WO2005110136A1 - Shrinkable fiber for artificial hair - Google Patents

Shrinkable fiber for artificial hair Download PDF

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Publication number
WO2005110136A1
WO2005110136A1 PCT/JP2005/009034 JP2005009034W WO2005110136A1 WO 2005110136 A1 WO2005110136 A1 WO 2005110136A1 JP 2005009034 W JP2005009034 W JP 2005009034W WO 2005110136 A1 WO2005110136 A1 WO 2005110136A1
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Prior art keywords
fiber
hair
bulkiness
artificial hair
crimping
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PCT/JP2005/009034
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French (fr)
Japanese (ja)
Inventor
Seiichi Sakurai
Satoru Harada
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Kaneka Corporation
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Application filed by Kaneka Corporation filed Critical Kaneka Corporation
Priority to JP2006513614A priority Critical patent/JP5105871B2/en
Publication of WO2005110136A1 publication Critical patent/WO2005110136A1/en

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/40Modacrylic fibres, i.e. containing 35 to 85% acrylonitrile

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Toys (AREA)

Abstract

Provided is a shrinkable fiber for an artificial hair, which is improved in the bulkiness of the hair as compared with a conventional one and also has acquired a soft touch. Although it has been proposed to improve the bulkiness by shrinkage, by utilizing a cross-sectional shape or the residual shrinkage of a fiber, the objective bulkiness has not been achieved and a problem of the lowering of characteristics as a commercial product has been arisen. The present inventors have found that the use of a fiber having shrinkability can impart excellent bulkiness to the resultant artificial hair and has completed the present invention, which is a shrinkable fiber for an artificial hair, which is a fiber for an artificial hair made of an acrylic polymer containing 30 wt % or more of acrylonitrile, characterized in that it exhibits a dry-heat shrinkage percentage of 5 % or more in a treatment at 100˚C for 30 minutes and has a single fiber fineness of 25 to 95 dtex.

Description

人工毛髪用収縮性繊維  Shrinkable fiber for artificial hair
技術分野  Technical field
[0001] 本発明は、かつら、ヘアピース、ブレード、エクステンションヘアー、ドールヘアー等 に用いられる新規な人工毛髪用収縮性繊維及びそれを用いた頭髪装飾用繊維束に 関するものである。  The present invention relates to a novel shrinkable fiber for artificial hair used for wigs, hairpieces, blades, extension hair, doll hair, and the like, and a hair bundle for hair decoration using the same.
背景技術  Background art
[0002] 一般的に人工毛髪に使用される合成繊維としては、モダクリル繊維、塩化ビニル繊 維、塩ィ匕ビユリデン繊維、ポリエステル繊維、ナイロン繊維等がある。従来、これらの 繊維を用いて、かつら、ヘアーピース、ブレード等の人工毛髪用商品に加工する場 合に、その商品にあった繊維の断面形状が研究され、改良が重ねられてきた。例え ば、嵩高でボリューム感に富んだ商品を得るために特許文献 1〜3では、断面形状に より嵩高性を向上させうる繊維が提案されているが、断面形状による嵩高効果は限界 があり、まだ改善の余地がある。特許文献 4では、繊維の残留収縮を利用して熱処理 する事で細力べ不均一な捲縮を付与する事ができる。又、特許文献 5では、残留収縮 率の差が 5〜80%である 2種以上の繊維を混合させ熱処理する事で任意に捲縮を 付与することが出来るとの記載があるとの記載があるが捲縮が細かすぎたり、不均一 な捲縮しか得られずに触感が硬くなつたり、目標の嵩高性が得られず商品性が低下 する問題があった。特許文献 6では、ポリ塩ィ匕ビニル系繊維を用い、カールを均一に 発現付与させる事ができるとの記載がある力 嵩高性については満足できるものは得 られていないのが現状である。又、捲縮を付与させる加工方法としては、ギヤクリンプ 法が作業性の観点から一般的である。しかし、捲縮を付与された繊維束の嵩高性は 、繊維の断面形状により決定されているのが現状であった。  [0002] Synthetic fibers generally used for artificial hair include modacrylic fiber, vinyl chloride fiber, Shiridani biureiden fiber, polyester fiber, nylon fiber and the like. Conventionally, when processing these fibers into artificial hair products such as wigs, hair pieces, blades, etc., the cross-sectional shape of the fibers suitable for the product has been studied and improved. For example, in order to obtain bulky and voluminous products, Patent Documents 1 to 3 propose fibers that can improve bulkiness by a cross-sectional shape, but the bulking effect by the cross-sectional shape is limited, There is still room for improvement. In Patent Document 4, non-uniform crimps can be imparted by performing heat treatment using residual shrinkage of fibers. Patent Document 5 also states that it is possible to arbitrarily impart crimp by mixing and heating two or more types of fibers having a difference in residual shrinkage of 5 to 80%. However, there were problems that the crimp was too fine, the uneven crimp was obtained and the feel was hard, and the desired bulkiness could not be obtained, resulting in a decrease in commercial properties. In Patent Document 6, there is a description that the curl can be uniformly expressed and imparted using a polychlorinated vinyl fiber, and satisfactory bulkiness is not obtained at present. As a processing method for imparting crimp, a gear crimping method is generally used from the viewpoint of workability. However, at present, the bulkiness of the crimped fiber bundle is determined by the cross-sectional shape of the fiber.
特許文献 1:実開昭 56—42980号公報  Patent Document 1: Japanese Utility Model Publication No. 56-42980
特許文献 2:特開平 8 - 296112号公報  Patent Document 2: JP-A-8-296112
特許文献 3:特開平 8— 302519号公報  Patent Document 3: JP-A-8-302519
特許文献 4:特開平 6— 287801号公報 特許文献 5 :特開平 9 302513号公報 Patent Document 4: JP-A-6-287801 Patent Document 5: JP-A-9302513
特許文献 6:特開 2003— 293213号公報  Patent Document 6: Japanese Patent Application Laid-Open No. 2003-293213
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0003] そこで、本発明の目的は、人工毛髪用繊維として、従来よりも嵩高性ならびに操業 性 (捲縮付与性)を向上させ、且つソフトな触感を付与した人工毛髪用収縮性繊維を 提供する事である。 [0003] Therefore, an object of the present invention is to provide an artificial hair shrinkable fiber having improved bulkiness and operability (crimpability) as compared to the conventional art, and imparted with a soft touch. It is to do.
