WO2005123827A1 - Modified polypropylene composition - Google Patents
Modified polypropylene composition Download PDFInfo
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- WO2005123827A1 WO2005123827A1 PCT/EP2005/006535 EP2005006535W WO2005123827A1 WO 2005123827 A1 WO2005123827 A1 WO 2005123827A1 EP 2005006535 W EP2005006535 W EP 2005006535W WO 2005123827 A1 WO2005123827 A1 WO 2005123827A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/363—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using non-actuated dynamic mixing devices
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
Definitions
- the invention relates to novel modified polypropylene compositions, especially for automobile exterior applications. More particularly, the invention relates to modified polypropylene compositions comprising a heterophasic propylene copolymer, a further elastomeric copolymer and an inorganic filler.
- the modified composition has excellent properties, especially impact strength, stiffness, elasticity and surface stability.
- compositions or the injection moulded parts produced therefrom have to fulfill the following requirements simultaneously: High impact strength, high stiffness, high elasticity, high surface stability.
- an average failure length which is determined by injection moulding the composition into a test specimen having the dimensions of 150 x 80 x 2 mm, creating surface defects by directing a water jet (76 bar; 60 °C, flat spray nozzle V ⁇ PMEG 2506) from a distance of 8 cm (from nozzle to specimen surface) at the specimen surface at three different locations at a distance of 6 cm from each location and for 60 sec each, measuring the length of each surface defect and calculating the average value of the three locations, of ⁇ 10 mm.
- AFL average failure length
- the new compositions shall be used for injection moulding.
- the MFR of the compositions shall not exceed 15 g/10 min, preferred are MFR-values of ⁇ 8 g/10 min.
- a Charpy notched impact strength according to ISO 179/1eA at +23 °C of ⁇ 55.0 kJ/m 2 , better of ⁇ 60 kJ/m 2 and, still better, of ⁇ 65.0 kJ/m 2 is considered as "high impact strength”.
- Minimum values for the Charpy notched impact strength according to ISO 179/1eA at -20 °C are ⁇ 7.0 kJ/m 2 , better > 8.0 kJ/m 2 and still better, > 8.5 kJ/m 2 .
- Stiffness is considered to be high with tensile moduli according to ISO 527-3 of > 1200 MPa. Still higher values are of course more preferable.
- Elasticity is considered to be high when elongation at break according to ISO 527-3 is > 80 %, preferably ⁇ 100 %.
- the surface stability of injection moulded parts is considered to be high, when the average failure length (AFL), determined according to the procedure described in the experimental section, is ⁇ 10 mm, preferably ⁇ 8 mm. Still more preferred are AFL values ⁇ 5 mm.
- polypropylene compositions containing the components A, B and C which are then modified using specific organic peroxides will result in new polypropylene compositions where the previous property profile regarding impact strength, stiffness and elasticity is largely retained, but where also a sudden increase in surface stability is observed.
- the new polypropylene compositions are characterised by simultaneous high levels of impact strength, stiffness, elasticity and surface stability.
- the high surface stability is believed to be due to an improved adhesion between matrix phase and disperse phase.
- the new polypropylene compositions are obtained by treating compositions containing the components A, B and C with specific organic peroxides.
- the matrix phase of the heterophasic propylene copolymer comprises a propylene homopolymer.
- the matrix phase is present in an amount of 60 - 90 wt%, preferably 70 - 20 wt%, based on the total amount of heterophasic propylene copolymer.
- the homopolymer part of the heterophasic propylene copolymer preferably has an isotacticity IR ⁇ of > 0.970, preferably 0.970 - 0.995.
- IR ⁇ of a propylene polymer is determined by Infrared spectroscopy and calculated as described in EP 0 277 514 A2 on page 3 (especially column 3, line 37 to column 4, line 30) and page 5 (column 7, line 53 to column 8, line 11 ).
