WO2005116089A1 - Light emitting apparatus and method for curing inks, coatings and adhesives - Google Patents

Light emitting apparatus and method for curing inks, coatings and adhesives Download PDF

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Publication number
WO2005116089A1
WO2005116089A1 PCT/US2004/001594 US2004001594W WO2005116089A1 WO 2005116089 A1 WO2005116089 A1 WO 2005116089A1 US 2004001594 W US2004001594 W US 2004001594W WO 2005116089 A1 WO2005116089 A1 WO 2005116089A1
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WO
WIPO (PCT)
Prior art keywords
led assemblies
panel
row
led
assemblies
Prior art date
Application number
PCT/US2004/001594
Other languages
French (fr)
Inventor
Stephen B. Siegel
Original Assignee
Con-Trol-Cure, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Con-Trol-Cure, Inc. filed Critical Con-Trol-Cure, Inc.
Priority to EP04704792A priority Critical patent/EP1706432A4/en
Priority to PCT/US2004/001594 priority patent/WO2005116089A1/en
Priority to CNA2004800407879A priority patent/CN1910206A/en
Priority to CA002553521A priority patent/CA2553521A1/en
Publication of WO2005116089A1 publication Critical patent/WO2005116089A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B41J11/002Curing or drying the ink on the copy materials, e.g. by heating or irradiating
    • B41J11/0021Curing or drying the ink on the copy materials, e.g. by heating or irradiating using irradiation
    • B41J11/00214Curing or drying the ink on the copy materials, e.g. by heating or irradiating using irradiation using UV radiation

Definitions

  • the present invention relates to a method and apparatus for utilizing ultraviolet (UV) light emitting diodes in staggered arrays and mechanisms for moving the arrays to avoid "hot spots" and provide a uniform application of ultraviolet light to a moving object including inks, coatings or adhesives having UV photo initiators for converting, when exposed to UV light, monomers in the inks, coatings or adhesives to linking polymers to solidify the monomer material. Also, an inert, non-oxygen, gas is injected into the area where the staggered arrays of ultraviolet light emitting diodes, UV-LED's are positioned to apply UV light to the moving objects to enhance the curing of the ultraviolet activated UV photo initiators.
  • UV ultraviolet
  • UV lamps have been used for the curing of ultraviolet inks, coatings and adhesives. More recently, EXFO and EFOS of Mississauga, Ontario, Canada have developed UV light emitting diodes (LED's) and gathered them in large numbers for use in curing ultraviolet light sensitive monomers to polymerize the monomers and solidify the ink, coating or adhesive. While the use of a large number of UV-LED's provide many efficiencies, namely in cost and energy consumption, there is still the problem of effective curing with low intensity UV-LED's and with respect to "hot spots” which provide more curing at "hot spots” then at other locations in the ink, coating or adhesive being cured.
  • LED's UV light emitting diodes
  • the LED is positioned to achieve uniformity for back light displays and other lighting applications.
  • the criteria for such uniformity are primarily designed to create an appearance that the backlight is uniform for a visual appearance. It is, therefore, desirable to provide an improved UV method and apparatus for applying UV light emitted from UV LED's more uniformly and avoid hot spots to more effectively cure UV inks, coatings and adhesives.
  • the method and device of the present invention provide techniques and structures for applying UV light emitted from UV-LED's more uniformly so that such light is more effective in curing inks, coatings and adhesives and, by applying the UV light more evenly, reducing, if not all together eliminating, "hot spots".
  • staggered arrays of UV LED assemblies on a panel with the UV LED assemblies being arranged in rows with each row being staggered from adjacent rows.
  • a UV curable product, article or other object having a UV ink, coating or adhesive to be cured is moved on or in a web past, and closely adjacent, the arrays. Further, the panel is moved or translated in an X direction and in a Y direction, much like an orbital sander, thereby to cause a slight sweeping of the light from each UV LED assembly over an orbital area, e.g., in a circular or elliptical pattern, thereby minimizing the creation of "hot spots" and to uniformly apply UV light to the product, article or other object having the UV ink, coating or adhesive.
  • the web containing the UV curable product, article or other object to be cured is arranged to move vertically.
  • a gas having a molecular weight heavier than air can be injected at the upper end of the path of movement of the UV curable product, article or other object having a UV ink, coating, or adhesive thereon as it moves past a panel of arrays of UV LED assemblies.
  • a gas having a molecular weight lighter than air can be injected at the lower end of the path of movement of the UV curable product, article or other object having a UV ink, coating or adhesive thereon as it moves past the panel of arrays of UV LED assemblies.
  • the method and apparatus of the present invention provide uniformity of light application from a flat panel having an array of UV-LED's.
  • This result is obtained when the product and/or the light fixture is moved relative to and across the UV light beams from the UV-LED assemblies.
  • This movement in of itself has the ability to offer one element of uniformity. That is, the movement of the product or the movement of the light array addresses the problem of providing uniformity in the direction of the product flow or of the lamp movement.
  • the "X Axis” uniformity is addressed by the movement of the product or of the LED array.
  • the "Y Axis” uniformity is addressed by how the LED chips are arranged. To achieve the cure rates that are associated with typical UV curing applications, a very large number of UV-LED chips are arranged to deliver, the amount of UV energy necessary to cure the polymers.
  • the first step in building these arrays is to create either a series or parallel electrical circuit either in series or in which the LED chips are placed in a linear fashion of equal distance from each other. (Lets say a distance of X).
  • the second row would start its row at a distance '/_ X and each LED chip would then be spaced from adjacent LED chips in the row by the distance X.
  • the third row would start at a distance l A X in from the start of the second row. This offset would continue for each row of LED chips in the array. Two things happen when this is done. First the light uniformity is increased because of the alternating position of the UV- LED chips. This creates an overlap of light emissions. Then, having each row begin half the distance of the row it precedes will create a stair case effect.