課題を解決するための手段  Means for solving the problem
[0004] 上記の課題を解決するため、鋭意検討を重ねた結果、特定の繊度範囲の繊維に 収縮性を持たせる事で、通常の繊維の物性を損なう事なぐ優れた嵩高性を付与で き、捲縮の付き易さや加工速度のアップ等、操業性が向上する事を見出し本発明に 到達した。すなわち本発明は、アクリル-トリルを 30重量%以上含有するアクリル系 重合体力 なる人工毛髪用繊維であって、 100°Cで 30分処理における乾熱収縮率 力 %以上を有し、単糸繊度が 25〜95dtexである事を特徴とする人工毛髪用収縮 性繊維に関する。 [0004] As a result of intensive studies to solve the above problems, it has been found that by giving fibers of a specific fineness range shrinkage properties, excellent bulkiness can be imparted without impairing the physical properties of ordinary fibers. The present inventors have found that operability is improved, such as ease of crimping and increase in processing speed, and have reached the present invention. That is, the present invention relates to an artificial hair fiber comprising an acrylic polymer containing 30% by weight or more of acryl-tolyl, and having a dry heat shrinkage of 100% or more for 30 minutes and a single yarn fineness. The present invention relates to a contractile fiber for artificial hair, wherein the fiber has a dtex of 25 to 95 dtex.
[0005] また、紡糸後の糸条を 90〜150°Cで 1. 2〜4. 0倍に延伸したことを特徴とし、好ま しくは、捲縮加工後の見掛け嵩高さが 6. 5cm以上である人工毛髪用収縮繊維であ る。さらに、前記人工毛髪用収縮性繊維において、繊維が頭髪装飾用であり、前記 頭髪装飾が、かつら、ヘアピース、ブレード、エクステンションヘアー、又はドールへ ァ一に好適に用いうる。また、前記人工毛髪用収縮性繊維において、 捲縮加工を 施した繊維束を形成してなることを特徴とする頭飾用繊維束であり、好ましくは捲縮 加工がギアクリンプ法である事を特徴とする。なお、前記頭飾用繊維束において、繊 維束が、かつら、ヘアピース、ブレード、エクステンションヘアー、又はドールヘアーと して用いうる。  [0005] Furthermore, the spun yarn is stretched 1.2 to 4.0 times at 90 to 150 ° C., and preferably, the apparent bulk after crimping is 6.5 cm or more. This is a shrinkable fiber for artificial hair. Further, in the above-mentioned artificial hair contractile fiber, the fiber is used for hair decoration, and the hair decoration can be suitably used for a wig, a hairpiece, a blade, an extension hair, or a doll hair. Further, in the artificial hair shrinkable fiber, a head decoration fiber bundle formed by forming a crimped fiber bundle, preferably the crimping process is a gear crimp method. I do. In the head decoration fiber bundle, the fiber bundle can be used as a wig, a hairpiece, a blade, an extension hair, or a doll hair.
発明の効果  The invention's effect
[0006] 本発明に係る人工毛髪用収縮性繊維は、特定以上の収縮率を有しており、ブレー ド用、エクステンションヘアー用をはじめとする人工毛髪用繊維として好ましい風合い とクリンプカ卩ェ等の操業性に優れたものである。更に、これらの繊維にギヤ一クリンプ 等の捲縮加工を施した繊維束を用いることにより、嵩高性に優れたブレード用、エタ ステンションヘアー用等の頭飾用商品を得ることができる。 [0006] The artificial hair shrinkable fiber according to the present invention has a shrinkage ratio of a specific level or more, and is a preferable texture as an artificial hair fiber for blades, extension hair, and the like. It has excellent operability, such as crimp kajue. Furthermore, by using a crimped fiber bundle such as a gear crimp on these fibers, it is possible to obtain head decoration products such as blades and extension hair having excellent bulkiness.
図面の簡単な説明  Brief Description of Drawings
[0007] [図 1]捲縮前及び捲縮後の嵩高さを測定する方法を示す説明図であり、(ィ)は斜視 図で(口)は測定時の断面図である。  FIG. 1 is an explanatory view showing a method of measuring bulkiness before and after crimping, wherein (a) is a perspective view and (mouth) is a cross-sectional view at the time of measurement.