- the elastomeric copolymer which comprises the disperse phase of the heterophasic copolymer and which also comprises - together with the further elastomeric copolymer - a disperse phase of the entire composition is present in an amount of from 10 - 40 wt%, preferably 20 - 30 wt%, based on the total amount of heterophasic propylene copolymer.
- the elastomeric copolymer is comprised of from 20 - 55 wt% preferably 30 - 50 wt% of ethylene and 80 - 45 wt% preferably 70 - 50 wt% of one or more C 3 -C 8 ⁇ -olefins.
- the ⁇ - olefin is preferably selected from the list of propylene, 1 -butene, 1 -pentene, 4-methyl-1- pentene, 1-hexene, 1 -heptene and 1-octene, where propylene, 1-butene and 1 -octene are particularly preferred.
- a further elastomeric copolymer is present in an amount of from 1 - 30 parts per weight .
- the further elastomeric copolymer comprises an ethylene- ⁇ -olefin elastomer, which comprises more than 65 wt% of ethylene and up to 35 wt% of one or more C 3 -C 8 ⁇ - olefins.
- the ⁇ -olefin is preferably selected from the list of propylene, 1 -butene, 1 -pentene, 4-methyl-1 -pentene, 1 -hexene, 1-heptene and 1 - octene, where propylene, 1-butene and 1-octene are particularly preferred.
- the polypropylene composition comprises 3 - 25 parts per weight of an inorganic filler.
- Preferred as inorganic filler are talc, mica, wollastonite and chalk.
- the polypropylene composition comprises 5 - 20 parts per weight of inorganic filler.
- Inorganic filler can be added to the composition before and/or during the modification with the organic peroxides. It is preferred to add at least a substantial amount, e.g. at least about 50 %, of the inorganic filler before and/or during the modification treatment. It is particularly preferred to add the entire amount of inorganic filler before and/or during the modification treatment.
- the polypropylene composition comprises A) 75 - 85 parts per weight of the heterophasic propylene copolymer, B) 5 - 15 parts per weight of the further elastomeric copolymer and C) 5 - 20 parts per weight of the inorganic filler.
- a particularly advantageous property profile is achievable with the above composition, i.e. with the above concentrations of heterophasic and further elastomeric copolymer and when the entire amount of filler is added to the composition before/during the modfication treatment.
- the polypropylene composition comprises from 0.01 to 10 parts per weight based on the weight of the polypropylene composition of a chemically bound bifunctionally unsaturated monomer and/or multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol. synthesised from one and/or more unsaturated monomers.
- Bifunctionally or multifunctionally unsaturated as used above means the presence of two or more non-aromatic double bonds, as in e.g. divinylbenzene or cyclopentadiene or polybutadiene. Only such bi- or multifunctionally unsaturated compounds are used which can be polymerised with the aid of free radicals. The unsaturated sites in the bi- or multifunctionally unsaturated compounds are in their chemically bound state not actually "unsaturated", because the double bonds are each used for a covalent bond to the polymer chains of the matrix polymer and/or the elastomeric copolymer.
- Reaction of the bifunctionally unsaturated monomer and/or multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol, synthesised from one and/or more unsaturated monomers with the heterophasic polymer may be performed in the presence of a free radical forming agent, e.g. a thermally decomposable peroxide, ionising radiation or microwave radiation.
- a free radical forming agent e.g. a thermally decomposable peroxide, ionising radiation or microwave radiation.
- the bifunctionally unsaturated monomers may be divinyl compounds, such as divinylaniline, m-divinylbenzene, p-divinylbenzene, divinylpentane and divinylpropane; allyl compounds, such as allyl acrylate, allyl methacrylate, allyl methyl maleate and allyl vinyl ether; dienes, such as 1 ,3-butadiene, chloroprene, cyclohexadiene, cyclopentadiene, 2,3-dimethylbutadiene, heptadiene, hexadiene, isoprene and 1 ,4-pentadiene; aromatic and/or aliphatic bis(maleimide) and bis(citraconimide) compounds and mixtures of these unsaturated monomers.