  • the third row starts its row at a distance Vi X in from the first LED chip in the first row or at a distance X in from the start of the previous row.
  • the method and apparatus of the present invention also address a very large number of LEDs that are mounted in long multiple rows, and still have a uniform distribution of light. Additionally, in situations where UV curable ink or adhesive may splatter onto the array of LED' s, a thin transparent plastic sheet or layer is positioned over the array to protect the array, and the sheet or layer is periodically cleaned or replaced.
  • FIG. 1 is a top plan elevational view of an UV LED assembly including a pad for a cathode and an anode mounting an UV LED chip in accordance with the teachings of the present invention
  • FIG. 2 is a top plan elevational view of a design of mating building blocks or substrates which can be blank or have an anode and cathode mounted thereon in accordance with the teachings of the present invention
  • FIG. 3 is a front elevational view of one array of UV LED assemblies wherein rows of UV LED assemblies are arranged in the array with alternate rows of UV LED assemblies in one row being staggered from the UV LED assemblies in the adjacent rows in accordance with the teachings of the present invention
  • FIG. 1 is a top plan elevational view of an UV LED assembly including a pad for a cathode and an anode mounting an UV LED chip in accordance with the teachings of the present invention
  • FIG. 2 is a top plan elevational view of a design of mating building blocks or substrates which can be blank or have an anode and
  • FIG. 4 is front elevational view of a panel of six arrays of UV LED assemblies shown in FIG. 3 in accordance with the teachings of the present invention and shows schematically a first eccentric cam which moves against one side edge of the panel against a spring at the opposite side edge of the panel so as to move, reciprocate or translate the panel in an X direction and a second eccentric cam which acts against an upper edge of the panel and against a spring bearing against a lower edge of the panel to cause movement of the panel in the Y direction and thereby cause all the arrays to move in a orbital, circular, or elliptical path when the first and second cams are rotated about their axes;
  • FIG. 1 first eccentric cam which moves against one side edge of the panel against a spring at the opposite side edge of the panel so as to move, reciprocate or translate the panel in an X direction
  • a second eccentric cam which acts against an upper edge of the panel and against a spring bearing against a lower edge of the panel to cause movement of the panel in the Y direction and thereby cause all
  • FIG. 5 is a block schematic diagram of a web made of, or carrying products, articles or other objects to be UV cured trained over rollers to move in a generally vertical path past the panel of arrays of UV LED assemblies shown in FIG. 4 such that the products, articles or other objects with UV photo initiators therein can be cured as each product, article or other object moves past the arrays of UV LED assemblies while a non-oxygen, heavier than air gas is injected from a gas tube located near the top of the path of movement of the web; and FIG. 6 is a block schematic view of a web made of, or carrying, products, articles or other objects to be UV cured trained over rollers to move in a generally vertical path past the panel of arrays of UV LED assemblies shown in FIG.
  • FIG. 7 is a plan view of another way of positioning UV LED assemblies in at least three rows where the spacing between UV LED assemblies in each row is increased to establish a three tier staggering of UV LED assemblies.
  • FIG. 1 a prior art ultraviolet light-emitting diode (UV LED) assembly 10 including a cathode pad 12 and an anode 14 mounting a chip 16, which comprises a UV LED chip 16.
  • Each cathode pad 12 (FIG. 1) is connected to a wire conductor as is each anode 14.
  • FIG. 2 there is illustrated therein a building block 20 having a first array 21 of the UV LED assemblies 10 thereon, namely, pads 12 and anodes 14, which provide a plurality of UV LED chips 16.
  • the building block 20 is designed to mate with similar building blocks to form a group 22 of arrays 21, 23 and 25 as shown in FIG's 3 and 4. In this way, several of the blocks 20 can matingly engage each other and be arranged in a pattern ( e.g. like tiles on a floor) on a panel 28 (FIG. 4). As shown in FIG. 3, the UV LED assemblies 10 in each array 21, 23 and 25 are spaced apart in a first lower row 36 of UV LED assemblies 10. Then, in a second adjacent row 38, the UV LED assemblies 10 are arranged in a staggered manner so that they are located above the spaces between the UV LED assemblies 10 in the first row.
  • next upper row 40 of UV LED assemblies 10 is staggered and a total of twenty (20) staggered rows are provided in the UV LED array 21 shown in FIG. 3.
  • the beginning of the first UV LED assembly 10 in the lowest row 36 in the first array 21 is aligned with the end of the last UV LED assembly 10 at the end of the lowest row 42 in the second, lower left, array 23.
  • the beginning of the first UV LED assembly 10 in the uppermost row 44 in the first array 21 is aligned with the end of the last UV LED assembly 10 in the uppermost row 46 in the second, lower left array 23.
  • the end of the last UV LED assembly 10 in the lowest row 36 in the first array 21 is aligned with the beginning of the first UV LED assembly 10 in the lowest row 48 in the third, lower right array 25.
  • the end of the last UV LED assembly 10 in the uppermost row 44 in the first array 21 is aligned with the beginning of the first UV LED assembly 10 in the uppermost row 49 in the third, lower right array 25, as shown in FIG. 3.
  • the three arrays 21, 23 and 25 can be arranged on the panel 28 in a staggered manner so that the UV light from each UV LED assembly 10 is not only spaced and staggered relative to adjacent rows in the array but also spaced and staggered relative to the rows in the other arrays.
  • eccentric cams 50 and 52 that can be provided for moving, translating or reciprocating the panel 28 back and forth in the X direction and up and down in the Y direction, much like in an orbital sander.
  • the first, x axis, eccentric cam 50 is mounted for rotation about a shaft 54 to act against one side edge 56 of the panel 28 with a spring 58, such as a helical tension spring, positioned to act against the other side edge 60 of the panel 28.
