WO2005076389A3 - Self-contained, alloy type, thin film anodes for lithium-ion batteries - Google Patents

Self-contained, alloy type, thin film anodes for lithium-ion batteries Download PDF

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Publication number
WO2005076389A3
WO2005076389A3 PCT/US2004/043445 US2004043445W WO2005076389A3 WO 2005076389 A3 WO2005076389 A3 WO 2005076389A3 US 2004043445 W US2004043445 W US 2004043445W WO 2005076389 A3 WO2005076389 A3 WO 2005076389A3
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WO
WIPO (PCT)
Prior art keywords
layers
lithium
self
contained
thin film
Prior art date
Application number
PCT/US2004/043445
Other languages
French (fr)
Other versions
WO2005076389A2 (en
WO2005076389A9 (en
Inventor
Prashant N Kumta
Jeff Maranchi
Moni Datta
Original Assignee
Univ Carnegie Mellon
Prashant N Kumta
Jeff Maranchi
Moni Datta
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Carnegie Mellon, Prashant N Kumta, Jeff Maranchi, Moni Datta filed Critical Univ Carnegie Mellon
Publication of WO2005076389A2 publication Critical patent/WO2005076389A2/en
Publication of WO2005076389A9 publication Critical patent/WO2005076389A9/en
Publication of WO2005076389A3 publication Critical patent/WO2005076389A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0414—Methods of deposition of the material by screen printing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0421—Methods of deposition of the material involving vapour deposition
    • H01M4/0423—Physical vapour deposition
    • H01M4/0426—Sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0421—Methods of deposition of the material involving vapour deposition
    • H01M4/0428—Chemical vapour deposition
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0483—Processes of manufacture in general by methods including the handling of a melt
    • H01M4/0485—Casting
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H01M4/0492—Chemical attack of the support material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

An electrically conductive substrate is provided upon which one or more layers of active materials, i.e. materials that act in a reversible manner with the charge carriers of an electrolyte, are formed. Prior to formation of these layers, the substrate is patterned so as to contain cavities. The active materials are then formed in one or more layers so that the total cumulative height of the layers is less than the entire depth of each of the cavities. The remaining 'unfilled' depth of the cavities provides suitable room for volumetric expansion and contraction of the active materials, resulting in little or no net volume change in the anode at any point during the cycling of the batteries.
PCT/US2004/043445 2003-12-23 2004-12-23 Self-contained, alloy type, thin film anodes for lithium-ion batteries WO2005076389A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53231803P 2003-12-23 2003-12-23
US60/532,318 2003-12-23

Publications (3)

Publication Number Publication Date
WO2005076389A2 WO2005076389A2 (en) 2005-08-18
WO2005076389A9 WO2005076389A9 (en) 2005-10-27
WO2005076389A3 true WO2005076389A3 (en) 2006-05-04

Family

ID=34837342

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/043445 WO2005076389A2 (en) 2003-12-23 2004-12-23 Self-contained, alloy type, thin film anodes for lithium-ion batteries

Country Status (1)

Country Link
WO (1) WO2005076389A2 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102169995B (en) * 2006-12-15 2014-09-24 东京应化工业株式会社 Negative electrode base member
FR2910721B1 (en) * 2006-12-21 2009-03-27 Commissariat Energie Atomique CURRENT-ELECTRODE COLLECTOR ASSEMBLY WITH EXPANSION CAVITIES FOR LITHIUM ACCUMULATOR IN THE FORM OF THIN FILMS.
US7816031B2 (en) 2007-08-10 2010-10-19 The Board Of Trustees Of The Leland Stanford Junior University Nanowire battery methods and arrangements
US8277974B2 (en) 2008-04-25 2012-10-02 Envia Systems, Inc. High energy lithium ion batteries with particular negative electrode compositions
US9012073B2 (en) 2008-11-11 2015-04-21 Envia Systems, Inc. Composite compositions, negative electrodes with composite compositions and corresponding batteries
US8426052B2 (en) 2009-05-08 2013-04-23 Robert Bosch Gmbh Li-ion battery with porous anode support
US8329327B2 (en) 2009-05-08 2012-12-11 Robert Bosch Gmbh Li-ion battery with variable volume reservoir
CN102630355A (en) 2009-11-03 2012-08-08 安维亚系统公司 High capacity anode materials for lithium ion batteries
US9061902B2 (en) 2009-12-18 2015-06-23 The Board Of Trustees Of The Leland Stanford Junior University Crystalline-amorphous nanowires for battery electrodes
DE102010063815A1 (en) * 2010-12-21 2012-06-21 Sgl Carbon Se Carbon-silicon multilayer systems
US9601228B2 (en) 2011-05-16 2017-03-21 Envia Systems, Inc. Silicon oxide based high capacity anode materials for lithium ion batteries
US9139441B2 (en) 2012-01-19 2015-09-22 Envia Systems, Inc. Porous silicon based anode material formed using metal reduction
US10553871B2 (en) 2012-05-04 2020-02-04 Zenlabs Energy, Inc. Battery cell engineering and design to reach high energy
US9780358B2 (en) 2012-05-04 2017-10-03 Zenlabs Energy, Inc. Battery designs with high capacity anode materials and cathode materials
US10020491B2 (en) 2013-04-16 2018-07-10 Zenlabs Energy, Inc. Silicon-based active materials for lithium ion batteries and synthesis with solution processing
US10886526B2 (en) 2013-06-13 2021-01-05 Zenlabs Energy, Inc. Silicon-silicon oxide-carbon composites for lithium battery electrodes and methods for forming the composites
WO2015024004A1 (en) 2013-08-16 2015-02-19 Envia Systems, Inc. Lithium ion batteries with high capacity anode active material and good cycling for consumer electronics
WO2016154617A1 (en) 2015-03-26 2016-09-29 David Mitlin Anodes for batteries based on tin-germanium-antimony alloys
DE102015120879A1 (en) * 2015-12-02 2017-06-08 Institut Für Solarenergieforschung Gmbh Process for producing a silicon-based porous electrode for a battery, in particular a lithium-ion battery
US10868290B2 (en) * 2016-02-26 2020-12-15 Apple Inc. Lithium-metal batteries having improved dimensional stability and methods of manufacture
US11094925B2 (en) 2017-12-22 2021-08-17 Zenlabs Energy, Inc. Electrodes with silicon oxide active materials for lithium ion cells achieving high capacity, high energy density and long cycle life performance

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030138554A1 (en) * 2002-01-17 2003-07-24 Hiromasa Yagi Method for manufacturing electrode for lithium secondary battery
EP1335438A1 (en) * 2000-09-01 2003-08-13 Sanyo Electric Co., Ltd. Negative electrode for lithium secondary cell and method for producing the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1335438A1 (en) * 2000-09-01 2003-08-13 Sanyo Electric Co., Ltd. Negative electrode for lithium secondary cell and method for producing the same
US20030138554A1 (en) * 2002-01-17 2003-07-24 Hiromasa Yagi Method for manufacturing electrode for lithium secondary battery

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BESENHARD J O ET AL: "METALLIZED MICROPOROUS POLYPROPYLENE MEMBRANES AS A SUPPORT FOR THIN-FILM ELECTRODES", 15 April 1993, JOURNAL OF POWER SOURCES, ELSEVIER, AMSTERDAM, NL, PAGE(S) 493-498, ISSN: 0378-7753, XP000412936 *

Also Published As

Publication number Publication date
WO2005076389A2 (en) 2005-08-18
WO2005076389A9 (en) 2005-10-27

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