)
- EVOH a copolymer of ethylene and partially hydrolysed vinyl acetate
- the invention therefore relates to a method for stake-fastening an accessory in a plastic fuel tank, whereby : - the accessory is equipped with at least one orifice which passes right through the accessory;
- the protruding molten plastic is given an appropriate shape to obtain a self- formed plastic rivet, and is left to solidify; the size and shape of the orifice and/or of the solidified plastic being such that the accessory is mechanically fastened to the tank by at least some of the solidified plastic, the stake-fastening of the accessory occurring at the time of manufacture of the tank through the moulding of a split or at least two-part parison.
- fuel tank is intended to denote a sealed tank able to store fuel under diverse and varying environmental and usage conditions.
- An example of this tank is a tank fitted to motor vehicles.
- the fuel tank produced according to the method according to the invention is made of plastic, that is to say of a material comprising at least one synthetic resin polymer.
- plastic may be suitable. Particularly suitable plastics come from the thermoplastics category.
- thermoplastic denotes any thermoplastic polymer, including thermoplastic elastomers, as well as blends thereof.
- polymer denotes both homopolymers and copolymers (especially binary or ternary copolymers). Examples of such copolymers are, non-limitingly, random copolymers, linear block copolymers, other block copolymers and graft copolymers.
- thermoplastic polymer or copolymer whose melting point is below the decomposition temperature is suitable.
- Synthetic thermoplastics that have a melting range spread over at least 10° Celsius are particularly suitable. Examples of such materials include those that exhibit polydispersion in their molecular weight.
- polyolefins thermoplastic polyesters, polyketones, polyamides and copolymers thereof may be used.
- a blend of polymers or copolymers may also be used, as may a blend of polymer materials with inorganic, organic and/or natural fillers such as, for example, but non-limitingly, carbon, salts and other inorganic derivatives, natural fibres or polymeric fibres.
- inorganic, organic and/or natural fillers such as, for example, but non-limitingly, carbon, salts and other inorganic derivatives, natural fibres or polymeric fibres.
- multilayer structures consisting of stacked layers bonded together comprising at least one of the polymers or copolymers described above.
- the tank also comprises a layer of a resin impermeable to the fuel, such as EVOH for example (a copolymer of ethylene and partially hydrolysed vinyl acetate).
- EVOH a copolymer of ethylene and partially hydrolysed vinyl acetate
- Non- limiting examples of such devices are : liquid pumps, level gauges, pipettes, tanks or baffles internal to the fuel tank, ventilation devices, electronic units and stiffening bars.
- the accessory is in actual fact a preassembled structure comprising a support and one or several identical or different devices which are fixed by any suitable fastening means.
- suitable fastening means are clipping, screw- fastening, welding, etc.
- the preassembled structure may bear means that allow additional devices that may be added on later to be attached.
- These means are also clipping devices, tapped holes or threaded protrusions of circular shape to allow screwing, surface regions suited to welding, etc.
- the accessory may consist of a simple support comprising suitable means for the later attachment of one or more devices.
- the accessory comprises a support which is either equipped with fastening means for one or several functional devices of the fuel tank (and which may be the lid of the accessory), or bears one or several such devices directly.
- the orifice used for stake-fastening the accessory is preferably situated on the support.
- the accessory comprises an orifice (hole) which passes right through its wall and allows the "staking” technique to be applied.
- This technique consists in forcing molten plastic through the orifice and causing it to protrude on the opposite side to the entry of said material into the orifice, while at the same time giving the protruding plastic an appropriate shape such that it somewhat “self- forms” a plastic rivet (i.e. it forms the rivet in-situ from molten plastic from the wall of the tank). This shape is generally that of a plateau.
- the orifice may have any shape.
- its cross section in section parallel to the wall of the accessory
- the shape of the cross section (and its variation along a plane perpendicular to the wall of the accessory) will preferably be tailored in such a way as to make it easier to force the material through the orifice, and for this to be done using an appropriate tool (insert).