  • a spring 58 such as a helical tension spring
  • each UV LED assembly 10 is mounted for rotation on a shaft 64 to act against an upper edge 66 of the panel 28 against the action of a spring 68, such as a helical tension spring, positioned to act against a lower edge 70 of the panel 28.
  • Rotation of the shafts 54 and 64 (FIG. 4) each by a prime mover such as a variable speed motor (not shown) can cause the panel 28 to move in a generally orbital, annular, circular, or elliptical path of movement. This will result in orbital movement of each UV LED assembly 10 in each of the rows in each of the arrays 21, 23 and 25 mounted on the panel 28 so as to spread out the emitted UV light and uniformly apply the UV light to the products, articles or other objects to be UV cured.
  • the panel 28 of UV LED arrays 21, 23 and 25 is positioned generally vertically and closely adjacent the path of movement of a conveyor belt comprising web 74 which is trained over rollers 76, 78 and 80 to move generally upright and vertically past and closely adjacent and in proximity to the panel of UV LED arrays 21, 23 and 25.
  • a conveyor belt comprising web 74 which is trained over rollers 76, 78 and 80 to move generally upright and vertically past and closely adjacent and in proximity to the panel of UV LED arrays 21, 23 and 25.
  • at least one of the rollers 76, 78 and/or 80 of a conveyor can be a drive roller.
  • UV curable products, articles or other objects, such as labels, positioned in or on the web 74 (FIG. 5), can have one or more UV curable inks, coatings and/or adhesives between a plastic cover layer and the label.
  • the UV curable ink, coating, and/or adhesive can have UV photo initiators therein which will polymerize the monomers in the UV curable ink, coating, or adhesive when subjected to UV light within a predetermined UV wavelength range.
  • the UV curable ink, coating and/or adhesive is preferably located on the side of the web 74 (FIG. 5) that is closest to and faces the panel 28.
  • the spacing between the UV LED assemblies and the ink, coating or adhesive is between 0.001 inch and 0.3 inch to enhance the effectiveness of the UV emitted light which dissipates exponentially as the distance to the product, article or other UV curable object to be treated increases.
  • the shafts 50 and 52 (FIG. 4) are rotated to cause orbital movement of the panel 28 and UV LED assemblies as the web 74 containing the product, article or other UV curable object moves past the panel 28. Such movement also minimizes "hot spots" and provide uniform sweeping, distribution, and application of the UV light from the UV LED assemblies 10.
  • the block schematic diagram of the assembly or device, shown in FIG. 5 is provided to minimize exposure of the products, articles or other objects during curing to oxygen, which inhibits UV curing.
  • a gas tube 84 providing an upper gas injection is provided on the assembly and device for injecting heavier-than-air, non-oxygen-containing gas, e.g., carbon dioxide, near an upper end 86 of a path of downward movement, indicated by the arrow 88, of the web 74, so that the gas can flow downwardly in the space between the panel 28 and the web 74 to provide an anaerobic area between the UV LED assemblies 10 on the panel 28 and the web 74 having UV curable products, articles or other objects to be cured.
  • a wiper blade 90 (FIG.
  • FIG. 5 providing a lower inhibitor go can be positioned adjacent the lower edge 70 of the panel 28 for holding, compressing, collecting and/or blanketing the gas in the area between the orbiting UV LED arrays 21, 23 and 25 (FIG. 4) and the moving web 74 (FIG. 5).
  • the wiper blade 90 is fixed to the lower edge 70 of the panel 28 and has an outer edge 92 that is positioned to wipe against the moving web 74. In this way, the injected gas can be inhibited from escaping the curing area.
  • FIG. 6 is a block schematic diagram of a UV curing apparatus, assembly, mechanism or device constructed according to the teachings of the present invention where the moving web 74 is trained about rollers 94, 96 and 98, at least one of which can be a drive roller, to cause the web 74 with the UV curable products, articles or other objects thereon or therein to move upwardly, as shown by the arrow 100, past the panel 28 mounting arrays 21, 23 and 25 (FIG. 4) of UV LED assemblies, much the same as in the UV curing apparatus, assembly and device shown in FIG. 5.
  • a gas tube 104 providing a lower gas injector is positioned near a lower end 106 of the path 100 of movement of the web 74 for injecting an inert lighter-than-air, non-oxygen-containing gas, e.g., helium, in the area between the orbiting panel 28 (FIG. 4) and the upwardly moving web 74 (FIG. 6) thereby provide an anaerobic area to enhance and facilitate curing of the UV photo initiators in the UV curable products, articles or other objects that are carried by the web 74.
  • a wiper blade 108 (FIG. 6) providing an upper inhibitor 108 is positioned near the upper edge 68 of the panel 28 as shown in FIG.
  • the wiper blade 108 can be fixed to the upper edge 68 and arranged to wipe against the web 74.
  • the power supplied to the UV LED assemblies can be periodically or sequentially activated and deactivated, i.e. can be turned on and off, at a relatively high frequency.
  • the duty cycle of the on-off cycle can be varied to adjust the UV light intensity.
  • FIG. 7 is illustrated another way to position the UV LED assemblies, namely, the LED chips 16, and achieve the same uniformity as shown in FIG's. 2 and 3. This would be to use 3 rows to achieve the uniformity. That is, to have the LED chips 16 in a first row 112 arranged at a distance of X, and to have the next row 114 (row 2) start at a distance 1/3 in from the start of the first row 112 and the next row 116 (row 3) start at a distance 2/3 in from the start of the first row 112 or at a distance 1/3 in from the start of the second row 114.
  • the space X can be equal to the width of 1, 2, 3, 4, 5, etc.
  • the panel 28 of UV LED assemblies 10 can be arranged closely adjacent the web 74 carrying UV curable products, articles or other objects which enables UV light from UV LED assemblies 10 to better effect curing of the UV curable ink, coating and/or adhesive.