符号の説明  Explanation of symbols
[0008] 1 測定容器 [0008] 1 Measurement container
2 測定容器用蓋  2 Lid for measuring container
3 人工毛髪用収縮性繊維、捲縮加工後の繊維束  3 Shrinkable fibers for artificial hair, fiber bundle after crimping
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0009] 以下に本発明の詳細について説明する。本発明でいうアクリル共重合体とは、ァク リロ-トリルを 30重量%以上含有している重合体が用いられる。アクリロニトリルが 30 重量%未満であると繊維の耐熱性が悪化する。また、アクリロニトリルの他にこれと共 重合しうるビニル系単量体を用いて重合してもよ 、。共重合しうるビニル系単量体とし ては、塩化ビュル、塩ィ匕ビユリデン、臭化ビュル、臭化ビ-リデン、アクリル酸エステ ル、メタクリル酸エステル、アクリルアミド、又はそれらのモ入又はジアルキル置換体 、アクリル酸、メタクリル酸、ィタコン酸、スチレンスルホン酸、メタリルスルホン酸、メタ クロィルォキシベンゼンスルホン酸、メタクロィルォキシプロピルスルホン酸、又はこれ らの金属塩類、及びアンモニゥムゃァミン塩類、グリシジルアルキレート、グリシジルメ タクリレート、アクリルグリシジルエーテル、メタリルグリシジルエーテル等がある。これ らの中でも塩ィ匕ビニル、塩ィ匕ビユリデンが好ましい。上記の重合体を、有機溶剤、例 えばアセトン、ァセトニトリル、ジメチルホルムアミド等に溶解させて紡糸原液とする。 なお、必要に応じて、耐光性等に効果のある安定剤等を添加してもよい。また、光沢 の調整のために種々の添加剤を適量カ卩えても差し支えない。さらに、着色繊維とする ために、適宜顔料、染料等を使用してもよい。 Hereinafter, the present invention will be described in detail. As the acrylic copolymer in the present invention, a polymer containing 30% by weight or more of acrylo-tolyl is used. If the content of acrylonitrile is less than 30% by weight, the heat resistance of the fiber deteriorates. Further, the polymerization may be performed using a vinyl monomer copolymerizable with acrylonitrile in addition to acrylonitrile. Examples of the copolymerizable vinyl monomer include: vinyl chloride, vinyl chloride bilidene, vinyl bromide, vinylidene bromide, ester acrylate, methacrylic ester, acrylamide, or a modified or dialkyl-substituted product thereof. Body, acrylic acid, methacrylic acid, itaconic acid, styrene sulfonic acid, methallyl sulfonic acid, methacryloxybenzene sulfonic acid, methacryloxypropyl sulfonic acid, or metal salts thereof, and ammonium nitramine salts, Examples include glycidyl alkylate, glycidyl methacrylate, acrylic glycidyl ether, methallyl glycidyl ether, and the like. Among them, Shiojiri vinyl and Shiridani biylidene are preferred. The above polymer is dissolved in an organic solvent, for example, acetone, acetonitrile, dimethylformamide or the like to prepare a spinning solution. Note that, if necessary, a stabilizer or the like having an effect on light resistance or the like may be added. Also, various additives may be added in appropriate amounts for adjusting the gloss. Further, pigments, dyes, and the like may be used as appropriate to obtain colored fibers.
[0010] 上記の紡糸原液を通常、湿式あるいは乾式の紡糸法でノズルより紡出し、延伸、熱 処理を行っても良い。得られた糸条を 90〜150°C、好ましくは 115°C〜140°Cで 1. 2〜4. 0倍に延伸して、 100°Cで 30分処理における乾熱収縮率が 5%以上有する収 縮性繊維を得ることができる。延伸温度が 90°Cより低!ヽと繊維への熱伝導が不十分 で所定の延伸倍率まで延伸する事が困難となる。また、 150°Cを超えると、延伸可能 ではあるが収縮率が低下してしまう為好ましくない。なお、本発明の人工毛髪用収縮 性繊維が有する乾熱収縮率は、乾熱 100°C X 30分で 5%以上、好ましくは 10%以 上である。乾熱収縮率が 5%に満たない人工毛髪用繊維は、捲縮の付与性が悪ぐ 満足できる嵩高性が得られな 、。 [0010] Usually, the above spinning stock solution may be spun from a nozzle by a wet or dry spinning method, stretched, and heat-treated. The obtained yarn is heated at 90 to 150 ° C, preferably at 115 to 140 ° C. 1. It is possible to obtain a shrinkable fiber having a dry heat shrinkage of 5% or more in a treatment at 100 ° C. for 30 minutes by stretching it by a factor of 2 to 4.0. When the stretching temperature is lower than 90 ° C! ヽ, heat conduction to the fiber is insufficient and it is difficult to stretch to a predetermined stretching ratio. On the other hand, when the temperature exceeds 150 ° C., although the film can be stretched, the shrinkage ratio is undesirably reduced. The shrinkage ratio of the heat-shrinkable fiber for artificial hair of the present invention is 5% or more, preferably 10% or more at a dry heat of 100 ° C for 30 minutes. Fibers for artificial hair having a dry heat shrinkage ratio of less than 5% have poor crimp-giving properties and cannot provide satisfactory bulkiness.
[0011] 本発明の人工毛髪用収縮性繊維の断面形状については特に限定されないが、人 ェ毛髪としての嵩高性やカール特性や櫛通り性等の美容特性を勘案すると、断面形 状としては、馬蹄型、 C字型、中空型、楕円型、円型、亜鈴型及び Y字型などが適し ているが、十分な嵩高さを得るためには、馬蹄型、 C字型、亜鈴型および Y字型が好 ましぐ特に Y字型の断面が嵩高さの点から優れているため好ましい。  [0011] The cross-sectional shape of the shrinkable fiber for artificial hair of the present invention is not particularly limited, but in consideration of the bulkiness, curl characteristics, combability, and other cosmetic characteristics of human hair, the cross-sectional shape is A horseshoe, C, hollow, elliptical, circular, dumbbell and Y-shape are suitable, but a horseshoe, C-shaped, dumbbell and Y A letter shape is preferred, and a Y-shaped section is preferred because it is excellent in terms of bulkiness.
[0012] 本発明でいう乾熱収縮率とは、乾熱 100°Cにおける収縮率を意味するものであり、 具体的には、 1デシテックス当たり lOmgZデシテックス荷重下の試長 (Lw)を測定し 、収縮は、対流型オーブン中で乾熱 100°C、 30分処理で収縮させた後、室温に戻し lOmgZデシテックス荷重下の試長 (LV)を測定し、下記式により収縮率を求めた。 乾熱収縮率(%) =((Lw—! w)/Lw) X 100  [0012] The dry heat shrinkage ratio in the present invention means a shrinkage ratio at a dry heat of 100 ° C. Specifically, a test length (Lw) under lOmgZ decitex load per decitex is measured. The shrinkage was determined by shrinking in a convection oven by dry heat treatment at 100 ° C. for 30 minutes, returning to room temperature, measuring the test length (LV) under a lOmgZ decitex load, and calculating the shrinkage ratio by the following equation. Dry heat shrinkage (%) = ((Lw-! W) / Lw) X 100
また、乾熱収縮率の処理温度は、乾熱 80°C下で 1%以上、好ましくは 2%以上。乾 熱 90°C下で 2%以上、好ましくは 4%以上。乾熱 110°C下では 10%以上、好ましくは 15%以上となり処理温度により収縮率は変化していく。  The processing temperature of the dry heat shrinkage is 1% or more, preferably 2% or more under dry heat of 80 ° C. 2% or more, preferably 4% or more at 90 ° C. Under dry heat of 110 ° C, the shrinkage ratio is 10% or more, preferably 15% or more, and the shrinkage ratio changes depending on the processing temperature.