- divinyl compounds such as divinylaniline, m-divinylbenzene, p-divinylbenzene, divinylp
- the multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol may be synthesised from one ore more unsaturated monomers.
- low molecular weight polymers are - polybutadienes, especially where the different microstructures in the polymer chain, i.e. 1 ,4-cis, 1 ,4-trans and 1 ,2-(vinyl) configuration are predominantly in the 1 ,2-(vinyl) configuration - copolymers of butadiene and styrene having 1 ,2-(vinyl) configuration in the polymer chain.
- the chemically bound bifunctionally unsaturated monomer and/or multifunctionally unsaturated low molecular weight polymer act as coupling agent between the matrix polymer and the elastomeric copolymers of the disperse phase. It is believed that those molecules, which - with one of their functionalities - are bound to a polymer molecule of the matrix polymer and - with their second or one of their further functionalities - are bound to a polymer molecule belonging to the disperse phase, effect the coupling action and thus promote dispersion of the elastomeric copolymers within the matrix phase.
- Preferred bifunctionally unsaturated monomers are 1 ,3-butadiene, isoprene, dimethyl butadiene and divinylbenzene.
- Preferred low molecular weight polymer is polybutadiene, in particular a polybutadiene having more than 50 wt% of the butadiene in the 1 ,2-(vinyl) configuration.
- the polypropylene composition may contain more than one bifunctionally unsaturated monomer and/or low molecular weight polymer.
- the modified polypropylene composition of the invention contains from 0.1 to 3 wt% based on the weight of the composition of a chemically bound bifunctionally unsaturated monomer and/or multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol.
- the polypropylene composition contains at least 0.1 wt% of the bifunctionally unsaturated monomer and/or multifunctionally unsaturated polymer.
- the modified polypropylene composition contains not more than 3 parts per weight of the bifunctionally unsaturated monomer and/or multifunctionally unsaturated polymer.
- a further object is a method for producing the polypropylene compositions of the invention.
- the polypropylene compositions are prepared by homogenising an educt mixture comprising A) 70 - 99 parts per weight of a heterophasic propylene copolymer comprising 60 - 90 wt% of a matrix phase comprising a propylene homopolymer having an isotacticity IR ⁇ ⁇ 0.970, and 10 - 40 wt% of an elastomeric copolymer comprising 20 - 55 wt% of ethylene and 80 - 45 wt% of one or more C 3 -C 8 ⁇ -olefins, B) 1 -30 parts per weight of a further elastomeric copolymer comprising an ethylene- ⁇ -olefin elastomer, with more than 65 wt% of ethylene and up to 35 wt% of one or more C 3 -C 8 ⁇ -olefins, C) 3 - 25 parts per weight of an inorganic filler, and D) 0.05 -
- Peroxides which are thermally decomposable upon the conditions of heating and melting the polymer/peroxide mixture and which meet the requirement of having a half life time t(1/2) at 110 °C of > 6 min and a half life time t(1/2) at 150 °C of ⁇ 6 min are suitable.
- the following organic peroxides are suitable for the above process:
- Dibenzoyl peroxide tert-Butyl peroxy-2-ethylhexanoate, tert-Amyl peroxy-2- ethylhexanoate, tert-Butyl peroxydiethylacetate, 1 ,4-Di(tert-butylperoxycarbo)cyclohexane, tert-Butyl peroxyisobutyrate, 1 ,1 -Di(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane, Methyl isobutyl ketone peroxide, 2,2-Di(4,4-di(tert-butylperoxy)cyclohexyl)propane, 1 ,1-Di(tert- butylperoxy)cyclohexane, tert-Butyl peroxy-3,5,5-trimethylhexanoate, tert-Amylperoxy 2- ethylhexyl carbon
- peroxides used in conventional degradation processes exert different modes of action.
- One effect is, that the peroxides effect a breakage of the longest chains of the polymer molecules and, consequently, a corresponding decrease in viscosity of the polymer.
- a second effect is, that peroxide-induced radicals are recombining. Both effects are to a certain extent always present in peroxide induced degradation processes. The actual extent of each effect is influenced by the nature of the peroxide.