  • the moving of the web 74, carrying the UV curable products, articles or other objects past staggered rows of UV LED assemblies 10 in staggered arrays 21, 23 and 25 of UV LED assemblies 10 on the panel 28 ensures uniform application of UV light to all of the ink, coating and/or adhesive to be cured in the UV curable product, article or object.
  • the oscillating or orbital movement of the UV LED assemblies 10 adjacent the moving web containing the UV curable products, articles or other objects to be cured ensures a more uniform sweeping of the UV light over the UV curable products, articles or other objects on or in the web 74.

Abstract

A UV curing apparatus and method is provided for enhancing the distribution and application of UV light to photoinitiators in a UV curable ink, coating or adhesive, and comprises UV LED assemblies mounted on a panel (68) in a first row with the UV LED assemblies spaced from adjacent UV LED assemblies. At least one second row of a plurality of UV LED assemblies next to the first row, but with assemblies positioned adjacent the spaces between adjacent UV LED assemblies in the first row thereby to stagger the second row assemblies from those of the first row. UV curable products that are in or on a web (74) can be conveyed (100) past the UV LED assemblies for effective UV curing using rollers (94, 96, 98), wiper blade (108), mechanisms for causing the panel to move, and an injection tube (104) for injecting gas in the UV curing area.

Description

SPECIFICATION TITLE OF THE INVENTION
LIGHT EMITTING APPARATUS AND METHOD FOR CURING INKS, COATINGS AND ADHESIVES
BACKGROUND OF THE INVENTION
1. Field of the Invention. The present invention relates to a method and apparatus for utilizing ultraviolet (UV) light emitting diodes in staggered arrays and mechanisms for moving the arrays to avoid "hot spots" and provide a uniform application of ultraviolet light to a moving object including inks, coatings or adhesives having UV photo initiators for converting, when exposed to UV light, monomers in the inks, coatings or adhesives to linking polymers to solidify the monomer material. Also, an inert, non-oxygen, gas is injected into the area where the staggered arrays of ultraviolet light emitting diodes, UV-LED's are positioned to apply UV light to the moving objects to enhance the curing of the ultraviolet activated UV photo initiators.
2. Description of the Prior Art. Heretofore, ultraviolet lamps have been used for the curing of ultraviolet inks, coatings and adhesives. More recently, EXFO and EFOS of Mississauga, Ontario, Canada have developed UV light emitting diodes (LED's) and gathered them in large numbers for use in curing ultraviolet light sensitive monomers to polymerize the monomers and solidify the ink, coating or adhesive. While the use of a large number of UV-LED's provide many efficiencies, namely in cost and energy consumption, there is still the problem of effective curing with low intensity UV-LED's and with respect to "hot spots" which provide more curing at "hot spots" then at other locations in the ink, coating or adhesive being cured. Also, in the UV-LED prior art, the LED is positioned to achieve uniformity for back light displays and other lighting applications. The criteria for such uniformity are primarily designed to create an appearance that the backlight is uniform for a visual appearance. It is, therefore, desirable to provide an improved UV method and apparatus for applying UV light emitted from UV LED's more uniformly and avoid hot spots to more effectively cure UV inks, coatings and adhesives.
BRIEF SUMMARY OF THE INVENTION As will be described in greater detail hereinafter, the method and device of the present invention provide techniques and structures for applying UV light emitted from UV-LED's more uniformly so that such light is more effective in curing inks, coatings and adhesives and, by applying the UV light more evenly, reducing, if not all together eliminating, "hot spots". According to the present invention there is provided staggered arrays of UV LED assemblies on a panel with the UV LED assemblies being arranged in rows with each row being staggered from adjacent rows. In addition to the staggering of the UV LED assemblies in adjacent rows, a UV curable product, article or other object having a UV ink, coating or adhesive to be cured, is moved on or in a web past, and closely adjacent, the arrays. Further, the panel is moved or translated in an X direction and in a Y direction, much like an orbital sander, thereby to cause a slight sweeping of the light from each UV LED assembly over an orbital area, e.g., in a circular or elliptical pattern, thereby minimizing the creation of "hot spots" and to uniformly apply UV light to the product, article or other object having the UV ink, coating or adhesive. In one preferred embodiment, the web containing the UV curable product, article or other object to be cured is arranged to move vertically. A gas having a molecular weight heavier than air can be injected at the upper end of the path of movement of the UV curable product, article or other object having a UV ink, coating, or adhesive thereon as it moves past a panel of arrays of UV LED assemblies. Furthermore, a gas having a molecular weight lighter than air can be injected at the lower end of the path of movement of the UV curable product, article or other object having a UV ink, coating or adhesive thereon as it moves past the panel of arrays of UV LED assemblies. The method and apparatus of the present invention provide uniformity of light application from a flat panel having an array of UV-LED's. This result is obtained when the product and/or the light fixture is moved relative to and across the UV light beams from the UV-LED assemblies. This movement in of itself has the ability to offer one element of uniformity. That is, the movement of the product or the movement of the light array addresses the problem of providing uniformity in the direction of the product flow or of the lamp movement. The "X Axis" uniformity is addressed by the movement of the product or of the LED array. The "Y Axis" uniformity is addressed by how the LED chips are arranged. To achieve the cure rates that are associated with typical UV curing applications, a very large number of UV-LED chips are arranged to deliver, the amount of UV energy necessary to cure the polymers. The first step in building these arrays is to create either a series or parallel electrical circuit either in series or in which the LED chips are placed in a linear fashion of equal distance from each other. (Lets say a distance of X). The second row would start its row at a distance '/_ X and each LED chip would then be spaced from adjacent LED chips in the row by the distance X. The third row would start at a distance lA X in from the start of the second row. This offset