発明の人工毛髪用収縮性繊維における単繊維繊度は、 25〜95デシテックスの範 囲が望ましいが、好ましくは、 30〜80デシテックスである。 25デシテックス未満では 人工毛髪としての外観上細すぎ、且つ柔らかすぎ、 95デシテックスを超えると太すぎ るため風合いが硬すぎて、いずれの場合も人工毛髪用の原料として不適である。  The single fiber fineness of the shrinkable fiber for artificial hair of the present invention is desirably in the range of 25 to 95 dtex, but is preferably 30 to 80 dtex. If it is less than 25 dtex, the appearance as artificial hair is too thin and too soft. If it exceeds 95 dtex, it is too thick and the texture is too hard. In any case, it is unsuitable as a raw material for artificial hair.
[0013] 本発明に係る人工毛髪用収縮性繊維を頭髪用繊維束とする場合には、繊維に捲 縮加工を施すことが好ましい。捲縮加工を施す方法としては、 2本のヒーター式歯車 のギヤロールに繊維を挟んで連続的に波形形状の捲縮を付与するギヤクリンプ法ゃ 蒸気等で加熱した繊維をスタッフイングボックス等に連続的に押し込んで捲縮を付与 するスタッフイングボックス法等がある力 頭髪装飾用途として必要な捲縮形状を付 与すれば良ぐ本発明でいう捲縮加工は、ギヤクリンプ法が一般的であり、この方法 が作業性等の観点から最も好ましい。これらの方法により、目的とする商品にあった 波形形状の捲縮を付与する事でブレード、エクステンションヘアー等の加工性が向 上する。本発明の人工毛髪用収縮性繊維及び繊維束は、かつら、ヘアピース、ブレ ード、エクステンションヘアー、又はドールヘアー等の頭髪装飾用として用いるもので あるが、ギヤクリンプ等の捲縮加工を施した繊維束は、上記頭飾用繊維束の中でも、 特にブレード、エクステンションヘアー等に好適である。 [0013] When the shrinkable fiber for artificial hair according to the present invention is used as a fiber bundle for hair, it is preferable to crimp the fiber. The crimping method is performed by a gear crimping method in which the fibers are sandwiched between gear rolls of two heater-type gears and a continuous crimp is applied. The fibers heated by steam or the like are continuously transferred to a stuffing box or the like. To give crimp The crimping method referred to in the present invention, which is good if a crimped shape required for hair decoration applications, is generally provided by a gear crimping method. Is most preferred. These methods improve the workability of blades, extension hairs, and the like by imparting a crimp in a corrugated shape suitable for the target product. The shrinkable fibers and fiber bundles for artificial hair of the present invention are used for hair decoration such as wigs, hairpieces, blades, extension hairs, doll hairs, etc., and are crimped fibers such as gear crimps. The bundle is particularly suitable for the blade, the extension hair and the like among the above head decoration fiber bundles.
[0014] 本発明における見掛け嵩高さとは、以下の条件により測定されるものである。すな わち、捲縮前の繊維束を正確に lmに切り揃え、 l lOgを計り取り、繊維束 Fとする。こ の繊維束 Fを図 1 (ィ)に示すような、長さ(L) X幅 (W) = 30cm X 6cmで両端が開放 された溝を有する溝状容器 1に静置し、上カゝら溝と同寸法の薄板 2を静かに置いて、 0. 25gZcm2の荷重をかけ、 1分間経過後の溝状容器 1内にある高さ Hを測定した。 Hは、図 1 (口)に示す溝状容器 1の内側底辺から薄板 2下面までの高さ(cm)である。  [0014] The apparent bulkiness in the present invention is measured under the following conditions. That is, the fiber bundle before crimping is cut exactly to lm, and the lOg is measured and taken as fiber bundle F. This fiber bundle F is placed in a grooved container 1 having a length (L) X width (W) = 30 cm x 6 cm and a groove open at both ends as shown in Fig. 1 (a). The thin plate 2 having the same dimensions as the flat groove was gently placed, a load of 0.25 gZcm2 was applied, and the height H in the grooved container 1 after 1 minute was measured. H is the height (cm) from the inner bottom side of the grooved container 1 shown in FIG.
[0015] またソフト感、嵩高性、操業性、総合評価は、以下に示す方法に従って調べた。そ の結果を表 1に示す。  [0015] Softness, bulkiness, operability, and overall evaluation were examined according to the methods described below. The results are shown in Table 1.
[0016] ソフト感は、 5名で官能テスト (捲縮加工後の繊維束の柔らかさ)を行って判断した。  [0016] The soft feeling was judged by performing a sensory test (softness of the fiber bundle after crimping) by five persons.
嵩高性は、見掛け嵩高さと捲縮後の繊維束及び三つ編み商品のボリューム感を評価 した。操業性は、実施例記載のクリンプ加工機械を用いたギアクリンプ法での捲縮付 与性にっ 、て、すなわちギアの波形に近 、クリンプが得られるかにつ 、て評価を行 つた。総合評価は、ソフト感、嵩高性、操業性において全て満足できるものを合格 (〇 )、それ以外の場合を不合格とした。  The bulkiness was evaluated based on the apparent bulkiness and the volume feeling of the fiber bundle and the braided product after crimping. The operability was evaluated based on the crimpability by the gear crimping method using the crimping machine described in the Examples, that is, whether the crimping was close to the gear waveform or not. In the overall evaluation, those satisfying all of softness, bulkiness and operability were judged as acceptable (〇), and other cases were judged as failed.