- the employed peroxides are of the above mentioned type and are selected from tert-butylperoxy isopropyl carbonate and tert-butyl peroxybenzoate.
- homogenisation usually takes from 5 to 60 seconds.
- melt After homogenisation the melt is heated to 220 - 250 °C, in order to completely deactivate any remaining peroxide, to remove and deactivate any still unreacted compounds, e.g. radicals, and to remove decomposition products .
- the educt mixture further comprises 0.01 - 10 parts per weight of bifunctionally unsaturated monomers and/or multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol.
- the polypropylene composition is prepared by mixing A) 70 - 99 parts per weight of a heterophasic propylene copolymer comprising 60 - 90 wt% of a matrix phase comprising a propylene homopolymer having an isotacticity IR ⁇ ⁇ 0.970, and 10 - 40 wt% of an elastomeric copolymer comprising 20 - 55 wt% of ethylene and 80 - 45 wt% of one or more C 3 -C 8 ⁇ -olefins, with B) 1 -30 parts per weight of a further elastomeric copolymer comprising an ethylene- ⁇ -olefin elastomer, with more than 65 wt% of ethylene and up to 35 wt% of one or more C 3 -C 8 ⁇ -olefins, and C) 3 - 25 parts per weight of an inorganic filler, and heating and melting the mixture, preferably in
- the polymers A and B and the filler C may be premixed before they are dosed into the extruder. Alternatively, they may be dosed separately into the extruder.
- the polypropylene compositions can also be prepared by dosing the polymer components
- a melt mixing device preferably an extruder
- This particular embodiment has the advantage, that the filler can be better dispersed in the polymer, because it is added into the melt. This requires less energy for homogeneously distributing the filler.
- unsaturated monomers and/or polymers are used in one of the latter two procedures, it is preferred to add 0.01 - 10 parts per weight of bifunctionally unsaturated monomers and/or multifunctionally unsaturated low molecular weight polymer having a molecular weight M n ⁇ 10000 g/mol into the polymer melt together with the addition of the peroxide and/or during the homogenising step.
- any unsaturated compounds are added before the homogenisation step is completed and before the melt is heated to 220-250 °C for removing unreacted compounds and decomposition products.
- the polypropylene compositions are produced by dosing the polymer components
- a melt mixing device preferably an extruder, heating and melting the mixture, adding C) 3 - 25 parts per weight of an inorganic filler into the melt, homogenising and heating the melt to 220 - 250 °C to remove unreacted compounds and decomposition products, cooling and pelletising.
- the unsaturated monomer and/or polymer is added into the polymer melt, it is preferably solvatised in an organic solvent, e.g. acetone, and the solution is injected into the polymermelt, e.g. into the extruder.
- an organic solvent e.g. acetone
- the unsaturated monomer and/or polymer if for example in a liquid state, are absorbed in a polymer powder and are then added into the polymer melt in form of solid pellets.
- the bifunctionally unsaturated monomer if for example in a gaseous state, can be directly injected into the polymer melt without the aid of a solvent.
- the bifunctionally unsaturated monomer can be applied as mixture with inert gases, e.g. nitrogen.
- the educt heterophasic copolymer may be produced by multistage process polymerisation of propylene and ethylene and/or an ⁇ -olefin such as bulk polymerisation, gas phase polymerisation, slurry polymerisation, solution polymerisation or combinations thereof using conventional catalysts. Those processes are well known to one skilled in the art.
- a preferred process is a combination of a bulk slurry loop reactor(s) and gas phase reactor(s).
- the matrix polymer can be made either in loop reactors or in a combination of loop and gas phase reactor.
- the polymer produced in this way is transferred into another reactor and the disperse phase, an ethylene/ ⁇ -olefin rubber, is polymerised.
- this polymerisation step is done in a gas phase polymerisation.