would continue for each row of LED chips in the array. Two things happen when this is done. First the light uniformity is increased because of the alternating position of the UV- LED chips. This creates an overlap of light emissions. Then, having each row begin half the distance of the row it precedes will create a stair case effect. This will allow uniformity in the Y Axis as the array grows in size. There is another way to position the LED chips, and achieve the same uniformity. This would be to use 3 rows to achieve the uniformity. That is, to have the LED chips arranged at a distance of X, and to have the next row (row 2) start at a distance 1/3 in from the start of the first row and the next row (row 3) start at a distance 2/3 in from the start of the first row or at a distance 1/3 in from the start of the second row. Still another way is to provide 4 rows to create the uniformity, with the LED chips in the first row being spaced at a distance of X from each other. The second row starts its first LED chip at a distance X in from the first LED chip in the first row. The third row starts its row at a distance Vi X in from the first LED chip in the first row or at a distance X in from the start of the previous row. The method and apparatus of the present invention also address a very large number of LEDs that are mounted in long multiple rows, and still have a uniform distribution of light. Additionally, in situations where UV curable ink or adhesive may splatter onto the array of LED' s, a thin transparent plastic sheet or layer is positioned over the array to protect the array, and the sheet or layer is periodically cleaned or replaced. A more detailed explanation of the invention is provided in the following detailed description and claims taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a top plan elevational view of an UV LED assembly including a pad for a cathode and an anode mounting an UV LED chip in accordance with the teachings of the present invention; FIG. 2 is a top plan elevational view of a design of mating building blocks or substrates which can be blank or have an anode and cathode mounted thereon in accordance with the teachings of the present invention; FIG. 3 is a front elevational view of one array of UV LED assemblies wherein rows of UV LED assemblies are arranged in the array with alternate rows of UV LED assemblies in one row being staggered from the UV LED assemblies in the adjacent rows in accordance with the teachings of the present invention; FIG. 4 is front elevational view of a panel of six arrays of UV LED assemblies shown in FIG. 3 in accordance with the teachings of the present invention and shows schematically a first eccentric cam which moves against one side edge of the panel against a spring at the opposite side edge of the panel so as to move, reciprocate or translate the panel in an X direction and a second eccentric cam which acts against an upper edge of the panel and against a spring bearing against a lower edge of the panel to cause movement of the panel in the Y direction and thereby cause all the arrays to move in a orbital, circular, or elliptical path when the first and second cams are rotated about their axes; FIG. 5 is a block schematic diagram of a web made of, or carrying products, articles or other objects to be UV cured trained over rollers to move in a generally vertical path past the panel of arrays of UV LED assemblies shown in FIG. 4 such that the products, articles or other objects with UV photo initiators therein can be cured as each product, article or other object moves past the arrays of UV LED assemblies while a non-oxygen, heavier than air gas is injected from a gas tube located near the top of the path of movement of the web; and FIG. 6 is a block schematic view of a web made of, or carrying, products, articles or other objects to be UV cured trained over rollers to move in a generally vertical path past the panel of arrays of UV LED assemblies shown in FIG. 4 such that each product, article or other object with UV photo initiators therein can be cured as each product, article or other object moves past the arrays of UV LED assemblies while a non-oxygen gas is injected from a gas tube located near the bottom of the path of movement of the web. FIG. 7 is a plan view of another way of positioning UV LED assemblies in at least three rows where the spacing between UV LED assemblies in each row is increased to establish a three tier staggering of UV LED assemblies.
DETAILED DESCRIPTION OF THE INVENTION- A detailed description of the preferred embodiments and best modes for practicing the invention are described herein. Referring now to the drawings in greater detail, there is illustrated in FIG. 1 a prior art ultraviolet light-emitting diode (UV LED) assembly 10 including a cathode pad 12 and an anode 14 mounting a chip 16, which comprises a UV LED chip 16. Each cathode pad 12 (FIG. 1) is connected to a wire conductor as is each anode 14. Referring now to FIG. 2, there is illustrated therein a building block 20 having a first array 21 of the UV LED assemblies 10 thereon, namely, pads 12 and anodes 14, which provide a plurality of UV LED chips 16. The building block 20 is designed to mate with similar building blocks to form a group 22 of arrays 21, 23 and 25 as shown in FIG's 3 and 4. In this way, several of the blocks 20 can matingly engage each other and be arranged in a pattern ( e.g. like tiles on a floor) on a panel 28 (FIG. 4). As shown in FIG. 3, the UV LED assemblies 10 in each array 21, 23 and 25 are spaced apart in a first lower row 36 of UV LED assemblies 10. Then, in a second adjacent row 38, the UV LED assemblies 10 are arranged in a staggered manner so that they are located above the spaces between the UV LED assemblies 10 in the first row. In the same manner, the next upper row 40 of UV LED assemblies 10 is staggered and a total of twenty (20) staggered rows are provided in the UV LED array 21 shown in FIG. 3. Also, as shown in FIG. 3 the beginning of the first UV LED assembly 10 in the lowest row 36 in the first array 21 is aligned with the end of the last UV LED assembly 10 at the end of the lowest row 42 in the second, lower left, array 23. Then, the beginning of the first UV LED assembly 10 in the uppermost row 44 in the first array 21 is aligned with the end of the last UV LED assembly 10 in the uppermost row 46 in the second, lower left array 23. Next, the end of the last UV LED assembly 10 in the lowest row 36 in the first array 21 is aligned with the beginning of the first UV LED assembly 10 in the lowest row 48 in the third, lower right array 25. Finally, the end of the last UV LED assembly 10 in the uppermost row 44 in the first array 21 is aligned with the beginning of the first UV LED assembly 10 in the uppermost row 49 in the third, lower right array 25, as shown in FIG. 3. As shown