- the plateau will preferably have a more or less oblong shape (whereas it is generally more or less circular in shape, as, incidentally, is the upper part of the orifice) or semi-oblong shape (if the flow of material through the orifice has been impeded on just one side, something which may be advantageous because the shrinkage is typically greater than the swelling in the presence of petrol), the orifice then preferably also having a more or less oblong shape.
- the tools mentioned hereinabove insert, counterform in the mould
- staking orifices In general, in the method according to the invention, recourse is had to several staking orifices. These are in fact somewhat pinpoint-like, i.e. small in size by comparison with the size of the accessory. Typically, their size is of the order of a few mm (10 mm or less).
- An advantageous embodiment positions the staking orifices, for the oblong or semi-oblong versions, in the direction of the dimensional changes. These changes generally occur along lines which meet at a point located at the centre of the various orifices.
- one way of achieving this is to arrange the said orifices in such a way that the planes normal to the surface of the accessory at the orifices and containing the longitudinal axes thereof intersect along the same axis (i.e. along one and the same straight line which kind of constitutes an axis of symmetry of the accessory).
- the longitudinal axes of the various orifices are in one and the same plane, this amounts to saying that these axes meet at a point more or less at their centre.
- This approach allows the accessory not to be deformed or shifted excessively with respect to the centre of the various orifices.
- the plastic of which the wall of the tank is made at the site intended for fastening the accessory is melted (which means to say in fact that it is truly subjected to fusion in the case of a semicrystalline polymer such as HDPE, but in fact means to say plasticized/softened in the case of amorphous polymers).
- the pasty material is then forced through the orifice of the accessory without detaching from the wall of the tank, and to solidify there.
- the size and shape of the orifice and/or of the solidified plastic are such that the accessory is mechanically fastened to the tank by at least some of the solidified plastic.
- the accessory is fastened by the method according to the invention at the time of manufacture of the tank by moulding. This approach can be achieved in practice by virtue of the fact that moulding takes place starting from a split or at least two-part parison.
- the stake-fastening occurs at the time of moulding of the tank by : • thermoforming sheets;
- the stake- fastening may be performed by a robot which introduces the accessory between the two parts of the mould in which the sheets are inserted and pushes it against these sheets in order to perform the stake-fastening.
- the tooling mentioned hereinabove insert, counterform in the mould
- the robot arm can be incorporated into the robot arm.
- the stake-fastening is preferably performed with the aid of an insert on the mould side (so as to force the material through the orifice) and a counterform actuated by a ram on the core side (so as to deform the material which has protruded through the orifice).
- a method of manufacturing the tank and of fastening the accessory by blow-moulding in a mould comprising a core and a moulding cavity) which uses such accessories generally runs as follows :
- the moulding cavities of the mould are advantageously provided with a heat regulating device that allows this region to be heated during the steps involved with the initial closing of the mould.
- a heat regulating device is described for example in application FR 04.13407 in the name of the applicant company, the content of which for this purpose is incorporated by reference into this application.
- the insert preferably bears a protrusion in the shape of a spike making an angle preferably of between 30 and 60°, or even 40 and 50°, and ideally of about 45°, thus encouraging the material of which the wall is made to flow through the orifice.
- Any abrupt transition in angle may be provided with a rounded radius so as to optimize the flow during the staking phase while at the same time preventing the barrier layer of the tank, if there is one, from rupturing.
- the counterform preferably applies pressure via the hydraulic ram not only to the accessory itself but also at least partially to the molten plastic of the wall of the tank surrounding the accessory to encourage its compaction.
- the present invention also relates to a plastic fuel tank equipped with at least one (support for) accessory in direct contact with part of the wall of the tank and being equipped with several orifices of more or less oblong shape in which and over which plastic identical to that of the wall of the tank is present, these orifices being arranged in such a way that the planes normal to the surface of the accessory at the orifices and comprising the longitudinal axes of the latter intersect on one and the same axis.