実施例  Example
[0017] (実施例 1)  (Example 1)
アクリロニトリル 49重量0 /0、塩化ビュル 50重量0 /0、スチレンスルホン酸ソーダ 1重量 %からなる共重合体榭脂をアセトンに溶解し、更にカーボンブラック 0. 6重量%,力 チオン液状染料 (保土谷ィ匕学製)レッド; 0. 25重量%,イェロー; 0. 4%重量%をを 添加させ、 27. 5重量%の紡糸原液を調整した。この紡糸原液を亜鈴型紡糸ノズル を用いて、ノズルドラフト 1. 1で 20重量%で20でのアセトン水溶液中に紡出し、得ら れた繊維を水洗浴 60°Cで脱溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処 理後、 120°Cで 2. 5倍の乾熱延伸を行った。こうして得られた繊維の単糸繊度は 50 dtexであり、乾熱収縮率は 13. 3%であった。得られた繊維を束ねて総繊度 113万 d texとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、高さ H = 1. 4cmあった。この繊維束をギヤ一ピッチ = 8mm、ギヤ一深さ = 5mmのギヤタリ ンプ加工機械を用いて、捲縮を付与した後、櫛で十分に整条し、見掛けの嵩高さを 前記と同様の測定器で測定した所、高さ H = 7. 95cmであった。また、前記測定条 件と同じ条件の捲縮加工を施し整条した繊維束を、代表的なブレードである 5g X 30 段(レギュラーサイズ)の三つ編み商品とし、ブレードとしての嵩高性とソフト感及び捲 縮付与性等操業性について官能評価を行い、総合評価を行った。これらの結果を表 1に示した。 Acrylonitrile 49 wt 0/0, chloride Bulle 50 weight 0/0, the copolymer榭脂of styrene sulfonate sodium 1 wt% was dissolved in acetone, further carbon black 0.6 wt%, the force thione liquid dyestuff (coercive (Tsuchiya-Danigaku) red; 0.25% by weight, yellow; 0.4% by weight were added to prepare a 27.5% by weight stock solution for spinning. This spinning solution is added to the dumbbell spinning nozzle. Using a nozzle draft 1.1 at 20% by weight in an aqueous acetone solution at 20 and spin-drying the resulting fiber in a washing bath at 60 ° C and drawing 1.5 times. After drying at ° C, the film was stretched by a factor of 2.5 at 120 ° C. The single yarn fineness of the fiber thus obtained was 50 dtex, and the dry heat shrinkage was 13.3%. The resulting fibers were bundled to a total fineness of 1.13 million dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height H was 1.4 cm. This fiber bundle is crimped by using a gear turret processing machine with a gear pitch = 8 mm and a gear depth = 5 mm, and then fully trimmed with a comb to measure the apparent bulkiness as described above. The height H was 7.95 cm when measured with a vessel. In addition, a fiber bundle that has been crimped and aligned under the same measurement conditions as the above is used as a typical braided product of 5 g × 30 steps (regular size), and the bulkiness and softness of the blade are A sensory evaluation was conducted for operability such as feeling and crimpability, and a comprehensive evaluation was performed. Table 1 shows the results.
[0018] (実施例 2)  (Example 2)
実施例 1と同様の紡糸原液を用いて、 Y字型紡糸ノズルを用いて、ノズルドラフト 1. 2で 25重量%で18でのアセトン水溶液に紡糸した。この繊維は、実施例 1と同様の 方法で乾燥〜乾熱延伸を行った。こうして得られた繊維の単糸繊度は 51dtexであり 、乾熱収縮率は 12. 5%であった。得られた繊維を束ねて総繊度 113万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、高さ H = 2. 5cmあ つた。又、この繊維束を実施例 1と同様にクリンプ加工機械を用いて、捲縮を付与し 整条した後、見掛けの嵩高さを測定した所、高さ H = 9. 80cmであった。この捲縮束 を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、代表的なブレードであ る 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレードとしての嵩高性とソフト 感及び捲縮付与性等操業性について官能評価を行い、総合評価を行った。これら の結果を表 1に示した。  Using the same spinning dope as in Example 1, using a Y-shaped spinning nozzle, the solution was spun at 25% by weight into an aqueous acetone solution at 18 at 25% by nozzle draft 1.2. This fiber was subjected to dry to dry heat drawing in the same manner as in Example 1. The single fiber fineness of the fiber thus obtained was 51 dtex, and the dry heat shrinkage was 12.5%. The resulting fibers were bundled to a total fineness of 1.13 million dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 2.5 cm. Further, this fiber bundle was crimped and straightened using a crimping machine in the same manner as in Example 1, and the apparent bulk was measured. The height was H = 9.80 cm. This crimped bundle was subjected to crimping in the same manner as in Example 1, and the aligned fiber bundle was converted into a typical braided product of 5 g × 30 steps (regular size) as a typical braid. A sensory evaluation was performed on the bulkiness, operability such as softness and crimpability, and a comprehensive evaluation was performed. Table 1 shows these results.
[0019] (実施例 3)  (Example 3)
実施例 1と同様の紡糸原液を用いて、馬蹄型紡糸ノズルを用いて、ノズルドラフト 1 . 1で 20重量%で20でのアセトン水溶液に紡糸した。この繊維は、実施例 1と同様の 方法で乾燥〜乾熱延伸を行った。こうして得られた繊維の単糸繊度は 55. 6dtexで あり、乾熱収縮率は 15. 1%であった。得られた繊維を束ねて総繊度 113万 dtexとし 、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、高さ H= l . 6c mあった。又、この繊維束を実施例と同様にクリンプ加工機械を用いて、捲縮を付与 し整条した後、見掛けの嵩高さを測定した所、高さ H = 8. 22cmであった。又、この 捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、代表的なブレ ードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレードとしての嵩高 性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合評価を行った 。これらの結果を表 1に示した。 Using the same spinning dope as in Example 1, using a horseshoe-type spinning nozzle, the solution was spun into an aqueous acetone solution at 20% by weight at 20% by nozzle draft 1.1. This fiber was subjected to dry to dry heat drawing in the same manner as in Example 1. The fiber fineness of the fiber thus obtained is 55.6 dtex. And the dry heat shrinkage was 15.1%. The obtained fibers were bundled to a total fineness of 1.13 million dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 1.6 cm. Further, this fiber bundle was crimped and aligned using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 8.22 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1 and straightened into a fiber bundle. The resulting braid was a typical braid of 5 g x 30 steps (regular size), A sensory evaluation was conducted on the operability such as the bulkiness, softness, and crimpability as a blade, and a comprehensive evaluation was performed. Table 1 shows the results.