best in FIG. 4, the three arrays 21, 23 and 25 can be arranged on the panel 28 in a staggered manner so that the UV light from each UV LED assembly 10 is not only spaced and staggered relative to adjacent rows in the array but also spaced and staggered relative to the rows in the other arrays. Also more than three arrays 21, 23 and 25 can be provided, such as six arrays, not shown. Also shown in FIG. 4, are mechanisms, preferably eccentric cams 50 and 52, that can be provided for moving, translating or reciprocating the panel 28 back and forth in the X direction and up and down in the Y direction, much like in an orbital sander. The first, x axis, eccentric cam 50 is mounted for rotation about a shaft 54 to act against one side edge 56 of the panel 28 with a spring 58, such as a helical tension spring, positioned to act against the other side edge 60 of the panel 28. Then the second, y axis, eccentric cam 52 (FIG. 4) is mounted for rotation on a shaft 64 to act against an upper edge 66 of the panel 28 against the action of a spring 68, such as a helical tension spring, positioned to act against a lower edge 70 of the panel 28. Rotation of the shafts 54 and 64 (FIG. 4) each by a prime mover such as a variable speed motor (not shown) can cause the panel 28 to move in a generally orbital, annular, circular, or elliptical path of movement. This will result in orbital movement of each UV LED assembly 10 in each of the rows in each of the arrays 21, 23 and 25 mounted on the panel 28 so as to spread out the emitted UV light and uniformly apply the UV light to the products, articles or other objects to be UV cured. This spreading of the UV light also minimizes, if not altogether eliminates the creation of, so called "hot spots" of UV light . As shown in FIG. 5, where a schematic block diagram of one UV curing apparatus, assembly, mechanism or device constructed according to the teachings of the present invention is shown, the panel 28 of UV LED arrays 21, 23 and 25 is positioned generally vertically and closely adjacent the path of movement of a conveyor belt comprising web 74 which is trained over rollers 76, 78 and 80 to move generally upright and vertically past and closely adjacent and in proximity to the panel of UV LED arrays 21, 23 and 25. For this purpose, at least one of the rollers 76, 78 and/or 80 of a conveyor can be a drive roller. UV curable products, articles or other objects, such as labels, positioned in or on the web 74 (FIG. 5), can have one or more UV curable inks, coatings and/or adhesives between a plastic cover layer and the label. The UV curable ink, coating, and/or adhesive can have UV photo initiators therein which will polymerize the monomers in the UV curable ink, coating, or adhesive when subjected to UV light within a predetermined UV wavelength range. The UV curable ink, coating and/or adhesive is preferably located on the side of the web 74 (FIG. 5) that is closest to and faces the panel 28. Preferably, the spacing between the UV LED assemblies and the ink, coating or adhesive is between 0.001 inch and 0.3 inch to enhance the effectiveness of the UV emitted light which dissipates exponentially as the distance to the product, article or other UV curable object to be treated increases. Preferably, the shafts 50 and 52 (FIG. 4) are rotated to cause orbital movement of the panel 28 and UV LED assemblies as the web 74 containing the product, article or other UV curable object moves past the panel 28. Such movement also minimizes "hot spots" and provide uniform sweeping, distribution, and application of the UV light from the UV LED assemblies 10. The block schematic diagram of the assembly or device, shown in FIG. 5 is provided to minimize exposure of the products, articles or other objects during curing to oxygen, which inhibits UV curing. A gas tube 84 providing an upper gas injection is provided on the assembly and device for injecting heavier-than-air, non-oxygen-containing gas, e.g., carbon dioxide, near an upper end 86 of a path of downward movement, indicated by the arrow 88, of the web 74, so that the gas can flow downwardly in the space between the panel 28 and the web 74 to provide an anaerobic area between the UV LED assemblies 10 on the panel 28 and the web 74 having UV curable products, articles or other objects to be cured. A wiper blade 90 (FIG. 5) providing a lower inhibitor go can be positioned adjacent the lower edge 70 of the panel 28 for holding, compressing, collecting and/or blanketing the gas in the area between the orbiting UV LED arrays 21, 23 and 25 (FIG. 4) and the moving web 74 (FIG. 5). Preferably the wiper blade 90 is fixed to the lower edge 70 of the panel 28 and has an outer edge 92 that is positioned to wipe against the moving web 74. In this way, the injected gas can be inhibited from escaping the curing area. FIG. 6 is a block schematic diagram of a UV curing apparatus, assembly, mechanism or device constructed according to the teachings of the present invention where the moving web 74 is trained about rollers 94, 96 and 98, at least one of which can be a drive roller, to cause the web 74 with the UV curable products, articles or other objects thereon or therein to move upwardly, as shown by the arrow 100, past the panel 28 mounting arrays 21, 23 and 25 (FIG. 4) of UV LED assemblies, much the same as in the UV curing apparatus, assembly and device shown in FIG. 5. In the apparatus, assembly or device shown in FIG. 6, a gas tube 104 providing a lower gas injector is positioned near a lower end 106 of the path 100 of movement of the web 74 for injecting an inert lighter-than-air, non-oxygen-containing gas, e.g., helium, in the area between the orbiting panel 28 (FIG. 4) and the upwardly moving web 74 (FIG. 6) thereby provide an anaerobic area to enhance and facilitate curing of the UV photo initiators in the UV curable products, articles or other objects that are carried by the web 74. A wiper blade 108 (FIG. 6) providing an upper inhibitor 108 is positioned near the upper edge 68 of the panel 28 as shown in FIG. 6 to minimize the escape of the lighter-than- air gas and hold, compress, collect and/or blanket the injected gas in the curing area between the orbiting panel 28 (FIG. 4) and the moving web 74 (FIG. 6), much the same as in the UV curing apparatus, assembly and device shown in FIG. 5. Again, the wiper blade 108 (FIG. 6) can be fixed to the upper edge 68 and arranged to wipe against the web 74. To avoid overheating the UV LED assemblies 10, i.e., to control the heat generated by the UV LED assemblies 10, the power supplied to the UV LED assemblies can be periodically or sequentially activated and deactivated, i.e. can be turned on and off, at a relatively high frequency. Also, the duty cycle of the on-off cycle can be varied to adjust the UV light intensity. In FIG. 7 is illustrated another way to position the UV LED