- the accessory may be based on a material different from the wall of the tank.
- the accessory is based on at least one material compatible or compatibilized with that of the wall of the tank (for example PA compatibilized with HDPE in particular by a suitable surface treatment or alternatively by overmoulding with an adhesive), which allows a strengthened mechanical fastening and imperviousness through chemical bonding between the two materials when the accessory comes into contact with the molten material of the tank to be fastened to the latter.
- the accessory may be made of two materials, one offering dimensional stability and the other permitting adhesion between the accessory and the wall of the tank.
- an accessory made of a material other than HDPE for example made of POM
- Figures 1 to 4 are to illustrate certain concrete aspects of the invention without in any way wishing to limit its scope.
- Figures 1 and 2 each depict a section (on a plane perpendicular to the surface of the tank at this point) through a tank to which an accessory is in the process of being stake-iastened, the said tank being in the process of being manufactured by moulding but the section confining itself to the vicinity of a staking point of given geometry.
- Figures 3 and 4 depict a view of the internal surface of the finished tank (bearing the accessory) seen in section (on planes 1- r and 2-2' respectively) of Figures 1 and 2.
- Figures 1 and 2 depict a fraction of the wall of a fuel tank (1) comprising two layers of HDPE (2,2') one on each side of a layer of EVOH (3), the said tank being in the process of being manufactured by moulding a two-part parison.
- An accessory (4) equipped with at least one orifice (5) is in the process of being stake-iastened to this wall (1).
- Constituent material of the wall of the tank (1) has been forced through this orifice (5) by means of an insert (6) fixed in the mould and has been deformed on the inside of the tank by a counterform (7) operated by a ram (not depicted but acting in the direction of the arrow) so as to form a kind of plateau (8) which overhangs the orifice (5) and prevents the accessory (4) from being removed without tearing/destroying the plateau (8).
- the plateau (8) has dimensions tailored to the desired mechanical strength for the fastening of the accessory before and after contact with a fuel.
- the insert (6) and the counterform (7) are cooled in order to accelerate the setting of the molten plastic around the orifice (5).
- the insert (6) bears a protrusion in the shape of a spike making an angle of about 45° (see Figure 1), encouraging the constituent material of the wall (1) to flow through the orifice (5).
- the abrupt transitions in angle have been given a rounded radius to optimize the flow during the stake-fastening phase while at the same time avoiding rupturing the layer of EVOH.
- the plateau (8) is circular and plastic occupies the entire orifice (5).
- the circular plateau (8) has been deformed (rendered oblong) by an appropriate relief (9) on the counterform (7), this being so as to absorb the dimensional changes introduced by shrinkage during cooling of the tank and expansion by swelling upon contact with the fuel.
- the counterform (7) has been designed to overhang the accessory (4) (see part (10) in the figure) and press against the wall of the tank (1) in the vicinity of the accessory (4). This approach makes it possible to increase the internal pressure at the plateau (8) and therefore improve the compacting in the plateau (8).
- FIGs 3 and 4 The respective shapes of the plateaus (8) in the two cases are illustrated in Figures 3 and 4 respectively, in an overall view of the interior surface of the tank bearing the accessory.
- the orifice (5) which is not visible, is circular and in Figure 4, the orifice is oblong.