- a suitable catalyst for the polymerisation of the educt heterophasic propylene copolymer is any stereospecific catalyst for propylene polymerisation which is capable of polymerising and copolymerising propylene and comonomers at a temperature of 40 to 110 °C and at a pressure form 10 to 100 bar.
- Ziegler Natta catalysts as well as metallocene catalysts are suitable catalysts.
- the educt heterophasic polyolefin composition may also be produced by mixing and melt blending a propylene homopolymer with an ethylene rubber copolymer.
- An ethylene ⁇ -olefin elastomeric copolymer may be produced by known polymerisation processes such as solution, suspension and gas-phase polymerisation using conventional catalysts. Ziegler Natta catalysts as well as metallocene catalysts are suitable catalysts.
- a widely used process is the solution polymerisation.
- Ethylene, ⁇ -olefin and catalyst systems are polymerised in an excess of hydrocarbon solvent.
- Stabilisers and oils, if used, are added directly after polymerisation.
- the solvent and unreacted monomers are then flashed off with hot water or steam, or with mechanical devolatilisation.
- the polymer, which is in crumb form, is dried with dewatering in screens, mechanical presses or drying ovens.
- the crumb is formed into wrapped bales or extruded into pellets.
- the suspension polymerisation process is a modification of bulk polymerisation.
- the monomers and catalyst system are injected into the reactor filled with ⁇ -olefin.
- the polymerisation takes place immediately, forming crumbs of polymer that are not soluble in the ⁇ -olefin. Flashing off the ⁇ -olefin and comonomer completes the polymerisation process.
- the gas-phase polymerisation technology consists of one or more vertical fluidised beds. Monomers and nitrogen in gas form along with catalyst are fed to the reactor and solid product is removed periodically. Heat of reaction is removed through the use of the circulating gas that also serves to fluidise the polymer bed. Solvents are not used, thereby eliminating the need for solvent stripping, washing and drying.
- the melt flow rates were measured with a load of 2.16 kg at 230 °C.
- the melt flow rate is that quantity of polymer in grams which the test apparatus standardized to ISO 1133 extrudes within 10 minutes at a temperature of 230 °C under a load of 2.16 kg.
- Tensile test was performed according to ISO 527-3 using injection moulded specimens as described in EN ISO 1873-2 (dog bone shape, 3 mm thickness).
- the Charpy notched impact strength was determined according to ISO 179 / 1 eA at 23 °C and at -20 °C by using injection moulded test specimens as described in EN ISO 1873-2 (80 x 10 x 4 mm).
- AFL was determined by injection moulding the composition into a test specimen having the dimensions of 150 x 80 x 2 mm, creating surface defects by directing a water jet (76 bar; 60 °C, flat spray nozzle V PMEG 2506, opening angle 25°) using the high pressure cleaner system Limex Ehrle HDE600 - 24kW with nozzle PMEG 2506) from a distance of 8 cm (from nozzle to specimen surface) perpendicularly at the specimen surface at three different locations at a distance of 6 cm from each location and for 60 sec each. The length of each surface defect was measured and average value of the three locations calculated. Nozzles of the above used type are standardised and are available from e.g. Spraying Systems Austria GmbH. Examples
- Filler C Talc A7, commercially available from Lucenac with the particle size distribution according to Sedigraph 5100 of 2.1 ⁇ m by d50 and 6.5 ⁇ m by d95
- Examples 2 and 3 were prepared analogously to E1 , but using different amounts of peroxide.
- the concentrations of peroxide in the polymer mixture are given in table 1.
- CE1 was prepared analogously to E1 , except that no peroxide was injected into the polymer melt.
- the properties of CE1 therefore are those of the unmodified composition.
- Comparative Example 2 (CE2) CE2 was prepared analogously to E1 , except that a solution of 2,5-dimethyl-2,5di(tert- butylperoxy)hexane (peroxide 2 in table 1 ) in acetone (10 wt%) was injected directly into zone 4 of the extruder, achieving a concentration of 0.07 % by weight, based on the mixture.