assemblies, namely, the LED chips 16, and achieve the same uniformity as shown in FIG's. 2 and 3. This would be to use 3 rows to achieve the uniformity. That is, to have the LED chips 16 in a first row 112 arranged at a distance of X, and to have the next row 114 (row 2) start at a distance 1/3 in from the start of the first row 112 and the next row 116 (row 3) start at a distance 2/3 in from the start of the first row 112 or at a distance 1/3 in from the start of the second row 114. It will be understood that the space X can be equal to the width of 1, 2, 3, 4, 5, etc. of an UV LED assembly 10 to provide a desired staggering of the light beams from the UV LED assemblies 10. Also, in situations where UV curable ink or adhesive might splatter on the UV LED assemblies 10, a clear/transparent sheet or layer of plastic material can be placed over the arrays 21, 23 and 25 to protect the UV LED assemblies 10. Then, the sheet or layer is cleaned or replaced periodically. From the foregoing description it will be apparent that the method and device of the present invention have a number of advantages, some of which have been described above and others of which are inherent in the invention. For example, the panel 28 of UV LED assemblies 10 can be arranged closely adjacent the web 74 carrying UV curable products, articles or other objects which enables UV light from UV LED assemblies 10 to better effect curing of the UV curable ink, coating and/or adhesive. Further, the moving of the web 74, carrying the UV curable products, articles or other objects past staggered rows of UV LED assemblies 10 in staggered arrays 21, 23 and 25 of UV LED assemblies 10 on the panel 28 ensures uniform application of UV light to all of the ink, coating and/or adhesive to be cured in the UV curable product, article or object. Still further, the oscillating or orbital movement of the UV LED assemblies 10 adjacent the moving web containing the UV curable products, articles or other objects to be cured ensures a more uniform sweeping of the UV light over the UV curable products, articles or other objects on or in the web 74. Finally, the application of a heavier-than-air or a lighter-than-air, non-oxygen- containing gas to the area between the oscillating or orbiting panel 28 of UV LED assemblies 10 and the web 74 carrying the UV curable products, articles or other objects having monomer material to be cured or polymerized enhances the emission and application of more uniform UV light upon the UV curable products, articles, or other objects. Although embodiments of the invention have been shown and described, it will be understood that various modifications and substitutions, as well as rearrangements of components, parts, equipment, apparatus, process (method) steps, and uses thereof, can be made by those skilled in the art without departing from the teachings of the invention. Accordingly, the scope of the invention is only to be limited as necessitated by the accompanying claims.

Claims

CLAIMS What is claimed is:
1. An apparatus for enhancing curing with an ultraviolet (UV) light applied to UV photo initiators in a UV curable ink, coating or adhesive in a UV curable product, article of other object, characterized in that apparatus comprises: a conveyor having roller assemblies for moving a web carrying or containing UV curable products, articles and/or other objects through a path; an array of UV light emitting diodes (LED) assemblies mounted on a panel in proximity to the conveyor for emitting UV light; an upper injector for injecting a heavier-than-air, non-oxygen gas at an upper end of a generally vertical path section of the web to create a substantially anaerobic area between the panel and the moving web during curing of the UV curable ink, coating or adhesive; and/or a lower injector for injecting a lighter-than-air, non-oxygen gas at a lower end of a generally vertical path section of the web to create a substantially anaerobic area during curing of the UV curable ink, coating or adhesive; and/or a mechanism for moving the panel containing the array of UV LED assemblies in a reciprocal path as the web carrying the UV curable products, articles and/or other objects is conveyed past the panel; and/or a mechanism comprising an oscillator for moving the panel of the array of LED assemblies in an orbital, annular, circular or elliptical path as the web carrying the UV curable products, articles and/or other objects is conveyed past the panel of UV LED assemblies; and/or the array of UV LED assemblies have at least one second row of a plurality of UV LED assemblies arranged on the panel next to a first row of UV LED assemblies but with the UV LED assemblies of the second row positioned adjacent the spaces between adjacent UV LED assemblies in the first row thereby to stagger the second row of UV LED assemblies relative to the UV LED assemblies in the first row.
2. The apparatus of claim 1 characterized in that the apparatus includes: thin, transparent sheet or layer of plastic material over the UV LED assemblies on the panel to protect the UV LED assemblies from splatter of UV curable ink and/or adhesive; and periodically cleaning or replacing the sheet or layer of transparent plastic material.
3. The apparatus of any of the preceding claims characterized in that: at least two staggered rows of UV LED assemblies on the panel form a staggered array of UV LED assemblies on the panel; and/or the UV LED assemblies in each row of the array of UV LED assemblies are spaced a distance X from each other and the first UV LED assembly in the second row starts the second row at a distance V2 X in from the first UV LED assembly in the first row and the UV LED assemblies in the second row are spaced from each other by the distance X and the first UV LED assembly in a third row starts at a distance Vi X from the start of the second row; or the UV LED assemblies in each row of the array of UV LED assemblies are spaced a distance X from each other and the first UV LED assembly in the second row starts the second row at a distance 1/3 in from the first UV LED assembly in the first row and the first UV LED assembly in the next or third row starts at a distance 2/3 in from the first UV LED assembly in the first row or at a distance 1/3 in from the first UV LED assembly in the second row; or the UV LED assemblies in each row of the array of UV LED assemblies are spaced a distance X from each other and the first UV LED assembly in the second row starts the second row at a distance lΛ X in from the first UV LED assembly in the first row and a first UV LED assembly in a third row starts in row at a distance lΛ X in from the start of the first row or at a distance lA X in from the start of the second row; and/or the array of UV LED assemblies comprises six arrays of staggered UV LED assemblies mounted in a staggered manner on the panel.