- the accessory (4) illustrated in these figures comprises a support (4') which allows for ease of staking (illustrated in the form of 3 -point staking in these figures) and the accessory proper (4") secured to it. It can be seen in Figure 4 that the axes (see dotted lines) of the oblong orifices (5) meet at the centre of the support of the accessory (4') which is more or less flat.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Transportation (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Cooling, Air Intake And Gas Exhaust, And Fuel Tank Arrangements In Propulsion Units (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007521950A JP5026265B2 (en) | 2004-07-23 | 2005-07-20 | How to connect accessories to a plastic fuel tank |
DE602005012275T DE602005012275D1 (en) | 2004-07-23 | 2005-07-20 | Method for fixing an accessory in a plastic fuel container |
KR1020077001670A KR101199271B1 (en) | 2004-07-23 | 2005-07-20 | Method for fastening an accessory in a plastic fuel tank |
US11/658,085 US8591798B2 (en) | 2004-07-23 | 2005-07-20 | Method for fastening an accesory in a plastic fuel tank |
BRPI0513687A BRPI0513687B1 (en) | 2004-07-23 | 2005-07-20 | method for punching an attachment to a plastic fuel tank and a plastic fuel tank |
EP05764640A EP1773570B1 (en) | 2004-07-23 | 2005-07-20 | Method for fastening an accessory in a plastic fuel tank |
US14/043,983 US9399326B2 (en) | 2004-07-23 | 2013-10-02 | Method for fastening an accessory in a plastic fuel tank |
US14/070,767 US9399327B2 (en) | 2004-07-23 | 2013-11-04 | Method for fastening an accessory in a plastic fuel tank |
US15/206,527 US20170008391A1 (en) | 2004-07-23 | 2016-07-11 | Method for fastening an accessory in a plastic fuel tank |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0408196 | 2004-07-23 | ||
FR0408196A FR2873321B1 (en) | 2004-07-23 | 2004-07-23 | METHOD FOR FIXING AN ACCESSORY IN A FUEL TANK OF PLASTIC MATERIAL |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/658,085 A-371-Of-International US8591798B2 (en) | 2004-07-23 | 2005-07-20 | Method for fastening an accesory in a plastic fuel tank |
US14/043,983 Continuation US9399326B2 (en) | 2004-07-23 | 2013-10-02 | Method for fastening an accessory in a plastic fuel tank |
US14/070,767 Continuation US9399327B2 (en) | 2004-07-23 | 2013-11-04 | Method for fastening an accessory in a plastic fuel tank |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006008308A1 true WO2006008308A1 (en) | 2006-01-26 |
Family
ID=34950833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/053519 WO2006008308A1 (en) | 2004-07-23 | 2005-07-20 | Method for fastening an accessory in a plastic fuel tank |
Country Status (10)
Country | Link |
---|---|
US (4) | US8591798B2 (en) |
EP (1) | EP1773570B1 (en) |
JP (1) | JP5026265B2 (en) |
KR (1) | KR101199271B1 (en) |
CN (1) | CN100569489C (en) |
AT (1) | ATE419971T1 (en) |
BR (1) | BRPI0513687B1 (en) |
DE (1) | DE602005012275D1 (en) |
FR (1) | FR2873321B1 (en) |
WO (1) | WO2006008308A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
CN100569489C (en) | 2009-12-16 |
KR101199271B1 (en) | 2012-11-09 |
FR2873321A1 (en) | 2006-01-27 |
BRPI0513687A (en) | 2008-05-20 |
US8591798B2 (en) | 2013-11-26 |
US9399327B2 (en) | 2016-07-26 |
KR20070034072A (en) | 2007-03-27 |
US20170008391A1 (en) | 2017-01-12 |
US9399326B2 (en) | 2016-07-26 |
CN1988994A (en) | 2007-06-27 |
JP5026265B2 (en) | 2012-09-12 |
EP1773570B1 (en) | 2009-01-07 |
EP1773570A1 (en) | 2007-04-18 |
US20140131918A1 (en) | 2014-05-15 |
US20140034649A1 (en) | 2014-02-06 |
DE602005012275D1 (en) | 2009-02-26 |
FR2873321B1 (en) | 2008-05-09 |
BRPI0513687B1 (en) | 2015-12-01 |
JP2008507651A (en) | 2008-03-13 |
ATE419971T1 (en) | 2009-01-15 |
US20080164639A1 (en) | 2008-07-10 |
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