(実施例 4) (Example 4)
実施例 1と同様の紡糸原液を用いて、亜鈴型紡糸ノズルを用いて、ノズルドラフト 1 . 1で 20重量%で20でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処理後、 120°Cで 1. 8倍の乾 熱延伸を行った。こうして得られた繊維の単糸繊度は 50dtexであり、乾熱収縮率は 5. 3%であった。得られた繊維を束ねて総繊度 113万 dtexとし、図 1に示す測定容 器にて、捲縮前の見掛けの嵩高さを測定した所、高さ H= l . 5cmあった。又、この繊 維束を実施例と同様にクリンプ加工機械を用いて、捲縮を付与し整条した後、見掛け の嵩高さを測定した所、高さ H = 6. 70cmであった。又、この捲縮束を、実施例 1と同 様にして捲縮加工を施し整条した繊維束を、代表的なブレードである 5g X 30段(レ ギュラーサイズ)の三つ編み商品とし、ブレードとしての嵩高性とソフト感及び捲縮付 与性等操業性について官能評価を行い、総合評価を行った。これらの結果を表 1〖こ 示した。  Using the same spinning dope as in Example 1, using a dumbbell-type spinning nozzle, the solution was spun into an aqueous acetone solution at 20% by weight in a nozzle draft 1.1 at 20%, and the resulting fiber was washed in a water washing bath at 60 ° C After removing the solvent and stretching by 1.5 times, the film was dried at 130 ° C and then stretched by dry heat at 120 ° C by 1.8 times. The single fiber fineness of the fiber thus obtained was 50 dtex, and the dry heat shrinkage was 5.3%. The obtained fibers were bundled to a total fineness of 1.13 million dtex, and the apparent bulkiness before crimping was measured with a measuring container shown in FIG. 1 to find that the height was H = 1.5 cm. Further, this fiber bundle was crimped and straightened using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 6.70 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1, and the aligned fiber bundle was used as a typical braided braid of 5 g x 30 steps (regular size), A sensory evaluation was performed on the operability such as the bulkiness, softness, and crimp impartability of the blade, and a comprehensive evaluation was performed. The results are shown in Table 1.
(比較例 1)  (Comparative Example 1)
実施例 1と同様の紡糸原液を用いて、亜鈴型紡糸ノズルを用いて、ノズルドラフト 1 . 4で 20重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処理後、 120°Cで 2. 5倍の乾 熱延伸を行い、更に 145°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 46dtexであり、乾熱収縮率は 1. 5%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H= l . 3cmあった。又、この繊維束を実施例と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 5. 50cmであ つた。又、この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、 代表的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレード としての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合 評価を行った。これらの結果を表 1に示した。 Using the same spinning solution as in Example 1, using a dumbbell-type spinning nozzle, the solution was spun into an aqueous acetone solution at 20% by weight in a nozzle draft 1.4 at 18 and the obtained fiber was washed in a water washing bath at 60 ° C. After removing the solvent and stretching by 1.5 times, followed by drying at 130 ° C, stretching by dry heat of 2.5 times at 120 ° C and relaxation heat treatment at 145 ° C. The single yarn fineness of the fiber thus obtained was 46 dtex, and the dry heat shrinkage was 1.5%. The obtained fibers were bundled to a total fineness of 1130,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1, Height H = l. 3 cm. Further, this fiber bundle was crimped and trimmed using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 5.50 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1 and straightened into a fiber bundle. The resulting braid was a typical braid of 5 g × 30 steps (regular size) braided product. An organoleptic evaluation was performed on the bulkiness, softness, and crimpability of the operability, and a comprehensive evaluation was performed. Table 1 shows the results.
[0021] (比較例 2)  (Comparative Example 2)
実施例 1と同様の紡糸原液を用いて、亜鈴型紡糸ノズルを用いて、ノズルドラフト 1 . 4で 20重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処理後、 120°Cで 2. 5倍の乾 熱延伸を行い、更に 150°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 51dtexであり、乾熱収縮率は 1. 1%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H= l . 4cmあった。又、この繊維束を実施例と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 6. 15cmであ つた。又、この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、 代表的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレード としての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合 評価を行った。これらの結果を表 1に示した。  Using the same spinning solution as in Example 1, using a dumbbell-type spinning nozzle, the solution was spun into an aqueous acetone solution at 20% by weight in a nozzle draft 1.4 at 18 and the obtained fiber was washed in a water washing bath at 60 ° C. After removing the solvent and stretching by 1.5 times, the film was dried at 130 ° C, stretched by dry heat at 120 ° C by 2.5 times, and further subjected to relaxation heat treatment at 150 ° C. The single yarn fineness of the fiber thus obtained was 51 dtex, and the dry heat shrinkage was 1.1%. The obtained fibers were bundled to a total fineness of 110,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 1.4 cm. Further, this fiber bundle was crimped and trimmed using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 6.15 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1 and straightened into a fiber bundle. The resulting braid was a typical braid of 5 g × 30 steps (regular size) braided product. An organoleptic evaluation was performed on the bulkiness, softness, and crimpability of the operability, and a comprehensive evaluation was performed. Table 1 shows the results.