- CE3 was prepared analogously to E2, except that the entire amount of talc was added after the modification treatment was finished.
- CE4 was prepared analogously to E2, except that no Polymer B was used.
- CE5 was prepared analogously to E2, except that the entire amount of Polymer B was added after the modification treatment was finished.
- CE6 was prepared analougously to CE2, except that a different amount of peroxide 2 was used and except that immediately after injection of the peroxide 2, butadiene as bifunctionally unsaturated monomer was injected into the same zone 4 of the extruder, through a second injection port.
- concentration of peroxide 2 in the polymer mixture is given in table 1.
- Examples 4 to 6 were prepared analogously to Examples 1 to 3, except that immediately after injection of the peroxide, butadiene as bifunctionally unsaturated monomer was injected into the same zone 4 of the extruder, through a second injection port.
- the amount of the injected butadiene was chosen to result in a concentration of 0.15 wt% based on the total weight of the modified composition of chemically bound butadiene.
- Example 7 was prepared analogously to Example 5 except that 1 ,2-polybutadiene as multifunctionally oligomer was injected into zone 4 of the extruder, through a second injection port.
- the 1 ,2-polybutadiene which is used in E7 is commercially available from Sartomer under the grade name Krasol LB2000. It has 65 wt% of the butadiene units in the 1 ,2-vinyl configuration and a molecular weight M n of 2100g/mol.
- Example 8 was prepared analogously to Example 5, except that 1 ,1'-(methylenedi- 4,1-phenylene)bismaleimide as monomer was added in powder form into zone 4 of the extruder using the side feeder.
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/629,945 US7649046B2 (en) | 2004-06-18 | 2005-06-17 | Modified polypropylene composition |
AU2005254685A AU2005254685B2 (en) | 2004-06-18 | 2005-06-17 | Modified polypropylene composition |
EP05757215.8A EP1781736B1 (en) | 2004-06-18 | 2005-06-17 | Modified polypropylene composition |
EA200700061A EA010287B1 (en) | 2004-06-18 | 2005-06-17 | A modified polypropylene composition and a method for producing thereof |
BRPI0512119A BRPI0512119B1 (en) | 2004-06-18 | 2005-06-17 | polypropylene composition and method for producing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP04102801A EP1607440A1 (en) | 2004-06-18 | 2004-06-18 | Modified polypropylene composition |
EP04102801.0 | 2004-06-18 |
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WO2005123827A1 true WO2005123827A1 (en) | 2005-12-29 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/EP2005/006535 WO2005123827A1 (en) | 2004-06-18 | 2005-06-17 | Modified polypropylene composition |
Country Status (8)
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US (1) | US7649046B2 (en) |
EP (2) | EP1607440A1 (en) |
KR (1) | KR100826822B1 (en) |
CN (1) | CN100567386C (en) |
AU (1) | AU2005254685B2 (en) |
BR (1) | BRPI0512119B1 (en) |
EA (1) | EA010287B1 (en) |
WO (1) | WO2005123827A1 (en) |
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RU2506287C2 (en) * | 2009-05-07 | 2014-02-10 | Бореалис Аг | Thermoplastic polyolefin compounds having low sensitivity to flame treatment |
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Also Published As
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US7649046B2 (en) | 2010-01-19 |
BRPI0512119A (en) | 2008-02-06 |
US20080287597A1 (en) | 2008-11-20 |
CN100567386C (en) | 2009-12-09 |
EP1607440A1 (en) | 2005-12-21 |
BRPI0512119B1 (en) | 2016-03-15 |
EA010287B1 (en) | 2008-08-29 |
KR20070051841A (en) | 2007-05-18 |
CN1989198A (en) | 2007-06-27 |
EA200700061A1 (en) | 2007-06-29 |
EP1781736B1 (en) | 2014-01-01 |
AU2005254685B2 (en) | 2008-10-09 |
AU2005254685A1 (en) | 2005-12-29 |
EP1781736A1 (en) | 2007-05-09 |
KR100826822B1 (en) | 2008-05-06 |
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