WO2005081715A3 - Gasoline sulfur reduction using hydrotalcite like compounds - Google Patents

Gasoline sulfur reduction using hydrotalcite like compounds Download PDF

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Publication number
WO2005081715A3
WO2005081715A3 PCT/US2004/039305 US2004039305W WO2005081715A3 WO 2005081715 A3 WO2005081715 A3 WO 2005081715A3 US 2004039305 W US2004039305 W US 2004039305W WO 2005081715 A3 WO2005081715 A3 WO 2005081715A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrotalcite
compounds
compound
gasoline
magnesium
Prior art date
Application number
PCT/US2004/039305
Other languages
French (fr)
Other versions
WO2005081715A2 (en
Inventor
Albert A Vierheilig
Bruce Keener
Original Assignee
Intercat Inc
Albert A Vierheilig
Bruce Keener
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/729,270 external-priority patent/US7431825B2/en
Application filed by Intercat Inc, Albert A Vierheilig, Bruce Keener filed Critical Intercat Inc
Priority to CA002548167A priority Critical patent/CA2548167C/en
Priority to AU2004316294A priority patent/AU2004316294B2/en
Priority to CN2004800398564A priority patent/CN101072849B/en
Priority to MXPA06006414A priority patent/MXPA06006414A/en
Priority to EP04821528A priority patent/EP1702027A4/en
Priority to JP2006542627A priority patent/JP2007517925A/en
Publication of WO2005081715A2 publication Critical patent/WO2005081715A2/en
Publication of WO2005081715A3 publication Critical patent/WO2005081715A3/en
Priority to AU2010202087A priority patent/AU2010202087A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B01J35/19—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C10G11/182—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The present invention describes novel methods for reducing sulfur in gasoline with hydrotalcite like compound additives, calcined hydrotalcite like compounds, and/or mixed metal oxide solution solutions. The additives can optionally further comprise one or more metallic oxidants and/or supports. The invention is also directed to methods for reducing gasoline sulfur comprising contacting a catalytic cracking feedstock with a mixed metal oxide compound comprising magnesium and aluminum and having an X-ray diffraction pattern displaying a reflection at least at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 1:1 to about 10:1.
PCT/US2004/039305 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds WO2005081715A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA002548167A CA2548167C (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds
AU2004316294A AU2004316294B2 (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds
CN2004800398564A CN101072849B (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds
MXPA06006414A MXPA06006414A (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds.
EP04821528A EP1702027A4 (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds
JP2006542627A JP2007517925A (en) 2003-12-05 2004-11-22 Reduction of gasoline sulfur using hydrotalcite-like compounds
AU2010202087A AU2010202087A1 (en) 2003-12-05 2010-05-24 Gasoline sulfur reduction using hydrotalcite like compounds

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/729,270 US7431825B2 (en) 2003-12-05 2003-12-05 Gasoline sulfur reduction using hydrotalcite like compounds
US10/729,270 2003-12-05
US10/749,695 US7347929B2 (en) 2003-12-05 2003-12-31 Gasoline sulfur reduction using hydrotalcite like compounds
US10/749,695 2003-12-31

Publications (2)

Publication Number Publication Date
WO2005081715A2 WO2005081715A2 (en) 2005-09-09
WO2005081715A3 true WO2005081715A3 (en) 2006-05-18

Family

ID=34915761

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/039305 WO2005081715A2 (en) 2003-12-05 2004-11-22 Gasoline sulfur reduction using hydrotalcite like compounds

Country Status (7)

Country Link
EP (1) EP1702027A4 (en)
JP (1) JP2007517925A (en)
KR (1) KR20060124664A (en)
AR (1) AR047402A1 (en)
AU (1) AU2004316294B2 (en)
CA (1) CA2548167C (en)
WO (1) WO2005081715A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5269321B2 (en) * 2007-01-11 2013-08-21 株式会社Ａｄｅｋａ Desulfurization agent for ultra-deep oxidative desulfurization and oxidative desulfurization method using the same
CN105148895A (en) * 2008-07-30 2015-12-16 沙特阿拉伯石油公司 Metallic clay based FCC gasoline sulfur reduction additive compositions
TW202202226A (en) * 2020-07-14 2022-01-16 美商Ｗ．Ｒ．康格雷氏公司 Process for catalytic cracking and equilibrium fcc catalyst

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5399329A (en) * 1993-07-06 1995-03-21 Aristech Chemical Corporation Hydrotalcite-like materials having a sheet-like morphology and process for production thereof
US5951851A (en) * 1997-10-31 1999-09-14 Poirier; Marc-Andre Sulfur removal from hydrocarbon fluids by contacting said fluids with hydrololcite-like adsorbent material
US6028023A (en) * 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO317500B1 (en) * 1998-03-13 2004-11-08 Statoil Asa Process and composition for reducing the sulfur content of a hydrocarbon mixture, and use thereof
JP2003507303A (en) * 1999-08-11 2003-02-25 アクゾ ノーベル ナムローゼ フェンノートシャップ Abrasion-resistant, shaped bodies containing crystalline anionic clay
KR100972705B1 (en) * 2002-06-28 2010-07-28 알베마를 네덜란드 비.브이. Fcc catalyst for reducing the sulfur content in gasoline and diesel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5399329A (en) * 1993-07-06 1995-03-21 Aristech Chemical Corporation Hydrotalcite-like materials having a sheet-like morphology and process for production thereof
US6028023A (en) * 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials
US5951851A (en) * 1997-10-31 1999-09-14 Poirier; Marc-Andre Sulfur removal from hydrocarbon fluids by contacting said fluids with hydrololcite-like adsorbent material

Also Published As

Publication number Publication date
AR047402A1 (en) 2006-01-18
WO2005081715A2 (en) 2005-09-09
EP1702027A2 (en) 2006-09-20
EP1702027A4 (en) 2011-01-12
KR20060124664A (en) 2006-12-05
AU2004316294B2 (en) 2010-05-27
JP2007517925A (en) 2007-07-05
AU2004316294A1 (en) 2005-09-09
CA2548167C (en) 2009-09-22
CA2548167A1 (en) 2005-09-09

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