[0022] (比較例 3)  (Comparative Example 3)
実施例 1と同様の紡糸原液を用いて、馬蹄型紡糸ノズルを用いて、ノズルドラフト 1 . 4で 20重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処理後、 120°Cで 2. 8倍の乾 熱延伸を行い、更に 130°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 43dtexであり、乾熱収縮率は 4. 2%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H= l . 3cmあった。又、この繊維束を実施例と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 5. 95cmであ つた。又、この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、 代表的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレード としての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合 評価を行った。これらの結果を表 1に示した。 Using the same spinning dope as in Example 1, using a horseshoe-type spinning nozzle, a nozzle draft 1.4 spins out 20% by weight into an aqueous acetone solution at 18 at 20% by weight. After removing the solvent and stretching by 1.5 times, the film was dried at 130 ° C, stretched by 2.8 times at 120 ° C, and further subjected to relaxation heat treatment at 130 ° C. The single yarn fineness of the fiber thus obtained was 43 dtex, and the dry heat shrinkage was 4.2%. The obtained fibers were bundled to a total fineness of 110,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 1.3 cm. Also, after applying a crimp to the fiber bundle and crimping it using a crimping machine in the same manner as in the example, the apparent bulkiness was measured, and the height H was found to be 5.95 cm. I got it. The crimped bundle was subjected to crimping in the same manner as in Example 1 and straightened into a fiber bundle. The resulting braid was a typical braid of 5 g × 30 steps (regular size) braided product. An organoleptic evaluation was performed on the bulkiness, softness, and crimpability of the operability, and a comprehensive evaluation was performed. Table 1 shows the results.
(比較例 4) (Comparative Example 4)
実施例 1と同様の紡糸原液を用いて、亜鈴型紡糸ノズルを用いて、ノズルドラフト 1 . 4で 20重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 130°Cで乾燥処理後、 140°Cで 2. 5倍の乾 熱延伸を行い、更に 155°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 50dtexであり、乾熱収縮率は 3. 5%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H= l . 5cmあった。又、この繊維束を実施例と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 5. 8cmであ つた。又、この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、 代表的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレード としての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合 評価を行った。これらの結果を表 1に示した。  Using the same spinning solution as in Example 1, using a dumbbell-type spinning nozzle, the solution was spun into an aqueous acetone solution at 20% by weight in a nozzle draft 1.4 at 18 and the obtained fiber was washed in a water washing bath at 60 ° C. After removing the solvent and stretching by 1.5 times, the film was dried at 130 ° C, stretched by dry heat at 140 ° C by 2.5 times, and further subjected to relaxation heat treatment at 155 ° C. The single yarn fineness of the fiber thus obtained was 50 dtex, and the dry heat shrinkage was 3.5%. The obtained fibers were bundled to a total fineness of 110,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 1.5 cm. Further, this fiber bundle was crimped and trimmed using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 5.8 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1 and straightened into a fiber bundle. The resulting braid was a typical braid of 5 g × 30 steps (regular size) braided product. An organoleptic evaluation was performed on the bulkiness, softness, and crimpability of the operability, and a comprehensive evaluation was performed. Table 1 shows the results.
(比較例 5) (Comparative Example 5)
実施例 1と同様の紡糸原液を用いて、 Y字型紡糸ノズルを用いて、ノズルドラフト 1. 2で 20重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 125°Cで乾燥処理後、 135°Cで 2. 5倍の乾 熱延伸を行い、更に 145°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 32dtexであり、乾熱収縮率は 1. 2%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H = 2. 1cmあった。又、この繊維束を実施例と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 7. 55cmであ つた。又、この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、 代表的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレード としての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合 評価を行った。これらの結果を表 1に示した。 Using the same spinning dope as in Example 1, using a Y-shaped spinning nozzle, the mixture was spun into an aqueous acetone solution at 18 at 20% by weight with a nozzle draft of 1.2, and the resulting fiber was washed in a washing bath at 60 ° C. The solvent was removed and stretched 1.5 times, followed by drying at 125 ° C, followed by 2.5 times dry heat stretching at 135 ° C, and relaxation heat treatment at 145 ° C. The single yarn fineness of the fiber thus obtained was 32 dtex, and the dry heat shrinkage was 1.2%. The resulting fibers were bundled to a total fineness of 110,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 2.1 cm. Further, this fiber bundle was crimped and trimmed using a crimping machine in the same manner as in the example, and the apparent bulkiness was measured. The height was H = 7.55 cm. The crimped bundle was subjected to crimping in the same manner as in Example 1, and the aligned fiber bundle was used as a typical braided braid of 5 g × 30 steps (regular size), which was a blade. The sensory evaluation was carried out for the bulkiness, softness, crimpability and other operability, and a comprehensive evaluation was performed. Table 1 shows the results.
(比較例 6) (Comparative Example 6)
実施例 1と同様の紡糸原液を用いて、 Y字型紡糸ノズルを用いて、ノズルドラフト 1. 2で 25重量%で18でのアセトン水溶液に紡出し、得られた繊維を水洗浴 60°Cで脱 溶剤及び 1. 5倍の延伸を行い、次いで 135°Cで乾燥処理後、 130°Cで 2. 5倍の乾 熱延伸を行い、更に 148°Cで弛緩熱処理を行った。こうして得られた繊維の単糸繊 度は 51dtexであり、乾熱収縮率は 1. 0%であった。得られた繊維を束ねて総繊度 1 13万 dtexとし、図 1に示す測定容器にて、捲縮前の見掛けの嵩高さを測定した所、 高さ H = 2. 5cmあった。又、この繊維束を実施例 1と同様にクリンプ加工機械を用い て、捲縮を付与し整条した後、見掛けの嵩高さを測定した所、高さ H = 7. Ocmであ つた。この捲縮束を、実施例 1と同様にして捲縮加工を施し整条した繊維束を、代表 的なブレードである 5g X 30段(レギュラーサイズ)の三つ編み商品とし、ブレードとし ての嵩高性とソフト感及び捲縮付与性等操業性にっ ヽて官能評価を行 ヽ、総合評 価を行った。これらの結果を表 1に示した  Using the same spinning dope as in Example 1, using a Y-shaped spinning nozzle, the fiber was spun into a 25% by weight aqueous acetone solution at 18 with a nozzle draft of 1.2, and the resulting fiber was washed in a washing bath at 60 ° C. The solvent was removed and the film was stretched 1.5 times, then dried at 135 ° C, stretched at 130 ° C by 2.5 times, and further subjected to relaxation heat treatment at 148 ° C. The single yarn fineness of the fiber thus obtained was 51 dtex, and the dry heat shrinkage was 1.0%. The resulting fibers were bundled to a total fineness of 110,000 dtex, and the apparent bulkiness before crimping was measured in the measurement container shown in FIG. 1 to find that the height was H = 2.5 cm. Further, the fiber bundle was crimped and aligned using a crimping machine in the same manner as in Example 1, and the apparent bulkiness was measured. The height was H = 7.0 cm. This crimped bundle was crimped and straightened in the same manner as in Example 1 to obtain a typical braided braid of 5 g x 30 steps (regular size), which was used as a braid. An organoleptic evaluation was conducted on the operability such as bulkiness, softness and crimpability, and a comprehensive evaluation was performed. These results are shown in Table 1.