4. The apparatus of any of the preceding claims characterized in that the apparatus includes: a gas injector for injecting a gas; and/or an inhibitor for substantially inhibiting the flow of a gas; the gas can be helium, carbon dioxide, or nitrogen; the inhibitor includes an upper inhibitor for substantially inhibiting exit flow of the gas at an upper end of the panel of the UV LED assemblies; and/or the inhibitor includes an upper inhibitor with a wiper blade mounted adjacent an upper end of the panel between the panel of the UV LED assemblies and web of the conveyor; and/or the inhibitor includes a lower inhibitor for substantially inhibiting exit flow of the gas at a lower end of the panel of the LED assemblies; and/or the inhibitor includes a lower inhibitor with a wiper blade mounted adjacent the upper end of the panel of the LED assemblies between the panel and the web of the conveyor.
5. The apparatus of any of the preceding claims characterized in that the apparatus includes: a mechanism for moving the panel of the UV LED assemblies in at least one of the X, Y axes thereby to apply UV light substantially uniformly over the UV curable products, articles and/or other objects on and/or in the web of the conveyor to substantially minimize hot spots; and the mechanism comprises an orbiting mechanism for moving the panel in both an X axis reciprocal path and a Y axis reciprocal path thereby to move the panel of the UV LED assemblies in an orbital, annular, circular or elliptical path as the web of the conveyor carrying UV curable products, article and/or other objects is conveyed past the panel of the UV LED assemblies; and/or the mechanism includes an eccentric cam acting against one side of the panel of the UV LED assemblies and against a spring acting against the other side of the panel of UV LED assemblies; and/or the mechanism includes a spring mounted adjacent one side of the panel of the UV LED assemblies, a cam eccentrically mounted on a shaft adjacent the other side of said panel of the UV LED assemblies, and a driver for rotating the shaft so as to rotate the cam and move the panel of the UV LED assemblies in a reciprocal path against the spring; and/or the mechanism includes a first eccentric cam acting against one side of the panel of the UV LED assemblies and against a spring acting against the other side of the panel of the UV LED assemblies and a second eccentric cam acting against another side of the panel for the UV LED assemblies and against a spring acting against the side opposite another side of the panel of the UV LED assemblies to reciprocally move the panel in both an X axis reciprocal path and a Y axis reciprocal path so as to move or oscillate the panel of the UV LED assemblies in a generally orbital, annular, circular or elliptical path as the web of the conveyor carrying the UV curable products, articles, and/or other objects is moved past the panel of the UV LED assemblies.
6. A method of constructing and/or using the apparatus of any of the preceding claims by: arranging an array of UV LED assemblies in a first row with the UV LED assemblies spaced from adjacent UV LED assemblies; arranging at least one second row of a plurality of UV LED assemblies next to the first row but with the UV LED assemblies of the second row positioned adjacent the spaces between adjacent UV LED assemblies in the first row thereby to stagger the second row of UV LED assemblies from the UV LED assemblies in the first row; mounting at least the first and second rows of staggered UV LED assemblies on a panel; and conveying the UV curable products, articles and/or other objects containing UV photo initiators that are in or on the web of the conveyor past the at least two rows of UV LED assemblies, so that the staggering of the UV LED assemblies provide a substantially uniform application of UV light on the UV curable ink, coating and/or adhesive on the UV curable products, articles and/or other objects.
7. The method of using the apparatus of any of the preceding claims by: moving the panel of the UV LED assemblies in both an X axis reciprocal path and a Y axis reciprocal path to move or oscillate the panel for the UV LED assemblies in an orbital, annular, circular or elliptical path as the web of the conveyor carrying the UV curable products, articles and/or other objects is conveyed past the panel of the UV LED assemblies; and/or conveying the UV curable products, articles and/or other objects containing UV photo initiators that are in or on a web on the conveyor past the array of LED assemblies; and/or reciprocally moving the panel of the UV LED assemblies to reciprocally sweep UV light across the panel of the UV LED assemblies to apply UV curable light substantially uniformly across the UV curable products, articles and/or objects so as to substantially minimize hot spots.
8. A method of using the apparatus of any of the preceding claims to cure the UV curable products, articles and/or other objects, characterized in that the curing comprises: emitting UV light on the UV photo initiators; polymerizing the UV curable ink, coating, and/or adhesive; and minimizing exposure of the UV curable ink, coating and/or adhesive to oxygen during polymerization by injecting a lighter than air gas along a path of movement of the web of the conveyor past the panel of the array of LED assemblies.
PCT/US2004/001594 2004-01-23 2004-01-23 Light emitting apparatus and method for curing inks, coatings and adhesives WO2005116089A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP04704792A EP1706432A4 (en) 2004-01-23 2004-01-23 Light emitting apparatus and method for curing inks, coatings and adhesives
PCT/US2004/001594 WO2005116089A1 (en) 2004-01-23 2004-01-23 Light emitting apparatus and method for curing inks, coatings and adhesives
CNA2004800407879A CN1910206A (en) 2004-01-23 2004-01-23 Light-emitting device and method for solidified oil ink, superposition layer and adhesive
CA002553521A CA2553521A1 (en) 2004-01-23 2004-01-23 Light emitting apparatus and method for curing inks, coatings and adhesives

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EP1706432A4 (en) 2008-09-03
CA2553521A1 (en) 2005-12-08
CN1910206A (en) 2007-02-07

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