[表 1] [table 1]
断 ¾ 繊度 乾熱 見掛け嵩高さ 嵩高性 操業性 総合評 収縮率 、cm) 感官 官能 価 (%) 捲縮前 捲縮後 評価 評価 Insulation fineness Dry heat Apparent bulkiness Bulkiness Operability Overall rating Shrinkage rate, cm) Sensuality (%) Evaluation before crimping Evaluation after crimping
実施 亜鈴 © 〇 〇 〇 例 §u Implement Arin © 〇 〇 〇 Example §u
実施 Y字 5 1 1 2. 2. 5 0 〇 ◎ 〇 〇 例 2 Implementation Y-shaped 5 1 1 2.2.5 0 〇 ◎ 〇 〇 Example 2
実施 馬蹄 55. 1. 6 ◎ O 〇 例 3 6 Implementation Horseshoe 55.1.6 ◎ O 〇 Example 3 6
実施 亜鈴 0 〇 〇 〇 〇 例 4 Implementation Arin 0 〇 〇 〇 〇 Example 4
比較 亜鈴 〇 Compare Arin 〇
例 ¾ Example ¾
比較 亜鈴 51 1. 4 〇 Comparison Arin 51 1.4 〇
例 2 型 Example 2 type
比較 馬蹄 43 1. 3 〇 Comparison Horseshoe 43 1.3 〇
例 3 Example 3
比較 亜鈴 50 1. 5 0 Δ Comparison Arin 50 1.5 0 Δ
An example
比較 Y字 32 1 2. 1 © Comparison Y character 32 1 2. 1 ©
例 5 m[ Example 5 m [
比較 Y字 51. 2. 5 〇 〇 Comparison Y character 51.2.5 5 〇
例 6 1 Example 6 1
注) 評価法及び官能評価基準 Note) Evaluation method and sensory evaluation criteria
ト感)  Feeling
方法 =官能テストによる。 Method = By sensory test.
◎:非常に柔ら 〇 柔ら力、い、 Δ:やや硬い、 :硬  ◎: very soft 〇 soft, good, Δ: slightly hard,: hard
(嵩高' )  (Bulky)
©:非常に優れる、 〇:優れる、 △:やや劣る、 :劣る。  ©: very good, 〇: good, Δ: slightly poor,: poor.
(総合評価)  (Comprehensive evaluation)
〇:合格、 :不合格。  〇: passed,: failed.

Claims

請求の範囲 The scope of the claims
[1] アクリル-トリルを 30重量%以上含有するアクリル系重合体力 なる人工毛髪用繊 維であって、 100°Cで 30分処理における乾熱収縮率が 5%以上を有し、単糸繊度が [1] An acrylic polymer fiber containing 30% by weight or more of acryl-tolyl, which is a fiber for artificial hair that has a dry heat shrinkage of 5% or more when treated at 100 ° C for 30 minutes, and has a single-fiber fineness. But
25〜95デシテックスである事を特徴とする人工毛髪用収縮性繊維。 Shrinkable fiber for artificial hair, which is 25 to 95 decitex.
[2] 紡糸後の糸条を 90〜150°Cで 1. 2〜4. 0倍に延伸したことを特徴とする請求項 1 記載の人工毛髪用収縮繊維。 [2] The shrinkable fiber for artificial hair according to claim 1, wherein the spun yarn is stretched 1.2 to 4.0 times at 90 to 150 ° C.
[3] 捲縮加工後の見掛け嵩高さが 6. 5cm以上であることを特徴とする請求項 1または 請求項 2記載の人工毛髪用収縮繊維。 3. The shrinkable fiber for artificial hair according to claim 1, wherein the apparent bulk after crimping is 6.5 cm or more.
[4] 繊維が頭髪装飾用である請求項 1〜3いずれかに記載の人工毛髪用収縮性繊維。 [4] The shrinkable fiber for artificial hair according to any one of claims 1 to 3, wherein the fiber is for hair decoration.
[5] 頭髪装飾が、かつら、ヘアピース、ブレード、エクステンションヘアー、又はドールへ ァーである請求項 4記載の人工毛髪用収縮性繊維。 5. The contractible fiber for artificial hair according to claim 4, wherein the hair decoration is a wig, a hairpiece, a blade, an extension hair, or a doll hair.
[6] 請求項 1〜3 ヽずれかに記載の人工毛髪用性繊維に捲縮加工を施した繊維束を 形成してなることを特徴とする頭飾用繊維束。 [6] A head decoration fiber bundle obtained by forming a crimped fiber bundle on the artificial hair property fiber according to any one of claims 1 to 3.
[7] ギヤクリンプ法による捲縮加工を施したことを特徴とする請求項 6記載の頭飾用繊 維束。 7. The head decoration fiber bundle according to claim 6, wherein a crimping process is performed by a gear crimp method.
[8] 繊維束が、かつら、ヘアピース、ブレード、エクステンションヘアー、又はドールヘア 一である請求項 6または請求項 7記載の頭飾用繊維束。  8. The head decoration fiber bundle according to claim 6, wherein the fiber bundle is a wig, a hairpiece, a blade, an extension hair, or a doll hair.
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